SLAG-BASED HYDRAULIC BINDER, DRY MORTAR COMPOSITION COMPRISING SAME AND SYSTEM FOR ACTIVATING A SLAG-BASED BINDER

Abstract

A hydraulic binder including (in % by dry weight); A. at least 50 of at least one ground and granulated blast-furnace slag; B. more than 5 of at least one calcium aluminate cement and/or of at least one calcium sulfoaluminate cement; C. more than 5 of at least one source of sulfate ions; D. between 1 and 5 of Ca(OH).sub.2 and/or Portland cement; E. between 0.01 and 1 of at least one alkali metal carbonate; F. and at least one alkalifying reagent consisting of at least one alkali metal carbonate and/or bicarbonate, different from E; under the following conditions: (i) amount of C allows sulfate ions of C to react with B and A; (ii) the amount of F sufficiently causes a reaction with D in water resulting in a wet formulation with a pH not less than 12, for a water-to-mortar mixing rate between 10 and 35% by weight.

Claims

1. A hydraulic binder comprising (in % by dry weight): A. at least 50 of at least one ground and granulated blast-furnace slag; B. more than 5 of at least one calcium aluminate cement and/or of at least one calcium sulfoaluminate cement; C. more than 5 of at least one source of sulfate ions; D. between 1 and 5 of Ca(OH).sub.2 and/or of Portland cement; E. between 0.01 and 1 of at least one alkali metal carbonate; F. and at least one alkalifying reagent consisting of at least one alkali metal carbonate and/or bicarbonate, different from E; subject to the following conditions: (i) the amount of C is sufficient to allow the sulfate ions of C to react with B and with A; (ii) the amount of F is sufficient so that its reaction with component D in the presence of water brings the pH of the resulting wet formulation to a value of not less than 12, for a water-to-binder mixing rate of between 10 and 35% by weight.

2. The hydraulic binder according to claim 1, wherein 0.1<[C]/[A]; 0.5<[C]/[B].

3. The hydraulic binder according to claim 1, wherein the source C of sulfate ions is selected from the group comprising: natural or synthetic gypsum, calcium sulfate hemihydrate, bassanite, anhydrite, selenite, alabaster, fibrous gypsum, saccharoidal gypsum, marine gypsum, gypsum flower, phosphogypsum, desulfurization gypsum, titanogypsum, citrogypsum, tartarogypsum, borogypsum, lactogypsum and mixtures thereof.

4. The hydraulic binder according to claim 1, comprising (in % by dry weight): A. 55 to 90 of at least one ground and granulated blast-furnace slag; B. 5.5 to 30 of at least one calcium aluminate cement and/or of at least one calcium sulfoaluminate cement; C. 6 to 30 of at least one source of sulfate ions; D. 1 to 5 of Ca(OH).sub.2 and/or of Portland cement; E. 0.01 to 1 of Li.sub.2CO.sub.3; F. and at least one alkalifying reagent consisting of at least one alkali metal carbonate and/or bicarbonate, different from E; G. 0 to 10 of at least one binder different from A, B and D, comprising: silica or silica-alumina binders, fly ashes, advantageously silica-alumina fly ashes, silica-calcium-alumina fly ashes, expanded or calcined clay dusts and/or metakaolins.

5. A dry mortar composition wherein it comprises a binder according to claim 1.

6. The composition according to claim 5, wherein it is an adhesive mortar and in that it comprises (in % by dry weight): A. 10 to 50 of at least one ground and granulated blast-furnace slag; B. 0.5 to 20 of at least one calcium aluminate cement and/or of at least one calcium sulfoaluminate cement; C. 1 to 20 of at least one source of sulfate ions with 0.5≤[C]/[B]≤3; D. 0.05 to 5 of Ca(OH).sub.2 and/or of Portland cement; E. 0.02 to 0.8 of Li.sub.2CO.sub.3; F. and at least one alkalifying reagent consisting of at least one alkali metal carbonate and/or bicarbonate, different from E; G. 30 to 80 of at least one type of aggregates; H. 1 to 10 of at least one redispersible polymer; I. 0.01 to 5 of at least one thickener; J. 0.01 to 0.5 of at least retarder.

7. The composition according to claim 5, wherein it is a screed or a render and in that it comprises (in % by dry weight): A. 3 to 50 of at least one ground and granulated blast-furnace slag; B. 0.5 to 20 of at least one calcium aluminate cement and/or of at least one calcium sulfoaluminate cement; C. 1 to 20 of at least one source of sulfate ions with 0.5≤[C]/[B]≤3; D. 0.05 to 5 of Ca(OH).sub.2 and/or of Portland cement; E. 0.02 to 0.8 of Li.sub.2CO.sub.3; F. and at least one alkalifying reagent consisting of at least one alkali metal carbonate and/or bicarbonate, different from E; G. 30 to 80, preferably from 40 to 70, of at least one type of aggregates; H. 1 to 10 of at least one redispersible polymer; I. 0.01 to 5 of at least one thickener; J. 0.01 to 0.5 of at least retarder.

8. An activating system for a hydraulic binder for mortars, wherein it comprises (in % by dry weight): C. 60 to 93 of at least one source of sulfate ions; D. 5 to 25 of Ca(OH).sub.2 and/or of Portland cement; E. 1 to 3 of Li.sub.2CO.sub.3; F. at least one alkali metal carbonate and/or bicarbonate, different from E; and in that the binder comprises (in % by dry weight): A. 60 to 99 of at least one ground and granulated blast-furnace slag; B. 40 to 1 of at least one calcium aluminate cement and/or at least one calcium sulfoaluminate cement.

9. A method comprising applying the binder according to claim 1 in a dry mortar composition or wet mortar formulation.

10. A method comprising applying an activating system comprising (in % by dry weight): C. 60 to 93 of at least one source of sulfate ions; D. 5 to 25 of Ca(OH).sub.2 and/or of Portland cement; E. 0.5 to 5 of Li.sub.2CO.sub.3; F. at least one alkali metal carbonate and/or bicarbonate, different from E; to a hydraulic binder for a mortar for activating the hydraulic binder, the binder comprising (in % by dry weight): A. 60 to 99 of at least one ground and granulated blast-furnace slag; B. 40 to 1 of at least one calcium aluminate cement and/or at least one calcium sulfoaluminate cement; wherein C is employed in an amount sufficient to allow the sulfate ions of C to react with B and with A.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0062] Binder ABCDEF

The inventors have succeeded in developing an eco-friendly binder ABCDEF which is based on ground and granulated blast-furnace slag and which enables the formulation of dry compositions, particularly mortar compositions and more particularly adhesive mortar compositions, which lead, after hardening (mixing with water), to hardened products which are adherent or mechanically strong and which meet the specifications expected in the end-use applications of building products, more particularly of adhesive mortars according to standard EN NF 12004 April 2017.

[0063] The Ground and Granulated Blast-Furnace Slag A

This is preferably a ground and dried, granulated blast-furnace slag having an average glass content of more than 90% (measurement by X-ray diffraction). This slag conforms to European standard NF EN 15167-1 of 1 Sep. 2006.

[0064] This slag is advantageously a C.E. ground granulated blast-furnace slag produced at Fos-sur-Mer by ECOCEM® and having the following characteristics:

Chemical Composition (Average Percentage)

[0065]

TABLE-US-00003 SiO  Fe  CaO MgO SO   O K.sub.2O Na.sub.2O  37.3 10.7 0.2 43.0 6.5 0.7 0.1 0.01 0.8 0.23 0.35 0.45 Chemical modulus (CaO + MgO   SiO2: > 1.25 (≥ 1.2: class A to NF EN 206-1/CN) indicates data missing or illegible when filed

Chemical Characteristics (Representative, Indicative Values)

[0066]

TABLE-US-00004 Formulation Initial Reference Compressive strengths ACTIVITY INDEX setting Ecocem cement 7 d 28 d 90 d 7 d 28 d 90 d time (min)  0% 100% 43 55 64 — 170 50%  50% 31 55 55  72% 100% 103% 210 Limits of the product standard ≥45% ≥70% <2× cement NF EN 15167-1 setting time Class A limits acc. to standard NF EN ≥65% ≥80% 206/CN

Other Characteristics

[0067]

TABLE-US-00005 Blame specific surface area 4 450 ± 250 cm.sup.2/g ≥2 750 cm.sup.2/g: NF EN 15167-9 ≥4 200 cm.sup.2/g: class A acc. to NF EN 206/CN Indicative median diameter (d50) 11 μm Undersize at 32 μm ≥9.5% Density 2.90 ± 0.03 cm.sup.3 Bulk density 0.8 ± 0.1 cm.sup.3 Index [CIE L*a*b*] with CR410 L* × 89.9 ± 2 Loss on ignition (950° C.) <1.5% Moisture constant (100° C.) <0.5%
Any other ground and granulated blast-furnace slag having the features above with a range of variation of +/−10% is an appropriate slag A for forming part of the composition of the binder according to the invention.
According to one notable mode of the invention, at least a portion of the slag A has a Blaine specific surface area of between 3000 and 5000 cm.sup.2/g, preferably between 4200 and 4700 cm.sup.2/g, and, optionally, at least one other portion of slag A has a Blaine specific surface area of more than 5000 and not more than 20 000 cm.sup.2/g, preferably between 6500 and 8500 cm.sup.2/g.

[0068] Calcium Aluminate and/or Sulfoaluminate Cement B and/or Binder

[0069] Cements based on calcium aluminate (CAC) or high-alumina cements result from the fusing of a mixture of limestone and bauxite, followed by milling without gypsum to a fineness comparable with that of Portland cements. The minimum strengths guaranteed in “standard mortar” are as follows: compressive strength in N/mm.sup.2 at 6 hours: ≥18; at 24 hours: ≥40. These cements are defined by standard EN14647.

[0070] The cement based on calcium sulfoaluminate (CSA) may be an alitic sulfoaluminate cement, a ye'elimitic cement and/or belitic cement and/or a binder having a high cement-phase content and being rich in alumina: (for example Al.sub.2O.sub.3>30%)

[0071] Sulfate Ion Source C

The source C of sulfate ions is selected from the group comprising—or better still consisting of—: natural or synthetic gypsum, calcium sulfate hemihydrate, bassanite, anhydrite, selenite, alabaster, fibrous gypsum, saccharoidal gypsum, marine gypsum, gypsum flower, phosphogypsum (gypsum from phosphoric acid manufacture), desulfurization gypsum, titanogypsum (gypsum from the neutralization of the sulfuric acid produced in the process synthesizing titanium dioxide), citrogypsum (gypsum from citric acid manufacture), tartarogypsum (gypsum from tartaric acid manufacture), borogypsum (gypsum from boric acid manufacture), lactogypsum (gypsum from lactic acid manufacture), and mixtures thereof.

[0072] The amount of C is sufficient to allow the sulfate ions of C to react with B and with A; in other words, there remains sufficient sulfate C to activate the slag A when all of the high-alumina cement or sulfoaluminate cement B has been consumed. Accordingly, the mass ratios C/A and C/B are, for example, as follows:

0.1≤[C]/[A]≤1

0.5≤[C]/[B]≤3

[0073] The following reactions takes place, for example when B is a calcium aluminate cement:

[00001]$C_5{S}_{3}A+2C\overline{S}+\frac{76}{3}H.fwdarw.3CSH+\frac{2}{3}{C}_{6}A{\overline{S}}_3{H}_{32}+\frac{1}{3}{\mathrm{AH}}_3$

[0074] Component D: Ca(OH).sub.2 and/or Portland Cement CEM

Lime ca(OH).sub.2: This may be provided by quicklime, slaked lime, air lime, or hydraulic lime.
ca(OH).sub.2 is preferably selected from the group comprising—ideally consisting of—the following limes: CL 90, DL 85, CL 80, DL 80, CL 70, DL 70, HL 2, HL 3.5, HL 5, NHL 2, NHL 3.5, NHL 5, NHL-Z, and mixtures thereof
It may for example be Chaubat CL90 air lime from Bonargent-Goyon; white hydraulic lime NHL-3.5Z CE sold by Lafarge ciments, usine du Cruas (composition: lime 89%, CEM II/A-LL 42.5 N CE PM-CP2 NF “white”: 11%).

Portland Cement:

[0075] In accordance with the invention, the Portland cement conforms to that defined in the European standard EN 197-1, comprising five classes as follows: CEM I: Portland cement; CEM II: composite Portland cement; CEM III: blast-furnace cement; CEM IV: pozzolanic cement; CEM V: composite cement.
Mention may be made, by way of example, of the following: CEM I 42.5 R, Portland cement CEM I, 52.5N.

[0076] Alkali Metal Carbonate E

According to one noteworthy mode of the invention, component E may be lithium carbonate, potassium carbonate and/or sodium carbonate. Lithium carbonate is preferred.

[0077] Alkalifyinq Reagent F

F is a metal carbonate and/or bicarbonate, preferably NaHCO.sub.3; Na.sub.2CO.sub.3; K.sub.2CO.sub.3, with KHCO.sub.3 being preferred.
The amounts of [D] and [F] are sufficient to react in a formulation comprising the binder, aggregates, fillers, water and, optionally, additives, and to bring the pH of this wet formulation to a value of not less than 12, preferably not less than 13. This may correspond, for example, to the following ratios [F]/[D]:
0.2<[F]/[D]; preferably 0.2≤[F]/[D]≤1.5, and, more preferably still,

0.3≤[F]/[D]≤1.

[0078] The reaction is, for example, Ca(OH).sub.2+NaHCO.sub.3.fwdarw.NaOH+CaCO.sub.3.

[0079] Binder G Different from A, B and D

G is preferably selected from the group comprising—or better still consisting of—: silica or silica-alumina binders, fly ashes, advantageously silica-alumina fly ashes, silica-calcium-alumina fly ashes, expanded or calcined clay dusts and/or metakaolins.
Possible examples include the metakaolins obtained by a flash process or a traditional process, and fly ashes of type C or F.

[0080] Dry Mortar Composition ABCDEF(G)HIJK

This composition is, for example, an adhesive mortar, a screed or a render. Components ABCDEF and their respective proportions are defined above. The aggregates or fillers H, the redispersible polymers I, the thickness J and the retarders K are defined below.

[0081] Aggregates or Fillers H

They are advantageously selected from the group comprising or, better still, consisting of: fillers and/or sands, preferably from silica, lime, silica-lime and magnesium-containing sands and mixtures thereof, silica, lime and silica-lime and magnesium-containing fillers and mixtures thereof, and/or from metal oxides, aluminas, and/or from glass beads and natural and synthetic silicate minerals preferably selected from clays, micas, metakaolins, silica fumes and mixtures thereof.

[0082] Redispersible Polymers I

I is selected from the group comprising or, better still, consisting of the following classes of resins: acrylic homo- or copolymers, ethylene-vinyl acetate copolymers, styrene-acrylic copolymers, terpolymers of vinyl acetate, vinyl versatate and dialkyl maleate, copolymers of vinyl acetate and vinyl versatate, copolymers of styrene and butadiene, and mixtures thereof.

[0083] Thickeners J

J is selected from the group comprising or, better still, consisting of polysaccharides and preferably cellulose ethers or starch ethers and mixtures thereof, and preferably from the group comprising methyl celluloses, hydroxyethyl celluloses, methylhydroxypropyl celluloses, methylhydroxyethyl celluloses and mixtures thereof, or from modified or unmodified guar ethers and mixtures thereof, or a mixture of these different classes.

[0084] Retarders K

K is selected from the group comprising or, better still, consisting of calcium-chelating agents, carboxylic acids and salts thereof, polysaccharides and derivatives thereof, phosphonates, lignosulfonates, phosphates, borates, and lead, zinc, copper, arsenic and antimony salts, and more particularly from tartaric acid and its salts, preferably its sodium or potassium salts, citric acid and its salts, preferably its sodium salt (trisodium citrate), sodium gluconates; sodium phosphonates; sulfates and their sodium or potassium salts, and mixtures thereof.

[0085] Various other additives may also be employed in the dry mortar composition, more particularly adhesive mortar composition.

These additives may be setting accelerators, water retainers, light fillers, water repellents, colourants, fibres, antifoams, rheological agents, air entrainers or foam-formers, gas-generating agents, flame retardants, etc., and mixtures thereof.
The setting accelerator additive may be selected from the group comprising or, better still, consisting of the alkali metal and alkaline earth metal salts of hydroxides, halides, nitrates, nitrites, carbonates, thiocyanates, sulfates, thiosulfates, perchlorates, silica, aluminium, and/or from carboxylic and hydroxycarboxylic acids and salts thereof, alkanolamines, insoluble silicate compounds such as silica fumes, fly ashes or natural pozzolans, quaternary ammonium silicates, finely divided inorganic compounds such as finely divided magnesium and/or calcium carbonates or silica gels, and mixtures thereof; said complementary setting accelerator (e) being preferably selected from the group comprising or, better still, consisting of chlorides and their sodium or calcium salts, carbonates and their sodium or lithium salts, sulfates and their sodium or potassium salts, calcium formates and hydroxides, and mixtures thereof.
The colourant additive is advantageously selected from the group comprising or, better still, consisting of organic and/or inorganic pigments, and more particularly from the oxides of iron, titanium, chromium, tin, nickel, cobalt, zinc and/or antimony, and/or from polysulfided sodium aluminosilicates, carbon, sulfides of cobalt, manganese, zinc, and/or from pigments which have high transparency or high reflectivity for infra-red radiation, and mixtures thereof.
The light filler additive is advantageously selected from the group comprising, or better still, consisting of: expanded perlite, expanded vermiculite, silica aerogels, expanded polystyrene, cenospheres (Fillites®), hollow alumina beads, expanded clays, pumices, hollow glass beads (3M® type) or expanded glass granules (Poraver®, Liaver®), silicate foam particles, and rhyolite (Noblite®).
The water repellent additive is advantageously selected from the group comprising or, better still, consisting of agents in the form of fluorine, silane, silicone and siloxane compounds, metal salts of fatty acids and mixtures thereof, and preferably from the sodium, potassium and/or magnesium salts of oleic and/or stearic acid and mixtures thereof.
The fibre additive preferably comprises mineral, animal, plant and synthetic fibres, more particularly selected from the group comprising or, better still, consisting of fibres of polyamide, polyacrylonitrile, polyacrylate, cellulose, polypropylene, polyvinyl alcohol, glass, metal, flax, polycarbonate, sisal, jute and hemp, and mixtures of these fibres.
The antifoam additive is preferably selected from the group comprising or, better still, consisting of polyether polyols, hydrocarbon molecules, silicone molecules, hydrophobic esters, nonionic surfactants, polyoxiranes, and mixtures thereof.
The rheological additive is preferably selected from the group comprising or, better still, consisting of thickeners, plasticizers (organic and/or inorganic) and mixtures thereof, and preferably from the subgroup comprising or, better still, consisting of polysaccharides and derivatives thereof, polyvinyl alcohols, inorganic thickeners, linear polyacrylamides, polynaphthalene sulfonates, polymelamine sulfonates, polycarboxylate ethers, polycarboxylate esters and mixtures thereof.
The surfactant additive is anionic, nonionic or amphoteric.
The sources of anionic surfactants are, for example, alkyl sulfates, alkyl ether sulfates, alkarylsulfonates, alkylsuccinates, alkylsulfosuccinates, alkoyl sarcosinates, alkyl phosphates, alkyl ether phosphates, alkyl ether carboxylates, and/or alpha-olefinsulfonates, and preferably sodium lauryl sulfate.
The nonionic surfactants are, for example, ethoxylated fatty alcohols, mono- or dialkyl alkanolamides, and/or alkyl polyglucosides.
The amphoteric surfactants are, for example, alkyl amine oxides, alkyl betaïnes, alkyl amido propyl betaïnes, alkyl sulfobetaïnes, alkyl glycinates, alkyl amphopropionates, and/or alkyl amidopropyl hydroxysultaïnes.
The in situ gas generator additive is advantageously selected from those adjuvants which, in contact with the compositions according to the invention, generate oxygen, hydrogen, nitrogen, carbon monoxide or dioxide, ammonia or methane. They may be selected from the adjuvants described in U.S. Pat. No. 7,288,147, and more particularly from the classes of the azodicarbonamides, sodium bicarbonate, organic or inorganic peroxides, toluene sulfonyl hydrazide, benzene sulfonyl hydrazide, toluene sulfonyl acetone hydrazone, toluene sulfonyl semicarbazide, phenyltetrazole, sodium borohydride and dinitrosopentamethylenetetramine.
The flame retardant additive is advantageously selected from the group comprising or, better still, consisting of flame-retarding agents having chemical and/or physical activities, halogenated flame retardants, phosphorus-containing flame retardants, nitrogen-containing flame retardants, intumescent systems, inorganic flame retardants, metal hydroxides, zinc compounds, borates, antimony oxides, nanocomposites based on clays based on aluminium silicates, and mixtures thereof; and preferably from the subgroup comprising or, better still, consisting of Tetrachlorobisphenol A (TBBPA), chlorinated paraffins, organic phosphates, red phosphorus, phosphonates, phosphinates, melamine, its salts and homologues, aluminium hydroxides or magnesium hydroxides, zinc hydroxystannates, zinc borate, and mixtures thereof.

[0086] Activating System

The invention likewise relates to an activated system CDEF for a binder AB.

[0087] Wet Formulation

The invention likewise relates to a wet formulation obtained from the dry composition defined above mixed with water, preferably according to a mixing rate of between 10 and 35%, preferably between 15 and 30%.

[0088] Process for Preparing a Wet Formulation

The invention likewise relates to a process for preparing the wet formulation above.

[0089] Use of an Activating System

The invention likewise relates to the use of an activating system CDEF for a binder AB.

[0090] Hardened Products for Construction

The invention is also directed to the hardened products for construction that are obtained starting from the above wet formulation and/or from that obtained by the process defined below, these hardened products being, in particular, as follows: products obtained on the building site by hardening the wet formulations resulting from the mixing of the compositions according to the invention, e.g.: adhesive mortars, seals, patching renders, smoothing renders; screeds, lightweight screeds for heated floors; exterior coatings in the form of thick-film or thin-film mineral coatings and mineral paints; components of exterior thermal insulation (ETI) systems, including the adhesive for insulating material, the undercoat used to fix the mesh, and the exterior finishing coat; tiling adhesives; tiling seals; jointing renders; interior and exterior renders, for example single-coat renders; insulating material for the exterior or interior of buildings; filling mortars or concretes; grouting mortar, mortars for concrete repair, mortars with freeze-thaw resistance, a concrete waterproofing system, sealing membranes; injection slurries, lightweight slurries for the cementation of oil wells; lightweight mortars or concretes intended for placement by spraying or pouring into hollow walls or into permanent formwork for the production of new buildings or the renovation of old buildings; products prefabricated industrially by hardening the wet formulations resulting from the mixing of the compositions according to the invention, e.g.: lightweight prefabricated panels intended for the assembly of buildings (load-bearing elements or insulating panels); lightweight concrete blocks for the use as structural or insulating or facing elements; prefabricated elements, such as window sills, brackets, mouldings, etc.

[0091] Construction or Civil Engineering Works

The invention also relates to construction or civil engineering works carried out at least partly with a wet formulation, this formulation hardening after it has been applied and shaped, or on the basis of the hardened construction products.

[0092] Processes

The invention also relates to processes for preparing the dry composition above, the process for applying the wet formulation defined above to a building surface, or the process for producing hardened products for construction, for building or civil engineering works, by means of the wet formulation according to the invention.

EXAMPLES

Examples 1 to 3

[0093] Table 1 below gives the formulas of three adhesive mortar compositions—C2S, C2S2 and C2F—according to examples 1, 2 and 3

[0094] I. Materials Used

Binder A, ground and granulated blast-furnace slag: Ecocem® ground slag
Component B: TERNAL® RG calcium aluminate cement from Imerys® Aluminates —CaO.Al.sub.2O.sub.3-2CaO.Al.sub.2O.sub.3.SiO.sub.2-12CaO.7Al.sub.2O.sub.3-2CaO.SiO.sub.2-4CaO.Al.sub.2O.sub.3.Fe.sub.2O.sub.3
Component C: source of sulfate ions: “SULFACAL AH Micro AF” CaSO.sub.4, micronized anhydrite from SMA FAULQUEMONT 57
Component D: Tradical® H90 from LHOIST (Précy sur Oise/U59)

Component H:

[0095] 1) natural calcium carbonate BL200 sold by Omya
2) Dried washed sand PE2LS—Fulchiron
Component I: redispersible polymer based on a vinyl acetate/vinyl chloride/ethylene copolymer, having a minimum film-forming temperature of 5° C.
Component J: hydroxyethylmethylcellulose (NEMC) with MW 40 000 or Opagel CMT pregelatinized starch ether 500-1500 mPa.Math.s from AVEBE®
Component E: lithium carbonate from RODACHEM BV
Component F: alkalifying reagent NaHCO.sub.3 from BRENNTAG SA
Retarder K: tartaric acid from Ets FAURE et FILS, trisodium citrate from BRENNTAG SA, sodium gluconates from UNIVAR, citric acid from UNIVAR.

[0096] II. Tests:

The standard employed for the test of determining the flexural and compressive strengths is NF EN 196-1.

[0097] III. Preparation of Mortars:

Procedure

Preparation of Dry Mixes:

[0098] The powdered starting materials are weighed out independently in accordance with the formulations. The starting materials are then mixed in a Guedu powder mixer for 3 minutes.

Water Mixing of the Dry Mixes

[0099] The dry mortars obtained are mixed with the water required to produce a homogeneous paste, in a Perrier planetary mixer, for one minute and thirty seconds.

TABLE-US-00006 TABLE 1 C.sub.2S.sub.1 C.sub.2S.sub.2 C.sub.2F Example 1 Example 2 Example 3 SM Type % % % ECOCEM FOS slag Binder A (ground and granulated 22.5 29.5 27 blast-furnace slag) Ternal RG B: calcium aluminate cement 2.5 2.5 7 (Imerys Aluminates) Micronized anhydrite C: Source of sulfate ions, CaSO.sub.4 4 4 7 Tradical H90 D: Ca(OH).sub.2 0.9 0.9 0.9 (Précy sur Oise/U59) CL90 BL200EN H: CaCO.sub.3 aggregate/filler 2.5 0 0 PE2LS H: silica sand aggregate/filler 0.1- 64.1 57.22 55.01 0.4 mm Redispersible polymer I: copolymer of vinyl acetate, vinyl 2.5 5 2 chloride and ethylene, having a minimum film-forming temperature of 5° C. Thickener J1 J1: Hydroxyethylmethyl cellulose 0.25 0.25 0.25 Thickener J2 HEMC 35 000-45 000 mPas 0.1 0 0 J2: pregelatinized starch ether 500-1500 mPas Lithium carbonate E: Li.sub.2CO.sub.3 0.1 0.1 0.1 Sodium bicarbonate F: alkalifying reagent, NaHCO.sub.3 0.4 0.4 0.4 K: mixture of retarders 0.15 0.13 0.34 CO.sub.2 footprint (kg/t) 182 256 189

[0100] IV. Results

TABLE-US-00007 TABLE 2 Example 1 Example 2 Example 3 Water demand (%) 22 23.5 24.5 Viscosity (Pa s) 330 290 310 Adhesion (MPa) 6 hours — — 0.55 Adhesion (MPa) 24 hours at 20° C. 0.48 0.51 0.75 Adhesion (MPa) 24 hours at 5° C. 0.30 — 0.48 Adhesion (MPa) 28 days 1.41 1.45 1.66 Wet adhesion (MPa) 28 days 1.60 1.91 1.28 Adhesion (MPa) with respect to heat, 28 1.46 1.63 1.71 days Adhesion (MPa) open time 30 minutes 0.89 1.11 1.19 Deformability mm/m 2.64 5.12 NC % transfer 10 mm 100 100 100 % transfer 15 mm 100 100 90 % transfer 20 mm 80 95 90 % transfer 25 mm 70 90 90 % transfer 30 mm 40 45 80

[0101] V. Comments:

The binder, the activating system and the mortars, more particularly the adhesive mortars, according to the invention (based on ground granulated blast-furnace slag with a low carbon footprint) are economical, exhibit a good open time and good transfer, have a satisfactory setting time at 5 and 20° C., possess high deformability with low levels of redispersible polymer, and do not require corrosive “Xi” labelling on the bags of dry mortar.
The wet formulations according to the invention also have good handling qualities, making them easier to use.

Examples 4 to 8

[0102] Tables 3 and 4 below give the formulas and the performance properties of three C2S1 adhesive mortar compositions and of two C2F adhesive mortar compositions. The materials employed, the preparation of the mortars and the tests are the same as for examples 1 to 3.

TABLE-US-00008 TABLE 3 Components of C2S1 ADHESIVE the compositions Example 4 Example 5 Example 6 according to the Percentage in the mortar formula invention Components (%) (%) (%) A GGBS 29.5 29.5 22.5 B CAC 2.5 2.5 2.5 C C$ 4 4 4 D Ca(OH)2 0.9 0.9 0.9 E Li2CO3 0 0.1 0.1 F NaHCO3 0.4 0.4 0.4 Percentage expressed at 100% relative to the binder (%) (%) (%) A GGBS 79 79 74 B CAC 7 7 8 C C$ 11 11 13 D Ca(OH)2 2.41 2.41 2.96 E Li2CO3 0 0.27 0.33 F NaHCO3 1.07 1.07 1.32 Performance Adhesion in 0.53 1.91 1.17 property water (MPa) Ratio C/A 0.14 0.14 0.18 Ratio C/B 1.60 1.60 1.60 Ratio F/D 0.44 0.44 0.44

TABLE-US-00009 TABLE 4 Components of C2S1 ADHESIVE the compositions Example 7 Example 8 according to the Percentage in the formula of mortar invention: Components: (%) (%) A GGBS 27 27 B CAC 7 7 C C$ 5.6 7 D Ca(OH)2 0.9 0.9 E Li2CO3 0.1 0.1 F NaHCO3 0.4 0.4 Percentages expressed at 100% relative to the binder (%) (%) A GGBS 66 64 B CAC 17 17 C C$ 14 17 D Ca(OH)2 2.2 2.12 E Li2CO3 0.24 0.24 F NaHCO3 0.98 0.94 Performance Adhesion in 0.77 1.22 property water (MPa) Ratio C/A 0.21 0.26 Ratio C/B 0.80 1.00 Ratio F/D 0.44 0.44

Examples 9 and 10

[0103] Table 5 below gives the formulas and the performance properties of two screed compositions. The preparation of the mortars and the tests are the same as for examples 1 to 8.

TABLE-US-00010 TABLE 5 Screed composition Example 9 Example 10 A ECOCEM Dunkirk slag 9.5 5.4 D Ca(OH).sub.2 Tradical H90 (Précy) 0.9 0.9 C CaSO.sub.4 Prestia Selecta 2.5 C CaSO.sub.4 Sulfacal Micro AF 4.5 B CAC Ternal RG 5.51 8.1 H sand Parcay 1/2 9.72 9.72 H sand MI 0.1/1.2 38.1 38.1 H sand Filler DC8 15 15 H sand PE2LS 16.19 16.19 I polymer I1: copolymer of vinyl acetate, vinyl 1.7 1.7 chloride and ethylene, having a minimum film-forming temperature of 5° C. I polymer I2: mixture of hydrocarbon liquids and 0.05 0.05 polyglycols on an inert support having a bulk density of 330 g/l I polymer I3: modified polycarboxyl ethers 0.15 0.15 having a density of between 300 and 600 kg/m3 E Lithium carbonate 0.1 0.1 K retarder K1 0.1 0.3 J thickener J: biopolymer gum 0.12 0.12 F alkalifying reagent Sodium bicarbonate 0.4 0.4 (pharm. Gr 13/27) Mixing rate (%) 17 17 Initial flow (sec) 15 18 Slump flow (mm) 133 125 / 125 / 128 Settling no no Setting time 12 40 DP 35 57 FP 55 75 Flexural strength 24 h (MPa) 3.4 5.24 Compressive strength 24 h (MPa) 8.4 11.5 Flexural strength 28 d (MPa) / / Compressive strength 28 d (MPa) 14.72 20.76

Examples 11 to 12

[0104] Table 6 below gives the formulas and performance properties of two adhesive mortar compositions.
The preparation of the mortars and the tests are the same as for examples 1 to 10

TABLE-US-00011 TABLE 6 Components of the C2S1 ADHESIVE compositions Example 11 Example 12 according to the Percentage in the formula of the mortar invention: Components: (%) (%) A GGBS 22.5 22.5 B CAC 2.5 2.5 C C$ 4 6 D Ca(OH)2 0.9 0.9 D Portland cement 2 0 E Li2CO3 0.1 0.1 F NaHCO3 0.4 0.4 Percentages expressed at 100% relative to the binder (%) (%) A GGBS 69.4 69.4 B CAC 7.7 7.7 C C$ 12.3 18.5 D Ca(OH)2 2.8 2.8 D Portland cement 6.2 0 E Li2CO3 0.3 0.3 F NaHCO3 1.2 1.2 Performance Adhesion in 0.75 0.76 property water (MPa) Ratio C/A 0.18 0.27 Ratio C/B 1.6 2.4 Ratio F/D 0.13 0.43