THERMAL CONDUCTIVITY DETECTOR

Abstract

A thermal conductivity detector (1) includes: a cell block (2) provided therein with a measurement cell (10) serving as a space in which a filament (12) for exchanging heat with a gas is arranged, the cell block (2) being provided with a cell inlet (11) for introducing a gas into the measurement cell (10) and a cell outlet (13) for flowing out the gas from the measurement cell (10); an outlet flow path (4) communicated with the cell outlet (13) of the cell block (2); a buffer block (6) provided therein with a buffer space (14), the buffer block (6) having an inlet port (15) for introducing the gas into the buffer space (14) and a discharge port (16) for discharging the gas from the buffer space (14), the inlet port (15) being fluidly connected to the outlet flow path (4); and a discharge member (8) retaining a fluid resistance portion (20) for increasing fluid resistance of the discharge port (16), the discharge member (8) being attached to the buffer block (6) such that the gas discharged from the discharge port (16) passes through the fluid resistance portion (20), the discharge member (8) being configured to be detachable from the buffer block (6) together with the fluid resistance portion (20).

Claims

1. A thermal conductivity detector comprising: a cell block provided therein with a measurement cell serving as a space in which a filament for exchanging heat with a gas is arranged, the cell block being provided with a cell inlet for introducing the gas into the measurement cell and a cell outlet for flowing out the gas from the measurement cell; an outlet flow path communicated with the cell outlet of the cell block; a buffer block provided therein with a buffer space, the buffer block having an inlet port for introducing the gas into the buffer space and a discharge port for discharging the gas from the buffer space, the inlet port being fluidly connected to the outlet flow path; and a discharge member retaining an outer peripheral surface of a fluid resistance portion for increasing fluid resistance of the discharge port, the discharge member being attached to the buffer block such that the gas discharged from the discharge port passes through the fluid resistance portion, the discharge member being configured to be integrally detachable from the buffer block together with the fluid resistance portion.

2. The thermal conductivity detector as recited in claim 1, wherein the fluid resistance portion is a resistance tube.

3. The thermal conductivity detector as recited in claim 2, wherein an outer diameter of the resistance tube is equal to or less than 1 mm.

4. The thermal conductivity detector as recited in claim 2, wherein the discharge member includes: a retaining member retaining an outer peripheral surface of the resistance tube; and a fixing member configured to be detachably fixed to the buffer block in a state of retaining the retaining member.

5. The thermal conductivity detector as recited in claim 4, wherein the retaining member is made of an elastic resin material.

6. The thermal conductivity detector as recited in claim 1, wherein the fluid resistance portion is a filter.

7. The thermal conductivity detector as recited in claim 1, further comprising: a heat retention unit configured to prevent a temperature drop of the discharge member.

8. The thermal conductivity detector as recited in claim 7, wherein the heat retention unit is provided with a thermally conductive block in contact with the discharge member and a heater for heating the thermally conductive block.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0014] FIG. 1 is a cross-sectional view showing one example of a thermal conductivity detector.

[0015] FIG. 2 is a cross-sectional view showing a structure of a discharge member of the same example.

[0016] FIG. 3 is a cross-sectional view schematically showing another example of a thermal conductivity detector.

[0017] FIG. 4 is a cross-sectional view schematically showing still another example of a thermal conductivity detector.

EMBODIMENTS FOR CARRYING OUT THE INVENTION

[0018] Hereinafter, some embodiments of a thermal conductivity detector according to the present invention will be described with reference to the attached drawings.

[0019] As shown in FIG. 1, the thermal conductivity detector 1 includes a cell block 2, an outlet pipe 4, a buffer block 6, and a discharge member 8.

[0020] The cell block 2 is provided therein with a measurement cell 10 in which a filament 12 is arranged. The cell block 2 is provided with a cell inlet 11 for introducing a gas into the measurement cell 10 and a cell outlet 13 for flowing out the gas from the measurement cell 10. One end of the outlet pipe 4 serving as an outlet flow path is fluidly connected to the cell outlet 13 of the cell block 2. The filament 12 is for exchanging heat with the gas flowing through the measurement cell 10. The thermal conductivity detector 1 quantifies the components contained in the gas by reading the signal corresponding to the heat exchange amount between the gas flowing through the measurement cell 10 and the filament 12.

[0021] The buffer block 6 is provided therein with a buffer space 14. The buffer block 6 is further provided with an inlet port 15 for introducing the gas into the buffer space 14 and a discharge port 16 for discharging the gas from the buffer space 14. The other end of the outlet pipe 4 is fluidly connected to the inlet port 15 of the buffer block 6. The inner cross-sectional area of the buffer space 14 perpendicular to the inflow direction of the gas from the inlet port 15 is greater than the cross-sectional area of the inner side flow path (i.e., outlet flow path) of the outlet pipe 4 perpendicular to the flow direction. The discharge member 8 is detachably attached to the buffer block 6.

[0022] Note that in FIG. 1, only one measurement cell 10 is shown inside the cell block 2. However, two measurement cells 10, i.e., a measurement cell for a sample gas and a measurement cell for a reference gas, may be provided within the cell block 2. In a case where two measurement cells 10 are provided in the cell block 2, these two measurement cells 10 may be fluidly connected to a common buffer space 14, or two buffer spaces 14 may be provided in the buffer block 6, and the two measurement cells 10 may be fluidly connected to the respective separate buffer spaces 14.

[0023] As shown in FIG. 2, the discharge member 8 is provided with a resistance tube 20, a retaining member 22, a fixing member 24, and a seal ring 26. The resistance tube 20 is, for example, a fine linear tube having an outer diameter of 1 mm or less and an inner diameter of 0.5 mm or less. The resistance tube 20 serves as a fluid resistance portion for increasing the fluid resistance of the discharge port 16. The retaining member 22 is made of a resin material (for example, silicone rubber) having elasticity. The retaining member 22 retains the outer peripheral surface of the resistance tube 20 with the resistance tube 20 penetrated therethrough. The fixing member 24 is a metal member having a recess for fitting and holding the retaining member 22. The fixing member 24 is detachably attached to a portion of the buffer block 6 where the discharge port 16 is provided in a state in which the retaining member 22 is retained by the recess.

[0024] A cylindrical protrusion 18 is provided at a portion of the outer surface of the buffer block 6 where the discharge port 16 is provided. A thread groove is formed on the outer peripheral surface of the protrusion 18. A thread groove is formed on the inner peripheral surface of the fixing member 24 of the discharge member 8 to be threaded with the thread groove of the outer peripheral surface of the protrusion 18 of the buffer block 6. By rotating the fixing member 24, the discharge member 8 can be attached to and detached from the buffer block 6.

[0025] The discharge member 8 is attached to the buffer block 6 such that the resistance tube 20 is in fluidic communication between the buffer space 14 and the atmosphere. A seal ring 26 is sandwiched between the tip of the protrusion 18 of the buffer block 6 and the retaining member 22 of the discharge member 8. The seal ring 26 deforms the resin retaining member 22 at the tip end of the protrusion 18 to enhance the sealing performance, thereby preventing a gas from being discharged from a path other than the resistance tube 20.

[0026] With the above-described structure, the fluid resistance of the gas to be discharged from the discharge port 16 increases, reducing the capacitance of the buffer space 14, which in turn can reduce the size of the buffer block 6. Since the resistance tube 20 is fine, sample clogging may occur within the resistance tube 20. However, the detachment/attachment of the discharge member 8 retaining the resistance tube 20 can be easily performed by rotating the fixing member 24, and therefore, the replacement of the resistance tube 20 can be easily performed.

[0027] Note that as the fluid resistance portion for increasing the fluid resistance of the discharge port 16, a filter (a metal crystal filter, a ceramic filter, or the like) may be used instead of the resistance tube 20. In this case, the filter may be retained by the retaining member 22 or brazed to the fixing member 24 of the discharge member 8.

[0028] Further, the attaching/detaching structure of the buffer block 6 with respect to the discharge member 8 is not limited to those utilizing a threaded engagement as long as the buffer block 6 can be detachably attached to the discharge member 8. Further, the discharge member 8 does not necessarily need to be directly attached to and detached from the buffer block 6, and may be configured to be detachably attached to the buffer block 6 via a pipe.

[0029] Further, as shown in FIG. 3 and FIG. 4, a heat retention unit may be provided to prevent the temperature drop of the discharge member 8 to prevent clogging in the fluid resistance portion, such as, e.g., the resistance tube 20. In the example shown in FIG. 3, a heat retention unit is configured by a thermal insulation member 30 surrounding the discharge member 8 to prevent the heat release so that the heat transferred to the discharge member 8 via the metal outlet pipe 4 and the buffer block 6 does not escape. In the example shown in FIG. 4, the heat retention unit is constituted by a metal thermally conductive block 32 in contact with the discharge member 8 and a heater 34 for heating the thermally conductive block 32.

[0030] The examples described above merely exemplify embodiments of the thermal conductivity detector according to the present invention. Embodiments of the thermal conductivity detector according to the present invention are as follows.

[0031] According to an embodiment of the present invention, a thermal conductivity detector includes:

[0032] a cell block provided therein with a measurement cell serving as a space in which a filament for exchanging heat with a gas is arranged, the cell block being provided with a cell inlet for introducing the gas into the measurement cell and a cell outlet for flowing out the gas from the measurement cell;

[0033] an outlet flow path communicated with the cell outlet of the cell block;

[0034] a buffer block provided therein with a buffer space, the buffer block having an inlet port for introducing the gas into the buffer space and a discharge port for discharging the gas from the buffer space, the inlet port being fluidly connected to the outlet flow path; and

[0035] a discharge member retaining a fluid resistance portion for increasing fluid resistance of the discharge port, the discharge member being attached to the buffer block such that the gas discharged from the discharge port passes through the fluid resistance portion, the discharge member being configured to be detachable from the buffer block together with the fluid resistance portion.

[0036] According to a first aspect of an embodiment of the thermal conductivity detector according to the present invention, the fluid resistance portion is a resistance tube.

[0037] In the first aspect of the present invention, an outer diameter of the resistance tube is equal to or less than 1 mm. It is difficult to detachably attach a fine resistance tube having an outer diameter of 1 mm or less to a buffer block by a threaded engagement or the like. However, in the embodiment according to the present invention, the resistance tube can be attached to and detached from the buffer block in accordance with the attachment/detachment of the discharge member, and therefore, even in the case of a fine resistance tube, the replacement can be easily performed.

[0038] Further, in the first aspect of the present invention, the discharge member may include:

[0039] a retaining member retaining an outer peripheral surface of the resistance tube; and

[0040] a fixing member configured to be detachably fixed to the buffer block in a state of retaining the retaining member.

[0041] In the above case, the retaining member may be made of an elastic resin material. With such an aspect, it is possible to prevent the fine resistance tube from being bent.

[0042] In a second aspect of the embodiment of the thermal conductivity detector according to the present invention, the fluid resistance portion is a filter.

[0043] In a third aspect of the embodiment of the thermal conductivity detector according to the present invention, the thermal conductivity detector further includes a heat retention unit configured to prevent a temperature drop of the discharge member. With such an aspect, it is possible to suppress clogging of a fluid resistance portion by a sample.

[0044] In the above-described third aspect of the present invention, the heat retention unit may be provided with a thermally conductive block in contact with the discharge member and a heater for heating the thermally conductive block.

DESCRIPTION OF SYMBOLS

[0045] 1: Thermal conductivity detector [0046] 2: Cell block [0047] 4: Outlet pipe [0048] 6: Buffer block [0049] 8: Discharge member [0050] 10: Measurement cell [0051] 11: Cell inlet [0052] 12: Filament [0053] 13: Cell outlet [0054] 14: Buffer space [0055] 15: Inlet port [0056] 16: Discharge port [0057] 18: Protrusion [0058] 20: Resistance tube (fluid resistance portion) [0059] 22: Retaining member [0060] 24: Fixing member [0061] 26: Seal ring [0062] 30: Thermal insulation member [0063] 32; Thermally conductive block