Method of revamping of a plant for distillation of methanol

Abstract

Method for revamping a refining section of a methanol distillation plant comprising a medium pressure (MP) column a low pressure (LP) column, wherein both said columns comprise at least one bottom boiler, a gaseous stream of distilled methanol withdrawn from the MP column is fed to at least one bottom boiler of the LP column and a liquid solution containing methanol withdrawn from the MP column is fed to the LP column, the method of revamping comprising the installation of a high pressure (HP) column; the installation of a line feeding a gaseous stream of distilled methanol from the HP column to at least one bottom boiler of the MP column and the installation of a bottom line for exporting from the HP column a liquid stream consisting essentially of water.

Claims

1. A method for revamping a refining section of a methanol distillation plant, said refining section receiving a stream of crude methanol and comprising a medium pressure (MP) refining column arranged to operate at a first distillation pressure (p1) and a low pressure (LP) refining column arranged to operate at a second distillation pressure (p2), wherein p1 is higher than p2 and wherein: said MP refining column and said LP refining column each comprises at least one bottom boiler providing distillation heat to the MP column and the LP column, respectively, said MP refining column comprises a top outlet line for a gaseous stream of distilled methanol and a bottom outlet line for a solution containing methanol, said top outlet line being directed to at least one bottom boiler of the LP refining column, wherein said gaseous stream of distilled methanol acts as a heat source, and said bottom outlet line being directed to the LP refining column, wherein said solution containing methanol is further refined, the method comprising: installation of a high pressure (HP) refining column arranged to operate at a third distillation pressure (p3), wherein p3 is higher than p1; installation of a line feeding a gaseous stream of distilled methanol withdrawn from the top of said HP column to at least one bottom boiler of the MP column, wherein said gaseous stream of distilled methanol acts as a heat source, and installation of a bottom outlet line for exporting a liquid stream consisting essentially of water from the newly installed HP column.

2. The method according to claim 1, comprising the installation of at least one side outlet line for exporting a fusel oil from the newly installed HP column.

3. The method according to claim 1, comprising the installation of at least one bottom boiler arranged to provide distillation heat to the MP refining column and the line feeding said gaseous stream of distilled methanol withdrawn from the top of said HP column is directed to said newly installed bottom boiler or at least one of said newly installed bottom boilers.

4. The method according to claim 1, comprising the installation of at least one boiler arranged to provide the distillation heat to said newly installed HP refining column.

5. The method according to claim 1, wherein the gaseous stream of distilled methanol from the HP column supplies heat to the MP column by indirect heat exchange with a solution containing methanol leaving the MP column.

6. The method according to claim 5, wherein said gaseous stream of distilled methanol from the HP column is at least partially condensed during said heat exchange, obtaining a liquid stream of distilled methanol.

7. The method according to claim 6, characterised by installation of a flow line returning a part of said liquid stream of distilled methanol to the HP column and of a flow line for exporting a remaining part of said liquid stream of distilled methanol.

8. The method according to claim 1, wherein the existing refining section comprises a topping column arranged to operate at a topping pressure (pT) and said topping column comprises an inlet line for said crude methanol, a top outlet line for a gaseous stream of volatile components and a bottom outlet line for a liquid solution which is directed to the MP refining column, wherein said topping pressure (pT) is not greater than said second pressure (p2), said method comprising: installation of a branch directing part of said liquid solution to the newly installed HP refining column.

9. The method according to claim 8, wherein the topping pressure (pT) is roughly equal to atmospheric.

10. The method according to claim 8, wherein said second distillation pressure (p2) is greater than said topping pressure (pT), said topping column comprises a bottom boiler and said LP column comprises a top outlet line for a gaseous stream of distilled methanol, said method comprising: installation of a branch directing part of said gaseous stream of distilled methanol to the bottom boiler of the topping column, wherein said part of the gaseous stream acts as a heat source for said boiler.

11. The method according to claim 10, wherein said part of the gaseous stream of distilled methanol is at least partially condensed through indirect heat exchange with a solution containing methanol withdrawn from the topping column.

12. The method according to claim 10, wherein the second distillation pressure (p2) is at least 2 bar.

13. The method according to claim 12, wherein the third distillation pressure (p3) is about 30 bar and the first distillation pressure (p1) is about 15-20 bar.

14. The method according to claim 9, wherein the second distillation pressure (p2) is roughly equal to the topping pressure.

15. The method according to claim 14, wherein the third distillation pressure (p3) is about 20 bar and the first distillation pressure (p1) is about 8-10 bar.

16. The method according to claim 8, wherein the topping pressure (pT) is about 1.5 bar.

17. The method according to claim 11, wherein said solution is at least partially evaporated through the effect of said heat exchange.

18. The method according to claim 12, wherein the second distillation pressure (p2) is about 5 bar.

19. The method according to claim 12, wherein said solution is at least partially evaporated by means of the effect of said heat exchange.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a diagram of a refining section of a methanol distillation plant according to the prior art.

(2) FIG. 2 is a diagram of the refining section of FIG. 1 after a revamping in accordance with an embodiment of the invention.

DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT

(3) The refining section of FIG. 1 comprises a topping column 100 and two distillation columns 300, 400. The distillation column 300 operates at pressure p1 and the distillation column 400 operates at pressure p2, wherein p1>p2. The topping column 100 operates at a pressure p.sub.T of about 1.5 bar; the pressure p2 of the column 400, in this example, is substantially equal to the topping pressure p.sub.T, i.e. p2=˜p.sub.T.

(4) The topping column 100 comprises a bottom reboiler 101 and a top condenser 102. The columns 300, 400 comprise respective bottom reboilers 301, 401. The bottom reboiler 401 of the column 400 also operates as a top condenser of the column 300, and the column 400 is provided with a top condenser 402.

(5) The topping column 100 receives a flow of crude methanol 103 and separates a gaseous stream 104 containing volatile components lighter than methanol (light ends) and a bottom solution 105 containing methanol.

(6) A first portion 106 of the bottom solution 105 is heated, preferably at least partially evaporated, and recirculated into the column 100 through the bottom reboiler 101. In an equivalent embodiment, instead of separating said portion 106, a liquid stream is taken from the bottom of the column 100, heated in the respective reboiler 101 and recirculated into the column 100. The reboiler 101 is fed by an external heat source Q1, for example steam.

(7) A second portion 107 of the bottom solution is fed to a pump 120 that feeds the column 300 with a stream of methanol solution 303. The stream 303 is substantially at the pressure p1, apart from the pressure drop in the supply duct to the column 300.

(8) The gaseous stream 104 is condensed in the top condenser 102 and a portion 110 of the condensed stream is recirculated into the column 100. The remaining portion 111 is discharged or removed.

(9) The column 300 separates a gaseous stream 304 of distilled methanol at the pressure p1 and a bottom solution 305.

(10) The bottom solution 305 passes through a throttling valve 320 or equivalent, obtaining a stream 403 substantially at the pressure p2. Said stream 403 feeds the subsequent LP column 400.

(11) A liquid stream 306 is taken from the bottom of the column 300, heated in the respective reboiler 301 and recirculated into the column 300, thus heating the bottom of the column and maintaining the distillation process. In an equivalent embodiment, the liquid stream 306 is a portion of the bottom solution 305. The reboiler 301 is fed by an external heat source Q3, for example steam.

(12) The gaseous stream 304 is used in the process to heat the column 400. Said stream 304 is fed to the hot side of the reboiler 401, wherein it is at least partially condensed providing a stream of condensed methanol 309. A portion 310 of said condensate 309 is recirculated in the column 300 and the remaining portion 311 is exported from the process as distilled methanol. Said reboiler 401 also operates as a top condenser of the column 300 since it condenses at least part of the distilled methanol 304, forming the top recirculation stream 310. Hence, said reboiler 401 is also termed reboiler/condenser.

(13) The column 400 separates a further stream 404 of gaseous methanol, which is condensed in the top condenser 402 providing a condensed stream. A portion 410 of said condensed stream is reintroduced into the column 400 and the remaining portion 411 is discharged or removed.

(14) Said LP column 400 also produces a stream 420 essentially consisting of water and a side stream 430 of fusel oil.

(15) A liquid stream 406 is taken from the bottom of the column 400, subjected to heat exchange with the stream of gaseous methanol 304 in the reboiler 401, at least partially evaporated and recirculated into the column 400 to maintain the distillation process.

(16) The streams 311, 411 are joined together to form the overall flow 412 of distilled methanol with a required purity grade (for example AA).

(17) The prior art refining section shown in FIG. 1 is advantageously revamped to provide the refining section illustrated in FIG. 2, by means of the following operations:

(18) installation of a refining column 200 arranged to operate at a pressure p3 higher than the pressure p1;

(19) installation of a branch 108 directing part of the bottom solution leaving the topping column 100 to the newly installed HP column 200;

(20) installation of a pump 121 for said branch 108;

(21) installation of a bottom reboiler 501 in place of the bottom reboiler 301 of the MP refining column;

(22) installation of a line 204 feeding a gaseous stream of distilled methanol withdrawn from the top of the newly installed column 200 to the bottom boiler 501, wherein said gaseous stream of distilled methanol acts as a heat source;

(23) installation of a bottom outlet line 205 for exporting as a product a liquid stream consisting essentially of water from the newly installed column 200;

(24) installation of a side outlet line 207 for exporting as a product a fusel oil from the newly installed HP column;

(25) installation of a bottom boiler 201;

(26) installation of a steam line Q2 and of a line 206 for extracting a liquid solution from the bottom of the column 200, said steam line Q2 and said line 206 feeding said newly installed boiler 201 to provide the distillation heat to the column 200.

(27) The gaseous stream fed to the bottom boiler 501 through the newly installed line 204 is used to heat the column 300. Said gaseous stream is fed to the hot side of the reboiler 501, wherein it is at least partially condensed, and the liquid stream 306 taken from the bottom of the column 300 is fed to the cold side thereof, wherein it is at least part evaporated. The method of revamping comprises the installation of a line 209 for exporting the condensed methanol from the boiler 501, a line 210 for recirculating part of the condensed methanol in the column 200 and a line 211 for exporting the remaining part of the condensed methanol as a product.

(28) The streams 211, 311, 411 are joined together to form the overall flow 412 of distilled methanol with a required purity grade (for example AA).