Detection component including black pixels and method for manufacturing such a component
11652119 · 2023-05-16
Assignee
Inventors
Cpc classification
H01L31/02164
ELECTRICITY
H01L27/14696
ELECTRICITY
International classification
Abstract
A detection component is provided for detecting electromagnetic radiation, the detection component comprising a mask arranged to block the electromagnetic radiation for at least one detector. The opaque mask comprises a successive stack of a first metal layer, a second metal layer, a third transparent layer having a low optical index, and an assembly of metal components. The second metal layer, the transparent layer, and the assembly of components form MIM structures in the wavelength range. The invention further relates to a method for manufacturing such a detection component.
Claims
1. A detection component for detecting electromagnetic radiation in a wavelength range, the detection component comprising: a support, and an active layer in which a plurality of detectors configured to detect electromagnetic radiation in the wavelength range is arranged, the support comprising a first surface from which the active layer extends, and a second surface opposite the first surface, with the support being configured to receive the electromagnetic radiation via the second surface, and an opaque mask arranged on a portion of the second surface of the support to block the electromagnetic radiation for a particular detector of the detectors, wherein the opaque mask comprises at least a first metal, a second metal, a third metal, and a transparent material with a refractive index less than or equal to 2 in the wavelength range, the first metal having an extinction coefficient k.sub.m1 greater than or equal to 5n.sub.m1, the second metal having an extinction coefficient k.sub.m2 strictly less than 5n.sub.m2, and the third metal having an extinction coefficient k.sub.m3 strictly less than 5n.sub.m3, with n.sub.m1 n.sub.m2, and n.sub.m3 being refractive indices of the first metal, the second metal, and the third metal, respectively, in the wavelength range, with the transparent material having an extinction coefficient k.sub.t less than or equal to 0.01, wherein the opaque mask comprises, starting from the second surface of the support, a successive stack of: a first metal layer of the first metal, a second metal layer of the second metal, a third layer of the transparent material, and a group of metal components, each comprising the third metal, said group being arranged on the third layer opposite the second metal layer, and wherein the second metal layer, the third layer, and the group form metal-insulator-metal (MIM) structures in the wavelength range.
2. The detection component according to claim 1, wherein the second metal has an extinction coefficient k.sub.m2 less than or equal to 2n.sub.m2 and the third metal has an extinction coefficient k.sub.m3 less than or equal to 2n.sub.m3.
3. The detection component according to claim 1, wherein the second and third metals are identical.
4. The detection component according to claim 3, wherein each of the metal components has at least one lateral dimension L, in a plane substantially parallel to the second surface, less than or equal to a value Lm satisfying:
5. The detection component according to claim 4, wherein each of the metal components has a maximum lateral dimension and a minimal lateral dimension within a plane substantially parallel to the second surface, of between 0.75 times the value Lm and 1.25 times the value Lm.
6. The detection component according to claim 3, wherein each component in the group has a thickness in a stacking direction of the opaque mask that is between one times a skin depth δ.sub.m3 of the third metal in the wavelength range and three times the skin depth δ.sub.m2 of the second metal.
7. The detection component according to claim 1, wherein the first metal layer has a thickness h.sub.m1 greater than 2 times a skin depth δ.sub.m1 of the first metal in the wavelength range.
8. The detection component according to claim 1, wherein the second metal layer has a thickness h.sub.m2 of between 0.5 times a skin depth δ.sub.m2 of the second metal in the wavelength range, and 4 times the skin depth δ.sub.m3 of the second metal in the wavelength range.
9. The detection component according to claim 1, wherein in the group, two adjacent metal components have an inter-barycentric distance therebetween that is less than or equal to λ.sub.0/n.sub.d, where λ.sub.0 is a central wavelength of the wavelength range and n.sub.d is the refractive index of the transparent material in the wavelength range.
10. The detection component according to claim 9, wherein components in the group are arranged periodically with a pitch P between components of less than λ.sub.0/n.sub.d.
11. The detection component according to claim 1, wherein the third layer has a thickness of between λ.sub.0/4n.sub.d and λ.sub.0/50n.sub.d, inclusively, with λ.sub.0 being a central wavelength in the wavelength range and n.sub.d being the refractive index of the transparent material in the wavelength range.
12. The detection component according to claim 1, wherein the opaque mask is arranged on the second surface of the support to block the electromagnetic radiation for the particular detector and those detectors adjacent to the particular detector.
13. The detection component according to claim 12, wherein the opaque mask is further arranged to block the electromagnetic radiation for any detector adjacent to those detectors adjacent to the particular detector.
14. The detection component according to claim 13, the support has a thickness of less than 10 μm, with the opaque mask extending, on either side of a projection of the particular detector, on the second surface of the support over a distance greater than 15 μm.
15. The detection component according to claim 1, wherein the opaque mask further comprises a fourth metal and a second transparent material, said second transparent material having a refractive index less than or equal to 2 in the wavelength range, and wherein, for each metal component in the group of metal components, there is a second successive stack, starting from the third layer, of: the metal component, a portion of a fourth layer made of the second transparent material, and a portion of a fifth metal layer made of the fourth metal, wherein, for each metal component in the group of metal components, the portion of the fourth layer and the portion of the fifth metal layer form a second MIM structure in the wavelength range.
16. A method for manufacturing a detection component for detecting electromagnetic radiation in a wavelength range, the manufacturing method comprising: providing a support and an active layer in which a plurality of detectors configured to detect electromagnetic radiation in said wavelength range is arranged, the support comprising a first surface from which the active layer extends, and a second surface opposite the first surface, the support being configured to receive the electromagnetic radiation via the second surface, starting from the second surface of the support, forming a successive stack of: a first metal layer of a first metal, a second metal layer of a second metal, a third layer of a transparent material with a refractive index less than or equal to 2 in the wavelength range, and a group of metal components, each comprising a third metal, said group being arranged on the third layer opposite the second metal layer, with the second metal layer, the third layer, and the group forming metal-insulator-metal (MIM) structures in the wavelength range, wherein an opaque mask is arranged on a portion of the second surface of the support to block the electromagnetic radiation for a particular detector of the detector, wherein the opaque mask comprises the first metal, the second metal, and the third metal, and the transparent material, with the first metal having an extinction coefficient k.sub.m1 greater than or equal to 5n.sub.m1, and the second metal having an extinction coefficient k.sub.m2 strictly less than 5n.sub.m2, and the third metal an extinction coefficient k.sub.m3 strictly less than 5n.sub.m3, with n.sub.m1, n.sub.m2, and n.sub.m3 being refractive indices of the first metal, the second metal, and the third metal, respectively, in the wavelength range, with the transparent material having an extinction coefficient k.sub.t less than or equal to 0.01.
17. The method for manufacturing an electromagnetic radiation detection component according to claim 16, wherein the forming step further comprises: depositing the first metal layer made of the first metal in contact with the second surface of the support, depositing the second metal layer made of the second metal in contact with the first metal layer, depositing the third layer made of the transparent material in contact with the second metal layer, and forming the group of metal components, each including the third metal, on the third layer opposite the second metal layer.
18. The method for manufacturing an electromagnetic radiation detection component according to claim 16, wherein, during the opaque mask forming step, the opaque mask is arranged on the second surface of the support to block the electromagnetic radiation for the particular detector and those detectors adjacent to the particular detector.
19. The method for manufacturing an electromagnetic radiation detection component according to claim 16, further comprising: for each metal component in the group of metal components, forming a portion of a fourth layer, of a second transparent material, and a portion of a fifth metal layer of a fourth metal so as to form a second stack for each metal component, comprising in succession, starting from the third layer: the metal component, the portion of the fourth layer, and the portion of the fifth metal layer, wherein the second transparent material has a refractive index less than or equal to 2 in the wavelength range, and wherein, for each metal component in the group of metal components, the portion of the fourth layer and the portion of the fifth metal layer form a second MIM structure in the wavelength range.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) The present invention will be more readily understood from a reading of the description of embodiments, given purely as examples and not intended to limit in anyway, in reference to the appended drawings, in which:
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(9) Identical, similar, or equivalent parts of the various figures have the same numerical references so as to facilitate the reading of the various figures.
(10) In an effort to make the figures more legible, the various parts in the figures are not necessarily shown according to a uniform scale.
(11) The various possibilities (variants and embodiments) must be understood as not being exclusive of each other, and may therefore be combined.
DESCRIPTION OF THE EMBODIMENTS
(12)
(13) Such a detection component 1, according to a main embodiment of the invention, is more specifically intended for the detection of electromagnetic radiation in the infrared wavelength range. Thus, the various values indicated in the embodiments described below refer to this practical application, in which the targeted wavelength range is in a mid-infrared wavelength range, for example a wavelength range of between 2.5 and 3.5 μm. Naturally, based on the disclosure herein, a person skilled in the art is perfectly capable of adapting these values in order to achieve an optimized detection of electromagnetic radiation in a wavelength range other than the infrared, by using such a detection structure 10. Thus, the invention is particularly advantageous in the context of applications for detecting electromagnetic radiation in the infrared wavelength ranges based on the detection components operating at low temperatures, that is, typically less than −100° C. or 173 K, most commonly around 80 K as in the case of HgCdTe-based detectors.
(14) Such a detection component 1 includes: the support 110 comprising a layer, called active layer 120, in which a plurality of detection structures 121a, 121b, 122, and 123 for detecting electromagnetic radiation λ in said wavelength range is arranged, with the support 110 comprising a first surface from which the active layer 120 extends, and a second surface opposite the first surface by which the support 110 is intended to receive the electromagnetic radiation λ, the opaque mask 140 arranged on a portion of the second surface of the support 110 to block the electromagnetic radiation of a detection structure 122, which is masked.
(15) As shown in
(16) The second metal layer 142, the transparent layer 143, and assembly of metal elements 144 form MIM structures in the wavelength range.
(17) The first metal has an extinction coefficient k.sub.m1 greater than or equal to 5n.sub.m1 and the second metal has an extinction coefficient k.sub.m2 strictly less than 5n.sub.m2, or even less than or equal to 2n.sub.m2, with n.sub.m1 and n.sub.m2 being refractive indices of the first and of the second metal in the wavelength range. Preferably, the first metal has an extinction coefficient k.sub.m1 greater than or equal to 10n.sub.m1.
(18) Note that according to one possibility of the invention, the second metal may have an extinction coefficient k.sub.m2 that is less than or equal to 4n.sub.m2.
(19) In this first embodiment, the first support 110 is a cadmium telluride and zinc CdZnTe, the first support 110 comprising the active layer 120 made of a mercury cadmium telluride, HgCdTe. Each detection structure 121A, 121B, 122, and 123 consists, for example, of a PN photodiode comparable to those implemented in the prior art, which are only shown by their respective volume footprints on the active layer.
(20) Naturally, while each detection structure 121A, 121B, 122, and 123 is a PN photodiode in this first embodiment, the invention is not limited to this sole type of detection structure. Thus, the component may, for example, comprise another type of photodiode, such as a PiN photodiode (i.e. a photodiode having an intrinsic area made between an N area and a P area), a zener diode, or a barrier diode, without the scope of the invention being exceeded.
(21) The support 110 may have a thickness between 1 and 20 μm, preferably between 5 and 15 μm. Thus, the support can therefore have a thickness of 10 μm, for example.
(22) The second surface of the support 110 may comprise an anti-reflective coating 130 according to the customary practice of a person skilled in the art, in the context of the detection components 1 from the prior art. Note that in the present embodiment, as shown in
(23) The opaque mask 140 is arranged on the second surface of the support 110 to block the electromagnetic radiation for at least one of the masked detection structures. In order to perfect such a block, as shown partially in
(24) As part of an application of the invention in the near infrared and mid-infrared, the first metal layer 141 may be made of gold Au, aluminum Al, or copper Cu, or even an alloy of two metals, or even an alloy of these three metals.
(25) Note that, especially if the first metal is gold Au a bonding layer of a few nanometers may be provided between the second surface of the support 110 and the first metal layer 141. Such a bonding layer may be made of Titanium Ti or nickel Ni for the first metal, which is gold Au.
(26) The first metal layer 141 preferably has a thickness h.sub.m1 more than 2 times greater than a skin depth δ.sub.m1 of the first metal in the wavelength range, with the thickness of the first metal layer 141 preferably being greater than or equal to 4 times skin depth δ.sub.m1 of the first metal in the wavelength range. Note also that the thickness of the first metal layer is preferably less than 10δ.sub.m1.
(27) In other words, thickness h.sub.m1 of the first metal layer preferably satisfies the inequality 2δ.sub.m1<h.sub.m1<10δ.sub.m1 and, in a particularly advantageous way, satisfies the following inequality:
4δ.sub.m1≤h.sub.m1<2δ.sub.m1 (2)
(28) For instance, thickness h.sub.m1 may be substantially equal to 4δ.sub.m1. In the event that the first metal is gold Au, gold having a refractive index of 1.24, an extinction coefficient of 15.7, and therefore a skin depth δ.sub.m1 of 25 nm at a wavelength of 2.5 μm, a first metal layer 141 with a thickness of 100 nm is therefore obtained.
(29) As part of an application of the invention in the near infrared and mid-infrared, the second metal layer 142 may be made of titanium Ti or platinum Pt or tungsten W or even an alloy of titanium and tungsten.
(30) The second metal layer 142 has a thickness h.sub.m2 of between a 0.5 times a skin depth δ.sub.m2 of the second metal in the wavelength range, and 4 times the skin depth δ.sub.m2 of the second metal in the wavelength range. In other words, the thickness of the second metal layer 142 satisfies the following equation:
0.5δ.sub.m2≤h.sub.m2≤2δ.sub.m2 (3)
(31) For example, thickness h.sub.m2 may be on the order of the skin depth of the second metal. In the event that the second metal is titanium Ti, the titanium Ti has, at a wavelength of 2.5 μm, a refractive index n.sub.m2 of 4.36 and an extinction coefficient k.sub.m2 of 3.19, and therefore a skin depth δ.sub.m2 of the titanium of 130 nm, a second metal layer 141 on the order of 130 nm, that is, between 100 nm and 160 nm, is therefore obtained.
(32) The transparent layer 143 is made of a material, called a transparent material, with a refractive index equal to or less than 2 in the wavelength range and having an extinction coefficient k.sub.t less than or equal to 0.01 in the wavelength range. In a typical configuration of the invention, the layer of transparent material is made of a dielectric material, such as a silicon dioxide SiO.sub.2, alumina Al.sub.2O.sub.3, and magnesium fluoride MgF.sub.2. As a variant, the layer of the transparent material 143 may be made of a conductive oxide, such as an indium tin oxide, more commonly known by the acronym ITO, a zinc oxide, more commonly known by the acronym ZnO, and an aluminum-doped zinc oxide, more commonly known by the acronym AZO. The assembly of these materials has an extinction coefficient k.sub.t less than or equal to 0.01 in the wavelength range.
(33) Note that the material of the transparent layer 143 preferably has a refractive index less than or equal to 1.5, which is particularly the case for silicon dioxide SiO.sub.2, alumina Al.sub.2O.sub.3, and magnesium fluoride MgF.sub.2.
(34) The transparent layer 143 may have a thickness Ep.sub.d of between λ.sub.0/4n.sub.d and λ.sub.0/50n.sub.d, inclusively, with λ.sub.0 being a central wavelength within the wavelength range and n.sub.d being the refractive index of the transparent material 143 in the wavelength range. In other words, thickness Ep.sub.d of the transparent layer 143 may satisfy the following inequalities:
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(36) For instance, thickness Ep.sub.d of the transparent layer 143 may be equal to λ.sub.0/10n.sub.d.
(37) In the same way, the transparent layer 143 may have a thickness Ep.sub.d of between λ.sub.0/4n.sub.d and λ.sub.0/25n.sub.d, inclusively.
(38) The assembly of the metal elements 144 is arranged on third layer 143 and is made of the second metal. Each metal element 144 of said assembly occurs in the form of a metal bump that may assume, for example, a square or circular shape or even a hexagonal shape, according to a projection onto the second surface of the support 110.
(39) Each metal element 144 preferably has, in a plane parallel to the second surface, at least one lateral dimension L.sub.em such that, for the metal elements 144 having a square projection onto the second surface of the support, a length of one side of said square, for the metal elements 144 having a circular projection onto the second surface of the support, a diameter of said circle, which is preferably less than or equal to a value Lm satisfying the following equation:
(40)
(41) where λ.sub.0 is a central wavelength of the wavelength range, n.sub.d is a refractive index of the transparent material at said central wavelength, h.sub.d is the thickness of the transparent layer, and δ.sub.m2 is the skin depth of the second metal at said central wavelength.
(42) Note that, in a particularly advantageous way, the metal elements 144 have a maximum lateral dimension and a minimal lateral dimension in the plane substantially parallel to the second surface, both of which are between 0.75 times the value Lm and 1.25 times the value Lm.
(43) According to a first possibility of the invention, the metal elements may have a non-periodic arrangement with a spacing between two adjacent metal elements preferably having a pitch P that is less than or equal to λ.sub.0/n.sub.d, where λ.sub.0 is a central wavelength of the wavelength range and n.sub.d is the refractive index of the transparent material in the wavelength range. In a particularly advantageous way, the pitch P between the two adjacent metal elements 144 in the assembly of the metal elements 144 is less than 0.75 times λ.sub.0/n.sub.d.
(44) According to a second possibility of the invention, the metal elements 144 may have a periodic arrangement with a lattice pitch P that is less than or equal to λ.sub.0/n.sub.d, the lattice pitch preferably being less than 0.75 times λ.sub.0/n.sub.d. Note that according to this second possibility, the metal elements may be arranged in a square lattice with the lattice pitch P.
(45) Note that in the case of a second non-noble metal such as Titanium Ti in order to limit the risk of oxidizing, according to a possibility not shown, a passivation layer of a few nanometers may be deposited on the metal elements 144. For instance, for a second metal consisting of titanium Ti the metal elements 144 may be covered with a passivation layer of silicon nitride SiN, or zinc sulfide ZnS at a thickness of between 5 and 30 nm. Such a passivation layer may therefore have a thickness of 10 nm, for example.
(46) In addition, when selecting the first and second metals and the transparent material for applications of a detection component 1 cooled to a relatively low temperature, i.e. typically less than −100° C. or 173 K, these materials may be chosen to have comparable thermal expansion coefficients. According to this possibility, the first metal may be platinum Pt the second metal titanium Ti and the transparent material may be an amorphous silicon dioxide a-SiO.sub.2 these materials having a thermal expansion coefficient on the order of 9.10.sup.−6 K.sup.−1.
(47) As a variant to the present embodiment, the metal elements may be made of a third metal. According to this variant, the third metal, as in the case of the second metal, is chosen so as to have an extinction coefficient k.sub.m3 that is less than or equal to 2n.sub.m3, with n.sub.m3 being the refractive index of the third metal in the wavelength range. Thus, as part of an application of the invention in the near infrared and mid-infrared, the third metal may be titanium Ti, or platinum Pt, or tungsten W, or even an alloy of titanium and tungsten.
(48) Thus, in a practical example of this first embodiment, for a wavelength range centered around a central wavelength Δ.sub.0 of 2.7 μm, the opaque mask 140 may have the following properties: a first metal layer 141 made of titanium Ti with a thickness h.sub.m1 of 150 nm, a second metal layer 142 made of gold Au with a thickness h.sub.m2 of 100 nm, a third transparent layer 143 made of silicon dioxide SiO.sub.2 with a thickness ha of 120 nm, an assembly of the metal elements 144 in which the metal elements have a square-shaped projection onto the second surface of the support with a side length L.sub.em of 450 nm and a thickness h.sub.em of 200 nm, with the metal elements being arranged according to a square lattice with a pitch P of 800 nm.
(49) The simulations of such an opaque mask 140 conducted by the inventors using the Rigorous Coupled-Waves Analysis (RCWA) show that such a mask has, as shown in
(50) In order to demonstrate the small variation in the reflectivity R of such an opaque mask 140 with the angle of incidence of the electromagnetic radiation λ,
(51) One can thus see that in the wavelength range going from 2.45 μm to 3.1 μm, the reflectivity remains below 0.02, and this regardless of the polarization and incidence of the electromagnetic radiation.
(52) In addition, it is possible to optimize the opaque mask 140 to obtain a larger wavelength range for which the reflectivity remains below 5%. For instance, if we take the opaque mask 140 from the previous example, in which the metal elements 144 have a lateral dimension L.sub.em equal to 500 nm, a thickness h.sub.em equal to 225 nm, and a lattice pitch P of 1.1 μm, and the transparent layer 143 has a thickness h.sub.d of 140 nm, it is possible to obtain, in keeping with the inventors' simulations, a variation of the reflectivity 211 as illustrated in
(53) In addition, it is possible to optimize the opaque mask 140 to obtain a larger wavelength range for which the reflectivity remains below 5%. For instance, if we take the opaque mask 140 from the previous example, in which the metal elements 144 have a lateral dimension L.sub.em equal to 500 run, a thickness h.sub.em equal to 225 nm, and a lattice pitch P of 1.1 μm, and the transparent layer 143 has a thickness h.sub.d of 140 nm, it is possible to obtain, in keeping with the inventors' simulations, a variation of the reflectivity 214 as illustrated in
(54) According to the invention, and to avoid any optical leakage in the masked structure, which could originate from diffraction phenomena associated with the edges of the opaque mask 140, it is possible to arrange the opaque mask 140 on the second surface of the support 110 to block the electromagnetic radiation λ for the at least one masked structure and certain detection structures adjacent to the said at least one masked structure. Such a possibility also makes it possible to limit the leakage current phenomena which may occur in such a detection component 1 between the detection structures, and which could therefore interfere with the noise signal measured by the masked structure.
(55) To illustrate this phenomenon, as shown in
(56) It is therefore clear that, for a support 110 made of cadmium telluride and zinc CdZnTe, with a thickness of 10 μm, i.e. with a ratio of the support thickness to the refractive index of 7.5, the directly adjacent structures and the structures that are adjacent to them must also be covered by the opaque mask 140 to achieve an absorption of less than 0.1%.
(57) Thus, in keeping with the calculations made by the inventors, it is possible, in the case of a detection component 1 comprising a support that is 10 thick and with an opaque mask 140 extending on either side of a projection of the masked structure on the second surface over a distance greater than 30 μm (that is, two adjacent pixels of 15 μm per side), for a distance greater than 15 μm, this absorption remains less than 0.1%. With this same support thickness, for such a distance greater than 15 μm (that is, a single adjacent pixel of 15 μm per side), this absorption remains under 0.15%.
(58)
(59) According to the first example shown in
(60) According to the second preferred example shown in
(61) A detection component 1 according to this first embodiment may be made using a method comprising the following steps: a support 110 comprising a layer, called active layer 120 in which a plurality of structures 121a, 121b, 122, and 123 for detecting electromagnetic radiation λ in said wavelength range is provided, the support 110 comprising a first surface from which the active layer 120 extends, and a second surface opposite the first surface by which the support 110 is intended to receive the electromagnetic radiation λ, deposition of the first metal layer 141 made of the first metal in contact with the second surface of the support 110, deposition of the second metal layer 142 made of the second metal in contact with the first metal layer 141, deposition of the transparent layer 143 made of the transparent material in contact with the second metal layer 142, the third layer 143 being called a transparent layer, formation of an assembly of metal elements 144 made of the second metal on the transparent layer 143 opposite the second metal layer 142.
(62) Note that the step for forming assembly of metal elements 144 may comprise a sub-step for depositing a fourth layer of the second metal with a thickness h.sub.em, and a localized etching sub-step, for example by optical lithography, to only keep the parts of the fourth layer corresponding to the metal elements 144.
(63) According to a first and a second variant of this main embodiment of the invention, illustrated in
(64) In such an arrangement, with metal element 144 being part of both the first MIM structure 151, in accordance with the teaching of this document and the main embodiment, as well as the second MIM structure 152, in accordance with these first and second variants, a stacking of the resonant cavities of these first and second MIM structures 151, 152 is achieved. The cavities corresponding to the second MIM structures 152 have lateral dimensions that are less than or equal to those corresponding to the first MIM structures 151, since the lateral dimensions of the cavities of the second MIM structures 152 correspond to the lateral dimensions of the portions of the fourth transparent layer 145.
(65) As discussed below in reference to
(66) Thus, taking the first variant of this first embodiment shown in
(67) Note, in addition, that in this first variant the portion of the fourth transparent layer 145 and the portion of the fifth metal layer 146 extend corresponding the metal element 144 and, thus, have lateral dimensions that are identical to those of said metal element 144. The respective thickness of the fourth transparent layer 145 and of the fifth metal layer may be determined in a similar way to the thickness of the third transparent layer 143 and of the metal elements 144, respectively, and may be adjusted to optimize the wavelength range. Thus, if according to one possibility of this first variant the fourth transparent layer 145 may have a thickness identical to that of the third transparent layer 143, it is also perfectly conceivable that the fourth transparent layer 145 can have a greater thickness than that of the third transparent layer 143, with the latter preferably remaining greater than or equal to λ.sub.0/50n.sub.d or even λ.sub.0/25n.sub.d.
(68) Thus, according to an embodiment example of this first variant, the opaque mask 140 may have the following properties: a first metal layer 141 of gold Au 100 nm thick, a second metal layer 142 of titanium Ti 150 nm thick, a third transparent layer 143 of zinc sulfide ZnS 100 nm thick, metal elements 144 of titanium Ti 600 nm thick, a fourth transparent layer 145 of zinc sulfide ZnS 200 nm thick, a fifth metal layer 146 of titanium Ti 600 nm thick, and a lateral dimension for the metal elements 144, the portions of the fourth transparent layer 145 and the fifth metal layer 146.
(69)
(70) It can be seen from this graph that such a first variant (curve 232) makes it possible to achieve a relatively extensive wavelength range, since it goes from approximately 9.50 μm to approximately 13 μm, compared to a wavelength range obtained for an opaque mask 140 according to the main embodiment (curve 231), which goes from about 10.2 μm to about 10.8 μm.
(71) A detection component 1 according to this first variant of the main embodiment may be made by means of a manufacturing method that differs from a method for manufacturing a detection component 1 according to the first main embodiment in that, when assembly of the metal elements 144 is being made, there is a step for forming the fourth transparent layer 145 and the fifth metal layer 146 on a metal layer made of the third metal intended to form the metal elements 144, and a step for localized etching of the fifth metal layer 146, of the fourth transparent layer 145, and of the metal layer made of the third metal in order to laterally delimit the metal elements, the portions of the fourth transparent layer 145, and the portions of the fifth metal layer 146.
(72) According to the second variant of the main embodiment of the invention, shown in
(73) So, a detection component 1 according to this second variant of the first embodiment differs from a detection component 1 according to the first variant of the first embodiment in that, for each metal element 144, the portion of the corresponding fourth transparent layer 145 and the portion of the corresponding fifth metal layer 146 have lateral dimensions that are less than that of the said metal element 144.
(74) The method for manufacturing a detection component 1 according to this second variant of the first embodiment differs from the method for manufacturing a detection component 1 according to the first variant of the first embodiment in that the step for localized etching of the fifth metal layer 146, of the fourth transparent layer 145, and of the metal layer made of the third metal is conducted in two parts, one for a local etching of the fourth transparent layer 145 and of the fifth metal layer, and the other for a local etching of the layer of the third metal. Such a local etching in two parts provides, for each metal element 144, a portion of the fourth transparent layer 145 and a portion of the fifth metal layer 146 with smaller dimensions than those of the fourth transparent layer.
(75) Note that if, in the first embodiment of the invention and in the first and second variants of the first embodiment, the second metal layer 142 and the metal elements 144 are made of the second metal, it is still conceivable that opaque mask 140 may comprise a third metal and that the metal elements may be made of the third metal, without exceeding the scope of the invention. Such a third metal will then have an extinction coefficient k.sub.m3 strictly less than 5n.sub.m3, or even less than or equal to 2n.sub.m3, where n.sub.m3 is the refractive index of the third metal in the wavelength range. Likewise, if, in the first and second variants of the main embodiment, the fourth transparent layer 145 is made of the transparent material, it is also conceivable, and without exceeding the scope of the invention, that the fourth transparent layer 145 may be made of a second transparent material, with the understanding that the second material will have a refractive index less than or equal to 2 in the wavelength range. Similarly, if, in the first and second variants of the main embodiment, the fifth metal layer 146 is made of the second metal, it is also conceivable, and without exceeding the scope of the invention, that fifth metal layer 146 may be made of a fourth metal. Such a fourth metal will then preferably have an extinction coefficient k.sub.m4 strictly less than 5n.sub.m4, or even less than or equal to 2n.sub.m4, where n.sub.m4 is the refractive index of the fourth metal in the wavelength range.