Abstract
An ozone generator system utilizes an electrochemical cell to produce and control ozone concentrations within an enclosure or to supply ozone to a flow conduit. The enclosure may he coupled with a flow conduit that carries the produced ozone to a desired location. An enclosure may be a sterilization chamber and the concentration of ozone produced by the ozone generating system may be sufficient to sterilize articles within the enclosure. An oxygen control electrolyzer cell and/or humidity control electrolyzer cell may be coupled with the enclosure to further control the environment of the enclosure. A humidity control electrolyzer cell may be fluidly coupled with the ozone generator to supply humidity for reaction on the anode of the ozone generator.
Claims
1. An ozone generator system that is coupled with an enclosure and comprises: a) an ozone producing electrochemical cell, b) a controller; wherein an ozone concentration within the enclosure is increased by the electrochemical cell.
2. The ozone generator system of claim 1, wherein the ozone producing electrochemical cell comprises: a) a proton exchange membrane; b) an anode; c) a cathode wherein the anode and cathode are configured on opposing sides of the proton exchange membrane.
3. The ozone generator system of claim 2, wherein the proton exchange membrane comprises an ionomer and wherein the ionomer comprises a perfluorosulfonic acid polymer.
4. The ozone generator of claim 1, further comprising an inlet anode conduit to supply a flow of air for reaction on the anode to form said ozone.
5. The ozone generator system of any of claim 4, wherein the inlet anode conduit is in fluid communication with an inside volume of the enclosure.
6. The ozone generator system of any of claim 1, wherein the anode is in fluid communication with an inside volume of the enclosure.
7. The ozone generator system of claim 6, comprising an outlet anode conduit that is coupled with an enclosure.
8. The ozone generator system of claim 1, wherein the enclosure is a sealed enclosure having a defined interior volume.
9. The ozone generator system of claims 1, wherein the enclosure is a sterilization enclosure.
10. The ozone generator system of claims 1, comprising a plurality of membrane electrode assemblies.
11. The ozone generator system of claims 1, wherein the membrane electrode assembly is configured into an electrochemical cell that is coupled with a power supply that is controlled by the controller.
12. The ozone generator system of claims 1, further comprising an air moving device configured to force a flow of air over the anode.
13. The ozone generator system of claim of claim 12, wherein the air moving device comprises a cowl induction frame that captures the air flow and moisture around the fan and channels it to the cell.
14. The ozone generator system of claim of claim 1, further comprising an environment control system that is coupled with the enclosure and comprises: a) an oxygen control electrolyzer cell, wherein the oxygen control electrolyzed cell comprises: i) an ion exchange medium; ii) an anode; iii) a cathode; wherein the anode and cathode are configured on opposing sides of the ion exchange medium; wherein the oxygen control electrolyzes cell is in fluid communication with said enclosure; and wherein a power source is coupled with the anode and cathode to provide an electrical potential across the anode and the cathode to initiate electrolysis of water, wherein water is reacted to form reactants on the anode and the cathode to control the humidity level of the enclosure; b) a controller that is coupled with the power source and the oxygen control electrolyzer cell to control electrical potential across the anode and the cathode; wherein an oxygen concentration within the enclosure is controlled by the oxygen control electrolyzer and a humidity level is controlled within the enclosure by the humidity control device.
15. The ozone generator system of claim of claim 15, wherein the environment control system is fluidly coupled with an anode chamber of the ozone generator, and wherein the environment control system produces water that is provided to the anode of the ozone generator.
16. The ozone generator system of claim at claim 14, further comprising a humidity control device.
17. A method of controlling an environment within an enclosure comprising the steps on a) providing an ozone generator system that is coupled with an enclosure and comprises: i) an ozone producing electrochemical cell comprising: a proton exchange membrane; an anode; a cathode wherein the anode and cathode are configured on opposing sides of the proton exchange membrane; ii) a controller; b) applying a voltage potential across the anode and cathode; c) forming ozone on the anode side; wherein the anode side is in fluid communication with the enclosure, and wherein an ozone concentration within the enclosure is increased by the ozone formed by the electrochemical cell.
18. The method of controlling an environment within an enclosure of claim 17, further comprising the steps of: a) providing an oxygen control electrolyzer cell, wherein the oxygen control electrolyzer cell comprises: i) an ion exchange medium; ii) an anode; iii) a cathode; wherein the anode and cathode are configured on opposing sides of the ion exchange medium; wherein the oxygen control electrolyzer cell is in fluid communication with said enclosure; and b) providing a contra controller that is coupled with a power source and the oxygen control electrolyzer cell to control electrical potential across the anode and the cathode; c) applying a voltage potential across the anode and cathode with the power source; d) reacting oxygen within the enclosure on said cathode of the oxygen control electrolyzer cell to reduce an oxygen concentration within the enclosure.
19. The method of controlling an environment within an enclosure of claim 8, wherein the oxygen control electrolyzer cell produces water on the cathode of the oxygen control electrolyzer cell and wherein the cathode of the oxygen control electrolyzer cell is in fluid communication with and supplies water to the anode of the ozone producing electrochemical cell for reaction to form ozone.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0050] The accompanying drawings are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention, and together with the description serve to explain the principles of the invention.
[0051] FIG. 1 shows an exemplary electrochemical cell comprising a membrane electrode assembly connected to a circuit for delivery of power from a power source, wherein electrolysis of water on the anode side produces protons that are transported across the ion conducting membrane to the cathode side.
[0052] FIG. 2 shows an exemplary environment control system comprising an electrochemical cell coupled with an enclosure.
[0053] FIG. 3 shows an exemplary environment control system configured at least partially within an enclosure.
[0054] FIG. 4 shows an exemplary environment control system comprising two electrolyzer cells coupled with an enclosure.
[0055] FIG. 5 shows an exemplary environment control system comprising two electrolyzer cells coupled with an enclosure with one of the cells having the anode in fluid communication with the enclosure and the other cell having the cathode in fluid communication with the enclosure.
[0056] FIG. 6 shows a diagram of an exemplary environment control system having a separator to draw moisture from the oxygen control chamber.
[0057] FIG. 7 shows a diagram of an exemplary environment control system having an exchange conduit through the conditioner chamber that exchanges moisture through a separator.
[0058] FIG. 8 shows a diagram of an exemplary environment control system having a serpentine exchange conduit through the conditioner chamber to enable effective moisture transfer from the exchange conduit to the conditioner chamber.
[0059] FIG. 9 shows a diagram of an exemplary environment control system having a recirculation loop between the conditioner chamber and the anode side of oxygen depletion electrolyzer cell.
[0060] FIG. 10 shows a diagram of an exemplary environment control system having a water chamber and an oxygen bleed valve.
[0061] FIG. 11 shows a diagram of an exemplary environment control system having an enclosure filter, a conditioner chamber and inlet and outlet filters to the conditioner chamber.
[0062] FIG. 12 shows a front view of a safe having a lock on the front door.
[0063] FIG. 13 show a back view of the safe shown in FIG. 12 with an exemplary environment control system coupled to the back.
[0064] FIG. 14 shows a front view of a wine cooler having a front door to the interior of the enclosure.
[0065] FIG. 15 show a back view of the wine cooler shown in FIG. 14 with an exemplary environment control system coupled to the back.
[0066] FIG. 16 shows a front perspective view of a humidor having a door to the interior of the enclosure on the top.
[0067] FIG. 17 show a bottom perspective view of the humidor shown in FIG. 16 with an exemplary environment control system coupled to the bottom.
[0068] FIG. 16 show a bottom perspective view of the humidor shown in FIG. 15 with an exemplary environment control system coupled to the bottom.
[0069] FIG. 18 shows a side view of an exemplary environment control system configured to control the environment of growing enclosure, such as a vase or pot for growing a plant.
[0070] FIG. 19 shows a perspective vie of an exemplary environment control system having two electrolyzer cells for placement of an enclosure thereon.
[0071] FIG. 20 show a person sleeping with the aid of a Positive Airway Pressure, PAP, device having an exemplary environment control system.
[0072] FIG. 21 shows a perspective exploded view of an exemplary electrolyzer cell.
[0073] FIG. 22 show a perspective view of an exemplary environment control device.
[0074] FIG. 23 shows a graph of an enclosure temperature and humidity with and without a fan blowing onto the cathode of a humidity control electrolyzer.
[0075] FIG. 24 shows a perspective view of exemplary oxygen control electrolyzer cell configured with an MEA air moving device to produce a flow of process air onto the anode of the membrane electrode assembly
[0076] FIG. 25 shows an exploded view of an exemplary oxygen control electrolyzer cell configured with an MEA air moving device to produce a flow of process air onto the anode of the membrane electrode assembly
[0077] FIG. 26 shows a diagram of a corona discharge ozone generating device.
[0078] FIG. 27 shows an exemplary ozone generating electrode assembly connected to a circuit for power, wherein electrolysis of water on the anode side produces protons that are transported across the ion conducting membrane to the cathode side.
[0079] FIG. 28 shows an exemplary ozone generator system comprising a membrane electrode assembly, MEA, a part of the electrochemical cell coupled with an enclosure and producing ozone within the enclosure.
[0080] FIG. 29 shows an exemplary ozone generator system in fluid communication with an enclosure.
[0081] FIG. 30 shows an exemplary ozone generator system configured at least partially within an enclosure.
[0082] FIG. 31 shows a perspective view of the components of an exemplary environment control system having a fan that directs air over the anode.
[0083] FIG. 32 shows a diagram or an exemplary ozone generator device having a plurality of ozone generators coupled with an enclosure, or control tank, as shown.
[0084] Corresponding reference characters indicate corresponding parts throughout the several views of the figures. The figures represent an illustration of some of the embodiments of the present invention and are not to be construed as limiting the scope of the invention in any manner. Further, the figures are not necessarily to scale, some features may be exaggerated to show details of particular components. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for teaching one skilled in the art to variously employ the present invention.
DETAILED DESCRIPTION OF THE ILLUSTRATED EMBODIMENTS
[0085] As used herein, the terms “comprises,” “comprising,” “includes,” “including,” “has,” “having” or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Also, use of “a” or “an” are employed to describe elements and components described herein. This is done merely for convenience and to give a general sense of the scope of the invention. This description should be read to include one or at least one and the singular also includes the plural unless it is obvious that it is meant otherwise.
[0086] Certain exemplary embodiments of the present invention are described herein and are illustrated in the accompanying figures. The embodiments described are only for purposes of illustrating the present invention and should not be interpreted as limiting the scope of the invention. Other embodiments of the invention, and certain modifications, combinations and improvements of the described embodiments, will occur to those skilled in the art and all such alternate embodiments, combinations, modifications, improvements are within the scope of the present invention.
[0087] FIG. 1 shows an exemplary environment control system 10 that utilizes an electrochemical cell 12 comprising a membrane electrode assembly 30 connected to a circuit 31 for delivery of power from a power source 87. The anode 20 of the MEA reacts with water to produce oxygen and protons. The protons H.sup.+ pass through proton conducting layer such as an ionomer, an example of an ion exchange medium 32, to the cathode 40. Water is pulled through the ionomer along with the protons. At the cathode, the protons react with oxygen and produce water, thereby reducing the oxygen at the cathode and increasing water. The cathode is in fluid communication with the enclosure 50 and therefore reduces the oxygen concentration and increases the moisture or RH of the enclosure. The electrochemical cell also includes a gas diffusion layer 39, a flow field 38 and a current collector 33, configured on both the anode and cathode.
[0088] As shown in FIG. 2, an exemplary electrochemical cell 12 utilizes a, membrane electrode assembly, MEA 30, connected to a circuit 31 for power. As shown, this is an oxygen control electrolyzer cell 16 that is reducing oxygen concentration in the enclosure 50. An electrical potential is created across the anode and cathode to initiate the electrolysis of water on the anode 20, that produces oxygen and protons that are transported across the ion conducting media 32 or membrane, or ionomer, to the cathode 40. A chamber is configured on the anode side 21 for receiving incoming air and water moisture and a chamber or space on the cathode side 41 is in fluid communication with an enclosure 50, such as through one or more openings 51 into the enclosure. On the cathode, the protons are reacted with oxygen to produce water. Oxygen is depleted on the cathode side and water is produced. The protons also drag water across the ionomer from the anode side to the cathode side. On the anode side, oxygen is produce and water is consumed in electrolysis reaction that produces oxygen and protons. The membrane electrode assembly is coupled between two electrical current collectors 33, or electrically conductive layers, that provide the electrical power to the MEA. An electrical conductor plate, may be a screen or perforated metal and may be the gas diffusion media and/or a flow field. A flow field 38 may have a plurality of channels for distributing gasses to the surface of the MA or gas diffusion media. A gas diffusion media 39 may further distribute gas to the anode and cathode. A sensor 82, such as a humidity sensor 83 and/or oxygen sensor 84, may be coupled with a control system 80 for maintaining the humidity and/or oxygen level within the enclosure to a desired level. A user input 85 may be used to set a desired level or range of humidity and/or oxygen concentration within the enclosure and a micro-processor 81 may control the power supply to the electrochemical cell to keep the oxygen and humidity within the set points by the user. The electrochemical cell may be run in the opposite direction, wherein the anode is in fluid communication with the enclosure and reduces moisture and increase oxygen concentration.
[0089] As shown in FIG. 3, an exemplary environment control system 10 comprises an electrochemical cell 12 at least partially configured within the enclosure 50. As shown, this is an oxygen control electrolyzer cell 16 that is reducing oxygen concentration in the enclosure 50. In this embodiment, the MEA 30 may be run in a direction to produce moisture within the enclosure or to pump moisture out of the enclosure. An inlet/outlet conduit 25 on the anode side 21 extends out of the enclosure. Again, the electrochemical cell may be run to increase or decrease the humidity and/or oxygen concentration within the enclosure. The cell can be operated to pump water into the enclosure or operated to pump water out of the enclosure by changing the polarity across the anode and cathode. The humidification control system may provide humid air to the enclosure by control of the circuit power to drive the electrolysis of water. A sensor 82, such as a humidity sensor 83, monitors humidity and relays this measured value to the controller system 80. A processor 81 may control the amount of power, voltage and/or current to the MEA to control the amount of humid air provided to the enclosure. A user interface 85, as shown by the up and down arrows may be used to adjust the humidity level within the enclosure. The cathode side of the electrochemical cell is coupled with and enclosure and will reduce the oxygen level, while increasing the humidity level.
[0090] Referring now to FIGS. 4 and 5, an exemplary environment control system 10 comprises two electrochemical cells 12, 12′ in fluid communication with the enclosure 50. The two cells may be operated in the same mode, such as oxygen depletion and humidification mode, as shown in FIG. 4, wherein the cathode is in fluid communication with the enclosure, thereby increase the rate of oxygen reduction within the enclosure and humidity increase within the enclosure. The two cells may also be operated in an oxygen increase and humidity reduction mode, wherein the anode is in fluid communication with the enclosure, thereby increasing the rate of oxygen increase and humidity reduction within the enclosure. Furthermore, the two electrochemical cells, may be operated in opposing modes, as shown in FIG. 5, wherein one electrochemical cell is configured to reduce oxygen concentration within the enclosure and one is configured to increase oxygen within the enclosure. In this opposing operation mode, the two cell may somewhat counteract each other and may be less effective.
[0091] As shown in FIG. 6, an exemplary environment control system 10 has two electrochemical cells 12, 12′ coupled with a conditioner chamber 62 and a separator 58 configured between the oxygen control chamber 60 and the humidity control chamber 70. An oxygen control electrolyzer cell 16 has the anode cathode 40 in fluid communication with the oxygen control chamber 60 and a humidity control electrolyzer cell 17 has the anode 20′ in fluid communication with the humidity control chamber 70. The separator membrane, as described herein, allows moisture to be transferred between the oxygen and humidity control chambers, but limits the transfer of oxygen, since it is essentially air impermeable. Therefore, when there is a differential in humidity levels between the oxygen control chamber 60 and the humidity control chamber 70, humidity will pass through the separator 58. The separator may be an ionomer membrane for example. The humidity control chamber 70 has the anode 20′ of the second electrochemical cell 12′ in fluid communication to reduce humidity and increase oxygen concentration. This reduces humidity level will cause humidity from the oxygen control chamber 60 to pass through the separator and therefore reduce the humidity level in the oxygen control chamber. In this way, the oxygen control chamber may have a reduces oxygen concentration and a reduce humidity concentration, which is desirable for many types of enclosures. A fan 97 may be configure to control the flow from the oxygen control chamber to the enclosure 50, through the enclosure wall 55. An inlet exchange conduit 57 is configured with a filter 67 and the outlet exchange conduit 59 is also configured with a filter 69. A fan 97 or other air moving device is configured to force flow and exchange between the enclosure and the conditioner chamber 62, and specifically the oxygen control chamber 60. A fan and valve may be configured on the oxygen control chamber 60 or the humidity control chamber 70 to allow exchange with the outside environment. The concentration of humidity and/or oxygen may require an air exchange with the outside air, for example. A desiccant 90 and filter 93 are configured to reduce the humidity concentration in the humidity control chamber and may reduce the moisture from air being drawn into the humidity control chamber or may be configured in a circulation loop of the humidity control chamber, as shown in FIG. 8, for example. A desiccant may be replaced periodically as required by the application. A controller 80 may utilize inputs from sensors 83,84 to control the operation of the environment control system 10.
[0092] As shown in FIGS. 7 and 8, an exemplary environment control system 10 has an exchange conduit 61 as an oxygen control chamber 60 with an inlet 57 and outlet 59. The exchange conduit 61 extends within the conditioner chamber, wherein at least a portion of the exchange conduit is configured with a separator 58 to allow moisture to pass from the exchange conduit, or oxygen control chamber, into the humidity control chamber 70 portion of the conditioner chamber 62. In this embodiment, more surface area may be provided for the separator. In addition, the humidity control chamber may be configured with a dehumidification loop 91 that circulates gases from the humidity control chamber through a desiccator 90. A fan 97 is configured to move gasses through the dehumidification loop. As shown in FIG. 8, the exchange conduit 61 is serpentine, to provide additional separator 58 exchange surface area. Again, any number of valves 98 and fans 97 may be used to exchange gasses within the chambers with the outside environment, as described herein. A condenser 64 is also shown in the dehumidification loop. A condenser and/or desiccant or desiccator may be configured in the dehumidification loop.
[0093] As shown in FIG. 9, a portion of the humidity control chamber 70 gas is fed to the anode side of the electrochemical cell 12, an oxygen control electrolyzer cell 16 operating as an oxygen depletion electrolyzer cell. The oxygen depletion electrolyze cell is configured with the cathode 40 in fluid communication with the oxygen control chamber 60 and the humidity control electrolyzer cell 17, acting as a humidity reduction electrolyzer cell, is configured with the anode 20′ in fluid communication with the humidity control chamber 70. The humidity control chamber may comprise moisture that can be consumed by the reaction at the anode of the oxygen depletion electrolyzer cell, wherein water is converted to oxygen and protons. A fuel loop 68 is configured to direct humidity control chamber gas to the anode of the oxygen depletion electrolyzer cell. In this way, the moisture can be reduced in the humidity control chamber 70 while providing the necessary fuel to the anode of the oxygen depletion electrolyzer cell. Again, any number of valves 98 and fans 97 may be used to exchange gasses within the chambers with the outside environment, as described herein. A condenser 64 is also shown in the dehumidification loop. A condenser and/or desiccant or desiccator may be configured in the dehumidification loop.
[0094] As shown in FIG. 10, an exemplary environment control system 10 has a water chamber 65 with a pervaporation layer 66 between the water chamber and the oxygen control electrolyzer cell. The pervaporation layer may be an ionomer membrane or any other material that allow water vapor to transfer through without any bulk flow of air, as described herein. A condenser 64 is configured condense humidity into liquid water from the conditioner chamber 62. In this embodiment, a single electrochemical cell 12 is utilized to reduce the oxygen concentration in the oxygen control chamber 60 of the conditioner chamber 62, which is in fluid communication with the enclosure 50 through the condenser. The condenser is configured to draw gas from the oxygen control chamber 60. In one embodiment, there is no separator between the oxygen control chamber and the humidity control chamber and the gas fed to the condenser is drawn from the conditioner chamber generally and the electrochemical cell reduces oxygen from this same conditioner cell. However, as shown, the oxygen control chamber is configured with an opening to the condenser, a valve 98 is shown here. The gas in the oxygen control chamber has a reduced oxygen concentration and an increased humidity level, or water content. An oxygen bleed valve 99 may be configured to bleed the gases from the oxygen control chamber or any portion of the conditioner chamber. Gas is drawn into the condenser and the water vapor is condensed and collects in the bottom of the condenser, wherein it can be fed to through a valve 73 to a water chamber 65, or fuel chamber for the oxygen control electrolyzer cell 16 acting as an oxygen depletion electrolyzer cell. This may be a way of providing the water required to the oxygen depletion electrolyzer cell, especially in arid environments. The pervaporation separator 66 keeps any contaminates in the water from fouling or poisoning the catalyst of the anode. A valve may be opened when required to draw in more air to the cathode side of the oxygen reduction electrolyzer cell.
[0095] As shown in FIGS. 6 to 10, a MEA air moving device 44 is configured to produce a flow of process air, or forced air onto the anode of the oxygen control electrolyzer cell 16. The forced air may impinge directly onto the anode as shown in FIGS. 6 to 9 or may flow across the MEA, as shown in FIG. 10. As shown in FIGS. 6 to 9 an MEA air moving device 44 is couple with the humidity control electrolyzer cell 17 and configured to produce a flow of process air onto the anode of the humidity control electrolyzer cell. As described herein, the flow of process air onto the anode can greatly improve the performance of the cell.
[0096] As shown in FIG. 11, an exemplary environment control system 10 has an enclosure filter 52 to the enclosure 50, and inlet and outlet filters to the conditioner chamber 62. An activated carbon may be used in the enclosure filter to protect the MEA from contaminates inside the enclosure. The conditioner chamber may also comprise inlet and/or outlet filters to protect the MEA from contaminants from the ambient air. This humidification control system has a single electrochemical cell 12, a humidification control electrochemical cell 17 that may be run with the anode or the cathode in fluid communication with the enclosure. Likewise, it may be an Oxygen control electrochemical cell.
[0097] As shown in FIGS. 12 and 13, an exemplary environment control system 10 is configured to control the environment within a safe 110. The front of the safe, as shown in FIG. 12 has a door 111 to form an enclosure 50. The environment control system 10 is configured on the back side of the safe, as shown in FIG. 13, and may control the level of oxygen and/or humidity within the safe enclosure.
[0098] As shown in FIGS. 14 and 15, an exemplary environment control system 10 is configured to control the environment within a refrigerator 119, in this a wine cooler. The front of the wine cooler, as shown in FIG. 14 has a door 11 to form an enclosure 50. The environment control system 10 is configured on the back side of the wine cooler, as shown in FIG. 15, and may control the level of oxygen and/or humidity within the refrigerator.
[0099] As shown in FIG. 16 and 17, an exemplary environment control system 10 is configured to control the environment within a humidor 114. The top of the humidor, as shown in FIG. 16 has a door 11 to form an enclosure 50. The environment control system 10 is configured on the bottom of the humidor, as shown in FIG. 17, and may control the level of oxygen and/or humidity within the humidor enclosure.
[0100] As shown in FIG. 18, an exemplary environment control system 10 is configured to control the environment of growing enclosure 117, such as a vase or pot for growing a plant. The environment control system 10 may control the humidity and/or oxygen level of the space below the plant or dirt within the enclosure 50.
[0101] As shown in FIG. 19, an exemplary environment control system 10 has two electrochemical cells 12,12′ for placement of an enclosure thereon.
[0102] FIG. 20 shows a person 101 sleeping with the aid of a Positive Airway Pressure (PAP) device 100. The PAP device or breathing device has a flow generator (PAP machine) 102 that provides the airflow to the hose 104 that connects the patient interface 106. The hose connects the flow generator (sometimes via an in-line humidifier) to the interface 106. An interface includes, but is not limited to, a nasal or full face mask, nasal pillows, or less commonly a lip-seal mouthpiece, provides the connection to the user's airway or respiratory system, such as through the nose or mouth. An exemplary environment control system 10 is attached to the flow generator 102 or enclosure of the flow generator 50 and may be used to increase the level of oxygen and/or humidity within the pressurized flow delivered to the person. A PAP device, as used herein, includes all of the variations of breathing aid devices described herein.
[0103] As shown in FIG. 21, an exemplary electrolyzer cell comprises a filter 94, MEA fan 44, housing components 43, 43′, flow fields 38, 38′, current collector 33, membrane electrode assembly 30, gas diffusion media 39, and a gasket 45. This assembly has a fan configured to blow air directly onto the MEA 30. As described herein, this improves performance of the MEA.
[0104] As shown in FIG. 22, an exemplary environment control device 10 comprises an oxygen control electrolyzer cell 16 and a humidity control electrolyzer cell 17 configured around a conditioner chamber 62. An MEA air moving device 44, such as a fan, is configured to produce a flow of process air 46, which is a flow of forced air, onto the anode of the oxygen control electrolyzer cell 16. As described herein, this greatly increases the efficiency of the oxygen control electrolyzer cell 16. The air moving device 44 is coupled directly to the MEA and has close proximity to the anode which may be important for improved efficiency. An MEA air moving device 44′, such as a fan, is configured between the humidity control electrolyzer cell 17 and the conditioner chamber 62 to produce a flow of process air 46′ onto the anode of the humidity control electrolyzer cell 17. This fan may be configured within the conditioner chamber with the MEA of the humidity control electrolyzer cell being sealed against the conditioner chamber. Electrical contacts are coupled to each of the electrolyzer cells to provide a potential across the anode and cathode.
[0105] FIG. 23 shows a graph an enclosure temperature and humidity with and without a fan blowing onto the anode of a humidity control electrolyzer. The data shows that the humidity was reduced much more quickly when the electrolyzer was operated with a fan blowing directly onto the MEA to produce a flow of process air, or forced air, onto the anode of the humidity control electrolyzer cell.
[0106] Referring now to FIGS. 24 and 25, an exemplary oxygen control electrolyzer cell 16, is configured with an MEA air moving device 44, such as a fan, configured to produce a flow of process air 46 onto the anode 20 of the membrane electrode assembly 30. A water chamber 65 is configured around a forced air opening 48 to allow the forced air to impinge directly onto the MEA or anode 20 of the MEA. A pervaporation layer 66 that allows the transport of water therethrough, but prevents the bulk flow of air, extends around the forced air opening to provide water or moisture to the MEA. A gasket 71 seals the pervaporation layer to the MEA. The flow of process air impinges directly onto the anode side 21 of the MEA 30 and the cathode side 41 or cathode 40 of the MEA may be sealed to a conditioner chamber, not shown. A data interface 86 is configured to allow coupling of a data storage and/or a data transmitter. Data related to the environment control device, such as humidity level, oxygen level, temperature, MEA voltage potential and the like may be stored and/or transferred to remote location. A fill port 63 for receiving fluid, such as water for hydrating the ion conducting media, such as an ionomer is shown. The port may receive water or fluid from a condenser of the conditioner chamber, or it may be manually filled, or attached to an automatic filing system, wherein when the water chamber 65 drops below a certain level, a valve on the fill port fills the water chamber above a threshold level.
[0107] FIG. 26 shows a diagram of a corona discharge ozone generating device.
[0108] As shown in FIG. 27, an exemplary ozone generator 11 produces ozone when the potential across the anode and cathode of an electrochemical cell is 1.51 and higher. The electrochemical cell 12 has an anode 20, cathode 40 and proton conducting layer 32 therebetween. Water or water vapor, such as from air, is converted by reaction on the anode 20 to ozone. Protons are passed through the proton conducting layer 32 to the cathode 40, where they react to form hydrogen or when oxygen is present water. The membrane electrode assembly 30 comprising the proton conducting layer, anode and cathode effectively produces ozone from ambient air having some water vapor. Water will be formed on the cathode if oxygen is present.
[0109] As shown in FIG. 28 an exemplary ozone generator system 10 comprises an exemplary electrochemical cell 12 having a proton conducting layer 32 with electrodes, gas diffusion material 39, 39′ and conductor plates 33,33′ on either side of the proton conducting layer. The ozone generator 11 produces ozone on the anode 20 while water and/or hydrogen is produced on the cathode 40, depending on the availability of oxygen on the cathode side. Ozone is being generated on the anode side 21 and hydrogen is being produced on the cathode side 41 of the electrochemical cell 12. The exemplary ozone generator has an anode chamber 320 and a cathode chamber 340. The exemplary membrane electrode assembly 30 is connected to a circuit 31 for power from a power source 87. When the potential across the membrane electrode assembly 30 exceeds 1.51V, protons are produced on the anode side and transported across the proton conducting layer 32 to the cathode side 41. On the cathode side, the protons are reacted with electrons to produce hydrogen and/or water. The protons also drag water across the MEA from the anode side to the cathode side. The membrane electrode assembly is coupled between two electrical conductor plates 33, 33′ to provide the electrical power to the MEA. An electrical conductor plate, may be a screen or perforated and may be the gas diffusion media and/or a flow field. A separate gas diffusion media 39, 39′ may be configured between the conductor plates and the membrane electrode assembly. A flow field 38, 38′ may have a plurality of channels for distributing gasses to the surface of the MEA or gas diffusion media.
[0110] As shown in FIG. 29, an exemplary ozone generator system 10 is coupled with an enclosure 50 and the anode side 21 is fluidly coupled with the enclosure. A power supply 87 provides a potential across the anode 20 and cathode 40 that causes water to be reacted on the anode side 21 and form ozone. The ozone concentration within the enclosure can be controlled by the controller system 80 and user interface 85. As shown, the ozone sensor 310 detects 3 ppm of ozone within the enclosure. The desired concentration of ozone within the enclosure can be changed by interfacing with the user interface. A control system 80 may comprise a microprocessor 81 to adjust and control the components of the ozone generator system 310 to provide a desired concentration of ozone. An inlet 300 to the anode 20 provides an exchange air to support the reaction. The ozone produced on the anode side 21 is transported into the enclosure 50 through an anode side outlet 302. A fan or other fluid moving device 44 may control the rate of flow of the fluid from the anode to the enclosure. The controller may control the fluid moving device flow rate. Water and/or hydrogen produce on the cathode side 41 is exhausted out of the cathode side exhaust 304.
[0111] As shown in FIG. 29, an exemplary micro climate control device 510, such as an oxygen control electrolyzer cell 16 is in fluid communication with the enclosure 50 and a second micro climate control device 510′, such as an oxygen control electrolyzer cell 16′ is in fluid communication with the anode chamber 320 to control a humidity level therein. PCT application US2016063699, hereby incorporated by reference, describes a novel proton-exchange membrane (PEM) based solid polymer electrolyte electrochemical oxygen control (EOC) system incorporating an oxygen control electrolyzer cell that can deplete and control the oxygen within an enclosure. In addition, this application describes a control of humidity levels within an enclosure utilizing said oxygen control electrolyzer cell 16. The oxygen levels within an enclosure can be controlled fix any suitable purpose such as for disinfestation and/or preservation of articles within an enclosure. IN addition, humidity levels can be controlled for preservation of items within an enclosure. Humidity may be provided to an anode chamber 320 by the micro climate control device 510′ as required. This would ensure a clean supply of water vapor to the anode. Likewise, the water vapor may be drawn out of the enclosure 50 by the micro climate control device 510. Note that an ozone generator system may be in fluid communication with the enclosure but may not require and anode chamber or anode inlet 300. The ozone generator may react with moisture within the enclosure to produce ozone.
[0112] As shown in FIG. 30, an exemplary ozone generator system 10 comprises an ozone generator 11 that is configured at least partially within the enclosure 50. The entire ozone generator 11 may be configured within the enclosure and the anode side inlet 300 may extend out from the enclosure and the cathode side outlet 304 may extend out from the enclosure. Note that the cathode side may have an inlet conduit to provide a flow of oxygen or air to allow water to be formed on the cathode side.
[0113] FIG. 31 shows a perspective view of the components of an exemplary ozone generator system 10 having an air or fluid moving device 44, such as a fan, that directs air over the anode or into an anode chamber. A filter 93 may be configured to remove contaminates from an incoming air stream. The membrane electrode assembly 30 and other components are configured in a housing 43, 43. A conductor plates 33′ is configured to provide the potential required to drive the reactions. A gas diffusion media, such as a carbon cloth, is configured adjacent the MEA in this embodiment.
[0114] The fan 44 attached to the housing is designed to create airflow on the surface of the membrane/catalyst to transfer moisture and break up surface tension to improve performance significantly. The flow of air through a duct across the anode side of the cell is another way of achieving a performance increase. It can be used in addition to the fan being placed directly on the Surface of the cell but does not generate as much increased performance. There are effects that can be attributed to this higher performance that can be linked to higher pressure on the surface and trapping/increasing moisture from the close proximity of the fan. The fan in this case has a cowl induction type of frame that captures the air flow and moisture around the fan and channels it to the cell. Higher speed fans without the cowl induction could compensate for the air flow losses. Results from placing the fan directly on the cell and channeling the air and humidity have shown to make the cell perform at least 3 times better than without the close air turbulence.
[0115] FIG. 32 shows a diagram of an exemplary ozone generator system 10 having three of ozone generators 11-11″ coupled with an enclosure 50, or control tank. An air moving device 44 provides air or process fluid to the anode side of the ozone generators 11, and ozone is produced and fed to the enclosure 50. An ozone depletion module 334 may be used to reduce the concentration of the ozone in the enclosure if it becomes too high, as determined by the ozone sensor 310. The ozone in the enclosure may be pumped to a second enclosure or over articles for disinfection as required by the application. The control system 80 may be used to specify the concentration of ozone desired and the controller may change the voltage and flow gas to achieve the desired concentration. The system may have a number of valves 98 that open, close and/or constrict flow therethrough. A flow meter may be used to control the flow of air or process fluid to the ozone generators 11-11″. The control system may control all of these components to produce ozone at a desired concentration and to produce a flow of ozone to a desired location.
[0116] Fluid communication, as used herein, means that gasses can flow to and from the two items described to be in fluid communication. For example, the cathode of an oxygen reduction electrolyzer cell may be in fluid communication with the oxygen control chamber, wherein the reaction products from the anode can freely now into the oxygen control chamber.
[0117] The electrochemical cells, 12 shown in the figures may run as electrolyzer cells, as described herein that perform electrolysis of water, wherein water is broken down on the anode into protons and oxygen and reformed on the cathode with the protons and oxygen.
[0118] The electrochemical cells can be operated at higher potentials to produce ozone, which may be used to clean and disinfect the enclosure.
[0119] When an electrochemical cell is operated at a potential above 12 volts, electrolysis of water will occur and when operated above 2.08 volts, ozone may be produced.
[0120] Dehumidification device, as used herein, is a device that reduces the humidity level or RH and includes, but is not limited to, a desiccant or desiccator employing a desiccant, a condenser and a humidity reduction electrolyzer cell.
[0121] It will be apparent to those skilled in the art that various modifications, combinations and variations can be made in the present invention without departing from the spirit or scope of the invention. Specific embodiments, features and elements described herein may be modified, and/or combined in any suitable manner. Thus, it is intended that the present invention cover the modifications, combinations and variations of this invention provided they come within the scope of the appended claims and their equivalents.
