Abstract
A security element including a first layer having a first surface, an array of image regions across the surface, each including at least first and second sub-regions, a first array of plasmonic nanostructures in or on the surface across the first sub-regions, defining in each a corresponding portion of a first image, a second array across the second sub-regions, defining in each a corresponding portion of a second image; wherein each sub-region has a respective average inclination and the average inclinations of the first sub-regions are such that the first image is displayed at least at a first viewing angle and those of the second sub-regions are such that the second image is displayed at least at a second viewing angle different from the first and the second image is substantially not or only partially displayed at least at the first angle. Also, a method of manufacturing the security element.
Claims
1. A security element comprising: a first layer having a first surface; an array of image regions across the first surface, each image region comprising at least a first sub-region and a second sub-region; a first array of plasmonic nanostructures provided in or on the first surface across the first sub-regions, the first array of plasmonic nanostructures defining in each first sub-region a corresponding portion of a first image, wherein said plasmonic nanostructures have dimensions of 500 nm or less, wherein the spacing of the plasmonic nanostructures within the first array is varied within one or more of the first sub-regions to vary the colour of the portion of the first image across those one or more first sub-regions, and wherein the plasmonic nanostructures of the first array of plasmonic nanostructures are discontinuously provided across the first sub-regions to provide image information of the first image; and a second array of plasmonic nanostructures provided in or on the first surface across the second sub-regions, the second array of plasmonic nanostructures defining in each second sub-region a corresponding portion of a second image, wherein said plasmonic nanostructures have dimensions of 500 nm or less, wherein the spacing of the plasmonic nanostructures within the second array is varied within one or more of the second sub-regions to vary the colour of the portion of the second image across those one or more second sub-regions, and wherein the plasmonic nanostructures of the second array of plasmonic nanostructures are discontinuously provided across the second sub-regions to provide image information of the second image; wherein the first surface is arranged such that each sub-region has a respective average inclination and wherein the average inclinations of the first sub-regions are such that the first image is displayed at least at a first viewing angle and wherein the average inclinations of the second sub-regions are such that the second image is displayed at least at a second viewing angle different from the first viewing angle and such that the second image is substantially not displayed or only partially displayed at least at the first viewing angle.
2. A security element according to claim 1, wherein each first sub-region has substantially the same first average inclination and each second sub-region has substantially the same second average inclination.
3. A security element according to claim 1, wherein the average inclinations of the first sub-regions are such that the first image is displayed over a first viewing angle range and wherein the average inclinations of the second sub-regions are such that the second image is displayed over a second viewing angle range, wherein the first and second viewing angle ranges do not overlap or only partially overlap one another.
4. A security element according to claim 1, wherein the second image is a colour-altered version of the first image.
5. A security element according to claim 1, wherein the plasmonic nanostructures of the first and/or second of plasmonic nanostructures vary in at least one of their shape and size across the corresponding first and/or second sub-regions to provide image information of the corresponding first and/or second image.
6. A security element according to claim 1, wherein the first and/or second array of plasmonic nanostructures comprises a two-dimensional array of nanopillars, each nanopillar comprising a dielectric body topped by a continuous metal cover layer.
7. A security element according to claim 1, wherein the first and/or second array of plasmonic nanostructures comprises a continuous metal base layer, a continuous dielectric layer on the continuous metal base layer and a two-dimensional array of metallic nanodiscs on the continuous dielectric layer overlapping the continuous metal base layer.
8. A security element according to claim 1, wherein the first and/or second array of plasmonic nanostructures comprises a two-dimensional array of nanoholes, each nanohole comprising an aperture through a metal layer, the metal layer being arranged on a substrate.
9. A security element according to claim 1, wherein the first and/or second array of plasmonic nanostructures comprises a one-dimensional or two-dimensional sub-wavelength grating structure formed in a dielectric layer, the one-dimensional or two-dimensional sub-wavelength grating structure being coated in a metal layer.
10. A security element according to claim 1, wherein the first surface is arranged such that each first and/or second sub-region is substantially convex.
11. A security element comprising: a first layer having a first surface; an array of image regions across the first surface, each image region comprising at least a first sub-region and a second sub-region; a first array of plasmonic nanostructures provided in or on the first surface across the first sub-regions, the first array of plasmonic nanostructures defining in each first sub-region a corresponding portion of a first image, wherein said plasmonic nanostructures have dimensions of 500 nm or less; and a second array of plasmonic nanostructures provided in or on the first surface across the second sub-regions, the second array of plasmonic nanostructures defining in each second sub-region a corresponding portion of a second image, wherein said plasmonic nanostructures have dimensions of 500 nm or less; wherein the first surface is arranged such that each sub-region has a respective average inclination and wherein the average inclinations of the first sub-regions are such that the first image is displayed at least at a first viewing angle and wherein the average inclinations of the second sub-regions are such that the second image is displayed at least at a second viewing angle different from the first viewing angle and such that the second image is substantially not displayed or only partially displayed at least at the first viewing angle; wherein the sub-regions of each image region are defined by an arrangement of at least four facets that substantially replicate inclinations of a convex surface and in which each facet is provided at substantially the same height, wherein each set of sub-regions corresponding to one of the four facets of each image region comprises a respective array of plasmonic nanostructures defining corresponding portions of a respective image displayed at a respective viewing angle.
12. A security element according to claim 11, wherein the arrangement of facets that substantially replicate inclinations of a convex surface define a diverging Fresnel mirror.
13. A security element according to claim 11, wherein the plasmonic nanostructures of the first and/or second of plasmonic nanostructures vary in at least their spacing between the corresponding first and/or second sub-regions to provide image information of the corresponding first and/or second image.
14. A security element according to claim 11, wherein the facets are convex or substantially planar.
15. A security element comprising: a first layer having a first surface; an array of image regions across the first surface, each image region comprising at least a first sub-region and a second sub-region; a first array of plasmonic nanostructures provided in or on the first surface across the first sub-regions, the first array of plasmonic nanostructures defining in each first sub-region a corresponding portion of a first image, wherein said plasmonic nanostructures have dimensions of 500 nm or less; and a second array of plasmonic nanostructures provided in or on the first surface across the second sub-regions, the second array of plasmonic nanostructures defining in each second sub-region a corresponding portion of a second image, wherein said plasmonic nanostructures have dimensions of 500 nm or less; wherein the first surface is arranged such that each sub-region has a respective average inclination and wherein the average inclinations of the first sub-regions are such that the first image is displayed at least at a first viewing angle and wherein the average inclinations of the second sub-regions are such that the second image is displayed at least at a second viewing angle different from the first viewing angle and such that the second image is substantially not displayed or only partially displayed at least at the first viewing angle; wherein each image region further comprises a third sub-region, wherein the first surface is arranged such that each third sub-region has a respective average inclination, wherein the first surface is arranged such that third sub-regions are visible at least at a third viewing angle, the third viewing angle being between the first and second viewing angles, and further comprising a uniform structure provided across the third sub-regions defining a neutral image.
16. A security element according to claim 15, wherein the uniform structure comprises a substantially planar reflective surface, an array of anti-reflective microstructures, an achromatic microstructure, or one or more diffraction gratings.
17. A security element according to claim 15, wherein each third sub-region is substantially parallel with a plane of the security element.
18. A security element according to claim 15, wherein the first surface is arranged such that each third sub-region comprises a substantially planar facet.
19. A security element according to claim 15, wherein the plasmonic nanostructures of the first and/or second of plasmonic nanostructures vary in at least their spacing between the corresponding first and/or second sub-regions to provide image information of the corresponding first and/or second image.
20. A security element comprising: a first layer having a first surface; an array of image regions across the first surface, wherein the array of image regions comprises a two-dimensional array of image regions, wherein each image region is substantially convex along two orthogonal directions, and wherein each image region defines a two-dimensional array of convex sub-regions having different average inclinations, each set of sub-regions comprising a respective array of plasmonic nanostructures defining corresponding portions of a respective image, such that the different images are exhibited at different viewing angles in two orthogonal directions of tilt of the security element by the corresponding sub-regions in combination.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0041] Examples of security elements will now be described with reference to the accompanying drawings, in which:
[0042] FIG. 1 shows, schematically, a security document including a first embodiment of a security element;
[0043] FIG. 2 shows, schematically, a perspective view of an enlarged portion of the security element according to the first embodiment;
[0044] FIG. 3 shows, schematically, an enlarged perspective view of an array of plasmonic nanostructures suitable for use in the security element according to the first embodiment;
[0045] FIG. 4 shows, schematically, an enlarged plan view of the security element according to the first embodiment including the plasmonic nanostructures on the surface;
[0046] FIGS. 5A and 5B show, schematically, a portion of the security element of the first embodiment in cross-section at two different viewing angles;
[0047] FIGS. 6A and 6B show, schematically, the security document including the security element of the first embodiment at two different viewing angles;
[0048] FIG. 7 shows, schematically, an enlarged plan view of a security element according to a second embodiment including the plasmonic nanostructures on the surface;
[0049] FIGS. 8A to 8C show, schematically, a security document including the security element of the second embodiment at three different viewing angles;
[0050] FIG. 9 shows schematically, an enlarged plan view of a security element according to a third embodiment including the plasmonic nanostructures on the surface;
[0051] FIG. 10 shows, schematically, an enlarged perspective view of an array of plasmonic nanostructures suitable for use in the security element according to the third embodiment;
[0052] FIGS. 11A and 11B show, schematically, a portion of a security element of a fourth embodiment in cross-section at two different viewing angles;
[0053] FIGS. 12A and 12B show, schematically, a portion of a security element of a fifth embodiment in cross-section and plan view respectively;
[0054] FIG. 13 shows, schematically, an enlarged portion of a security element of a sixth embodiment in cross-section;
[0055] FIGS. 14A to 14C show, schematically, a security document including the security element of the sixth embodiment at three different viewing angles;
[0056] FIG. 15 shows, schematically, a security document including a seventh embodiment of a security element;
[0057] FIGS. 16A to 16C show, schematically, enlarged portions of the security element of the seventh embodiment;
[0058] FIGS. 17A to 17D show, schematically, a security document including the seventh embodiment of the security element at four different viewing angles;
[0059] FIG. 18 shows, schematically, a security document including an eighth embodiment of a security element;
[0060] FIGS. 19A to 19C show, schematically, enlarged portions of the security element of the eighth embodiment;
[0061] FIG. 20 shows, schematically, an enlarged portion of a security element according to a ninth embodiment;
[0062] FIGS. 21A to 21B show, schematically an enlarged cross-sectional view and plan view of an array of plasmonic nanostructures suitable for use in security elements according to the invention;
[0063] FIG. 22 shows, schematically, an enlarged perspective view of an array of plasmonic nanostructures suitable for use in security elements according to the invention;
[0064] FIGS. 23A to 23D show, schematically, four different stages during a method of manufacture of the security element of the first embodiment;
[0065] FIGS. 24A to 24D show, schematically, a plan view and first and second cross-sections through a security element according to the invention; and
[0066] FIG. 25 shows a surface shaped to define a diverging Fresnel mirror.
DETAILED DESCRIPTION
[0067] A security element according to a first embodiment will now be described with reference to FIGS. 1 to 6B.
[0068] FIG. 1 shows a security document 100, in this case a banknote, with a security element 1. The security document has a short axis A and a long axis B perpendicular to the short axis. The security element has a first surface that faces away from the security document. This first surface is made up of an array of image regions 10, in this case elongate image regions, each elongate image region extending in a first direction, i.e. along the direction of the axis A. The array of elongate image regions are arranged so as to repeat along a second direction along the surface, i.e. along the direction of axis B, the image regions repeating so as to provide the width of the security element.
[0069] FIG. 2 shows a small area of the security element, illustrating the arrangement of the surface of the security element across three image regions 10 in a perspective view. As can be seen in this figure, each image region has an elongate triangular prism shape, providing each image region with two facets facing away from the security document. The triangular prism is elongate along the direction of axis A (which corresponds to the first direction mentioned above) and has substantially constant cross-section as viewed along the direction of axis B (which corresponds to the second direction mentioned above). FIG. 2 shows only three image regions 10, but it will be appreciated that many more are typically used to make up the full security element. Each image region 10 has a respective first sub-region 10a, being a facet that is inclined away from being parallel with the security document towards the viewer's left. Each first sub-region 10a across the image regions 10 has substantially the same inclination such that the first sub-regions all have the same effect on the angle of incidence of light. Each image region also has a respective second sub-region 10b, being a facet that is inclined away from being parallel with the security document towards the viewer's right. Again, all inclinations are substantially the same for each second sub-region 10b.
[0070] In FIG. 2, the inclinations shown are purely schematic and the actual angle the facet makes to the surface of the document will be selected so that over a desired range of viewing angles the facets forming the first sub-regions obscure the facets forming the second sub-regions and vice versa to provide optical variability. This will be discussed in more detail below, but essentially, sub-regions will become obscured at least when the viewing angle becomes parallel to the surface of the sub-region and the information in those sub-regions will cease to be visible. Sub-regions may cease being visible before the viewing angle becomes parallel with the surface in the sub-regions as some plasmonic nanostructures exhibit their colours poorly at very steep viewing angles.
[0071] FIG. 3 shows an array of plasmonic nanostructures 50 suitable for use in the present invention. The array of plasmonic nanostructures 50 is in the form of nanopillars. Each nanopillar sits on a uniform metal base layer 53 that extends across the security element surface. Each nanopillar comprises a dielectric shaft 51 that in this Figure is shown as being generally cylindrical. Each nanopillar is topped with a metal cover layer 52 that forms a nanodisc on the top of the cylindrical shaft. The metal base layer 53 and metal nanodiscs may be of aluminium, while the shafts of the nanopillars may be formed of hydrogen silsesquioxane (HSQ), for example, where the substrate is formed by electron beam replication. Alternatively, for roll to roll or sheet fed replication, the pillar may be formed in a UV curable material typically used for cast cure replication of surface relief micro-structures, such as acrylated oligomers, such as acrylic esters of polyesters, polyethers, polyurethanes and epoxy resins, or formed in thermoplastic resins based on acrylic (PMMA) or urethane chemistries. While these are preferred, other material combinations are known to be suitable for forming plasmonic nanostructures. Typical dimensions of nanopillar include diameters between 10 and 500 nm and spacings of 50 to 500 nm. While the nanopillars shown in this figure are all the same shape and size and equally spaced, it will be appreciated that the desired colour to be generated can be tuned by mixing different sizes and shapes of nanopillar and varying the spacing. Only 16 nanopillars are shown in FIG. 3, but it will be appreciated that many more are typically used across the sub-regions of the present security device.
[0072] FIG. 4 shows the arrangement of plasmonic nanostructures across the security element. In this case, a first array of plasmonic nanostructures 50a, being nanopillars having a particular shape, size and spacing, are provided across each of the first sub-regions 10a, which correspond to those facets inclined towards the viewer's left. Similarly, a second array of plasmonic nanostructures 50b, being nanopillars having a particular shape, size and spacing different from that of the first array 50a, are provided across each of the second sub-regions 10b, which correspond to those facets inclined towards the viewer's right.
[0073] FIGS. 5A to 6B illustrate the appearance of the security element when viewed at different viewing angles upon rotation about the axis A. FIGS. 5A and 6A relate to a security element rotated about axis A such that the left-hand side of the document is closer to the viewer than the right-hand side. This effectively rotates the security element 1 about the long axis of the image regions 10 such that the first sub-regions 10a are visible while the second sub-regions 10b are obscured. The viewing geometry is shown in FIG. 5A in particular. Here, the viewing angle relative to the surface defining the second sub-regions 10b is effectively beyond 90° such that the second sub-regions are not visible. In this embodiment, the image regions have widths on a scale imperceptible to the human eye and hence, as shown in FIG. 6A, the appearance of the security element is of a uniform colour as generated by the first array of plasmonic nanostructures 50a. FIGS. 5B and 6B relate to the security element rotated about axis A such that the right-hand side of the document is closer to the viewer than the left-hand side. This effectively rotates the security element 1 about the long axis of the image regions 10 such that the second sub-regions 10b are visible while the first sub-regions 10a are obscured. The viewing geometry is shown in FIG. 5B and is essentially the reverse of FIG. 5B such that the viewing angle of the first sub-regions 10a is effectively beyond 90° such that the first sub-regions are not visible. Now, as shown in FIG. 6B, the appearance of the security element is of a uniform colour as generated by the second array of plasmonic nanostructures 50b.
[0074] While the first embodiment shows the arrays of plasmonic nanostructures provided entirely across each of the respective sets of first sub-regions 10a and second sub-regions 10b, it will be appreciated that this simplicity is merely to aid in understanding the effects utilised in the invention. In practice the arrays of plasmonic nanostructures in these sub-regions may be provided only in certain areas of the sub-regions and/or may be modulated (i.e. varied in size, shape and/or spacing) across the sub-regions. FIGS. 7 to 8C illustrate an embodiment in which the plasmonic nanostructures are only in certain areas of the sub-regions.
[0075] In this embodiment, the same triangular prismatic shape defining sets of first and second sub-regions 10a, 10b is used as in the first embodiment. FIG. 7 shows these triangular prismatic image regions 10 in plan view, to illustrate the manner in which the plasmonic nanostructures are provided. Specifically, it shows that the first array of plasmonic nanostructures 50a in the first sub-regions 10a is only provided in certain areas of those sub-regions so as to define an image 60a, in this case a circle. That is, each first sub-region 10a corresponds to a slice of the image to be displayed 60a and the first array 50a is provided in each first sub-region 10a so as to delimit the corresponding slice of the circle in that image. Similarly, the second array of plasmonic nanostructures 50b in the second sub-regions 10b is only provided in certain areas of those sub-regions so as to define a second image 60b, in this case a triangle. That is, each second sub-region 10b corresponds to a slice of the image to be displayed 60b and the second array 50b is provided in each second sub-region 10b so as to delimit the corresponding slice of the triangle in that image. In this embodiment, again, different plasmonic nanostructures are used between the first and second sub-regions to provide different colours. For both sets of sub-regions, the areas not including the first and second arrays of plasmonic nanostructures are left empty such that no colour effect is exhibited at any viewing angle in those regions.
[0076] FIGS. 8A to 8C illustrate the appearance of the security element 1 on a security document 100. FIG. 8A shows the security document 1 rotated about axis A such that the left-hand side of the document is closer to the viewer than the right-hand side, while FIG. 8B shows the security document 1 viewed perpendicularly, and FIG. 8C shows the security document rotated about axis A such that the right-hand side of the document is closer to the viewer than the left-hand side. As can be seen, when viewed in the position of FIG. 8A, the viewing angle relative to the surface defining the second sub-regions 10b is effectively beyond 90° such that the second sub-regions 10b are not visible, while the first sub-regions 10a are visible. Hence, the viewer sees the first image 60a, i.e. a circle. When viewed in the position of FIG. 8B, neither of the first or second sub-regions is obscured from view and so both the first and second images 60a, 60b are visible in superposition. That is, the images of a circle and a triangle are visible simultaneously. Finally, when viewed in the in the position of FIG. 8C, the viewing angle relative to the surface defining the first sub-regions 10a is effectively beyond 90° such that the first sub-regions are not visible, while the second sub-regions 10b become visible. Hence, the viewer sees the second image 60b, i.e. a triangle.
[0077] In the above embodiment, different images are used as the first and second images 60a, 60b such that the image changes upon rotation of the security element. As has been mentioned, this may involve some viewing angles at which both images are visible simultaneously. In some embodiments, the security element may be designed to take advantage of this feature by providing that the two images integrate in some way, e.g. by providing that the first image provides a first half of a combined image and the second image a second half of a combined image. However, in other embodiments, the first and second images may be provided defining substantially the same image but in different colours such that rotation of the security element produces an apparent colour change of the image as different amounts of the different arrays of plasmonic nanostructures are visible. Some embodiments that utilise this effect will be described further below.
[0078] While in the above embodiment, the areas not including the first and second arrays of plasmonic nanostructures are left empty such that no colour effect is exhibited at any viewing angle in those regions, this is not essential. The embodiment of FIGS. 9 and 10 illustrate an embodiment in which the plasmonic nanostructures are modulated across the sub-regions 10a, 10b. That is, each first sub-region 10a is provided with an area of a first size, shape and spacing of plasmonic nanostructures 50a and an area of a second size, shape and spacing of plasmonic nanostructures 55a. Similarly, each second sub-region 10b is provided with an area of a third size, shape and spacing of plasmonic nanostructures 50b and an area of a fourth size, shape and spacing of plasmonic nanostructures 55b. These plasmonic nanostructures produce a colour effect depending on their size, shape and spacing and so each of these areas will appear a different colour. FIG. 10 illustrates this variation in the plasmonic nanostructures and shows first plasmonic nanostructures 50, comprising a dielectric shaft 51 and metal nanodisc 52 having a first diameter, and second plasmonic nanostructures 50, comprising a dielectric shaft 56 and metal nanodisc 57 having a second diameter. It will be appreciated that more complex modulation of the types of nanostructures can be used to produce images with more colour complexity, for example by providing many different combinations of variations in size, shape and spacing.
[0079] The above embodiments have described image regions 10 having a regular and generally triangular prismatic shape, however, it will be appreciated that many different arrangements of the first surface can be used depending on the desired optically variable effect. FIGS. 11A and 11B illustrate one option for the arrangement of the first surface. Here, the image element 1 is again formed of an array of interlaced, elongate image regions 10. Each image region 10 has a first sub-region 10a, being an area of the surface that is substantially parallel with the plane of the security element. Each image region 10 also has a second sub-region 10b, formed as one facet of a groove in the first surface, the facet being inclined away from parallel with the plane of the security element, towards the viewer's right. When the security element 1 is viewed with the left-hand side closer to the viewer than the right-hand side, as illustrated in FIG. 11A, the first sub-regions 10a are visible, but the second sub-regions 10b are obscured from view. Hence, only the colours generated by the plasmonic nanostructures in the first sub-regions 10a are visible to the viewer. However, when the security element is rotated so that the right-hand side is closer to the viewer than the left-hand side, as illustrated in FIG. 11B, the second sub-regions 10b become visible, together with the first sub-regions 10a. That is, since the first sub-regions 10a are parallel with the plane of the security element and arranged at the upper surface of the security element, the plasmonic nanostructures provided in the first sub-regions are visible over a very wide range of viewing angles as they are not obscured at substantially any viewing angle when the front surface of the security element is being viewed.
[0080] FIGS. 12A and 12B illustrate an embodiment with another arrangement of the first surface of the security element 1. Here, again we have an array of elongate image regions 10 being arranged so as to repeat along a direction perpendicular to their length. Each image region 10 has a trapezium-shaped cross-section, as shown in FIG. 12A, that is constant along the length of the image region 10. That is, three facets are defined in each image region 10 providing a first sub-region 10a that is inclined towards the viewer's left, a second sub-region 10b that is substantially parallel with the plane of the security element and a third sub-region 10c that is inclined towards the viewer's right. A first array of plasmonic nanostructures 50a are disposed across the first sub-regions 10a in accordance with a first image, a second array of plasmonic nanostructures 50b are disposed across the second sub-regions 10b in accordance with a second image and a third array of plasmonic nanostructures 50c are disposed across the third sub-regions 10c in accordance with a third image. This arrangement is shown for three image regions in FIG. 12B. This embodiment provides three different images that are visible over three different viewing angle ranges, increasing the complexity of the optically variable effect.
[0081] The embodiment of FIGS. 12A and 12B increases visual complexity; however, it may be the case that for many viewing angles more than one image is visible at the same time. For example, there may be a large range of viewing angles over which the first and second images are visible simultaneously and similarly for the second and third images. It is possible that the images used could be designed so as to integrate with one another to take advantage of this. However, in some embodiments, it is preferred to minimise the viewing angles at which multiple images are visible. FIGS. 13 to 14C illustrate such an embodiment.
[0082] FIG. 13 shows a single image region 10 of a security element 1 in cross-section. The image region 10 has the same shape as in the embodiment of FIGS. 12A and 12B. That is, each image region 10 has a trapezium-shaped cross-section that is constant along the length of the image region 10. Again, the image regions 10 are arranged so as to repeat along a direction perpendicular to the length of the image region to form the security element with a plurality of image regions. The first sub-region 10a of each image region 10, which is inclined towards the viewer's left, is provided with a first array of plasmonic nanostructure 50a defining a corresponding portion of a first image 60a. Similarly, the third sub-region 10c of each image region 10, which is inclined towards the viewer's right, is provided with a third array of plasmonic nanostructure 50c defining a corresponding portion of a third image 60c. The second sub-region 10b of each image region 10, which is substantially parallel to the plane of the security element, is provided with a structure that defines a neutral image 60b. The structure may in some embodiments be an array of plasmonic nanostructures defining, for example, a uniform colour; however, in preferable embodiments, the structure is an anti-reflective structure. Specifically, in this embodiment, the second sub-region 10b of each image region 10 is completely filled with an array of anti-reflective moth-eye structures 70b defining the neutral image 60b.
[0083] FIGS. 14A to 14C illustrate the appearance of the security element 1 on a security document 100. FIG. 14A shows the security document 1 rotated about axis A such that the left-hand side of the document is closer to the viewer than the right-hand side, while FIG. 14B shows the security document 1 viewed perpendicularly, and FIG. 14C shows the security document rotated about axis A such that the right-hand side of the document is closer to the viewer than the left-hand side. As can be seen, when viewed in the position of FIG. 14A, the viewing angle relative is such that the second and third sub-regions 10b, 10c are substantially not visible, while the first sub-regions 10a are visible. Hence, the viewer sees the first image 60a, in this case a circle. When viewed in the position of FIG. 14B, substantially only the second sub-regions 10b are visible. That is, the security element appears uniformly dark owing to the anti-reflective structures provided across the second sub-regions. Finally, when viewed in the in the position of FIG. 14C, the viewing angle is such that the first and second sub-regions are not visible, while the third sub-regions 10c become visible. Hence, the viewer sees the third image 60c, i.e. a triangle. Advantageously, even when the second sub-regions are visible simultaneously with the first or second sub-regions, since they comprise anti-reflective structures, they do not contribute significantly to the appearance of the device and the viewer perceives only the corresponding image carried by the first or third sub-regions 10a, 10c. The first and third images 60a, 60c are therefore visible distinctly and separately.
[0084] The above embodiments have focused on one-dimensional arrays of image regions in which the inclinations of the sub-regions contribute to variability in the direction of rotation about axis A. However, in other embodiments, two-dimensional arrays of image regions may be used and an example will now be described.
[0085] FIG. 15 shows a security document 100, again a banknote, with a security element 1. The security document has a short axis A and a long axis B perpendicular to the short axis. The security element has a first surface that faces away from the security document. This first surface is made up of a two-dimension array of image regions 10. The image regions are shown in more detail in FIGS. 16A to 16C. In this case, each image region 10 is shaped as a square based pyramid such that each image region 10 has four facets providing four different sub-regions 10a, 10b, 10c, 10d. Again, it should be appreciated that the angle of inclinations of these facets shown in the Figures is schematic and the inclinations used will be selected for the desired viewing angle ranges of the plasmonic nanostructures. As can be seen in FIG. 16A, the first sub-region 10a is provided by a facet facing towards the viewer's left, the second sub-region 10b is provided by a facet facing downwards, the third sub-region 10c is provided by a facet facing towards the viewer's right and the fourth sub-region is provided by a facet facing upwards. As shown in FIG. 16C, each sub-regions 10a, 10b, 10c, 10d is provided with a corresponding array of plasmonic nanostructures 50a, 50b, 50c, 50d, disposed according to respective first to fourth images 60a, 60b, 60c, 60d. In this embodiment, the plasmonic nanostructures are shown as being present across the whole of the sub-regions (i.e. the images are uniformly coloured areas); however, this is merely for ease of demonstration and it will be appreciated that the nanostructures may be selectively provided across only certain sub-regions and certain areas of sub-regions in accordance with more complex image information and can also be modulated across the sub-regions so as to vary colour. When this security document is viewed, the security element will exhibit a colour effect at four different viewing angles according to the plasmonic nanostructures on the different facets in each image region 10. These four different viewing angles are separated by rotation about both axis A and B, providing the security element with optical variability in two orthogonal directions of rotation, and this is shown in FIGS. 17A to 17D.
[0086] FIG. 17A shows the security element rotated from perpendicular viewing about axis A so that the left-hand side is closer to the viewer than the right-hand side. Here substantially only the first sub-region is visible and so only the colour from the first array of plasmonic nanostructures 50a is exhibited to the viewer, displaying the first image 60a. FIG. 17B shows the security element rotated from perpendicular viewing about axis B so that the bottom of the security document is closer to the viewer than the top. Here substantially only the second sub-region 10b is visible and so only the colour from the second array of plasmonic nanostructures 50b is exhibited to the viewer, displaying the second image 60b. FIG. 17C shows the security element rotated from perpendicular viewing about axis A so that the right-hand side is closer to the viewer than the left-hand side. Here substantially only the third sub-region is visible and so only the colour from the third array of plasmonic nanostructures 50c is exhibited to the viewer, displaying the third image 60c. Finally, FIG. 17D shows the security element rotated from perpendicular viewing about axis B so that the top of the security document 100 is closer to the viewer than the bottom. Here substantially only the fourth sub-region is visible and so only the colour from the fourth array of plasmonic nanostructures 50d is exhibited to the viewer, displaying the fourth image 60d. The result is a security element that exhibits optical variability in two orthogonal directions or rotation.
[0087] It will be appreciated that other shapes of image regions can be used in two-dimensional variants of the invention. For example, the pyramidal shape can be truncated to provide an upper facet that is parallel with the plane of the security element for carrying a neutral image.
[0088] In another embodiment, shown in FIGS. 18 to 19C, convex-shaped image regions are used. FIG. 18 shows another security document 100, again a banknote, with a security element 1. The security element in this embodiment comprises a two-dimensional array of convex dome shaped image regions 10, i.e. semi-spherical image regions, which are substantially circular in plan view, as shown in FIG. 19A. While semi-spherical image regions are used here, aspherical image regions may also be used. Additionally, the thickness of the device may be decreased by using a diverging Fresnel mirror, as described above. A single image region 10 is shown in perspective view in FIG. 19B, omitting the plasmonic nanostructures. FIG. 19C shows a single image region 10 divided into a set of sub-regions. In this embodiment, the image region 10 is divided into quarters so as to define four sub-regions 10a, 10b, 10c, 10d. While not shown in this embodiment, these sub-regions are assigned corresponding arrays of plasmonic nanostructures. Specifically, the first sub-regions 10a are assigned a plasmonic nanostructure array defining a first image, the second sub-regions are assigned a plasmonic nanostructure array defining a different second image, and similarly the third and fourth sub-regions are assigned plasmonic nanostructure arrays defining the respective third and fourth different images. As before, each sub-region will carry a respective portion of the corresponding image, such that, for example, all first image sub-regions 10a, in combination, exhibit the first image across the security element. As this security element 1 is tilted about axes A and B, the four different images will be visible at different viewing angles. In particular, the image that is visible will correspond to the sub-region from which light is reflecting in the direction of the viewer. Light incident along a single direction will be directed in different directions by the different sub-regions in accordance with the local surface normal in those sub-regions. In particular, each sub-region is itself convex as so the local surface normal varies across each individual sub-region. This acts to ensure that each image is visible over a relatively wide range of viewing angles and prevents narrow viewing windows for each of the images. It will be appreciated that fewer than or more than four sub-regions may be used, as well as different arrangements of the sub-regions, depending on the effect desired.
[0089] A more complex arrangement for a two-dimensional array of image regions is shown in FIGS. 24A to 24C. In particular, FIG. 24A shows a small area of the security element in plan view, illustrating a three by three arrangement of image regions, although again it will be appreciated that many more than this are typically provided across the full security element. Here, the image regions 10 again repeat along two orthogonal directions of the security element. FIG. 24B shows a cross-section through the image regions 10 along a first of the two orthogonal repeat directions. As illustrated in FIG. 24B, each image region 10 is convex along this first repeat direction such that the sub-regions vary in average inclination along this direction. FIG. 24C shows a cross-section through the image regions 10 along a second of the two orthogonal repeat directions and again illustrates that each image region 10 is convex along this second repeat direction. As shown in FIG. 24A, each image region is divided into a seven by seven array of sub-regions for a total of 49 sub-regions. Here, the sub-regions are interlaced along the same two orthogonal directions along which the image regions repeat and each sub-region will thereby have a unique average inclination with respect to the plane of the security element as a result of the image region being convex along both orthogonal directions. That is, the sub-regions are interlaced from left to right (from VL to VR in the Figure) along the image region as well as from top to bottom (from VU to VB in the Figure). As with the previous embodiment, each of these sub-regions is associated with a respective image. Respective arrays of plasmonic nanostructures are provided across the image regions such that, within each image region, each sub-region carries a corresponding portion of a respective image. The resulting security element will exhibit 49 different images as it is tilted along two orthogonal directions in accordance with the local surface normal across the sub-regions. For example, the top-left sub-region within each image region will carry a corresponding portion of a first image, such that when the security element is arranged such that incident light is reflected from each of these top-left sub-regions towards the viewer, the first image will be visible as a result of the combined appearance of these top-left sub-regions. The same will be true of each of the other sets of sub-regions at their own corresponding viewing angles. In other words, each image region will effectively display a respective pixel of one of the 49 images in accordance with the viewing angle such that each of the 49 images is visible across the security device over the respective viewing angle ranges.
[0090] The use of convex reflective image regions can also be employed with a one-dimensional array of image regions, and an embodiment of such a security element is shown in FIG. 20. This shows a small area of the security element, illustrating the arrangement of the surface of the security element across three image regions 10 in a perspective view. As can be seen in this figure, each image region 10 is elongate with a constant circular segment cross-section, defining a partial cylinder shaped, or semi-cylindrical, image region 10. Each image region is divided lengthwise into three sub-regions 10a, 10b, 10c, which will be provided with respective arrays of plasmonic nanostructures, each defining a different respective image across the corresponding sets of sub-regions. That is, each first sub-region, for example, carries a different “slice” of the first image, such that the combined appearance of the first sub-region displays this first image to the viewer. As this security element is rotated about an axis parallel with the length of the image regions 10, the three different images will be visible over different viewing angle ranges depending on the local surface normal in each of the different sub-regions 10a, 10b, 10c. That is, light incident along a single direction will be directed in different directions by the three different sub-regions in accordance with the local surface normal in those sub-regions. Since each sub-region is itself convex along the direction perpendicular to the length of the image regions, the local surface normal varies across each individual sub-region in a plane perpendicular to the length of the image regions. This acts to ensure that each image is visible over a relatively wide range of viewing angles as the security element is rotated about the axis parallel with the length of the image regions 10 and, again, prevents narrow viewing windows for each of the images.
[0091] The above embodiments have described plasmonic nanostructures in the form of nanopillars, as shown in FIGS. 3 and 10; however, as mentioned above, other types of plasmonic nanostructures can be used. FIGS. 21A to 22 show other plasmonic nanostructures.
[0092] FIGS. 21A and 21B show plasmonic nanostructures in the form of an array of nanoholes 150. The surface of the security element 1 includes a base layer in the form of a continuous metal layer 153, such as aluminium. Over this metal layer is provided a continuous layer of dielectric material. The layer of dielectric material is then coated on its upper surface in a layer of metal 152. The metal layer 152 includes an array of circular holes formed through the metal layer, exposing the continuous dielectric layer. This structure produces plasmonic colour effects in much the same way described above with respect to nanopillar structures. Again, the shape of the holes, the size of the holes and their spacing can be varied in order to control the colour generated by these plasmonic nanostructures.
[0093] FIG. 22 shows plasmonic nanostructures in the form of an array of nanodiscs 250 on a continuous layer of dielectric material. The surface of the security element 1 includes a continuous metal layer 251, for example aluminium or more rarely gold, on top of which is provided a continuous dielectric layer 252, for example silicon dioxide (SiO.sub.2). On the dielectric layer sits an array of circular metal nanoplates 253, again aluminium or more rarely gold is used as an example of a suitable material, that complete the nanostructure. Again, the shape of the plates, the size of the plates and their spacing can be varied in order to control the colour generated by these plasmonic nanostructures.
[0094] While electron beam origination has been mentioned, preferably the above structures are formed in web-based on sheet fed production methods, which more typically require UV cast-cure or thermoplastic embossing techniques. A specific example will now be described in which the structures are formed using a cast-cure process and the process is illustrated in FIGS. 23A to 23D. The surface structure, including both the coarse image region surface structure providing the inclinations of the sub-regions and the plasmonic nanostructures can be provided in a master die, for example by using e-beam lithography. FIG. 23A shows a master die 200 with a negative of the desired surface structure 201. This surface structure in the die defines negatives of array of image regions 210, including an array of nanopillars 212 and the prismatic structure 211. FIG. 23A also shows a transparent support layer 2, which may be a layer of the final security element 1. On the surface of the transparent support layer 2 is provided a UV curable material 3. In alternative embodiments, the curable material 3 is directly applied onto the security document and the surface relief subsequently formed in the surface of the curable material while on the security document. This alternative requires no subsequent transferral of the security element onto a security document. In embodiments that require a metal base layer, this may be applied first to a carrier layer or security document and a curable dielectric layer applied thereover. A transparent die 200 may be used to cure the material on the metal layer. In yet further alternatives, the security element may be formed directly into the substrate of the security document by using a formable polymer substrate in place of the UV curable material 3.
[0095] FIG. 23B shows the die 200 being brought into contact with the curable material 3 so as to form the curable material into the desired surface shape, i.e. into a series of prismatic elements with nanopillars provided on the facets. FIG. 22B also illustrates that the curable material 3 is exposed to UV radiation 220 through the transparent support layer 2, while in contact with the die 200.
[0096] FIG. 23C shows the cured curable material 3, which corresponds to the first layer of the security element discussed above, after separation from the die 200. The cured curable material now exhibits a plurality of image regions 10 with corresponding sub-regions 10a, 10b and respective arrays of nanopillars.
[0097] FIG. 23D shows a cross section of the final security element 1 after the surface has been coated in a metal enhancing layer 4, to form the nanodiscs on the top of the nanopillars. The metal layer may be formed using an electron beam evaporator, which directionally deposits metal so that a metal nanodisc is formed on the tops on nanopillars. As can be seen here, the security element comprises the layer of cured curable material 3 whose surface carries array of image regions 10, each having first and second sub-regions 10a, 10b, and each sub-region including first and second arrays of plasmonic nanostructures 50a, 50b.
[0098] Security elements of the sorts described above are suitable for forming on security articles such as threads, stripes, patches, foils and the like which can then be incorporated into or applied onto security documents such as banknotes. The security elements can also be constructed directly on security documents, such as polymer banknotes.
[0099] Security elements of the sorts described above can be incorporated into or applied to any product for which an authenticity check is desirable. In particular, such devices may be applied to or incorporated into documents of value such as banknotes, passports, driving licences, cheques, identification cards etc. The security element can either be formed directly on the security document (e.g. on a polymer substrate forming the basis of the security document) or may be supplied as part of a security article, such as a security thread or patch, which can then be applied to or incorporated into such a document. The security element may be applied to a security document, for example by using a pressure sensitive adhesive.
[0100] Such security articles can be arranged either wholly on the surface of the base substrate of the security document, as in the case of a stripe or patch, or can be visible only partly on the surface of the document substrate, e.g. in the form of a windowed security thread. Security threads are now present in many of the world's currencies as well as vouchers, passports, travelers' cheques and other documents. In many cases the thread is provided in a partially embedded or windowed fashion where the thread appears to weave in and out of the paper and is visible in windows in one or both surfaces of the base substrate. One method for producing paper with so-called windowed threads can be found in EP 0059056 A1. EP 0860298 A2 and WO 03095188 A2 describe different approaches for the embedding of wider partially exposed threads into a paper substrate. Wide threads, typically having a width of 2 to 6 mm, are particularly useful as the additional exposed thread surface area allows for better use of optically variable devices, such as that presently disclosed.
[0101] Base substrates suitable for making security substrates for security documents may be formed from any conventional materials, including paper and polymer. Techniques are known in the art for forming substantially transparent regions in each of these types of substrate. For example, WO 8300659 A1 describes a polymer banknote formed from a transparent substrate comprising an opacifying coating on both sides of the substrate. The opacifying coating is omitted in localised regions on both sides of the substrate to form a transparent region. In this case the transparent substrate can be an integral part of the security element or a separate security element can be applied to the transparent substrate of the document. WO 0039391 A1 describes a method of making a transparent region in a paper substrate. Use of full or half-window features in this way allows the security element to be applied to one side of the security document for viewing from the opposite side, through the window.
[0102] The security element may also be applied to one side of a paper substrate, optionally so that portions are located in an aperture formed in the paper substrate. An example of a method of producing such an aperture can be found in WO 03054297 A2. An alternative method of incorporating a security element which is visible in apertures in one side of a paper substrate and wholly exposed on the other side of the paper substrate can be found in WO 2000/39391 A1.
[0103] The security element of the current invention can be made machine readable by the introduction of detectable materials in any of the layers or by the introduction of separate machine-readable layers. Detectable materials that react to an external stimulus include but are not limited to fluorescent, phosphorescent, infrared absorbing, thermochromic, photochromic, magnetic, electrochromic, conductive and piezochromic materials.
[0104] Particularly in embodiments in which the plasmonic nanostructures include a continuous metal layer, the security element can be used to conceal the presence of a machine readable dark magnetic layer. When a magnetic material is incorporated into the device the magnetic material can be applied in any design but common examples include the use of magnetic tramlines or the use of magnetic blocks to form a coded structure. Suitable magnetic materials include iron oxide pigments (Fe.sub.2O.sub.3 or Fe.sub.3O.sub.4), barium or strontium ferrites, iron, nickel, cobalt and alloys of these. In this context the term “alloy” includes materials such as Nickel:Cobalt, Iron:Aluminium:Nickel:Cobalt and the like. Flake Nickel materials can be used, in addition Iron flake materials are suitable. Typical nickel flakes have lateral dimensions in the range 5-50 microns and a thickness less than 2 microns. Typical iron flakes have lateral dimensions in the range 10-30 microns and a thickness less than 2 microns.
[0105] FIG. 25 shows a surface shaped to define a diverging Fresnel mirror. A diverging Fresnel mirror is essentially an arrangement of facets that substantially replicate the surface of a convex mirror, but eliminate the unnecessary thickness towards the centre of the mirror arrangement by providing each facet at substantially the same height. This structure operates on the same principle as Fresnel lenses, which are well known in the art. These structures have the advantage of reduced thickness compared with the convex structure they emulate. The facets of the diverging Fresnel mirror shown are substantially planar to approximate respective areas of the replicated convex structure, but could also be convex to more accurately replicate a convex structure.
