Inductive Plasma Source
20170372870 · 2017-12-28
Inventors
- Valery A. Godyak (Brookline, MA, US)
- Charles Crapuchettes (Santa Clara, CA, US)
- Vladimir Nagorny (Tracy, CA, US)
Cpc classification
H05H1/46
ELECTRICITY
H01J37/321
ELECTRICITY
H01J37/32174
ELECTRICITY
H01J37/32137
ELECTRICITY
International classification
Abstract
Methods and apparatus to provide efficient and scalable RF inductive plasma processing are disclosed. In some aspects, the coupling between an inductive RF energy applicator and plasma and/or the spatial definition of power transfer from the applicator are greatly enhanced. The disclosed methods and apparatus thereby achieve high electrical efficiency, reduce parasitic capacitive coupling, and/or enhance processing uniformity. Various embodiments comprise a plasma processing apparatus having a processing chamber bounded by walls, a substrate holder disposed in the processing chamber, and an inductive RF energy applicator external to a wall of the chamber. The inductive RF energy applicator comprises one or more radiofrequency inductive coupling elements (ICEs). Each inductive coupling element has a magnetic concentrator in close proximity to a thin dielectric window on the applicator wall.
Claims
1-33. (canceled)
34. An apparatus for processing a substrate, comprising: a processing chamber having an interior space; a substrate holder in the interior space; at least one dielectric window constituting at least a portion of a wall of the processing chamber; an inductive coupling element having a flat coil disposed proximate the dielectric window; an electrostatic shield disposed between the inductive coupling element and interior space; wherein the electrostatic shield comprises an array of metal strips, each of the metal strips disposed in a direction that is generally normal to the flat coil.
35. The apparatus of claim 34, wherein the array of metal strips are coupled by a conductive loop.
36. The apparatus of claim 35, wherein the conductive loop is broken.
37. The apparatus of claim 34, wherein the electrostatic shield is grounded.
38. The apparatus of claim 34, wherein the electrostatic shield is floating.
39. The apparatus of claim 34, wherein the inductive coupling element comprises a U-shaped magnetic flux concentrator disposed about the flat coil.
40. The apparatus of claim 34, wherein the magnetic flux concentrator has a first pole area and a second pole area facing the dielectric window.
41. The apparatus of claim 34, wherein a conductive shield is disposed at least partially around the magnetic flux concentrator.
42. An apparatus for processing a substrate, comprising: a processing chamber having an interior space; a substrate holder in the interior space; at least one dielectric window constituting at least a portion of a wall of the processing chamber; an inductive coupling element having a flat coil disposed proximate the dielectric window; an electrostatic shield disposed between the inductive coupling element and interior space; wherein the electrostatic shield comprises a flat sheet parallel to the flat coil, the flat sheet having at least one discontinuity
43. The apparatus of claim 42, wherein the electrostatic shield is grounded.
44. The apparatus of claim 42, wherein the electrostatic shield is floating.
45. The apparatus of claim 42, wherein the inductive coupling element comprises a U-shaped magnetic flux concentrator disposed about the flat coil.
46. The apparatus of claim 42, wherein the magnetic flux concentrator has a first pole area and a second pole area facing the dielectric window.
47. The apparatus of claim 42, wherein a conductive shield is disposed at least partially around the magnetic flux concentrator.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0043] A full and enabling disclosure of the present invention, including the best mode thereof, directed to one of ordinary skill in the art, is set forth in the specification, which makes reference to the appended figures, in which:
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DETAILED DESCRIPTION OF THE DRAWINGS
[0061] Reference now will be made in detail to embodiments of the invention, one or more examples of which are illustrated in the drawings. Each example is provided by way of explanation of the invention, not limitation of the invention. In fact, it will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the scope or spirit of the invention. For instance, features illustrated or described as part of one embodiment can be used with another embodiment to yield a still further embodiment. Thus, it is intended that the present invention covers such modifications and variations as come within the scope of the appended claims and their equivalents.
[0062] Methods and apparatus to provide efficient and scalable RF inductive plasma processing are disclosed. In some aspects, the coupling between an inductive RF energy applicator and plasma and/or the spatial definition of power transfer from the applicator are greatly enhanced. The disclosed methods and apparatus thereby achieve high electrical efficiency, reduce parasitic capacitive coupling, and/or enhance processing uniformity.
[0063] Various embodiments comprise a plasma processing apparatus having a processing chamber bounded by walls, a substrate holder disposed in the processing chamber, and an inductive RF energy applicator external to a wall of the chamber. The inductive RF energy applicator comprises one or more radiofrequency inductive coupling elements (ICEs). Each inductive coupling element has a magnetic concentrator in close proximity to a thin dielectric window on the applicator wall.
[0064] The inductive coupling element is operable to send magnetic flux lines from the concentrator directionally through the thin dielectric window such that a substantial portion of the magnetic flux lines emerge from the dielectric window and continue downward into a volume of the chamber beneath the applicator. The flux lines curl laterally within this volume, then turn in an upward direction and return back to the dielectric window. A majority of the magnetic flux lines return from the interior of the chamber and through the dielectric window to the inductive coupling element. The high frequency magnetic flux lines from the concentrator, thus, surround a portion of plasma in the region immediately beneath the inductive coupling element. The magnetic flux can induce an electromotive force that is operable to power an inductively coupled plasma current in the region surrounded by the flux.
[0065] In particular embodiments, a conductive shield surrounds at least a portion of the magnetic flux concentrator of the inductive coupling elements. The conductive shield serves to further focus magnetic flux lines into the processing chamber interior and serves to isolate inductive coupling elements from other components of the plasma processing apparatus, such as other inductive coupling elements and feed gas conduits. The conductive shield also reduces power losses in the inductive coupling element arising from other components of the plasma processing apparatus, facilitating measurement of real power delivered to the plasma and enhancing process control.
[0066] The present subject matter can be embodied in various different forms. In the following description, for the purposes of explanation, numerous specific details are set forth to provide a thorough understanding of the disclosure. It will be apparent, however, to one skilled in the art, that the disclosed method and apparatus can be practiced without these specific details. In other instances, structures and devices are shown in simplified form in order to avoid obscuring the concepts. However, it will be apparent to one skilled in the art that the principles can be practiced in various different forms without these specific details. Hence aspects of the disclosure should not be construed as being limited to the embodiments set forth herein.
[0067] Reference in the specification to “one embodiment” or “an embodiment” means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment. The appearances of the phrase “one embodiment,” “an embodiment” etc. in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments.
[0068] An embodiment of an applicator and processing chamber can be further understood with respect to a cylindrical chamber shown with respect to
[0069] In a number of embodiments, feed gas can be introduced into the chamber through a plurality of feed gas holes 1041 in an applicator wall. The feed holes 1041 can receive process gas through tubulations such as feed gas conduits 1040. It has been found that introducing feed gas through holes interspersed among ICEs over the substrate provides excellent process uniformity and profile control. For instance, as illustrated in
[0070] Furthermore, in some applications, processing uniformity can be improved based on delivering a plurality of suitable feed gas flow rates through the various holes 1040. For example, each feed gas conduit 1040 and feed hole 1041 with respect to
[0071] In some processing applications, the interior volume of the processing chamber is maintained at low pressure. A preselected chamber pressure can be maintained using conventional pressure sensing devices (capacitance manometers, ion gauges, liquid manometers, spinning rotor gauges, and others), pumps such as oil based pumps, dry mechanical pumps, diffusion pumps, and others, and pressure control means such as automatic feedback control systems and/or conventional manual controls. Various embodiments do not depend on having any specific type of pumping system, pressure sensing means, or a preselected pressure. In vacuum processing applications, the applicator wall, and the lateral chamber walls, can support a pressure differential of at least one atmosphere.
[0072] Two annular ICEs 1020, 1070 over thin dielectric window areas in an applicator wall are depicted in
[0073] The term dielectric window area in an applicator wall will be understood to reference the portion of a thin window immediately adjacent to an ICE, through which a substantial portion of the magnetic flux lines from that ICE enter and/or return from the chamber interior in a relatively uniform direction. It will be understood that applicator walls and/or thin window areas can be configured in various different ways. For example, as shown with respect to
[0074] In various embodiments, such as shown with respect to
[0075] In various aspects, the thin dielectric windows 1087 are relatively narrow to have sufficient mechanical strength to support external atmospheric pressure when there is vacuum in the chamber. Thus, the width of thin window areas 1087 with respect to
[0076] Other embodiments have at least one thin and relatively narrow discrete dielectric window segment disposed in a recess and/or channel of a relatively thick, load bearing chamber wall. The thin dielectric window in the recess (trough) is interposed between an ICE and the plasma processing chamber. The thin window and receiving channel width are sufficiently narrow to allow the relatively thin dielectric window to withstand atmospheric pressure. For instance, as illustrated in
[0077] There arc embodiments where a low pressure differential across a large thin window, such as shown in
[0078] In various embodiments a chamber profile is approximately a circular cylinder comprising at least one ICE above a dielectric window in a flat applicator wall at upper interior end of the chamber. However, chamber shape does not limit the scope of the claims. In further embodiments the cross-section of a chamber can be rectangular, elliptical, polygonal, and others.
[0079] In further embodiments, the various ICEs can be selectively powered in a manner operable to optimize plasma uniformity and/or obtain various other processing characteristics such as an electron density and/or energy distribution, a reactive species concentration profile, a degree of feed gas decomposition, and/or others. For example, in some embodiments a relatively greater amount of power can be deposited at the periphery of a processing chamber, to compensate for species loss and lower concentration from diffusive loss to the peripheral walls around the chamber and in other embodiments. In yet another example, the power sent to some and/or all of the ICEs is pulsed at a suitable rate and duty to produce precursor species for low stress films.
[0080] Preselected voltages, currents and/or power can be applied to the various ICEs using suitable matching networks. An exemplary power circuit and control loop for controlling voltages, currents, and/or power to ICEs will be discussed in more detail below with reference to
[0081] It has been found that an ICE comprising a magnetic flux concentrator can send magnetic flux relatively directionally and deeply into the interior chamber immediately below the ICE. More particularly, the directionality of magnetic flux emitted from the ICE through a thin window and immediately below the dielectric window into the chamber can be controlled using a magnetic flux concentrator and a sufficiently thin window.
[0082] The synergistic operation of an ICE having a magnetic flux concentrator and an adjacent thin window on an applicator wall can be further understood with respect to the simplified diagram of
[0083] The magnetic flux concentrator 8030 can comprise magnetically permeable material such as a ferromagnetic metal, a ferrite, and/or others. In various embodiments, a magnetic flux concentrator 8030 can include magnetically permeable material having a magnetic permeability of at least 10 relative to vacuum. In
[0084] Magnetically permeable material can reduce magnetic path resistance for magnetic flux lines in the concentrator medium. Accordingly, upper portions of magnetic flux lines 8085 are found to be generally confined within the concentrator, although a relatively small amount of leakage is possible. Highly conductive shielding, such as disclosed above, has been found to be effective as a barrier to electric and magnetic field lines emanating from structures in an ICE. In various embodiments, shielding over various portions of an ICE was found to improve magnetic flux confinement. Furthermore, a highly conductive shield is useful to reduce and/or eliminate parasitic power loss and/or electromagnetic interference in some embodiments.
[0085] ICE 8070 can be powered using high frequency voltage and/or current applied to the terminals of a coil 8060. In various embodiments, the coil can be flat. A flat coil 8060 comprising parallel conductors adjacent to thin dielectric window 8020 has been found to be particularly effective. High frequency current flowing in the coil 8060 can stimulate magnetic flux lines 8085 circulating through a localized volume 8080 adjacent to the dielectric window 8020 in a processing chamber.
[0086] In various embodiments, high frequency current through the coil 8060 is operable to power magnetic flux lines 8085 generally emanating from a first momentary pole area 8035 of the magnetic flux concentrator 8030, through an area of thin window 8020 and into the chamber. The magnetic flux lines 8085 circulate through a localized volume 8080 adjacent to the window area in the chamber, and return to the window area in a relatively uniform direction to a second momentary pole area 8037, different from 8035. The magnetic flux concentrator 8030 can be configured to emit magnetic flux lines 8085 generally in a predetermined first direction 8071 (
[0087] Where magnetic flux is emitted from an ICE in this manner, excellent power coupling and high power transfer efficiency can be effectuated. Furthermore, since the magnetic flux circulated from a magnetic flux concentrator can induce plasma current selectively in a volume of plasma immediately below the ICE, power can be transferred from the ICE directly into this volume. Accordingly, the plasma current and power can be deposited from an ICE into a preselected localized volume in the processing chamber.
[0088] In various embodiments, having flux emerge through a thin window chamber into the process chamber and return through the thin window from the chamber depends on having the momentary pole faces 8035, 8037 of a magnetic flux concentrator generally face the thin window and be within a minimum useful distance t.sub.w of the interior chamber space below. With respect to
[0089] For instance,
[0090] In contrast,
[0091] With respect to
[0092] In various embodiments with respect to
[0093] The directionality of magnetic flux emitted from an ICE through a window and immediately below the window into the chamber depends on geometry and physical properties of the magnetic flux concentrator, the conductive shield disposed around the magnetic flux concentrator, and the dielectric window. It has been found that an ICE comprising a magnetic flux concentrator can send magnetic flux through the dielectric window and deeply into the chamber immediately below the ICE through the dielectric window. The material around the magnetic flux concentrator also plays an important role. Currents which may be induced in that material affect the magnetic fluxes, and losses, and depending on conductivity of the material, can improve performance or deplete performance. For example, if a highly conductive shield at least partially surrounds the magnetic flux concentrator, currents induced on the surface do not result in any significant losses, but can increase the magnetic flux inside the magnetic flux concentrator and thus, increase magnetic flux in the plasma adjacent to the dielectric window. On the other hand, if conductivity is low, losses induced in the shield can be large, while effect on magnetic flux might be low. Finally, material and geometry of the magnetic flux concentrator preferably includes a high magnetic flux density, low dissipation factor, and relatively wide foot at the base of U or C shaped magnetic flux concentrator. Otherwise, magnetic flux lines will exit and enter the magnetic flux concentrator at a wide angle distribution other than close to a preferred perpendicular direction.
[0094] A different embodiment can be understood with respect to
[0095] Here the distance D.sub.g between adjacent momentary pole faces is marked with reference number 8035. Also, the distance separating the pole faces from the chamber interior is approximately the thickness of the thin window 8025. In this configuration, the flux from pole faces 8035 and/or 8075 can emerge from the pole faces and through thin window 8020 into the process chamber interior. In a particular configuration, the thin window 8020 has a thickness 8025 of less than about D.sub.g/4 and more preferably less than D.sub.g/8.
[0096] In general, a relatively higher coupling coefficient between an external applicator and ICP in a chamber is attained as distance between the applicator and interior of the chamber is reduced. In various embodiments, a thin window allows the applicator to be relatively proximate to the process gas in which an ICP is sustained in the processing chamber. A relatively high coupling coefficient between the applicator and ICP generally results in more efficient power transfer.
[0097] Additional embodiments can be understood with respect to
[0098] There is a thin disk shaped dielectric window (not apparent) above the ICE's and its supporting structure. The thin dielectric window is in contact with the various ICE's and the flat coil turns. Gas can be delivered into the interior 190 of the chamber through feed gas holes 170 in the thin window. The thin window thickness is less than about 1/10 of the distance between the flux emitting and receiving areas (pole gaps) 160, 166, 165 of the magnetic flux concentrators. Therefore each of the pole faces is within a distance of 1/10 of the gap distance between pole faces from the interior of the chamber. This embodiment is operable to send flux lines directionally from each ICE through an adjacent thin window area, to circulate flux lines through a respectively localized volume in the chamber interior, and to return those flux lines to the ICE generally perpendicular through the thin window area. The circulating flux lines induce an outer plasma current ring in localized chamber volumes under the flat coil turns in the aligned troughs of the outer magnetic flux concentrators, and an inner plasma current ring under the flat coil rings in the trough of the inner ICE magnetic flux concentrator.
[0099] In various embodiments, ICEs can be selectively energized. In some embodiments, different selected amounts of power having a selected phase relationship can be coupled to the various inductive coupling elements of the applicator. Furthermore, in some embodiments process uniformity over a substrate can be effectuated based on selectively delivering suitable amounts of RF power to the various ICEs. For example, some embodiments comprise processing diagnostic measurements coupled to a control loop in a manner operable to deliver selected amounts of power from the various ICEs into various localized regions of volume under the thin windows.
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[0101] Any method of measuring power delivered to a system suffers from inaccuracies. Existing processing equipment typically monitors power using a power measurement device located at the match network. This power measurement device captures power delivered to the plasma, losses in the ICE, losses in the antenna cage outside the chamber, and losses inside the chamber. All of these parameters will be different for different chambers, requiring process control parameters to be adjusted, for instance, each time an ICE is replaced and for each different chamber. Moreover, measurement performed at the matching network is particularly sensitive to the current and voltage waveforms applied to the ICE due to large phase angle differences (close to 90°) between voltage and current waveforms at the matching network for any good (high Q-factor) coil.
[0102] Use of the power circuit and control loop of
[0103] Moreover, because resonant capacitor 630 resonates with the inductance of the ICE 640 and plasma 650, the current is determined only by the active resistance of the ICE and plasma. The power delivered to any component (plasma, coil, other lossy elements such as the shield surround the ICE), is then simply the product of I.sup.2R.sub.coil Because of the magnetic flux concentrators and highly conductive shields surrounding the ICE, losses in the ICE walls are small, making it easier to separate losses in the plasma from losses in the coil. The use of highly conductive shields at least partially surrounding the ICE also reduces interference from adjacent inductive coupling elements and feed gas conduits, further increasing the accuracy of power measurements.
[0104] As shown in
[0105] After determining real power delivered to the plasma, signal calculator 670 provides a real power signal 680 representative of real power delivered to the plasma. This real power signal 680 can be used by control loop for manual or automatic adjustments to the power delivered to the ICE. Adjusting the power provided to the ICE based on real power measurements delivered to the plasma provides for more accurate and efficient control of the plasma process.
[0106] This sensing arrangement is of particular usefulness when driving multiple inductive coupling elements from a single Power generator and matcher, unlike commonly used systems that measure power upstream of the matcher.
[0107] ICEs may generate a noticeable amount of capacitively coupled plasma due to parasitic capacitive coupling of inductive elements in the ICE. Such capacitive coupling may be undesirable, leading to process non-uniformities and to sputtering of the applicator window. An electrostatic or Faraday shield is often used to reduce capacitive coupling of ICE coils to plasma. Existing electrostatic shields can significantly reduce ICE coupling to the plasma and inflict significant losses in RF power, both reducing inductively coupled plasma transfer efficiency.
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[0109] An electrostatic shield 720 is disposed on the dielectric window 710. Electrostatic shield 720 can be formed from any conductive material, such as copper, aluminum, silver, or other suitable conductor. Electrostatic shield 720 can be affixed to dielectric window 710 using any suitable process. For instance, electrostatic shield 720 can be screwed, glued, or deposited to the window. In a particular embodiment, electrostatic shield 720 can be adhered to dielectric window using thick film deposition or self-adhesive copper or aluminum foil.
[0110] Electrostatic shield 720 generally comprises an array of thin metal strips 722 disposed in a direction substantially normal to the coil of the inductive coupling element 740. The thin metal strips 722 are arranged close enough to each other to effectively shield electric fields from the process chamber interior. The electrostatic shield 720 nearly satisfies the condition of anisotropic conductivity. Namely, the conductivity of the electrostatic shield 720 is about zero in the direction of the inductively induced field and substantially large in the direction normal to the inductively induced field and tangent to the plasma surface.
[0111] As illustrated in
[0112] In a particular embodiment, conductive loop 725 can be coupled to ground or reference voltage. In an alternative embodiment, conductive loop 725 can remain floating to provide for a little amount of capacitive coupling through the electrostatic shield 720. A little capacitive coupling may be desired to help ignite or sustain the plasma or to intentionally introduce non-uniformities into the plasma. In another embodiment, conductive loop 725 can be coupled to a voltage source. The voltage applied to the conductive loop can be adjusted to control the amount of capacitive coupling through the electrostatic shield.
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[0116] An embodiment for scalable processing of large rectangular substrates can be understood with respect to
[0117] In various embodiments, ICEs can be connected and/or powered in alternative manners. With respect to
[0118] These and other modifications and variations to the present invention may be practiced by those of ordinary skill in the art, without departing from the spirit and scope of the present invention, which is more particularly set forth in the appended claims. In addition, it should be understood that aspects of the various embodiments may be interchanged both in whole or in part. Furthermore, those of ordinary skill in the art will appreciate that the foregoing description is by way of example only, and is not intended to limit the invention so further described in such appended claims.