Use of phosphorus containing herbicides as desiccant for plants of the genus <i>Saccharum</i>

Abstract

The invention primarily relates to the use of phosphorus containing herbicidal active ingredients (herbicides) as desiccant for (parts of) plants of the genus Saccharum, and to corresponding methods for desiccation, i.e. for the desiccating treatment. In another aspect the present invention relates to a method for increasing the amount of saccharose (sucrose) obtainable from (aerial parts of) plants of the genus Saccharum officinarum, and to a method for producing saccharose from (aerial parts of) plants of the genus Saccharum officinarum.

Claims

1. A method for desiccating treatment of one or more plants of the genus Saccharum, comprising treatment of applying to said plants an effective amount of a composition comprising a phosphorus containing herbicidal active ingredient selected from the group consisting of glufosinate and salts thereof, to thereby have a drying out effect on the plant, wherein the treatment of the plants of the genus Saccharum is done at a growth height of 200 cm or more, wherein the plants are selected from the group consisting of Saccharum officinarum and of hybrids of Saccharum officinarum, wherein at least 54% of the leaves of the plants are desiccated, wherein the treatment is carried out at a growth stage of later than BBCH 35, and wherein the phosphorus containing herbicidal active ingredient is applied in a total amount in a range of from 800 to 1000 g/ha.

2. The method according to claim 1, wherein the phosphorus containing herbicidal active ingredient is glufosinate-ammonium.

3. The method according to claim 1, wherein the treatment is a foliar application.

4. The method according to claim 1, wherein a total amount of sucrose obtainable from a plant of the genus Saccharum officinarum and/or hybrids thereof is increased.

5. A method according to claim 1, comprising after the treatment (i): (ii) harvesting sucrose containing plant material comprising or consisting essentially of stalks, (iii) obtaining sucrose from the plant material resulting from (ii).

6. The method according to claim 5, wherein (ii) the harvesting is carried out 3 to 30 days after completion of (i), and/or (ii) the harvesting is carried out mechanically.

7. A method according to claim 1, wherein the treatment is carried out at a growth stage of later than BBCH 37.

8. A method according to claim 5, wherein the treatment is carried out at a growth stage of later than BBCH 37.

9. The method according to claim 1, wherein the treatment of the one or more plants of the genus Saccharum is performed at a growth height of 250 cm or more.

10. The method according to claim 1, wherein the treatment of the one or more plants of the genus Saccharum is performed at a growth height of 300 cm or more.

11. A method according to claim 1, wherein the treatment is carried out at a growth stage of BBCH 38 to BBCH 85.

12. A method according to claim 1, wherein the treatment is carried out at a growth stage of BBCH 40 to BBCH 71.

13. A method for desiccating treatment of one or more plants of the genus Saccharum, comprising treatment of applying to said plants an effective amount of a composition comprising a phosphorus containing herbicidal active ingredient selected from the group consisting of glufosinate and salts thereof, to thereby have a drying out effect on the plant, wherein the treatment of the plants of the genus Saccharum is done at a growth height of 250 cm or more, wherein the plants are selected from the group consisting of Saccharum officinarum and of hybrids of Saccharum officinarum, wherein the leaves of the plants are desiccated, wherein the treatment is carried out at a growth stage of later than BBCH 45, and wherein the phosphorus containing herbicidal active ingredient is applied in a total amount in a range of from 800 to 1000 g/ha.

14. The method according to claim 13, wherein the phosphorus containing herbicidal active ingredient is glufosinate-ammonium.

15. The method according to claim 13, wherein the treatment is a foliar application.

16. The method according to claim 13, wherein a total amount of sucrose obtainable from a plant of the genus Saccharum officinarum and/or hybrids thereof is increased.

Description

DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT

(1) Thus, in the context of the present invention a single phosphorus containing herbicidal active ingredients, a mixture of two or more phosphorus containing herbicidal active ingredients, or compositions comprising one or more phosphorus containing herbicidal active ingredients, optionally comprising other herbicidal active ingredients, may be used.

(2) Compositions (and/or concentrates for obtaining compositions) for use in the context of the present invention are described for example in EP 0336151 A2, U.S. Pat. No. 5,258,358, U.S. Pat. No. 5,491,125, US 2005/0266995 A1, US 2005/0266998 A1, US 2005/266999 A1, US 2007/0184982 A1 and US 2008/0045415 A1.

(3) Preferably, the one or more phosphorus containing herbicidal active ingredients are used in the form of a composition comprising or consisting of (a) one or more phosphorus containing herbicidal active ingredients, (b) water, (c) one or more organic solvents, (d) one or more surfactants, preferably one or more nonionic, cationic, anionic and/or zwitterionic surfactants,
and optionally one, two, three or more further constituents selected from the following groups (e) to (g), (e) inorganic salts (preferably ammonium salts), (f) further active crop protectant ingredients free of phosphorus, (g) other formulation adjuvants.

(4) Surprisingly it has now been found that phosphorus containing herbicidal active ingredients, in particular those described in more detail hereinafter, exhibit a strong desiccating, i.e. drying or drying out, effect on (preferably aerial parts of) plants of the genus Saccharum, in particular on the leaves thereof. Consequently, harvesting is facilitated and easier, less time-consuming post-harvest processing possible, e.g. for obtaining plant ingredients like sucrose (saccharose), e.g. due to the reduction of impurities and accompanying plant materials.

(5) In particular, as a result of the application of one or more phosphorus containing herbicidal active ingredients to (preferably aerial parts of) plants of the genus Saccharum, in particular to (preferably leaves of) Saccharum officinarum, energy consumption, particularly fuel consumption, is significantly reduced, in particular during mechanized harvesting, and subsequent drying, and transportation of the harvested plants. As additional environmental benefit, inter alia the amount of unwanted and waste biomass is reduced.

(6) Further, the phosphorus containing herbicidal active ingredients improve or increase of the yield, in particular of the sugar containing plant material of plants of the genus Saccharum, more specifically of sugar, especially of sucrose in Saccharum officinarum.

(7) It was also found that the treatment of (preferably aerial parts of) plants of the genus Saccharum with (compositions comprising) the one or more phosphorus containing herbicidal active ingredients did not adversely affect re-growing of plants of the genus Saccharum.

(8) Overall, the present invention allows an increase in harvesting and production efficiency.

(9) A further aspect of the present invention relates to the use of (compositions comprising) one or more phosphorus containing herbicidal active ingredients, in particular of one or more herbicidal active ingredients of formula (I), (I-a) or (I-b), for increasing the yield of plant material of a plant of the genus Saccharum, in particular of Saccharum officinarum.

(10) The present invention allows operational ease for the sugarcane harvester allows decrease in the amount of unwanted impurities (e.g. trash content) and consequently also increases the efficiency of the subsequent extraction of sugarcane juice. Also, the separation process of dried leaves (straws) is faster and the heating value of the straw for energy production becomes greater. Further, the efficiency of boilers is increased and maintenance costs associated with the equipment for steam generation are reduced. Pre-harvest application of the desiccant may also significantly increase the cleaning efficiency of all raw material delivered to sugarcane plants.

(11) As used herein the phrase “increasing the yield” or “increase the yield”, of a plant of the genus Saccharum relates to an increase in the yield or content of a product or ingredient of the plant by a measurable amount over the yield or content of the same product or ingredient of the plant produced under the same conditions, but without the application of the method or the use according to the present invention. It is preferred that the yield is increased by at least 0.5%, more preferred that the increase is 1% or more, even more preferred 2% or more, and yet more preferred 4% or more. Yield can be expressed in terms of an amount by weight or volume of a product of the plant, and preferably is expressed in terms of the total weight of the sugar containing aerial parts of the Saccharum plant, more preferably the proportion (percentage by weight) of sucrose in the aerial parts of the Saccharum plant, even more preferably the total amount by weight of sucrose obtainable from the aerial parts of the Saccharum plant. The sugar (especially sucrose) containing aerial parts of the Saccharum plant particularly preferably are the stems and stalks of the Saccharum plant.

(12) Preferably, the present invention to the use of (a composition comprising) the one or more phosphorus containing herbicidal active ingredients as desiccant for (preferably aerial parts, particularly the leaves, of) plants of the genus Saccharum officinarum,
and/or for increasing the proportion by weight of sucrose in (preferably aerial parts, particularly stems or stalks, of) plants of the genus Saccharum officinarum or hybrids thereof.

(13) Preference is given in the context of the present invention to the use of (compositions comprising) one or more phosphorus containing herbicidal active ingredients of formula (I) or the salts thereof,

(14) ##STR00001##
wherein

(15) X is C.sub.1-C.sub.4 alkyl or OY, wherein Y is H, a cation, alkyl, alkenyl, alkoxyalkyl or unsubstituted or substituted C.sub.6-C.sub.10 aryl,

(16) R is H, alkyl or unsubstituted or substituted C.sub.6-C.sub.10 aryl,

(17) E is a structural element in total containing 1 to 22 carbon atoms linking W to the —CH.sub.2—P(O)(OR)X moiety, preferably 1 to 18, more preferably 1 to 12, even more preferably 1 to 8 carbon atoms, and preferably 1 to 4 N-atoms,

(18) W is CN or CO.sub.2M, wherein M is H or a cation.

(19) In the context of the present invention further preference is given to the use of (compositions comprising) one or more phosphorus containing herbicidal active ingredients of formula (I-a) or the salts thereof,

(20) ##STR00002##
wherein

(21) Z.sup.1 is a radical of the formula —OM, —NHCH(CH.sub.3)CONHCH(CH.sub.3)CO.sub.2M or —NHCH(CH.sub.3)CONHCH[CH.sub.2CH(CH.sub.3).sub.2]CO.sub.2M, wherein

(22) M is H or a cation,

(23) and/or

(24) one or more phosphorus containing herbicidal active ingredients of formula (I-b) or the salts thereof,

(25) ##STR00003##
wherein

(26) Z.sup.2 is a radical of the formula CN or CO.sub.2R.sub.1, in which R.sup.1 is H, a cation, alkyl, alkenyl, alkoxyalkyl or unsubstituted or substituted C.sub.6-C.sub.10 aryl which is preferably unsubstituted or substituted by one or more radicals from the group consisting of alkyl, alkoxy, halogen, CF.sub.3, NO.sub.2 and CN, and

(27) R.sup.2 and R.sup.3 each independently of one another are H, a cation, alkyl or C.sub.6-C.sub.10 aryl which is unsubstituted or substituted, preferably unsubstituted or substituted by one or more radicals from the group consisting of alkyl, alkoxy, halogen, CF.sub.3, NO.sub.2 and CN, or biphenylyl.

(28) Preferably, the carbon-containing radicals in connection with Q, R.sup.2 or R.sup.3, respectively, in total contain up to 10 carbon atoms, more preferably up to 6 carbon atoms.

(29) Preferred compositions used in the context of the present invention comprise one or more phosphorus containing herbicidal active ingredients selected from the group consisting of glufosinate (salts), glyphosate (salts), and bilanafos (=bialaphos) (salts) [i.e. glufosinate and its salts, glyphosate and its salts, and bilanafos and its salts], more preferred is glufosinate and its salts. In case of salts being used, the cations (M in formulae (I), (I-a) and (I-b)) of said salts are preferably selected from the group consisting of Na.sup.+, K.sup.+, and ammonium NH(R.sup.4).sub.3.sup.+ wherein each R.sup.4 independently is H or a C.sub.1-C.sub.12 alkyl group, preferably H or a C.sub.2-C.sub.6 alkyl group, more preferably NH.sub.4.sup.+ or a monoisopropylammonium group.

(30) A particularly preferred phosphorus containing herbicidal active ingredient in the context of the present invention is glufosinate-ammonium.

(31) The compounds of the formula (I-a) contain an asymmetric carbon atom. The L enantiomer is regarded as being the biologically active isomer. The formula (I-a) therefore embraces all stereoisomers and mixtures thereof, particularly the racemate, and the biologically active enantiomer in each case. Examples of active ingredients of the formula (I-a) are as follows: glufosinate and its ammonium salt in racemic form, i.e., 2-amino-4-[hydroxy(methyl)phosphinoyl]butanoic acid and its ammonium salt, the L enantiomer of glufosinate and its ammonium salt, bilanafos=bialaphos, i.e., L-2-amino-4-[hydroxy(methyl)phosphinoyl]butanoyl-L-alaninyl-L-alanine and its sodium salt.

(32) The racemate of glufosinate-ammonium on its own is usually applied at rates of between 200 and 1000 g a.i./ha (i.e., grams of active ingredient (a.i.) per hectare). Glufosinate-ammonium at these rates is effective in particular when it is taken up via green parts of the plant. Glufosinate-ammonium generally is used predominantly for controlling broadleaf and gramineous weeds in plantation crops and on uncultivated lands and also, using special application techniques, for inter-row control in agricultural or surface crops.

(33) The compounds of the formula (I-b) comprise N-(phosphonoalkyl)glycine and hence derivatives of the amino acid glycine. The herbicidal derivatives of N-(phosphonomethyl)glycine (glyphosate) have been described, for example, in U.S. Pat. No. 3,799,758.

(34) Generally speaking, glyphosate is used in crop protectant formulations in the form of the water-soluble salts, with the isopropylammonium salt being of particular significance in connection with the present invention.

(35) For the purpose of the present invention, foliar application of (compositions comprising) one or more phosphorus containing herbicidal active ingredients, in particular of one or more herbicidal active ingredients of formula (I), (I-a) or (I-b), to the Saccharum plant is preferred. In a preferred embodiment, said foliar application is carried out via aerial application (e.g. using an aeroplane). In contrast thereto, ground application is not preferred.

(36) In a particularly preferred embodiment, the present invention relates to the use or the method according to the present invention, wherein glufosinate-ammonium, or a mixture comprising glufosinate-ammonium and a further phosphorus containing herbicidal active ingredients, or a composition comprising glufosinate-ammonium and optionally one or more further phosphorus containing herbicidal active ingredients,
is used as desiccant for plants of the genus Saccharum, preferably as desiccant for (preferably aerial parts, particularly the leaves, of) plants of the genus Saccharum officinarum, in particular sugarcane.

(37) In an even more preferred embodiment, the present invention relates to the use or the method according to the present invention, wherein glufosinate-ammonium, or a composition comprising glufosinate-ammonium and optionally one or more further phosphorus containing herbicidal active ingredients,
is used as desiccant for aerial parts, particularly the leaves, of plants of the genus Saccharum officinarum, in particular sugarcane.

(38) For the purpose of the present invention, preferably (compositions comprising) one or more phosphorus containing herbicidal active ingredients, in particular one or more herbicidal active ingredients of formula (I), (I-a) or (I-b), are applied in a total amount in the range of from 100 to 1500 g/ha, more preferably in the range of from 150 to 1250 g/ha, even more preferably in the range of from 250 to 1000 g/ha to the plants of the genus Saccharum.

(39) In an even more preferred embodiment, the present invention relates to the use or the method according to the present invention, wherein glufosinate-ammonium, or a composition comprising glufosinate-ammonium
is used as desiccant for aerial parts, particularly the leaves, of sugarcane plants,

(40) wherein preferably glufosinate-ammonium is applied in a total amount in the range of from 150 to 1250 g/ha, even more preferably in the range of from 250 to 1000 g/ha to the sugarcane plants.

(41) In the context of the present invention, an use or a method of the present invention may be carried only once or two, three, four, five, six, seven, or eight times or more per full life cycle of a plant of the genus Saccharum.

(42) Preferably, an use or a method of the present invention is carried only once or twice per full life cycle of a plant of the genus Saccharum, typically once per season.

(43) The use or method according to the present invention is preferably performed such that one or more treatments with (a composition comprising) the one or more phosphorus containing herbicidal active ingredients, in particular one or more herbicidal active ingredients of formula (I), (I-a) or (I-b), are carried out 3 to 30 days, preferably 4 to 24 days, more preferably 5 to 18 days before harvesting.

(44) The use or method according to the present invention is preferably performed such that the last treatment with (a composition comprising) the one or more phosphorus containing herbicidal active ingredients, in particular one or more herbicidal active ingredients of formula (I), (I-a) or (I-b), is carried out 3 to 30 days, preferably 4 to 24 days, more preferably 5 to 18 days before harvesting.

(45) Thus, harvesting, preferably mechanical harvesting, is preferably carried out 3 to 30 days, more preferably 4 to 24 days, yet more preferably 5 to 18 days after the last application of phosphorus containing herbicidal active ingredients.

(46) In a preferred embodiment of the present invention, (compositions comprising) the one or more phosphorus containing herbicidal active ingredients, in particular one or more herbicidal active ingredients of formula (I), (I-a) or (I-b), are used which are free of an effective amount of encapsulated pesticide as described in WO 2010/105971 A2 and/or free of an effective amount of core-shell microcapsules as described in WO 2008/155097 A2.

(47) In a preferred embodiment of the present invention, (compositions comprising) the one or more phosphorus containing herbicidal active ingredients, in particular one or more herbicidal active ingredients of formula (I), (I-a) or (I-b), are used which are free of an effective amount of encapsulated pesticide and/or free of an effective amount of core-shell microcapsules, more preferably free of encapsulated pesticides and/or free of core-shell microcapsules, even more preferred free of capsules and free of microcapsules.

(48) In a preferred embodiment of the present invention, (compositions comprising) the one or more phosphorus containing herbicidal active ingredients, in particular one or more herbicidal active ingredients of formula (I), (I-a) or (I-b), are used in absence of, i.e. without a further active crop protectant ingredient free of phosphorus (constituent (f) of compositions for use according to the present invention).

(49) In a preferred embodiment, plants of the genus Saccharum, in particular of Saccharum officinarum, are treated in accordance with the present invention when having reached a total height (measured from the ground) of 150 cm or taller, preferably of 200 cm or taller, more preferably of 250 cm or taller, even more preferably of 300 cm or taller.

(50) The term “growth stage” refers to the growth stages as defined by the BBCH Codes in “Growth stages of mono- and dicotyledonous plants”, 2nd edition 2001, edited by Uwe Meier from the Federal Biological Research Centre for Agriculture and Forestry. The BBCH codes are a well-established system for a uniform coding of phenologically similar growth stages of all mono- and dicotyledonous plant species. Some of these BBCH growth stages are indicated in the following.

(51) Growth stage 3: Stem elongation, shoot development (main shoot)

(52) BBCH 31—Stem 10% of final length; 1 node detectable

(53) BBCH 33—Stem 30% of final length; 3 nodes detectable

(54) BBCH 36—Stem 60% of final length; 6 nodes detectable

(55) BBCH 39—Maximum stem length reached; 9 or more nodes detectable

(56) Growth stage 4: Development of harvestable vegetative plant parts (main shoot)

(57) BBCH 40—Harvestable vegetative plant parts begin to develop

(58) BBCH 45—Harvestable vegetative plant parts have reached 50% of final size

(59) BBCH 49—Harvestable vegetative plant parts have reached final size

(60) Growth stage 5: Inflorescence emergence (main shoot)/heading

(61) BBCH 51—Inflorescence or flower buds visible

(62) BBCH 55—First individual flowers visible (still closed)

(63) Growth stage 6: Flowering (main shoot)

(64) BBCH 60—First flowers open (sporadically)

(65) BBCH 64—40% of flowers open

(66) BBCH 69—End of flowering: fruit set visible

(67) In another preferred embodiment plants of the genus Saccharum are treated in accordance with the present invention at a growth stage later than BBCH 31 (stem 10% of final length), preferably later than BBCH 35 (stem 50% of final length), more preferably later than BBCH 37 (stem 70% of final length).

(68) Preferably, plants of the genus Saccharum are treated in accordance with the present invention at a growth stage of BBCH 38 (stem 80% of final length) to BBCH 85 (advanced ripening or fruit colouration), more preferably at growth stage BBCH 39 (stem 90% of final length) to BBCH 79 (nearly all fruits have reached final size), even more preferably at growth stage BBCH 40 (harvestable vegetative plant parts begin to develop) to BBCH 71 (10% of fruits have reached final size).

(69) Particularly preferably, plants of the genus Saccharum are treated in accordance with the present invention at a growth stage of BBCH 43 (harvestable vegetative plant parts have reached 30% of final size) to BBCH 69 (end of flowering: fruit set visible), yet more preferably at a growth stage of BBCH 47 (harvestable vegetative plant parts have reached 70% of final size) to BBCH 65 (50% of flowers open).

(70) In another preferred embodiment, plants of the genus Saccharum are treated in accordance with the present invention at a growth stage later than BBCH 49 (harvestable vegetative plant parts have reached final size).

(71) In connection with the present invention the term “organic solvents” (constituent (c) of a composition for use in accordance with the present invention) includes, for example, nonpolar organic solvents, polar protic organic solvents or aprotic organic polar solvents and mixtures thereof. Examples of organic solvents in the sense of the invention are aliphatic or aromatic hydrocarbons, such as mineral oils and toluene, xylenes and naphthalene derivatives, for example, halogenated aliphatic or aromatic hydrocarbons such as methylene chloride and chlorobenzene; aliphatic alcohols, such as alkanols having 1 to 12 carbon atoms, preferably 1 to 6 carbon atoms, such as methanol, ethanol, propanol, isopropanol and butanol, for example, or polyhydric alcohols such as ethylene glycol, propylene glycol and glycerol; ethers such as diethyl ether, tetrahydrofuran (THF), and dioxane; alkylene glycol monoalkyl and dialkyl ethers, such as propylene glycol monomethyl ether, propylene glycol monoethyl ether, ethylene glycol monomethyl and monoethyl ether, diglyme, and tetraglyme, for example; amides such as dimethylformamide (DMF), dimethylacetamide, dimethylcaprylamide, dimethylcapramide (®Hallcomide), and N-alkylpyrrolidones; ketones such as acetone; esters based on glyceryl and carboxylic acids, such as glyceryl mono-, di- and triacetate, phthalic esters; lactams; carbonic diesters; nitriles such as acetonitrile, propionitrile, butyronitrile, and benzonitrile; sulfoxides and sulfones such as dimethyl sulfoxide (DMSO) and sulfolane; oils, examples being plant-based oils such as corn germ oil, rapeseed oil or soybean oil.

(72) In many cases combinations of two or more different solvents, such as combinations containing alcohols such as methanol, ethanol, n- and isopropanol, and n-, iso-, tert- and 2-butanol, are also suitable.

(73) Preferred organic solvents in the sense of the present invention are aromatic solvents such as toluene, o-, m- or p-xylene and mixtures thereof, 1-methylnaphthalene, 2-methylnaphthalene, C.sub.6-C.sub.16 aromatics mixtures such as, for example, the Solvesso® series (ESSO) with the grades Solvesso® 100 (b.p. 162-177° C.), Solvesso® 150 (b.p. 187-207° C.), and Solvesso® 200 (b.p. 219-282° C.), phthalic acid (C.sub.1-C.sub.12)alkyl esters, especially phthalic acid (C.sub.4-C.sub.8) alkyl esters, water-immiscible ketones, such as cyclohexanone or isophorone, for example, or C.sub.6-C.sub.20 aliphatics, which may be linear or cyclic, such as the products of the Shellsol® series, grades T and K, or BP-n paraffins, and esters such as glyceryl triacetate.

(74) Particular preference is given to polar organic solvents, preferably polar organic solvents of substantial or unlimited miscibility with water which are suitable for preparing an single-phase aqueous solution. These preferably are selected from the group consisting of N-methylpyrrolidone (NMP), propylene glycol monomethyl ether (e.g. Dowanol® PM), dimethylformamide (DMF), dimethylacetamide (DMA), THF (tetrahydrofuran), propylene glycol, dipropylene glycol, glycerol, iso-propanol, and tetrahydrofurfuryl alcohol.

(75) The compositions for use according to the present invention preferably comprise surfactants (surface-active compounds) as constituent (d), preferably one or more anionic, cationic or zwitterionic and/or nonionic surfactants. The surfactants contribute to improved stability, availability of the one or more phosphorus containing herbicidal active ingredients for the Saccharum plants, or activity of the phosphorus containing herbicidal active ingredients, preferably those corresponding to formulae (I), (I-a) and (I-b).

(76) Preferably, a composition for use in accordance with the present invention comprises one or more anionic surfactants, preferably one or more anionic surfactants and one or more nonionic surfactants.

(77) Examples of suitable anionic surfactants are (where EO=ethylene oxide units, PO=propylene oxide units and BO=butylene oxide units): d1-1) anionic derivatives of fatty alcohols having 10-24 carbon atoms with 0-60 EO and/or 0-20 PO and/or 0-15 BO in any order, in the form of ether carboxylates, sulfonates, sulfates, and phosphates, and their inorganic salts (e.g., alkali metal and alkaline earth metal salts) and organic salts (e.g., salts based on amine or alkanolamine), such as Genapol®LRO, Sandopan® grades, and Hostaphat/Hordaphos® grades from Clariant; d1-2) anionic derivatives of copolymers consisting of EO, PO and/or BO units having a molecular weight of 400 to 10.sup.8, in the form of ether carboxylates, sulfonates, sulfates, and phosphates, and their inorganic salts (e.g., alkali metal and alkaline earth metal salts) and organic salts (e.g., salts based on amine or alkanolamine), d1-3) anionic derivatives of alkylene oxide adducts of C.sub.1-C.sub.9 alcohols, in the form of ether carboxylates, sulfonates, sulfates and phosphates, and their inorganic salts (e.g., alkali metal and alkaline earth metal salts) and organic salts (e.g., salts based on amine or alkanolamine); d1-4) anionic derivatives of fatty acid alkoxylates, in the form of ether carboxylates, sulfonates, sulfates and phosphates, and their inorganic salts (e.g., alkali metal and alkaline earth metal salts) and organic salts (e.g., salts based on amine or alkanolamine).

(78) Preferred anionic surfactants are

(79) alkyl polyglycol ether sulfates, especially fatty alcohol diethylene glycol ether sulfate (e.g., Genapol LRO®, Clariant), or

(80) alkyl polyglycol ether carboxylates (e.g., 2-(isotridecyloxypolyethyleneoxy)ethyl carboxymethyl ether, Marlowet 4538®, Hüls).

(81) Examples of cationic or zwitterionic surfactants are as follows (where EO=ethylene oxide units, PO=propylene oxide units, and BO=butylene oxide units): d2-1) alkylene oxide adducts of fatty amines, quaternary ammonium compounds having 8 to 22 carbon atoms (C.sub.8-C.sub.22), such as the Genamin® C, L, O, and T grades from Clariant, for example; d2-2) surface-active zwitterionic compounds such as taurides, betaines and sulfobetaines in the form of Tegotain® grades from Goldschmidt, and Hostapon®T and Arkopon®T grades from Clariant.

(82) Examples of nonionic surfactants are: d3-1) fatty alcohols having 10-24 carbon atoms with 0-60 EO and/or 0-20 PO and/or 0-15 BO in any order. Examples of such compounds are Genapol® C, L, O, T, UD, UDD, and X grades from Clariant, Plurafac® and Lutensol® A, AT, ON, and TO grades from BASF, Marlipal® 24 and O13 grades from Condea, Dehypon® grades from Henkel, and Ethylan® grades from Akzo-Nobel, such as Ethylan CD 120; d3-2) fatty acid alkoxylates and triglyceride alkoxylates such as the Serdox®NOG grades from Condea or the Emulsogen® grades from Clariant; d3-3) fatty acid amide alkoxylates such as the Comperlan® grades from Henkel or the Amam® grades from Rhodia; d3-4) alkylene oxide adducts of alkynediols, such as the Surfynol® grades from Air Products; sugar derivatives such as amino sugars and amido sugars from Clariant, d3-5) glucitols from Clariant, d3-6) silicone- and/or silane-based surface-active compounds such as the Tegopren® grades from Goldschmidt and the SE® grades from Wacker, and also the Bevaloid®, Rhodorsil®, and Silcolapse® grades from Rhodia (Dow Corning, Reliance, GE, Bayer), d3-7) surface-active sulfonamides, from Bayer, for example; d3-8) surface-active polyacrylic and polymethacrylic derivatives such as the Sokalan® grades from BASF; d3-9) surface-active polyamides such as modified gelatins or derivatized polyaspartic acid from Bayer, and derivatives thereof, d3-10) surfactant polyvinyl compounds such as modified PVP, such as the Luviskol® grades from BASF and the Agrimer® grades from ISP, or the derivatized polyvinyl acetates, such as the Mowilith® grades from Clariant, or the polyvinyl butyrates, such as the Lutonal® grades from BASF, the Vinnapas® and the Pioloform® grades from Wacker, or modified polyvinyl alcohols, such as the Mowiol® grades from Clariant, d3-11) surface-active polymers based on maleic anhydride and/or reaction products of maleic anhydride and also maleic anhydride copolymers and/or copolymers containing reaction products of maleic anhydride, such as the Agrimer® VEMA grades from ISP, d3-12) surface-active derivatives of montan waxes, polyethylene waxes, and polypropylene waxes, such as the Hoechst® waxes or the Licowet® grades from Clariant, d3-13) polyol-based alkylene oxide adducts, such as Polyglycol® grades from Clariant; d3-14) surface-active polyglycerides and derivatives thereof from Clariant.

(83) The weight ratio of the total amount of phosphorus containing herbicidal active ingredients of constituent (a) to the total amount of anionic surfactants of constituent (d) in a composition for use in accordance with the present invention preferably is in the range from 5:1 to 1:10, preferably 5:1 to 1:10, in particular 2:1 to 1:6.

(84) The weight ratio of the total amount of phosphorus containing herbicidal active ingredients of constituent (a) to the total amount of nonionic surfactants of constituent (d) in a composition for use in accordance with the present invention preferably is in the range from 20:1 to 1:1, preferably 10:1 to 2:1, especially 8:1 to 3:1.

(85) The compositions for use according to the present invention preferably comprise, as part of constituent (d), one or more nonionic surfactants from the group of the alkylpolyglycosides. Preferred alkylpolyglycosides in this context are the following:

(86) alkylpolysaccharides and mixtures thereof such as those, for example, from the ®Atplus range from Uniqema, preferably Atplus 435,

(87) alkylpolyglycosides in the form of the APG® grades from Henkel, an example being ®Plantaren APG 225 (fatty alcohol C.sub.8-C.sub.10 glucoside),

(88) sorbitan esters in the form of the Span® or Tween® grades from Uniqema,

(89) cyclodextrin esters or ethers from Wacker,

(90) surface-active cellulose derivatives and algin, pectin, and guar derivatives such as the Tylose® grades from Clariant, the Manutex® grades from Kelco, and guar derivatives from Cesalpina,

(91) alkylpolyglycoside-alkylpolysaccharide mixtures based on C.sub.8-C.sub.10 fatty alcohol, such as ®Glucopon 225 DK and ®Glucopon 215 CSUP (Cognis).

(92) Preferred as alkylpolyglycosides are the alkylpolyglycosides-alkylpolysaccharide mixtures such as Atplus 435.

(93) The compositions for use according to the present invention may comprise as constituent (e) inorganic salts from the group of ammonium salts, examples being ammonium sulfate, ammonium chloride, ammonium bromide, preferably ammonium sulfate.

(94) The use of alkylpolyglycosides as surfactants in crop protectant compositions is known in principle (see, for example U.S. Pat. No. 5,258,358). It is also mentioned therein that ammonium sulfate can be added as a frost protectant.

(95) The compositions for use in the context of the present invention may optionally comprise as constituent (g) customary formulation adjuvants, for example stickers, wetters, dispersants, penetrants, preservatives, frost protectants, fillers, carriers, colorants, evaporation inhibitors, pH modifiers (such as buffers, acids, and bases), viscosity modifiers (e.g. thickeners) or defoamers (defoaming agents).

(96) Preferred formulation adjuvants (g) are defoamers, frost protectants, carriers, evaporation inhibitors and preservatives, e.g., Mergal K9N® (Riedel) or Cobate C®.

(97) In a preferred embodiment fatty acid mono-alkyl esters are used as a formulation adjuvant of constituent (g), preferably fatty acid mono-alkyl esters derived from vegetable oil, more preferably soybean oil methyl esters.

(98) In the aqueous compositions for use in the context of the present invention it is often advantageous to add defoamers. Suitable defoamers include all customary defoamers, preferably silicone-based defoamers, such as silicone oils.

(99) Preferred defoamers are those from the group of linear polydimethylsiloxanes having an average dynamic viscosity, measured at 25° C., in the range from 1000 to 8000 mPas (mPas=millipascal-second), preferably 1200 to 6000 mPas, and containing silica. Silica comprehends forms/modifications such as polysilicic acids, meta-silicic acid, ortho-silicic acid, silica gel, silicic acid gels, kieselguhr, precipitated SiO.sub.2, etc.

(100) Defoamers from the group of linear polydimethylsiloxanes contain as their chemical backbone a compound of the formula HO—[Si(CH.sub.3).sub.2—O—].sub.n—H, in which the end groups are modified, by etherification for example, or, in general, are attached to the groups —Si(CH.sub.3).sub.3.

(101) Examples of defoamers of this kind are ®Rhodorsil Antifoam 416 (Rhodia) and ®Rhodorsil Antifoam 481 (Rhodia). ®Rhodorsil Antifoam 416 is a medium-viscosity silicone oil having a dynamic viscosity at 25° C. of about 1500 mPas and containing surfactant and silica. Because of the surfactant content the density is reduced as compared with the unadditized silicone oil, and amounts to about 0.995 g/cm.sup.3. ®Rhodorsil Antifoam 481 is a medium-viscosity silicone oil having a dynamic viscosity at 25° C. of about 4500 mPas and containing silica. The density amounts to about 1.045 g/cm.sup.3. Other defoamers from the silicone group are Rhodorsil 1824, Antimussol 4459-2 (Clariant), Defoamer V 4459 (Clariant), SE Visk and AS EM SE 39 (Wacker). The silicone oils can also be used in the form of emulsions.

(102) The compositions used in the context of the present invention may additionally comprise (as constituent (f)) further active crop protectant ingredients, preferably herbicides from the group of diphenyl ethers, carbamates, thiocarbamates, triphenyltin and tributyltin compounds, haloacetanilides, herbicides from the group of diphenyl ethers, carbamates, thiocarbamates, triphenyltin and tributyltin compounds, haloacetanilides, phenoxyphenoxyalkanecarboxylic acid derivatives and heteroaryloxyphenoxyalkanecarboxylic acid derivatives, such as quinolyloxy-, quinoxalyloxy-, pyridyloxy-, benzoxalyloxy- and benzothiazolyloxyphenoxyalkanecarboxylic esters, which generally have a suitable solubility in organic solvents, examples being active ingredients such as oxyfluorfen, diclofop-methyl, fenoxaprop-ethyl or fenoxaprop-P-ethyl.

(103) It is also possible to include one or more further active ingredients from the group of safeners, plant growth regulators, insecticides, and fungicides as constituent (f).

(104) The compositions for use in the context of the present invention can be prepared by processes which are customary and known in the art, i.e., by mixing the ingredients with stirring or shaking or by means of static mixing techniques.

(105) In the following examples, amounts are by weight, unless indicated otherwise.

(106) The composition examples shown in the following table are concentrates suitable—after appropriate dilution with water—for use in the context of the present invention. The section “Biological examples” summarizes results of biological trials.

(107) TABLE-US-00001 1 2 3 4 5 Glufosinate-ammonium (a.i.) 25.00 20.00 25.00 25.00 18.00 C.sub.12/C.sub.14—O—(EO).sub.2—SO.sub.3.sup.−Na.sup.+.sup.(2) 35.00 35.00 35.00 Glucopon 225 DK.sup.(3) 35.00 Glucopon 215 CSUP.sup.(3) 30.00 Atplus 435.sup.(3) 5.00 5.00 5.00 5.00 5.00 Ammonium sulfate 7.00 5.00 7.00 Propylene glycol monomethyl ether 3.00 3.00 Propylene glycol 2.75 2.50 2.50 Rhodorsil 481.sup.(4) 0.25 Rhodorsil 416.sup.(5) 0.25 Antimussol 4459-2.sup.(6) 0.50 Rhodorsil 454.sup.(7) 0.50 Water ad 100 ad 100 ad 100 ad 100 ad 100 Abbreviations used: .sup.(2)C.sub.12/C.sub.14—O—(EO).sub.2—SO.sub.3.sup.−Na.sup.+ = C.sub.12/C.sub.14 fatty alcohol diethylene glycol ether sulfate (used as ® Genapol LRO, Clariant), ® TEGO XP 5902 = blend of trisiloxane and a sodium salt solution (Degussa) ® Empilan KAS = ethoxylated alcohol with 5 EO (Huntsman); ® Sapogenat T 300 = triisobutylphenol ethoxylate with 30 EO (Clariant), ® Berol 900 = alkylglyceride (castor ethoxylate) with 40 EO (Akzo-Nobel), ® Geropon-CF 812-I = sulfosuccinate amine salt (Rhodia) .sup.(3)® Glucopon 225 DK = alkylpolyglycoside-alkylpolysaccharide mixture based on C.sub.8-C.sub.10 fatty alcohol (Cognis), ® Glucopon 215 CSUP = alkylpolyglycoside-alkylpolysaccharide mixture based on C.sub.8-C.sub.10 fatty alcohol (Cognis), ® Atplus 435 = alkylpolyglycoside-alkylpolysaccharide mixture (Uniqema) .sup.(4)® Rhodorsil 481 = polydimethylsiloxane oil with silica gel (Rhodia) .sup.(5)® Rhodorsil 416 = polydimethylsiloxane oil with silica gel and surfactant (Rhodia) .sup.(6)® Antimussol 4459-2 = silicone-based defoamer emulsion (Clariant) .sup.(7)® Rhodorsil 454 = defoamer based on polydimethylsiloxane oil without silica (Rhodia)

(108) The compositions disclosed in the above table are concentrates which are diluted with an appropriate amount of water, optionally adding further adjuvants like ammonium sulfate, thereby obtaining a tank mix. The thus obtained tank mix is preferably used such a total amount of herbicides of component (a) is applied to the Saccharum plants as indicated hereinbefore at growth stage as indicated hereinbefore.

(109) Biological Examples

(110) The compositions described in the table above were diluted with water and applied to a field of Saccharum officinarum plants at growth stage BBCH 49 (approximately 300 cm growth height; corresponding to about 2 weeks before harvest), such that the amount of glufosinate ammonium was 800 g/ha or 1000 g/ha, respectively. The evaluation 2 weeks after application of glufosinate ammonium revealed a desiccation of sugarcane leaves of 54% and 60%, respectively.