Composition for the oxidation dyeing of keratin fibres, comprising particular fatty alcohols, a liquid fatty substance and a cationic polymer

Abstract

The present invention relates to a composition for dyeing keratin fibres, comprising: one or more oxidation dyes; one or more basifying agents; one or more non-oxyalkylenated fatty substances that are liquid at room temperature in a content of less than or equal to 20% by weight relative to the total weight of the composition; one or more oxidizing agents; one or more oxyethylenated fatty alcohols with a number of oxyethylene units of greater than or equal to 10; one or more oxyethylenated fatty alcohols with a number of oxyethylene units of less than 10; one or more non-oxyethylenated fatty alcohols that are solid at room temperature; and one or more cationic polymers. The present invention also relates to a process for dyeing keratin fibres using such a composition, and also to a kit for preparing the said composition.

Claims

1. Composition for dyeing keratin fibres, comprising: one or more oxidation dyes, one or more basifying agents, one or more non-oxyalkylenated fatty substances that are liquid at room temperature, chosen from hydrocarbons containing more than 16 carbon atoms selected from the group consisting of liquid parafins, liquid petroleum jelly, polydecenes, hydrogenated polyisobutene, squalane, and mixtures thereof, one or more oxidizing agents, one or more oxyethylenated fatty alcohols with a number of oxyethylene units of greater than or equal to 10, one or more oxyethylenated fatty alcohols with a number of oxyethylene units of less than 10; one or more non-oxyethylenated fatty alcohols that are solid at room temperature, and one or more cationic polymers, the content of one or more non-oxyalkylenated fatty substances that are liquid at room temperature ranging from 1% to 10% by weight relative to the total weight of the composition.

2. Composition according to claim 1, characterized in that the basifying agent is chosen from aqueous ammonia, alkaline carbonates, sodium hydroxide, potassium hydroxide, organic amines, and the compounds of formula (I) below: ##STR00016## in which W is a C.sub.1-C.sub.6 alkylene residue optionally substituted with a hydroxyl group or a C.sub.1-C.sub.6 alkyl radical; Rx, Ry, Rz and Rt, which may be identical or different, represent a hydrogen atom, or a C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 hydroxyalkyl, or C.sub.1-C.sub.6 aminoalkyl radical.

3. Composition according to claim 1, characterized in that the oxidizing agent is chosen from hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, and redox enzymes optionally in the presence of the respective donor or cofactor thereof.

4. Composition according to claim 1, characterized in that the oxidation dyes are chosen from oxidation bases, optionally combined with one or more couplers.

5. Composition according to claim 1, characterized in that the oxyethylenated fatty alcohol(s) with a number of oxyethylene units of greater than or equal to 10 are chosen from those in which the number of oxyethylene units is greater than or equal to 15.

6. Composition according to claim 1, characterized in that the content of oxyethylenated fatty substances with a number of oxyethylene units of greater than or equal to 10 ranges from 0.1% to 10% by weight relative to the total weight of the composition.

7. Composition according to claim 1, characterized in that the oxyethylenated fatty alcohol(s) with a number of oxyethylene units of less than 10 are chosen from those in which the number of oxyethylene units is less than or equal to 5.

8. Composition according to claim 1, characterized in that the content of oxyethylenated fatty substances with a number of oxyethylene units of less than 10 ranges from 0.1% to 10% by weight relative to the total weight of the composition.

9. Composition according to claim 1, characterized in that the non-oxyethylenated fatty alcohol(s) that are solid at room temperature comprise from 14 to 30 carbon atoms.

10. Composition according to claim 1, characterized in that the content of non-oxyethylenated fatty alcohols that are solid at room temperature ranges from 0.1% to 20% by weight relative to the total weight of the composition.

11. Composition according to claim 1, characterized in that the cationic polymer(s) are chosen from: (1) Homopolymers or copolymers derived from crosslinked or non-crosslinked acrylic or methacrylic esters or amides and comprising at least one of the units of formula (I), (II), (III) or (IV) below: ##STR00017## in which: R.sub.1 and R.sub.2, which are identical or different, each represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms; R.sub.3, which may be identical or different at each occurrence, denotes a hydrogen atom or a CH.sub.3 group; A, which may be identical or different, in each case represents a linear or branched alkyl group of 1 to 6 carbon atoms, or a hydroxyalkyl group of 1 to 4 carbon atoms; R.sub.4, R.sub.5 and R.sub.6, which may be identical or different, each represent an alkyl group containing from 1 to 6 carbon atoms or a benzyl group; X.sup.− denotes an anion derived from a mineral or organic acid or a halide; (2) Cationic polysaccharides, especially those chosen from: cellulose ether derivatives comprising quaternary ammonium groups; cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer; guar gums containing trialkylammonium cationic groups; (3) Polymers formed from piperazinyl units and divalent alkylene or hydroxyalkylene radicals containing straight or branched chains, optionally interrupted with oxygen, sulfur or nitrogen atoms or with aromatic or heterocyclic rings, and also the oxidation and/or quaternization products of these polymers; (4) Water-soluble cationic polyaminoamides, prepared in particular by polycondensation of an acid compound with a polyamine; these polyaminoamides possibly being crosslinked with an epihalohydrin, a diepoxide, a saturated or unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine or a bis-alkyl halide or else by an oligomer resulting from the reaction of a bifunctional compound which is reactive towards a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide, an epihalohydrin, a diepoxide or a bis-unsaturated derivative; these polyaminoamides possibly being alkylated, or quaternized if they contain one or more tertiary amine functions; (5) Polyamino amide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents; (6) The polymers obtained by reaction of a polyalkylene polyamine containing two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 6 carbon atoms; (7) Alkyldiallylamine or dialkyldiallylammonium cyclopolymers comprising, as the main constituent of the chain, units corresponding to the formula (V) or (VI): ##STR00018## in which k and t are equal to 0 or 1, the sum k+t being equal to 1; R.sub.12 denotes a hydrogen atom or a methyl group; R.sub.10 and R.sub.11, independently of one another, denote an alkyl group having from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group has 1 to 5 carbon atoms, a lower amidoalkyl group (i.e. the alkyl part of which is C.sub.1-C.sub.4), or else R.sub.10 and R.sub.11 may, together with the nitrogen atom to which they are attached, denote heterocyclic groups; Y.sup.− is an anion; (8) The quaternary diammonium polymers containing repeating units corresponding to formula (VII): ##STR00019## in which: R.sub.13, R.sub.14, R.sub.15 and R.sub.16, which may be identical or different, represent aliphatic, alicyclic or arylaliphatic groups containing from 1 to 6 carbon atoms or lower hydroxyalkylaliphatic groups (i.e. the alkyl part of which is C.sub.1-C.sub.4), or alternatively R.sub.13, R.sub.14, R.sub.15 and R.sub.16, together or separately, constitute, with the nitrogen atoms to which they are attached, heterocycles optionally containing a second heteroatom other than nitrogen, or alternatively R.sub.13, R.sub.14, R.sub.15 and R.sub.16 each represent a linear or branched C.sub.1-C.sub.6 alkyl group substituted with a nitrile, ester, acyl or amide group or a —CO—O—R.sub.17-E or —CO—NH—R.sub.17-E group where R.sub.17 is an alkylene group and E is a quaternary ammonium group; A.sub.1 and B.sub.1 represent polymethylene groups containing from 2 to 8 carbon atoms, which may be linear or branched and saturated or unsaturated and may contain, joined to or intercalated in the main chain, one or more aromatic rings, or one or more oxygen or sulfur atoms or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups; and X.sup.− denotes an anion derived from a mineral or organic acid; A.sub.1, R.sub.13 and R.sub.15 may, with the two nitrogen atoms to which they are attached, form a piperazine ring; moreover, if A.sub.1 denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene group, B.sub.1 may also denote a group:
—(CH.sub.2).sub.n—CO-E′-OC—(CH.sub.2).sub.n— in which n denotes an integer from 0 to 7 and E′ denotes: a) a glycol residue of formula —O—Z—O—, in which Z denotes a linear or branched hydrocarbon-based group, or a group corresponding to one of the following formulae:
—(CH.sub.2—CH.sub.2—O).sub.x—CH.sub.2—CH.sub.2—
—[CH.sub.2—CH(CH.sub.3)—O].sub.y—CH.sub.2—CH(CH.sub.3)— in which x and y each denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization; b) a bis-secondary diamine residue; c) a bis-primary diamine residue of formula —NH—Y—NH—, in which Y denotes a linear or branched hydrocarbon-based group, or alternatively the divalent group —CH.sub.2—CH.sub.2—S—S—CH.sub.2—CH.sub.2—; d) a ureylene group of formula —NH—CO—NH—. (9) Polyquaternary ammonium polymers consisting of units of formula (IX): ##STR00020## in which: p denotes an integer ranging from 1 to 6 approximately; D may be nothing or may represent a group —(CH.sub.2).sub.r—CO— in which r denotes a number equal to 4 or 7; and X.sup.− denotes an anion derived from a mineral or organic acid; (10) Quaternary polymers of vinylpyrrolidone and of vinylimidazole; (11) Ethoxylated cationic tallow polyamines; (12) Vinylamide homopolymers or copolymers; (13) Cationic polyurethanes; (14) Cationic proteins or cationic protein hydrolysates, polyalkyleneimines, polymers containing vinylpyridine or vinylpyridinium units, and chitin derivatives.

12. Composition according to claim 1, characterized in that the content of cationic polymers ranges from 0.01% to 10% by weight relative to the weight of the composition.

13. Composition according to claim 1, characterized in that it results from the mixing of several compositions.

14. Process for dyeing keratin fibres, comprising the application to the said wet or dry fibres of the dye composition as defined according to claim 1.

15. Process for dyeing keratin fibres according to claim 14, comprising the application of compositions (A) and then (B), successively and without intermediate rinsing, to the said wet or dry fibres, (A) comprising one or more oxidation dyes and (B) comprising one or more oxidizing agents.

16. Process for dyeing keratin fibres according to claim 14, comprising the application to the said wet or dry fibres of a composition obtained by the extemporaneous mixing of compositions (A) and then (B), (A) comprising one or more oxidation dyes and (B) comprising one or more oxidizing agents.

17. Multi-compartment dyeing device or “kit”, comprising a first compartment containing a composition (A), and a second compartment containing a composition (B), compositions (A) and (B) being such that their mixing leads to a composition as defined in claim 1.

Description

EXAMPLE

(1) The oxidation dye compositions (A) below were prepared (in the table below, the amounts are expressed as grams of active material):

(2) Dye Compositions (A):

(3) TABLE-US-00001 Compositions A1 A2 A3 A4 Pentasodium pentetate 0.8 0.8 0.8 0.8 Thiolactic acid — 0.4 0.4 — Aqueous ammonia 0.8 2.2 — 0.8 (expressed as NH.sub.3) Erythorbic acid 0.3 0.3 0.3 0.3 Sodium metabisulfite 0.7 — — 0.7 Ethanolamine 5.24 0.5 5.24 5.24 Steareth-2 1.38  1.38 1.38 1.25 Steareth-20 2.75  2.75 2.75 2.5 2,4-Diaminophenoxyethanol 0.31 — — — hydrochloride N,N-Bis(2-hydroxyethyl)-p- 0.28 — — — phenylenediamine sulfate monohydrate Resorcinol 1.66  0.15 — 0.12 m-Aminophenol 0.14  0.009 — 0.0072 p-Phenylenediamine 2  0.137 0.35 0.1096 5-Amino-6-chloro-o-cresol — — 0.21 — 4-Amino-2-hydroxytoluene — — 0.98 — 2-Methylresorcinol —  0.013 — 0.0104 1-Hydroxyethyl-5-diaminopyrazole — — 1.19 — sulfate Mineral oil 8.8 8.8 8.8 8 Cetylstearyl alcohol 8.8 8.8 8.8 8 Camellia oil 0.2 0.2 — 0.2 Olive oil — — 0.2 — Hexadimethrine chloride — 0.3 — — (Mexomer PO from Chimex) Polyquaternium-6 0.72 0.4 0.72 2 (Merquat 100 from Nalco) Fragrance 0.5 0.5 0.5 0.5 Water qs 100 qs 100 qs 100 qs 100
Oxidizing Composition (B): (In Grams of Active Material)

(4) TABLE-US-00002 Hydrogen peroxide 6 Sodium stannate 0.04 Tetrasodium pyrophosphate decahydrate 0.02 Pentasodium pentetate 0.06 Glycerol 0.5 Cetylstearyl alcohol 2.28 Cetylstearyl alcohol containing 25 OE 0.57 Trideceth-2 carboxamide MEA 0.85 Water qs 100

(5) The compositions described above were mixed at the time of use in the following manner: the dye composition (A1) was mixed with the oxidizing composition (B), in a weight ratio (A1):(B) of 1:1.5; the dye composition (A2) was mixed with the oxidizing composition (B), in a weight ratio (A2):(B) of 1:1.5; the dye composition (A3) was mixed with the oxidizing composition (B), in a weight ratio (A3):(B) of 1:1.5; the dye composition (A4) was mixed with the oxidizing composition (B), in a weight ratio (A4):(B) of 1:1.

(6) These mixtures led to ready-to-use compositions that are particularly easy to apply, and that remain localized at the point of application.

(7) In each case, the mixture obtained was applied to locks of hair, at a rate of 10 g of mixture per 1 g of locks. After a leave-on time of 30 minutes, the locks were rinsed, washed with a standard shampoo and dried. The application is easy, the mixtures are easy to spread on the hair and remain localized on the locks.

(8) In the four cases, the colorations obtained are very homogeneous and particularly strong.