DISPLAY PANEL AND DISPLAY APPARATUS
20260107658 ยท 2026-04-16
Assignee
Inventors
- Lixia QIU (Beijing, CN)
- Haiyan SUN (Beijing, CN)
- Dan Wang (Beijing, CN)
- Haidong WU (Beijing, CN)
- Tong WU (Beijing, CN)
Cpc classification
H10K85/6572
ELECTRICITY
H10K85/633
ELECTRICITY
H10K59/353
ELECTRICITY
H10K85/6574
ELECTRICITY
H10K85/636
ELECTRICITY
H10K85/615
ELECTRICITY
H10K85/626
ELECTRICITY
International classification
H10K59/00
ELECTRICITY
Abstract
The present disclosure belongs to the technical field of display. Disclosed are a display panel and a display apparatus. The display panel comprises a driving backplane, a pixel electrode layer, a light-emitting functional layer and a common electrode layer, which are sequentially arranged in a stacked manner, wherein the light-emitting functional layer has common material layers, which cover gaps between a plurality of light-emitting elements; and at least one of the common material layers contains a hole-transport-type nitrogen-containing compound, and the hole-transport-type nitrogen-containing compound has relatively high transverse resistance after becoming a film. The display panel can reduce the crosstalk between light-emitting elements.
Claims
1. A display panel, comprising a driving backplane, a pixel electrode layer, a light-emitting functional layer, and a common electrode layer stacked in sequence; wherein the light-emitting functional layer comprises a common material layer that covers the gaps between a plurality of light-emitting elements; at least one of the common material layers comprises a hole-transport-type nitrogen-containing compound, the structural formula of which is shown in Chemical Formula 1: ##STR00019## wherein, L.sub.1, L.sub.2, L.sub.3 are each independently selected from a single bond, a substituted or unsubstituted phenylene, a substituted or unsubstituted biphenylene, a substituted or unsubstituted naphthylene, a substituted or unsubstituted phenanthrenylene, a substituted or unsubstituted triphenylene, a substituted or unsubstituted 9,9-dimethylfluorenylene, a substituted or unsubstituted 9,9-diphenylfluorenylene, a substituted or unsubstituted spirofluorenylene, a substituted or unsubstituted carbazolylene; Ar.sub.1 to Ar.sub.3 are each independently selected from a substituted or unsubstituted aryl with 6 to 50 ring carbon atoms, a substituted or unsubstituted heteroaryl with 5 to 40 ring carbon atoms, and N(Ar.sub.4Ar.sub.5); Ar.sub.4 and Ar.sub.5 are each independently selected from a substituted or unsubstituted aryl with 6 to 50 ring carbon atoms, a substituted or unsubstituted heteroaryl with 5 to 40 ring carbon atoms; wherein at least one of Ar.sub.1 to Ar.sub.3 contains a benzopentacyclic fragment or a dithiophene fragment; when L.sub.1, L.sub.2, L.sub.3, Ar.sub.1, Ar.sub.2, Ar.sub.3, Ar.sub.4 or Ar.sub.5 has a substituent, the substituent is selected from deuterium, halogen, substituted or unsubstituted alkyl with 1 to 10 carbon atoms, substituted or unsubstituted cycloalkyl with 5 to 10 carbon atoms, substituted or unsubstituted aryl with 6 to 30 carbon atoms, and substituted or unsubstituted heteroaryl with 5 to 30 carbon atoms.
2. The display panel according to claim 1, wherein at least one of Ar.sub.1 to Ar.sub.3 has a group shown in the following Chemical Formula 2 or Chemical Formula 3: ##STR00020## wherein, * indicates connection with L.sub.1, L.sub.2, L.sub.3 or N; L.sub.4, L.sub.5 are each independently selected from a single bond, a substituted or unsubstituted phenylene, a substituted or unsubstituted biphenylene, a substituted or unsubstituted naphthylene, a substituted or unsubstituted phenanthrenylene, a substituted or unsubstituted triphenylene, a substituted or unsubstituted 9,9-dimethylfluorenylene, a substituted or unsubstituted 9,9-diphenylfluorenylene, a substituted or unsubstituted spirofluorenylene, a substituted or unsubstituted carbazolylene; X is selected from N(R.sub.2), C(R.sub.3R.sub.4), O, S, Si (R.sub.3R.sub.4); m is 0, 1 or 2; R.sub.1 is selected from the group consisting of deuterium, halogen, substituted or unsubstituted alkyl with 1 to 10 carbon atoms, substituted or unsubstituted cycloalkyl with 5 to 10 carbon atoms, substituted or unsubstituted aryl with 6 to 30 carbon atoms, and substituted or unsubstituted heteroaryl with 5 to 30 carbon atoms; R.sub.2 to R.sub.4 are each independently selected from a substituted or unsubstituted alkyl with 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl with 5 to 10 carbon atoms, a substituted or unsubstituted aryl with 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl with 5 to 30 carbon atoms; when the number of R.sub.1 is two, the two R.sub.1 are connected to each other to form an aromatic ring or an aliphatic ring, or remain unconnected; R.sub.3 and R.sub.4 are connected to each other to form an aromatic ring or an aliphatic ring, or remain unconnected.
3. The display panel according to claim 1, wherein the L.sub.1, L.sub.2 and L.sub.3 are each independently selected from a single bond, a phenylene, a biphenylene, a terphenylene, a naphthylene, and a trimphenylene; Ar.sub.1 to Ar.sub.5 are each independently selected from 9,9-dimethylfluorenyl, spirofluorenyl, benzothiophenyl, N-phenylcarbazolyl, phenyl, biphenyl, 9-phenyl-1,2,3,4-tetrahydrocarbazolyl, phenyl-substituted thieno[3,2-b]thienyl, thieno[3,2-b]thienyl, naphthyl, 9,9-diphenylfluorenyl, dibenzofuranyl, dibenzothienyl; and at least one of Ar.sub.1 to Ar.sub.3 contains phenyl-substituted thieno[3,2-b]thienyl or thieno[3,2-b]thienyl.
4. The display panel according to claim 1, wherein the hole-transport-type nitrogen-containing compound is selected from the group consisting of the following compounds: ##STR00021## ##STR00022## ##STR00023##
5. The display panel according to claim 1, wherein the light-emitting functional layer comprises a hole injection material layer; the hole injection maternal layer covers the gaps between the plurality of light-emitting elements and comprises the hole-transport-type nitrogen-containing compound.
6. The display panel according to claim 5, wherein a material of the hole injection material layer consists of the hole-transport-type nitrogen-containing compound and a P-type dopant, and a mass content of the P-type dopant does not exceed 3%.
7. The display panel according to claim 5, wherein a material of the hole injection material layer consists of the hole-transport-type nitrogen-containing compound and a P-type dopant, and a mass content of the P-type dopant is between 0.5% and 1.5%.
8. The display panel according to claim 1, wherein the light-emitting functional layer comprises a P-type charge generation material layer, which covers the gaps between the plurality of light-emitting elements and comprises the hole-transport-type nitrogen-containing compound.
9. The display panel according to claim 8, wherein a material of the P-type charge generation material layer consists of the hole-transport-type nitrogen-containing compound and a P-type dopant, and a mass content of the P-type dopant is not less than 10%.
10. The display panel according to claim 8, wherein a material of the P-type charge generation material layer consists of the hole-transport-type nitrogen-containing compound and a P-type dopant, and a mass content of the P-type dopant is between 10% and 15%.
11. The display panel according to claim 1, wherein the light-emitting functional layer comprises an N-type charge generation material layer, and the N-type charge generation material layer covers the gaps between the plurality of light-emitting elements; a material of the N-type charge generation material layer consists of an electron transport compound and an N-type dopant; the electron transport compound contains a phenanthroline fragment or a phosphorus oxygen fragment.
12. The display panel according to claim 1, wherein the display panel is provided with a partition structure between the light-emitting elements; and at least one layer of the common material layer is discontinuously provided at the partition structure.
13. The display panel according to claim 12, wherein the display panel is provided with a pixel definition layer between the pixel electrode layer and the light-emitting function layer, and the partition structure is provided in the pixel definition layer.
14. The display panel according to claim 12, wherein the light-emitting element comprises a red light-emitting element, a green light-emitting element and a blue light-emitting element; the partition structure is arranged between the red light-emitting element and the green light-emitting element.
15. The display panel according to claim 12, wherein the light-emitting functional layer comprises a hole injection material layer covering the gaps between the plurality of light-emitting elements; the hole injection material layer is discontinuously arranged at the partition structure.
16. The display panel according to claim 12, wherein the light-emitting functional layer comprises a charge-generation material layer covering gaps between the plurality of light-emitting elements, and the charge-generation material layer is discontinuously disposed at the partition structure.
17. The display panel according to claim 1, wherein the display panel further comprises an auxiliary electrode layer disposed on a side of the common electrode layer away from the driving backplane, and the auxiliary electrode layer is electrically connected to the common electrode layer and does not overlap with the light-emitting element.
18. The display panel according to claim 17, wherein the display panel is provided with an organic cover layer between the common electrode layer and the auxiliary electrode layer; the organic cover layer comprises a connection via hole exposing the common electrode layer, and the auxiliary electrode layer is electrically connected to the common electrode layer through the connection via hole.
19. A display apparatus, comprising the display panel; wherein the display panel comprises a driving backplane, a pixel electrode layer, a light-emitting functional layer, and a common electrode layer stacked in sequence; the light-emitting functional layer comprises a common material layer that covers the gaps between a plurality of light-emitting elements; at least one of the common material layers comprises a hole-transport-type nitrogen-containing compound, the structural formula of which is shown in Chemical Formula 1: ##STR00024## wherein, L.sub.1, L.sub.2, L.sub.3 are each independently selected from a single bond, a substituted or unsubstituted phenylene, a substituted or unsubstituted biphenylene, a substituted or unsubstituted naphthylene, a substituted or unsubstituted phenanthrenylene, a substituted or unsubstituted triphenylene, a substituted or unsubstituted 9,9-dimethylfluorenylene, a substituted or unsubstituted 9,9-diphenylfluorenylene, a substituted or unsubstituted spirofluorenylene, a substituted or unsubstituted carbazolylene; Ar.sub.1 to Ar.sub.3 are each independently selected from a substituted or unsubstituted aryl with 6 to 50 ring carbon atoms, a substituted or unsubstituted heteroaryl with 5 to 40 ring carbon atoms, and N(Ar.sub.4Ar.sub.5); Ar.sub.4 and Ar.sub.5 are each independently selected from a substituted or unsubstituted aryl with 6 to 50 ring carbon atoms, a substituted or unsubstituted heteroaryl with 5 to 40 ring carbon atoms; wherein at least one of Ar.sub.1 to Ar.sub.3 contains a benzopentacyclic fragment or a dithiophene fragment; when L.sub.1, L.sub.2, L.sub.3, Ar.sub.1, Ar.sub.2, Ar.sub.3, Ar.sub.4 or Ar.sub.5 has a substituent, the substituent is selected from deuterium, halogen, substituted or unsubstituted alkyl with 1 to 10 carbon atoms, substituted or unsubstituted cycloalkyl with 5 to 10 carbon atoms, substituted or unsubstituted aryl with 6 to 30 carbon atoms, and substituted or unsubstituted heteroaryl with 5 to 30 carbon atoms.
20. The display apparatus according to claim 19, wherein at least one of Ar.sub.1 to Ar.sub.3 has a group shown in the following Chemical Formula 2 or Chemical Formula 3: ##STR00025## wherein, * indicates connection with L.sub.1, L.sub.2, L.sub.3 or N; L.sub.4, L.sub.5 are each independently selected from a single bond, a substituted or unsubstituted phenylene, a substituted or unsubstituted biphenylene, a substituted or unsubstituted naphthylene, a substituted or unsubstituted phenanthrenylene, a substituted or unsubstituted triphenylene, a substituted or unsubstituted 9,9-dimethylfluorenylene, a substituted or unsubstituted 9,9-diphenylfluorenylene, a substituted or unsubstituted spirofluorenylene, a substituted or unsubstituted carbazolylene; X is selected from N(R.sub.2), C(R.sub.3R.sub.4), O, S, Si (R.sub.3R.sub.4); m is 0, 1 or 2; R.sub.1 is selected from the group consisting of deuterium, halogen, substituted or unsubstituted alkyl with 1 to 10 carbon atoms, substituted or unsubstituted cycloalkyl with 5 to 10 carbon atoms, substituted or unsubstituted aryl with 6 to 30 carbon atoms, and substituted or unsubstituted heteroaryl with 5 to 30 carbon atoms; R.sub.2 to R.sub.4 are each independently selected from a substituted or unsubstituted alkyl with 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl with 5 to 10 carbon atoms, a substituted or unsubstituted aryl with 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl with 5 to 30 carbon atoms; when the number of R.sub.1 is two, the two R.sub.1 are connected to each other to form an aromatic ring or an aliphatic ring, or remain unconnected; R.sub.3 and R.sub.4 are connected to each other to form an aromatic ring or an aliphatic ring, or remain unconnected.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0038] The drawings here are incorporated into the specification and constitute a part of the specification, show embodiments in consistent with the present disclosure, and are used together with the specification to explain principles of the present disclosure. Obviously, the drawings in the following description are only some embodiments of the present disclosure. For those of ordinary skill in the art, other drawings can be obtained based on these drawings without creative work.
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DESCRIPTION OF REFERENCE NUMERALS
[0055] AA, display area; AE, anode; BB, peripheral area; BEBL, electron blocking layer of blue light-emitting element; BEML, organic light-emitting layer of blue light-emitting element; B, blue light-emitting element; BP, substrate; Buff, inorganic buffer layer; CE, cathode; CFL, color filter layer; CGL, charge generation layer; CGLX, charge generation material layer; CML, organic cover layer; CNT, connection via; COML, common electrode layer; COMLX, auxiliary electrode layer; CVD1, first inorganic encapsulation layer; CVD2, second inorganic encapsulation layer; DBP, driving backplane; DH, row direction; DRL, driving layer; DV, column square; DX, first direction; DY, second direction; EBL, electron blocking layer; EFL, light-emitting functional layer; EFU, light-emitting functional unit; EIL, electron injection layer; EILX, electron injection material layer; ELS, light-emitting stack structure; EML, organic light-emitting layer; ETL, electron transport layer; ETLX, electron transport material layer; GEBL, electron blocking layer of green light-emitting element layer; GEML, organic light-emitting layer of green light-emitting element; GI, gate insulating layer; G, green light-emitting element; GT, gate layer; HBL, hole blocking layer; HBLX, hole blocking material layer; HIL, hole injection layer; HILX, hole injection material layer; HTL, hole transport layer; HTLX, hole transport material layer; IP, organic encapsulation layer; ILD, interlayer dielectric layer; NCGL, N-type charge generation layer; NCGLX, N-type charge generation material layer; PCGL, P-type charge generation layer; PCGLX, P-type charge generation material layer; PDL, pixel definition layer; PE, pixel electrode; PEL, pixel electrode layer; PIXL, pixel layer; PLN, planarization layer; PNL, display panel; PTS, partition structure; QDL, quantum dot layer; REBL, electron blocking layer of red light-emitting element; REML, organic light-emitting layer of red light-emitting element; R, red light-emitting element; SCL, semiconductor layer; SD, source and drain metal layer; TFE, thin film encapsulation layer; TFT, thin film transistor; TSL, touch function layer; LD, light-emitting element.
DETAILED DESCRIPTION
[0056] Now, exemplary embodiments will be described more fully with reference to the accompanying drawings. However, the exemplary embodiments can be implemented in various forms and should not be construed as limited to the embodiments set forth herein. On the contrary, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of the exemplary embodiments to those skilled in the art. The same reference numerals in the drawings denote the same or similar structures, and thus their detailed descriptions will be omitted. In addition, the drawings are only schematic illustrations of the present disclosure and are not necessarily drawn to scale.
[0057] Although relative terms such as upper and lower are used in this specification to describe the relative relationship of one component to another component in the drawings, these terms are used in this specification for convenience only, for example, according to the direction of the example shown in the drawings. It can be understood that if the element in the drawing is turned upside down, the component described as upper will become lower. When a structure is on another structure, it may mean that the structure is integrally formed on the other structure, or that the structure is directly arranged on the other structure, or that the structure is indirectly arranged on the other structure through another structure.
[0058] The terms a, an, the, and at least one are used to indicate the presence of one or more elements/components/and the like; the terms including and having are used to indicate an open-ended inclusion and mean that in addition to the listed elements/components/and the like, there may be additional elements/components/and the like; the terms first, second, and third are used only as labels and are not intended to limit the number of their objects.
[0059] The embodiments of the present disclosure provide a display panel PNL, as shown in
[0060] In the embodiments of the present disclosure, the sub-pixels in the display panel PNL are thin-film self-luminescence light-emitting elements LD, such as OLED, PLED, QLED, and the like. Furthermore, the light-emitting elements LD in the display area AA include light-emitting elements LD of different colors. For example, in the examples of
[0061] In an embodiment of the present disclosure, as shown in
[0062] In an embodiment of the present disclosure, as shown in
[0063] Optionally, the substrate BP may be an inorganic material substrate, an organic material substrate, or a composite substrate formed by stacking an inorganic material substrate and an organic material substrate. For example, in some embodiments of the present disclosure, the material of the substrate BP may be soda-lime glass, quartz glass, sapphire glass, and so on. In other embodiments of the present disclosure, the material of the substrate BP may be polymethyl methacrylate, polyvinyl alcohol, polyvinyl phenol, polyethersulfone, polyimide, polyamide, polyacetal, polycarbonate, polyethylene terephthalate, polyethylene naphthalate, or a combination thereof. In other embodiments of the present disclosure, the substrate BP may also be a flexible substrate, for example, the material of the substrate BP may include polyimide.
[0064] Optionally, in the driving layer DRL, any pixel driving circuit may include a thin-film transistor TFT and a storage capacitor. Furthermore, the thin-film transistor TFT may be selected from a top-gate thin-film transistor, a bottom-gate thin-film transistor, or a dual-gate thin-film transistor; the material of the active layer of the thin-film transistor may be amorphous silicon semiconductor material, low-temperature polysilicon semiconductor material, metal oxide semiconductor material, organic semiconductor material, carbon nanotube semiconductor material, or other types of semiconductor materials; the thin-film transistor may be an N-type thin-film transistor or a P-type thin-film transistor.
[0065] It can be understood that in the pixel driving circuit, any two transistors may be of the same type or different types. For example, in some embodiments, in a pixel driving circuit, some transistors may be N-type transistors and some transistors may be P-type transistors. For another example, in other embodiments, in a pixel driving circuit, some transistors may include active layers made of low-temperature polysilicon semiconductor material, and some transistors may include active layers made of metal oxide semiconductor material. In some embodiments of the present disclosure, the thin-film transistor is a low-temperature polysilicon transistor. In other embodiments of the present disclosure, some thin-film transistors are low-temperature polysilicon transistors, and some thin-film transistors are metal oxide transistors.
[0066] Optionally, the driving layer DRL may include a semiconductor layer SCL, a gate insulating layer GI, a gate layer GT, an interlayer dielectric layer ILD, a source-drain metal layer SD, a planarization layer PLN, and the like, stacked between the substrate BP and the pixel layer PIXL. Each thin-film transistor and storage capacitor may be formed by the semiconductor layer SCL, the gate insulating layer GI, the gate layer GT, the interlayer dielectric layer ILD, the source-drain metal layer SD, and the like. The positional relationship of each layer may be determined according to the layer structure of the thin-film transistor. Furthermore, the semiconductor layer SCL can be used to form the channel region of a transistor, and if necessary, partial routing or conductive structures can also be formed by conducting. The gate layer may be used to form one or more of the scan line, the reset control line, the light-emitting control line, and the like, and may also be used to form the gate of the transistor, and may also be used to form part or all of the electrode plate of the storage capacitor. The source-drain metal layer may be used to form the data line, the driving power supply voltage line, and the like, and may also be used to form part of the electrode plate of the storage capacitor. Of course, in other embodiments of the present disclosure, the driving layer DRL may also include other layers as needed, for example, it may also include a light-shielding layer between the semiconductor layer SCL and the substrate BP. As needed, any one of the above semiconductor layer SCL, gate layer GT, source-drain metal layer SD, and the like may also be multiple layers, for example, the driving layer DRL may include two different semiconductor layers SCL, or two or three source-drain metal layers SD, or two or three gate layers GT; accordingly, the insulating layers in the driving layer DRL (for example, the gate insulating layer GI, the interlayer dielectric layer ILD, the planarization layer PLN, and the like) may be increased or decreased as needed, or new insulating layers may be added as needed.
[0067] Optionally, the driving layer DRL may also include a passive layer, which may be arranged on the surface of the source-drain metal layer SD away from the substrate BP to protect the source-drain metal layer SD.
[0068] As an example, as shown in
[0069] It can be understood that the above example of the driving backplane DBP is only one possible form of the driving backplane DBP in the embodiments of the present disclosure. In other embodiments of the present disclosure, the driving backplane DBP may also include other structures, for example, the driving backplane DBP may also be a passive driving glass substrate, a silicon-based driving substrate, and the like
[0070] As shown in
[0071] Furthermore, the pixel layer PIXL may also include a pixel definition layer PDL between the pixel electrode layer PEL and the light-emitting functional layer EFL. The pixel definition layer PDL includes multiple pixel openings corresponding to the multiple pixel electrodes PE, and any pixel opening exposes at least part of the area of the corresponding pixel electrode. For example, the pixel definition layer PDL covers the edges of the pixel electrode PE and exposes at least part of the internal area of the pixel electrode PE, so that the pixel definition layer PDL can effectively define the actual effective area of the pixel electrode PE (the area directly connected to the light-emitting functional unit EFU), thereby defining the light-emitting area and light-emitting area of the light-emitting element LD. The light-emitting functional layer EFL at least covers the pixel electrode PE exposed by the pixel definition layer PDL. The common electrode layer COML may cover the light-emitting functional layer EFL in the display area. The pixel electrode PE and the common electrode layer COML provide carriers such as electrons and holes to the light-emitting functional layer EFL, so that the light-emitting functional layer EFL emits light. The part of the light-emitting functional layer EFL between the pixel electrode PE and the common electrode layer COML may serve as the light-emitting functional unit EFU. The pixel electrode PE, the common electrode layer COML, and the light-emitting functional unit EFU form the light-emitting element LD. One of the pixel electrode PE and the common electrode layer COML serves as the anode of the light-emitting element LD, and the other serves as the cathode of the light-emitting element LD.
[0072] In an example, the pixel electrode PE serves as the anode of the light-emitting element LD, and the common electrode layer COML serves as the cathode of the light-emitting element LD.
[0073] It can be understood that the materials and layers of the light-emitting functional unit EFU are different for different types of light-emitting elements.
[0074] For example, as shown in
[0075] For another example, as shown in
[0076] In the embodiments of the present disclosure, as shown in
[0077] In the examples of
[0078] The hole adjustment layer may include one or more of a hole injection layer HIL, a hole transport layer HTL, and an electron blocking layer EBL, wherein the hole injection layer HIL, the hole transport layer HTL, and the electron blocking layer EBL are stacked in sequence from the anode AE to the light-emitting layer. It can be understood that in some examples, one or more of the hole injection layer HIL, the hole transport layer HTL, and the electron blocking layer EBL may be provided as a multi-layer stacked structure, for example, the hole transport layer HTL may include a first hole transport layer and a second hole transport layer stacked.
[0079] The electron adjustment layer may include one or more of an electron injection layer EIL, an electron transport layer ETL, and a hole blocking layer HBL, wherein the electron injection layer EIL, the electron transport layer ETL, and the hole blocking layer HBL are stacked in sequence from the cathode CE to the light-emitting layer. It can be understood that in some examples, one or more of the electron injection layer EIL, the electron transport layer ETL, and the hole blocking layer HBL may be provided as a multi-layer stacked structure, for example, the electron transport layer ETL may include a first electron transport layer and a second electron transport layer stacked.
[0080] In the examples of
[0081] Optionally, the light-emitting functional unit EFU may also include a charge generation layer CGL between adjacent light-emitting stacked structures ELS to improve the efficiency of injecting electrons and holes into the adjacent light-emitting stacked structures ELS. For example, the charge generation layer CGL includes an N-type charge generation layer NCGL and a P-type charge generation layer PCGL stacked between adjacent light-emitting stacked structures ELS; the N-type charge generation layer NCGL is adjacent to the electron adjustment layer of one light-emitting stacked structure ELS and is used to inject electrons into the electron adjustment layer of the light-emitting stacked structure ELS; the P-type charge generation layer PCGL is adjacent to the hole adjustment layer of the other light-emitting stacked structure ELS and is used to inject holes into the hole adjustment layer of the light-emitting stacked structure ELS. In other words, the P-type charge generation layer PCGL is arranged on the side of the N-type charge generation layer NCGL away from the anode AE. Of course, it can be understood that in other examples, the charge generation layer CGL may also include other structures.
[0082] It can be understood that in some other embodiments of the present disclosure, the electron adjustment layer of the light-emitting stacked structure ELS may be omitted, or may include other structures in addition to the electron injection layer EIL, the electron transport layer ETL, and the hole blocking layer HBL.
[0083] It can be understood that in some other embodiments of the present disclosure, the hole adjustment layer of the light-emitting stacked structure ELS may be omitted, or may include other structures in addition to the hole injection layer HIL, the hole transport layer HTL, and the electron blocking layer EBL.
[0084] It can be understood that when multiple light-emitting layers are provided in the light-emitting stacked structure ELS, the colors of the multiple light-emitting layers may be the same or different, and the types of the multiple light-emitting layers may be the same or different. For example, two light-emitting layers are provided in a light-emitting stacked structure ELS, and the two light-emitting layers may be a red organic light-emitting layer EML and a green organic light-emitting layer EML stacked. For another example, two light-emitting layers are provided in a light-emitting stacked structure ELS, and the two light-emitting layers may be a red organic light-emitting layer EML and a red quantum dot layer QDL stacked.
[0085] It can be understood that for any light-emitting stack structure (ELS), it can be provided with a light-emitting layer (such as a quantum dot layer QDL or an organic light-emitting layer EML), as well as one or more of a hole injection layer HIL, an electron transport layer ETL, an electron blocking layer EBL, a hole blocking layer HBL, an electron transport layer ETL, and an electron injection layer EIL, or other layers can be added as needed. Of course, in the light-emitting stack structure ELS, one or more of the hole injection layer HIL, the electron transport layer ETL, the electron blocking layer EBL, the hole blocking layer HBL, the electron transport layer ETL, and the electron injection layer EIL can also be omitted. For the two light-emitting stack structures ELS of the same light-emitting element LD, the layer structures of the two light-emitting stack structures ELS can be the same or different.
[0086] For example, in the example shown in
[0087] Referring to
[0088] In some embodiments of the present disclosure, referring to
[0089] In some embodiments of the present disclosure, referring to
[0090] In the embodiments of the present disclosure, due to process reasons, such as when using an open mask process, the light-emitting functional layer EFL may include a common material layer, which can cover the gaps between a plurality of light-emitting elements LD, causing adjacent light-emitting elements LD to be connected through the common material layer. For example, the common material layer can cover the display area AA and be applied to each light-emitting functional unit EFU at the same time, and the part of the common material layer in each light-emitting functional unit EFU serves as the structural layer of the light-emitting functional unit EFU (such as one of the hole injection layer HIL, the hole transport layer HTL, the electron blocking layer EBL, the N-type charge generation layer NCGL, the P-type charge generation layer PCGL, the hole blocking layer HBL, the electron transport layer ETL, and the electron injection layer EIL).
[0091] For example, in the example shown in
[0092] It can be understood that the common material layer illustrated in
[0093] However, when a light-emitting element LD is loaded with a driving current to emit light, the driving current may leak laterally along the common material layer to another light-emitting element LD, causing the other light-emitting element LD to emit light, which results in crosstalk between adjacent light-emitting elements LD. Especially, when the green light-emitting element G emits light, it can cause the adjacent red light-emitting element R to emit light. The lower the gray level of the green light-emitting element G, the closer the gray level of the crosstalked red light-emitting element R is to the gray level of the green light-emitting element G, which makes the crosstalk more severe.
[0094] When the inventor analyzed this crosstalk, it was found that in related technologies, the lateral resistance of some common material layers in the light-emitting functional layer EFL is relatively small, which leads to severe lateral leakage. Especially, the lateral resistance of at least part of the common material layers with hole transport materials in the light-emitting functional layer EFL is relatively small, resulting in a large lateral current. For example, in some related technologies, the hole injection layer and the hole transport layer use the same hole transport materials, and the lateral resistance of these hole transport materials is relatively small; moreover, the hole injection layer is doped with P-type dopants, which increases the lateral current of the hole injection layer by hundreds of times.
[0095] Therefore, in some embodiments of the present disclosure, at least one common material layer of the light-emitting functional layer EFL can include a hole-transport-type nitrogen-containing compound, and the structural formula of the hole-transport-type nitrogen-containing compound is as shown in Chemical Formula 1:
##STR00010## [0096] wherein, L.sub.1, L.sub.2, L.sub.3 are each independently selected from a single bond, a substituted or unsubstituted phenylene, a substituted or unsubstituted biphenylene, a substituted or unsubstituted naphthylene, a substituted or unsubstituted phenanthrenylene, a substituted or unsubstituted triphenylene, a substituted or unsubstituted 9,9-dimethylfluorenylene, a substituted or unsubstituted 9,9-diphenylfluorenylene, a substituted or unsubstituted spirofluorenylene, a substituted or unsubstituted carbazolylene; [0097] Ar.sub.1 to Ar.sub.3 are each independently selected from a substituted or unsubstituted aryl with 6 to 50 ring carbon atoms, a substituted or unsubstituted heteroaryl with 5 to 40 ring carbon atoms, and N(Ar.sub.4Ar.sub.5); Ar.sub.4 and Ar.sub.5 are each independently selected from a substituted or unsubstituted aryl with 6 to 50 ring carbon atoms, a substituted or unsubstituted heteroaryl with 5 to 40 ring carbon atoms; wherein at least one of Ar.sub.1 to Ar.sub.3 contains a benzopentacyclic fragment or a dithiophene fragment; [0098] when L.sub.1, L.sub.2, L.sub.3, Ar.sub.1, Ar.sub.2, Ar.sub.3, Ar.sub.4 or Ar.sub.5 has a substituent, the substituent is selected from deuterium, halogen, substituted or unsubstituted alkyl with 1 to 10 carbon atoms, substituted or unsubstituted cycloalkyl with 5 to 10 carbon atoms, substituted or unsubstituted aryl with 6 to 30 carbon atoms, and substituted or unsubstituted heteroaryl with 5 to 30 carbon atoms.
[0099] In this embodiment, at least one common material layer uses a hole-transport-type nitrogen-containing compound, for example, the hole injection material layer HILX or the hole transport material layer HTLX uses a hole-transport-type nitrogen-containing compound. The hole-transport-type nitrogen-containing compound contains a benzopentacyclic fragment or a dithiophene fragment, which makes the hole-transport-type nitrogen-containing compound have a large steric hindrance and a large lateral resistance, thereby reducing the lateral leakage of the common material layer using the hole-transport-type nitrogen-containing compound, and weakening or eliminating the crosstalk between adjacent light-emitting elements LD.
[0100] In an embodiment of the present disclosure, the L.sub.1, L.sub.2 and L.sub.3 are each independently selected from a single bond, a substituted or unsubstituted phenylene, a substituted or unsubstituted biphenylene, a substituted or unsubstituted terphenylene, a substituted or unsubstituted naphthylene, and a substituted or unsubstituted trimethyleneene.
[0101] In an embodiment of the present disclosure, when L.sub.1, L.sub.2 and L.sub.3 have substituents, the substituents are selected from deuterium, fluorine, methyl, ethyl, propyl, isopropyl, tert-butyl, cyclofluorenyl, cyclohexyl, adamantyl, phenyl, naphthyl, biphenyl, carbazolyl, benzothiophenyl and benzofuranyl.
[0102] In an example, L.sub.1, L.sub.2 and L.sub.3 are each independently selected from a single bond, a phenylene, a biphenylene, a terphenylene, a naphthylene, and a trimphenylene.
[0103] In an embodiment of the present disclosure, when Ar.sub.1, Ar.sub.2, Ar.sub.3, Ar.sub.4 or Ar.sub.5 has a substituent, the substituent is selected from deuterium, fluorine, methyl, ethyl, propyl, isopropyl, tert-butyl, cyclofluorenyl, cyclohexyl, adamantyl, phenyl, naphthyl, biphenyl, carbazolyl, benzothiophenyl, and benzofuranyl.
[0104] In an embodiment of the present disclosure, at least one of Ar.sub.1 to Ar.sub.3 has a group shown in the following Chemical Formula 2 or Chemical Formula 3:
##STR00011## [0105] wherein, * indicates connection with L.sub.1, L.sub.2, L.sub.3 or N; [0106] L.sub.4, L.sub.5 are each independently selected from a single bond, a substituted or unsubstituted phenylene, a substituted or unsubstituted biphenylene, a substituted or unsubstituted naphthylene, a substituted or unsubstituted phenanthrenylene, a substituted or unsubstituted triphenylene, a substituted or unsubstituted 9,9-dimethylfluorenylene, a substituted or unsubstituted 9,9-diphenylfluorenylene, a substituted or unsubstituted spirofluorenylene, a substituted or unsubstituted carbazolylene; [0107] X is selected from N(R.sub.2), C(R.sub.3R.sub.4), O, S, Si (R.sub.3R.sub.4); m is 0, 1 or 2; [0108] R.sub.1 is selected from the group consisting of deuterium, halogen, substituted or unsubstituted alkyl with 1 to 10 carbon atoms, substituted or unsubstituted cycloalkyl with 5 to 10 carbon atoms, substituted or unsubstituted aryl with 6 to 30 carbon atoms, and substituted or unsubstituted heteroaryl with 5 to 30 carbon atoms; [0109] R.sub.2 to R.sub.4 are each independently selected from a substituted or unsubstituted alkyl with 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl with 5 to 10 carbon atoms, a substituted or unsubstituted aryl with 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl with 5 to 30 carbon atoms; [0110] When the number of R.sub.1 is two and they are connected to two adjacent carbon atoms respectively, the two R.sub.1 can also be connected to each other to form an aromatic ring or an aliphatic ring; [0111] R.sub.3 and R.sub.4 can also be connected to each other to form an aromatic ring or an aliphatic ring. It is understood that R.sub.3 and R.sub.4 can be independently connected to C or Si without being connected to each other to form a ring, or they can be connected to each other to form an aromatic ring or an aliphatic ring.
[0112] In an example, when L.sub.4 and L.sub.5 have a substituent, the substituent is selected from deuterium, fluorine, methyl, ethyl, propyl, isopropyl, tert-butyl, cyclofluorenyl, cyclohexyl, adamantyl, phenyl, naphthyl, biphenyl, carbazolyl, benzothiophenyl, and benzofuranyl.
[0113] In an example, L.sub.4 and L.sub.5 are each independently selected from a single bond, a phenylene, a biphenylene, a terphenylene, a naphthyl, and a trimphenylene.
[0114] In an example, R.sub.1 is selected from deuterium, fluorine, methyl, ethyl, propyl, isopropyl, tert-butyl, cyclofluorenyl, cyclohexyl, adamantyl, phenyl, naphthyl, biphenyl, carbazolyl, benzothienyl, and benzofuranyl.
[0115] In an example, R.sub.2 to R.sub.4 are each independently selected from methyl, ethyl, propyl, isopropyl, tert-butyl, cyclofluorenyl, cyclohexyl, adamantyl, phenyl, naphthyl, biphenyl, carbazolyl, benzothiophenyl, and benzofuranyl.
[0116] In an embodiment of the present disclosure, the Ar.sub.1 to Ar.sub.5 are each independently selected from 9,9-dimethylfluorenyl, spirofluorenyl, benzothiophenyl, N-phenylcarbazolyl, phenyl, biphenyl, 9-phenyl-1,2,3,4-tetrahydrocarbazolyl, phenyl-substituted thieno[3,2-b]thienyl, thieno[3,2-b]thienyl, naphthyl, 9,9-diphenylfluorenyl, dibenzofuranyl, dibenzothienyl; and at least one of Ar.sub.1 to Ar.sub.3 contains phenyl-substituted thieno[3,2-b]thienyl or thieno[3,2-b]thienyl.
[0117] In an embodiment of the present disclosure, the hole-transport-type nitrogen-containing compound is selected from the group consisting of the following compounds:
##STR00012## ##STR00013## ##STR00014## ##STR00015## ##STR00016## ##STR00017## ##STR00018##
[0118] In the embodiment of the present disclosure, the performance of some hole-transport-type nitrogen-containing compounds was also tested. In this test, the control compound used was the common hole transport compound NPB. Both the test compound and the control compound were doped with 3% of P-type dopant, and then the lateral current was measured at a test voltage of 10V. The test results were normalized to the lateral current of NPB as the benchmark. The test results are shown in Table 1:
TABLE-US-00001 TABLE 1 Compound Lateral current NPB (Reference compound) 100.0% Compound 1 11.9% Compound 2 50.2% Compound 3 52.6% Compound 4 48.1% Compound 5 60.2% Compound 6 46.3% Compound 7 70.1% Compound 8 50% Compound 9 49.2% Compound 10 61.2% Compound 16 10.1% Compound 17 8.7% Compound 18 8.90% Compound 19 7.80% Compound 20 11.3% Compound 21 35.4%
[0119] It can be seen from the test data in Table 1 that the hole-transport-type nitrogen-containing compound provided in the embodiment of the present disclosure can effectively reduce the lateral current. Therefore, when the hole-transport-type nitrogen-containing compound is applied to the common material layer of the light-emitting functional layer EFL, it can avoid that the lateral current of the common material layer is too large to cause crosstalk between different light-emitting elements LD.
[0120] In some embodiments of the present disclosure, L.sub.1, L.sub.2 and L.sub.3 are all single bonds, so that the hole-transport-type nitrogen-containing compound has a large steric hindrance, thereby reducing the lateral current of the hole-transport-type nitrogen-containing compound after film formation.
[0121] In some embodiments of the present disclosure, at least one of Ar.sub.1, Ar.sub.2, and Ar.sub.3 is a 9,9-dimethylfluorenyl, 9,9-diphenylfluorenyl, or spirofluorenyl, and the fluorenyl group is connected to the central nitrogen atom of the hole-transporting nitrogen-containing compound by a single bond; at least one of Ar.sub.1, Ar.sub.2, and Ar.sub.3 is a substituted or unsubstituted thieno[3,2-b]thienyl, or a substituted or unsubstituted benzothienyl; wherein, either the substituted or unsubstituted benzothienyl is connected to the central nitrogen atom of the hole-transporting nitrogen-containing compound by a single bond, and the substituted or unsubstituted thieno[3,2-b]thienyl can be connected to the central nitrogen atom of the hole-transporting nitrogen-containing compound by a single bond or a phenylene group.
[0122] It is understood that in the light-emitting functional layer EFL of the embodiment of the present disclosure, there may be multiple common material layers with hole transport materials. The hole-transport-type nitrogen-containing compound provided in the embodiment of the present disclosure may be present in only one layer of these common material layers, or may be present in multiple layers; the embodiment of the present disclosure does not necessarily require that all hole transport materials in the light-emitting functional layer EFL are hole-transport-type nitrogen-containing compounds.
[0123] In an embodiment of the present disclosure, the light-emitting functional layer EFL includes a hole injection material layer HILX, and the hole injection material layer HILX covers the gaps between the plurality of light-emitting elements, for example, covers the display area AA. In this way, the hole injection material layer HILX is a common material layer of the light-emitting functional layer EFL. The portion of the hole injection material layer HILX in each light-emitting functional unit EFU can serve as the hole injection layer HIL of the light-emitting functional unit EFU. In this embodiment, the hole injection material layer HILX can include the above-mentioned hole-transport-type nitrogen-containing compound, thereby reducing the lateral resistance of the hole injection material layer HILX.
[0124] In some examples of this embodiment, the hole injection material layer HILX may also contain a P-type dopant to enhance the hole injection capability of the hole injection layer HIL. The mass content of the P-type dopant in the hole injection material layer HILX does not exceed 3% to avoid excessive lateral current of the hole injection material layer HILX due to excessive content of the P-type dopant. Furthermore, the mass content of the P-type dopant in the hole injection material layer HILX is 0.5% to 1.5%, for example, 1%.
[0125] In some examples of this embodiment, the material of the hole injection material layer HILX may consist of a hole-transport-type nitrogen-containing compound and a P-type dopant; the mass content of the P-type dopant is between 0.5% and 1.5%. Compared with the related art, the lateral current of the hole injection material layer HILX can be greatly reduced, so that the crosstalk between the light-emitting elements LD is greatly reduced or eliminated.
[0126] This embodiment also provides test results of the lateral current of the hole injection material layer HILX when the hole injection material layer HILX includes different doping amounts (mass content) of the P-type dopant. Referring to
[0127] In an embodiment of the present disclosure, referring to
[0128] For example, in an example, the hole transport material layer HTLX is made of the hole-transport-type nitrogen-containing compound. For another example, the hole transport material layer HTLX includes multiple different and mutually mixed materials, at least one of which is the hole-transport-type nitrogen-containing compound.
[0129] In an embodiment of the present disclosure, referring to
[0130] In an example of this embodiment, the P-type charge generation material layer PCGLX may include the hole-transport-type nitrogen-containing compound described above, which can reduce the lateral current of the P-type charge generation material layer PCGLX and weaken or eliminate the crosstalk between the light-emitting elements LD.
[0131] Optionally, the P-type charge generation material layer PCGLX is also doped with a P-type dopant to improve the ability of the P-type charge generation layer PCGL to generate holes. Furthermore, the material of the P-type charge generation material layer PCGLX consists of the hole-transport-type nitrogen-containing compound and the P-type dopant, and the mass content of the P-type dopant is not less than 10%. For example, the material of the P-type charge generation layer PCGL consists of the hole-transport-type nitrogen-containing compound and the P-type dopant, and the mass content of the P-type dopant is between 10% and 15%. In this way, the P-type charge generation material layer PCGLX can have a larger hole generation ability, and the P-type charge generation material layer PCGLX can be prevented from having an excessively large lateral current, achieving a balance between improving luminous efficiency and reducing crosstalk.
[0132] In an example, the hole transport material in the P-type charge generation material layer PCGLX is the same as the hole transport material in the hole injection material layer HILX; the P-type dopant in the P-type charge generation material layer PCGLX is the same as the P-type dopant in the hole injection material layer HILX; the only difference is that the mass content of the P-type dopant in the P-type charge generation material layer PCGLX is greater.
[0133] In an embodiment of the present disclosure, the material of the N-type charge generation material layer NCGLX consists of an electron transport compound and an N-type dopant; the electron transport compound contains a phenanthroline fragment or a phosphorus oxygen fragment. In this example, the electron transport compound contains a phenanthroline fragment or a phosphorus oxygen fragment, which makes the electron transport compound have a large lateral resistance, which is conducive to reducing the lateral current of the N-type charge generation material layer NCGLX. In this way, the lateral current of the common material layer can be further reduced, and the crosstalk between the light-emitting elements LD can be reduced.
[0134] Optionally, the N-type dopant may be a metal material of the first main group, such as lithium.
[0135] It can be understood that in some other embodiments of the present disclosure, even if the light-emitting element LD includes a multi-layer light-emitting stack structure ELS, the light-emitting functional layer EFL may not be provided with the P-type charge generation material layer PCGLX or the N-type charge generation material layer NCGLX as common material layers; for example, the P-type charge generation layer PCGL or the N-type charge generation layer NCGL may not be provided in some light-emitting elements LD.
[0136] It can be understood that when a part of the light-emitting elements LD of the display panel PNL includes a multi-layer light-emitting stack structure ELS and another part of the light-emitting elements LD includes a single-layer light-emitting stack structure ELS, the light-emitting elements LD including the single-layer light-emitting stack structure ELS may be provided with a charge generation layer CGL or may not be provided with a charge generation layer CGL.
[0137] In an embodiment of the present disclosure, the electron transport layer ETL may include an electron transport material, for example, an electron transport material containing an azine fragment, and in particular, an electron transport material containing a triazine fragment. Further, the electron transport layer ETL may be doped with a dopant, for example, the electron transport layer ETL may be doped with Liq (lithium hydroxyquinoline).
[0138] In an example, the electron transport material in the electron transport layer ETL may be different from the electron transport material in the N-type charge generation layer NCGL.
[0139] In an embodiment of the present disclosure, the hole blocking layer HBL may include an electron transport material, for example, may include an electron transport material containing an azine segment, and in particular, may include an electron transport material containing a triazine segment.
[0140] In some embodiments of the present disclosure, referring to
[0141] In some examples, referring to
[0142] In some examples, referring to
[0143] In some examples, the step difference T1 between different parts of the partition structure PTS is not less than the step difference between the light-emitting layer closest to the pixel electrode PE and the pixel electrode PE, for example, the step difference between different parts of the partition structure PTS is greater than 0.5 microns. This can ensure that the common material layer of the light-emitting functional layer EFL, especially the hole injection material layer HILX, is staggered and separated at the partition structure PTS. In the embodiment of the present disclosure, the step difference between different parts of the partition structure PTS refers to the height difference (in the normal direction of the display panel PNL) between the highest point of the partition structure PTS (farthest from the substrate BP) and the lowest point of the partition structure PTS (closest to the substrate BP). For example, when the partition structure PTS is a convex structure, the step difference T1 refers to the height difference between the base surface of the convex structure and the top surface of the convex structure. For another example, when the partition structure PTS is a groove structure, the step difference T1 refers to the height difference between the surface where the groove notch of the groove structure is located and the bottom of the groove.
[0144] Optionally, the display panel PNL is provided with a pixel definition layer PDL between the pixel electrode layer PEL and the light-emitting function layer EFL, and the partition structure PTS is provided on the pixel definition layer PDL. In this way, the partition structure PTS can be prepared at the same time as the pixel definition layer PDL is prepared, thereby reducing the number of processes and masks, and reducing the preparation cost of the display panel PNL.
[0145] For example, a pixel definition material layer covering the pixel electrode layer PEL may be formed first, and then the pixel definition material layer may be patterned to form a pixel definition layer PDL. The pixel definition layer PDL may have a pixel opening exposing at least a portion of the pixel electrode, and a groove structure as a partition structure PTS; or the pixel definition layer PDL may have a pixel opening exposing at least a portion of the pixel electrode, and a convex structure as a partition structure PTS. Optionally, when patterning the pixel definition material layer, a grayscale mask process may be used to achieve simultaneous preparation of the pixel opening and the partition structure PTS.
[0146] In some embodiments of the present disclosure, referring to
[0147] In some embodiments of the present disclosure, when a partition structure PTS is provided between two adjacent light-emitting elements LD, the partition structure PTS is in a strip shape; the arrangement square DV of the two adjacent light-emitting elements LD is perpendicular to the extension direction (length direction) of the partition structure PTS. In this way, the partition structure PTS can maximize the isolation effect of the lateral current.
[0148] For example, in the example of
[0149] Furthermore, the orthographic projections of the red light-emitting element R and the green light-emitting element G in the row direction DH can be located within the orthographic projections of the adjacent partition structure PTS in the row direction DH; this enables the shortest path of the lateral current between the red light-emitting element R and the adjacent green light-emitting element G to be completely isolated by the partition structure PTS, which, on the one hand, can compress the current channel width of the lateral current between the red light-emitting element R and the green light-emitting element G to a greater extent, and on the other hand, greatly extend the current path of the lateral current, thereby further weakening the lateral current between the red light-emitting element R and the green light-emitting element G.
[0150] For another example, in the example of
[0151] In the example of
[0152] In some embodiments of the present disclosure, referring to
[0153] In an embodiment of the present disclosure, referring to
[0154] Optionally, referring to
[0155] Of course, in some other implementations, a patterned impedance reduction layer may also be formed by evaporation through a precision metal mask.
[0156] The present disclosure also provides a display apparatus, which includes any one of the display panels described in the above display panel embodiments. The display apparatus can be a smartphone screen, a smart watch screen, or other types of display elements. Since the display apparatus includes any one of the display panels described in the above display panel embodiments, it has the same beneficial effects, and the present disclosure will not be repeated here.
[0157] Other embodiments of the present disclosure will be apparent to those skilled in the art from consideration of the specification and practice of the present disclosure disclosed herein. The present application is intended to cover any variations, uses, or adaptations of the present disclosure, which are in accordance with the general principles of the present disclosure and include common general knowledge or conventional technical means in the art that are not disclosed in the present disclosure. The specification and embodiments are illustrative, and the real scope and spirit of the present disclosure is defined by the appended claims.