METHOD AND APPARATUS FOR GASIFYING CARBON-CONTAINING MATERIAL

20170369801 · 2017-12-28

    Inventors

    Cpc classification

    International classification

    Abstract

    An apparatus and a method for gasifying carbon-containing materials in which the material for gasification and oxygen, usually in the form of air, are supplied to a gas generator where the gasification takes place in a fixed bed reactor. The product gas is drawn off via a product gas line and introduced into a hot gas filter. A filter, preferably provided with filter candles, removes solids such as particles not yet gasified, ash and foreign bodies, while clean gas passes through and is taken off via a clean gas line. An outlet is provided in the bottom region of the hot gas filter to remove residual solids. The hot gas filter is supplied through a line with oxygen, preferably in the form of air, in its middle height region, between the filter bottom and the outlet.

    Claims

    1.-3. (canceled)

    4. An apparatus for gasifying carbon-containing material, comprising: a gas generator; the gas generator having an upper region, a middle region, and a lower region; wherein the carbon-containing material is supplied to the upper region of the gas generator, oxygen is supplied to the middle region of the gas generator, and the carbon-containing material is largely gasified to a product gas in a fixed bed reactor in the lower region of the gas generator; and a hot gas filter, wherein the hot gas filter receives the product gas from the gas generator via a product gas line coupled to a lowermost region of the gas generator and passes the product gas through a filter assembly to yield a clean gas; the hot gas filter further including a solids outlet in a bottom region of the hot gas filter for taking off residual solids removed from the product gas by the filter assembly; wherein oxygen is supplied via a gas line to a middle region of the hot gas filter between the filter assembly and the solids outlet.

    5. The apparatus of claim 4, wherein oxygen is supplied to the middle region of the gas generator in the form of air.

    6. The apparatus of claim 4, wherein the carbon-containing material includes wood.

    7. The apparatus of claim 4, wherein the filter assembly includes one or more filter candles.

    8. The apparatus of claim 4, wherein the filter assembly is configured to remove solid particles not yet gasified, ash, and foreign bodies.

    9. The apparatus of claim 4, wherein oxygen is supplied to the middle region of the hot gas filter in the form of air.

    10. The apparatus of claim 4, wherein the oxygen supplied to the middle region of the hot gas causes an additional gasification of constituents of the carbon-containing material that were not yet gasified.

    11. The apparatus of claim 4, wherein a draft in the product gas line is sufficiently strong that particles not gasified in the gas generator are transported substantially into the hot gas filter.

    12. A method for gasifying a carbon-containing material, comprising: adding a carbon-containing material to a gas generator; adding oxygen to the gas generator; at least partially gasifying the carbon-containing material in the gas generator to yield a product gas stream; supplying the product gas stream to a hot gas filter having a filter assembly; and supplying oxygen to the hot gas filter prior to the filter assembly so that a further gasification of the product gas stream occurs.

    13. The method of claim 12, wherein supplying oxygen to the hot gas filter includes supplying air to the hot gas filter.

    14. The method of claim 12, wherein supplying the product gas stream to the hot gas filter includes supplying the product gas line to the hot gas filter with sufficient draft that particles not gasified in the gas generator are transported substantially into the hot gas filter.

    Description

    BRIEF DESCRIPTION OF THE DRAWINGS

    [0041] FIG. 1 is a chart depicting selected processes occurring during gasification of carbon-containing materials, and their products.

    [0042] FIG. 2 is a schematic depiction of a gasification plant according to an exemplary embodiment of the current invention.

    DETAILED DESCRIPTION

    [0043] According to an embodiment of the present invention, the charcoal obtained in ungasified form in the bottom region of the gas generator is at least predominantly transferred with the gas stream to the downstream hot gas filter. This can be carried out through appropriate choice of the flow rate in the manner of pneumatic transport, as has long been known in the conveying of bulk goods. In the hot gas filter, charcoal, along with coal dust and entrained ash, is deposited on the surface of the filter, composed preferably of filter candles. Depending on the pressure drop at the filter upstream of the filter candles, oxygen (usually in the form of air) is introduced in as far as possible a pulselike manner, causing the filter cake on the filter candles to break apart, and, promoted by pressure wave and temperature, there is a second gasification step, through which the entrained charcoal and/or the coal dust is to by far the predominant extent gasified. The fraction that is still not being gasified is ultimately gasified by the oxygen supplied in the bottom part of the filter—again preferably in the form of air. Depending on the process parameters, which are easily determined for the plant constructor and the plant operator, if not being already known anyway, it is possible to carry out the gasification of wood substantially completely, leaving only the mineral ash.

    [0044] A plant according to the invention is depicted purely schematically in FIG. 2. The depiction of all of the components which are not causally associated with the invention has been left out. In particular, the numerous meters, the regulating and shutoff elements, the control, the components upstream and downstream of the plant, such as stores, drying apparatus, final product gas cleaning, and transfer to the user, are very well known to the person skilled in the field of wood gasification plants, and require no more detailed elucidation in connection with the invention.

    [0045] The plant of the invention, with its components and elements necessary for the invention—albeit without the meters, etc.—is depicted schematically, and features essentially the following: a gas generator 1 and a hot gas filter 2. Wood chips, wood pellets, coal or the like, from a reservoir bunker which is not shown, are supplied via a feed 3 to the gas generator 1, appropriately at its top, and, in the generator, they pass through the steps, known from the prior art and referred to at the outset, of drying, of carbonization, of oxidation, and of reduction; in the bottom region, indicated by the installation 4, air is appropriately supplied by a line and a distributor system 5. This apparatus is a conventional wood gasifier having a fixed bed operated in concurrent. In the bottom region, after the oxidation, there is reduction, and uncombusted portions and ash are drawn off with the product gas via a line 6 in the bottom region of the gas generator, and are introduced into the middle region of a hot gas filter 2.

    [0046] Projecting into this bottom region of the hot gas filter 2 are filter candles 7 comprising a filter bottom 13, directed downward. Although one filter candle is sufficient under certain circumstances, it is favorable, for continuous operation, though not vital, for at least two such filter candles 7 to be provided. The product gas passes through the filter candles and arrives, here as product referred to as clean gas, into the upper region of the hot gas filter 2, from where it is taken off via a clean gas line 8 and supplied for further processing and/or use.

    [0047] The filter candles 7 are connected controllably to a pressurized air supply 9; by means of this compressed air supply, they can be placed in a pulselike manner, on their clean gas side, under superatmospheric pressure, in order to burst filter cakes which have collected on the crude gas side and to permit at least partial gasification. Provided in the bottom region of the hot gas filter 2 is an outlet 10 for the ungasified constituents, and a corresponding ash vat 11.

    [0048] Then, in accordance with the invention, as already mentioned, via line 12, oxygen, in the form for example of air, optionally heated and/or dried, is supplied into the region below the filter bottom 13 (approximately at the lower end of the filter candles), and consequently, in the crude gas region of the hot gas filter 2, there is a further, very largely complete gasification of those constituents of the wood that up to this point have not been gasified.

    [0049] In this way, the remaining, ungasified fraction of the wood can be reduced substantially to the mineral ash, with notable consequences both for the environment and in economic respects: in the prior art, 5 to 10 wt % of the fuel used is ungasifiable, and therefore requires proper disposal; as a result of the invention, this fraction is compressed to less than 1 wt % of the fuel used, and so the invention produces a boost in yield from 90%-95% to 99%, with the plus of a reduction in waste to 10-20% of the previous level of waste. On the other side are the negligible extra costs of strengthening the draft in line 6, and the costs for the blowing of the reaction air through line 12 into the hot gas filter 2, which are insubstantial.

    [0050] The invention is not confined to the exemplary embodiment shown, but can be modified in a variety of ways. For instance, with large plants, a plurality of gas generators and/or of hot gas filters can be fittingly combined with one another, in order to obtain continuous operation even in the event of maintenance. For wood constituents which are too heavy even for the increased draft, a discharge device for such parts can be provided in the gas generator; whether these parts are subsequently resupplied to the gas generator or else disposed of depends on the nature of the starting material and the possibility for return into the product stream.

    [0051] The invention can be combined with various other embodiments of the method or of the apparatus, as long as the only reaction in the hot gas filter is not disrupted and/or the other embodiments of the filter operation do not cause disruption.

    [0052] As a result of the implementation of the second gasification step in the hot gas filter, the status conditions there are not changed in so substantial a manner as to necessitate a change in or adaptation of the materials, and it is therefore possible to use all the components and materials which are also contemplated for this purpose by the skilled person with conventional hot gas filters.

    [0053] The level of the entry of nozzles or other openings of the supply line 12 into the hot gas filter 2 is appropriately, when filter candles 7 are present, at the bottom end thereof. There, when the filter cake is burst apart, the entire material will pass in front, just as, during undisrupted operation, the material not yet gasified likewise passes in front. Operating parameters such as superatmospheric pressure and volume flow rate are easily determined by means of a few trials. If different materials are being degassed, it is advantageous under certain circumstances to provide nozzles at different heights, which may be provided individually or in groups.

    [0054] It is also possible, through slanted arrangement of nozzles, to obtain specific flow patterns through which the further gasification is promoted.

    [0055] In summary it may be stated that the invention provides an apparatus for gasifying carbon-containing material, more particularly wood, having a gas generator 1, to which the material for gasification is supplied in its upper region and to which oxygen, usually in the form of air, is supplied in its middle region, and in whose lower region it is largely gasified in a fixed bed reactor, the product gas being drawn off via a product gas line 6 from the lowermost region of the gas generator 1 and introduced into the lower region of a hot gas filter 2, where a filter, preferably provided with filter candles 7, removes solids such as particles not yet gasified, ash, and foreign bodies, while the clean gas passes through and is taken off via a clean gas line 8, an outlet 10 being provided for taking off the residual solids in the bottom region of the hot gas filter 2. Here, the hot gas filter 2 is supplied in its middle height region, between the filter bottom 13 and the outlet 10, through a line 12, with oxygen, preferably in the form of air.

    [0056] The invention also relates to a method for gasifying carbon-containing material, more particularly wood, featuring a gas generator 1 and a hot gas filter 2 downstream thereof in the product stream, wherein the hot gas filter 2 is supplied, ahead of the filter in the product stream, with oxygen, preferably in the form of air, and so a further gasification procedure takes place.

    [0057] It should also be noted that details such as “largely” in the case of materials mean more than 50 wt %, preferably more than 80 wt %, and more preferably more than 95 wt %; that “bottom region” of a reactor, filter, construction, or apparatus or, very generally, of an article, means the lower half and more particularly the lower quarter of the overall height, “lowermost region” means the lowermost quarter and more particularly an even smaller part; while “middle region” refers to the middle third of the overall height. All of these details, along with “top”, “bottom”, etc., have their generally accepted meaning, applied to the as-defined position of the article under consideration.

    [0058] “Substantially” can be delimited with a deviation of 10% from the stated figure, if physically possible, both upwardly and downwardly, or otherwise only in the direction that makes sense.

    TABLE-US-00005 List of reference symbols: 01 Gasifier 02 Hot air filter 03 Supply 04 Installation 05 Distributor system 06 Product line 07 Filter candle(s) 08 Clean gas line 09 Compressed air supply 10 Outlet 11 Ash bin 12 Supply line 13 Filter bottom