Foldable Pouch-Shaped Battery Cell and Method of Manufacturing the Same
20230145579 · 2023-05-11
Assignee
Inventors
- Kwang Ho Won (Daejeon, KR)
- Young Hoon Kim (Daejeon, KR)
- Ki Tae Kim (Daejeon, KR)
- Chan Ki Park (Daejeon, KR)
- Jung Shik Oh (Daejeon, KR)
- Hyun Tae Kim (Daejeon, KR)
Cpc classification
H01M10/0585
ELECTRICITY
Y02E60/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M10/0463
ELECTRICITY
H01M50/538
ELECTRICITY
H01M2220/30
ELECTRICITY
International classification
Abstract
The present invention relates to a pouch-shaped battery cell having an electrode assembly in a pouch-shaped battery case, the electrode assembly including positive electrodes and negative electrodes, each of the positive electrodes and the negative electrodes having a structure in which the length of the electrode in a width direction is less than the length of the electrode in a length direction, each of the positive electrodes and the negative electrodes has an uncoated portion extending parallel to outer peripheries of the electrode in the overall width direction or outer peripheries of the electrode in the overall length direction and a coated portion, which is coated with an electrode mixture, formed at the remaining portion of the electrode excluding the uncoated portion, and a stepped structure is formed at the part of the pouch-shaped battery case corresponding to the uncoated portion so as to be recessed inwards.
Claims
1. A pouch-shaped battery cell having an electrode assembly received in a pouch-shaped battery case, wherein the electrode assembly comprises positive electrodes and negative electrodes, each of the positive electrodes and the negative electrodes being having a structure in which a length of the electrode in an overall width direction is less than a length of the electrode in an overall length direction, each of the positive electrodes and the negative electrodes has an uncoated portion, which is a portion not coated with an electrode mixture, extending parallel to outer peripheries of the electrode in the overall width direction or outer peripheries of the electrode in the overall length direction and a coated portion, which is coated with the electrode mixture, disposed at a remaining portion of the electrode excluding the uncoated portion, and a stepped structure is formed at a part of the pouch-shaped battery case adjacent to the uncoated portion, the stepped structure being recessed inwards from adjacent portions of the pouch-shaped battery case.
2. The pouch-shaped battery cell according to claim 1, wherein positive electrode tabs and negative electrode tabs protrude from an outer periphery of the electrode assembly in the overall width direction.
3. The pouch-shaped battery cell according to claim 1, wherein each of the positive electrodes and the negative electrodes has a first coated portion and a second coated portion disposed at opposite sides of the uncoated portion, and wherein each of the positive electrodes and the negative electrodes is folded at the respective uncoated portion.
4. The pouch-shaped battery cell according to claim 3, wherein a positive electrode tab or a negative electrode tab protrudes from one of the first coated portion or the second coated portion of each of the electrodes.
5. The pouch-shaped battery cell according to claim 1, wherein each of the positive electrodes and the negative electrodes has a respective insulating member overlying outer surfaces of a part of the respective uncoated portion and a portion of each respective coated portion, each insulating member serving as a border portion extending between the respective uncoated portion and the respective coated portion.
6. The pouch-shaped battery cell according to claim 5, wherein each insulating member is an insulation tape or an insulating solution.
7. The pouch-shaped battery cell according to claim 1, wherein a wrinkled folding line extends along each uncoated portion.
8. The pouch-shaped battery cell according to claim 1, wherein the pouch-shaped battery case comprises a first battery case and a second battery case, and wherein the stepped structure is formed at a portion of at least one of the first battery case and the second battery case.
9. The pouch-shaped battery cell according to claim 8, wherein the a respective stepped structure of the first battery case and the second battery case is attached to each of an uppermost electrode and a lowermost electrode of the electrode assembly.
10. The pouch-shaped battery cell according to claim 1, wherein the pouch-shaped battery case and the electrode assembly are folded, and wherein a notch is formed in a sealed portion located at a portion of the pouch-shaped battery case that is folded.
11. A method of manufacturing the pouch-shaped battery cell according to claim 1, the method comprising: (a) coating an electrode sheet to form the coated portion and the uncoated portion; (b) adding an insulating member to outer surfaces of a part of the coated portion and a part of the uncoated portion, the insulating member serving as a border portion between the coated portion and the uncoated portion; (c) rolling the electrode sheet; and (d) slitting the electrode sheet.
12. The method according to claim 11, wherein an insulating tape is attached to the electrode sheet or an insulation solution is applied to the electrode sheet during step (b) to form the insulating member.
13. The method according to claim 11, further comprising: manufacturing the electrode assembly by stacking a positive electrode and a negative electrode manufactured by cutting the electrode sheet slit with a separator interposed therebetween; disposing the electrode assembly in the pouch-shaped battery case having two of the stepped structures formed thereat; and hermetically sealing the pouch-shaped battery case.
14. The method according to claim 13, further comprising: receiving the electrode assembly in the pouch-shaped battery case; and attaching each of an uppermost electrode and a lowermost electrode of the electrode assembly to a corresponding one of the stepped structures of the pouch-shaped battery case.
Description
DESCRIPTION OF DRAWINGS
[0035]
[0036]
[0037]
[0038]
[0039]
[0040]
[0041]
[0042]
[0043]
BEST MODE
[0044] Now, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings such that the preferred embodiments of the present invention can be easily implemented by a person having ordinary skill in the art to which the present invention pertains. In describing the principle of operation of the preferred embodiments of the present invention in detail, however, a detailed description of known functions and configurations incorporated herein will be omitted when the same may obscure the subject matter of the present invention.
[0045] In addition, the same reference numbers will be used throughout the drawings to refer to parts that perform similar functions or operations. In the case in which one part is said to be connected to another part throughout the specification, not only may the one part be directly connected to the other part, but also, the one part may be indirectly connected to the other part via a further part. In addition, that a certain element is included does not mean that other elements are excluded, but means that such elements may be further included unless mentioned otherwise.
[0046] In addition, a description to embody elements through limitation or addition may be applied to all inventions, unless particularly restricted, and does not limit a specific invention.
[0047] Also, in the description of the invention and the claims of the present application, singular forms are intended to include plural forms unless mentioned otherwise.
[0048] Also, in the description of the invention and the claims of the present application, “or” includes “and” unless mentioned otherwise. Therefore, “including A or B” means three cases, namely, the case including A, the case including B, and the case including A and B.
[0049] In addition, all numeric ranges include the lowest value, the highest value, and all intermediate values therebetween unless the context clearly indicates otherwise.
[0050] Embodiments of the present invention will be described in detail with reference to the accompanying drawings.
[0051] A pouch-shaped battery cell according to the present invention is configured to have a structure in which an electrode assembly is received in a pouch-shaped battery case made of a laminate sheet including an outer resin layer, a barrier layer, and an inner adhesive layer in a hermetically sealed state. The electrode assembly may be a stacked type electrode assembly, which is configured to have a structure in which a positive electrode and a negative electrode are stacked in the state in which a separator is interposed therebetween, or a laminated and stacked type electrode assembly, which is configured to have a structure in which two or more bicells, each of which positive electrodes and negative electrodes are disposed in the state in which two separators are interposed respectively therebetween, are laminated in a state of being stacked.
[0052] Each of the positive electrode and the negative electrode is configured to have a rectangular planar shape of a structure in which the length of the electrode in an overall width direction is less than the length of the electrode in an overall length direction, and has a structure in which an uncoated portion, which is a portion coated with no electrode mixture, is formed parallel to the outer peripheries of the electrode in the overall width direction or the outer peripheries of the electrode in the overall length direction and a coated portion, which is coated with an electrode mixture, is formed at the remaining portion of the electrode excluding the uncoated portion.
[0053] The pouch-shaped battery cell according to the present invention is foldable, wherein the uncoated portion is folded, whereby the pouch-shaped battery cell is folded.
[0054] In connection therewith, an electrode mixture formed on an electrode current collector by coating may be separated from the folding portion of the electrode current collector when the pouch-shaped battery cell is folded. In order to prevent this, in the present invention, the uncoated portion is formed, and the pouch-shaped battery cell is folded at the uncoated portion, whereby it is possible to prevent the above problem.
[0055]
[0056] Referring to
[0057] The electrodes (a) and the electrodes (b) are stacks of positive electrodes 110 and 210 and negative electrodes 120 and 220 configured to have a structure in which the length of the electrode in the overall width direction, i.e. an x-axis direction, is less than the length of the electrode in the overall length direction, i.e. a y-axis direction. Each of positive electrode tabs 112 and 212 and negative electrode tabs 122 and 222 protrudes from one of the outer peripheries of a corresponding one of the electrodes in the overall width direction.
[0058] Each of the electrodes (a) has a structure in which an uncoated portion, which is a portion coated with no electrode mixture, is formed parallel to the outer peripheries of the electrode in the overall width direction. The positive electrode 110 has coated portions 111 formed symmetrical with respect to an uncoated portion 115 formed parallel to the outer peripheries of the electrode in the overall width direction, and the negative electrode 120 has coated portions 121 formed symmetrical with respect to an uncoated portion 125 formed parallel to the outer peripheries of the electrode in the overall width direction.
[0059] For the positive electrode 110, an insulating member 113 is added to outer surfaces of a part of the uncoated portion 115 and a part of each coated portion 111 as a border portion between the uncoated portion 115 and the coated portion 111. For the negative electrode 120, an insulating member 123 is added to outer surfaces of a part of the uncoated portion 125 and a part of each coated portion 121 as a border portion between the uncoated portion 125 and the coated portion 121.
[0060] Each of the electrodes (b) has a structure in which an uncoated portion, which is a portion coated with no electrode mixture, is formed parallel to the outer peripheries of the electrode in the overall length direction. The positive electrode 210 has coated portions 211 formed symmetrical with respect to an uncoated portion 215 formed parallel to the outer peripheries of the electrode in the overall length direction, and the negative electrode 220 has coated portions 221 formed symmetrical with respect to an uncoated portion 225 formed parallel to the outer peripheries of the electrode in the overall length direction.
[0061] For the positive electrode 210, an insulating member 213 is added to outer surfaces of a part of the uncoated portion 215 and a part of each coated portion 211 as a border portion between the uncoated portion 215 and the coated portion 211. For the negative electrode 220, an insulating member 223 is added to outer surfaces of a part of the uncoated portion 225 and a part of each coated portion 221 as a border portion between the uncoated portion 225 and the coated portion 221.
[0062] Meanwhile, the present invention relates to a pouch-shaped battery cell that is folded based on an uncoated portion, and therefore coated portions may be formed asymmetrical with respect to the uncoated portion, unlike what is shown in
[0063] Although the present invention relates to a foldable pouch-shaped battery cell, it is preferable to understand that the pouch-shaped battery cell does not always remain folded when in use and may be folded or unfolded as needed.
[0064] Consequently, it is preferable for the electrode tabs to protrude in one direction in the state in which the pouch-shaped battery cell according to the present invention is not folded. The electrode tabs protrude from one of the outer peripheries of the electrode in the overall width direction.
[0065] In addition, on the assumption that, for the electrodes (a), the coated portions 111 and 121 located above the uncoated portions 115 and 125 are first coated portions and the coated portions 111 and 121 located under the uncoated portions 115 and 125 are second coated portions, the positive electrode tab 112 and the negative electrode tab 122 protrude from the first coated portions. On the assumption that, for the electrodes (b), the coated portions 211 and 221 located on the left sides of the uncoated portions 215 and 225 are first coated portions and the coated portions 211 and 221 located on the right sides of the uncoated portions 215 and 225 are second coated portions, the positive electrode tab 212 and the negative electrode tab 222 protrude from the first coated portions. Since the positive electrode tab or the negative electrode tab is formed at any one coated portion, as described above, the positions of a positive electrode terminal and a negative electrode terminal may be uniformly fixed irrespective of whether the pouch-shaped battery cell is folded or unfolded.
[0066] Each of the insulating members 113 and 213 may be a member configured to have a structure in which an insulating layer is attached to an adhesive layer as a substrate, such as an insulating tape. Consequently, the insulating tape may be added to the border portion between the coated portion and the uncoated portion by attachment, or an insulating solution obtained by dissolving an insulating material in a solvent may be added to the border portion between the coated portion and the uncoated portion by coating.
[0067] The insulating layer of the insulating tape may be made of cast polypropylene (CPP) or polyethylene terephthalate (PET).
[0068] The insulating solution may be manufactured, for example, by mixing styrene butadiene rubber (SBR), alumina (Al.sub.2O.sub.3), and carboxymethyl cellulose (CMC) in a weight ratio of 80:20:0.008 to prepare a mixture and adding 40 weight % of distilled water to the mixture.
[0069] A method of manufacturing a pouch-shaped battery cell according to the present invention may include (a) a step of coating an electrode sheet to form a coated portion, which is a portion coated with an electrode mixture, and an uncoated portion, which is a portion coated with no electrode mixture; (b) a step of adding an insulating member to outer surfaces of a part of the coated portion and a part of the uncoated portion as a border portion between the coated portion and the uncoated portion; (c) a step of rolling the electrode sheet; and (d) a step of slitting the electrode sheet of step (c).
[0070] The insulating member may be formed on the coated portion by coating so as to have a size of at least 0.1 mm. Preferably, the insulating member is formed on the coated portion by coating so as to overlap the coated portion by less than 0.4 mm. In order to prevent an increase in overall thickness of the electrode due to addition of the insulating member, however, it is preferable for the thickness of the insulating member not to be greater than the thickness of the coated portion based on the insulating member formed on the uncoated portion by coating.
[0071] Since the insulation member is added to the border portion between the uncoated portion and the coated portion, as in the present invention, it is possible to prevent occurrence of short circuit due to contact between the positive electrode and the negative electrode even though the separator interposed between the positive electrode and the negative electrode shrinks.
[0072] In connection therewith, since the area of the coated portion of the negative electrode is generally designed so as to be greater than the area of the coated portion of the positive electrode, the coated portion of the negative electrode is disposed in contact with the coated portion of the positive electrode in the stacking direction. In the case in which the separator shrinks due to overheating of the electrode assembly, therefore, short circuit may occur due to contact between the coated portion of the negative electrode and the coated portion of the positive electrode.
[0073] In the present invention, since the insulating member is added to the border between the coated portion and the uncoated portion, it is possible to prevent contact between the coated portion of the negative electrode and the coated portion of the positive electrode even though the separator shrinks.
[0074] In the electrode according to the present invention, it is preferable for the height of the uncoated portion, which corresponds to the distance between the first coated portion and the second coated portion, to be uniformly formed in a lateral direction of the uncoated portion perpendicular thereto. In order to prevent the coated portion from being separated from the electrode current collector even though the electrode assembly is folded 180 degrees, the height of the uncoated portion may be set in consideration of the thickness of the electrode current collector and the thickness of the coated portion formed on one surface or opposite surfaces of the electrode current collector by coating.
[0075]
[0076] Referring to
[0077] In the case in which the folding line 318 is formed, as described above, stress concentrated on a bent portion when the electrode is folded is dispersed, whereby it is possible to prevent damage to the bent portion.
[0078] The above description of the electrode of
[0079] Meanwhile, the method of manufacturing the pouch-shaped battery cell according to the present invention may include a process of manufacturing an electrode assembly by stacking a positive electrode and a negative electrode manufactured by cutting the electrode sheet slit in step (d) in the state in which a separator is interposed therebetween, receiving the electrode assembly in a pouch-shaped battery case having a stepped portion formed thereat, and hermetically sealing the pouch-shaped battery case.
[0080]
[0081] Referring to
[0082] A receiving portion 533 configured to receive an electrode assembly is formed in each of the first battery case 531 and the second battery case 532 of the pouch-shaped battery cell (b), and a stepped portion 536 is formed at the receiving portion 533 so as to be recessed inwards. The stepped portion 536 is formed at a portion corresponding to the portion of the electrode assembly at which an uncoated portion is located.
[0083] Since the pouch-shaped battery cell (a) and the pouch-shaped battery cell (b) are configured respectively such that the stepped portions 436 and 536 are formed so as to correspond to the portions of the electrode assemblies at which the uncoated portions are located, as described above, coated portions of the electrode assemblies are received respectively in protruding portions 437 and 537, which relatively protrude, whereby fixation in position of the electrode assemblies in the battery cases may be achieved.
[0084] In addition, the method of manufacturing the pouch-shaped battery cell according to the present invention may further include a process of receiving the electrode assembly in a pouch-shaped battery case having a stepped portion formed thereat and attaching the uppermost electrode and the lowermost electrode of the electrode assembly to the stepped portion of the pouch-shaped battery case.
[0085] In connection therewith,
[0086] Referring to
[0087] The electrode assembly is a stacked type electrode assembly, which is configured to have a structure in which positive electrodes 110 and negative electrodes 120 are alternately stacked in the state in which separators are interposed respectively between the positive electrodes and the negative electrodes. Each of the positive electrodes 110 and the negative electrodes 120 is provided with a coated portion and an uncoated portion. A stepped portion of a first battery case 531 is attached to the uncoated portion of the negative electrode 120 located at the uppermost end of the electrode assembly, and a second battery case 532 is attached to the uncoated portion of the positive electrode 110 located at the lowermost end of the electrode assembly.
[0088] Since the electrode assembly is coupled to the pouch-shaped battery case, as described above, it is possible to prevent movement of the electrode assembly in the battery case due to external impact. Consequently, it is possible to prevent damage to electrode tabs and an electrode lead due to movement of the electrode assembly.
[0089] Pouch-shaped battery cells manufactured using the method of manufacturing the pouch-shaped battery cell described above are shown in
[0090]
[0091] In the pouch-shaped battery cell according to the present invention, a notch may be formed in a battery case in order to prevent damage to the battery case due to tensile force generated at a folding portion of the battery case at the time of folding.
[0092] Referring to
[0093]
[0094] Referring to
[0095] Consequently, in the case in which the pouch-shaped battery cell is bent upwards, as shown in
[0096] However, in the case in which the pouch-shaped battery cell is bent downwards, as shown in
[0097] Unlike what is shown in
[0098]
[0099] Referring to
[0100] The pouch-shaped battery cell of
[0101] Consequently, the height of an uncoated portion of an electrode assembly and the distance between protruding portions 837 must be set in consideration of the height of the protruding portions.
[0102] Although
[0103] In addition, unlike what is shown in
[0104] As described above, the pouch-shaped battery cell according to the present invention is configured such that the uncoated portion is formed at the electrode assembly and the stepped portion is formed at the pouch-shaped battery case so as to correspond to the uncoated portion, whereby it is possible for a user to fold or unfold the pouch-shaped battery cell when in use.
[0105] In addition, since the electrode assembly and the inner surface of the pouch-shaped battery case are partially coupled to each other, it is possible to prevent movement of the electrode assembly in the pouch-shaped battery case, and therefore it is possible to improve safety of the pouch-shaped battery cell.
[0106] Those skilled in the art to which the present invention pertains will appreciate that various applications and modifications are possible within the category of the present invention based on the above description.
DESCRIPTION OF REFERENCE NUMERALS
[0107] 110, 310: Positive electrodes [0108] 111, 121, 211, 221, 311: Coated portions [0109] 112, 212, 312: Positive electrode tabs [0110] 113, 123, 213, 223, 313: Insulating members [0111] 115, 125, 215, 225, 315: Uncoated portions [0112] 120, 220: Negative electrodes [0113] 122, 222: Negative electrode tabs [0114] 431, 531, 631: First battery cases [0115] 432, 532, 632: Second battery cases [0116] 433, 533, 633: Receiving portions [0117] 436, 536, 636, 736, 836: Stepped portions [0118] 437, 537, 737, 837: Protruding portions [0119] 660: Notch
INDUSTRIAL APPLICABILITY
[0120] As is apparent from the above description, a pouch-shaped battery cell according to the present invention is configured to have a structure in which an uncoated portion, which is a portion coated with no electrode mixture, is formed at each of a positive electrode and a negative electrode, and an electrode assembly is folded at the uncoated portion, whereby it is possible to prevent separation of an electrode mixture layer from an electrode current collector as a result of folding.
[0121] In addition, a stepped portion having a recessed shape is formed at the portion of a pouch-shaped battery case corresponding to the uncoated portion of the electrode assembly, whereby it is possible to seat and fix a coated portion of the electrode assembly onto a protruding portion of the pouch-shaped battery case, which relatively protrudes.
[0122] Also, in the case in which the uncoated portion of the electrode assembly is attached to the stepped portion of the pouch-shaped battery case, it is possible to more securely fix the position of the electrode assembly. Consequently, it is possible to prevent separation of the electrode assembly, and therefore it is possible to prevent damage to electrode tabs and an electrode lead.