SEPARATOR PLATE WITH A BEAD PASSAGE
20230155142 · 2023-05-18
Inventors
Cpc classification
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/0258
ELECTRICITY
International classification
Abstract
The present disclosure relates to a separator plate for an electrochemical system. The electrochemical system may be, for example, a fuel cell system, an electrochemical compressor, or an electrolyzer.
Claims
1. A separator plate for an electrochemical system, comprising a first individual plate and a second individual plate, which are connected to each other, wherein at least the first individual plate comprises: an electrochemically active region, at least one through-opening for the passage of a fluid, having an inner edge that bounds the through-opening, a sealing bead arranged around the through-opening for sealing off the through-opening, wherein the sealing bead has a sealing bead interior, a first bead flank facing towards the through-opening, and a second bead flank a plurality of first conveying channels, which adjoin the first bead flank of the sealing bead, are in fluid connection with the sealing bead interior, extend from the sealing bead in the direction of the through-opening, and are fluidically connected to the through-opening via at least one first aperture formed in the separator plate, wherein the through-opening and the sealing bead interior are fluidically connected to each other via the first conveying channels and the at least one first aperture, and a first weld, surrounding the through-opening, for connecting the two individual plates, wherein the first weld is at a smaller distance from the inner edge than the at least one aperture and/or the first conveying channels.
2. The separator plate according to claim 1, further comprising a second weld for connecting the individual plates, said second weld arranged around the sealing bead on a side of the sealing bead remote from the through-opening.
3. The separator plate according to claim 2, wherein the first weld and/or the second weld are continuous welds or stitch welds.
4. The separator plate according to claim 1, further comprising a first auxiliary bead having a first auxiliary bead interior, a first bead flank facing towards the through-opening, and a second bead flank facing towards the sealing bead, wherein the first conveying channels adjoin the second bead flank of the first auxiliary bead and are in fluid connection with the first auxiliary bead interior.
5. The separator plate according to claim 4, wherein a maximum height of the first auxiliary bead, determined perpendicular to a flat surface plane of the separator plate, is smaller than a corresponding maximum height of the sealing bead.
6. The separator plate according to claim 4, wherein the first auxiliary bead extends all the way around the through-opening, or wherein the first auxiliary bead is provided only in a region in which the first conveying channels are arranged.
7. The separator plate according to claim 4, wherein the first auxiliary bead and the inner edge of the through-opening extend at least in part parallel to each other.
8. The separator plate according to claim 1, comprising a plurality of second conveying channels, which adjoin the second bead flank of the sealing bead and are in fluid connection with the sealing bead interior, wherein the electrochemically active region and the sealing bead interior are fluidically connected to each other via the second conveying channels.
9. The separator plate according to claim 8, wherein the second conveying channels are fluidically connected to the electrochemically active region via at least one second aperture formed in the separator plate.
10. The separator plate according to claim 8, comprising a second auxiliary bead having a second auxiliary bead interior, a first bead flank facing towards the sealing bead, and a second bead flank facing away from the sealing bead, wherein the second conveying channels adjoin the first bead flank of the second auxiliary bead and are in fluid connection with the second auxiliary bead interior.
Description
BRIEF DESCRIPTION OF THE FIGURES
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DETAILED DESCRIPTION
[0059] Here and below, features that recur in different figures are denoted by the same or similar reference signs in each case.
[0060]
[0061] In alternative embodiments, the system 1 may also be designed as an electrolyzer, as an electrochemical compressor, or as a redox flow battery. Separator plates may likewise be used in these electrochemical systems. The structure of these separator plates may then correspond to the structure of the separator plates 2 explained in detail here, although the media guided on and/or through the separator plates in the case of an electrolyzer, an electrochemical compressor or a redox flow battery may differ in each case from the media used for a fuel cell system.
[0062] The z-axis 7, together with an x-axis 8 and a y-axis 9, spans a right-handed Cartesian coordinate system. The separator plates 2 each define a plate plane, each of the plate planes of the separator plates being oriented parallel to the x-y plane and thus perpendicular to the stacking direction or to the z-axis 7. The end plate 4 usually has a plurality of media ports 5, via which media can be fed to the system 1 and via which media can be discharged from the system 1. Said media that can be fed to the system 1 and discharged from the system 1 may comprise for example fuels such as molecular hydrogen or methanol, reaction gases such as air or oxygen, reaction products such as water vapor or depleted fuels, or coolants such as water and/or glycol.
[0063] Both known separator plates, as shown in
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[0065] The individual plates 2a, 2b typically have through-openings, which are aligned with one another and form through-openings 11a-c of the separator plate 2. When a plurality of separator plates of the same type as the separator plate 2 are stacked, the through-openings 11a-c form lines which extend through the stack 6 in the stacking direction 7 (see
[0066] In order to seal off the through-openings 11a-c with respect to the interior of the stack 6 and with respect to the surrounding environment, the first individual plates 2a may each have sealing arrangements in the form of sealing beads 12a-c, which are in each case arranged around the through-openings 11a-c and in each case completely surround the through-openings 11a-c. On the rear side of the separator plates 2, facing away from the viewer of
[0067] In an electrochemically active region 18, the first individual plates 2a have, on the front side thereof facing towards the viewer of
[0068] The sealing beads 12a-12c have conveying channels 13a-13c, of which the conveying channels 13a are formed both on the underside of the upper individual plate 2a and on the upper side of the lower individual plate 2b, while the conveying channels 13b are formed in the upper individual plate 2a and the conveying channels 13c are formed in the lower individual plate 2b. By way of example, the conveying channels 13a enable coolant to pass between the through-opening 12a and the distribution and/or collection region 20, so that the coolant enters the distribution and/or collection region 20 between the individual plates 2a, 2b and is guided out therefrom.
[0069] Furthermore, the conveying channels 13b enable hydrogen to pass between the through-opening 12b and the distribution or collection region on the upper side of the upper individual plate 2a; these conveying channels 13b adjoin apertures which face towards the distribution or collection region and which extend at an angle to the plate plane. Hydrogen, for example, thus flows through the conveying channels 13b and the apertures from the through-opening 12b to the distribution or collection region on the upper side of the upper individual plate 2a, or in the opposite direction. The conveying channels 13c enable air, for example, to pass between the through-opening 12c and the distribution or collection region, so that air enters the distribution or collection region on the underside of the lower individual plate 2b and is guided out therefrom. The associated apertures are not visible here.
[0070] The first individual plates 2a each also have a further sealing arrangement in the form of a perimeter bead 12d, which extends around the flow field 17 of the active region 18 and also around the distribution and/or collection region 20 and the through-openings 11b, 11c and seals these off with respect to the through-openings 11a, that is to say with respect to the coolant circuit, and with respect to the environment surrounding the system 1. The second individual plates 2b each comprise corresponding perimeter beads 12d. The structures of the active region 18, the distributing or collecting structures of the distribution and/or collection region 20 and the sealing beads 12a-d are each formed in one piece with the individual plates 2a and are integrally formed in the individual plates 2a, for example in an embossing, hydroforming or deep-drawing process. The same applies to the corresponding distributing structures and sealing beads of the second individual plates 2b. Each sealing bead 12a-12d may have in cross-section at least one bead top and two bead flanks, but a substantially angular arrangement between these elements is not necessary; a curved transition may also be provided, e.g. arcuate beads are also possible.
[0071] While the sealing beads 12a-12c have a substantially round course, the perimeter bead 12d has various sections that are shaped differently. For instance, the course of the perimeter bead 12d may include at least two wavy sections.
[0072] The two through-openings 11b or the lines through the plate stack of the system 1 that are formed by the through-openings 11b are in each case in fluid connection with each other via conveying channels 13b in the sealing beads 12b, via the distributing structures of the distribution or collection region 20 and via the flow field 17 in the active region 18 of the first individual plates 2a facing towards the viewer of
[0073] In contrast, the through-openings 11a or the lines through the plate stack of the system 1 that are formed by the through-openings 11a are in each case in fluid connection with each other via a cavity 19 which is surrounded or enclosed by the individual plates 2a, 2b. This cavity 19 serves in each case to guide a coolant through the bipolar plate 2, such as for cooling the electrochemically active region 18 of the separator plate 2. The coolant thus serves primarily to cool the electrochemically active region 18 of the separator plate 2. The coolant flows through the cavity 19 from an inlet opening 11a towards an outlet opening 11a. Mixtures of water and antifreeze are often used as coolants. However, other coolants are also conceivable. For guidance of the coolant or cooling medium, channel structures are present on the inner side of the separator plate 2. These are not visible in
[0074] While
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[0078] The through-opening 11 of the separator plate 2 is formed by aligned or at least partially overlapping through-openings of the two individual plates 2a, 2b. The through-openings of the individual plates 2a, 2b each have embossed inner edges 16 around the circumference, which point away from each other and are spaced apart from each other. An inlet and/or outlet of a conveying channel 26, which points towards the through-opening 11, is formed on the embossed inner edge 16 of the through-opening, the conveying channel 26 and the embossed inner edge 16 having an equal height, measured perpendicular to a flat surface plane (plate plane) of the separator plate 2.
[0079] These embossed inner edges 16, or more specifically the embossed regions that directly adjoin the inner edges 16, are on the one hand advantageous with regard to forming the conveying channels 26 and punching out or cutting the through-openings 11 in one plane. On the other hand, however, the spaced-apart inner edges 16 pose a risk of short-circuits, for instance when the individual plates 2a, 2b diverge even further from each other due to the compression force on the sealing bead 12 in the stack 6 and the associated lever effect on the inner edge 16, as a result of which adjacent separator plates 2 may damage or destroy the reinforcing edge (not shown here) of the MEA and in the worst case may make contact with each other through the resulting openings and thus may form a short-circuit. It can therefore be seen from the diagram in
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[0081] The present disclosure has been designed to solve the problems mentioned above. Various embodiments of the separator plate 2 according to the present disclosure are shown in
[0082] The separator plates 2 of the embodiments in
[0083] In order to convey the corresponding fluid from the through-opening 11, through the bead 12, to the electrochemically active region 18, or from the electrochemically active region 18, through the bead 12, to the through-opening 11, a group 25 of bead passages 25′ is provided. To this end, a plurality of first conveying channels 26 are provided, which adjoin the first bead flank 32 of the sealing bead 12. The first conveying channels 26 are in fluid connection with the sealing bead interior 31, extend from the sealing bead 12 in the direction of the through-opening 11, and are fluidically connected to the through-opening 11 via at least one first aperture 30 formed in the separator plate 2. The through-opening 11 and the sealing bead interior 31 are therefore fluidically connected to each other via the first conveying channels 26 and the at least one first aperture 30. It may be provided that the number of first apertures 30 is equal to the number of first conveying channels 26.
[0084] The individual plates 2a, 2b are connected to each other in a materially bonded manner via a first weld 36, wherein the first weld 36 may be designed as a laser weld. The first weld 36 surrounds the through-opening 11 and ensures that the individual plates bear against each other in the edge region of the through-opening 11 and can no longer diverge from each other there.
[0085] The first weld 36 is at a smaller distance from the inner edge 16 than the at least one aperture 30 and/or the first conveying channels 26. The respective distance of one element from the next element will be understood here as the smallest distance between the elements. The circumferential first weld 36 is arranged between the inner edge 16 and the aperture 30 and/or the first conveying channels 26 and extends between them.
[0086] The individual plates 2a, 2b of the separator plate 2 may be connected to each other in a materially bonded manner at various other points. For example,
[0087] Depending on requirements, the first weld 36 and/or the second weld may be designed as continuous welds or as stitch welds. For instance, the first weld 36 is designed as a stitch weld in
[0088] In many embodiments, a plurality of second conveying channels 27 are provided, which adjoin the second bead flank 33 of the sealing bead 12 and are in fluid connection with the sealing bead interior 31. The electrochemically active region 18 and the sealing bead interior 31 are fluidically connected to each other via the second conveying channels 27. It should be noted here that the above-mentioned distribution and/or collection region 20 may optionally still be arranged between the electrochemically active region 18 and the second conveying channels 27. In this case, the fluid connection between the electrochemically active region 18 and the sealing bead interior 31 comprises of the second conveying channels 27 and the distribution and/or collection region 20. Additional connecting sections may sometimes also be provided in the fluid connection.
[0089] In some embodiments, the second conveying channels 27 are fluidically connected to the electrochemically active region 18 via at least one second aperture 35 formed in the separator plate 2. Embodiments of through-opening 11 are designed as a through-opening 11b, 11c for reaction media, such as reaction gas. The at least one second aperture 35 is, or the second apertures 35 are, for instance formed in the same individual plate 2a, 2b as the second conveying channels 27. It may be provided that the number of second apertures 35 is equal to the number of second conveying channels 27.
[0090] The first and/or second apertures 30, 35 may be designed as cutouts and/or punched holes and can accordingly be formed by cutting and/or punching the plate 2 or the individual plates 2a, 2b.
[0091] In the embodiments of
[0092] The first auxiliary bead 40 usually has a first auxiliary bead interior 41, a first bead flank 42 facing towards the through-opening 11, and a second bead flank 43 facing towards the sealing bead 12, wherein the first conveying channels 26 adjoin the second bead flank 43 of the first auxiliary bead 40 and are in fluid connection with the first auxiliary bead interior 41. The first conveying channels 26 extend from the first auxiliary bead 40 to the sealing bead 12, more specifically from the second bead flank 43 of the first auxiliary bead 40 to the first bead flank 32 of the sealing bead 12. The bead flanks 42, 43 are connected to each other by a bead top 44. In addition, the first auxiliary bead 40 is designed as a full bead.
[0093] A maximum height of the first auxiliary bead 40, determined perpendicular to a flat surface plane of the separator plate 2, is typically smaller than a corresponding maximum height of the sealing bead 12. Unlike the sealing bead 12, the first auxiliary bead 40 is usually not compressed in the compressed state of the separator plate 2.
[0094] In some embodiments, the first auxiliary bead 40 extends all the way around the through-opening 11. In other embodiments, the first auxiliary bead 40 is provided only in a region where the first conveying channels 26 are provided, cf.
[0095] The second auxiliary bead 50 usually comprises a second auxiliary bead interior 51, a first bead flank 52 facing towards the sealing bead 12, and a second bead flank 53 facing away from the sealing bead 12, wherein the second conveying channels 27 adjoin the first bead flank 52 of the second auxiliary bead 50 and are in fluid connection with the second auxiliary bead interior 51. The second conveying channels 27 extend from the second auxiliary bead 50 to the sealing bead 12, more specifically from the first bead flank 52 of the second auxiliary bead 50 to the second bead flank 33 of the sealing bead 12. The bead flanks 52, 53 are connected to each other by a bead top 54. In addition, the second auxiliary bead 50 is designed as a full bead.
[0096] A maximum height of the second auxiliary bead 50, determined perpendicular to a flat surface plane of the separator plate 2, is typically smaller than a corresponding maximum height of the sealing bead 12. Unlike the sealing bead 12, the first auxiliary bead 50 is usually not compressed in the compressed state of the separator plate 2.
[0097] Embodiments of second auxiliary bead 50 are usually provided only in a region in which the second conveying channels 27 are arranged, cf.
[0098] Uniformity of the area surrounding the sealing bead 12 increases the possibility that the compression force on the sealing bead 12 and the area around the latter in the stack 6 is as homogeneous as possible. For this reason, it is advantageous if both the first auxiliary bead and the second auxiliary bead 50 are provided. For the same reason, the two auxiliary beads 40, 50 may have the same height. In addition, the auxiliary beads 40, 50 and their associated conveying channels 26, 27 may have the same height, measured perpendicular to a plate plane of the separator plate 2. On the other hand, it is also possible for the heights of, for example, the auxiliary beads 40, 50 and optionally also the conveying channels 26, 27 on both sides of the sealing bead to be different, so as to optimize the relative compression; by way of example, the auxiliary bead 40 may have a height that lies between the height of the auxiliary bead 50 and the height of the sealing bead 12. The adjoining conveying channels can in this case be set to the height of the adjacent auxiliary bead or may have the same height as each other.
[0099] In the embodiments in which the two auxiliary beads 40, 50 are provided, the inlets and outlets of the conveying channels 26, 27 are located in the bead flanks 43, 52 of the auxiliary beads 40, 50 and are therefore spaced apart from the apertures 30, 35.
[0100] The auxiliary beads 40, 50 optionally extend parallel to each other. Furthermore, the first auxiliary bead 40, the second auxiliary bead 50, the inner edge 16 of the through-opening 11 and/or a main direction of extension of the sealing bead 12 may extend at least in part in a parallel manner. The conveying channels 26, 27 are optionally oriented at an angle to the first weld 36, to the second weld 38, to the first auxiliary bead 40, to the second auxiliary bead 50 and/or to the main direction of extension of the sealing bead 12, such as at an angle of at least 60° and/or at most 120°, for instance around 90°. The selected angle may depend on the space available.
[0101] The sealing bead 12, the conveying channels 26, 27 and the auxiliary beads 40, 50 are usually integrally formed in the respective individual plate 2a, 2b, for example by embossing, hydroforming or deep-drawing. The sealing bead 12, the conveying channels 26, 27 and the auxiliary beads 40, 50 are thus an integral part of the respective separator plate 2a, 2b.
[0102] The through-opening 11 may have different shapes, for example square with rounded corners (
[0103] In the embodiments of
[0104] The group 25 of bead passages 25′ in
[0105] The first apertures 30 of the separator plates of
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[0107] The separator plate 2 of
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[0109] It will be appreciated that the configurations and routines disclosed herein are exemplary in nature, and that these specific embodiments are not to be considered in a limiting sense, because numerous variations are possible. Moreover, unless explicitly stated to the contrary, the terms “first,” “second,” “third,” and the like are not intended to denote any order, position, quantity, or importance, but rather are used merely as labels to distinguish one element from another. The subject matter of the present disclosure includes all novel and non-obvious combinations and sub-combinations of the various systems and configurations, and other features, functions, and/or properties disclosed herein.
[0110] As used herein, the term “approximately” or “substantially” is construed to mean plus or minus five percent of the range unless otherwise specified.
[0111] The following claims particularly point out certain combinations and sub-combinations regarded as novel and non-obvious. These claims may refer to “an” element or “a first” element or the equivalent thereof. Such claims should be understood to include incorporation of one or more such elements, neither requiring nor excluding two or more such elements. Other combinations and sub-combinations of the disclosed features, functions, elements, and/or properties may be claimed through amendment of the present claims or through presentation of new claims in this or a related application. Such claims, whether broader, narrower, equal, or different in scope to the original claims, also are regarded as included within the subject matter of the present disclosure.