System and method for separating methane and nitrogen with reduced horsepower demands
12631393 ยท 2026-05-19
Assignee
Inventors
Cpc classification
F25J2240/12
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2205/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/40
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2270/12
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0257
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/72
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/78
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2245/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/50
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A system and method for removing nitrogen from natural gas using two fractionating columns, that may be stacked, and a plurality of separators and heat exchangers, with horsepower requirements that are 50-80% of requirements for prior art systems. The fractionating columns operate at different pressures. A feed stream is separated with a vapor portion feeding the first column to produce a first column bottoms stream that is split into multiple portions at different pressures and first column overhead stream that is split or separated into two portions at least one of which is subcooled prior to feeding the top of the second column. Optional heat exchange between first column and second column streams provides first column reflux and reboil heat for a second column ascending vapor stream. Three sales gas streams are produced, each at a different pressure.
Claims
1. A NRU system for separating nitrogen from methane and heavier hydrocarbons to produce a methane product stream, the NRU system comprising: a first fractionating column wherein at least a first feed stream comprising nitrogen, methane, and heavier hydrocarbons is separated into a first vapor stream and a first column bottoms stream; a first splitter for splitting the first column bottoms stream into a first portion, a second portion, and a third portion; a second fractionating column wherein at least a first column overhead stream is separated into a second column overhead stream and a second column bottoms stream; a first heat exchanger wherein the first feed stream is cooled upstream of the first fractionating column through heat exchange with a first set of heat exchange streams comprising the second column overhead stream, the first portion of the first column bottoms stream, the second portion of the first column bottoms stream, and the third portion of the first column bottoms stream; a second heat exchanger wherein the first vapor stream from an upper fractionation zone of the first fractionating column is cooled and partially condensed through heat exchange with a refrigerant stream to produce the first column overhead stream and a reflux stream that is returned to the first fractionating column; wherein the methane product stream comprises the first portion of the first column bottoms stream, the second portion of the first column bottoms stream, and the third portion of the first column bottoms stream; wherein the refrigerant stream comprises the third portion of the first column bottoms stream; and wherein the second column overhead stream comprises 98% or more nitrogen.
2. The NRU system of claim 1 wherein the second heat exchanger comprises a first shell and tube heat exchanger comprising a tube side and a shell side, and wherein the first vapor stream is on the tube side and the refrigerant stream is on the shell side; wherein an amount of methane in the first feed stream on a mole fraction basis is substantially higher than an amount of heavier hydrocarbons in the first feed stream; and wherein the reflux stream comprises (1) an amount of nitrogen that is greater on a mole fraction basis than an amount of nitrogen in the first feed stream and (2) an amount methane that is less on a mole fraction bases than the amount of methane in the first feed stream.
3. The NRU system of claim 2 wherein the tube side of the second heat exchanger comprises a plurality of tubes disposed inside the shell side of the second heat exchanger and wherein the plurality of tubes are oriented substantially vertically.
4. The NRU system of claim 3 wherein the second heat exchanger is external to the first fractionating column and external to the second fractionating column.
5. The NRU system of claim 1 wherein the second heat exchanger is external to the first fractionating column and external to the second fractionating column.
6. The NRU system of claim 3 wherein the refrigerant stream comprises at least a first portion of the second column bottoms stream.
7. The NRU system of claim 1 wherein a second feed stream also comprising nitrogen, methane, and heavier hydrocarbons is also separated into the first vapor stream and the first column bottoms stream in the first fractionating column; wherein the second feed stream feeds into the first fractionating column as a mixed liquid and vapor stream at a second level lower than a first level where the first feed stream feeds into the first fractionating column as a liquid stream.
8. The NRU system of claim 7 further comprising a reboiler for the first fractionating column wherein a liquid stream from a lower fractionation zone of the first fractionating column is warmed and partially vaporized into a second vapor stream through heat exchange with the second feed stream and wherein the second vapor stream is returned to the first fractionating column; and wherein the second feed stream is cooled in the reboiler prior to feeding into the first fractionating column.
9. The NRU system of claim 8 wherein the reboiler comprises a second shell and tube heat exchanger comprising a tube side and a shell side, wherein the second feed stream is on the tube side of the reboiler and the liquid stream is on the shell side of the reboiler.
10. The NRU system of claim 6 wherein the refrigerant stream comprises a higher vapor mole fraction percentage when it exits the second heat exchanger than when it entered the second heat exchanger.
11. The NRU system of claim 6 wherein the refrigerant stream is substantially in vapor form when it exits the second heat exchanger and is substantially in liquid form when it enters the second heat exchanger.
12. The NRU system of claim 1 further comprising: a second splitter for splitting the first column overhead stream upstream of the second fractionating column into a first portion of the first column overhead stream and a second portion of the first column overhead stream; a third heat exchanger for subcooling the first portion of the first column overhead stream by at least 40 F. upstream of feeding into a too level of the second fractionating column through heat exchange with the second column overhead stream upstream of the first heat exchanger.
13. The NRU system of claim 12 further comprising a fourth heat exchanger wherein the second portion of the first column overhead stream is cooled upstream of feeding into the top level of the second fractionating column through heat exchange with a second set of heat exchange streams comprising the second column bottoms stream.
14. The NRU system of claim 13 further comprising a first separator wherein the second column bottoms stream downstream of the fourth heat exchanger is separated into a first separator overhead stream and a first separator bottoms stream; and wherein the first separator overhead stream feeds into a bottom fractionation level of the second fractionating column; wherein the methane product stream further comprises the first separator bottoms stream; and wherein the second set of heat exchange streams further comprises the first separator bottoms stream.
15. The NRU system of claim 14 further comprising: a second separator for separating a system feed stream into a second separator overhead stream and a second separator bottoms stream; a third splitter to split the second separator overhead stream into the first feed stream and a second feed stream also comprising nitrogen, methane, and heavier hydrocarbons and wherein the second feed stream is also separated into the first vapor stream and the first column bottoms stream in the first fractionating column; and wherein the first set of heat exchange streams further comprises the first separator bottoms stream downstream of the fourth heat exchanger and the second separator bottoms stream.
16. The NRU system of claim 15 wherein the system feed stream is cooled in the first heat exchanger upstream of the second separator and wherein the first portion of the first column overhead stream is subcooled by at least 60 F. in the third heat exchanger upstream of feeding into the second fractionating column.
17. The NRU system of claim 16 wherein the second heat exchanger is external to the first fractionating column and external to the second fractionating column.
18. The NRU system of claim 17 further comprising a reboiler for the first fractionating column wherein a liquid stream from a lower fractionation zone of the first fractionating column is warmed and partially vaporized into a second vapor stream through heat exchange with the second feed stream upstream of the second feed stream feeding into the first fractionating column and wherein the second vapor stream is returned to the first fractionating column.
19. The NRU system of claim 1 wherein the second heat exchanger comprises a knockback condenser.
20. The NRU system of claim 2 wherein the first shell and tube heat exchanger comprises a knockback condenser.
21. The NRU system of claim 19 wherein the knockback condenser comprises: a plurality of heat exchange tubes disposed inside a shell space; a headspace zone disposed above and in fluid communication with the plurality of heat exchange tubes; a riser tube configured to allow fluid communication of the first vapor stream from the upper fractionation zone of the first fractionating column to the headspace zone; and a refrigerant inlet and a refrigerant outlet to allow fluid communication of the refrigerant stream through the shell space.
22. The NRU system of claim 21 wherein the knockback condenser further comprises: an intermediate zone disposed below the plurality of heat exchange tubes, the intermediate zone configured to receive a mixed stream comprising a vapor portion and a liquid portion from the plurality of heat exchange tubes and allow the liquid portion to separate from the vapor portion by gravity, the intermediate zone comprising a first outlet for the vapor portion of the mixed stream and a second outlet for the liquid portion of the mixed stream; a lower zone disposed between the intermediate zone and the upper fractionation zone of the first fractionating column, the lower zone configured to receive the liquid portion from the intermediate zone through the second outlet and comprising a liquid distribution plate configured to distribute the liquid portion to the upper fractionation zone of the first fractionating column; wherein the vapor portion of the mixed stream is the first column overhead stream and the liquid portion of the mixed stream is the reflux stream; and wherein the plurality of heat exchange tubes are oriented substantially vertically, each having an inlet end in fluid communication with the headspace zone to receive the first vapor stream and an outlet end in fluid communication with the intermediate zone.
23. The NRU system of claim 22 wherein the refrigerant inlet is disposed below the refrigerant outlet.
24. The NRU system of claim 21 wherein the refrigerant inlet is disposed below the refrigerant outlet.
25. The NRU system of claim 19 further comprising: a second splitter for splitting the first column overhead stream upstream of the second fractionating column into a first portion of the first column overhead stream and a second portion of the first column overhead stream; a third heat exchanger for cooling the first portion of the first column overhead stream upstream of feeding into the second fractionating column through heat exchange with the second column overhead stream upstream of the first heat exchanger.
26. The NRU system of claim 25 further comprising a fourth heat exchanger wherein the second portion of the first column overhead stream is cooled upstream of feeding into the second fractionating column through heat exchange with a second set of heat exchange streams comprising the second column bottoms stream.
27. The NRU system of claim 26 further comprising a first separator wherein the second column bottoms stream downstream of the fourth heat exchanger is separated into a first separator overhead stream and a first separator bottoms stream; and wherein the first separator overhead stream feeds into a bottom fractionation level of the second fractionating column; wherein the second set of heat exchange streams further comprises the first separator bottoms stream; and wherein the methane product stream further comprises the first separator bottoms stream.
28. The NRU system of claim 27 further comprising: a second separator for separating a system feed stream into a second separator overhead stream and a second separator bottoms stream; a third splitter to split the second separator overhead stream into the first feed stream and a second feed stream; wherein the second feed stream also comprises nitrogen, methane, and heavier hydrocarbons and is also separated into the first vapor stream and the first column bottoms stream in the first fractionating column; and wherein the first set of heat exchange streams further comprises the first separator bottoms stream downstream of the fourth heat exchanger and the second separator bottoms stream.
29. The NRU system of claim 28 wherein the system feed stream is cooled in the first heat exchanger upstream of the second separator; wherein an amount of methane in the first feed stream on a mole fraction basis is substantially higher than an amount of heavier hydrocarbons in the first feed stream; and wherein the reflux stream comprises (1) an amount of nitrogen that is greater on a mole fraction basis than an amount of nitrogen in the first feed stream and (2) an amount methane that is less on a mole fraction bases than the amount of methane in the first feed stream.
30. The NRU system of claim 21 wherein a second feed stream that also comprises nitrogen, methane, and heavier hydrocarbons is also separated into the first column overhead stream and the first column bottoms stream in the first fractionating column; wherein the second feed stream feeds into the first fractionating column as a mixed liquid and vapor stream at a second level lower than a first level where the first feed stream feeds into the first fractionating column as liquid stream.
31. The NRU system of claim 30 further comprising a reboiler for the first fractionating column wherein a liquid stream from a lower fractionation zone of the first fractionating column is warmed and partially vaporized through heat exchange with the second feed stream to produce the first column bottoms stream and a second vapor stream that is returned to the first fractionating column; and wherein the second feed stream is cooled in the reboiler prior to feeding into the first fractionating column.
32. The NRU system of claim 31 wherein the reboiler comprises a second shell and tube heat exchanger comprising a tube side and a shell side, wherein the second feed stream is on the tube side of the reboiler and the liquid stream is on the shell side of the reboiler.
33. The NRU system of claim 32 wherein the refrigerant stream comprises a first vapor mole fraction percentage when it enters the refrigerant inlet and a second vapor mole fraction percentage when it exits the refrigerant outlet; and wherein the first vapor mole fraction percentage is substantially equal to the second vapor mole fraction percentage.
34. The NRU system of claim 19 wherein the second fractionating column is stacked on the first fractionating column.
35. The NRU system of claim 19 wherein the first fractionating column is operated at a pressure between 315 and 415 psia and the second fractionating column is operated at a pressure between 65 and 115 psia.
36. The NRU system of claim 19 wherein the first heat exchanger comprises a single plate-fin heat exchanger.
37. The NRU system of claim 28 wherein the system feed stream comprises 20-50% nitrogen on a mole fraction basis.
38. The NRU system of claim 1 wherein the NRU system is configured to produce the second column overhead stream based on a system feed stream comprising 20 or less nitrogen on a mole fraction basis.
39. The NRU system of claim 1 wherein heat exchange in the first heat exchanger occurs simultaneously between each of the first feed stream and the first set of heat exchange streams; and wherein the first heat exchanger comprises a single plate-fin heat exchanger.
40. The NRU system of claim 1 wherein the methane product stream has a first volumetric flow rate and wherein the first column bottoms stream has a second volumetric flow rate that is more than 50% of the fir volumetric flow rate.
41. The NRU system of claim 1 wherein the methane product stream further comprises, as a minor portion, the second column bottoms stream after the second column bottoms stream is further processed downstream of the second fractionating column.
42. The NRU system of claim 1 wherein a major portion of the methane product stream is the first column bottoms stream.
43. The NRU system of claim 1 wherein the second heat exchanger comprises a vertical tube, falling film condenser.
44. The NRU system of claim 1 further comprising one or more compressors to compress the methane product stream and wherein the NRU system has an energy requirement for the one or more compressors of around 55 to 75 HP per MMSCFD of a system feed stream volume.
45. The NRU system of claim 1 wherein the methane product stream comprises less than 2% total nitrogen.
46. The NRU system of claim 18 wherein the reboiler comprises a shell and tube heat exchanger comprising a tube side and a shell side, wherein the second feed stream is on the tube side of the reboiler and the liquid stream is on the shell side of the reboiler.
47. The NRU system of claim 46 further comprising a mixer for mixing the first separator bottoms stream downstream of the fourth heat exchanger with the third portion of the first column bottoms stream downstream of the second heat exchanger to form a mixed stream; and wherein the first set of heat exchange streams comprises the first portion of the first column bottoms stream, the second portion of the first column bottoms stream, the mixed stream, and the second column overhead stream downstream of the third heat exchanger.
48. The NRU system of claim 47 wherein the methane product stream comprises a high pressure sales gas stream having a pressure between 315 and 465 psia, an intermediate pressure sales gas stream having a pressure between 75 and 215 psia, and a low pressure sales gas stream having a pressure between 45 and 115 psia; wherein high pressure sales gas stream is the first portion of the first column bottoms stream; wherein the intermediate pressure sales gas stream is the second portion of the first column bottoms stream; and wherein the low pressure sales gas stream is the mixed stream.
49. The NRU system of claim 15 wherein the first feed stream and the second feed stream each comprise an amount of methane on a mole fraction basis that is higher than a total amount of heavier hydrocarbons; and wherein the second separator bottoms stream comprises an amount of methane on a mole fraction basis that is less than a total amount of the heavier hydrocarbons.
50. The NRU system of claim 1 further comprising a feed separator wherein a system feed stream comprising nitrogen, methane, and heavier hydrocarbons is separated into a feed separator overhead stream and a feed separator bottoms stream; wherein the feed separator overhead stream comprises the first feed stream; wherein the first feed stream comprises an amount of methane on a mole fraction basis that is higher than a total amount of heavier hydrocarbons; and wherein the feed separator bottoms stream comprises an amount of methane on a mole fraction basis that is less than a total amount of heavier hydrocarbons.
51. The NRU system of claim 14 wherein the methane product stream has a first volumetric flow rate and wherein the first column bottoms stream has a second volumetric flow rate that is more than 50% of the first volumetric flow rate.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The systems and methods of the invention are further described and explained in relation to the following drawings wherein:
(2)
(3)
(4)
DESCRIPTION OF THE PREFERRED EMBODIMENTS
(5) Referring to
(6) In both systems 10 and 210, NRU feed stream 12 preferably comprises around 5-50% nitrogen, more preferably around 5-40% nitrogen and is at a temperature between 50-120 F, more preferably between 80-100 F, and a pressure of 450-1015 psia. Most preferably, system 10 is used when NRU feed stream 12 contains in excess of 25% nitrogen system 210 is used when NRU feed stream 12 contains less than around 20% nitrogen. Although either system 10 or 210 may be used when NRU feed stream 12 contains around 20-25% nitrogen, it is preferred to use system 210 with such feed stream nitrogen content. Feed stream 12 is preferably cooled in a first heat exchanger 14 to a temperature between 0 to 75 F. before feeding into a first separator 18 as stream 16. If stream 12 contains hydrocarbon components such that cooling to a temperature of between 0 and 75 deg F. will cause condensation of the heavier hydrocarbon components then a bottoms liquid stream 158 from first separator 18 is warmed in first heat exchanger 14 and is then sent for further processing as stream 164 to refine contained NGL components. An overhead vapor stream 20 from first separator 18 is split into streams 24 and 34. Stream 24 is recycled back through first heat exchanger 14 where it is cooled and condensed prior to passing through a JT valve 28 and then feeding into an upper level of first fractionating column 32 as liquid stream 30. Stream 34 passes through a tube side of a reboiler 36 for the first column 32 where it is cooled and partially condensed before passing through valve 40 (most preferably a throttle valve) and then feeding into a mid-to-lower level of first fractionating column 32 as mixed liquid-vapor stream 42. First column 32 is preferably operated at pressures ranging from 315-415 psia, more preferably from 325-385 psia with feed stream (streams 30 and 42) temperatures ranging from 210 to 170 F, more preferably 205 to 175 F.
(7) In both systems 10 and 210, a liquid stream 46 from a bottom of first column 32 passes through a shell side of reboiler 36 with a vapor portion 44 returning to the bottom of column 32 and a liquid portion 48 exiting as a first column bottoms stream. Bottoms stream 48 preferably comprises around 1-4% nitrogen, more preferably 2-3% nitrogen. A vapor stream 80 from a top of first column 32 passes through a tube side 82 (tube) of a heat exchanger 82, where it is partially condensed, with a vapor portion exiting as first fractionating column overhead stream 86 and a liquid portion 84 returning to column 32. The refrigerant source for heat exchanger 82 in system 10 differs from that in system 210, as further described below. First fractionating column overhead stream 86 preferably comprises around 15-40% methane and 60-85% nitrogen.
(8) Referring to
(9) In system 10, stream 56 preferably has a pressure of 325-385 psia and a temperature of 145 to 165 F. before being warmed in first heat exchanger 14 to become a high pressure sales gas stream 58. Stream 64 preferably has a pressure of 150-175 psia and a temperature of 175 to 200 F. before being warmed in first heat exchanger 14 to become an intermediate pressure sales gas stream 66. In system 10, stream 72 preferably has a pressure of 45-105 psia and a temperature of 200 to 235 F. before being mixed in mixer 74 with a bottoms stream from second separator 132 to form stream 76. Stream 76 preferably has a pressure of 45-105 psia and a temperature of 200 to 235 F. before being warmed in first heat exchanger 14 to become a low pressure sales gas stream 78.
(10) Most preferably, in system 10, high pressure sales gas stream 58 is at a pressure between 315-415 psia, and is at a pressure higher than intermediate sales gas stream 66 and higher than low pressure sales gas stream 78. Most preferably, intermediate pressure sales gas stream 66 is at a pressure between 145-215 psia, and is at a pressure lower than high sales gas stream 58 and higher than low pressure sales gas stream 78. Most preferably, low pressure sales gas stream 78 is at a pressure between 45-105 psia, and is at a pressure lower than intermediate sales gas stream 66 and lower than high pressure sales gas stream 58. The pressures of high pressure sales gas stream 58 and lower pressure sales gas stream 78 are substantially higher than prior art systems, such as U.S. Pat. No. 9,816,752, where the bottoms stream from the NRU column is separated into multiple streams at different pressures. The pressures of the high pressure sales gas stream 58 and intermediate sales gas stream 66 are also substantially higher than other prior art systems having only a single sales gas stream from the bottoms of the NRU column, such as U.S. Pat. No. 5,141,544. Each sales gas stream preferably comprises at no more than 4% nitrogen.
(11) In system 10, first column overhead stream 86 is cooled and partially condensed in a second heat exchanger 88, before entering a third separator or flash drum 92 as stream 90. Cooled first column overhead stream 90 is separated in third separator 92 into a primarily liquid bottoms portion 98 and a vapor overhead portion 144. The amount of vapor exiting the third separator 92 is controlled by the amount of vapor needed to achieve certain thermal conditions as dictated by the requirements of the heat exchanger 112. Specifically, the amount of vapor entering the third exchanger 112 is determined by the difference in temperature between streams 144 and 114 so that stream 114 preferably exits the third heat exchanger 112 at temperature approximately 2 to 5 F. colder than stream 144. The excess vapor, not required by the heat exchanger 112, exits the third separator 92 from the bottom of the separator with the exiting liquid as stream 98. Vapor stream 144 is then cooled and condensed in the third heat exchanger 112 prior to feeding into a top of the second column 104 as a liquid reflux stream 150. Third separator 92 is designed to allow a measured amount of vapor flow from the cooled first column overhead stream 90, to pass through third heat exchanger 112 to control subcooling stream 144 prior to feeding into the top of the second column 104 as stream 150. The amount of subcooling achieved in the third exchanger 112 is preferably approximately 40 to 80 F. This subcooling is required to cool the overhead of the second tower, stage 1, to an adequately low temperature to create reflux inside of the second column 324. This reflux is required to achieve a high degree of methane/nitrogen separation within the second column 324 and to achieve a preferred purity of nitrogen exiting the second column 324 of approximately 96-99%, most preferably at least approximately 98%. The balance of the vapor present in stream 90 and not utilized by the exchanger 112 exits the third separator along with the liquid present in stream 90 as stream 98. The two phase stream 98 then enters the expansion valve 100 where the pressure and temperature are preferably reduced 55-75 psia, more preferably around 70 psia, and a temperature of 265 to 285 F., more preferably around 275 F. respectively.
(12) In system 10, second column 104 is preferably operated at pressures ranging from 50-115 psia, more preferably from 55-75 psia with feed stream (streams 150, 102, 134). The approximate feed temperature of stream 150 feeding the top of the second tower is approximately 295 F. The temperature feeding the intermediate feed, mid column is approximately 275 F. and the temperature feeding the column bottom is approximately 225 F. The subcooled liquid stream 150 entering the column top into tray 1 provides the required reflux for the column and the vapor entering as stream 134 provides the reflux vapor. An overhead stream 106 from the second column 104 is routed to an expansion valve 108 where the temperature and pressure are further reduced. The approximate temperature at this point is preferably 290 to 310 F., most preferably approximately 300 F. The vapor exiting the expansion valve 108 is then warmed in third heat exchanger 112, then warmed again in second heat exchanger 88, then warmed again in the first heat exchanger 14 before exiting system 10 as nitrogen vent stream 118. Nitrogen vent stream 118 preferably comprises less than 2% methane and more than 98% nitrogen.
(13) In system 10, a liquid bottoms stream 120 from second column 104 is split in splitter 122 into two portions 124 and 180 that are later recombined, along with a fourth portion of the bottoms stream from first column 32, in mixer 128 to form stream 130, which feeds into second separator 132. A first portion of the bottoms stream from column 104, stream 124, is a refrigerant source for heat exchanger 82, being warmed in a shell side of heat exchanger 82 upstream of mixer 128. A second portion of the bottoms stream from column 104, stream 180, enters temperature control valve 182 upstream of mixer 128. The placement of this control valve 182, and the piping configuration involving streams 124, 180, 184, and 126, are important aspects to operation of system 10 in that it provides the pressure drop necessary to offset the pressure loss through the shell side of heat exchanger 82.
(14) Stream 130 in system 10 preferably feeds into second separator 132 at a temperature 220 to 235 F. and a pressure between 50-75 psia. An additional two phase stream 156 (a partially vaporized fourth portion of the first column bottoms stream, preferably at a temperature of 220 to 210 F. and a pressure between 50-115 psia) is added to separator 132 to provide additional refrigeration as required to allow exchanger 88 to function properly. Stream 156 is preferably mixed with two portions of the bottoms stream from second column 104 in mixer 128 to form stream 130 prior to feeding into second separator 132. A vapor stream 134 exits the separator 132 and is then routed to the second column 104. Likewise, a liquid stream 166, preferably comprising less than 4% nitrogen and more preferably less than 2% nitrogen, exits the separator 132. Second column 104 preferably does not comprise a reboiler, but uses heat exchanger 82 (or condenser 482) and second separator 132 to effectively act as a reboiler with stream 134 being returned to a bottom of column 104 as an ascending vapor stream. Bottoms stream 166 from second separator 132 is then routed to level valve 168 as required to hold a desired liquid level in the separator 132. Stream 166 exits the level valve 168 as stream 170 where it then enters heat exchanger 88. Stream 170 is warmed in second heat exchanger 88 before mixing in mixer 74 with a third portion 72 of the bottoms stream from first column 32 to form low pressure sales gas stream 78.
(15) System 10 utilizes efficient heat exchange between various process streams to improve process performance. In first heat exchanger 14, feed stream 12 and a portion 24 of an overhead stream from first separator 18 are cooled through heat exchange with first portion 56 of the first column bottoms stream, second portion 64 of the first column bottoms stream, mixed stream 76, overhead stream 116 from the second column 104 (downstream of heat exchange in second heat exchanger 88 and third heat exchanger 112) and a bottoms stream 162 from the first separator 18. The feed stream 12 is cooled in first heat exchanger 14 upstream of feeding first separator 18. The purpose of separator 18 is to provide separation of heavier hydrocarbon components such as propane, butanes and gasolines from the inlet feed stream 12 before entering the colder part of the system 10. Portion 24 is cooled in first heat exchanger 14 upstream of routing the stream to the first column 32. In second heat exchanger 88, overhead stream 86 from first column 32 is cooled through heat exchange with overhead stream 114 from second column 104 (downstream of heat exchanger in third heat exchanger 112) and bottoms stream 170 from second separator 132. Overhead stream 86 is cooled in second heat exchanger 88 prior to feeding third separator 92. In third heat exchanger 112, stream 144 from third separator 92 is subcooled through heat exchange with overhead stream 110 from second column 104. System 10 also preferably allows for heat exchange between a second portion 34 of the overhead stream from the first separator 18 and a liquid stream 46 from a bottom of column 32 in a reboiler 36. The exchanger 36 (tube) is the tube side of a shell and tube style heat exchanger used to provide the necessary heat source for the bottom of the first column 32. The exchanger depicted as 36 (shell) is the shell side of the exchanger 36.
(16) System 10 preferably also comprises a fourth heat exchanger comprising a tube side 82 (tube) and a shell side 82 (shell), that are independent pieces of equipment configured as a vertical tube, falling film condenser. Heat exchanger 82 (tube) and 82 (shell) provide the similar function as an internal knockback condenser 482 and shown and described in connection with
(17) Referring to
(18) Most preferably, as with system 10, high pressure sales gas stream 58 in system 210 is at a pressure between 315-465 psia (more preferably 365-415 psia), and is at a pressure higher than intermediate sales gas stream 66 and is at a pressure higher than the intermediate sale gas stream 66 and higher than than low pressure sales gas stream 378. Most preferably, intermediate pressure sales gas stream 66 in system 210 is at a pressure between 75-215 psia (more preferably 145-215 psia), and is at a pressure lower than high sales gas stream 58 and higher than low pressure sales gas stream 378. Most preferably, low pressure sales gas stream 378 in system 210 is at a pressure between 45-115 psia (more preferably 50-115 psia), and is at a pressure lower than intermediate sales gas stream 66 and lower than high pressure sales gas stream 58. The pressures of high pressure sales gas stream 58 and lower pressure sales gas stream 378 are substantially higher than prior art systems, such as U.S. Pat. No. 9,816,752, where the bottoms stream from the NRU column is separated into multiple streams at different pressures. Additionally, the pressure of low pressure sales gas stream 378 in system 210 is generally higher than low pressure sales gas stream 78 in system 10. The pressures of the high pressure sales gas stream 58 and intermediate sales gas stream 66 are also substantially higher than other prior art systems having only a single sales gas stream from the bottoms of the NRU column, such as U.S. Pat. No. 5,141,544. Each sales gas stream in system 210 preferably comprises at no more than 4% nitrogen.
(19) In system 210, first fractionating column overhead stream 86 preferably comprises around 15-40% methane and 60-85% nitrogen. First column overhead stream 86 is split into streams 344 and 289 in splitter 287. Stream 289 is cooled and condensed in a second heat exchanger 288, before passing through expansion valve 100, exiting as mixed liquid-vapor stream 302 with a pressure preferably reduced to around 55 to 115 psia and a temperature reduced to around 265 to 300 F. Second heat exchanger 288 in system 210 is different from second heat exchanger 88 in system 10 in the number of streams absorbing heat and rejecting heat. In system 10, two of the three stream passing through second heat exchanger 88 are absorbing heat and only one is rejecting heat. In system 210, two of the three streams passing through heat exchanger 288 are rejecting heat and only one is absorbing heat. Stream 302 then feeds into a mid-level of second fractionating column 104. Stream 344 is cooled and condensed in third heat exchanger 112, exiting as stream 346. Stream 346 which passes through valve 148, reducing the pressure to become mixed liquid-vapor stream 350 prior to feeding into an upper tray level of second fractionating column 104. In the configuration of system 210, a third separator or flash drum 92 used in system 10 is not needed for overhead stream 86, saving on equipment costs. The amount of subcooling of stream 344 to stream 346 achieved in the third exchanger 112 is preferably approximately 40 to 80 F. As in system 10, this subcooling is required in system 210 to cool the overhead of the second tower, stage 1, to an adequately low temperature to create reflux inside of the second column 324. This reflux is required to achieve a high degree of methane/nitrogen separation within the second column 324 and to achieve a preferred purity of nitrogen exiting the second column 324 of approximately 96-99%, most preferably at least approximately 98%. A third stream 334 also feeds into a bottom of second fractionating column 104, as further described below.
(20) In system 210, second column 104 is preferably operated at pressures ranging from 50-115 psia, more preferably from 55-75 psia with feed stream (streams 350, 302, 334). The approximate feed temperature of stream 350 feeding the top of the second tower is approximately 295 F. The temperature of stream 302 feeding the intermediate feed, mid column is approximately 285 F. and the temperature of stream 334 feeding the column bottom is approximately 236 F. The subcooled liquid stream 350 entering the column top into tray 1 provides the required reflux for the column and the vapor entering as stream 334 provides the reboiler vapor. An overhead stream 306 from the second column 104 is routed to an expansion valve 108 where the temperature and pressure are further reduced. The approximate temperature at this point is preferably 290 to 310 F., most preferably approximately 300 F. The vapor exiting the expansion valve 108 is then warmed in third heat exchanger 112 and then warmed again in the first heat exchanger 14 before exiting system 210 as nitrogen vent stream 318. Unlike system 10 (where stream 110 passes through third heat exchanger 112, then second heat exchanger 88, then first heat exchanger 14), stream 310 in system 210 only passes through third heat exchanger 112 and first heat exchanger 14. Nitrogen vent stream 318 preferably comprises less than 2% methane and more than 98% nitrogen.
(21) A liquid bottoms stream 320 from second column 104 is warmed in second heat exchanger 288, exiting as stream 330, which feeds into second separator 132. Stream 330 preferably feeds into second separator 132 at a temperature 250 to 275 F. and a pressure between 50-115 psia. A vapor stream 334 exits the separator 132 and is then routed to the second column 104. Likewise, a liquid stream 366, preferably comprising less than 6% nitrogen and more preferably less than 4% nitrogen, exits the separator 132. The permissible nitrogen specification for the second tower is preferably more lenient than the first tower because of the relative flow rates from the bottom of each tower and in order to allow heat exchanger 288 to operate more efficiently. Second column 104 preferably does not comprise an independent reboiler, but uses a heat exchange pass in the second heat exchanger as a source of heat. The vapor generated in this (reboiler) heat exchange pass is separated in the second separator 132 providing stream 334 that is returned to a bottom of column 104 as an ascending vapor stream. Bottoms stream 366 from second separator 132 is then routed to level valve 168 as required to hold a desired liquid level in the separator 132. Stream 366 exits the level valve 168 as stream 370 where it then enters second heat exchanger 288. Stream 370 is warmed in second heat exchanger 288, exiting as stream 372, which is mixed in mixer 74 with a third portion 271 of the bottoms stream from first column 32 to form low pressure sales gas stream 378.
(22) System 210 utilizes efficient heat exchange between various process streams to improve process performance. In first heat exchanger 14, feed stream 12 and a portion 24 of an overhead stream from first separator 18 are cooled through heat exchange with first portion 56 of the first column bottoms stream, second portion 64 of the first column bottoms stream, mixed stream 276, overhead stream 316 from the second column 104 (downstream of heat exchange in third heat exchanger 112) and a bottoms stream 162 from the first separator 18. The feed stream 12 is cooled in first heat exchanger 14 upstream of feeding first separator 18. The purpose of separator 18 is to provide separation of heavier hydrocarbon components such as propane, butanes and gasolines from the inlet feed stream 12 before entering the colder part of the system 210. Portion 24 is cooled in first heat exchanger 14 upstream of routing the stream to the first column 32. In second heat exchanger 288, a first portion of overhead stream 86 from first column 32 is cooled through heat exchange with bottoms stream 320 from second column 104 and bottoms stream 370 from second separator 132. In third heat exchanger 112, a second portion of overhead stream 86 is subcooled through heat exchange with overhead stream 310 from second column 104. System 210 also preferably allows for heat exchange between a second portion 34 of the overhead stream from the first separator 18 and a liquid stream 46 from a bottom of column 32 in heat exchanger 36. The exchanger 36 (tube) is the tube side of a shell and tube style heat exchanger used to provide the necessary heat source for the bottom of the first column 32. The exchanger depicted as 36 (shell) is the shell side of the exchanger 36.
(23) System 210 preferably also comprises a fourth heat exchanger comprising a tube side 82 (tube) and a shell side 82 (shell), that are independent pieces of equipment configured as a vertical tube, falling film condenser. Heat exchanger 82 (tube) and 82 (shell) provide the similar function as an internal knockback condenser 482 and shown and described in connection with
(24) Acceptable inlet compositions in which systems 10 and 210 may operate satisfactorily are listed in the following Table 1:
(25) TABLE-US-00001 TABLE 1 INLET STREAM COMPOSITIONS Inlet Component Acceptable Inlet Composition Ranges Methane 50-95% Ethane and Heavier 0-20% Components Carbon Dioxide 0-100 ppm Nitrogen 5-50% Preferably 20% or greater for system 10 and less than 20% for system 210
Example 1Computer Simulation for 100 MMSCFD Feed with 20% Nitrogen in System 10
(26) Still referring to
(27) Feed stream 12 passes through first heat exchanger 14, which preferably comprises a plate-fin heat exchanger. The feed stream emerges from the heat exchanger and enters separator 18 having been cooled to 17.4 F. as stream 16. This cooling is the result of heat exchange with other process streams 56, 64, 76, 116, and 162. The cooled stream 16 is then separated into an overhead vapor stream 20 and a bottoms liquid stream 158. Bottoms liquid stream 158 comprises around 1.8% nitrogen, 26% methane, 10% ethane, and 14% propane. The pressure of stream 158 is reduced in valve 160 to around 165 psia in mixed liquid-vapor stream 162. Stream 162 is then warmed in heat exchanger 14, exiting as stream 164 at 101.7 F. and 160 psia. Stream 164 may be sent to an NGL stabilizer column (not shown) for further processing.
(28) Overhead vapor stream 20, comprising around 20% nitrogen and around 73% methane is split in splitter 22 into streams 24 and 34. Stream 24 is then routed for another pass through heat exchanger 14, exiting as a subcooled liquid stream 26 having been cooled to 195 F. Stream 26 passes through a pressure reducing valve 28, exiting as stream 30 with a pressure around 395 psia. Stream 30 feeds into an upper tray level on first fractionating column 32. First fractionating column 32 is preferably a high pressure column upstream of a low pressure second fractionating column 104. Vapor stream 34, the other portion of the first separator overhead stream, passes through the tube side of exchanger 36 in order to provide heat for the reboiler 36 for first fractionating column 32, exiting as mixed liquid-vapor stream 38 having been cooled to around 138 F. Around 8.04 million Btu/Hr of heat energy (Q-4) passes from tube side of reboiler 36 (tube) (from stream 34) to shell side of reboiler 36 (shell) (to stream 46). Stream 38 passes through temperature control valve 40 (preferably a throttling valve), exiting as stream 42 with a reduced pressure of around 391 psia. Mixed liquid-vapor stream 42 feeds into first fractionating column 32 near a mid-level tray location. Stream 80 comprising around 59% nitrogen and 40.5% methane at 189 F. from the top of column 32 feeds into a tube side 82 (tube) of a shell and tube heat exchanger that acts as a condenser for column 32. Alternatively, column 32 may be configured with a knockback condenser 482 as further described with respect to
(29) First column overhead stream 86 passes through second heat exchanger 88, which preferably comprises a plate-fin heat exchanger, exiting as cooled, mixed liquid-vapor stream 90 at 224 F. Stream 90 then enters a third separator or flash drum 92 where it is separated into liquid stream 98 and vapor stream 144. Stream 98 comprises 63% nitrogen and 37% methane at 224 F. and 379 psia. Stream 98 passes through valve 100, existing as stream 102 at 276 F. with a pressure of around 70 psia. Stream 102 feeds into a mid-level of second fractionating column 104. Vapor stream 144 passes through third heat exchanger 112, which preferably comprises a plate-fin heat exchanger, exiting as stream 146 having been subcooled to around 296 F. Stream 146 then passes through valve 148 to reduce the pressure of exiting stream 150 to around 70 psia. Stream 150 comprising around 86% nitrogen and 14% methane at 295 F. and 70 psia then feeds into an upper level of column 104. A third stream, stream 134 comprising around 20% nitrogen and 80% methane at 226 F. and 65 psia, also feeds into a lower level of column 104 as an ascending vapor stream.
(30) Components of feed streams 150, 102, and 134 are separated in second fractionating column 104 into an overhead stream 106 and a bottoms stream 120. Overhead stream 106 comprises around 98% nitrogen and less than 2% methane at 290 F. and 62.5 psia before passing through valve 108, existing at stream 110 at 300 F. and 20 psia. Stream 110 passes through third heat exchanger 112, exiting as stream 114 warmed to 229 F. Stream 114 then passes through second heat exchanger 88, exiting as stream 116 warmed to 204 F. Stream 116 then passes through first heat exchanger 14, exiting as stream 118 warmed to 101.7 F. Stream 118 is the nitrogen vent stream for system 10.
(31) Bottoms stream 120 comprising around 9% nitrogen and 91% methane at 246 F. and 65 psia is split in splitter 122 into streams 124 and 180. Liquid stream 124 passes through the shell side 82 (shell) of a shell and tube heat exchanger that acts as a condenser for column 32, exiting as vapor stream 126 at around 221 F. Stream 180 passes through valve 182, exiting as stream 184. Streams 184 and 126 are mixed in mixer 128 to form stream 130 that feeds into a low pressure second separator 132. Valve 182 is used to control the temperature of mixed stream 130 feeding into separator 132, by controlling a flow rate of stream 180 inversely relative to stream 124. Stream 156 is also preferably mixed in mixer 128 to form stream 130, but may also be separately fed into separator 132. Stream 130 (and 156 if separate from 130) are separated in separator 132 into overhead vapor stream 134 and bottoms liquid stream 166. Stream 134 is returned to second fractionating column 104 as an ascending vapor stream providing heat to the second column as is similar to having a reboiler in second column 104. Bottoms stream 166 comprises less than 2% nitrogen and around 96% methane at 226 F. and 65 psia. Stream 166 passes through level valve 168, exiting as stream 170 with a slight pressure reduction to 60 psia. Stream 170 passes through heat exchanger 88, exiting as stream 172 having been warmed to 204 F. Stream 172 is mixed with a partially vaporized third portion 72 of a bottoms stream from fractionating column 32 in mixer 74 to form mixed stream 76.
(32) Liquid stream 46 from a bottom of column 32 passes through reboiler 36 (shell) where there is heat exchange with stream 34 (which is a portion of first separator overhead stream for system 10). A vapor portion 44 of stream 46 returns to the bottom of column 32 and a liquid portion exits as bottoms stream 48 comprising less than 2% nitrogen and around 89% methane at 145 F. and 388.5 psia. Bottoms stream 48 is then split in splitter 50 into streams 52, 60, 68 and 152. Stream 52 passes through valve 54, exiting as stream 56 at 345 psia. Stream 56 then passes through heat exchanger 14, exiting as stream 58 having been warmed to around 101.5 F. and at a pressure of 340 psia. Stream 58 is one of the three sales gas streams. Stream 60 passes through valve 62, exiting as stream 64 at 183 F. and a pressure of 165 psia. Stream 64 then passes through heat exchanger 14, exiting as stream 66 having been warmed to around 101.7 F. and a pressure of 160 psia. Stream 66 is a second of the sales gas streams. Stream 68 passes through valve 70, exiting as stream 72 having been cooled to 216 F. at a pressure of 65 psia. Stream 72 is mixed with stream 172 in mixer 74 to form stream 76 at 217.8 F. and 57.5 psia, which passes through heat exchanger 14 exiting as stream 78 at 101.7 F. and 55 psia. Stream 78 is a third sales gas stream. Of the sales gas streams, stream 58 is a high pressure stream (higher than streams 66 and 78) and depending on the requirements of the installation, this stream may not need further compression to enter existing facility equipment or the compression requirements would be significantly reduced when compared with existing nitrogen rejection technologies. Stream 66 is an intermediate pressure stream (lower pressure than stream 58 but higher pressure than stream 78), and stream 78 is a low pressure stream (lower pressure than streams 58 and 66). These streams 66 and 78 may be further compressed as needed to meet pipeline requirements.
(33) Stream 152, the fourth portion split from bottoms stream 48, passes through valve 154, exiting as partially vaporized stream 156 having been cooled to 214 F. at a pressure of 70 psia. Stream 156 is the third stream to enter mixer 128. The mixed stream from 128 exits as stream 130 and feeds into second separator 132.
(34) The specific flow rates, temperatures, pressures, and compositions of various flow streams referred to in connection with the above discussion of a computer simulation for a system 10 appear in Table 2 below. These values are based on a feed gas stream 12 comprising 20% nitrogen, around 73% methane, and 50 ppm of carbon dioxide with a flow rate of 100 MMSCFD.
(35) TABLE-US-00002 TABLE 2 FLOW STREAM PROPERTIES FOR EXAMPLE 1 - SYSTEM 10 Mole Fraction/ Property - Stream No. 12 16 20 24 26 30 34 Nitrogen 20.0000* 20.0000 20.1842 20.1842 20.1842 20.1842 20.1842 CO2 0.005* 0.005 0.00499903 0.00499903 0.00499903 0.00499903 0.00499903 Methane 72.7672* 72.7672 73.2420 73.2420 73.2420 73.2420 73.2420 Ethane 4.28875* 4.28875 4.22698 4.22698 4.22698 4.22698 4.22698 Propane 1.64580* 1.64580 1.51655 1.51655 1.51655 1.51655 1.51655 i-Butane 0.313443* 0.313443 0.251551 0.251551 0.251551 0.251551 0.251551 n-Butane 0.616397* 0.616397 0.445057 0.445057 0.445057 0.445057 0.445057 i-Pentane 0.126174* 0.126174 0.0640669 0.0640669 0.0640669 0.0640669 0.0640669 n-Pentane 0.103348* 0.103348 0.0447387 0.0447387 0.0447387 0.0447387 0.0447387 Hexane 0.133944* 0.133944 0.0198272 0.0198272 0.0198272 0.0198272 0.0198272 Temperature 120* 17.4194 17.4875 17.4875 195* 195.030 17.4875 F. Pressure psia 664.5* 659.5 658.5 658.5 653.5 395* 658.5 Mole 100 99* 100 100 0 0 100 Fraction Vapor % Std Vapor 100* 100 98.9982 70.5388 70.5388 70.5388 28.4594 Volumetric Flow MMSCFD Mole Fraction/ Property - Stream No. 38 42 44 46 48 52 56 Nitrogen 20.1842 20.1842 7.76152 3.73593 1.93913 1.93913 1.93913 CO2 0.00499903 0.00499903 0.00166185 0.00531146 0.00694044 0.00694044 0.00694044 Methane 73.2420 73.2420 91.6747 89.7532 88.8955 88.8955 88.8955 Ethane 4.22698 4.22698 0.527887 4.23647 5.89178 5.89178 5.89178 Propane 1.51655 1.51655 0.0315056 1.47234 2.11545 2.11545 2.11545 i-Butane 0.251551 0.251551 0.00111929 0.242955 0.350896 0.350896 0.350896 n-Butane 0.445057 0.445057 0.00154193 0.429712 0.620823 0.620823 0.620823 i-Pentane 0.0640669 0.0640669 2.12102E05 0.0617961 0.0893689 0.0893689 0.0893689 n-Pentane 0.0447387 0.0447387 2.53333E05 0.0431562 0.0624074 0.0624074 0.0624074 Hexane 0.0198272 0.0198272 1 62426E06 0.0191229 0.0276576 0.0276576 0.0276576 Temperature 137.715* 160.830 145.335 151.495 145.335 145.335 151.019 F. Pressure psia 653.5 391.273* 388.5 388.5 388.5 388.5 345* Mole 40.1571 50.8018 100 0 0 0 4.97369 Fraction Vapor % Std Vapor 28.4594 28.4594 31.6770 102.647 70.9699 42.2528 42.2528 Volumetric Flow MMSCFD Mole Fraction/ Property - Stream No. 58 60 64 66 68 72 76 Nitrogen 1.93913 1.93913 1.93913 1.93913 1.93913 1.93913 1.91623 CO2 0.00694044 0.00694044 0.00694044 0.00694044 0.00694044 0.00694044 0.00390743 Methane 88.8955 88.8955 88.8955 88.8955 88.8955 88.8955 93.0578 Ethane 5.89178 5.89178 5.89178 5.89178 5.89178 5.89178 3.23637 Propane 2.11545 2.11545 2.11545 2.11545 2.11545 2.11545 1.15643 i-Butane 0.350896 0.350896 0.350896 0.350896 0.350896 0.350896 0.191808 n-Butane 0.620823 0.620823 0.620823 0.620823 0.620823 0.620823 0.339356 i-Pentane 0.0893689 0.0893689 0.0893689 0.0893689 0.0893689 0.0893689 0.0488510 n-Pentane 0.0624074 0.0624074 0.0624074 0.0624074 0.0624074 0.0624074 0.0341132 Hexane 0.0276576 0.0276576 0.0276576 0.0276576 0.0276576 0.0276576 0.0151182 Temperature 101.540 145.335 183.260 101.727* 145.335 216.425 217.785 F. Pressure psia 340 388.5 165* 160 388.5 65* 57.5 Mole 100 0 23.9490 100 0 36.8655 75.7586 Fraction Vapor % 42.2528 17.5* 17.5 17.5 8* 8 20.5208 Mole Fraction/ Property - Stream No. 78 80 84 86 90 98 Nitrogen 1.91623 59.4154 31.3690 66.3824 66.3824 63.1382 CO2 0.00390743 0.000326395 0.00130540 8.31993E05 8.31993E05 9.63111E05 Methane 93.0578 40.4844 68.1744 33.6059 33.6059 36.8482 Ethane 3.23637 0.0959951 0.435886 0.0115625 0.0115625 0.0134116 Propane 1.15643 0.00367169 0.0182156 5.88178E05 5.88178E05 6.84284E05 i-Butane 0.191808 9.24393E05 0.000463516 2.59683E07 2.59683E07 3.02222E07 n-Butane 0.339356 0.000126703 0.000635588 2.90617E07 2.90617E07 3.38227E07 i-Pentane 0.0488510 8.01838E07 4.02941 E06 7.25370E11 7.25370E11 8.44288E11 n-Pentane 0.0341132 1.29730E06 6.51837E06 3.23020E10 3.23020E10 3.75973E10 Hexane 0.0151182 8.00757E08 4.02408E07 4.85066E12 4.85066E12 5.64582E12 Temperature 101.727* 189.094 199.103 199.103 223.793 223.896 F. Pressure psia 55 385 385 385 380 379 Mole 100 100 0 100 15* 1.22019 Fraction Vapor % Std Vapor 20.5208 34.9908 6.96253 28.0282 28.0282 24.0804 Volumetric Flow MMSCFD Mole Fraction/ Property - Stream No. 102 106 110 114 116 118 120 Nitrogen 63.1382 98.4286 98.4286 98.4286 98.4286 98.4286 8.92683 CO2 9.63111E05 4.30858E10 4.30858E10 4.30858E10 4.30858E10 4.30858E10 0.000178860 Methane 36.8482 1.57143 1.57143 1.57143 1.57143 1.57143 91.0478 Ethane 0.0134116 4.62270E08 4.62270E08 4.62270E08 4.62270E08 4.62270E08 0.0250017 Propane 6.84284E05 5.06148E13 5.06148E13 5.06148E13 5.06148E13 5.06148E13 0.000145857 i-Butane 3.02222E07 0 0 0 0 0 7.50615E07 n-Butane 3.38227E07 0 0 0 0 0 8.64756E07 i-Pentane 8.44288E11 0 0 0 0 0 4.25543E10 n-Pentane 3.75973E10 0 0 0 0 0 1.57601E09 Hexane 5.64582E12 0 0 0 0 0 1.78131E11 Temperature 275.993 290.157 299.700 228.767 204.101* 101.727* 245.576 F. Pressure psia 70* 62.5 20* 19 18 17 65 Std Vapor 41.7445 100 100 100 100 100 0 Volumetric Flow MMSCFD 24.0804 18.7245 18.7245 18.7245 18.7245 18.7245 15.2885 Mole Fraction/ Property - Stream No. 124 126 130 134 144 Nitrogen 8.92683 8.92683 7.71205 19.8681 86.1708 CO2 0.000178860 0.000178860 0.00135433 6.72785E05 3.22226E06 Methane 91.0478 91.0478 90.6737 80.1220 13.8289 Ethane 0.0250017 0.0250017 1.04492 0.00971970 0.000283701 Propane 0.000145857 0.000145857 0.367883 9.71550E05 1.96930E07 i-Butane 7.50615E07 7.50615E07 0.0610024 7.01445E07 2.08579E10 n-Butane 8.64756E07 8.64756E07 0.107928 8.48176E07 2.15697E10 i-Pentane 4.25543E10 4.25543E10 0.0155364 7.47518E10 1.60550E15 n-Pentane 1.57601E09 1.57601E09 0.0108493 2.51369E09 2.50524E14 Hexane 1.78131E11 1.78131E11 0.00480815 2.27921 E11 5.04462E16 Temperature 245.576 221.201 225.657 225.657 223.896 F. Pressure psia 65 65 65 65 379 Std Vapor 0 100* 32.3405 100 100 Volumetric Flow MMSCFD 5.12485 5.12485 18.5056 5.98481 3.94784* Mole Fraction/ Property - Stream No. 146 150 152 156 158 162 164 Nitrogen 86.1708 86.1708 1.93913 1.93913 1.79515 1.79515 1.79515 CO2 3.22226E06 3.22226E06 0.00694044 0.00694044 0.00509588 0.00509588 0.00509588 Methane 13.8289 13.8289 88.8955 88.8955 25.8431 25.8431 25.8431 Ethane 0.000283701 0.000283701 5.89178 5.89178 10.3922 10.3922 10.3922 Propane 1.96930E07 1.96930E07 2.11545 2.11545 14.4181 14.4181 14.4181 i-Butane 2.08579E10 2.08579E10 0.350896 0.350896 6.42948 6.42948 6.42948 n-Butane 2.15697E10 2.15697E10 0.620823 0.620823 17.5478 17.5478 17.5478 i-Pentane 1.60550E15 1.60550E15 0.0893689 0.0893689 6.26342 6.26342 6.26342 n-Pentane 2.50524E14 2.50524E14 0.0624074 0.0624074 5.89497 5.89497 5.89497 Hexane 5.04462E16 5.04462E16 0.0276576 0.0276576 11.4107 11.4107 11.4107 Temperature 295.724* 294.945 145.335 214.065 17.4875 38.8154 101.727* F. Pressure psia 374 70* 388.5 70* 658.5 165* 160 Mole 0 0 0 36.0482 0 23.0297 53.0054 Fraction Vapor % Std Vapor 3.94784 3.94784 3.21712 3.21712 1.00183 1.00183 1.00183 Volumetric Flow MMSCFD Mole Fraction/ Property - Stream No. 166 170 172 180 184 Nitrogen 1.90160 1.90160 1.90160 8.92683 8.92683 CO2 0.00196953 0.00196953 0.00196953 0.000178860 0.000178860 Methane 95.7172 95.7172 95.7172 91.0478 91.0478 Ethane 1.53973 1.53973 1.53973 0.0250017 0.0250017 Propane 0.543680 0.543680 0.543680 0.000145857 0.000145857 i-Butane 0.0901606 0.0901606 0.0901606 7.50615E07 7.50615E07 n-Butane 0.159516 0.159516 0.159516 8.64756E07 8.64756E07 i-Pentane 0.0229626 0.0229626 0.0229626 4.25543E10 4.25543E10 n-Pentane 0.0160351 0.0160351 0.0160351 1.57601E09 1.57601 E09 Hexane 0.00710639 0.00710639 0.00710639 1.78131E11 1.78131 E11 Temperature 225.657 227.698 204.007 245.576 245.576 F. Pressure psia 65 60* 57.5 65 65 Mole 0 0.990159 96.2238 0 0 Fraction Vapor % Std Vapor 12.5208 12.5208 12.5208 10.1636 10.1636 Volumetric Flow MMSCFD
(36) It will be appreciated by those of ordinary skill in the art that these values are based on the particular parameters and composition of the feed stream in the above computer simulation example. The temperature, pressure, and compositional values will differ depending on the parameters and composition of the NRU Feed stream 12 and specific operating parameters for various pieces of equipment in system 10.
Example 2Computer Simulation for 100 MMSCFD Feed with 20% Nitrogen in System 210
(37) Referring to
(38) Overhead vapor stream 20, comprising around 20.9% nitrogen and around 74.6% methane is split in splitter 22 into streams 24 and 34. Stream 24 is then routed for another pass through heat exchanger 14, exiting as a subcooled liquid stream 26 having been cooled to 195 F. Stream 26 passes through a pressure reducing valve 28, exiting as stream 30 with a pressure around 425 psia. Stream 30 feeds into an upper tray level on first fractionating column 32. First fractionating column 32 is preferably a high pressure column upstream of a low pressure second fractionating column 104. Vapor stream 34, the other portion of the first separator overhead stream, passes through the tube side of exchanger 36 in order to provide heat for the reboiler 36 for first fractionating column 32, exiting as mixed liquid-vapor stream 38 having been cooled to around 137.4 F. Around 7.15 million Btu/Hr of heat energy (Q-4) passes from tube side of reboiler 36 (tube) (from stream 34) to shell side of reboiler 36 (shell) (to stream 46). Stream 38 passes through temperature control valve 40 (preferably a throttling valve), exiting as stream 42 with a reduced pressure of around 421.3 psia. Mixed liquid-vapor stream 42 feeds into first fractionating column 32 near a mid-level tray location. Stream 80 comprising around 61.6% nitrogen and 38.3% methane at 190 F. from the top of column 32 feeds into a tube side 82 (tube) of a shell and tube heat exchanger that acts as a condenser for column 32. A liquid portion of stream 80 returns to column 32 as stream 84 and a vapor portion exits tube side 82 (tube) as overhead stream 86 comprising around 77.5% nitrogen and 22.5% methane at 209.85 F. and 415 psia. The amount of nitrogen in overhead stream 86 in system 210 is higher than the similar computer simulation example for system 10 (66% nitrogen) and the amount of methane is lower than the example for system 10 (34% methane), showing greater efficiency in nitrogen removal in system 210. Around 6.07 million Btu/hr of heat energy (Q-1) passes from tube side 82 (tube) to shell side 82 (shell).
(39) First column overhead stream 86 is split in splitter 287 into a first portion stream 289 and a second portion stream 344. Vapor stream 289 passes through second heat exchanger 288, which preferably comprises a plate-fin heat exchanger, exiting as cooled, mixed liquid-vapor stream 298 at 265 F. Stream 298 at 265 F. and 412.5 psia passes through valve 100, existing as stream 302 at 285 F. with a pressure of around 70 psia. Mixed liquid-vapor stream 302 feeds into a mid-level of second fractionating column 104. Vapor stream 344 passes through third heat exchanger 112, which preferably comprises a plate-fin heat exchanger, exiting as stream 346 having been subcooled to around 294 F. Stream 346 then passes through valve 148 to reduce the pressure of exiting stream 350 to around 75 psia. Stream 350 then feeds into an upper level of column 104. A third stream, stream 334 comprising around 42% nitrogen and 58% methane at 236 F. and 64 psia, also feeds into a lower level of column 104 as an ascending vapor stream.
(40) Components of feed streams 350, 302, and 334 are separated in second fractionating column 104 into an overhead stream 306 and a bottoms stream 320. Overhead stream 306 comprises around 97.8% nitrogen and around 2.2% methane at 285 F. and 72.5 psia before passing through valve 108, existing at stream 310 at 297 F. and 20 psia. Stream 310 passes through third heat exchanger 112, exiting as stream 316 warmed to 215 F. Stream 316 then passes through first heat exchanger 14, exiting as stream 318 warmed to around 103 F. Stream 318 is the nitrogen vent stream for system 210.
(41) Bottoms stream 320 comprising around 32% nitrogen and 68% methane at 269 F. and 75 psia is warmed in second heat exchanger 288, exiting as mixed liquid-vapor stream 330 at 236 F. Stream 330 is separated in separator 132 into overhead vapor stream 334 and bottoms liquid stream 366. Stream 334 is returned to second fractionating column 104 as an ascending vapor stream providing heat to the second column as is similar to having a reboiler in second column 104. Bottoms stream 366 comprises around 5% nitrogen and around 95% methane at 236 F. and 64 psia. Stream 366 passes through heat exchanger 288, exiting as mixed liquid-vapor stream 372 having been warmed to 217.5 F. Stream 372 is mixed with a partially vaporized third portion 271 of a bottoms stream from fractionating column 32 (downstream of heat exchange in fourth heat exchanger 82) in mixer 74 to form mixed stream 276.
(42) Liquid stream 46 from a bottom of column 32 passes through reboiler 36 (shell) where there is heat exchange with stream 34 (which is a portion of first separator overhead stream for system 210). A vapor portion 44 of stream 46 returns to the bottom of column 32 and a liquid portion exits as bottoms stream 48 comprising around 2.9% nitrogen and around 91.2% methane at 145 F. and 418.5 psia. Bottoms stream 48 is then split in splitter 50 into streams 52 (first portion), 60 (second portion), and (third portion) Unlike system 10, there is no fourth portion of the first column bottoms stream in system 210. Stream 52 passes through valve 54, exiting as stream 56 at 345 psia. Stream 56 then passes through heat exchanger 14, exiting as stream 58 having been warmed to around 103 F. and at a pressure of 340 psia. Stream 58 is one of the three sales gas streams. Stream 60 passes through valve 62, exiting as stream 64 at 185 F. and a pressure of 165 psia. Stream 64 then passes through heat exchanger 14, exiting as stream 66 having been warmed to around 103 F. and a pressure of 160 psia. Stream 66 is a second of the sales gas streams. Stream 68 passes through valve 70, exiting as stream 269 having been cooled to 214 F. at a pressure of 75 psia. Stream 269 is a refrigerant for heat exchanger 82, exiting as stream 271 warmed to 194.7 F. Stream 271 is mixed with stream 372 in mixer 74 to form stream 276 at 206 F. and 72.5 psia, which passes through heat exchanger 14 exiting as stream 378 at 102.7 F. and 70 psia. Stream 378 is a third sales gas stream. Of the sales gas streams, stream 58 is a high pressure stream (higher than streams 66 and 378) and depending on the requirements of the installation, this stream may not need further compression to enter existing facility equipment or the compression requirements would be significantly reduced when compared with existing nitrogen rejection technologies. Stream 66 is an intermediate pressure stream (lower pressure than stream 58 but higher pressure than stream 378), and stream 378 is a low pressure stream (lower pressure than streams 58 and 66). These streams 66 and 378 may be further compressed as needed to meet pipeline requirements.
(43) The specific flow rates, temperatures, pressures, and compositions of various flow streams referred to in connection with the above discussion of a computer simulation for a system 210 appear in Table 3 below. These values are based on a feed gas stream 12 comprising 20% nitrogen, around 73% methane, and 50 ppm of carbon dioxide with a flow rate of 100 MMSCFD.
(44) TABLE-US-00003 TABLE 3 FLOW STREAM PROPERTIES FOR EXAMPLE 2 - SYSTEM 210 Mole Fraction/ Property - Stream No. 12 16 20 24 26 30 34 Nitrogen 20.0000* 20.0000 20.9263 20.9263 20.9263 20.9263 20.9263 CO2 0.005* 0.005 0.00479276 0.00479276 0.00479276 0.00479276 0.00479276 Methane 72.7672* 72.7672 74.5651 74.5651 74.5651 74.5651 74.5651 Ethane 4.28875* 4.28875 3.58786 3.58786 3.58786 3.58786 3.58786 Propane 1.64580* 1.64580 0.756602 0.756602 0.756602 0.756602 0.756602 i-Butane 0.313443* 0.313443 0.0621838 0.0621838 0.0621838 0.0621838 0.0621838 n-Butane 0.616397* 0.616397 0.0867579 0.0867579 0.0867579 0.0867579 0.0867579 i-Pentane 0.126174* 0.126174 0.00579575 0.00579575 0.00579575 0.00579575 0.00579575 n-Pentane 0.103348* 0.103348 0.00376879 0.00376879 0.00376879 0.00376879 0.00376879 Hexane 0.133944* 0.133944 0.000813590 0.000813590 0.000813590 0.000813590 0.000813590 Temperature 120* 74.6841 74.7642 74.7642 195* 195.215 74.7642 F. Pressure psia 614.5* 609.5 608.5 608.5 603.5 425* 608.5 Mole 100 95* 100 100 0 0 100 Fraction Vapor % Std Vapor 100* 100 94.9975 52.1944 52.1944 52.1944 42.8031 Volumetric Flow MMSCFD Mole Fraction/ Property - Stream No. 38 42 44 46 48 52 56 Nitrogen 20.9263 20.9263 9.59387 4.84624 2.87481 2.87481 2.87481 CO2 0.00479276 0.00479276 0.00165300 0.00494659 0.00631423 0.00631423 0.00631423 Methane 74.5651 74.5651 89.8808 90.7982 91.1792 91.1792 91.1792 Ethane 3.58786 3.58786 0.502344 3.49065 4.73153 4.73153 4.73153 Propane 0.756602 0.756602 0.0205138 0.711218 0.998029 0.998029 0.998029 i-Butane 0.0621838 0.0621838 0.000405626 0.0580783 0.0820266 0.0820266 0.0820266 n-Butane 0.0867579 0.0867579 0.000455393 0.0809976 0.114442 0.114442 0.114442 i-Pentane 0.00579575 0.00579575 3.26962E06 0.00540297 0.00764517 0.00764517 0.00764517 n-Pentane 0.00376879 0.00376879 3.70709E06 0.00351384 0.00497141 0.00497141 0.00497141 Hexane 0.000813590 0.000813590 1.39212E07 0.000758359 0.00107321 0.00107321 0.00107321 Temperature 137.351* 154.446 144.791 150.370 144.791 144.791 154.003 F. Pressure psia 603.5 421.273* 418.5 418.5 418.5 418.5 345* Mole 61.4339 64.9859 100 0 0 0 8.75183 Fraction Vapor % Std Vapor 42.8031 42.8031 29.9047 101.922 72.0169 32.0169 32.0169 Volumetric Flow MMSCFD Mole Fraction/ Property - Stream No. 58 60 64 66 68 269 271 Nitrogen 2.87481 2.87481 2.87481 2.87481 2.87481 2.87481 2.87481 CO2 0.00631423 0.00631423 0.00631423 0.00631423 0.00631423 0.00631423 0.00631423 Methane 91.1792 91.1792 91.1792 91.1792 91.1792 91.1792 91.1792 Ethane 4.73153 4.73153 4.73153 4.73153 4.73153 4.73153 4.73153 Propane 0.998029 0.998029 0.998029 0.998029 0.998029 0.998029 0.998029 i-Butane 0.0820266 0.0820266 0.0820266 0.0820266 0.0820266 0.0820266 0.0820266 n-Butane 0.114442 0.114442 0.114442 0.114442 0.114442 0.114442 0.114442 i-Pentane 0.00764517 0.00764517 0.00764517 0.00764517 0.00764517 0.00764517 0.00764517 n-Pentane 0.00497141 0.00497141 0.00497141 0.00497141 0.00497141 0.00497141 0.00497141 Hexane 0.00107321 0.00107321 0.00107321 0.00107321 0.00107321 0.00107321 0.00107321 Temperature 102.756 144.791 185.758 102.757* 144.791 213.887 194.720 F. Pressure psia 340 418.5 165* 160 418.5 75* 72.5 Mole 100 0 27.2528 100 0 38.0720 89.8426 Fraction Vapor % Std Vapor 32.0169 10* 10 10 30* 30 30 Volumetric Flow MMSCFD Mole Fraction/ Property - Stream No. 80 84 86 289 298 302 Nitrogen 61.6377 47.9156 77.4962 77.4962 77.4962 77.4962 CO2 0.000263415 0.000469946 2.47286E05 2.47286E05 2.47286E05 2.47286E05 Methane 38.2840 51.9416 22.5000 22.5000 22.5000 22.5000 Ethane 0.0759625 0.138410 0.00379258 0.00379258 0.00379258 0.00379258 Propane 0.00202842 0.00377091 1.46279E05 1.46279E05 1.46279E05 1.46279E05 i-Butane 2.96717E05 5.53060E05 4.62839E08 4.62839E08 4.62839E08 4.62839E08 n-Butane 3.33338E05 6.21379E05 4.50275E08 4.50275E08 4.50275E08 4.50275E08 i-Pentane 1.10636E07 2.06361E07 6.17194E12 6.17194E12 6.17194E12 6.17194E12 n-Pentane 1.71614E07 3.20085E07 2.74717E11 2.74717E11 2.74717E11 2.74717E11 Hexane 7.36483E09 1.37369E08 6.35870E13 6.35870E13 6.35870E13 6.35870E13 Temperature 190.214 209.857 209.857 209.857 265* 285.411 F. Pressure psia 415 415 415 415 412.5 70* Mole 100 0 100 100 0 14.7122 Fraction Vapor % Std Vapor 49.5392 26.5586 22.9806 18.9976 18.9976 18.9976 Volumetric Flow MMSCFD Mole Fraction/ Property - Stream No. 344 346 350 306 310 316 318 Nitrogen 77.4962 77.4962 77.4962 97.7679 97.7679 97.7679 97.7679 CO2 2.47286E05 2.47286E05 2.47286E05 5.10442E09 5.10442E09 5.10442E09 5.10442E09 Methane 22.5000 22.5000 22.5000 2.23207 2.23207 2.23207 2.23207 Ethane 0.00379258 0.00379258 0.00379258 7.74273E07 7.74273E07 7.74273E07 7.74273E07 Propane 1 46279E05 1 46279E05 1.46279E05 5.11716E11 5.11716E11 5.11716E11 5.11716E11 i-Butane 4.62839E08 4.62839E08 4.62839E08 0 0 0 0 n-Butane 4.50275E08 4.50275E08 4.50275E08 2.72021E14 2.72021 E14 2.72021 E14 2.72021 E14 i-Pentane 6.17194E12 6.17194E12 6.17194E12 0 0 0 0 n-Pentane 2.74717E11 2.74717E11 2.74717E11 0 0 0 0 Hexane 6.35870E13 6.35870E13 6.35870E13 0 0 0 0 Temperature 209.857 293.599* 292.620 285.458 296.961 214.763 102.757* F. Pressure psia 415 410 75* 72.5 20* 19 18 Mole 100 0 0 100 100 100 100 Fraction Vapor % Std Vapor 3.98301* 3.98301 3.98301 17.4079 17.4079 17.4079 17.4079 Volumetric Flow MMSCFD Mole Fraction/ Property - Stream No. 320 330 334 366 370 372 Nitrogen 32.4611 30.0413 42.3124 5.01559 5.01559 5.01559 CO2 3.73729E05 4.67684E05 2.58363E06 0.000136879 0.000136879 0.000136879 Methane 67.5333 69.9510 57.6875 94.9610 94.9610 94.9610 Ethane 0.00552599 0.00765791 7.95320E05 0.0231132 0.0231132 0.0231132 Propane 2.11247E05 4.56127E05 1.11114E08 0.000138612 0.000138612 0.000138612 i-Butane 6.68191E08 2.67431E07 2.41581E12 8.12824E07 8.12824E07 8.12824E07 n-Butane 6.50051E08 3.21385E07 2.00276E12 9.76814E07 9.76814E07 9.76814E07 i-Pentane 8.91010E12 8.63913E11 2.07022E18 2.62578E10 2.62578E10 2.62578E10 n-Pentane 3.96594E11 3.99677E10 6.00004E17 1.21478E09 1.21478E09 1.21478E09 Hexane 9.17972E13 1.57875E11 4.74668E20 4.79843E11 4.79843E11 4.79843E11 Temperature 269.184 236.193 236.193 236.193 236.241 217.466 F. Pressure psia 75 64 64 64 80* 79 Mole 0 67.0987 100 0 0 35.1102 Fraction Vapor % Std Vapor 15.9185 15.4186 10.3457 5.07292 5.07292 5.07292 Volumetric Flow MMSCFD Mole Fraction/ Property - Stream No. 276 378 158 162 164 Nitrogen 3.18445 3.18445 2.40974 2.40974 2.40974 CO2 0.00542075 0.00542075 0.00893552 0.00893552 0.00893552 Methane 91.7262 91.7262 38.6237 38.6237 38.6237 Ethane 4.05051 4.05051 17.5985 17.5985 17.5985 Propane 0.853695 0.853695 18.5315 18.5315 18.5315 i-Butane 0.0701625 0.0701625 5.08483 5.08483 5.08483 n-Butane 0.0978896 0.0978896 10.6742 10.6742 10.6742 i-Pentane 0.00653938 0.00653938 2.41214 2.41214 2.41214 n-Pentane 0.00425235 0.00425235 1.99434 1.99434 1.99434 Hexane 0.000917979 0.000917979 2.66208 2.66208 2.66208 Temperature 205.936 102.757* 74.7642 109.565 102.757* F. Pressure psia 72.5 70 608.5 165* 160 Mole 84.6009 100 0 27.8845 93.1194 Fraction Vapor % Std Vapor 35.0729 35.0729 5.00253 5.00253 5.00253 Volumetric Flow MMSCFD
(45) It will be appreciated by those of ordinary skill in the art that these values in Example 2 are based on the particular parameters and composition of the feed stream in the above computer simulation example. The temperature, pressure, and compositional values will differ depending on the parameters and composition of the NRU Feed stream 12 and specific operating parameters for various pieces of equipment in system 210.
(46) For inlet feed conditions in Example 1 or in Example 2, a prior art single column design would require around 11,000 hp (or around 110 hp per inlet feed MMSCF of gas); however, a preferred embodiment of the invention according to
(47) When nitrogen levels are around 20% (as in Examples 1 and 2), it is preferred to use system 210 and the corresponding method described herein, which has less complex process flows, requires fewer pieces of equipment, and generally results in a low pressure sales gas stream with a higher pressure than in system 10. However, system 10 is preferred when nitrogen content of feed stream 12 is substantially above 20%, most preferably around 40 to 75%.
(48) According to another preferred embodiment, a natural gas expander may be used in place of valve 108 in either system 10 or system 210, which would provide a higher degree of cooling of the second column overhead stream than with the valve alone. For example, where the differential across the valve (stream 106 to stream 110 or stream 306 to 310) is calculated to be approximately 10 F., the differential across an expander is approximately 37 F. This higher degree of cooling results in a slightly higher purity of nitrogen to be vented in stream 118 or stream 318 of approximately 0.5 to 1 percent higher nitrogen quality than when a valve 108 alone is used, but also significantly reduces the residue compression required. With a standard control valve in the position of valve 108 the amount of compression is calculated to be approximately 66.5 BHP/MMSCF of inlet gas. The calculated residue HP required with the expander in place instead of the valve 108 is approximately 56.4 BHP/MMSCF. This represents a near 18% reduction in compression HP along with the associated reduction in fuel or power and the associated reduction in environmental impact.
(49) A downflow, knockback condenser 482 may also be used to provide heat exchange in the fourth heat exchanger in systems 10 and 210. A downflow, knockback condenser and method of use as disclosed herein that are particularly useful for partially condensing a vapor stream so that a lighter gas fraction can be efficiently removed and separated from the liquid that is condensed from the vapor stream. The term lighter refers to the actual density of the vapor constituent as compared to the liquid constituent density that may be present at any point in the knockback condenser. The knockback condenser and method are particularly useful for separating gaseous nitrogen from condensed natural gas liquid.
(50) A principal distinction between the knockback condenser described herein and condensers disclosed in the prior art is the provision and use of a vapor riser to introduce vapor captured from the fractionation section of a tower into a headspace above a tubular heat exchanger section to thereby establish downflow or countercurrent cooling of the vapor within the tubes of the condenser to partially condense it into a condensed liquid fraction from which a remaining uncondensed gaseous fraction is then separated and removed.
(51) According to one preferred embodiment, a knockback condenser is useful for partially condensing vapor in the upper section of the first fractionation column to separate vapor and a lighter gaseous fraction (as an overhead stream from the first fractionation column) from a condensed liquid component (as a reflux stream for the first fractionation column). The knockback condenser preferably comprises a substantially cylindrical shell and a condenser section having upper and lower tube sheets attached transversely to the inside of the shell. The tube sheets support a plurality of spaced-apart, vertically oriented, heat exchange tubes extending between the upper and lower tube sheets to provide fluid communication through the tubes. Refrigerant inlet and outlet ports are preferably and desirably disposed so as to establish a generally upward flow of refrigerant around the heat exchange tubes between the lower and upper tube sheets. A vapor riser provides fluid communication between a space in the fractionation tower disposed below the liquid trap plate and a headspace disposed above the upper tube sheet, thereby establishing an upward flow of vapor through the riser and a downward flow of vapor, condensed liquid and an uncondensed, lighter gaseous fraction through the heat exchange tubes. As a refrigerant stream (such as stream 124 or 269) flows through the shell around the tubes, it sufficiently cools the tubes to condense natural gas passing downwardly through the tubes, thereby liquefying the natural gas and separating it from the gaseous nitrogen.
(52) A vapor outlet port is preferably disposed below the lower tube sheet to receive the lighter gaseous fraction and any remaining vapor exiting the lower tube sheet. Liquid collection and recovery apparatus disposed below the lower tube sheet and below the vapor outlet port receive liquid condensed from the vapor.
(53) According to another preferred embodiment, a method for partially condensing a vapor stream from an upper level or zone of the first fractionating column to separate a lighter gaseous fraction from a condensed liquid fraction, comprises the steps of providing a condenser having a substantially cylindrical, vertically oriented shell; upper and lower tube sheets attached transversely to the inside of the shell, the tube sheets supporting a plurality of spaced-apart, vertically oriented, heat exchange tubes extending between the upper and lower tube sheets, and providing fluid communication through the tubes; providing refrigerant inlet and outlet ports disposed in the shell so as to establish a generally upward flow of refrigerant around the heat exchange tubes between the lower and upper tube sheets; providing a vapor riser providing fluid communication between a space in the shell disposed below the lower tube sheet and a headspace disposed above the upper tube sheet; establishing an upward flow of vapor through the riser and a downward flow comprising vapor, condensed liquid fraction and lighter gaseous fraction through the heat exchange tubes, the refrigerant having sufficient cooling capacity to condense a desired liquid fraction from the vapor while passing through the heat exchange tubes; and separately recovering the lighter gaseous fraction from the condensed liquid fraction collected below the heat exchange tubes.
(54) Through use of a knockback condenser and method disclosed herein, one is able to achieve more predictable condenser performance, improved plant flexibility; higher sales gas recoveries, and lower capital costs. Greater predictability in condenser performance is particularly significant for meeting performance guarantees required by gas plant owners, especially for larger plants, where specific component performance plays a significant role in overall plant design.
(55) In the previous condenser designs, such as in Applicant's prior U.S. Pat. Nos. 5,275,505 and 5,375,422 that utilize an internal condenser in a single column nitrogen rejection system, the gas enters at the bottom of the tubes and exits at the top, whereas with the knockback condenser herein, the gas enters at the top of the tubes and exits at the bottom. The performance improvement arises from the fact that some of the gas entering the tubes is condensed, regardless of gas flow direction. In the vapor up-flow models, the liquid must exit by flowing downward or counter-current to the gas flow. While this was anticipated in the design of the prior art condensers, Applicant learned from their use that the falling liquid creates a film that negatively affects the heat transfer coefficient, requiring more condenser surface area to be installed with each condenser application and adding complexity to the estimation of condenser performance.
(56) In contrast, a downflow, knockback condenser utilizes a vapor riser to introduce a flow of vapor into a headspace above a vertical tubular heat exchanger, thereby establishing a downflow of condensed liquid and a lighter gaseous fraction through the heat exchange tubes. Referring to
(57) As used herein, the term condenser section collectively refers to Zones A, B and C and shown in
(58) As condensed liquid and an uncondensed gaseous fraction exit downwardly from tubes 420 through lower tube sheet 418 into Zone C, the gaseous fraction exits shell 212 through outlet 444 as indicated by arrow 446, and the condensed liquid is collected on liquid trap plate 440. From liquid trap plate 440, the condensed liquid received into Zone C from condenser 482 flows downwardly through opening 450, through reflux liquid return seal leg 448, as shown by arrow 464, where it is discharged from end 453 into reflux seal pan 452 in Zone A. From reflux seal pan 452, the condensed reflux liquid spills over, as shown by arrow 466, onto liquid distribution plate 454, from which it is returned to the fractionation section as indicated by arrow 458.
(59) The design, structure and general operation of a preferred embodiment of downflow, knockback condenser 482 is further described and explained below in relation to a computer simulation wherein rich vapor containing natural gas (methane) and nitrogen is partially condensed to separate and remove the gaseous nitrogen from the condensed natural gas liquid. The reference numerals used below generally relate to the structures and flows as described above in relation to
(60) Zone A contains both vapor and liquid. The vapor enters Zone A from section 460 of the fractionation tower via liquid distribution tray 454 disposed below liquid trap plate 440. The liquid enters Zone A from condenser 482 above via the reflux liquid return seal leg 448. The Zone A vapor component is expected to exist at the temperature, pressure and composition given below, and is at the dew point of the rich vapor, meaning that any reduction in temperature at the same pressure will create liquid condensate. In a computer simulation of fractionation column 32 (operated generally, not specifically with respect to systems 10 or 210) as operated with the downflow knockback condenser 482 of a preferred embodiment, the Zone A vapor and liquid conditions are as follows:
(61) TABLE-US-00004 Zone A Vapor (Entering) Temperature (deg. F.) 245.46 Pressure (psia) 315.00 Component (mole %) Nitrogen 97.54 Methane 2.46 Zone A Liquid (Entering) Temperature (deg. F.) 247.52 Pressure (psia) 315.00 Component (mole %) Nitrogen 98.4570 Methane 1.5430
(62) The liquid in Zone A provides the reflux for fractionation column 32 to minimize the amount of methane that is vented with the nitrogen waste gas through outlet 444. The vapor from Zone A proceeds upward through the vapor riser 432 into Zone B. Entrance 434 to vapor riser 432 is preferably cut obliquely on a 60 degree bias to provide greater entrance area to riser 432 and thereby reduce the entrance velocity and associated pressure losses of the rich vapor. Reducing the velocity at entrance 434 allows less liquid, in the form of droplets, to enter riser 432. Some liquid droplets entering riser 432 will not significantly impair the performance of fractionation column 32 or condenser 482, but neither does it help. The entrance of riser 432 is desirably spaced approximately one foot from the underside of liquid trap plate 440 to reduce the vapor velocity at the lower or bottom face of liquid trap plate 440. Lowering this velocity will help minimize the heat transfer across the plate. Heat transfer across liquid trap plate 440 is not desirable because it will reduce the overall effectiveness of condenser 482, and should be minimized. Upper end 436 of vapor riser 432 is desirably extended about six inches above upper tube sheet 416. This extension will help in more evenly distributing the vapor flow across upper tube sheet 416.
(63) The section between upper tube sheet 416 and lower tube sheet 418 is the principal heat exchanger section of condenser 482. A primary point of distinction between this invention and some prior art systems and methods is that, in this disclosure, a flow direction of the vapor to be cooled through the heat exchange section is reversed. In some prior art systems, the gas enters at the bottom of the heat exchange tubes and exits at the top, whereas with the present design, the gas enters at the top of heat exchange tubes 420 and exits at the bottom.
(64) The Zone B vapor conditions are substantially the same as in Zone A but there is no liquid present. In reality, the temperature in Zone B is slightly lower than in Zone A and the computer predicts a slight temperature decrease and a lower pressure due to the vertical elevation difference between Zone A and Zone B. The temperature differences here are insignificant in the overall operation of the unit, but the pressure drop is significant, as is further explained below. Any temperature reduction in riser 432 is beneficial, but a conservative approach plans for minimal temperature decrease and only as predicted by the computer simulations. The Zone B vapor conditions are as follows:
(65) TABLE-US-00005 Zone B Vapor Temperature (deg. F.) 245.56 Pressure (psia) 314.09 Component (mole %) Nitrogen 97.54 Methane 2.46
(66) Condenser 482 is desirably mounted on the top of fractionation column 32 approximately 70 feet from grade. Condenser 482 is preferably a shell and tube heat exchanger configured with substantially vertical tubes 420 supported at the ends by the upper and lower tube sheets 416, 418, respectively. Heat exchange tubes 420 provide the heat transfer surface between the refrigerant, on the shell side, and the process vapor on the tube side. The shell side of the exchanger is isolated from the tube side as a different process fluid is present on that side. The refrigerant used on the shell side of the condenser is preferably LNG created from a tower bottom source. In one preferred embodiment, the refrigerant stream comprises stream 124 (a portion of the second column bottoms stream). In another preferred embodiment, the refrigerant stream comprises stream 269 (a portion of the first column bottoms stream). The refrigerant stream desirably enters condenser 482 through a nozzle at inlet 424 in shell 412 and exits shell 412 through a nozzle at outlet 428.
(67) The approximate conditions of the refrigerant entering inlet 424 of condenser 482 in one example are as follows:
(68) TABLE-US-00006 Inlet Refrigerant Temperature (deg. F.) 254.75 Pressure (psia) 21.88 Vapor mole fraction 0.095 Component (mole %) Nitrogen 4.00 Methane 84.81 Ethane 8.62 Propane 2.17 I-Butane 0.09 N-Butane 0.24 I-Pentane 0.02 N-Pentane 0.04 N-Hexane 0.00724 N-Heptane 0.0019
(69) The approximate conditions of the refrigerant exiting condenser 482 at outlet 428 based on the above example are as follows:
(70) TABLE-US-00007 Exit Refrigerant Temperature (deg. F.) 247.47 Pressure (psia) 18.57 Vapor mole fraction 0.641 Component (mole %) Nitrogen 4.00 Methane 84.81 Ethane 8.62 Propane 2.17 I-Butane 0.09 N-Butane 0.24 I-Pentane 0.02 N-Pentane 0.04 N-Hexane 0.0072 N-Heptane 0.0019
(71) It should be noted that the temperature is slightly higher on the exiting stream, but, and this is of greater significance, that the vapor fraction is much greater on the exiting stream. Because the temperatures of the refrigerant streams entering and exiting the heat exchanger are lower than the vapor inside the vertical tubes 420, heat will be transferred from the process vapor from Zone B into the refrigerant.
(72) The fluid next passes from Zone B into Zone C through condenser 482, where the temperature is reduced. As stated before, the condition of the vapor in Zone B is at the dew point, which means that any reduction in temperature will produce condensate from the entering vapor.
(73) The conditions of the fluid stream entering Zone C from condenser 482 in this example are as follows:
(74) TABLE-US-00008 Zone C Entering Vapor and Liquid Mixture Temperature (deg. F.) 247.55 Pressure (psia) 314.30 Vapor mole fraction 0.25 Component (mole %) Nitrogen 97.54 Methane 2.46
(75) Completing the circuit, the vapor part of the fluid stream exiting from heat exchange tubes 420 at the lower tube sheet exits the unit at vapor fraction outlet 444, from which liquid is preferably shielded by liquid barrier 442, and the condensed liquid component falls to liquid trap plate 440 where it flows by gravity through inlet 450 into reflux liquid return seal leg 448, and from there into reflux seal pan 452. The purpose of the seal leg 448 is to provide a liquid head created by standing liquid in the seal leg to offset the pressure loss in moving the vapor from Zone A into Zone B and eventually into Zone C. The pressure drop through the total circuit is critical and is held to approximately 0.70 psi. The standing liquid in seal leg 448 creates this differential by using gravity and the higher density of the liquid component as compared to the same compounds as vapor. Reflux seal pan 452 provides a liquid trapping mechanism to prevent flow of the vapor in Zone A from flowing directly up seal leg 448 and bypassing condenser 482. Under normal operating conditions, the liquid level is anticipated to be approximately 1 foot deep on top of liquid trap plate 440.
(76) It will also be appreciated by those of ordinary skill in the art upon reading this disclosure that references to separation of nitrogen and methane used herein refer to processing an NRU feed gas to produce various multi-component product streams containing large amounts of the particular desired component, but not pure streams of any particular component. One of those product streams is a nitrogen vent stream, which is primarily comprised of nitrogen but may have small amounts of other components, such as methane and ethane. Other product streams are processed gas streams, or sales gas streams, which are primarily comprised of methane but may have small amounts of other components, such as nitrogen, ethane, and propane. Amounts of components in the various streams described herein as a percentage are mole fraction percentage. All numeric range values indicated herein include each individual numeric value within those ranges and any and all subset combinations within ranges, including subsets that overlap from one preferred range to a more preferred range.
(77) It will also be appreciated by those of ordinary skill in the art upon reading this disclosure that additional processing sections for removing carbon dioxide, water vapor, and possibly other components or contaminants that are present in the NRU feed stream, can also be included in the system and method of the invention, depending upon factors such as, for example, the origin and intended disposition of the product streams and the amounts of such other gases, impurities or contaminants as are present in the NRU feed stream. Other alterations and modifications of the invention will likewise become apparent to those of ordinary skill in the art upon reading this specification in view of the accompanying drawings, and it is intended that the scope of the invention disclosed herein be limited only by the broadest interpretation of the appended claims to which the inventor is legally entitled.