LIQUID CRYSTAL COMPOSITION AND DIMMING DEVICE THEREOF

Abstract

A liquid crystal composition includes a component A composed of one or more liquid crystals with negative dielectric anisotropy and a component B composed of one or more compounds selected from a general formula I, where the optical anisotropy of the liquid crystal composition is larger than 0.14. The elastic coefficient of a liquid crystal system is adjusted by introducing a bi-mesogenic compound into a negative liquid crystal or a negative liquid crystal mixture. When the liquid crystal composition is used for the dimming device, the minimum light transmittance of the dimming device in the dark state can be significantly reduced, the adjustment range of the light transmittance in the light state and the dark state can be expanded, and the haze in the dark state can be increased, thereby broadening the use range.

##STR00001##

Claims

1. A liquid crystal composition, comprising: Component A consists of one or more negative liquid crystals; Component B consists of one or more compounds selected from the group of compounds of formula I; and Component C consists of one or more ionic compounds; ##STR00072## wherein, R.sub.1 and R.sub.2 each independently denote —H, —F, —Cl, —CN, —NCS or a chain alkyl group with 1 to 25 C atoms where one or more H atoms may be independently substituted by halogen or CN and one or more nonadjacent —CH.sub.2— may be independently replaced by —O—, —S—, —NH—, —N(CH.sub.3)—, —CO—, —COO—, —OCO—, —OCOO—, —SCO—, —COS—, —CH═CH—, —CH═CF—, —CF═CF— or —C═C— in such a manner that two —O— are not directly adjacent to one another, MG.sub.1 and MG.sub.2 each independently denote a mesogenic group, X is a straight-chain or branched alkyl group with 1, 3 or 5-40 C atoms where one or more nonadjacent —CH.sub.2— may be independently replaced by —O—, —S—, —NH—, —N(CH.sub.3)—, —CO—, —COO—, —OCO—, —OCOO—, —SCO—, —COS—, —CH═CH—, —CH═CF—, —CF═CF—, —C═C— or —CH(CN)—in such a manner that no two —O— are adjacent to one another or no two groups selected from —OCO—, —SCO—, —OCOO—, —COS—, —COO— and —CH═CH— are adjacent to each other, the optical anisotropy of the liquid crystal composition is greater than 0.14.

2. The liquid crystal composition of claim 1, wherein mesogenic group is selected from the group of formula II ##STR00073## wherein, H.sub.1, H.sub.2, H.sub.3 and H.sub.4 each independently denote a ring structure selected from the group of ##STR00074## ##STR00075## ##STR00076## ##STR00077## ##STR00078## ##STR00079## ##STR00080## ##STR00081## ##STR00082## ##STR00083## ##STR00084## ##STR00085## ##STR00086## ##STR00087## ##STR00088## ##STR00089## ##STR00090## ##STR00091## ##STR00092## ##STR00093## ##STR00094## ##STR00095## ##STR00096## ##STR00097## ##STR00098## wherein 1-4 H atoms of the ring structures may be independently substituted by halogen, CN or a chain alkyl group with 1-7 C atoms where at least one —CH.sub.2— may be replaced by —CHO—, —CO—, —COO— or —OCO— and at least one H atom may be substituted by F or Cl, B.sub.1, B.sub.2 and B.sub.3 each independently denote—COO—, —OCO—, —OCOO—, —OCH.sub.2—, —CH.sub.2O—, —CF.sub.2O—, —(CH.sub.2).sub.2—, —(CH.sub.2).sub.4—, —C═C—, —CH═CH—, —CF.sub.2CF.sub.2—, —CF═CF—, —CH═CH—COO—, —OCO—CH═CH— or a single bond, p, q and r is 0 or 1.

3. The liquid crystal composition of claim 2, wherein the mesogenic group each independently comprises at least two six-membered rings.

4. The liquid crystal composition of claim 3, wherein the mesogenic group is each independently selected from the group of ##STR00099## ##STR00100## ##STR00101## ##STR00102## ##STR00103## ##STR00104## ##STR00105## ##STR00106## and their mirror structures, wherein 1-4 H atoms of the six-membered ring may be independently substituted by halogen, CN or a chain alkyl group with 1-7 C atoms where one or more nonadjacent —CH.sub.2— may be replaced by —CHO—, —CO—, —COO— or —OCO— and one or more H atoms may be substituted by F or Cl.

5. The liquid crystal composition of claim 1, wherein R.sub.1 and R.sub.2 each independently denote —F, —Cl, —CN, —OCF.sub.3, —CF.sub.3 or an unsubstituted chain alkyl group with 1-10 C atoms.

6. The liquid crystal composition of claim 1, wherein X is selected of formula III ##STR00107## wherein, Y.sub.1 and Y.sub.2 each independently denote —COO—, —OCO—, —O—, —CH═CH—, —CF.sub.2O—, —OCF.sub.2—, —CF.sub.2CF.sub.2— or a single bond, and s is an odd number between 3-13.

7. (canceled)

8. The liquid crystal composition of claim 1, wherein the liquid crystal composition further comprises one or more dyes.

9. The liquid crystal composition of claim 8, wherein the dye is a dichroic dye.

10. The liquid crystal composition of claim 1, wherein the liquid crystal composition further comprises a light stabilizer and an UV inhibitor.

11. The liquid crystal composition of claim 1, wherein the component B is 1%-20% by weight of the liquid crystal composition.

12. A light modulating device comprising the liquid crystal composition of claim 1, and further comprising: an upper transparent substrate and a lower transparent substrate, wherein the inner surfaces of the upper transparent substrate and the lower transparent substrate are respectively provided with an upper transparent electrode and a lower transparent electrode; and a liquid crystal layer disposed between the upper transparent substrate and the lower transparent substrate, which contains the liquid crystal composition; wherein, the light modulating device is in a transparent state when no voltage is applied, and is in a dark state when a voltage is applied.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0030] The present invention can be better understood through the illustration of the following embodiments, wherein:

[0031] FIG. 1 illustrates the voltage-transmittance (V-T) curve of comparative example and Example 1.

DETAILED DESCRIPTION OF THE INVENTION

[0032] The following description of the disclosed embodiments is provided in detail to enable any person skilled in the art to fully understand the present invention. However, the present invention can be practiced without these specific details to those skilled in the art. In this regard, the description of the different illustrative exemplary embodiments presented herein are for the purpose of illustration and description and are not intended to be exhaustive or limited to the inventive concept. Accordingly, the scope of the invention is not to be limited by the specific embodiments described above, and is subject only to the scope of the appended claims.

[0033] Components used in following examples can be either synthesized using a known method or purchased from a commercial supplier. These synthetic methods are conventional and each of the obtained liquid crystal compounds should meet the standards for electronic compounds.

[0034] First, the present invention discloses a liquid crystal composition and a light modulating device thereof. The light modulating device comprises: an upper transparent substrate, a lower transparent substrate, wherein the inner surfaces of the upper transparent substrate and the lower transparent substrate are respectively provided with an upper transparent electrode and a lower transparent electrode, a liquid crystal layer containing the liquid crystal composition disposed between the upper transparent substrate and the lower transparent substrate. When no voltage is applied, the liquid crystal molecules in the liquid crystal layer are arranged perpendicular to the surface of the light modulating device and the incident light is substantially transmitted through the device, so that the device is in transparent state. When an external voltage is applied, the liquid crystal molecules are driven towards being parallel to the surface of the device, and the elastic property of the liquid crystal composition is such that the incident light is scattered forwards and backwards, furthermore, the light transmittance of the device is reduced, the device is in dark state and the haze is increased. The degree of incident light scattering is dependent on the amplitude of the applied electric field.

[0035] The liquid crystal composition comprises component A and component B. Component A consists of one or more negative liquid crystals. In the following examples, component A is selected from commercially available negative liquid crystal mixtures BHR 28100-400 (purchased from Beijing Bayi Space LCD Technology Co., Ltd.). Component B is a liquid crystal compound comprising two mesogenic groups, that is, two groups capable of inducing a liquid crystal phase. Due to the flexible chain between the two mesogenic groups, the whole liquid crystal compound forms a bended structure, thereby obtaining a relatively low bending elastic constant K.sub.33. When the liquid crystal composition of the present invention is applied to a light modulating device, the liquid crystal molecules will not form a uniform director structure, but rather a complex domained structure when a voltage is applied, thereby causing the liquid crystals to scatter light and increase haze of the dark state. Meanwhile, under the same voltage and frequency, the minimum dark state transmittance of the light modulating device can be largely decreased and the haze of the dark state can be increased, thus broadening its scope of applications. Meanwhile, in order to achieve sufficient scattering of the light modulating device in the dark state and enable the haze of the dark state to meet requirement of privacy protection, the optical anisotropy Δn of the liquid crystal composition needs to be large enough. In the present invention, the optical anisotropy Δn of the liquid crystal composition is greater than 0.14, preferably greater than 0.20.

[0036] The liquid crystal composition may further include one or more ionic compounds. The ionic compound is a compound that can be dissolved in a liquid crystal composition and thus in an ionic state. the driving voltage of the light modulating device may be effectively reduced while improving the dark-state haze. In some embodiments, the ionic compound is organic ionic compound, the organic ionic compound includes one or more selected from amine compounds, alkyl sulfate compounds, alkyl phosphate compounds and alkyl iodate compounds. The amine compound includes one or more selected from (Ferrocenylmethyl) trimethylammonium iodide, Phenyltrimethylammonium iodide, Cetyltrimethylammonium bromide, Tetrabutylammonium bromide, Tetraoctadecylammonium bromide, 1-Butyl-3-methylimidazolium tetrachloroferrate, 1-Butyl-3-methylimidazolium-L-lactate, 1-Ethyl-3-methylimidazolium-L-lactate, Cetyltrimethylammonium perchlorate, Benzyldimethylhexadecylammonium chloride, Dodecylpyridinium bromide, Hexadecylpyridinium bromide, Cetylpyridinium chloride, Cetyltributylammonium bromide, Octadecyltributylammonium bromide, Octadecyltrimethylammonium bromide, Dodecyltrimethylammonium bromide and Cetyltrimethylammonium chloride. The weight ratio of the ionic compound is generally less than 2%.

[0037] The liquid crystal composition further comprises one or more dyes in order to add color to the light modulating device. Preferably, the dye is a dichroic dye, so that the device can further adjust the light transmittance, due to the light absorption of the dichroic dye. For example, when the 10 V low voltage applies, the liquid crystal molecules along with the dye molecules rotate away from a vertical arrangement to a parallel arrangement, and, the dye molecules absorb part of the light to reduce the light transmission and darken the device. With the increase of voltage, the alignment of the liquid crystal molecules becomes non-uniform due to the influence of flexoelasticity of the liquid crystals, and the incident light is scattered, so that the light transmittance of the device continues to decrease and the haze increases. Meanwhile, with the different applied electric field, we can control the scattering degree of incident light, making the device appear in different dark states. The dye can be a commercially available dichroic dye, such as the black dye X12, black dye X13 and blue dye X15 produced by BASF, the dye is 0.1%- 5% by weight of the liquid crystal composition.

[0038] The liquid crystal composition further comprises a light stabilizer and an UV inhibitor, so that it will reduce the material decomposition and aging risk typically caused by exposure to the UV light when the light modulating device containing the liquid crystal composition is used.

[0039] In the following examples, the group structures of the liquid crystal molecules are represented by the codes listed in Table 1.

TABLE-US-00001 the code for groups of liquid crystal Code Group structure H [00064] O [00065] P [00066] P.sup.11 [00067] P.sup.12 [00068] P.sup.21 [00069] P.sup.22 [00070] N [00071] F —F n —C.sub.nH.sub.2n+1 or —C.sub.nH.sub.2n—

where, if n=3, the group is —C.sub.3H.sub.7 or —C.sub.3H.sub.6—

[0040] Generally, the liquid crystal composition was prepared in accordance with the mass ratio of each compound listed in the corresponding table of each example, and then the liquid crystal composition was filled into a liquid crystal light modulating substrate (liquid crystal cell) to determine its optical performance. The light transmittance is characterized by testing a conventional V-T curve (the test range 0-70 V), the haze is measured by the haze meter WGT-S, and the optical anisotropy Δn is measured by the Abbe refractometer at 25° C. The composition of each liquid crystal composition and its performance parameter are shown in tables below.

Comparative Example

[0041] TABLE-US-00002 formula of liquid crystal composition, parameters of the liquid crystal cell and its performance data Component Ratio / % parameters of the liquid crystal cell and its performance data BHR28100-400 100 Cell gap(.Math.m) 20 Δn 0.235 Minimum light transmittance 42.64% Maximum haze 78.80%

Example 1

[0042] TABLE-US-00003 formula of liquid crystal composition, parameters of the liquid crystal cell and its performance data Component Ratio / % parameters of the liquid crystal cell and its performance data BHR28100-400 97 Cell gap(.Math.m) 20 NPP7PPN 3 Δn 0.232 Minimum light transmittance 26.25% Total 100 Maximum haze 91.56%

[0043] Wherein, the voltage-transmittance(V-T) curve of comparative example and example 1 is shown in FIG. 1.

Example 2

[0044] TABLE-US-00004 formula of liquid crystal composition, parameters of the liquid crystal cell and its performance data Component Ratio / % parameters of the liquid crystal cell and its performance data BHR28100-400 82 Cell gap(.Math.m) 20 NPP7PPN 6 Δn 0.22 NPP9PPN 6 Minimum light transmittance 8.81% NPP11PPN 6 Maximum haze 94.15% Total 100

Example 3

[0045] TABLE-US-00005 formula of liquid crystal composition, parameters of the liquid crystal cell and its performance data Component Ratio / % parameters of the liquid crystal cell and its performance data BHR28100-400 93 Cell gap(.Math.m) 20 NPP7PPN 5 Δn 0.231 4PP7PP4 2 Minimum light transmittance 36.62% Total 100 Maximum haze 88.78%

Example 4

[0046] TABLE-US-00006 formula of liquid crystal composition, parameters of the liquid crystal cell and its performance data Component Ratio / % parameters of the liquid crystal cell and its performance data BHR28100-400 93 Cell gap(.Math.m) 20 NPP7PPN 5 Δn 0.231 FP.sup.12P9PP.sup.11F 2 Minimum light transmittance 33.69% Total 100 Maximum haze 89.54%

Example 5

[0047] TABLE-US-00007 formula of liquid crystal composition, parameters of the liquid crystal cell and its performance data Component Ratio / % parameters of the liquid crystal cell and its performance data BHR28100-400 93 Cell gap(.Math.m) 20 NPP7PPN 5 Δn 0.231 NP.sup.12P7PP.sup.11N 2 Minimum light transmittance 29.52% Total 100 Maximum haze 90.48%

Example 6

[0048] TABLE-US-00008 formula of liquid crystal composition, parameters of the liquid crystal cell and its performance data Component Ratio / % parameters of the liquid crystal cell and its performance data BHR28100-400 89.99 Cell gap(.Math.m) 20 NPP7PPN 4 Δn 0.228 NPP9PPN 3 Minimum light transmittance 6.02% NPP11PPN 3 Maximum haze 94.26% Cetyltrimethylammonium chloride 0.01 Total 100

Example 7

[0049] TABLE-US-00009 formula of liquid crystal composition, parameters of the liquid crystal cell and its performance data Component Ratio / % parameters of the liquid crystal cell and its performance data BHR28100-400 87.57 Cell gap(.Math.m) 20 NPP7PPN 3.89 Δn 0.228 NPP9PPN 2.92 Minimum light transmittance 3.46% NPP11PPN 2.92 Maximum haze 82.17% Black dye X12 2.7 Total 100

Example 8

[0050] TABLE-US-00010 formula of liquid crystal composition, parameters of the liquid crystal cell and its performance data Component Ratio / % parameters of the liquid crystal cell and its performance data BHR28100-400 84.59 Cell gap(.Math.m) 20 NPP7PPN 4.97 Δn 0.224 NPP9PPN 4.97 Minimum light transmittance 4.95% NPP11PPN 4.97 Maximum haze 90.01 Black dye X12 0.5 Total 100

Example 9

[0051] TABLE-US-00011 formula of liquid crystal composition, parameters of the liquid crystal cell and its performance data Component Ratio / % parameters of the liquid crystal cell and its performance data BHR28100-400 84.8 Cell gap(.Math.m) 20 NPP7PPN 5 Δn 0.223 NPP9PPN 5 Minimum light transmittance 33.74% NPP11PPN 5 Maximum haze 90.67% NPPO5OPPN 0.2 Total 100

[0052] From the above examples and comparative example, it is demonstrated that the light modulating device containing the liquid crystal composition of the present invention has a significantly reduced minimum dark state light transmittance and increased haze, therefore, the tuning range of the light transmittance of the light modulating device is increased, broadening the field of the application for the devices.

[0053] While several specific exemplary embodiments have been described above in detail, the disclosed embodiments are considered illustrative rather than limiting. Those skilled in the art will readily realize that alternatives, modifications, variations, improvements, and substantial equivalents are possible without substantially departing from the novelty spirits or scope of the present disclosure. Thus, all such alternatives, modifications, variations, improvements, and substantial equivalents are intended to be embraced within the scope of the present disclosure as defined by the appended claims.

Industrial Applicability

[0054] The liquid crystal composition and the light modulating devices using the same can be applied to the field of liquid crystals.