Method and apparatus for improving energy efficiency in existing gas turbine combined cycle plants
20230145545 · 2023-05-11
Inventors
Cpc classification
F02C6/18
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01K3/265
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C3/305
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01K23/103
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01K7/22
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C6/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02T50/60
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F05D2230/80
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E20/16
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
F02C6/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
Method and apparatus for improving the energy efficiency of existing gas turbine combined cycle plants in which a compressor pressurises air which is combusted with fuel in a combustion chamber, followed by a turbine and a high temperature heat exchanger and a low temperature heat exchanger. In the secondary circulation after the steam turbine II, steam is condensed in the condenser into water, which is pressurised to the maximum pressure by means of a pump and preheated in low temperature heat exchanger and vaporised in a high temperature heat exchanger. After the high temperature heat exchanger, steam enters the steam turbine wherefrom a tap is taken, if necessary, which is injected after preheating into the combustion chamber of the gas turbine process or at the latest the beginning of the vanes of the turbine. Before steam turbine II, the enthalpy of steam (and additional water) at below 1 atm is increased by means of the condensation heat of the water contained in the combustion gases, after which intermediate superheating is applied to the saturated Rankine circulation steam using the excess heat of the low temperature heat exchanger.
Claims
1. A method for improving the energy efficiency of existing gas turbine combined cycle plants, wherein the compressor pressurises the combustion air which is combusted with fuel in a combustion chamber, followed by a turbine and a high temperature heat exchanger, wherein feed water pressurised by a pump is vaporized, the pump being arranged after a secondary process steam turbine II followed by a condenser-heat exchanger, wherein condensing heat of the steam contained by the combustion gases in atmospheric pressure and formed in combustion is used for increasing the enthalpy of the process circulation steam at a pressure of less than 1 bar by 100 to 350 kJ/kg in constant temperature subsequent to a steam turbine at a low temperature heat exchanger, subsequent to which the excess heat of the low temperature heat exchanger is used, subsequent to the high temperature heat exchanger, for intermediate superheating of steam between the steam turbine and the steam turbine II.
2. A method for improving the energy efficiency of existing gas turbine combined cycle plants, wherein the compressor pressurises the combustion air which is combusted with fuel in a combustion chamber, followed by a turbine and a high temperature heat exchanger, wherein feed water pressurised by a pump is vaporized, the pump being arranged after a secondary process steam turbine II followed by a condenser-heat exchanger, wherein condensing heat of the steam contained by the combustion gases in 1 atm pressure and formed in combustion is used for increasing the enthalpy of the circulation steam of Rankine process at a pressure of less than 1 bar by 100 to 350 kJ/kg in constant temperature subsequent to a steam turbine at a low temperature heat exchanger and/or for vaporising the liquid additional water fed to the Rankine process circulation in a pressure below 1 bar that is combined with the main Rankine circulation only at a pressure below 1 bar, subsequent to which steam is superheated in the low temperature heat exchanger by using, subsequent to the high temperature heat exchanger, the heat of the combustion gases between the steam turbine and the steam turbine.
3. The method according to claim 2, wherein the tapped steam from the secondary process and introduced into the combustion chamber or the beginning of the turbine vanes or a portion of the mixture formed by the air mass flow from the compressor and the above-mentioned steam is preheated in the high temperature heat exchanger.
4. The method according to claim 2, wherein the gas turbine process comprises a second turbine and/or a second combustion chamber.
5. The method according to claim 2, wherein the high temperature heat exchanger or the low temperature heat exchanger is provided with an additional combustion at a pressure of 1 atm at least partially above the vaporisation temperature of the Rankine process, the combustion being utilized in the vaporisation of steam of the Rankine cycle, superheating or intermediate superheating.
6. The method according to claim 2, wherein the intercooling of the compressor is carried out with water injected into the compressor or with partially vaporised water or the intercooling is carried out by heat transfer in a heat exchanger.
7. The method according to claim 2, wherein the injection water is taken partially from the tap outlet of the steam turbine or from the feed water after the low temperature heat exchanger.
8. The method according to claim 2, wherein a steam turbine II having a maximum pressure of at least 3 bar is supplied with an additional mass flow of water at a pressure of less than 1 atmosphere as an intermediate supply.
9. The method according to claim 2, wherein the plant operates as a district heating/back-pressure plant by heating the district heating water in a single-phase or two phases using condensation heat of steam from the steam turbine in a condensing heat exchanger and with condensation heat of steam contained by the combustion gases at a low temperature heat exchanger, or a portion of the water of the district heating circuit is heated in the heat exchanger and the remainder in the condensing heat exchanger, after which the water circulations are combined in the mixing heat exchanger.
10. The method according to claim 2, wherein the low-temperature heat exchangers are parallel or connected together to form a single integrated heat exchanger.
11. The method according to claim 2, wherein the high temperature heat exchanger and the low temperature heat exchangers are connected together, forming a single waste heat boiler.
12. The method according to claim 2, wherein the amount of water in the secondary process circulation is kept constant, for example, by introducing additional water into the process circulation and removing the required amount of water from the Rankine process circulation.
13. The method according to claim 2, wherein the maximum pressure of steam turbine II is from 3 to 8 bar.
14. The method according to claim 2, wherein the steam from the Rankine process circulation is superheated without additional combustion by a temperature increase equal to 0 to 400 Kelvin by means of combustion gases from the gas turbine process before the steam turbine II.
15. The method according to claim 9, wherein intermediate superheating of Rankine steam in a heat exchanger is provided between the steam turbines.
16. An apparatus for improving the energy efficiency of existing gas turbine combined cycle plants, wherein the compressor pressurises the combustion air which is combusted with fuel in a combustion chamber, followed by a turbine and a high temperature heat exchanger, wherein feed water pressurised by a pump is vaporized, the pump being arranged after a secondary process steam turbine II followed by a condenser-heat exchanger, wherein condensing heat of the steam contained by the combustion gases in atmospheric pressure and formed in combustion is used for increasing the enthalpy of the process circulation steam at a pressure of less than 1 bar by 100 to 350 kJ/kg in constant temperature subsequent to a steam turbine at a low temperature heat exchanger, subsequent to which the excess heat of the low temperature heat exchanger is used, subsequent to the high temperature heat exchanger, for intermediate superheating of steam between the steam turbine and the steam turbine II.
17. An apparatus for improving the energy efficiency of existing gas turbine combined cycle plants, wherein the compressor pressurises the combustion air which is combusted with fuel in a combustion chamber, followed by a turbine and a high temperature heat exchanger, wherein feed water pressurised by a pump is vaporized, the pump being arranged after a secondary process steam turbine II followed by a condenser-heat exchanger, wherein condensing heat of the steam contained by the combustion gases in 1 atm pressure and formed in combustion is used for increasing the enthalpy of the circulation steam of Rankine process at a pressure of less than 1 bar by 100 to 350 kJ/kg in constant temperature subsequent to a steam turbine at a low temperature heat exchanger and/or for vaporising the liquid additional water fed to the Rankine process circulation in a pressure below 1 bar that is combined with the main Rankine circulation only at a pressure below 1 bar, subsequent to which steam is superheated in the low temperature heat exchanger by using, subsequent to the high temperature heat exchanger, the heat of the combustion gases between the steam turbine and the steam turbine II.
18. The apparatus according to claim 17, wherein the tapped steam from the secondary process and introduced into the combustion chamber or the beginning of the turbine vanes or a portion of the mixture formed by the air mass flow from the compressor and the above-mentioned steam is preheated in the high temperature heat exchanger.
19. The apparatus according to claim 17, wherein the gas turbine process comprises a second turbine and/or a second combustion chamber.
20. The apparatus according to claim 17, wherein the high temperature heat exchanger or the low temperature heat exchanger is provided with an additional combustion at a pressure of 1 atm at least partially above the vaporisation temperature of the Rankine process, the combustion being utilized in the vaporisation of steam of the Rankine cycle, superheating or intermediate superheating.
21. The apparatus according to claim 17, wherein the intercooling of the compressor is carried out with water injected into the compressor or with partially vaporised water or the intercooling is carried out by heat transfer in a heat exchanger.
22. The apparatus according to claim 17, wherein the injection water is taken partially from the tap outlet of the steam turbine or from the feed water after the low temperature heat exchanger.
23. The apparatus according to claim 17, wherein a steam turbine II having a maximum pressure of at least 3 bar is supplied with an additional mass flow of water at a pressure of less than 1 atmosphere as an intermediate supply.
24. The apparatus according to claim 17, wherein the plant operates as a district heating/back-pressure plant by heating the district heating water in a single-phase or two phases using condensation heat of steam from the steam turbine in a condensing heat exchanger and with condensation heat of steam contained by the combustion gases at a low temperature heat exchanger, or a portion of the water of the district heating circuit is heated in the heat exchanger and the remainder in the condensing heat exchanger after which the water circulations are combined in the mixing heat exchanger.
25. The apparatus according to claim 17, wherein the low-temperature heat exchangers are parallel or connected together to form a single integrated heat exchanger.
26. The apparatus according to claim 17, wherein the high temperature heat exchanger and the low temperature heat exchangers are connected together, forming a single waste heat boiler.
27. The apparatus according to claim 17, wherein the amount of water in the secondary process circulation is kept constant, for example, by introducing additional water into the process circulation and removing the required amount of water from the Rankine process circulation.
28. The apparatus according to claim 17, wherein the maximum pressure of steam turbine II is from 3 to 8 bar.
29. The apparatus according to claim 17, wherein the steam from the Rankine process circulation is superheated without additional combustion by a temperature increase equal to 0 to 400 Kelvin by means of combustion gases from the gas turbine process before the steam turbine II.
30. The apparatus according to claim 24, wherein intermediate superheating of Rankine steam in a heat exchanger is provided between the steam turbine.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0015]
[0016]
[0017]
[0018]
[0019]
[0020]
[0021]
and additionally intercooling of the compressor with preheated (and partially vaporised) water. The process also comprises two combustion chambers and two turbines in the gas turbine process.
[0022]
[0023]
[0024]
EMBODIMENTS
[0025] In the tables 1 and 2, the status points are shown with number plus the letter c (e.g. 1c) and the components without the letter c.
TABLE-US-00001 TABLE 1 h(N2) h)O2) h(CO2) h(H2O) p(bar) T(K) kJ/kg kJ/kg kJ/kg kJ/kg 1c 1.0 288.0 15.4 13.5 2c 29.0 792.5 554.8 509.8 3c 28.4 1767 1732.2 1598.4 1779.1 5935 4c 1.04 917.5 696.8 643 679 3804 5c 6 1649 1623.3 5615 7c 173.5 626 8c 0.7 1700 11c 177.0 313 130 13c 170.0 873 3560 14c 0.036 2609 15c 0.035 300 111 17c 1.0 330 59.1 52.1 48.2 238 20c 0.71 2438 26c 1.02 671 420.5 383.7 391.9 3279 30c 1.02 31c 1.0 330 34c 0.71
TABLE-US-00002 TABLE 2 h(N2) h)O2) h(CO2) h(H2O) p(bar) T(K) kJ/kg kJ/kg kJ/kg kJ/kg 1c 1.0 288.0 15.4 13.5 2c 24.0 751.8 509.4 467.1 3c 23.52 1767 1732.2 1598.4 1779.1 5935 4c 1.04 979.1 768.1 709.6 754.1 3943 7c 173.5 626 1700 8c 0.7 3170 11c 177.0 130 13c 170.0 873 3560 14c 170.0 2609 15c 0.035 300 111 17c 1.0 330 59.1 52.1 48.2 238 20c 0.71 2438 21c 1.02 26c 1.02 671 420.5 383.7 391.9 3279 27c 24.0 29c 1.02 30c 1.02 31c 1.0 330 32c 24.5 3026 33c 24.0 873 3686 34c 0.71
[0026]
[0027] In
[0028]
[0029] It should be noted that in
[0030]
[0031]
[0032]
[0033]
[0034]
[0035] Thus, the combustion gases flow from the second combustion chamber 21 to the second turbine 22. After this, the combustion gases (vaporise and) superheat feed water in the high temperature heat exchanger 12. The superheated steam exiting from it expands in the steam turbine 14a, b to a pressure less than 1 atm. The above-mentioned combustion gases pass from the high temperature heat exchanger 12 to the low temperature heat exchanger 15a,b and to a small branch to a heat exchanger 42 for preheating natural gas. Feed water from the post-condenser 10 pump 11 is heated in the low temperature heat exchanger 15a,b. From the pump 11, considered to be a two-stage one in the diagram, supplies additional water, if necessary, to the steam from the steam turbine 14a,b. If the pump 11 is a single-phase one, the water pressure must naturally be reduced by means of a valve. The above-mentioned mass flow of steam also goes to the low-temperature heat exchanger 15a,b. A branch is taken from the water preheated between the low-temperature heat exchanger 15a,b and the high-temperature heat exchanger 12 to the pressure reducing valve 57, wherein the water is partially vaporised and then introduced to between the above-mentioned compressor 1a and the compressor 1b. For the above-mentioned reason, the intermediate superheating in the low temperature heat exchanger 15a,b after the constant-temperature heating of steam can be reduced and in some versions the intermediate superheating can be (almost) non-existent. Because of this, the additional claims include limits for enthalpy and temperature with regard to the heat transfer in the heat exchanger mentioned above. Increasing enthalpy at a constant temperature before the intermediate superheating is naturally performed by means of the condensation heat of the steam contained by the combustion gas. From the low temperature heat exchanger 15a,b the steam is introduced into the steam turbine II 16 and thereafter to the condenser 10 at a pressure of less than 1 atm. If necessary, additional water is also fed into the process circulation.
[0036] It should be emphasised that the pre-cooling of the steam used for the intercooling of the compressor of the gas turbine process can also be taken, for example, by tapping the steam turbine and mixing it with additional water, if necessary, and by countless other means.
[0037] Intercooling of the compressor 1a,b shown in the figures could, of course, also be carried out in plants which do not have the inventive idea disclosed in this patent application, which differs from those in existing plants. In this case, excess heat, such as the waste heat from the oxygen compressor of an IGCC plant, is used to preheat the water injected into the compressor 1a, b. Thus that is an additional invention.
[0038] In
[0039]
[0040] Additional water can be taken between the two-stage pump or also from the main steam circulation before the vaporisation phase. In this case, the valve is used to reduce the pressure to a suitable level (such as 0.7 bar). If the heat exchanger 15b were separate, it would be advantageous to direct the combustion gases from it, for example, to the heat exchanger 15a. This case is disclosed in the claims of the CHP plant for the sake of clarity, but it also includes an integrated heat exchanger.
[0041]
[0042] The claim related to additional combustion relates to
[0043]
[0044] If pure oxygen is introduced to applications according to the invention, the power demand for its pressurisation is naturally lower if it is introduced to the second combustion chamber. It is sensible to take any additional air introduced to this combustion chamber from the compressor 1a,b by tapping. The air used for production of oxygen can also be taken from the tap of the compressor 1a,b. The compressor 1a,b naturally forms a single integrated compressor or is formed by two compressors. The additional air or oxygen can also be preheated in a waste heat boiler.
[0045] In the low-temperature part of the waste heat boiler (heat exchangers 15a,b), water is preheated and in the high-temperature part, water is vaporised and superheated. Intermediate superheating of steam also takes place in the low-temperature part. However, the additional combustion mentioned earlier also allows the use of the high temperature part for intermediate superheating, at least partly.
[0046] The invention has many advantages over existing installations. Naturally, the very high efficiency is the most significant advantage. Similarly, a smaller amount of expensive superheater materials is needed, because the intermediate superheating temperature and pressure are lower. The share of the gas turbine process of the total power is proportionally higher in CHP applications, which is important for competitiveness. Modern technology can also be applied to start-up and shut-down as well as to the shaft arrangement of compressors and turbines. The mass flow of water to the combustion chamber can naturally also be 100% of the mass flow of the steam turbine 14a,b.
[0047] Naturally, the expansion energy of natural gas and/or the cold energy generated by pressure decrease can be utilized, for example, for the cold cleaning/separation of the combustion gas, for production of oxygen or for the separation of carbon dioxide formed in combustion.
[0048] A thermal battery can also be connected to the process, if necessary. In some constructions, the additional water can also be introduced directly to point 35c (the place corresponding to point in
[0049] It should be noted that the pressure range is disclosed in the main claim as wide as possible, but in practice the range is around 0.5 to 0.8 bar, even 0.3 to 0.95 bar may be possible.
[0050] The embodiment examples of the invention have been described only to illustrate the invention, and they do not limit the scope of invention, because details such as water treatment and generator(s), which are not necessary for understanding the invention, have been omitted for the sake of clarity. Thus, the invention is not limited to the described embodiments, but it includes everything covered by the scope of the appended claims.