METHOD FOR TREATING THE SURFACE OF METAL FOILS WITH UV-CURED PROTECTIVE VARNISH

Abstract

The method includes the steps of: applying atmospheric plasma on each area portion of the surface of a metal foil to be treated; increasing the surface free energy of the metal foil, making said surface free energy compatible with the surface tension of the varnish to be applied to the metal foil; applying a UV-cured varnish layer, which may be a oligomer, a monomer or a photo-initiator, having a solids content of 99% to 100% to the surface of the metal foil subjected to the atmospheric plasma; and curing the varnish layer using UV radiation to form a varnish coating adhered to the surface of the metal foil.

Claims

1. A method for treating the surface of metal foils with UV-cured protective varnish, the method comprising the steps of: applying atmospheric plasma on each area portion, of a surface to be treated, of a metal foil, increasing a surface free energy of the metal foil, making the surface free energy compatible with a surface tension of the varnish to be applied to the metal foil; applying, on the surface of the metal foil, submitted to the atmospheric plasma, a UV-cured varnish layer, selected from compounds of oligomers, monomers and photo-initiators, with a viscosity from 40 to 60 Sec CF4/25° C., specific weight from 1.01 to 1.05/25° C. and with a solids content from 99% to 100%; and curing the varnish layer, applied on the surface of the metal foil, by polarization of the varnish compounds, by interaction of the photo-initiator with UV radiation in a curing unit, forming a varnish coating adhered to the surface of the metal foil.

2. The method, according to claim 1, wherein the varnish coating has a thickness from 4.65 to 7.75 g/m.sup.2.

3. The method, according to claim 1, wherein the atmospheric plasma is released, on the surface to be treated of the metal foil, from at least one plasma nozzle, the atmospheric plasma being produced by a controlled discharge of electrical energy made by a plasma generator, of high frequency and high voltage, inside the plasma nozzle, the atmospheric plasma being fed by compressed air from a compressed air generator.

4. The method, according to claim 3, wherein the plasma generator generates 300 to 400 Volts, with a pulse frequency from 20 to 30 kHz and a power from 900 to 1000 W, with the gas to be compressed being selected from oxygen or nitrogen and in an amount from 50 to 60 liters per minute, with a pressure from 240 to 250 mbar.

5. The method, according to claim 4, wherein the metal foil is maintained at a distance from 1 to 3 mm of the plasma nozzle, moving at 50 m/min, submitted to the atmospheric plasma at a flow of 56 liters of nitrogen per minute and at a pressure of 245 mbar, to present a surface free energy of 56 mN/m.

6. The method, according to claim 1, wherein the curing unit applies, to the varnish layer, an ultraviolet radiation above 100 mJ/cm2, emitted by mercury vapor or LED lamps.

7. The method, according to claim 2, wherein the atmospheric plasma is released, on the surface to be treated of the metal foil, from at least one plasma nozzle, the atmospheric plasma being produced by a controlled discharge of electrical energy made by a plasma generator, of high frequency and high voltage, inside the plasma nozzle, the atmospheric plasma being fed by compressed air from a compressed air generator.

8. The method, according to claim 7, wherein the plasma generator generates 300 to 400 Volts, with a pulse frequency from 20 to 30 kHz and a power from 900 to 1000 W, with the gas to be compressed being selected from oxygen or nitrogen and in an amount from 50 to 60 liters per minute, with a pressure from 240 to 250 mbar.

9. The method, according to claim 8, wherein the metal foil is maintained at a distance from 1 to 3 mm of the plasma nozzle, moving at 50 m/min, submitted to the atmospheric plasma at a flow of 56 liters of nitrogen per minute and at a pressure of 245 mbar, to present a surface free energy of 56 mN/m.

10. The method, according to claim 2, wherein the curing unit applies, to the varnish layer, an ultraviolet radiation above 100 mJ/cm2, emitted by mercury vapor or LED lamps.

11. The method, according to claim 3, wherein the curing unit applies, to the varnish layer, an ultraviolet radiation above 100 mJ/cm2, emitted by mercury vapor or LED lamps.

12. The method, according to claim 4, wherein the curing unit applies, to the varnish layer, an ultraviolet radiation above 100 mJ/cm2, emitted by mercury vapor or LED lamps.

13. The method, according to claim 5, wherein the curing unit applies, to the varnish layer, an ultraviolet radiation above 100 mJ/cm2, emitted by mercury vapor or LED lamps.

14. The method, according to claim 7, wherein the curing unit applies, to the varnish layer, an ultraviolet radiation above 100 mJ/cm2, emitted by mercury vapor or LED lamps.

15. The method, according to claim 8, wherein the curing unit applies, to the varnish layer, an ultraviolet radiation above 100 mJ/cm2, emitted by mercury vapor or LED lamps.

16. The method, according to claim 9, wherein the curing unit applies, to the varnish layer, an ultraviolet radiation above 100 mJ/cm2, emitted by mercury vapor or LED lamps.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0017] The present disclosure will be described below, with reference to the attached drawing in which:

[0018] FIG. 1 represents, in a schematic and simplified way, the steps of the method of treatment of the present disclosure when applied for surface protection of metal foils.

DESCRIPTION OF THE METHOD

[0019] As already mentioned and illustrated in FIG. 1 of the attached drawing, the method of the present disclosure aims to provide a surface protective treatment on one or both faces of metal foils 10, by the application of a protective varnish, curable by ultraviolet radiation.

[0020] The metal foil 10, submitted to the present method, may be coated or not with chromium or tin and is particularly used in the metallic packaging industry in the form of cans formed with two or three pieces.

[0021] According to the method, the metal foil 10 has any of its faces submitted to contact with an ionized gas called atmospheric plasma PA, which is considered the fourth state of matter and which is released against the surface to be treated, from a plasma nozzle 20.

[0022] Atmospheric plasma PA is produced by a controlled discharge of electrical energy made by a plasma generator 21, of high frequency and high voltage, inside the plasma nozzle 20, which is further fed, by compressed air, from a compressed air generator 22. FIG. 1 of the attached drawing illustrates only one plasma generator 21, of high frequency and high voltage, a compressed air generator 22 and a plasma nozzle 20 generating atmospheric plasma PA that impinges on the surface of a metal foil 10. It should be understood that the number of plasma nozzles 20 and plasma generators 21 could vary according to the transversal dimension of the metal foil 10, the relative displacement speed between the metal foil 10 and the plasma nozzles 20 and the intensity of the plasma nozzles.

[0023] FIG. 1 of the drawing illustrates an example of the displacement of a metal foil 10 by conveyor belts 30 passing under the atmospheric plasma PA at a linear speed determined by the other parameters mentioned above and related to the type of metal foil 10 and to the power of the plasma nozzles 20, assuming that the latter are adequate in number and positioning for the necessary coverage of the width of the metal foil 10 passing under the atmospheric plasma PA.

[0024] The surface free energy of the metal foil 10 before its exposition to the atmospheric plasma is on average from 28 to 45 mN/m, the polar part, considered hydrophilic, being low, with averages from 1 to 3, for metal foils coated with tin, and from 4 to 5 for chromium plated foils, depending on their production, machining, layer of free tin or chromium and passivation. The cohesion between atoms and molecules, which causes the surface energy/tension of a substance, may be explained by different interaction types. In particular, dispersive interactions and polar interactions can be differentiated to each other. The interactions caused by temporary fluctuations of the load distribution in the atoms/molecules are called dispersive interactions (van der Waals interaction).

[0025] The polar interactions comprise Coulomb interactions between permanent dipoles and between permanent and induced dipoles (for example, hydrogen links). Since the van der Waals interactions occur between all the atoms and molecules, there is no substance with surface energy/tension that consists only of a polar part. The surface energy/tension σ.sub.i of a component i is composed, in an additive way, by dispersed parts σi.sup.d and polar parts σi.sup.p according to:

σ.sub.i=σ.sub.i.sup.d+σ.sub.i.sup.p

[0026] The comparison of the proportion between the dispersive part and the polar part of the surface energy/tension, between the substrate and the varnish, allows predicting the adhesion between said two components. The closer the relationships between substrate and varnish are, the more interactions are possible between the components and a greater the adhesion between them.

[0027] After exposing the metallic substrate (steel foil) to the atmospheric plasma PA, with the plasma nozzle 20 positioned from 1 to 3 mm distant from the steel foil, using plasma generators 21, of high frequency and high voltage, with a flow of 50 to 60 liters of nitrogen per minute and at a pressure of 245 mbar (24.5 KPa) at the outlet of the jet, the substrate, in the form of a metal foil 10, under displacement at a speed of 40 to 80 m/min, has its surface free energy increased to parameters that can be adjusted to the compatible of the surface tension of the varnish to be applied, said surface free energy of the treated foil could be defined from 29 to 72 mN/m, with a high polar part, for metal foils coated with tin or chrome. If a metal foil coated with tin is used, with a surface free energy before the treatment of 41 mN/m, dispersive 39/polar 2, the result, after the plasma application, led to an increase of the free energy to 56 mN/m, with the polar part being 16. If a metal foil coated with chrome is used, with a surface free energy of 41 mN/m, dispersive 35/polar 6, the result, after the plasma application, led to an increase of the free energy to 56 mN/m, with the polar part being 16.

[0028] The plasma generator 21, of high frequency and high power, must be configured to generate 300 to 400 Volts, with the pulse frequency between 20 and 30 kHz, for reaching a power between 900 and 1000 W. The gas to be compressed can be oxygen or nitrogen, the latter, N2, being the most effective. The amount of gas released should be, in both cases, from 50 to 60 liters per minute, with a pressure from 240 to 250 mbar (24.5 to 25.0 KPa) at the outlet of the jet.

[0029] In the parameters above mentioned, it was found the stability between the metal foil surface and the varnish, allowing good wettability and adhesion of the used UV-cured varnishes. The foils can be then submitted, with success, to the standard tests “Scratch and tape—Adhesion” and reverse impact.

[0030] This procedure of pre-treatment produces the cleaning of the organic matter, the polarization of the metallic surface under treatment and the increase of the surface free energy of the steel of the metal foil 10, making said surface free energy compatible with the surface tension of the UV-cured varnish to be applied to the metal foil 10, allowing adhesion and spreading of the varnish on the foil, in a speed greater than 3500 steel foils per hour (foils coated with tin or with chromium), considering atmospheric plasma PA produced from nitrogen or from the compressed oxygen, using 56 liters of the gas per minute, at a pressure at the outlet of the jet of 245 mbar (24.5 KPa) and at a speed of the metal foils of about 50 m/min.

[0031] The metal foil 10, superficially treated by atmospheric plasma PA, is transported by the belts 30 to a varnish applicator 40, which can be, for example, defined by a varnish roller 41 feeding an applicator roller 42 which works in opposition to a support roller 43. Upon passing between the applicator roller 42 and the support roller 43, the metal foil 10 receives, on its face that contacts the applicator roller 42, a UV-cured varnish layer CV. Immediately after, the metal foil 10 enters into a cure unit 50, which is formed, for example, by mercury vapor or LED lamps, which generate sufficient ultraviolet radiation to activate the photo-initiators of the chemical composition of the varnish, producing its polymerization, its adhesion to the surface of the metal foil and a total covering and protection of the mentioned surface of the metal foil to be used in the production of bodies, domes and bottoms of metallic packages.

[0032] It is necessary to use varnishes with high solid content, without dispersants or vehicles based on chemical solvents, and cured by ultraviolet radiation generated by mercury vapor lamps.

[0033] The varnishes used in this process comprise oligomers, monomers and photo-initiators, applied by lithographic roller 42, without the need for dilution, with a viscosity from 40 to 60 Sec CF4/25° C., specific weight from 1.01 to 1.05/25° C. with solid contents from 99 to 100%.

[0034] The method in question allows the use of the protection product, that is the varnish, both on the internal and external parts of the bodies and components, dome and bottom, of metallic packages composed of three or two pieces, the varnish having 99% of solids cured by ultraviolet radiation, the method also allowing the substitution of the gas furnace by a curing station with UV lamps.

[0035] The curing of the varnish takes place by polymerization of the varnish caused by the interaction of the photo-initiator of the varnish composition with the ultraviolet radiation, above 100 mJ/cm2, emitted by the lamps of the curing unit 50, leads to a final dry layer of 4.65 to 7.75 g/m.sup.2.

[0036] The effects of the method being now proposed may be listed as follows: [0037] Elimination of emission of gases harmful to health and environment; [0038] Elimination of the use of gas in the industrial process; [0039] Elimination of hazards in the environment, due to the use of non-flammable varnishes, in opposition to the methods that use solvent-based varnishes, which are eliminated by thermal curing and treatment of toxic gases; [0040] Reduction of plant spaces, with elimination of the gas furnace for thermal curing of the solvent-based varnishes and use of a UV curing station much smaller; [0041] Reduction of the maintenance of the application and treatment lines, since they are smaller and simplified; [0042] Significant savings in terms of maintenance, rent and less operators; [0043] Savings in freight, since it is no more necessary the transport of the varnish solvents previously used, but only the solids to be applied to the steel foil; [0044] Greater stability of the metallic substrate, ensuring better adherence and wettability.