ALUMINUM ALLOY FOR CASTING HIGH-STRENGTH AND HIGH ELECTRICALLY CONDUCTIVE COMPONENTS
20230067206 · 2023-03-02
Inventors
Cpc classification
C22F1/047
CHEMISTRY; METALLURGY
International classification
Abstract
An electrically conductive aluminum diecast alloy and an induction motor rotor made of the diecast aluminum alloy. The aluminum alloy includes commercially pure aluminum and a sufficient weight percent (wt%) of Copper (Cu), Magnesium (Mg), and Silicon (Si) to precipitate a 0.1 wt% to 5.0 wt% of a thermally stable Q-phase precipitate, AlwCuxMgySiz, after age hardening. Wherein w = about 14.3 at% to about 23.82 at% of Al; x = about 5.90 at% to about 9.52 at% of Cu; y = about 35.30 at% to about 42.85 at% of Mg; and z = about 28.57 at% to about 35.30 at% of Si. The induction motor rotor includes an aluminum squirrel cage rotor diecast onto a laminated electrical steel. The aluminum diecast squirrel cage rotor includes about 1.0 wt% of thermally stable Al.sub.5Cu.sub.2Mg.sub.8Si.sub.6 after age hardening.
Claims
1. An aluminum alloy for diecasting an electrically conductive work piece, comprising: aluminum (Al); and a sufficient weight percent (wt%) of Copper (Cu), a sufficient wt% of Magnesium (Mg), and a sufficient wt% of Silicon (Si) to precipitate a 0.1 wt% to 5.0 wt% of at least one thermally stable Q-phase precipitate after age hardening, wherein the at least one thermally stable Q-phase precipitate is Al.sub.wCu.sub.xMg.sub.ySi.sub.z: w = atomic percent (at%) of AI; x = at% of Copper (Cu); y = at% of Magnesium (Mg); and z = at% of Silicon (Si).
2. The aluminum alloy of claim 1, wherein: w = about 14.3 at% to about 23.82 at% of AI; x = about 5.90 at% to about 9.52 at% of Cu; y = about 35.30 at% to about 42.85 at% of Mg; and z = about 28.57 at% to about 35.30 at% of Si.
3. The aluminum alloy of claim 1, comprising about 1.0 wt% of the Q-phase precipitate Al.sub.wCu.sub.xMg.sub.ySi.sub.z, wherein: w = about 23.82 at% of AI; x = about 9.52 at% of Cu; y = about 38.09 at% of Mg; and z = about 28.57 at% of Si.
4. The aluminum alloy of claim 1, comprising: about 0.027 wt% to about 1.734 wt% Si; about 0.030 wt% to about 1.754 wt% Mg; about 0.013 wt% to about 1.019 wt% Cu; and remaining wt% of Al.
5. The aluminum alloy of claim 1, comprising: about 0.270 wt% to about 1.041 wt% Si; about 0.300 wt% to about 1.053 wt% Mg; about 0.131 wt% to about 0.611 wt% Cu; and remaining wt% of Al.
6. The aluminum alloy of claim 1, comprising: about 0.270 wt% to about 0.347 wt% Si; about 0.300 wt% to about 0.351 wt% Mg; about 0.131 wt% to about 0.204 wt% Cu; and remaining wt% of Al.
7. The aluminum alloy of claim 1, wherein the Q-phase precipitate is Al.sub.5Cu.sub.2MgsSi.sub.6.
8. The aluminum alloy of claim 7, further comprising: greater than 0 wt% to 0.2 wt% Iron (Fe); greater than 0 wt% to 0.5 wt% Manganese (Mn); and greater than 0 wt% to 0.05 wt% Zinc (Zn).
9. The aluminum alloy of claim 8, further comprising greater than 0 wt% to 0.25 wt% of a sum of Chromium (Cr), Nickel (Ni), Titanium (Ti), and Vanadium (V).
10. The aluminum alloy of claim 1, comprising: 0.13 wt% to 0.21 wt% Cu; 0.30 wt% to 0.35 wt% Mg; 0.27 wt% to 0.35 wt% Si; and remainder wt% Al to precipitate about 1.0 wt% of the at least one thermally stable Q-phase precipitate consisting essentially of Al.sub.5Cu.sub.2Mg.sub.8Si.sub.6.
11. A diecast electrically conductive cast aluminum work piece, consisting essentially of: Aluminum (Al); 0.1 wt% to 5.0 wt% of a thermally stable Q-phase precipitate Al.sub.wCu.sub.xMg.sub.ySi.sub.z, wherein: w = about 14.3 at% to about 23.82 at% of AI; x = about 5.9 at% to about 9.52 at% of Cu; y = about 35.3 at% to about 42.85 at% of Mg; and z = about 28.57 at% to about 35.3 at% of Si.
12. The diecast electrically conductive cast aluminum work piece of claim 11, wherein the thermally stable Q-phase precipitate Al.sub.wCu.sub.xMg.sub.ySi.sub.z consist essentially of: w = about 23.82 at% of AI; x = about 9.52 at% of Cu; y = about 38.09 at% of Mg; and z = about 28.57% of Si.
13. The diecast electrically conductive cast aluminum work piece of claim 11, wherein the thermally stable Q-phase precipitate Al.sub.wCu.sub.xMg.sub.ySi.sub.z is about 1.0 wt. %.
14. The diecast electrically conductive cast aluminum work piece of claim 13, wherein the thermally stable Q-phase precipitate Al.sub.wCu.sub.xMg.sub.ySi.sub.z includes one or more of a precipitate selected from a group consisting of Al.sub.5Cu.sub.2Mg.sub.8Si.sub.6, Al.sub.4Cu.sub.2Mg.sub.8Si.sub.7, Al.sub.4Cu.sub.1Mg.sub.6Si.sub.6, and Al.sub.3Cu.sub.2Mg.sub.9Si.sub.7.
15. The diecast electrically conductive cast aluminum work piece of claim 14, wherein diecast electrically conductive cast aluminum work piece is a squirrel cage of an induction motor rotor assembly.
16. An induction motor rotor, comprising: a laminated electrical steel; a squirrel cage rotor cast onto the laminated electrical steel, wherein the squirrel cage rotor includes an age hardened aluminum alloy comprising: about 0.1 weight percent (wt%) to about 5.0 wt% percent of a thermally stable Q-phase precipitate; and a remaining wt% of commerciallly pure Aluminum (Al).
17. The induction motor rotor of claim 16, wherein the Q-phase precipitate comprises at least one Al.sub.wCu.sub.xMg.sub.ySi.sub.z precipitate, where: w = about 14.3 atomic percent (at%) to about 23.82 at% of AI; x = about 5.9 at% to about 9.52 at% of Copper (Cu); y = about 35.3 at% to about 42.85 at% of Magnesium (Mg); and z = about 28.57 at% to about 35.3 at% of Silicon (Si).
18. The induction motor rotor of claim 17, wherein the age hardened aluminum alloy comprising about 1.0 wt% of the Q-phase precipitate.
19. The induction motor rotor of claim 18, wherein Q-phase precipitate comprises Al.sub.5Cu.sub.2Mg.sub.8Si.sub.6.
20. The induction motor rotor of claim 16, wherein the age hardened aluminum alloy comprises: about 0.270 wt% to about 0.347 wt% Si; about 0.300 wt% to about 0.351 wt% Mg; and about 0.131 wt% to about 0.204 wt% Cu.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0027] The drawings described herein are for illustration purposes only and are not intended to limit the scope of the present disclosure in any way.
[0028]
[0029]
[0030]
[0031]
[0032]
[0033]
DETAILED DESCRIPTION
[0034] The following description is merely exemplary in nature and is not intended to limit the present disclosure, application, or uses. The illustrated embodiments are disclosed with reference to the drawings, wherein like numerals indicate corresponding parts throughout the several drawings. The figures are not necessarily to scale and some features may be exaggerated or minimized to show details of particular features. The specific structural and functional details disclosed are not intended to be interpreted as limiting, but as a representative basis for teaching one skilled in the art as to how to practice the disclosed concepts.
[0035] Shown in
[0036] The improved aluminum alloy has good castability, high electrical conductivity, and good mechanical properties particularly at both ambient room temperature and elevated temperatures. The improved aluminum alloy is composed of commercially pure aluminum (Al) together with a sufficient weight percent (wt%) of Copper (Cu), a sufficient wt% of Magnesium (Mg), and a sufficient wt% of Silicon (Si) to precipitate a 0.1 wt% to 5.0 wt% of at least one thermally stable Q-phase precipitate after age hardening. An exemplary Q-phase precipitate is expressed by the formula Al.sub.wCu.sub.xMg.sub.ySi.sub.z, where: [0037] w = atomic percent (at%) of Al; [0038] x = at% of Copper (Cu); [0039] y = at% of Magnesium (Mg); and [0040] z = at% of Silicon (Si).
[0041] Table 1 below presents four (4) exemplary embodiments of thermally stable Q-phase precipitates having the formula Al.sub.wCu.sub.xMg.sub.ySi.sub.z and corresponding at% of Al, Cu, Mg, Si in the Q-phase precipitates after the improved Al alloy has been age hardened. The maximum (Max) at% and the minimum (Min) at% of each of Al, Cu, Mg, Si for the 4 exemplary embodiments of the thermally stable Q-phase precipitates are also shown in Table 1.
TABLE-US-00001 Q-Phase Embodiment Q-Phase at% Al at% Cu at% Mg at% Si Embodiment 1 Al.sub.5Cu.sub.2Mg.sub.8Si.sub.6 23.82 9.52 38.09 28.57 Embodiment 2 Al.sub.4Cu.sub.2Mg.sub.8Si.sub.7 19.06 9.52 38.09 33.33 Embodiment 3 Al.sub.4Cu.sub.1Mg.sub.6Si.sub.6 23.50 5.90 35.30 35.30 Embodiment 4 Al.sub.3Cu.sub.2Mg.sub.9Si.sub.7 14.30 9.52 42.85 33.33 Embodiments 1-4 Max 23.82 9.52 42.85 35.30 Embodiments 1-4 Min 14.30 5.90 35.30 28.57
[0042] Table 2 below presents the 4 exemplary embodiments of the thermally stable Q-phase precipitates of Table 1 and corresponding weight percent (wt%) of Al, Cu, Mg, Si in each of the embodiments of the Q-phase precipitates. The maximum (Max) wt% and the minimum (Min) wt% of each of Al, Cu, Mg, Si are also shown in Table 2.
TABLE-US-00002 Q-Phase Embodiments 1 2 3 4 Element wt% wt% wt% wt% Max wt% Min wt% Al 21.60 17.25 22.18 13.00 13.00 22.18 Si 26.96 31.40 34.68 31.54 26.96 34.68 Mg 31.11 31.05 30.02 35.09 30.02 35.09 Cu 20.33 20.29 13.12 20.30 13.12 20.38
[0043] Based on the wt% of Al, Cu, Mg, and Si of the Q-phase precipitates shown in Table 2, the wt% of Cu, Mg, and Si required to be added to a commercially pure Al can be calculated to provide for the improved aluminum alloy to precipitate a 0.1 wt% to 5.0 wt% of at least one thermally stable Q-phase precipitate after age hardening, wherein the at least Q-phase precipitate is Al.sub.wCu.sub.xMg.sub.ySi.sub.z.
[0044] Table 3 shows a minimal and maximum wt% of Cu, Mg, and Si required in an aluminum alloy to precipitate between 0.1% to 5.0 wt% Q-phase having the formula Al.sub.wCu.sub.xMg.sub.ySi.sub.z.
TABLE-US-00003 Electrically conductive Cast Aluminum Alloy 0.1% Q-phase 1.0% Q-Phase 3.0% Q-Phase 5.0% Q-Phase Element Min Max Min Max Min Max Min Max Al 0.013 0.022 0.130 0.222 0.390 0.665 0.650 1.109 Si 0.027 0.035 0.270 0.347 0.809 1.041 1.348 1.734 Mg 0.030 0.035 0.300 0.351 0.900 1.053 1.501 1.754 Cu 0.013 0.020 0.131 0.204 0.393 0.611 0.656 1.019
[0045]
[0046] At lower temperatures, shown left of the vertical dash line C, the UTS and YS of the age hardened cast Al alloy having Q-phase Al.sub.wCu.sub.xMg.sub.ySi.sub.z precipitates is slightly lower than the UTS and YS of the cast Al alloy having Mg.sub.2Si precipitates, but within acceptable range for a casted squirrel cage rotor. However, at elevated temperatures, shown right of the vertical dash line C, the UTS and YS of the cast Al alloy having Q-phase Al.sub.wCu.sub.xMg.sub.ySi.sub.z precipitates outperforms the UTS and YS of the cast Al alloy having Mg.sub.2Si precipitates. The lower temperatures at which the Al alloy having Q-phase Al.sub.wCu.sub.xMg.sub.ySi.sub.z precipitates has lower UTS and YS are not as important to the application of induction motors because the squirrel cage rotor heats up during normal operating conditions. Having higher UTS and YS at the higher operating temperatures is more beneficial to the applications of induction motors.
[0047] Adding Si, Mg, Cu contents to a commercially pure Al alloy increases strengths but may reduces ductility. Adding Fe may also reduce ductility. However, referring to
[0048]
[0049]
[0050] Moving to block 604, the molten improved aluminum alloy undergoes the processes of degassing to remove hydrogen, fluxing to remove aluminum oxides, and adding grain refinement such as TiB, Ce or La.
[0051] Moving to block 606, the molten improved aluminum alloy is poured or injected into a diecast mold that defines an die cast electrically conductive component. In one embodiment, the electrically conductive component is squirrel-cage rotor assembly 100 of
[0052] Moving to block 608, the diecast electrically conductive component is heat treated at 450° C. to 550° C. for 0.5 to 12 hours isothermally, multi-step isothermally, or non-isothermally, preferably isothermally at 530° C. for 2 hours. The diecast electrically conductive component is then quenched in a liquid or gas medium at 25° C. to 100° C. For example, the hot diecast electrically conductive component may be quenched in 90° C. water. After quenching, the work piece is aged at 100° C. to 250° C. for 1 to 10 hours isothermally, multi-step isothermally, or non-isothermally to effectuate the precipitation of a desired wt% of Q-phase and a given embodiment or embodiments of Q-phases. For example, the work piece may be aged isothermally at 200° C. for 4 hours.
[0053] The above disclosure provides an improved high strength and improved castability aluminum alloy containing up to 1.0 wt% Si, up to 0.5 wt% Mg, up to 0.5 wt% Cu, up to 0.2 wt% Fe, up to 0.5 wt% Mn, up to 0.05 wt% Zn, and up to 0.025 wt% of the sum of Cr, Ni, Ti, and V. The improved high strength and castability conductivity aluminum alloy is suitable for die-casting aluminum induction rotors for electric motors due to its comparable electrical conductive properties as that of commercially pure aluminum. A preferable combination of alloying elements Si, Mg, and Cu in the alloys is to form substantially 100% thermal stable Q precipitates, preferably AlsCu.sub.2Mg.sub.8Si.sub.6, after age hardening. The improved Al alloy is absent of β(AlFeSi), therefore improving material ductility. The improved Al Alloy is suitable for high pressure die casting and metal mold casting with high die soldering resistance. The improved Al alloy also has better mechanical properties particularly at elevated temperatures as compared to commercially pure Al while maintaining comparable electrical conductivity as commercially pure Al.
[0054] Numerical data have been presented herein in a range format. “The term “about” as used herein is known by those skilled in the art. Alternatively, the term “about” includes +/- 0.05% by weight”. It is to be understood that this range format is used merely for convenience and brevity and should be interpreted flexibly to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. While examples have been described in detail, those familiar with the art to which this disclosure relates will recognize various alternative designs and examples for practicing the disclosed method within the scope of the appended claims.
[0055] The description of the present disclosure is merely exemplary in nature and variations that do not depart from the general sense of the present disclosure are intended to be within the scope of the present disclosure. Such variations are not to be regarded as a departure from the spirit and scope of the present disclosure.