Wastewater treatment system and process
11643349 · 2023-05-09
Assignee
Inventors
Cpc classification
Y02W10/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C02F2203/006
CHEMISTRY; METALLURGY
C02F3/307
CHEMISTRY; METALLURGY
International classification
Abstract
A wastewater treatment system and a wastewater treatment process, fluidly combining a one or more SBR (sequencing batch reactor) module/s, in which nitrification and denitrification of the wastewater are performed in sequences and one or more MBR (membrane bioreactor) module/s.
Claims
1. A wastewater treating system, comprising: at least one sequencing batch reactor (SBR) module for a sequential nitrification and denitrification process, the at least one SBR module comprising a first tank and a second tank; and at least one membrane bioreactor (MBR) module, wherein the at least one SBR module and the at least one MBR module are fluidly connected, and wherein wastewater is fed from the sequential nitrification and denitrification process of the at least one SBR module to the at least one MBR module, wherein the at least one SBR module is further provided with openings connected to a wastewater inlet pipe, said wastewater inlet pipe and openings being arranged in an inlet provided with a control mechanism to control fed flow from the inlet to the openings, and where the openings are connected to the second tank and the first tank, respectively, wherein the first tank further is provided with a first weir interfacing with the at least one MBR module, which first weir is opened and closed by a first closing mechanism, and wherein the second tank is further provided with a second weir interfacing with the at least one MBR module, which second weir is opened and closed by a second closing mechanism, wherein the at least one MBR module includes at least two chambers, each chamber being provided with an opening facing the at least one SBR module and an outlet being in hydraulic connection with the at least two chambers and an outlet pipe extending from the outlet, and wherein in the at least one SBR module there is arranged an opening between the first tank and the second tank through which a flow equivalent to a feed flow is arranged to flow from a tank receiving the feed flow to a tank provided with a closed opening connected with an inlet housing during four phases of the sequential nitrification/denitrification process of a wastewater treatment process; and a MBR channel having a first wall between the MBR channel and the SBR module and a second wall between the MBR channel and MBR module.
2. The wastewater treatment system according to claim 1, wherein the MBR channel is arranged between the first tank and the second tank of the at least one SBR module and the at least two chambers of the at least one MBR module, being in hydraulic connection with outlets of the first tank and the second tank and inlets of the at least two chambers the at least one MBR module and being in hydraulic connection with the first tank and the second tank of the SBR module through the weirs.
3. The wastewater treatment system according to claim 2, further comprising a recyclization pipe which connects both the first tank and the second tank to the at least two chambers of the at least one MBR module.
4. The wastewater treatment system according to claim 1, further comprising a nitrogen or ammonia sensor in the first tank or the second tank.
5. The wastewater treatment system according to claim 1, wherein a number of MBR chambers within the at least one MBR module is more than five.
6. The wastewater treatment system according to claim 2, further comprising a nitrogen or ammonia sensor in the first tank or the second tank.
7. The wastewater treatment system according to claim 3, further comprising a nitrogen or ammonia sensor in the first tank or the second tank.
8. A wastewater treating system, comprising: a sequencing batch reactor (SBR) module for a sequential nitrification and denitrification process, the SBR module comprising a first tank and a second tank; an opening between the first tank and the second tank through which a flow is arranged to flow; a MBR channel having a first wall between the MBR channel and the SBR module, each of the first tank and the second tank having an inlet in the first wall communicating with the MBR channel; at least one membrane bioreactor (MBR) module, the MBR channel having a second wall between the MBR channel and the MBR module, wherein the first tank has a first weir interfacing with the MBR channel, the first weir opened and closed by a first closing mechanism, wherein the second tank has a second weir interfacing with the MBR channel, the second weir opened and closed by a second closing mechanism, and wherein the at least one MBR module includes at least one chamber, the at least one chamber being provided with an inlet in the second wall and an outlet being in hydraulic connection with an outlet pipe.
9. The wastewater treatment system according to claim 8, further comprising an inlet housing, the inlet housing having a pair of opening communication with the first tank and the second tank, respectively.
10. The wastewater treatment system according to claim 8, wherein the at least one chamber of the MBR module comprises three chambers, each of the three chambers having an inlet in the second wall.
11. The wastewater treatment system according to claim 2, wherein the outlets of the first tank and the second tank are in the first wall and the inlets of the at least two chambers of the at least one MBR module are in the second wall.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Further objects, features and advantages will appear from the following detailed description of several embodiments of the invention with reference to the drawings, in which:
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DETAILED DESCRIPTION OF INVENTION
(12) With reference to
(13) In phase-1, as shown in
(14)
(15)
(16)
(17) In
(18)
(19) It should be noted that phase3 is equivalent to phase-1, though with inverted tanks. This means that tank-A 2 in phase3 is equivalent to tank-B 3 in phase1 and tank-B 3 in phase3 is equivalent to tank-A 2 in phase1. Therefore
(20)
(21) Here it should be noted that phase-4 is equivalent to phase-2, though with inverted tanks. This means that tank-A 2 in phase-4 is equivalent to tank-B 3 in phase2 and tank-B 3 in phase-4 is equivalent to tank-A 2 in phase2. Therefore
(22)
(23) In the present invention, the calculation for the biological process for either SBR or MBR configuration will not be different from prior art biological process calculation. The activity of the biological bacteria in either SBR or MBR is not influenced by the design or configuration of wastewater treatment system. The amount of sludge (biological mixture of different strains of bacteria) necessary for nitrification, depends on sludge age and the temperature of the wastewater. The amount of sludge necessary for the denitrification process, depends on the chemical composition of the wastewater (including external carbon sources and total nitrogen) and the temperature of the wastewater.
(24) With the combined SBR/MBR system of the current invention, the need for a settle-phase (as demonstrated by phase 3 in
(25) One of the advantages of the present invention is the possibility of increasing the biomass concentration in the biological tanks from the prior art concentration of 4-5 g/I to concentration as high as 12 g/I. The increase of the biomass concentration will result in decrease in biological tank volume, and thereby saving of energy and space, compared to prior art SBR/MBR wastewater plant.
(26) Another advantage of the present invention over prior art SBR/MBR wastewater plants, is the steady level of wastewater within the MBR part of the system. In prior art wastewater plant with a separate MBR, the wastewater level within the MBR tank will vary considerable, resulting in an insufficient utilization of the tank volume and the biomass within the tank. A saving in the range of 20 to 30% in MBR tank volume can be expected with the new configuration, and thereby considerable saving of energy and space, compared to prior art SBR/MBR wastewater plant.
(27) Yet another advantage of the present invention over prior art SBR/MBR wastewater plants, is the direct and controllable hydraulic connection between the MBR tank to the SBR tanks. This hydraulic connection brings return sludge from the MBR tank(s) where aeration is taking place, only into the SBR tank(s) in nitrification, where the oxygen in the activated sludge can be utilized. This control of the activated return sludge and of dissolved oxygen, eliminates the need for the deoxidation tank for oxygen removal, that is needed in prior art. One further advantage of the control of the activated return sludge over prior art SBR/MBR wastewater plants, is the utilization of the oxygen in the activated return sludge from the MBR tank in the nitrification of the SBR tank. The activated return sludge has an oxygen content close to oxygen-saturation, and by controlling the return of the activated sludge so it enters only the SBR tanks in nitrification, the oxygen will be utilized during nitrification, resulting in energy savings as high as between 3 and 6%.
(28) By introduction of a sedimentation phase within phase-2, for increased sludge concentration, yet another advantage over prior art will be gained. The increased sludge concentration will allow for reduced sludge return from the MBR tank, thereby resulting in savings of energy and volume.
Definitions
(29) Activated sludge as used within this document, is a biological matter, comprising biomass of microorganism or floc, comprising mostly of bacteria and protozoa. Activated sludge, is used for removing organic matter from wastewater by a biological reaction involving oxygen. In biological tank oxygen will be added with aerators to overcome the need for biological degradation, endogenous respiration and nitrification.
(30) In MBR scouring air will be used to reduce fouling on membrane resulting in sludge saturation with oxygen. Oxygen saturated sludge will be returned to nitrification phase.
(31) Membrane bioreactor or MBR as referred to within this document, is a known modern wastewater treatment technology. It combines membrane separation technology and bioorganic wastewater treatment technology. MBR comprises activated sludge that is separated from any outlet by a membrane. Thereby, MBR separates the activated sludge and other biological or organic matter from the cleaned effluent coming out of the MBR. MBR process is called as a hybrid system, as it works with biological treatment in conjunction with separation.
(32) Sequencing batch reactor or SBR as referred to within this document is a known modern industrial wastewater treatment technology. The process within the SBR (sequencing batch reactor) is a fill and draw activated sludge process for nitrification. It is commonly used in wastewater treatment due to operational flexibility and process control possibilities. The wastewater enters partially filled SBR and once the reactor is full, it behaves like a conventional activated sludge system, but without continuous influent or effluent flow. For further details of the chemical reaction and traditional stages/phases of SBR see above in this document.
(33) Sludge as referred to within this document is a residual, semi-solid material that is produced as a by-product during sewage treatment of industrial or municipal wastewater.
(34) Wastewater or sewage as referred to within this document is any water that has been affected by human use. Wastewater is “used water from any combination of domestic, industrial, commercial or agricultural activities, surface runoff or storm-water, and any sewer inflow or sewer infiltration”. [1] Therefore, wastewater is a byproduct of domestic, industrial, commercial or agricultural activities. The characteristics of wastewater vary depending on the source. Types of wastewater include: domestic wastewater from households, municipal wastewater from communities (also called sewage) or industrial wastewater from industrial activities. Wastewater can contain physical, chemical and biological pollutants that will vary depending on the source of the wastewater.
(35) Influent as referred to within this document is the flow in. That is the pre-treated wastewater that is flowing to the wastewater treatment system of the present invention.
(36) Effluent as referred to within this document is the flow out, or the treated wastewater from the wastewater treatment system of the present invention that has been treated and is flowing out of the system.
(37) Wastewater treatment as referred to within this document is the process of removing contaminants from wastewater. Physical, chemical, and biological processes are used to remove contaminants and produce treated wastewater or an effluent (outflowing of water to a receiving body of water) that can be returned to the water cycle with minimal impact on the environment.
(38) Nitrification process as referred to within this document is a biological process, where microorganism oxidize ammonium ions to nitrate (as explained above in this document).
(39) Denitrification process as referred to within this document is a microbial facilitated process where nitrate is reduced and ultimately produces molecular nitrogen (N.sub.2) (as explained above in this document).
(40) Biological volume as referred to within this document is the part of the wastewater treatment plant, wherein biological processes take pace.
(41) DO-phase or double-phase, as referred to within this document is a phase sometimes also referred to as Simultaneous nitrification—denitrification (SNdN). It is a phase within a bioreactor (such as SBR) where microbial nitrification and denitrification takes place parallel and simultaneously within same container/bioreactor or tank.
(42) Sedimentation phase as referred to within this document is a process where gravity is used to concentrate biological matter and other suspended solids from the wastewater, so they will accumulate at the bottom the container/tank.
Example 1
(43) Example 1, discloses the calculation for wastewater treatment plant, utilizing the present invention.
(44) Dimensions
(45) Table 1 and 2 below list the flow through the wastewater treatment plant of the example. The amount of wastewater flowing into the plant are shown in table 1, that furthermore discloses the variation in flow, and the average/total amount of different pollutants.
(46) TABLE-US-00001 TABLE 1 Parameter Unit Value Daily flow m3/day 3300 Dimensioning flow m3/h 160 Max MBR flow m3/h 240 Max flow biology m3/h 320 Max flow screen m3/h 640 BOD.sub.7 mg/l 122 COD mg/l 240 Tot P mg/l 3 Tot N mg/l 37 SS mg/l 150 BOD.sub.7 Kg/d 400 Tot P Kg/d 10 Tot N Kg/d 125 SS Kg/d 495
(47) Comparable, the amount of treated wastewater, or effluent flowing from the plant after treatment in the system of the current invention is shown in table 2, below.
(48) TABLE-US-00002 TABLE 2 Treatment Target Parameter Unit level treatment BOD.sub.7 mg/l 10 <8 Tot N mg/l 15 <10 NH.sub.4—N mg/l — <2 Tot P mg/l 0.3 <0.2
(49) Calculations:
(50) Daily Sludge Production:
(51) The daily sludge production can be calculated by converting BOD.sub.7 to BOD.sub.5
400×0.85=340 kg/d
(495×0.5)+(340×0.4)×1.0=421 kg/day
(52) Calculation of the necessary sludge needed for efficient nitrification is giving following figures:
(53) At 10 degrees Celsius:
10.14 days (421×10.14)=4.269 kg
(54) At 7 degrees Celsius:
16.8 days (421×16.8)=7072.8 kg
(55) Necessary sludge amount needed for denitrification:
(56) The necessary sludge needed for denitrification can also be calculated. The amount sludge needed will depend on the amount of nitrate that will have to be denitrified, that in return depends on the total amount of N flowing into the wastewater treatment plant and acceptable levels of N in the effluent of the wastewater treatment plant:
Total N to be denitrified=(Total N in)−(total N out)−(total N in sludge).
Total N 125 kg/d−Total N outlet 26 kg/d (based on 8 mg/I)−Total N in sludge 18 kg/d=Total N to denitrify: 81 kg/d (here 90 kg/d will be used for safety reason).
(57) Denitrification Rate:
(58) Using the results from the calculation above, the denitrification rate for the wastewater within the wastewater treatment plant will be:
(59) At 10 degrees Celsius:
(60) Standard denitrification rate of municipal wastewater at 10 degrees Celsius=1.5 g N/kg MLVSS×h.
(61) At 7 degrees Celsius:
(62) Standard denitrification rate of municipal wastewater at 10 degrees Celsius=1.5 g N/kg MLVSS×h.
(63) For getting the standard denitrification rate at 7 degrees Celsius, the value for 10 degrees Celsius is converted to lover temperature=1.5×1.112.sup.(6-10). This gives the dentification rate at 7 degrees Celsius=1.09 g N/kg MLVSS×h.
(64) Total amount of sludge needed in wastewater plant:
(65) Again, utilizing the values in the calculations shown above, the total amount of sludge needed in the wastewater plant can be calculated.
(66) At 10 degrees Celsius:
(67) N Sludge 4.269 kg
(68) DN Sludge 4000 kg
(69) Total: 8.269 kg
(70) At 7 degrees Celsius:
(71) N sludge 7.072.8 kg
(72) DN sludge 4.615 kg
(73) Total: 11.688 kg
(74) Therefore, the necessary volume for biological treatment with a sludge concentration of 8 gr/I will be 1.033 m3 at 10 degrees Celsius.
(75) For safety reason the design will be made with a total biological volume of 1.200 m.sup.3. This is enough biological volume to remove N at temperature as low as 7° C. (1200 m3 at 9.74 gr/I; that will give 11.688 kg sludge).
(76) MBR volume of the wastewater treatment plant of this example is 360 m.sup.3. If we consider that 1/3 of volume can be considered as biological volume we have at disposition 120 m.sup.3 more than a traditional wastewater treatment plant with separate MBR and SBR systems.
(77) Here in this example, a design with a total biological volume of 1.200 m.sup.3 will be used. This is enough biological volume to remove N at temperature as low as 7° C. (1200 m3 at 9.74 gr/I; that will give 11.688 kg sludge).
(78) As illustrated above, the additional biological volume resulting from the combined MBR/SBR system of the current invention, will give 10% extra capacity within the plant.
(79) This additional capacity can be utilized for introduction sedimentation in the SBR tank. This would increase the sludge concentration in the bottom of the SBR tank, resulting in a higher sludge concentration in the tank and a decrease in recirculation rate of the return sludge. Another alternative is to reduce the total biological volume (SBR and MBR tanks) by 120 m.sup.3 (in a plant with the dimensions of this example). This means 10% savings in total biological volume.
Embodiments
(80) The current invention, as explained in reference to the drawings is only one possible embodiment.
(81) In one embodiment of the invention, a sedimentation phase is included within phase2 of the system. In another embodiment of the present invention, a sedimentation phase is included within phase2 of the system, resulting in a higher sludge concentration. In yet another embodiment of the present invention, a sedimentation phase is included within phase2 of the system, resulting in a higher sludge concentration and a decrease in return sludge flow from the SBR part of the system to the MBR part of the system.
(82) In one embodiment of the invention, a sedimentation phase is included within phase-4 of the system. In another embodiment of the present invention, a sedimentation phase is included within phase-4 of the system, resulting in a higher sludge concentration. In yet another embodiment of the present invention, a sedimentation phase is included within phase-4 of the system, resulting in a higher sludge concentration and a decrease in return sludge flow from the SBR part of the system to the MBR part of the system. In one embodiment of the invention, a sedimentation phase is included within phase2 and phase-4 of the system. In another embodiment of the present invention, a sedimentation phase is included within phase2 and phase-4 of the system, resulting in a higher sludge concentration.
(83) In one embodiment of the invention, a sedimentation phase is included within phase2 and/or phase-4 of the system. In another embodiment of the present invention, a sedimentation phase is included within phase2 and/or phase-4 of the system, resulting in a higher sludge concentration. In yet another embodiment of the present invention, a sedimentation phase is included within phase2 and/or phase-4 of the system, resulting in a higher sludge concentration and a decrease in return sludge flow from the SBR part of the system to the MBR part of the system.
(84) In one embodiment of the invention, a sedimentation phase is included within either phase2 and/or phase-4 of the system. In another embodiment of the present invention, a sedimentation phase is included within either phase2 and/or phase-4 of the system, resulting in a higher sludge concentration. In yet another embodiment of the present invention, a sedimentation phase is included within either phase2 and/or phase-4 of the system, resulting in a higher sludge concentration and a decrease in return sludge flow from the SBR part of the system to the MBR part of the system.
(85) The number of SBR and/or MBR tanks and/or number of membrane modules (MBR modules) within each MBR tank can vary within the combined MBR/SBR system of the present invention.
(86) In one embodiment of the invention the combined MBR/SBR system comprises three SBR tanks. In another embodiment of the invention the combined MBR/SBR system comprises four SBR tanks. In yet another embodiment of the invention the combined MBR/SBR system comprises five or more SBR tanks.
(87) In one embodiment of the invention the combined SBR/MBR system comprises one MBR tank. In another embodiment of the invention the combined SBR/MBR system comprises two MBR tanks. In yet another embodiment of the invention the combined SBR/MBR system comprises four MBR tanks. In one embodiment of the invention the combined SBR/MBR system comprises five or more MBR tanks.
(88) In one embodiment of the invention the combined SBR/MBR system each MBR tank comprises one MBR module. In another embodiment of the invention the combined SBR/MBR system each MBR tank comprises two MBR modules. In yet another embodiment of the invention the combined SBR/MBR system, each MBR tank comprises three MBR modules. In one embodiment of the invention the combined SBR/MBR system, each MBR tank comprises four MBR modules. In another embodiment of the invention the combined SBR/MBR system, each MBR tank comprises five or more MBR modules.
(89) In one embodiment of the present invention, the combined MBR/SBR system comprises two SBR tanks combined with one MBR tank comprising 3 MBR modules within one tank (as disclosed in
(90) In one embodiment of the present invention, the combined SBR/MBR system comprises two SBR tanks combined with one MBR tank comprising one MBR module. In another embodiment of the present invention, the combined SBR/MBR system comprises two SBR tanks combined with one MBR tank comprising two MBR modules. In yet another embodiment of the present invention, the combined SBR/MBR system comprises two SBR tanks combined with one MBR tank comprising four MBR modules. In one embodiment of the present invention, the combined SBR/MBR system comprises two SBR tanks combined with one MBR tank comprising five or more MBR modules.
(91) The combined SBR/MBR system of the present invention can be automatically controlled, using nitrogen and/or ammonia sensor in tank-A 2 and/or tank-B 3.
(92) In one embodiment of the present invention, the combined SBR/MBR system comprises a nitrogen sensor in tank-A 2 of the system. In another embodiment of the present invention, the combined SBR/MBR system comprises a nitrogen sensor in tank-A 2 and tank-B 3 of the system. In yet another embodiment of the present invention, the combined SBR/MBR system comprises a nitrogen sensor in tank-B 3 of the system.
(93) In one embodiment of the present invention, the combined SBR/MBR system comprises an ammonia/ammonium sensor in tank-A 2 of the system. In another embodiment of the present invention, the combined SBR/MBR system comprises an ammonia/ammonium sensor in tank-A 2 and tank-B 3 of the system. In yet another embodiment of the present invention, the combined SBR/MBR system comprises an ammonia/ammonium sensor in tank-B 3 of the system.
(94) In one embodiment of the present invention, the combined SBR/MBR system comprises an ammonia/ammonium sensor and a nitrogen sensor in tank-A 2 of the system. In one embodiment of the present invention, the combined SBR/MBR system comprises an ammonia/ammonium sensor and a nitrogen sensor in tank-B 3 of the system.
(95) In another embodiment of the present invention, the combined SBR/MBR system comprises an ammonia/ammonium sensor in tank-A 2 and a nitrogen sensor in tank-B 3 of the system. In another embodiment of the present invention, the combined SBR/MBR system comprises an ammonia/ammonium sensor in tank-B 3 and a nitrogen sensor in tank-A 2 of the system.
(96) The invention is not limited to the embodiments described above and shown on the drawings, but can be supplemented and modified in any manner within the scope of the invention as defined by the enclosed claims.