Magnetoresistance effect element and magnetic memory
11690299 · 2023-06-27
Assignee
Inventors
- Hideo Sato (Miyagi, JP)
- Shinya ISHIKAWA (Miyagi, JP)
- Shunsuke Fukami (Miyagi, JP)
- Hideo Ohno (Miyagi, JP)
- Tetsuo Endoh (Miyagi, JP)
Cpc classification
H10B61/20
ELECTRICITY
H10B99/00
ELECTRICITY
International classification
H10B61/00
ELECTRICITY
Abstract
Provided is an X-type 3-terminal STT-MRAM (spin orbital torque magnetization reversal component) having a high thermal stability index Δ and a low writing current I.sub.C in a balanced manner. A magnetoresistance effect element has a configuration of channel layer (1)/barrier layer non adjacent magnetic layer (2b)/barrier layer adjacent magnetic layer (2a)/barrier layer (3).
Claims
1. A magnetoresistance effect element, comprising: a channel layer, a recording layer disposed adjacent to said channel layer, and including a ferromagnetic substance, and a barrier layer disposed adjacent to said recording layer on an opposite side thereof to said channel layer, and constituted by an insulator, wherein said recording layer has at least two or more magnetic layers including films having different magnetic characteristics, wherein said two or more magnetic layers consist of one barrier-layer-adjacent-magnetic-layer disposed adjacent to said barrier layer, and one or more barrier-layer-non-adjacent-magnetic-layers that are not adjacent to said barrier layer, wherein the barrier-layer-adjacent-magnetic-layer and the barrier-layer-non-adjacent-magnetic-layers are magnetically bonded, and a magnetization direction of both of said barrier-layer-adjacent-magnetic-layer and said barrier-layer-non-adjacent-magnetic-layers is in parallel with a film surface, is variable, and is made reversal in a same direction, wherein a current in a direction substantially in parallel with said recording layer is introduced to said channel layer, thereby making a magnetization direction of said recording layer reversal, wherein said barrier-layer-non-adjacent-magnetic-layer is constituted by a magnetic material film made of a Co film serving as an in-plane axis of easy magnetization, and wherein an axis of easy magnetization of said recording layer is in a direction at within ±45° with respect to a direction of said current.
2. The magnetoresistance effect element according to claim 1, wherein said barrier-layer-adjacent-magnetic-layer includes at least Fe, and said barrier layer includes at least O.
3. The magnetoresistance effect element according to claim 1, wherein a non-magnetic insertion layer is inserted between said two or more magnetic layers forming said recording layer.
4. The magnetoresistance effect element according to claim 1, wherein said channel layer has a heavy metal.
5. The magnetoresistance effect element according to claim 1, wherein a longitudinal effective field to be applied to said recording layer from a direction perpendicular to a film surface of said channel layer due to introduction of a current to said channel layer makes the magnetization direction of said recording layer reversal.
6. The magnetoresistance effect element according to claim 1, wherein said channel layer has a shape extended in the direction of said current to be introduced, and said recording layer has substantially a two-fold symmetric shape in a recording layer plane, and a longitudinal direction has a component in the direction of said current.
7. The magnetoresistance effect element according to claim 1, wherein a pulse width of the current to be introduced to said channel layer is 0.3 to 10 nanoseconds.
8. A magnetic memory comprising the magnetoresistance effect element according to claim 1.
9. A magnetoresistance effect element, comprising: a channel layer, a recording layer disposed adjacent to said channel layer, and including a ferromagnetic, and a barrier layer disposed adjacent to said recording layer on an opposite side thereof to said channel layer, and including an insulator, wherein said recording layer has at least two or more magnetic layers including films having different magnetic characteristics, wherein said two or more magnetic layers consists of one barrier-layer-adjacent-magnetic-layer disposed adjacent to said barrier layer, and one or more barrier-layer-non-adjacent-magnetic-layers not adjacent to said barrier layer, wherein the barrier-layer-adjacent-magnetic-layer and the barrier-layer-non-adjacent-magnetic-layers are magnetically bonded, and a magnetization direction of both of said barrier-layer-adjacent-magnetic-layer and said barrier-layer-non-adjacent-magnetic-layers is in parallel with a film surface, is variable, and is made reversal in a same direction, wherein a current in a direction substantially in parallel with said recording layer is introduced to said channel layer, thereby making a magnetization direction of said recording layer reversal, wherein said at least one or more barrier-layer-non-adjacent-magnetic-layers is constituted by a magnetic material film made of a Co film serving as an in-plane axis of easy magnetization, and wherein an axis of easy magnetization of said recording layer is in a direction at within ±45° with respect to a direction of said current.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DESCRIPTION OF EMBODIMENTS
(27) A magnetoresistance effect element and a magnetic memory of the present invention will be described in details below with reference to the accompanying drawings.
(28) Note that each drawing is only an example, and is described with a reference number, which does not restrict the present invention at all.
Embodiment 1
(29)
(30) The channel layer (1) may only be a material having a characteristic just to generate a spin current enough to reverse the recording layer at the magnetic tunnel junction, and especially desirably has a heavy metal. When a writing current I.sub.C is introduced to the channel layer, a spin current is generated. Accordingly, the magnetization direction of the adjacent recording layer (A1) is made reversal, so that writing to the magnetoresistance effect element is performed. For this reason, the channel layer (1) desirably includes a heavy metal having a large spin orbital interaction such as Ta, W, Hf, Re, Os, Ir, Pt, or Pd, or an alloy thereof. Alternatively, the material may be either a material obtained by appropriately adding a transition metal to the heavy metal layer, or a material obtained by doping a conductive material or the like with a heavy metal. Still alternatively, for the purpose of improving the electric material characteristics, or other purposes, B, C, N, O, Al, Si, P, Ga, Ge, or the like may be added. Further, Co—Ga described in NPL 4, or the like also becomes an option.
(31) The shape of the channel layer (1) has no particular restriction so long as it allows passage of a writing current I.sub.C therethrough, and allows efficient magnetization reversal with respect to the recording layer (A1). A planar shape extended in the direction of the writing current I.sub.C is desirable. The current is introduced to the channel layer in the direction substantially in parallel with the recording layer. Assuming that the direction of the current is an X axis, the thickness of the channel layer is 0.5 nm to 20 nm, and preferably 1 nm to 10 nm, the length in the X axial direction is 60 nm to 260 nm, and preferably 100 nm to 150 nm, and the width in the Y axial direction is 20 nm to 150 nm, and preferably 60 nm to 120 nm.
(32) The recording layer (A1) has at least two or more magnetic layers including films having different magnetic characteristics. The two or more magnetic layers include a barrier layer (3), one barrier layer adjacent magnetic layer (2a) that is disposed adjacent to the barrier layer (3), and one or more barrier layer non adjacent magnetic layers (2b) that is not adjacent to the barrier layer (3).
(33) Herein, the films having different magnetic characteristics denote alloy films or laminated layer films having different various characteristics such as magnetic anisotropy and saturation magnetization. Generally, by changing the material, the composition, and the adjacent materials, it is possible to manufacture films having different magnetic characteristics with ease.
(34) For the barrier layer adjacent magnetic layer (2a) that is adjacent to the barrier layer (3), it is desirable that a material including at least Fe is used in order to increase the TMR ratio. Specific examples thereof may include alloys such as Fe—B and Co—Fe—B. Further, for the purpose of improving the electric material characteristics, C, N, O, Al, Si, P, Ga, Ge, or the like may be added.
(35) The film thickness of the barrier layer adjacent magnetic layer (2a) is appropriately adjusted so as to be able to absorb the film thickness variation in the wafer, and is typically 0.5 nm or more, and more preferably 1.4 nm or more.
(36) Particularly, the film thickness of the barrier layer adjacent magnetic layer (2a) is adjusted as thin as possible within the range where the in-plane easy axis is exhibited in view of the film thickness variation within the wafer and the reduction of diamagnetic field coefficient in the direction perpendicular to a film surface upon processing into a component shape. When CoFeB is used for the barrier layer adjacent magnetic layer (2a), and MgO is used for the barrier layer (3), the film thickness is about 1.0 nm to 2.5 nm. The reason why the film thickness is adjusted as thin as possible within the range where the in-plane easy axis is exhibited is as follows: the absolute value of the effective anisotropic magnetic field in the perpendicular direction increases with an increase in film thickness, resulting in an increase in writing current.
(37) The barrier layer non adjacent magnetic layer (2b) that is not adjacent to the barrier layer (3) preferably includes a magnetic material film having perpendicular magnetic anisotropy, and exhibiting an in-plane axis of easy magnetization. Here, the magnetic material film having perpendicular magnetic anisotropy, and exhibiting an in-plane axis of easy magnetization represents a material in which the magnetic field upon saturation of magnetization is smaller than the spontaneous magnetization when the magnetization is measured while making application of a magnetic field in the perpendicular direction.
(38) Specific examples thereof may include a film including at least Co, a laminated layer film including at least Co, and an alloy film including at least Co or Mn. Mention may be made of a Co film, a Co/Pt laminated layer film, a Co/Pd laminated layer film, a Co/Ni laminated layer film, a CoPt alloy film, a CoPd alloy film, a CoNi alloy film and Mn type ordered alloys such as Mn—Al, Mn—Ga, and Mn—Ge. The laminated layer film has a laminated layer structure of two or more layers, and may only be a material which has perpendicular magnetic anisotropy, and can be adjusted so as to have an in-plane axis of easy magnetization according to the film thickness, the film formation conditions, the composition, and the like. For the Co film, the CoPt alloy film, the Co/Pt laminated layer film, the CoPd alloy film, the Co/Pd laminated layer film, the CoNi alloy film, the Co/Ni laminated layer film, and the like, the magnetic characteristics may be adjusted by appropriately adding another or more elements to each layer material, and the electric material characteristics, and the like may be improved by adding one or more elements such as B, C, N, O, Al, Si, P, Ga, and Ge.
(39) Particularly, the film thickness of the barrier layer non adjacent magnetic layer (2b) is appropriately adjusted so as to prevent an increase in the absolute value of the effective diamagnetic field in the perpendicular direction when the interface magnetic anisotropy generated between the material of the channel layer (1) and the material of the barrier layer non adjacent magnetic layer (2b) is used. For example, Pt is used for the material of the channel layer (1), and Co is used for the barrier layer non adjacent magnetic layer (2b). In this case, when the Co film thickness is small (e.g., to 1 nm), a perpendicular easy axis is achieved by the perpendicular magnetic anisotropy at the interface with the material Pt of the channel layer (1). When the Co film thickness increases, the in-plane easy axis is achieved while imparting the perpendicular magnetic anisotropy. After achieving the in- plane easy axis, the film thickness is appropriately adjusted so as not to excessively increase the absolute value of the effective diamagnetic field. On the other hand, in each case of the Co/Pt laminated layer film, the Co/Pd laminated layer film, the Co/Ni laminated layer film, and the like, each laminated film has perpendicular magnetic anisotropy due to the interface anisotropy between Co and Pt, Pd, or Ni. The film thickness of each layer is appropriately adjusted so that the absolute value of the effective diamagnetic field in the perpendicular direction becomes constant, and the number of cycles of deposition for forming a laminated films is increased. The number of cycles of deposition for forming a laminated films may be appropriately adjusted so as to obtain a desirable thermal stability index Δ. Alternatively, in the case using a CoPt alloy film having bulk perpendicular magnetic anisotropy, or the like, the composition and the film formation conditions are appropriately adjusted so as to prevent the absolute value of the effective diamagnetic field in the perpendicular direction from becoming larger than that of the barrier layer adjacent magnetic layer (2a) in the in-plane magnetic film. Thus, the film thickness is appropriately adjusted so as to obtain a desirable thermal stability index Δ.
(40) Further, when the size of the component is changed, the diamagnetic field coefficient in the perpendicular direction changes. For this reason, the film thicknesses, the compositions, and the film formation conditions of the barrier layer adjacent magnetic layer (2a) and the barrier layer non adjacent magnetic layer (2b) are appropriately adjusted.
(41) As described up to this point, the film thickness of the barrier layer non adjacent magnetic layer (2b) is appropriately adjusted so as to obtain a desirable thermal stability index Δ. When the film thickness is increased with the effective diamagnetic field in the direction perpendicular to a film surface set constant, design is achieved so as to prevent the extreme increase in thermal stability index Δ. From such a viewpoint, in the case using a Co/Pt laminated layer film, a Co/Pd laminated layer film, a Co/Ni laminated layer film, a CoPd alloy film, or the like, the film thickness is typically 1 nm to 10 nm, and more preferably 1 nm to 6 nm. When the barrier layer non adjacent magnetic layer is added for making a laminated layer, the total of the film thicknesses is adjusted to typically 40 nm or less, and more preferably 24 nm or less. Further, in the case using a Mn type ordered alloy such as Mn—Al, Mn—Ga, or Mn—Ge illustrating less spontaneous oxidation, the film thickness of the barrier layer non adjacent magnetic layer (2b) is typically 90 nm or less, and more preferably 54 nm or less.
(42) The barrier layer (3) includes at least O. Specific examples may include MgO, Al.sub.2O.sub.3, and AlN.
(43) The film thickness of the barrier layer (3) is desirably 0.1 nm to 5 nm, and further 0.5 nm to 2 nm. When the film thickness is smaller than 0.1 nm, it becomes difficult to form continuous films in association with the atom size. On the contrary, when the film thickness is larger than 5 nm, the film formation time increases. For this reason, the length of time for manufacturing one wafer increases, resulting in a higher cost.
(44) Incidentally, the recording layer (A1) is configured so as to have not only one magnetic layer but also at least two or more magnetic layers including films having different magnetic characteristics for the following reasons.
(45) First, at the interface between the barrier layer adjacent magnetic layer (2a) and the barrier layer (3), the interface magnetic anisotropy is caused. For this reason, in order to decrease the writing current I.sub.C of the recording layer (A1) having the in-plane axis of easy magnetization, it is essential only that the absolute value of the effective diamagnetic field H.sub.K.sup.eff in the direction perpendicular to a film surface is reduced by thinning the barrier layer adjacent magnetic layer (2a).
(46) However, thinning of the barrier layer adjacent magnetic layer (2a) also causes a reduction of the thermal stability index Δ. In other words, with the configuration of only one magnetic layer adjacent to the barrier layer, the decrease in the writing current I.sub.C and the increase in thermal stability index Δ hold the relationship of tradeoff.
(47) Thus, the barrier layer non adjacent magnetic layer (2b) constituted by a magnetic material film having perpendicular magnetic anisotropy and serving as the in-plane axis of easy magnetization is used to form a laminated layer between the barrier layer adjacent magnetic layer (2a) and the channel layer (1). As a result, without increasing the absolute value of the effective diamagnetic field H.sub.K.sup.eff in the direction perpendicular to a film surface, the film thickness of the whole (overall) magnetic layers of the recording layer is increased, thereby increasing the thermal stability index Δ.
(48) Note that, as the actual magnetoresistance effect element, the configuration is exemplified in which a reference layer is disposed adjacent to the barrier layer (3) on the opposite side thereof to the barrier layer adjacent magnetic layer (2a) in the basic configuration of Embodiment 1.
Embodiment 2
(49)
(50) The configuration and features of the additional barrier layer non adjacent magnetic layer (2c) are the same as those of the barrier layer non adjacent magnetic layer (2b). In order to increase the thermal stability index Δ by increasing the film thickness of the whole (overall) magnetic layers of the recording layer without increasing the absolute value of the effective diamagnetic field H.sub.k .sup.eff in the direction perpendicular to a film surface, the additional barrier layer non adjacent magnetic layer (2c) is additionally inserted.
(51)
Embodiment 3
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(53) The non-magnetic insertion layer (2d) is inserted for providing the discontinuity of a crystal between the barrier layer adjacent magnetic layer (2a) and the barrier layer non adjacent magnetic layer (2b). For example, when Co is used for the barrier layer non adjacent magnetic layer (2b), and Pt is used for the channel layer (1), Co includes a face-centered cubic lattice or a hexagonal closest packed structure. The (111) plane or (002) plane thereof is oriented in parallel with the film surface. However, in this case, with a general configuration in which MgO and CoFeB are used for the materials of the barrier layer (3) and the barrier layer adjacent magnetic layer (2a), respectively, in order to increase the tunnel magnetoresistance ratio, the (001) plane of the body-centered cubic lattice of CoFeB is required to be oriented in parallel with the film surface, so that the crystallographic symmetry is not aligned. For this reason, in order to provide the discontinuity of a crystal, the non-magnetic insertion layer (2d) is provided. The non-magnetic insertion layer (2d) is preferably Ta, W, Mo, Nb, or the like. Further, even a material having magnetism is usable so long as the discontinuity of a crystal can be provided. For example, an alloy obtained by adding Zr or Ta to Fe, or the like can be used.
(54) The film thickness of the non-magnetic insertion layer (2d) is 0.1 nm to 0.5 nm. When the film thickness of the non-magnetic insertion layer (2d) is larger than 0.5 nm, the magnetic bond between the barrier layer adjacent magnetic layer (2a) and the barrier layer non adjacent magnetic layer (2b) is weakened, resulting in a reduction of the thermal stability.
(55) Further, the interface magnetic anisotropy varies between the barrier layer adjacent magnetic layer (2a) and the barrier layer (3) depending upon the material of the non-magnetic insertion layer (2d), and hence the film thickness of the barrier layer adjacent magnetic layer (2a) is appropriately adjusted so as to be able to absorb the film thickness variation.
Embodiment 4
(56)
(57) The reference layer (4) is used to form a laminated layer so as to be adjacent to the barrier layer (3) on the opposite side thereof to the barrier layer adjacent magnetic layer (2a). The magnetization direction of the reference layer (4) may be substantially fixed in the longitudinal direction of the two-fold symmetric shape.
(58) The bit information is read out based on the magnetization direction of the reference layer (4) substantially fixed in the longitudinal direction, and the magnetization direction of the recording layer (A1) having a component variable and in the direction of the current.
(59) The reference layer (4) has no particular restriction so long as it is a material with the magnetization direction fixed in a longitudinal direction, and preferably includes a material including at least one ferromagnetic transition metal element such as Co, Fe, Ni, or Mn. More preferably, the one obtained by adding an element such as B to the transition metal is used.
Embodiment 5
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(61) For the ferromagnetic layer (4a) and the ferromagnetic layer (4c), a material including a ferromagnetic transition metal element such as Fe, Co, or Ni is desirably used. For the coupling layer (4b), a material including Ru, Ir, or the like is desirably used.
(62) The ferromagnetic layer (4a) and the ferromagnetic layer (4c) are magnetically bonded with each other by the coupling layer (4b), thereby stabilizing the magnetization of the reference layer (B1).
Embodiment 6
(63)
(64) The auxiliary magnetic layer (5a) is disposed adjacent to the channel layer (1) on the opposite side thereof to the recording layer (A1), and has a magnetic field fixed in the Z axial direction. The magnetic field thereof is stably applied to the recording layer (A1). The auxiliary magnetic layer (5a) has no restriction so long as it is a material having a magnetic field fixed in the Z axial direction, for which a material including a ferromagnetic transition metal element such as Fe, Co, or Ni is desirably used. For example, a Co/Pt laminated layer film, a Co/Pd laminated layer film, a Co/Ni laminated layer film, a CoPt alloy film, a CoPd alloy film, a CoNi alloy film, a Co film, and Mn type ordered alloys such as Mn—Al, Mn—Ga, and Mn—Ge, each appropriately adjusted in film formation conditions, composition, and film thickness so as to have perpendicular magnetic anisotropy, and exhibit perpendicular axis of easy magnetization, may become options.
(65) When the magnetoresistance effect element has the auxiliary magnetic layer (5a), the magnetoresistance effect element itself can be applied with a perpendicular magnetic field. This eliminates the necessity of applying an external magnetic field H.sub.0 in the write operation.
Embodiment 7
(66)
(67) The electrically conducting layer (6) is disposed adjacent to the reference layer (B1) on the opposite side thereof to the barrier layer (3). The auxiliary magnetic layer (5b) is disposed adjacent to the electrically conducting layer (6) on the opposite side thereof to the reference layer (B1). The electrically conducting layer (6) includes a conductive non-magnetic body, and is inserted for preventing the switched connection between the auxiliary magnetic layer (5b) and the reference layer (B1). The auxiliary magnetic layer (5b) has a magnetic field fixed in the Z axial direction. The magnetic field is stably applied to the recording layer (A1). The auxiliary magnetic layer (5b) has no restriction so long as it is a material having a magnetic field fixed in the Z axial direction, for which a material including a ferromagnetic transition metal element such as Fe, Co, or Ni is desirably used.
(68) When the magnetoresistance effect element includes the auxiliary magnetic layer (5b), the magnetoresistance effect element itself can be applied with a perpendicular magnetic field. This eliminates a necessity of applying an external magnetic field H.sub.0 in the write operation.
Embodiment 8
(69)
(70) Examples of respective layers in
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(72) When the external magnetic field H.sub.0 is applied, the intensity of the external magnetic field H.sub.0 is about 1 mT to 500 mT, and more desirably about 5 mT to 200 mT.
(73) Further,
(74)
Embodiment 9
(75)
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(78) The pulse width of the writing current I.sub.C is set equal to, or larger than the time required for writing, and varies according to the conditions such as composition and the film thickness of each layer, the current value, and the intensity of the magnetic field to be subjected to application. Specific examples thereof are less than 30 nanoseconds, for example, 0.1 nanosecond to 10 nanoseconds, and more preferably 0.3 nanosecond to 10 nanoseconds.
(79) In
Embodiment 10
(80)
(81) Any in-plane axis of easy magnetization of the recording layer (A1) is acceptable so long as it has an X axial component on which a spin orbital torque acts by the writing current I.sub.C to the channel layer (1). For this reason, the direction of the in-plane axis of easy magnetization of the recording layer (A1) is not required to be strictly the X axial direction, and the shape thereof is also arbitrary. However, the recording layer (A1) desirably has substantially two-fold symmetry within the range of ununiformity in the plane (in the layer, in the X-Y axial direction) of the recording layer (A1).
Embodiment 11
(82)
(83) The planar shape of the channel layer (1) is a rectangle, the planar shapes of the recording layer (A1), the barrier layer (3), and the reference layer (4) are each an ellipse, and the axis of easy magnetization of the recording layer is arranged at an angle θ in the X-Y axial direction with respect to the direction of the current of the channel layer (1) (X axial direction).
(84) The axis of easy magnetization of the recording layer (A1) has an X axial component and a Y axial component. By allowing the axis of easy magnetization to have a Y axial component, the magnetization direction of the recording layer (A1) can be made reversal even if the magnetic field in the Z axial direction by the external magnetic field H.sub.0 or the auxiliary magnetic layers (5a and 5b) is not subjected for application.
(85) The angle θ is set so as to be ±3° to ±45°, and preferably ±3° to ±25° when the X axial direction is assumed to be 0°.
(86) Note that the angle θ is a preferable value when the external magnetic field H.sub.0 or the magnetic field in the Z axial direction by the auxiliary magnetic layers (5a and 5b) is not applied. When the magnetic field in the Z axial direction is separately applied, for example, the write operation also becomes possible within the range of 0° to ±3°.
Embodiment 12
(87)
(88) When data is written to the magnetic memory cell circuit, a difference is caused in level setting between the first bit line (BL1) and the second bit line (BL2). As a result, the writing current I.sub.C is introduced to the channel layer (1), and the magnetization direction of the recording layer (A1) is made reversal, so that data is written.
(89) When data is read out from the magnetic memory cell circuit, the word line (WL) is set to an active level. Then, the first transistor (Tr1) and the second transistor (Tr2) are turned ON, and both of the first bit line (BL1) and the second bit line (BL2) are set to High level, or one of them is set to High level and the other is opened. As a result, a readout current passes from channel layer (1) through recording layer (A1), barrier layer (3), reference layer (B1), third terminal (T3), to ground line (GND), so that the recorded data is read out from the resistance value of the path.
(90)
(91)
(92) The magnetic memory cell circuit configuration of Embodiment 12 is one example, and may only be a circuit configuration such that the writing current I.sub.C is introduced to the channel layer for writing, and the magnetic resistance of the recording layer (A1) and the reference layer (B1) interposing the barrier layer (3) therebetween can be read.
Embodiment 13
(93)
(94) The magnetic memory include a memory cell array, an X driver, a Y driver, and a controller. The memory cell array has magnetic memory cells arranged in an array. The X driver is connected to a plurality of word lines (WL), and the Y driver is connected to a plurality of bit lines (BL), and function as a readout means and a writing means.
Embodiment 14
(95)
(96) The basic configuration of the magnetoresistance effect element of the conventional example is channel layer (1): Ta, barrier layer adjacent magnetic layer (2a): CoFeB, and barrier layer (3): MgO.
(97) On the other hand, the configuration of the magnetoresistance effect element of Embodiment 14 is channel layer (1): Pt (5 nm), barrier layer non adjacent magnetic layer (2b): Co (2.1 nm), non-magnetic insertion layer (2d): Ta (0.2 nm), barrier layer adjacent magnetic layer (2a): CoFeB (1.4 nm), and barrier layer (3): MgO. Herein, in Embodiment 14, the effective film thickness of the Co layer is reduced by about 0.7 nm due to mutual diffusion with Ta of the non-magnetic insertion layer (2d).
(98) The graph shown in (c) shows each saturation magnetization Ms (T) determined from the magnetization curves of the magnetoresistance effect elements when the film thickness t.sub.FM of CoFeB is set at 1.4 nm to 2.5 nm in the basic configuration of the magnetoresistance effect element of the conventional example, and Embodiment 14.
(99) When the film thickness of CoFeB increases in the conventional example, the saturation magnetization Ms shows roughly a constant value, and the value is about 1.5 T. When a material of an in-plane easy axis is used, the thermal stability index Δ is proportional to the square of the saturation magnetization and the film thickness of the magnetic layer. For this reason, when the film thickness of CoFeB increases, the thermal stability also increases.
(100) On the other hand, in Embodiment 14, CoFeB has a film thickness of 1.4 nm, and the total of the effective film thicknesses of the magnetic layers in the recording layer is 2.9 nm. In this system, the saturation magnetization Ms was about 1.7 T. As compared with the film thickness (1.4 nm) of CoFeB, the saturation magnetization Ms is about 1.13 times that of the conventional example. It is considered that the thermal stability also increases to about 1.3 times when comparison is made with the conventional example of the same film thickness.
(101) Accordingly, it is indicated as follows: even when the film thickness of CoFeB of the barrier layer adjacent magnetic layer (2a) is minimized at 1.4 nm so as to cause the in-plane easy axis in Embodiment 14, it is possible to obtain the thermal stability about 1.3 times larger than that of the one obtained by increasing the film thickness of CoFeB by inserting the barrier layer non adjacent magnetic layer (2b).
(102) Further, (d) is the graph showing the product μ.sub.0H.sub.K.sup.eff (T) of the effective diamagnetic field H.sub.K.sup.eff in a direction perpendicular to a film surface and the space permeability μ.sub.0 determined from the magnetization curve of the recording layer of each magnetoresistance effect element when the film thickness t.sub.FM of CoFeB is set at 1.4 nm to 2.5 nm in the basic configuration of the magnetoresistance effect element of the conventional example, and Embodiment 14.
(103) It is indicated that when the film thickness of CoFeB increases in the conventional example, the product μ.sub.0H.sub.K.sup.eff (T) of the effective diamagnetic field H.sub.K.sup.eff in a direction perpendicular to a film surface and the space permeability μ.sub.0 decreases, and the absolute value increases. The absolute value of the effective diamagnetic field H.sub.K.sup.eff in a direction perpendicular to a film surface and the value of the writing current I.sub.C have positive correlation. For this reason, an increase in film thickness of CoFeB also results in an increase in writing current I.sub.C.
(104) On the other hand, in Embodiment 14, even when the total of the film thicknesses of the effective magnetic layers in the recording layer becomes 2.9 nm, the absolute value of the product μ.sub.0H.sub.K.sup.eff (T) of the effective diamagnetic field H.sub.K.sup.eff in a direction perpendicular to a film surface and the space permeability μ.sub.0 becomes about 150 mT, and is roughly equal to the value (about 100 mT) when the film thickness of CoFeB of the conventional example is 1.4 nm to 1.6 nm.
(105) Accordingly, conceivably, even when the barrier layer non adjacent magnetic layer (2b) is inserted to the barrier layer adjacent magnetic layer (2a) of CoFeB, and the total of the film thicknesses of the magnetic layers increases to 2.9 nm in Embodiment 14, the operation is possible at an about 80% lower writing current as compared with the case where the film thickness of CoFeB is set at 2.9 nm in the conventional example.
(106) From the description up to this point, the magnetoresistance effect element of Embodiment 14 combines both characteristics of a higher thermal stability index Δ and a lower writing current I.sub.C as compared with the conventional example.
(107) Note that the layer configuration shown in each embodiment may only include layers arranged sequentially adjacent to one another, and has no restriction on the method of deposition to form a laminated layer, the order of deposition for forming laminated layer, the vertical and horizontal orientations, and the like.
REFERENCE SIGNS LIST
(108) 1 Channel layer 2a Barrier layer adjacent magnetic layer 2b Barrier layer non adjacent magnetic layer 2c Additional barrier layer non adjacent magnetic layer 2d Non-magnetic insertion layer 3 Barrier layer 4 Reference layer 4a, 4c Ferromagnetic layer 4b Coupling layer 5a, 5b Auxiliary magnetic layer 6 Electrically conducting layer A1 Recording layer B1 Reference layer BL1 First bit line BL2 Second bit line GND Ground line T1 First terminal T2 Second terminal T3 Third terminal Tr1 First transistor Tr2 Second transistor WL Word line