Techniques for marking a substrate using a physical vapor deposition material
09849650 · 2017-12-26
Assignee
Inventors
- Douglas Weber (Arcadia, CA, US)
- Christopher Prest (San Francisco, CA, US)
- David Pakula (San Francisco, CA, US)
- Stephen Paul Zadesky (Portola Valley, CA)
Cpc classification
C23C14/024
CHEMISTRY; METALLURGY
C03C17/3607
CHEMISTRY; METALLURGY
C03C17/3411
CHEMISTRY; METALLURGY
Y10T428/31681
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/31678
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B15/04
PERFORMING OPERATIONS; TRANSPORTING
C03C17/3684
CHEMISTRY; METALLURGY
Y10T428/265
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/31645
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C03C17/3636
CHEMISTRY; METALLURGY
C03C17/38
CHEMISTRY; METALLURGY
B05D5/06
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/31692
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/31855
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
C23C14/00
CHEMISTRY; METALLURGY
B05D5/06
PERFORMING OPERATIONS; TRANSPORTING
B32B15/04
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Techniques, processes and structures are disclosed for providing markings on products, such as electronic devices. For example, the markings can be formed using physical vapor deposition (PVD) processes to deposit a layer of material. The markings or labels may be textual and/or graphic. The markings are deposited on a compliant layer that is disposed on a surface to be marked. The compliant layer is arranged to isolate the surface to be marked from the layer of material deposited using the PVD process.
Claims
1. A method for forming a housing for an electronic device, the method comprising: depositing an intermediate layer on an interior glass surface of the housing, wherein the intermediate layer comprises a liquefiable adhesive; compressing the intermediate layer against the surface of the housing using a compression member; heating the intermediate layer while compressing the intermediate layer against the surface of the housing using the compression member; curing the intermediate layer using ultraviolet light while compressing the intermediate layer against the surface of the housing using the compression member; and depositing a layer of physical vapor deposition material over the intermediate layer, wherein the intermediate layer is positioned between the housing and the layer of physical vapor deposition material and wherein the layer of physical vapor deposition material forms a logo on the interior glass surface of the housing.
2. The method defined in claim 1 wherein the intermediate layer is arranged to completely isolate the surface of the housing from the layer of physical vapor deposition material.
3. The method defined in claim 1 wherein the layer of physical vapor deposition material forms text on the interior glass surface of the housing.
4. A method for forming a housing for an electronic device, wherein the housing has an interior and an exterior, the method comprising: depositing an intermediate layer on a surface of the interior of the housing, wherein the surface comprises glass and wherein the intermediate layer is a liquefiable intermediate layer; compressing the intermediate layer against the surface using a compression member; heating the intermediate layer using the compression member while compressing the intermediate layer against the surface to liquefy the intermediate layer; and depositing a layer of metal physical vapor deposition material on the intermediate layer, wherein the intermediate layer is positioned between the surface of the interior of the housing and the layer of metal physical vapor deposition material, and wherein both the intermediate layer and the layer of metal physical vapor deposition material are located in the interior of the housing.
5. The method defined in claim 4 wherein the intermediate layer comprises an adhesive.
6. The method defined in claim 5 wherein the adhesive comprises a liquefiable optical adhesive.
7. The method defined in claim 4 wherein the intermediate layer has a thickness between 50 nm and 500 nm.
8. The method defined in claim 4 wherein heating the intermediate layer comprises heating the intermediate layer to 80 degrees Celsius.
9. The method defined in claim 4 wherein the layer of metal physical vapor deposition material forms text on the surface of the interior of the housing.
10. A method for forming a housing of an electronic device, wherein the housing has an interior and an exterior and wherein the housing comprises a glass substrate having a surface, the method comprising: depositing a clear polymer layer on the glass substrate to coat the surface; depositing a physical vapor deposition layer on the clear polymer layer; assembling the glass substrate into the electronic device with the surface in the interior of the housing, wherein the physical vapor deposition layer is viewable from the exterior of the housing through the glass substrate and the clear polymer layer; compressing the clear polymer layer against the coated surface, heating the clear polymer layer while compressing the clear polymer layer against the coated surface; and curing the clear polymer layer using ultraviolet light while compressing the clear polymer layer against the coated surface.
11. The method defined in claim 10 wherein depositing the physical vapor deposition layer comprises depositing a metal layer on the clear polymer layer.
12. The method defined in claim 11 wherein depositing the metal layer comprises forming a logo on the glass substrate.
13. The method defined in claim 11 wherein depositing the metal layer comprises forming text on the glass substrate.
14. The method defined in claim 10 wherein depositing the clear polymer layer comprises depositing a liquefiable optical layer.
15. The method defined in claim 10 wherein assembling the glass substrate into the electronic device comprises surrounding the clear polymer layer and the physical vapor deposition layer with portions of the housing.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The invention will be readily understood by the following detailed description in conjunction with the accompanying drawings, wherein like reference numerals designate like structural elements, and in which:
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DETAILED DESCRIPTION OF THE INVENTION
(10) A product, e.g., electronic device, includes a substrate that can be marked. The substrate may be marked using a physical vapor deposition (PVD) process.
(11) Using a PVD process, a PVD coating formed from a material, such as metal, may be deposited directly onto a surface of a substrate to mark the surface of the substrate. The PVD coating is deposited as a layer, e.g., film, that is bonded to the surface of the substrate. However, as the thickness of a layer of PVD coating that is bonded directly onto a surface of a substrate, residual stresses increase within the layer of PVD coating. Such residual stresses may cause the shape of the layer to change, thus effectively altering the marking. These residual stresses in a layer of PVD coating may apply contraction or expansion at an interface between the layer of PVD coating and a surface of a substrate. When the substrate is a relatively brittle, the residual stresses may cause the substrate to crack in the vicinity of the PVD coating. That is, local tensile loading may be created on the surface of the substrate, thereby compromising the resistance of the substrate to fracture. For example, when a layer of PVD coating is bonded to one surface of a glass substrate such that a marking is formed, and a force is applied to an opposite surface of the glass substrate substantially over the marking, residual stresses in the layer PVD coating typically can cause the glass substrate to crack in a location over the marking. In general, as the thickness of the layer of PVD coating increases, the resistance to the glass substrate to cracking decreases. When a substrate cracks, the integrity of a device which includes the substrate may be compromised. Thus, there is a need for improved techniques for enabling PVD coating to be used to create markings on surfaces of substrates.
(12) The invention pertains generally to techniques or processes for providing markings on products. For example, the markings can be formed using physical vapor deposition (PVD) processes. The markings (e.g., labeling) may be textual and/or graphic. The markings may be used to provide a product (e.g., a product's housing) with certain information. The marking may, for example, be use to label the product with various information. When a marking includes text, the text may provide information concerning the product (e.g., electronic device). For example, the text may include one or more of: name of product, trademark or copyright information, design location, assembly location, model number, serial number, license number, agency approvals, standards compliance, electronic codes, memory capacity of device, and the like. When a marking includes a graphic, the graphic may pertain to a logo, a certification mark, standards mark, or an approval mark that is often associated with the product. The marking may be used for advertisements to be provided on products. The markings may also be used for customization (e.g., user customization) of a housing of a product.
(13) A substrate associated with a product may be marked using a material deposited using a PVD process. When a PVD coating is deposited directly on a substrate, residual stresses may be formed in the layer of PVD coating, thereby decreasing the resistance of the substrate to fracture. To reduce the likelihood of premature fracture in the substrate, e.g., to substantially prevent significant reduction to a substrate's resistance to fracture, a complaint intermediate layer (or buffer layer) may be disposed between the surface of the substrate and a layer of PVD coating (or a thin film of PVD material). Such a complaint intermediate layer may effectively reduce stresses on the substrate that may be caused by residual stresses in the layer of PVD coating. In general, the compliant intermediate layer can act as a barrier and thus can isolate the substrate from the layer of PVD coating.
(14) In one embodiment, a compliant intermediate layer used in a substrate structure may be formed from substantially any material that is relatively compliant, such that stress from a layer of PVD coating is not imparted to a substrate. Materials used to form an intermediate layer may include, but are not limited to including, silicon dioxide (SiO.sub.2), silicon nitride (Si.sub.3N.sub.4), titanium dioxide (TiO.sub.2), fluorinated anti-smudge coatings, paint, clearcoat, adhesives, and ink. An intermediate layer may also be formed from any suitable combination of these materials. With respect to adhesives, suitable adhesives include a liquefiable optical adhesive, such as a Polyvinyl Acetate (PVA) adhesive. A liquefiable optical adhesive can provide excellent transparency as well as conformity to surface geometry. One particular example of a suitable adhesive is ThreeBond TB1630 adhesive from Three Bond Co., Ltd., Toyko, Japan.
(15) Referring initially to
(16) An intermediate layer 112 may be deposited, or otherwise substantially bonded, to surface 108a of substrate 104. The intermediate layer 112 can also be referred to as a barrier layer, a buffer layer or a compliant layer. A layer of PVD material 116 may be deposited on intermediate layer 112. Layer of PVD material 116, or a layer of PVD coating, may be formed from any suitable metal, as for example chromium or aluminum. In general, intermediate layer 112 is arranged to substantially isolate substrate 104 from layer of PVD material 116.
(17) The overall thicknesses of layer of PVD material 116 and intermediate layer 112 may vary. As shown in
(18) In general, layer of PVD material 116 may have a thickness of between approximately 25 nanometers (nm) and approximately 200 nm, as for example approximately 100 nm. The thickness of an intermediate layer may vary widely, as indicated in
(19) As mentioned above, a substrate structure which includes an intermediate or buffer layer between a substrate and a layer of PVD coating may be included in a device such that the layer of PVD coating is located substantially inside the device. The device may be a portable electronic device such as a personal digital assistant, a digital media player, a game player, a handheld communications device (e.g., mobile phone), or any suitable computing device.
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(21) As shown, the marking formed on substrate 204 by layer of PVD coating 216 is arranged substantially along the perimeter of substrate 204. In one implementation, substrate 204 and intermediate layer 212 are highly translucent (e.g., clear) such that when device 220 is viewed from the outside, PVD coating 216 appears as if it is directly on substrate 204. It should be appreciated, however, that the size, shape and position of the marking may vary widely. Further, the number of markings may also vary widely.
(22) With reference to
(23) In step 313, an intermediate layer is deposited on the appropriate surface of the substrate. The intermediate layer may be deposited using any suitable method. The intermediate layer may be formed from materials including, but not limited to including, SiO.sub.2, Si.sub.3N.sub.4, TiO.sub.2, fluorinated anti-smudge coatings, paint, clearcoat, adhesive, and ink. Depositing the intermediate layer may involve monitoring a thickness of the intermediate layer to ascertain when a desired thickness of the intermediate layer is reached.
(24) From step 313, process flow proceeds to step 317 in which a PVD process is used to deposit PVD material onto the intermediate layer. Depositing the PVD material onto the intermediate layer allows a layer of PVD coating, or thin film, to be formed on the intermediate layer. The PVD material may be a metal such as chromium, aluminum, or silver. It should be appreciated, however, that the PVD material is not limited to being chromium, aluminum, or silver. The PVD process may include monitoring a thickness of a layer of PVD coating to determine when the layer of PVD coating reaches a desired thickness. It should be appreciated that if a mask is used to effectively control where an intermediate layer and a layer of PVD coating are formed, the mask may be removed when the layer of PVD coating reaches a desired thickness.
(25) After the layer of PVD coating is deposited, a substrate structure which includes the substrate, the intermediate layer, and the layer of PVD coating is effectively formed, and the process of creating a substrate structure is effectively completed. As will be understood by those skilled in the art, however, creating a substrate structure may include optionally assembling the substrate structure into a device, e.g., a portable electronic device, in step 321.
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(30) With reference to
(31) In step 606, an intermediate layer is deposited on the appropriate surface of the substrate. The intermediate layer may be deposited using any suitable method. The intermediate layer may be formed from materials including, but not limited to including, SiO.sub.2, Si.sub.3N.sub.4, TiO.sub.2, fluorinated anti-smudge coatings, paint, clearcoat, adhesive, and ink. Depositing the intermediate layer may involve monitoring a thickness of the intermediate layer to ascertain when a desired thickness of the intermediate layer is reached.
(32) In step 608, the intermediate layer is compressed using a compression surface. For example, the intermediate layer can be an adhesive that under pressure and elevated temperature softens or liquefies so as to conform to and bond with the substrate and also to provide a smooth, uniform, flat exposed surface. The intermediate layer, e.g., adhesive, can then be cured at step 610. For example, UV light can be directed towards the intermediate layer to accelerate or activate curing.
(33) From step 610, process flow proceeds to step 612 in which a PVD process is used to deposit PVD material onto appropriate portions the intermediate layer. Depositing the PVD material onto the intermediate layer allows a layer of PVD coating, or thin film, to be formed on the intermediate layer. The PVD material may be a metal such as chromium, aluminum, or silver. It should be appreciated, however, that the PVD material is not limited to being chromium, aluminum, or silver. The PVD process may include monitoring a thickness of a layer of PVD coating to determine when the layer of PVD coating reaches a desired thickness. It should be appreciated that if a mask is used to effectively control where an intermediate layer and a layer of PVD coating are formed, the mask may be removed when the layer of PVD coating reaches a desired thickness.
(34) After the layer of PVD coating is deposited, a substrate structure which includes the substrate, the intermediate layer, and the layer of PVD coating is effectively formed, and the process of creating a substrate structure is effectively completed. As will be understood by those skilled in the art, however, creating a substrate structure may include optionally assembling the substrate structure into a device, e.g., a portable electronic device, in step 614.
(35) Although only a few embodiments of the invention have been described, it should be understood that the invention may be embodied in many other specific forms without departing from the spirit or the scope of the present invention. By way of example, while an intermediate layer and a layer of PVD coating have been described as being deposited on a side of a substrate that is to be substantially inside of a device, it should be appreciated that an intermediate layer and a layer PVD coating may instead be deposited on a side of the substrate that is to be substantially outside of the device.
(36) The use of an intermediate layer as a buffer between a substrate and a layer of PVD coating is particularly suitable for reducing the occurrence of premature fractures in brittle substrates, e.g., substrates which are formed from glass. However, an intermediate layer in a substrate structure may be used to reduce stresses on any suitable substrate, including those which are not substantially brittle.
(37) In general, an intermediate layer may include discrete portions configured to correspond to a marking that is to be formed by a PVD coating. That is, an intermediate layer may have substantially the same footprint as a marking that is formed by the PVD coating. The intermediate layer, however, is not limited to having substantially the same footprint as a marking. For instance, the intermediate layer may instead be arranged to cover substantially all of a surface of a substrate, while the marking covers only certain portions of the intermediate layer and, hence, the substrate. In other words, an intermediate layer may be substantially continuous, rather than discrete. Portions of the intermediate layer which are not overlaid by a PVD coating may, in some instances, be arranged to enhance the overall cosmetic appearance of the substrate.
(38) As mentioned above, an intermediate layer may include a plurality of sub-layers. In other words, an intermediate layer may be formed from sub-layers of different materials, and is not limited to being formed as a substantially single layer using a single material.
(39) The thicknesses of an intermediate layer and a layer of PVD coating may vary widely depending upon factors which may include, but are not limited to including, the thickness of a substrate, the size of a marking to be provided on the substrate, and the materials used to form the intermediate layer and/or the layer PVD coating.
(40) U.S. Provisional Patent Application No. 61/236,847, filed Aug. 25, 2009 and entitled “Method and Apparatus for Applying a Physical Vapor Deposition Material on a Substrate” is hereby incorporated herein by reference.
(41) Numerous specific details are set forth in order to provide a thorough understanding of the invention. However, it will become obvious to those skilled in the art that the invention may be practiced without these specific details. The description and representation herein are the common meanings used by those experienced or skilled in the art to most effectively convey the substance of their work to others skilled in the art. In other instances, well-known methods, procedures, components, and circuitry have not been described in detail to avoid unnecessarily obscuring aspects of the invention.
(42) In the foregoing description, reference to “one embodiment” or “an embodiment” means that a particular feature, structure, or characteristic described in connection with the embodiment can be included in at least one embodiment of the invention. The appearances of the phrase “in one embodiment” in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments. Further, the order of blocks in process flowcharts or diagrams representing one or more embodiments of the invention do not inherently indicate any particular order nor imply any limitations in the invention.
(43) The many features and advantages of the invention are apparent from the written description. Further, since numerous modifications and changes will readily occur to those skilled in the art, the invention should not be limited to the exact construction and operation as illustrated and described. Hence, all suitable modifications and equivalents may be resorted to as falling within the scope of the invention.