Cryogenic liquid energy storage
11686527 · 2023-06-27
Assignee
Inventors
Cpc classification
F25J2290/62
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2265/05
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C3/22
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0045
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2260/60
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2265/07
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0012
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2240/80
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/023
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C7/143
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E20/16
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
F25J1/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C3/22
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C7/143
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
Apparatus, systems, and methods use cryogenic liquids such as, for example, liquefied natural gas and liquefied air or liquefied air components to store thermal energy. The cryogenic liquids may be produced using electrically powered liquefaction methods, for example, using excess electric power during periods of over-generation on the electric grid.
Claims
1. A method of storing and recovering energy, the method comprising: regasifying liquid air or liquid air components to produce gaseous air or gaseous air components using heat from an exhaust gas stream from a turbine; expanding the regasified liquid air or liquid air components through at least one stage of expansion in an engine without combusting the regasified liquid air or liquid air components; mixing the expanded regasified liquid air or liquid air components with inlet air to a compressor to form an air mixture; compressing the air mixture with the compressor and introducing the compressed air mixture into a combustor; introducing a fuel into the combustor and combusting it with the compressed air mixture to form a hot gaseous working fluid; and expanding the hot gaseous working fluid through the turbine to form the exhaust gas stream from the turbine.
2. The method of claim 1, comprising pumping the liquid air or liquid air components to higher pressure prior to regasifying the liquid air or liquid air components.
3. The method of claim 1, wherein mixing the expanded regasified liquid air or liquid air components with inlet air to a compressor to form an air mixture cools the inlet air.
4. The method of claim 1, wherein the air mixture is denser than the inlet air.
5. The method of claim 1, comprising producing electricity with a first generator driven by the turbine and with a second generator driven by the engine.
6. The method of claim 1, wherein the engine is or comprises a turbine.
7. The method of claim 1, wherein the engine is or comprises a two stroke reciprocating engine.
8. The method of claim 1, comprising expanding the heated regasified liquid air or liquid air components through two or more stages of expansion in the engine, and reheating the liquid air or liquid air components with heat from the first turbine exhaust gas stream between expansion stages.
9. The method of claim 1, comprising producing the liquid air or liquid air components with an electrically powered liquefaction process and storing the liquid air or liquid air components.
10. The method of claim 9, comprising: producing the liquid air or liquid air components with the electrically powered liquefaction process during a first time period in which the cost of electricity is a first price; and producing electricity with a first generator driven by the turbine and with a second generator driven by the engine during a second time period, after the first time period, in which the electricity generated by the first generator and the second generator may be sold at a second price greater than the first price.
11. The method of claim 10, wherein the engine is or comprises a turbine.
12. The method of claim 11, wherein mixing the expanded regasified liquid air or liquid air components with inlet air to a compressor to form an air mixture cools the inlet air.
13. The method of claim 11, wherein the air mixture is denser than the inlet air.
14. The method of claim 10, wherein the engine is or comprises a two stroke reciprocating engine.
15. The method of claim 14, wherein mixing the expanded regasified liquid air or liquid air components with inlet air to a compressor to form an air mixture cools the inlet air.
16. The method of claim 14, wherein the air mixture is denser than the inlet air.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(9) The following detailed description should be read with reference to the drawings, in which identical reference numbers refer to like elements throughout the different figures. The drawings, which are not necessarily to scale, depict selective embodiments and are not intended to limit the scope of the invention. The detailed description illustrates by way of example, not by way of limitation, the principles of the invention. This description will clearly enable one skilled in the art to make and use the invention, and describes several embodiments, adaptations, variations, alternatives and uses of the invention, including what is presently believed to be the best mode of carrying out the invention. As used in this specification and the appended claims, the singular forms “a,” “an,” and “the” include plural referents unless the context clearly indicates otherwise.
(10) This specification discloses apparatus, systems, and methods for using cryogenic liquids such as, for example, liquefied natural gas (LNG) and liquefied air or liquefied air components (e.g., liquid Nitrogen) to store thermal energy. The cryogenic liquids may be produced using electrically powered refrigeration systems, for example, using excess electric power during periods of over-generation on the electric grid. The stored thermal energy can later be extracted in fossil fuel fired power plants such as, for example, combustion turbine generator (CTG) peaking power plants, Combined Cycle power plants incorporating one or more CTGs in combination with a heat recovery steam generator and steam turbine generator (STG), and Liquid Air Power & Storage (LAPS) systems as described, for example, in U.S. patent application Ser. No. 14/546,406 titled “Liquid Air Power and Storage” filed Nov. 18, 2014; U.S. Provisional Patent App. No. 62/169,172 titled “Part Load Operation of Liquid Air Power and Storage System” filed Jun. 1, 2015; and U.S. Provisional Patent App. No. 62/170,377 titled “Liquid Air Power and Storage with Carbon Capture” filed Jun. 3, 2015, each of which is incorporated herein by reference in its entirety. Hence, in effect the apparatus, systems, and methods disclosed in this specification may provide for storing electric power from the grid and then subsequently delivering it back to the grid, and may therefore address both the under and over generation aspects of renewable power integration with the electric grid.
(11) Further, the apparatus, systems, and methods disclosed herein may increase the reliability of fossil fuel fired power plants by securing their fuel supplies, increase the efficiency of power generation equipment, increase the power output of power plants, and/or facilitate integration of renewable energy by integrating energy storage capability at gas-fired power plants. These apparatus, systems, and methods may be suitable for use with any gas-fueled power plants, and may be particularly appropriate for natural gas fired CTGs including those employed in Combined Cycle applications and also those employed in LAPS systems.
(12) The performance of CTG based power plants may be increased by exploiting the cold cryogenic liquid to cool the CTG inlet air, thereby increasing the mass flow and power output. This may be particularly valuable on hot summer days, when peaking power plants are most needed and most affected by ambient conditions.
(13) Referring now to
(14) A cooling loop, not shown, may be used to transfer heat indirectly from the inlet air to a heat transfer fluid, such as a low freezing point “coolanol” for example, and then to the LNG to vaporize the fuel. To further improve CTG efficiency, the vaporized LNG may be further heated using heat transferred from lubrication oil coolers, or from the CTG outlet exhaust gas.
(15) By way of example, the performance of a General Electric LM6000 SPRINT PC CTG was estimated at the ISO rating condition, with 40° C. inlet air temperature as might occur on a hot summer day, and with inlet air cooling as illustrated in
(16) The estimated performance of the CTG is tabulated in Table 1 below under the heading “Cooled by LNG”. With the use of LNG for inlet air cooling, the compressor inlet temperature would be reduced from 40° C. to about 22.5° C., thereby increasing the mass flow through the CTG to increase power output, pressure ratio and efficiency. In particular, the power output would be increased by about 5.14 MW, and the fuel consumption increases by about 10.9 MW to heat the additional mass of air due to the inlet cooling. This is a marginal efficiency of 47.2%, more than the base design efficiency, illustrating why CTG inlet air cooling as disclosed herein may be advantageous.
(17) In the process of cooling the compressor inlet air, the evaporating LNG absorbs about 2.14 MW of thermal energy. Liquefaction of LNG has a coefficient of performance of about 0.5, so production of that LNG would consume about 4.5 MW, in addition to the added fuel consumption. As noted above, lower cost electricity may be used to produce the LNG. Off-peak electricity might cost about $30/MWh in North America, so the cost of liquefying one hour of fuel would be about $135. The natural gas fuel might cost about $4 per Million Btu (Higher Heating Value), which is equivalent to 13.65 $/MWh, so the hourly fuel consumption is approximately $149. So the cost of producing an incremental 5.14 MWh is $284, for a marginal power cost of $55.25/MWh. On-peak power prices typically exceed this cost by quite substantial margins, so inlet air cooling by means of the present invention may be quite profitable. Pumping liquid natural gas to the pressure required for combustion would also require less power than compressing the natural gas.
(18) An operator of peaking power plants may realize additional economic benefits from employing inlet air cooling as just described, including: assuring capacity payments, which might be lost without a secure fuel supply. securing fuel at more favorable prices (fuel arbitrage) by avoiding peak fuel demand periods. participating in emerging energy storage markets. supplying LNG fuel, for example to the long-haul transportation markets, in addition to electricity sales.
(19) With low ambient temperatures, the use of inlet air for regasifying the LNG may be constrained by the CTG torque limit, in which case another source of heat may be supplied to regasify the LNG. Auxiliary heat could be provided, for example, by CTG exhaust gas, component cooling loops, such as for lubricating oil, or by a small auxiliary burner meant for regasification and black start. The LNG could therefore provide a secure fuel source under all ambient conditions.
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(21) The liquid air or liquid air components may be produced, for example, using off-peak or low-cost electric power, and stored for later use for cooling and then mixing with the working fluid to generate electric power during an on-peak period when the cost of power and demand for power is higher.
(22) In some variations, as illustrated in
(23) Still referring to
(24) The quantity of liquid air or liquid air components through gasifier 340 is constrained by the turbine torque limit, which may be approached as the mass flow is increased. Another constraint is the compressor surge margin, which is the difference between the operating point and the pressure ratio at which the compressor begins to stall. CTGs are typically designed with 10 to 15% of surge margin, which permits additional flow through the turbine section. Surge margin is also increased by cooling the inlet air, so using liquid air for cooling and injection into the turbine section will be acceptable, within limits.
(25) By way of example, the performance of a General Electric LM6000 SPRINT PC CTG was estimated at the ISO rating condition, with 40° C. inlet air temperature, and with inlet air cooling as illustrated in
(26) Liquid air can be produced for about 0.4 kWh per kg, so production of the 7.3 kg/s of liquid air cited above would consume about 10.51 MW. As noted above, lower cost electricity may be used to produce the liquid air. Off-peak electricity might cost about $30/MWh in North America, so the cost of liquefying liquid air would be about $315 per hour of inlet cooling. The natural gas fuel might cost about $4 per Million Btu (Higher Heating Value), which is equivalent to 13.65 $/MWh, so the additional hourly fuel consumption, compared to the uncooled case is approximately $92/h. So the cost of producing the incremental 14.8 MW is $407, for a marginal power cost of $27.52/MWh, which is less than the marginal fuel cost of the CTG at the ISO condition, and comparable to base-load coal-fired generators.
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(28) Still referring to
(29) LAPS system 400 includes an organic Rankine bottoming cycle that extracts heat from the combustion turbine exhaust gas. In this bottoming cycle, gasifier 440 condenses a low pressure gaseous organic secondary working fluid to produce a low pressure liquid organic working fluid by heat exchange with liquid air or one or more liquid air components, as described above. Organic liquid pump 495 then pumps the liquid organic working fluid to higher pressure and through heat recovery organic vapor generator 460, which vaporizes the liquid organic working fluid to provide a high pressure gas that expands through ORC turbine 497 to generate additional power. The low pressure organic vapor exhaust from ORC turbine 497 is then recycled through gasifier 440.
(30) In addition to storing thermal energy in liquid air, a LAPS system may also store thermal energy in LNG produced, for example, using low cost or excess electric power, similarly to as described above for conventional CTGs. When needed, the LNG can be re-gasified using heat from any of many different locations in the LAPS cycle. In the example LAPS system 500 illustrated in
(31) Storing LNG at a power plant improves the dispatchability of CTG and LAPS peaking plants, by assuring the availability of fuel for when peaking power is needed. Natural gas can be stored as ‘line pack’ in gas pipelines, by increasing the pressure, but fluctuations in demand due to both hot and cold ambient conditions can reduce availability of fuel. Also, because the demand for peaking plants is not known in advance, the operators may not secure long-term supply agreements, and instead purchase fuel on the spot market. Often there are “tolling arrangements” with the “off-takers” which purchase the electric power, which make operators indifferent to fuel cost. Nevertheless, when insufficient fuel is available for peaking plants, both grid reliability and the Capacity Payments essential for commercial viability of peaking power plants is endangered. By liquefying natural gas and storing it, the fuel supply is secured, potentially at lower cost, and the peaking plant can be assured of meeting Capacity obligations.
(32) Cryogenic liquid energy storage may be used with conventional combustion turbines deployed in combination with LAPS systems. In some variations, some or all of the liquid air gasified by inlet air cooling of a conventional combustion turbine, as described with respect to
(33) Cryogenic liquid energy storage systems combining inlet air cooling of a conventional combustion turbine with a LAPS system may use multiple combustion turbines (e.g., in peaking plants) with inlet air cooling/liquid air gasification, and then combine the gasified liquid air to feed a single LAPS system. This may be a commercially attractive approach for combustion turbines that cannot readily accept additional compressed air (because there is no port, for example, or because there is inadequate compressor surge margin). Peaking plants often are installed with multiple units, and may for example be refit for inlet air cooling/liquid air gasification for six units, for example, all of which feed gasified liquid air to a single LAPS system. In such a case the LAPS system may be a replacement for a (e.g., seventh) combustion turbine unit in the peaking plant.
(34) Liquid air gasified by inlet air cooling of a conventional combustion turbine may be further heated with exhaust gas from the combustion turbine, and then expanded in an engine to generate power. The engine may be a turbine or a two stroke reciprocating engine, for example. Multiple stages of expansion could be used, with or without reheating between stages by the combustion turbine exhaust gas. In example cryogenic liquid energy storage system 700 shown in
(35) In example cryogenic liquid energy storage system 800 shown in
(36) The following enumerated clauses provide additional non-limiting aspects of the disclosure.
(37) 1. A method of storing and recovering energy, the method comprising:
(38) regasifying liquid natural gas to gaseous form by heat exchange with inlet air to a compressor, thereby cooling the inlet air;
(39) compressing the inlet air with the compressor and introducing the compressed inlet air into a combustor;
(40) introducing the gaseous natural gas into the combustor and combusting it with the compressed inlet air to form a hot gaseous working fluid; and
(41) expanding the hot gaseous working fluid through a turbine.
(42) 2. The method of clause 1, comprising producing electricity with a generator driven by the turbine.
(43) 3. The method of clause 1 or clause 2, comprising further heating the gaseous natural gas before introducing it into the combustor.
(44) 4. The method of any of clauses 1-3, comprising further heating the gaseous natural gas with heat from exhaust gas from the turbine before introducing it into the combustor.
(45) 5. The method of any of clauses 1-4, comprising producing the liquid natural gas with an electrically powered liquefaction process and storing the liquid natural gas.
(46) 6. A method of storing and recovering energy, the method comprising:
(47) regasifying liquid air or liquid air components by heat exchange with inlet air to a compressor, thereby cooling the inlet air;
(48) compressing the inlet air with the compressor and introducing the compressed inlet air into a combustor;
(49) introducing the regasified liquid air or liquid air components into the combustor;
(50) introducing a fuel into the combustor and combusting it with the compressed inlet air and with the regasified liquid air or liquid air components to form a hot gaseous working fluid; and
(51) expanding the hot gaseous working fluid through a turbine.
(52) 7. The method of clause 6, comprising producing electricity with a generator driven by the turbine.
(53) 8. The method of clause 6 or clause 7, comprising further heating the regasified liquid air or liquid air components before introducing the regasified liquid air or liquid air components into the combustor.
(54) 9. The method of any of clauses 6-8, comprising further heating the regasified liquid air or liquid air components with heat from exhaust gas from the turbine before introducing the regasified liquid air or liquid air components into the combustor.
(55) 10. The method of clause 9, comprising matching the temperature of the regasified liquid air or liquid air components to the temperature of the compressed inlet air exiting the compressor.
(56) 11. The method of any of clauses 6-10, comprising introducing the regasified liquid air or liquid air components into a path to the combustor through compressor bleed ports, compressor discharge flanges, steam injection ports, or fuel nozzles.
(57) 12. The method of any of clauses 6-11, comprising producing the liquid air or liquid air components with an electrically powered liquefaction process and storing the liquid air or liquid air components.
(58) 13. A method of storing and recovering energy, the method comprising:
(59) regasifying liquid air or liquid air components to produce gaseous air or gaseous air components using heat from exhaust gas from a first turbine;
(60) regasifying liquid natural gas to produce gaseous natural gas using heat from exhaust gas from the first turbine;
(61) combusting the gaseous natural gas with the gaseous air or gaseous air components to form a gaseous primary working fluid at an elevated temperature; and expanding the primary working fluid through the first turbine.
(62) 14. The method of clause 13, comprising producing electricity with a generator driven by the first turbine.
(63) 15. The method of clause 13 or clause 14, comprising heating a secondary working fluid with heat from the first turbine exhaust gas to convert the secondary working fluid from a liquid to a gas phase, expanding the gaseous secondary working fluid through a second turbine, and condensing the secondary working fluid from gas phase to liquid phase by transferring heat from the secondary working fluid to the liquid natural gas and to the liquid air or liquid air components during regasification of the liquid natural gas and regasification of the liquid air or liquid air components.
(64) 16. The method of clause 15, comprising producing electricity with a first generator driven by the first turbine and with a second generator driven by the second turbine.
(65) 17. The method of clause 15 or clause 16, wherein the secondary working fluid is an organic working fluid.
(66) 18. The method of any of clauses 13-17, comprising producing the liquid air or liquid air components with an electrically powered liquefaction process and storing the liquid air or liquid air components.
(67) 19. The method of any of clauses 13-18, comprising producing the liquid natural gas with an electrically powered liquefaction process and storing the liquid natural gas.
(68) 20. A method of storing and recovering energy, the method comprising:
(69) regasifying liquid air or liquid air components by heat exchange with inlet air to a compressor, thereby cooling the inlet air;
(70) compressing the inlet air with the compressor and introducing the compressed inlet air into a first combustor;
(71) introducing a fuel into the first combustor and combusting it with the compressed inlet air to form a first hot gaseous working fluid;
(72) expanding the first hot gaseous working fluid through a first turbine;
(73) introducing the regasified liquid air or liquid air components into a second combustor;
(74) introducing a fuel into the second combustor and combusting it with the regasified liquid air or regasified liquid air components to form a second hot gaseous working fluid; and
(75) expanding the second hot gaseous working fluid through a second turbine.
(76) 21. The method of clause 20, comprising producing electricity with a first generator driven by the first turbine and with a second generator driven by the second turbine.
(77) 22. A method of storing and recovering energy, the method comprising:
(78) regasifying liquid air or liquid air components by heat exchange with inlet air to a compressor, thereby cooling the inlet air;
(79) compressing the inlet air with the compressor and introducing the compressed inlet air into a combustor;
(80) introducing a fuel into the combustor and combusting it with the compressed inlet air to form a hot gaseous working fluid;
(81) expanding the hot gaseous working fluid through a turbine; further heating the regasified liquid air or liquid air components with heat from exhaust gas from the turbine; and
(82) expanding the heated regasified liquid air or liquid air components through at least one stage of expansion in an engine.
(83) 23. The method of clause 22, comprising producing electricity with a first generator driven by the turbine and with a second generator driven by the engine.
(84) 24. The method of clause 22 or clause 23 wherein the engine is or comprises a turbine.
(85) 25. The method of clause 22 or clause 23, wherein the engine is or comprises a two stroke reciprocating engine.
(86) 26. The method of any of clauses 22-25, comprising expanding the heated regasified liquid air or liquid air components through two or more stages of expansion in the engine, and reheating the liquid air or liquid air components with heat from the first turbine exhaust gas stream between expansion stages.
(87) 27. A method of storing and recovering energy, the method comprising:
(88) regasifying liquid air or liquid air components to produce gaseous air or gaseous air components using heat from exhaust gas from a turbine;
(89) expanding the regasified liquid air or liquid air components through at least one stage of expansion in an engine;
(90) mixing the expanded regasified liquid air or liquid air components with inlet air to a compressor to form an air mixture;
(91) compressing the air mixture with the compressor and introducing the compressed air mixture into a combustor;
(92) introducing a fuel into the combustor and combusting it with the compressed air mixture to form a hot gaseous working fluid; and
(93) expanding the hot gaseous working fluid through the turbine.
(94) 28. The method of clause 27, comprising producing electricity with a first generator driven by the turbine and with a second generator driven by the engine.
(95) 29. The method of clause 27 wherein the engine is or comprises a turbine.
(96) 30. The method of clause 27, wherein the engine is or comprises a two stroke reciprocating engine.
(97) 31. The method of any of clauses 27-30, comprising expanding the heated regasified liquid air or liquid air components through two or more stages of expansion in the engine, and reheating the liquid air or liquid air components with heat from the first turbine exhaust gas stream between expansion stages.
(98) This disclosure is illustrative and not limiting. Further modifications will be apparent to one skilled in the art in light of this disclosure and are intended to fall within the scope of the appended claims.
(99) TABLE-US-00001 TABLE 1 Performance of CTG with inlet air cooling LM6000 SPRINT PC 15 C. 40 C. Cooled Cooled by estimates inlet air inlet air by LNG Liquid Air Compressor Inlet Flow 101.88 101.88 101.88 101.88 (m.sup.3/s) Compressor Inlet Flow 124.9 114.9 119.315 124.9 (kg/s) Compressor Pressure 30.8 28.25 29.43 32.63 Ratio Compressor Inlet 15 40 22.5 15 Temperature (C.) Turbine Inlet 1243 1243 1243 1243 Temperature (C.) Turbine Inlet Flow 17.66 17.65 17.65 17.65 (m.sup.3/s) Turbine Outlet 468 482 475 459 Temperature (C.) Net Generator Power 47.43 38.98 44.12 53.8 (MW) Fuel Flow (MW) 112.1 97.3 108.2 123.3 Efficiency 42.3% 40.0% 40.8% 43.6% HHV Heat Rate 8510 8991 8827 7822 (kJ/kWh)