LIQUID-CRYSTALLINE MEDIUM
20170362506 · 2017-12-21
Assignee
Inventors
Cpc classification
C09K2019/3027
CHEMISTRY; METALLURGY
C09K2019/3425
CHEMISTRY; METALLURGY
C09K2019/0448
CHEMISTRY; METALLURGY
C09K19/32
CHEMISTRY; METALLURGY
C09K19/44
CHEMISTRY; METALLURGY
C09K19/3003
CHEMISTRY; METALLURGY
C09K2019/3408
CHEMISTRY; METALLURGY
C09K19/3098
CHEMISTRY; METALLURGY
C09K19/12
CHEMISTRY; METALLURGY
C09K19/3405
CHEMISTRY; METALLURGY
International classification
C09K19/30
CHEMISTRY; METALLURGY
C09K19/12
CHEMISTRY; METALLURGY
C09K19/44
CHEMISTRY; METALLURGY
C09K19/32
CHEMISTRY; METALLURGY
Abstract
Liquid-crystalline medium contains at least one compound of formula I,
##STR00001##
and at least one compound formulae ST-1 to ST-17 and the use thereof for an active-matrix display, in particular based on the VA, PSA, PA-VA, SS-VA, SA-VA, PS-VA, PALC, IPS, PS-IPS, UB-FFS, U-IPS, FFS or PS-FFS effect.
Claims
1. Liquid-crystalline medium, characterised in that it comprises at least one compound of the formula I, ##STR00523## in which R.sup.1 and R.sup.1* each, independently of one another, denote H, an alkyl or alkoxy radical having 1 to 15 C atoms, where, in addition, one or more CH.sub.2 groups in these radicals may each be replaced, independently of one another, by —C≡C—, —CF.sub.2O—, —OCF.sub.2—, —CH═CH—, ##STR00524## —O—, —CO—O—, —O—CO— in such a way that O atoms are not linked directly to one another, and in which, in addition, one or more H atoms may be replaced by halogen, A.sup.1 and A1* each, independently of one another, denote a) a 1,4-cyclohexenylene or 1,4-cyclohexylene radical, in which one or two non-adjacent CH.sub.2 groups may be replaced by —O— or —S—, b) a 1,4-phenylene radical, in which one or two CH groups may be replaced by N, c) a radical from the group piperidine-1,4-diyl, 1,4-bicyclo-[2.2.2]octylene, naphthalene-2,6-diyl, decahydronaphthalene-2,6-diyl, 1,2,3,4-tetrahydronaphthalene-2,6-diyl, phenanthrene-2,7-diyl and fluorene-2,7-diyl, where the radicals a), b) and c) may be mono- or polysubstituted by halogen atoms, Z.sup.1 and Z.sup.1* each, independently of one another, denote —CO—O—, —O—CO—, —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —OCH.sub.2—, —CH.sub.2—, —CH.sub.2CH.sub.2—, —(CH.sub.2).sub.4—, —CH═CH—CH.sub.2O—, —C.sub.2F.sub.4—, —CH.sub.2CF.sub.2—, —CF.sub.2CH.sub.2—, —CF═CF—, —CH═CF—, —CF═CH—, —CH═CH—, —C≡C— or a single bond, X denotes —S— or —O—, and L.sup.1 and L.sup.2 each, independently of one another, denote F, Cl, CF.sub.3 or CHF.sub.2, and at least one compound selected from the group of the compounds of the formulae ST, ##STR00525## ##STR00526## ##STR00527## in which R.sup.ST denotes H, an alkyl or alkoxy radical having 1 to 15 C atoms, where, in addition, one or more CH.sub.2 groups in these radicals may each be replaced, independently of one another, by —C≡C—, —CF.sub.2O—, —OCF.sub.2—, —CH═CH—, ##STR00528## —O—, —CO—O—, —O—CO— in such a way that O atoms are not linked directly to one another, and in which, in addition, one or more H atoms may be replaced by halogen, ##STR00529## ##STR00530## ##STR00531## Z.sup.ST each, independently of one another, denotes —CO—O—, —O—CO—, —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —OCH.sub.2—, —CH.sub.2—, —CH.sub.2CH.sub.2—, —(CH.sub.2).sub.4—, —CH═CH—CH.sub.2O—, —C.sub.2F.sub.4—, —CH.sub.2CF.sub.2—, —CF.sub.2CH.sub.2—, —CF═CF—, —CH═CF—, —CF═CH—, —CH═CH—, —C≡C— or a single bond, L.sup.1 and L.sup.2 each, independently of one another, denote F, Cl, CF.sub.3 or CHF.sub.2, p denotes 1 or 2, q denotes 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10.
2. Liquid-crystalline medium according to claim 1, characterised in that the medium comprises at least one compound of the formulae I-1 to I-20, ##STR00532## ##STR00533## in which alkyl and alkyl* each, independently of one another, denote a straight-chain alkyl radical having 1-6 C atoms, alkenyl and alkenyl* each, independently of one another, denote a straight-chain alkenyl radical having 2-6 C atoms, alkoxy and alkoxy* each, independently of one another, denote a straight-chain alkoxy radical having 1-6 C atoms, and L.sup.1 and L.sup.2 each, independently of one another, denote F, Cl, CF.sub.3 or CHF.sub.2.
3. Liquid-crystalline medium according to claim 1, characterised in that L.sup.1 and L.sup.2 in the formula I each denote F.
4. Liquid-crystalline medium according to claim 1, characterised in that it comprises one or more compounds selected from the group of the compounds of the formulae ST-1, ST-2a, ST-3a, ST-3b, ST-8-1, ST-9-1, ST-12, ST-15, ST-16 ##STR00534## ##STR00535## where n=1, 2, 3, 4, 5, 6 or 7.
5. Liquid-crystalline medium according to claim 1, characterised in that it additionally comprises one or more compounds selected from the group of the compounds of the formulae IIA, IIB and IIC, ##STR00536## in which R.sup.2A, R.sup.2B and R.sup.2C each, independently of one another, denote H, an alkyl or alkenyl radical having up to 15 C atoms which is un-substituted, monosubstituted by CN or CF.sub.3 or at least monosubstituted by halogen, where, in addition, one or more CH.sub.2 groups in these radicals may be replaced by —O—, —S—, ##STR00537## —C≡C—, —CF.sub.2O—, —OCF.sub.2—, —OC—O— or —O—CO— in such a way that O atoms are not linked directly to one another, L.sup.1-4 each, independently of one another, denote F or Cl, Z.sup.2 and Z.sup.2′ each, independently of one another, denote a single bond, —CH.sub.2CH.sub.2—, —CH═CH—, —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —O CH.sub.2—, —COO—, —OCO—, —C.sub.2F.sub.4—, —CF═CF—, —CH═CHCH.sub.2O—, p denotes 0, 1 or 2, q denotes 0 or 1, and v denotes 1 to 6.
6. Liquid-crystalline medium according to claim 1, characterised in that the medium additionally comprises one or more compounds of the formula III, ##STR00538## in which R.sup.31 and R.sup.32 each, independently of one another, denote a straight-chain alkyl, alkoxyalkyl or alkoxy radical having up to 12 C atoms, and ##STR00539## Z.sup.3 denotes a single bond, —CH.sub.2CH.sub.2—, —CH═CH—, —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —OCH.sub.2—, —COO—, —OCO—, —C.sub.2F.sub.4—, —C.sub.4H.sub.9—, —CF═CF—.
7. Liquid-crystalline medium according to claim 1, characterised in that the medium additionally comprises one or more compounds of the formulae L-1 to L-11, ##STR00540## in which R, R.sup.1 and R.sup.2 each, independently of one another, denote H, an alkyl or alkenyl radical having up to 15 C atoms which is unsubstituted, monosubstituted by CN or CF.sub.3 or at least monosubstituted by halogen, where, in addition, one or more CH.sub.2 groups in these radicals may be replaced by —O—, —S—, ##STR00541## —C≡C—, —CF.sub.2O—, —OCF.sub.2—, —OC—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and alkyl denotes an alkyl radical having 1-6 C atoms, and s denotes 1 or 2.
8. Liquid-crystalline medium according to claim 1, characterised in that the medium additionally comprises one or more terphenyls of the formulae T-1 to T-21, ##STR00542## ##STR00543## in which R denotes a straight-chain alkyl or alkoxy radical having 1-6 C atoms, and m denotes 1-6.
9. Liquid-crystalline medium according to claim 1, characterised in that the medium additionally comprises one or more compounds of the formulae O-1 to O-18, ##STR00544## ##STR00545## in which R.sup.1 and R.sup.2 each, independently of one another, denote H, an alkyl or alkenyl radical having up to 15 C atoms which is unsubstituted, monosubstituted by CN or CF.sub.3 or at least monosubstituted by halogen, where, in addition, one or more CH.sub.2 groups in these radicals may be replaced by —O—, —S—, ##STR00546## —C≡C—, —CF.sub.2O—, —OCF.sub.2—, —OC—O— or —O—CO— in such a way that O atoms are not linked directly to one another.
10. Liquid-crystalline medium according to claim 1, characterised in that the medium additionally comprises one or more compounds selected from the group of the compounds of the formulae O-6, O-7 and O-17, ##STR00547## in which R.sup.1 denotes alkyl or alkenyl having 1-6 or 2-6 C atoms respectively and R.sup.2 denotes alkenyl having 2-6 C atoms.
11. Liquid-crystalline medium according to claim 1, characterised in that the medium additionally comprises one or more indane compounds of the formula In, ##STR00548## in which R.sup.11, R.sup.12, R.sup.13 denote a straight-chain alkyl, alkoxy, alkoxyalkyl or alkenyl radical having 1-5 C atoms, R.sup.12 and R.sup.13 additionally also denote halogen, ##STR00549## i denotes 0, 1 or 2.
12. Liquid-crystalline medium according to claim 1, characterised in that the medium additionally comprises one or more compounds of the formulae BF-1 and BF-2, ##STR00550## in which R.sup.1 and R.sup.2 each, independently of one another, denote H, an alkyl or alkenyl radical having up to 15 C atoms which is unsubstituted, monosubstituted by CN or CF.sub.3 or at least monosubstituted by halogen, where, in addition, one or more CH.sub.2 groups in these radicals may be replaced by —O—, —S—, ##STR00551## —C≡C—, —CF.sub.2O—, —OCF.sub.2—, —OC—O— or —O—CO— in such a way that O atoms are not linked directly to one another, c denotes 0, 1 or 2 and d denotes 1 or 2.
13. Liquid-crystalline medium according to claim 1, characterised in that the proportion of compounds of the formula I in the mixture as a whole is 1-40% by weight.
14. Liquid-crystalline medium according to claim 1, characterised in that the medium comprises at least one polymerisable compound.
15. Liquid-crystalline medium according to claim 1, characterised in that the medium comprises one or more additives.
16. Liquid-crystalline medium according to claim 1, characterised in that the additive is selected from the group free-radical scavenger, antioxidant and/or UV stabiliser.
17. Process for the preparation of a liquid-crystalline medium according to claim 1, characterised in that at least one compound of the formula I is mixed with at least one further liquid-crystalline compound, and optionally one or more additives and optionally at least one polymerisable compound are added.
18. Use of the liquid-crystalline medium according to claim 1 in electro-optical displays.
19. Electro-optical display having active-matrix addressing, characterised in that it contains, as dielectric, a liquid-crystalline medium according to claim 1.
20. Electro-optical display according to claim 19, characterised in that it is a VA, PSA, PA-VA, SS-VA, SA-VA, PS-VA, PALC, IPS, PS-IPS, FFS, UB-FFS, U-IPS or PS-FFS display.
Description
WORKING EXAMPLES
[0298] The following examples are intended to explain the invention without limiting it. In the examples, m.p. denotes the melting point and C denotes the clearing point of a liquid-crystalline substance in degrees Celsius; boiling temperatures are denoted by m.p. Furthermore: C denotes crystalline solid state, S denotes smectic phase (the index denotes the phase type), N denotes nematic state, Ch denotes cholesteric phase, I denotes isotropic phase, T.sub.g denotes glass-transition temperature. The number between two symbols indicates the conversion temperature in degrees Celsius an.
[0299] The host mixture used for determination of the optical anisotropy Δn of the compounds of the formula I is the commercial mixture ZLI-4792 (Merck KGaA). The dielectric anisotropy Ac is determined using commercial mixture ZLI-2857. The physical data of the compound to be investigated are obtained from the change in the dielectric constants of the host mixture after addition of the compound to be investigated and extrapolation to 100% of the compound employed. In general, 10% of the compound to be investigated are dissolved in the host mixture, depending on the solubility.
[0300] Unless indicated otherwise, parts or per cent data denote parts by weight or per cent by weight.
[0301] Above and below: [0302] V.sub.o denotes threshold voltage, capacitive [V] at 20° C., [0303] n.sub.e denotes extraordinary refractive index at 20° C. and 589 nm, [0304] n.sub.o denotes ordinary refractive index at 20° C. and 589 nm, [0305] Δn denotes optical anisotropy at 20° C. and 589 nm, [0306] ε.sub.⊥ denotes dielectric permittivity perpendicular to the director at 20° C. and 1 kHz, [0307] ε| denotes dielectric permittivity parallel to the director at 20° C. and 1 kHz, [0308] Δε denotes dielectric anisotropy at 20° C. and 1 kHz, [0309] cl.p., T(N,I) denotes clearing point [° C], [0310] γ.sub.1 denotes rotational viscosity measured at 20° C. [mPa.Math.s], determined by the rotation method in a magnetic field, [0311] K.sub.1 denotes elastic constant, “splay” deformation at 20° C. [pN], [0312] K.sub.2 denotes elastic constant, “twist” deformation at 20° C. [pN], [0313] K.sub.3 denotes elastic constant, “bend” deformation at 20° C. [pN], [0314] LTS denotes low-temperature stability (nematic phase), determined in test cells.
[0315] Unless explicitly noted otherwise, all values indicated in the present application for temperatures, such as, for example, the melting point T(C,N), the transition from the smectic (S) to the nematic (N) phase T(S,N) and the clearing point T(N,I), are indicated in degrees Celsius (° C.). M.p. denotes melting point, cl.p.=clearing point. Furthermore, Tg=glass state, C=crystalline state, N=nematic phase, S=smectic phase and I=isotropic phase. The numbers between these symbols represent the transition temperatures.
[0316] The term “threshold voltage” for the present invention relates to the capacitive threshold (V.sub.0), also called the Freedericksz threshold, unless explicitly indicated otherwise. In the examples, as is generally usual, the optical threshold can also be indicated for 10% relative contrast (V.sub.10).
[0317] The display used for measurement of the capacitive threshold voltage consists of two plane-parallel glass outer plates at a separation of 20 μm, which each have on the insides an electrode layer and an unrubbed polyimide alignment layer on top, which cause a homeotropic edge alignment of the liquid-crystal molecules.
[0318] The display or test cell used for measurement of the tilt angle consists of two plane-parallel glass outer plates at a separation of 4 μm, which each have on the insides an electrode layer and a polyimide alignment layer on top, where the two polyimide layers are rubbed antiparallel to one another and cause a homeotropic edge alignment of the liquid-crystal molecules.
[0319] The polymerisable compounds are polymerised in the display or test cell by irradiation with UVA light (usually 365 nm) of a defined intensity for a pre-specified time, with a voltage simultaneously being applied to the display (usually 10 V to 30 V alternating current, 1 kHz). In the examples, unless indicated otherwise, a 50 mW/cm.sup.2 mercury vapour lamp is used, and the intensity is measured using a standard UV meter (make Ushio UNI meter) fitted with a 365 nm band-pass filter.
[0320] The tilt angle is determined by a rotational crystal experiment (Autronic-Melchers TBA-105). A low value (i.e. a large deviation from the 90° angle) corresponds to a large tilt here.
[0321] The VHR value is measured as follows: 0.3% of a polymerisable monomeric compound are added to the LC host mixture, and the resultant mixture is introduced into TN-VHR test cells (rubbed at 90°, alignment layer TN polyimide, layer thickness d≈6 μm). The HR value is determined after 5 min at 100° C. before and after UV exposure for 2 h (sun test) at 1 V, 60 Hz, 64 μs pulse (measuring instrument: Autronic-Melchers VHRM-105).
[0322] In order to investigate the low-temperature stability, also known as “LTS”, i.e. the stability of the LC mixture to spontaneous crystallisation-out of individual components at low temperatures, bottles containing 1 g of LC/RM mixture are stored at −10° C., and it is regularly checked whether the mixtures have crystallised out.
[0323] The so-called “HTP” denotes the helical twisting power of an optically active or chiral substance in an LC medium (in μm). Unless indicated otherwise, the HTP is measured in the commercially available nematic LC host mixture MLD-6260 (Merck KGaA) at a temperature of 20° C.
[0324] Unless explicitly noted otherwise, all concentrations in the present application are indicated in per cent by weight and relate to the corresponding mixture as a whole, comprising all solid or liquid-crystalline components, without solvents. All physical properties are determined in accordance with “Merck Liquid Crystals, Physical Properties of Liquid Crystals”, Status November 1997, Merck KGaA, Germany, and apply for a temperature of 20° C., unless explicitly indicated otherwise.
[0325] The following mixture examples having negative dielectric anisotropy are suitable, in particular, for liquid-crystal displays which have at least one planar alignment layer, such as, for example, IPS and FFS displays, in particular UB-FFS=ultra-bright FFS), and for VA displays.
MIXTURE EXAMPLES
Example M1
[0326] The liquid-crystalline mixture
TABLE-US-00008 CC-3-V 43.00% Clearing point [° C.]: 74.5 CCY-3-O1 4.00% Δn [589 nm, 20° C.]: 0.1008 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.4 CCY-4-O2 2.50% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 13.1 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.7 CY-3-O2 6.50% γ.sub.1 [mPa .Math. s, 20° C.]: 82 PY-3-O2 11.00% V.sub.0 [20° C., V]: 2.19 B(S)—2O—O5 3.00%
[0327] additionally comprises 0.01% of ST-3a-1.
Example M2
[0328] The liquid-crystalline mixture
TABLE-US-00009 CC-3-V 5.00% Clearing point [° C.]: 75.5 CC-3-V1 8.00% Δn [589 nm, 20° C.]: 0.1082 CCH-23 11.50% Δε [1 kHz, 20° C.]: −3.3 CCH-34 5.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCP-3-1 10.00% K.sub.1 [pN, 20° C.]: 15.2 CCP-3-3 5.00% K.sub.3 [pN, 20° C.]: 16.0 CCY-3-O1 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 104 CCY-3-O2 11.50% V.sub.0 [20° C., V]: 2.31 CY-3-O2 14.50% PY-3-O2 8.00% PYP-2-3 8.00% B—2O—O5 3.50% B(S)—2O—O5 3.50% PP-1-2V1 2.50%
[0329] additionally comprises 0.02% of ST-8-1.
Example M3
[0330] The liquid-crystalline mixture
TABLE-US-00010 CC-3-V1 8.00% Clearing point [° C.]: 74.0 CCH-23 18.00% Δn [589 nm, 20° C.]: 0.0979 CCH-34 3.00% Δε [1 kHz, 20° C.]: −3.4 CCH-35 4.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCP-3-1 14.00% K.sub.1 [pN, 20° C.]: 15.0 CCY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 16.0 CCY-3-O1 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 100 CPY-3-O2 11.00% V.sub.0 [20° C., V]: 2.28 CY-3-O2 10.00% PY-3-O2 12.00% Y—4O—O4 4.00% B(S)—2O—O5 3.00%
[0331] additionally comprises 0.02% of ST-12.
Example M4
[0332] The liquid-crystalline mixture
TABLE-US-00011 CC-3-V 46.00% Clearing point [° C.]: 72.5 CCY-3-O2 11.00% Δn [589 nm, 20° C.]: 0.1009 CCY-4-O2 2.50% Δε [1 kHz, 20° C.]: −3.5 CPY-2-O2 10.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 13.1 CY-3-O2 5.00% K.sub.3 [pN, 20° C.]: 14.2 PY-3-O2 8.50% γ.sub.1 [mPa .Math. s, 20° C.]: 78 B—2O—O5 4.00% V.sub.0 [20° C., V]: 2.13 B(S)—2O—O5 3.00%
[0333] additionally comprises 0.02% of ST-8-1 and 0.01% of ST-3a-1.
Example M5
[0334] The liquid-crystalline mixture
TABLE-US-00012 CC-3-V 41.50% Clearing point [° C.]: 75.0 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1016 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −3.4 CCY-4-O2 4.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CPY-2-O2 5.50% K.sub.1 [pN, 20° C.]: 13.3 CPY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 14.8 CY-3-O2 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 88 PY-3-O2 12.00% V.sub.0 [20° C., V]: 2.20 B(S)-5-O3 5.00%
[0335] additionally comprises 0.02% of ST-3a-1.
Example M6
[0336] The liquid-crystalline mixture
TABLE-US-00013 CC-3-V 37.00% Clearing point [° C.]: 79.0 CY-3-O2 8.50% Δn [589 nm, 20° C.]: 0.1062 CCY-3-O1 6.00% Δε [1 kHz, 20° C.]: −3.9 CCY-3-O2 10.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCY-4-O2 7.00% K.sub.1 [pN, 20° C.]: 13.8 CPY-2-O2 3.50% K.sub.3 [pN, 20° C.]: 15.5 CPY-3-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 101 PYP-2-3 4.50% V.sub.0 [20° C., V]: 2.12 PY-3-O2 9.50% B(S)—2O—O5 4.00%
[0337] additionally comprises 0.025% of ST-3a-1.
Example M7
[0338] The liquid-crystalline mixture
TABLE-US-00014 CC-3-V 41.00% Clearing point [° C.]: 81.0 CY-3-O2 7.00% Δn [589 nm, 20° C.]: 0.1074 CCY-3-O1 6.00% Δε [1 kHz, 20° C.]: −3.8 CCY-3-O2 10.50% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 14.0 CPY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 15.5 PYP-2-3 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 97 PY-3-O2 3.50% V.sub.0 [20° C., V]: 2.13 B—2O—O5 4.00% B(S)—2O—O5 3.00%
[0339] additionally comprises 0.025% of ST-3a-1.
Example M8
[0340] The liquid-crystalline mixture
TABLE-US-00015 CY-3-O2 11.00% Clearing point [° C.]: 86.0 CY-3-O4 7.00% Δn [589 nm, 20° C.]: 0.1020 PY-3-O2 3.00% Δε [1 kHz, 20° C.]: −4.9 CCY-3-O1 7.50% ε.sub.|| [1 kHz, 20° C.]: 3.8 CCY-3-O2 11.00% K.sub.1 [pN, 20° C.]: 14.4 CCY-4-O2 10.00% K.sub.3 [pN, 20° C.]: 16.5 CPY-2-O2 6.50% γ.sub.1 [mPa .Math. s, 20° C.]: 138 CPY-3-O2 11.00% V.sub.0 [20° C., V]: 1.94 CC-3-V 29.00% B(S)-2O-O5 4.00%
[0341] additionally comprises 0.025% of ST-3a-1.
Example M9
[0342] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.7% of the mixture according to Example M1 are mixed with 0.3% of the polymerisable compound of the formula
##STR00439##
Example M10
[0343] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M1 are mixed with 0.25% of the polymerisable compound of the formula
##STR00440##
Example M11
[0344] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.8% of the mixture according to Example M2 are mixed with 0.2% of the polymerisable compound of the formula
##STR00441##
Example M12
[0345] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M4 are mixed with 0.25% of the polymerisable compound of the formula
##STR00442##
Example M13
[0346] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M4 are mixed with 0.25% of the polymerisable compound of the formula
##STR00443##
Example M14
[0347] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M1 are mixed with 0.25% of the polymerisable compound of the formula
##STR00444##
Example M15
[0348] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.8% of the mixture according to Example M1 are mixed with 0.2% of the polymerisable compound of the formula
##STR00445##
Example M16
[0349] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M5 are mixed with 0.25% of the polymerisable compound of the formula
##STR00446##
Example M17
[0350] The liquid-crystalline mixture
TABLE-US-00016 CC-3-V1 8.00% Clearing point [° C.]: 75.0 CCH-23 13.50% Δn [589 nm, 20° C.]: 0.1085 CCH-34 6.00% Δε [1 kHz, 20° C.]: −3.4 CCP-3-1 12.00% ε.sub.|| [1 kHz, 20° C.]: 3.5 CCP-3-3 7.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.9 CCY-3-O2 8.50% K.sub.1 [pN, 20° C.]: 15.5 CY-3-O2 20.50% K.sub.3 [pN, 20° C.]: 16.0 PY-3-O2 3.50% γ.sub.1 [mPa .Math. s, 20° C.]: 102 PYP-2-3 8.00% V.sub.0 [20° C., V]: 2.31 B(S)-2O-O5 4.00% B(S)-2O-O4 3.00% B(S)-2O-O6 3.00% PP-1-2V1 3.00%
[0351] additionally comprises 0.025% of ST-3a-1.
Example M18
[0352] The liquid-crystalline mixture
TABLE-US-00017 CC-3-V1 8.00% Clearing point [° C.]: 74.5 CCH-23 14.50% Δn [589 nm, 20° C.]: 0.1081 CCH-34 6.00% Δε [1 kHz, 20° C.]: −3.3 CCP-3-1 12.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCP-3-3 7.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.9 CCY-3-O2 9.00% K.sub.1 [pN, 20° C.]: 15.3 CY-3-O2 18.50% K.sub.3 [pN, 20° C.]: 15.8 PY-3-O2 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 101 PYP-2-3 8.00% V.sub.0 [20° C., V]: 2.31 B-2O-O5 3.00% B(S)-2O-O5 3.00% B(S)-2O-O4 2.00% B(S)-2O-O6 2.00% PP-1-2V1 3.00%
[0353] additionally comprises 0.03% of ST-8-1.
Example M19
[0354] The liquid-crystalline mixture
TABLE-US-00018 CC-3-V1 8.00% Clearing point [° C.]: 72.5 CCH-23 11.50% Δn [589 nm, 20° C.]: 0.1082 CCH-34 5.00% Δε [1 kHz, 20° C.]: −3.3 CCP-3-1 14.50% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCP-3-3 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CCY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 15.3 CY-3-O2 14.00% K.sub.3 [pN, 20° C.]: 15.7 PY-3-O2 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 105 PGIY-2-O4 3.50% V.sub.0 [20° C., V]: 2.28 B-2O-O5 4.00% LTS [bulk, −20° C.]: >1000 h B(S)-2O-O5 3.50% B-3-O2 4.00% PP-1-3 5.00%
[0355] additionally comprises 0.03% of ST-12.
Example M20
[0356] The liquid-crystalline mixture
TABLE-US-00019 CC-3-V 36.50% Clearing point [° C.]: 74.0 CC-3-V1 7.00% Δn [589 nm, 20° C.]: 0.1088 CCY-3-O1 7.50% Δε [1 kHz, 20° C.]: −3.6 CCY-3-O2 11.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-4-O2 1.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CLY-3-O2 5.00% K.sub.1 [pN, 20° C.]: 14.4 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 15.0 PY-3-O2 12.00% γ.sub.1 [mPa .Math. s, 20° C.]: 85 PY-1-O4 4.00% V.sub.0 [20° C., V]: 2.15 PYP-2-3 3.00% LTS [bulk, −20° C.]: >1000 h PP-1-2V1 0.50% B(S)-2O-O5 4.00% B(S)-2O-O4 3.00%
[0357] additionally comprises 0.03% of ST-12.
Example M21
[0358] The liquid-crystalline mixture
TABLE-US-00020 CC-3-V 36.50% Clearing point [° C.]: 75.0 CC-3-V1 7.00% Δn [589 nm, 20° C.]: 0.1088 CCY-3-O1 7.50% Δε [1 kHz, 20° C.]: −3.7 CCY-3-O2 11.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-4-O2 2.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CLY-3-O2 5.00% K.sub.1 [pN, 20° C.]: 14.7 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 15.2 PY-3-O2 12.00% γ.sub.1 [mPa .Math. s, 20° C.]: 86 PY-1-O4 1.00% V.sub.0 [20° C., V]: 2.15 PYP-2-3 3.00% PP-1-2V1 1.50% B-2O-O5 4.00% B(S)-2O-O4 4.00%
[0359] additionally comprises 0.03% of ST-12.
Example M22
[0360] The liquid-crystalline mixture
TABLE-US-00021 CC-3-V 36.50% Clearing point [° C.]: 75.0 CC-3-V1 7.00% Δn [589 nm, 20° C.]: 0.1083 CCY-3-O1 7.50% Δε [1 kHz, 20° C.]: −3.6 CCY-3-O2 11.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-4-O2 2.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CLY-3-O2 5.00% K.sub.1 [pN, 20° C.]: 14.5 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 15.2 PY-3-O2 12.00% γ.sub.1 [mPa .Math. s, 20° C.]: 86 PY-1-O4 1.00% V.sub.0 [20° C., V]: 2.16 PYP-2-3 3.00% PP-1-2V1 1.50% B-2O-O5 4.00% B(S)-2O-O5 4.00%
[0361] additionally comprises 0.015% of ST-8-1.
Example M23
[0362] The liquid-crystalline mixture
TABLE-US-00022 CC-3-V 41.50% Clearing point [° C.]: 75.0 CC-3-V1 7.00% Δn [589 nm, 20° C.]: 0.0985 CCY-3-O1 8.00% Δε [1 kHz, 20° C.]: −3.2 CCY-3-O2 11.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCY-4-O2 4.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.8 CY-3-O2 3.50% K.sub.1 [pN, 20° C.]: 13.8 PY-3-O2 14.50% K.sub.3 [pN, 20° C.]: 15.0 B(S)-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 80 PGIY-2-O4 5.00% V.sub.0 [20° C., V]: 2.29 LTS [bulk, −25° C.]: >1000 h
[0363] additionally comprises 0.015% of ST-9-1.
Example M24
[0364] The liquid-crystalline mixture
TABLE-US-00023 CC-3-V1 8.00% Clearing point [° C.]: 74.0 CCH-23 18.00% Δn [589 nm, 20° C.]: 0.0979 CCH-34 3.00% Δε [1 kHz, 20° C.]: −3.4 CCH-35 4.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCP-3-1 14.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CCY-3-O2 11.00% K.sub.1 [pN, 20° C.]: 15.0 CCY-3-O1 2.00% K.sub.3 [pN, 20° C.]: 16.0 CPY-3-O2 11.00% γ.sub.1 [mPa .Math. s, 20° C.]: 100 CY-3-O2 10.00% V.sub.0 [20° C., V]: 2.28 PY-3-O2 12.00% Y-4O-O4 4.00% B(S)-2O-O5 3.00%
[0365] additionally comprises 0.03% of ST-2a-1.
Example M25
[0366] The liquid-crystalline mixture
TABLE-US-00024 CC-3-V1 8.50% Clearing point [° C.]: 74.5 CCH-23 18.00% Δn [589 nm, 20° C.]: 0.0986 CCH-35 5.50% Δε [1 kHz, 20° C.]: −3.4 CCP-3-1 13.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCY-3-O1 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.9 CCY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 15.3 CPY-3-O2 10.50% K.sub.3 [pN, 20° C.]: 15.8 CY-3-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 95 Y-4O-O4 6.00% V.sub.0 [20° C., V]: 2.30 B(S)-2O-O5 4.00% PP-1-3 6.40% B(S)-2O-O4 3.00%
[0367] additionally comprises 0.03% of ST-2a-1 and 0.02% of ST-3a-1.
Example M26
[0368] The liquid-crystalline mixture
TABLE-US-00025 CC-3-V1 8.00% Clearing point [° C.]: 73.5 CCH-23 18.00% Δn [589 nm, 20° C.]: 0.0979 CCH-35 5.00% Δε [1 kHz, 20° C.]: −3.3 CCH-34 1.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCP-3-1 13.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.9 CCY-3-O1 5.00% K.sub.1 [pN, 20° C.]: 15.2 CCY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 15.7 CPY-3-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 95 CY-3-O2 11.00% V.sub.0 [20° C., V]: 2.30 Y-4O-O4 5.50% B(S)-2O-O5 3.00% PP-1-3 6.50% B(S)-2O-O4 2.00% B(S)-2O-O6 2.00%
[0369] additionally comprises 0.01% of ST-3b-1.
Example M27
[0370] The liquid-crystalline mixture
TABLE-US-00026 CC-3-V 42.00% Clearing point [° C.]: 74.0 CCY-3-O2 11.00% Δn [589 nm, 20° C.]: 0.1008 CPY-2-O2 10.00% Δε [1 kHz, 20° C.]: −3.7 CPY-3-O2 11.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CY-3-O3 17.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 PGIY-2-O4 5.00% K.sub.1 [pN, 20° C.]: 12.8 B(S)-2O-O5 4.00% K.sub.3 [pN, 20° C.]: 14.6 γ.sub.1 [mPa .Math. s, 20° C.]: 86 V.sub.0 [20° C., V]: 2.11
[0371] additionally comprises 0.02% of ST-8-1.
Example M28
[0372] The liquid-crystalline mixture
TABLE-US-00027 CC-3-V 42.00% Clearing point [° C.]: 73.0 CCY-3-O2 11.00% Δn [589 nm, 20° C.]: 0.1004 CPY-2-O2 9.00% Δε [1 kHz, 20° C.]: −3.7 CPY-3-O2 11.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 PGIY-2-O4 5.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CY-3-O2 17.50% K.sub.1 [pN, 20° C.]: 12.7 B(S)-2O-O5 2.00% K.sub.3 [pN, 20° C.]: 14.5 B(S)-2O-O4 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 85 V.sub.0 [20° C., V]: 2.10
[0373] additionally comprises 0.02% of ST-8-1.
Example M29
[0374] The liquid-crystalline mixture
TABLE-US-00028 CC-3-V 44.50% Clearing point [° C.]: 74.0 CCY-3-O2 11.00% Δn [589 nm, 20° C.]: 0.1010 CPY-2-O2 9.50% Δε [1 kHz, 20° C.]: −3.7 CPY-3-O2 11.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CY-3-O2 13.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 PGIY-2-O4 4.00% K.sub.1 [pN, 20° C.]: 13.0 B-2O-O5 4.00% K.sub.3 [pN, 20° C.]: 14.5 B-2O-O4 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 83 V.sub.0 [20° C., V]: 2.09
[0375] additionally comprises 0.02% of ST-8-1.
Example M30
[0376] The liquid-crystalline mixture
TABLE-US-00029 CC-3-V 42.00% Clearing point [° C.]: 80.5 CY-3-O2 11.50% Δn [589 nm, 20° C.]: 0.1070 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.7 CCY-4-O2 4.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-2-O2 6.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CPY-3-O2 11.00% K.sub.1 [pN, 20° C.]: 13.9 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 15.2 PYP-2-3 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 94 B(S)-2O-O5 4.00% V.sub.0 [20° C., V]: 2.14 B(S)-2O-O4 3.00%
[0377] additionally comprises 0.02% of ST-8-1.
Example M31
[0378] The liquid-crystalline mixture
TABLE-US-00030 CC-3-V 32.50% Clearing point [° C.]: 80.5 CCP-3-1 6.50% Δn [589 nm, 20° C.]: 0.1031 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −4.4 CLY-3-O2 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.8 CLY-3-O3 4.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.2 CPY-3-O2 9.50% K.sub.1 [pN, 20° C.]: 14.4 CY-3-O2 21.50% K.sub.3 [pN, 20° C.]: 16.6 PGIY-2-O4 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 109 B(S)-2O-O5 3.00% V.sub.0 [20° C., V]: 2.05 B(S)-2O-O4 4.00%
[0379] additionally comprises 0.02% of ST-12.
Example M32
[0380] The liquid-crystalline mixture
TABLE-US-00031 CC-3-V 32.00% Clearing point [° C.]: 81.0 CCP-3-1 8.00% Δn [589 nm, 20° C.]: 0.1031 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −4.5 CLY-3-O2 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.8 CLY-3-O3 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.2 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.8 CY-3-O2 21.00% K.sub.3 [pN, 20° C.]: 16.9 PGIY-2-O4 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 110 B-2O-O5 2.00% V.sub.0 [20° C., V]: 2.05 B(S)-2O-O5 2.00% B(S)-2O-O4 2.00% B(S)-2O-O6 2.00%
[0381] additionally comprises 0.02% of ST-8-1.
Example M33
[0382] The liquid-crystalline mixture
TABLE-US-00032 CC-3-V 33.00% Clearing point [° C.]: 80.5 CCP-3-1 6.00% Δn [589 nm, 20° C.]: 0.1031 CCY-3-O2 10.50% Δε [1 kHz, 20° C.]: −4.5 CLY-3-O2 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.8 CLY-3-O3 4.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.2 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.3 CY-3-O2 20.50% K.sub.3 [pN, 20° C.]: 16.6 PGIY-2-O4 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 109 B-2O-O5 2.00% V.sub.0 [20° C., V]: 2.04 B(S)-2O-O5 2.00% B(S)-2O-O4 3.00%
[0383] additionally comprises 0.02% of ST-9-1 and 0.02% of ST-3b-1.
Example M34
[0384] The liquid-crystalline mixture
TABLE-US-00033 CC-3-V 33.00% Clearing point [° C.]: 80.0 CCP-3-1 6.50% Δn [589 nm, 20° C.]: 0.1030 CCY-3-O2 10.50% Δε [1 kHz, 20° C.]: −4.4 CLY-3-O2 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.8 CLY-3-O3 3.50% ε.sub.⊥ [1 kHz, 20° C.]: 8.2 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.3 CY-3-O2 20.50% K.sub.3 [pN, 20° C.]: 16.6 PGIY-2-O4 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 108 B-2O-O5 3.00% V.sub.0 [20° C., V]: 2.04 B(S)-2O-O4 4.00%
[0385] additionally comprises 0.01% of ST-9-1.
Example M35
[0386] The liquid-crystalline mixture
TABLE-US-00034 CC-3-V 38.50% Clearing point [° C.]: 79.5 CCY-3-O1 4.00% Δn [589 nm, 20° C.]: 0.1034 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −4.4 CLY-3-O2 7.00% ε.sub.|| [1 kHz, 20° C.]: 3.8 CLY-3-O3 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.2 CPY-2-O2 4.00% K.sub.1 [pN, 20° C.]: 14.4 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 15.9 CY-3-O2 9.50% γ.sub.1 [mPa .Math. s, 20° C.]: 102 PY-3-O2 6.00% V.sub.0 [20° C., V]: 2.01 B(S)-2O-O5 4.00% B-2O-O5 4.00%
[0387] additionally comprises 0.01% of ST-8-1.
Example M36
[0388] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.7% of the mixture according to Example M17 are mixed with 0.3% of the polymerisable compound of the formula
##STR00447##
Example M37
[0389] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M17 are mixed with 0.25% of the polymerisable compound of the formula
##STR00448##
Example M38
[0390] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.8% of the mixture according to Example M17 are mixed with 0.2% of the polymerisable compound of the formula
##STR00449##
Example M39
[0391] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M17 are mixed with 0.25% of the polymerisable compound of the formula
##STR00450##
Example M40
[0392] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M17 are mixed with 0.25% of the polymerisable compound of the formula
##STR00451##
Example M41
[0393] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M17 are mixed with 0.25% of the polymerisable compound of the formula
##STR00452##
Example M42
[0394] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.8% of the mixture according to Example M17 are mixed with 0.2% of the polymerisable compound of the formula
##STR00453##
Example M43
[0395] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.7% of the mixture according to Example M19 are mixed with 0.3% of the polymerisable compound of the formula
##STR00454##
Example M44
[0396] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M19 are mixed with 0.25% of the polymerisable compound of the formula
##STR00455##
Example M45
[0397] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.8% of the mixture according to Example M19 are mixed with 0.2% of the polymerisable compound of the formula
##STR00456##
Example M46
[0398] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M19 are mixed with 0.001% of Irganox and 0.25% of the polymerisable compound of the formula
##STR00457##
Example M47
[0399] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M19 are mixed with 0.25% of the polymerisable compound of the formula
##STR00458##
Example M48
[0400] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M19 are mixed with 0.25% of the polymerisable compound of the formula
##STR00459##
Example M49
[0401] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.8% of the mixture according to Example M19 are mixed with 0.2% of the polymerisable compound of the formula
##STR00460##
Example M50
[0402] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M19 are mixed with 0.25% of the polymerisable compound of the formula
##STR00461##
Example M51
[0403] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.7% of the mixture according to Example M22 are mixed with 0.3% of the polymerisable compound of the formula
##STR00462##
Example M52
[0404] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M22 are mixed with 0.25% of the polymerisable compound of the formula
##STR00463##
Example M53
[0405] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.8% of the mixture according to Example M22 are mixed with 0.2% of the polymerisable compound of the formula
##STR00464##
Example M54
[0406] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M22 are mixed with 0.25% of the polymerisable compound of the formula
##STR00465##
Example M55
[0407] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M22 are mixed with 0.25% of the polymerisable compound of the formula
##STR00466##
Example M56
[0408] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M22 are mixed with 0.25% of the polymerisable compound of the formula
##STR00467##
Example M57
[0409] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.8% of the mixture according to Example M22 are mixed with 0.2% of the polymerisable compound of the formula
##STR00468##
Example M58
[0410] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.8% of the mixture according to Example M28 are mixed with 0.2% of the polymerisable compound of the formula
##STR00469##
Example M59
[0411] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M28 are mixed with 0.25% of the polymerisable compound of the formula
##STR00470##
Example M60
[0412] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.7% of the mixture according to Example M33 are mixed with 0.3% of the polymerisable compound of the formula
##STR00471##
Example M61
[0413] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.7% of the mixture according to Example M33 are mixed with 0.3% of the polymerisable compound of the formula
##STR00472##
Example M62
[0414] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.8% of the mixture according to Example M33 are mixed with 0.2% of the polymerisable compound of the formula
##STR00473##
[0415] and 0.2% of the polymerisable compound
##STR00474##
Example M63
[0416] The liquid-crystalline mixture
TABLE-US-00035 CC-3-V 41.00% Clearing point [° C.]: 74.0 CCY-3-O2 11.00% Δn [589 nm, 20° C.]: 0.1005 CCY-3-O1 2.50% Δε [1 kHz, 20° C.]: −3.7 CLY-3-O2 4.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CLY-3-O3 4.00% K.sub.1 [pN, 20° C.]: 13.3 CPY-2-O2 4.00% K.sub.3 [pN, 20° C.]: 15.0 CPY-3-O2 11.00% γ.sub.1 [mPa .Math. s, 20° C.]: 87 CY-3-O2 7.50% V.sub.0 [20° C., V]: 2.14 PY-3-O2 12.00% B-3O-O5 3.00%
[0417] additionally comprises 0.025% of ST-8-1.
Example M64
[0418] The liquid-crystalline mixture
TABLE-US-00036 CC-3-V 42.00% Clearing point [° C.]: 73.5 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1009 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.5 CCY-4-O2 2.50% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 12.9 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.5 CY-3-O2 6.50% γ.sub.1 [mPa .Math. s, 20° C.]: 88 PY-3-O2 11.00% V.sub.0 [20° C., V]: 2.14 B-3O-O5 3.00%
[0419] additionally comprises 0.025% of ST-12.
Example M65
[0420] The liquid-crystalline mixture
TABLE-US-00037 CC-3-V 43.00% Clearing point [° C.]: 73.5 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1011 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.6 CCY-4-O2 2.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 13.3 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.7 CY-3-O2 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 83 PY-3-O2 11.00% V.sub.0 [20° C., V]: 2.14 B-3O-O5 4.00%
[0421] additionally comprises 0.025% of ST-3a-1.
Example M66
[0422] The liquid-crystalline mixture
TABLE-US-00038 CC-3-V 40.50% Clearing point [° C.]: 74.0 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1005 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.6 CCY-4-O2 3.50% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 12.9 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.6 CY-3-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 88 PY-3-O2 11.00% V.sub.0 [20° C., V]: 2.14 B-3O-O4 2.00%
[0423] additionally comprises 0.025% of ST-12.
Example M67
[0424] The liquid-crystalline mixture
TABLE-US-00039 CC-3-V 42.00% Clearing point [° C.]: 73.5 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1011 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.6 CCY-4-O2 2.50% ε.sub.|| [1 kHz, 20° C.]: 3.7 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 12.9 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.6 CY-3-O2 6.50% γ.sub.1 [mPa .Math. s, 20° C.]: 85 PY-3-O2 11.00% V.sub.0 [20° C., V]: 2.14 B-2O-O4 3.00%
[0425] additionally comprises 0.03% of ST-2a-1.
Example M68
[0426] The liquid-crystalline mixture
TABLE-US-00040 CC-3-V 42.00% Clearing point [° C.]: 73.5 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1001 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.5 CCY-4-O2 2.50% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 13.0 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.5 CY-3-O2 6.50% γ.sub.1 [mPa .Math. s, 20° C.]: 84 PY-3-O2 11.00% V.sub.0 [20° C., V]: 2.15 B-3O-O6 3.00%
[0427] additionally comprises 0.025% of ST-8-1.
Example M69
[0428] The liquid-crystalline mixture
TABLE-US-00041 CC-3-V 42.00% Clearing point [° C.]: 73.5 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1007 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.5 CCY-4-O2 2.50% ε.sub.|| [1 kHz, 20° C.]: 3.7 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 12.9 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.6 CY-3-O2 6.50% γ.sub.1 [mPa .Math. s, 20° C.]: 84 PY-3-O2 11.00% V.sub.0 [20° C., V]: 2.15 B-2O-O5 3.00%
[0429] additionally comprises 0.025% of ST-8-1.
TABLE-US-00042 Comparison VHR after UV M69 without stabiliser 60% M69 with stabiliser 79% (0.025% of ST-8-1)
Example M70
[0430] The liquid-crystalline mixture
TABLE-US-00043 CC-3-V 45.50% Clearing point [° C.]: 73.0 CCY-3-O1 3.00% Δn [589 nm, 20° C.]: 0.1011 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −3.5 CCY-4-O2 3.50% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-2-O2 7.50% K.sub.1 [pN, 20° C.]: 13.1 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.3 CY-3-O2 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 79 PY-3-O2 11.50% V.sub.0 [20° C., V]: 2.15 B-2O-O5 6.00%
[0431] additionally comprises 0.025% of ST-8-1.
Example M71
[0432] The liquid-crystalline mixture
TABLE-US-00044 CC-3-V 42.00% Clearing point [° C.]: 73.5 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.0993 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.5 CCY-4-O2 2.50% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 12.9 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.5 CY-3-O2 6.50% γ.sub.1 [mPa .Math. s, 20° C.]: 84 PY-3-O2 11.00% V.sub.0 [20° C., V]: 2.14 B-3O-O3 3.00%
[0433] additionally comprises 0.025% of ST-8-1.
Example M72
[0434] The liquid-crystalline mixture
TABLE-US-00045 CC-3-V 45.50% Clearing point [° C.]: 73.5 CCY-3-O1 3.00% Δn [589 nm, 20° C.]: 0.1009 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −3.5 CCY-4-O2 3.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CPY-2-O2 8.50% K.sub.1 [pN, 20° C.]: 13.2 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.3 CY-3-O2 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 80 PY-3-O2 11.00% V.sub.0 [20° C., V]: 2.15 B—2O—O5 3.00% B—3O—O5 3.00%
[0435] additionally comprises 0.025% of ST-8-1.
Example M73
[0436] The liquid-crystalline mixture
TABLE-US-00046 CC-3-V 35.50% Clearing point [° C.]: 73.0 CCY-3-O1 6.00% Δn [589 nm, 20° C.]: 0.1006 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −4.4 CCY-4-O2 6.50% ε.sub.∥ [1 kHz, 20° C.]: 3.9 CPY-2-O2 4.00% K.sub.1 [pN, 20° C.]: 12.9 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.6 CY-3-O2 12.00% γ.sub.1 [mPa .Math. s, 20° C.]: 99 PY-3-O2 10.00% V.sub.0 [20° C., V]: 1.93 B—3O—O5 2.50% B—3O—O4 2.50%
[0437] additionally comprises 0.025% of ST-3a-1.
Example M74
[0438] The liquid-crystalline mixture
TABLE-US-00047 CC-3-V 34.50% Clearing point [° C.]: 75.0 CC-3-V1 8.00% Δn [589 nm, 20° C.]: 0.1084 CCY-3-O1 6.00% Δε [1 kHz, 20° C.]: −3.1 CCY-3-O2 11.50% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCY-4-O2 3.50% K.sub.1 [pN, 20° C.]: 14.3 CPY-3-O2 11.50% K.sub.3 [pN, 20° C.]: 15.9 PY-3-O2 16.00% γ.sub.1 [mPa .Math. s, 20° C.]: 87 PYP-2-3 3.00% V.sub.0 [20° C., V]: 2.40 PP-1-2V1 3.00% B—3O—O5 3.00%
[0439] additionally comprises 0.02% of ST-2a-1.
Example M75
[0440] The liquid-crystalline mixture
TABLE-US-00048 CC-3-V 34.50% Clearing point [° C.]: 75.0 CC-3-V1 8.00% Δn [589 nm, 20° C.]: 0.1075 CCY-3-O1 7.00% Δε [1 kHz, 20° C.]: −3.1 CCY-3-O2 11.50% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCY-4-O2 3.50% K.sub.1 [pN, 20° C.]: 14.7 CPY-3-O2 11.50% K.sub.3 [pN, 20° C.]: 16.4 PY-3-O2 13.00% γ.sub.1 [mPa .Math. s, 20° C.]: 84 PP-1-2V1 6.00% V.sub.0 [20° C., V]: 2.41 B—2O—O5 5.00%
[0441] additionally comprises 0.02% of ST-8-1.
Example M76
[0442] The liquid-crystalline mixture
TABLE-US-00049 CC—V—V 37.00% Clearing point [° C.]: 73.5 CC—V—V1 10.00% Δn [589 nm, 20° C.]: 0.1026 CCVC—V—V 7.00% Δε [1 kHz, 20° C.]: −3.0 CCVC-3-V 7.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCC-2-V 3.00% K.sub.1 [pN, 20° C.]: 11.8 CCC-3-V 4.00% K.sub.3 [pN, 20° C.]: 11.9 B—4O—O4 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 57 B—3O—O4 8.50% V.sub.0 [20° C., V]: 2.10 B—3O—O5 8.50% PB-3-O4 7.00% CB-3-O4 5.00%
[0443] additionally comprises 0.02% of ST-8-1.
Example M77
[0444] The liquid-crystalline mixture
TABLE-US-00050 CC—V—V 18.00%% Clearing point [° C.]: 77.8 CC-3-V 21.00% Δn [589 nm, 20° C.]: 0.1040 CC—V—V1 10.00% Δε [1 kHz, 20° C.]: −3.2 CCVC—V—V 7.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCVC-3-V 7.00% K.sub.1 [pN, 20° C.]: 13.3 CCC-2-V 2.00% K.sub.3 [pN, 20° C.]: 12.2 CCC-3-V 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 64 B—4O—O4 3.00% V.sub.0 [20° C., V]: 2.07 B—3O—O4 8.50% B—3O—O5 8.50% PB-3-O4 7.00% CB-3-O4 5.00%
[0445] additionally comprises 0.02% of ST-12.
Example M78
[0446] The liquid-crystalline mixture
TABLE-US-00051 CC—V—V 38.00% Clearing point [° C.]: 74.0 CCVC—V—V 5.00% Δn [589 nm, 20° C.]: 0.1119 CCVC-3-V 10.00% Δε [1 kHz, 20° C.]: −4.8 CCC-2-V 3.00% ε.sub.∥ [1 kHz, 20° C.]: 4.3 CCC-3-V 4.00% K.sub.1 [pN, 20° C.]: 12.3 B—4O—O4 2.00% K.sub.3 [pN, 20° C.]: 11.0 B—3O—O4 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 76 B—3O—O5 7.00% V.sub.0 [20° C., V]: 1.60 PB-3-O4 6.00% CB-3-O4 7.00% B—2O—O5 8.00% B—2O—O6 5.00%
[0447] additionally comprises 0.025% of ST-8-1.
Example M79
[0448] The liquid-crystalline mixture
TABLE-US-00052 CC—V—V 25.00% Clearing point [° C.]: 81.0 CCVC—V—V 4.00% Δn [589 nm, 20° C.]: 0.1068 CCVC-3-V 9.00% Δε [1 kHz, 20° C.]: −4.2 CCC-2-V 3.00% ε.sub.∥ [1 kHz, 20° C.]: 4.1 CCC-3-V 3.00% K.sub.1 [pN, 20° C.]: 14.6 B—3O—O4 4.00% K.sub.3 [pN, 20° C.]: 11.8 B—3O—O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 90 PB-3-O4 4.00% V.sub.0 [20° C., V]: 1.70 CB-3-O4 7.00% B—2O—O5 6.00% B—2O—O6 5.00% B—2O—O4 3.00% B—1O—O4 3.00% CCOC-3-3 3.00% CCH-23 3.00% CCH-34 10.00% CCOC-4-3 3.00%
[0449] additionally comprises 0.02% of ST-8-1 and 0.1% of ST-3a-1.
Example M80
[0450] The liquid-crystalline mixture
TABLE-US-00053 CC—V—V 28.00% Clearing point [° C.]: 55.5 CCVC—V—V 5.00% Δε [1 kHz, 20° C.]: −7.6 CCVC-3-V 10.00% ε.sub.∥ [1 kHz, 20° C.]: 5.8 CCC-2-V 3.00% K.sub.1 [pN, 20° C.]: 11.1 CCC-3-V 3.00% K.sub.3 [pN, 20° C.]: 8.6 B—4O—O4 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 90 B—3O—O4 4.00% V.sub.0 [20° C., V]: 1.12 B—3O—O5 3.00% B—4O—O5 3.00% B—2O—O4 3.00% B—2O—O5 5.00% B—2O—O6 3.00% B—1O—O5 3.00% B—3O—O3 4.00% B—3O—O6 3.00% B—1O—O4 5.00% B—2O—O5i 5.00% CCP—V-1 7.00%
[0451] additionally comprises 0.02% of ST-8-1.
Example M81
[0452] The liquid-crystalline mixture
TABLE-US-00054 CC—V—V 35.00% Clearing point [° C.]: 67.5 CCVC—V—V 5.00% Δε [1 kHz, 20° C.]: −6.2 CCVC-3-V 8.00% ε.sub.∥ [1 kHz, 20° C.]: 4.8 CCC-2-V 3.00% K.sub.1 [pN, 20° C.]: 11.9 CCC-3-V 4.00% K.sub.3 [pN, 20° C.]: 9.6 B—4O—O4 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 86 B—3O—O4 5.00% V.sub.0 [20° C., V]: 1.32 B—3O—O5 7.00% PB-3-O4 6.00% CB-3-O4 7.00% B—2O—O5 8.00% B—2O—O6 5.00% B—3O—O3 5.00%
[0453] additionally comprises 0.02% of ST-8-1.
Example M82
[0454] The liquid-crystalline mixture
TABLE-US-00055 CC—V—V 35.00% Clearing point [° C.]: 67.5 CCVC—V—V 5.00% Δε [1 kHz, 20° C.]: −6.2 CCVC-3-V 8.00% ε.sub.∥ [1 kHz, 20° C.]: 4.8 CCC-2-V 3.00% K.sub.1 [pN, 20° C.]: 11.9 CCC-3-V 4.00% K.sub.3 [pN, 20° C.]: 9.6 B—4O—O4 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 86 B—3O—O4 5.00% V.sub.0 [20° C., V]: 1.32 B—3O—O5 7.00% PB-3-O4 6.00% CB-3-O4 7.00% B—2O—O5 8.00% B—2O—O6 5.00% B—3O—O3 5.00%
[0455] additionally comprises 0.03% of ST-12.
Example M83
[0456] The liquid-crystalline mixture
TABLE-US-00056 CC-3-V 10.00% Clearing point [° C.]: 74.5 CC-3-V1 8.00% Δn [589 nm, 20° C.]: 0.1078 CCH-23 10.00% Δε [1 kHz, 20° C.]: −3.3 CCH-34 5.00% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCP-3-1 7.00% K.sub.1 [pN, 20° C.]: 14.6 CCY-3-O1 5.00% K.sub.3 [pN, 20° C.]: 15.7 CCY-3-O2 11.00% γ.sub.1 [mPa .Math. s, 20° C.]: 101 CCY-4-O2 4.50% V.sub.0 [20° C., V]: 2.32 CPY-3-O2 3.00% CY-3-O2 12.00% PY-3-O2 8.50% PYP-2-3 8.00% B—2O—O5 4.00% PP-1-2V1 4.00%
[0457] additionally comprises 0.03% of ST-9-1.
Example M84
[0458] The liquid-crystalline mixture
TABLE-US-00057 CC-3-V 15.00% Clearing point [° C.]: 74.0 CC-3-V1 8.00% Δn [589 nm, 20° C.]: 0.1078 CCH-23 10.00% Δε [1 kHz, 20° C.]: −3.1 CCH-34 7.00% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCY-3-O1 8.00% K.sub.1 [pN, 20° C.]: 14.6 CCY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 15.1 CCY-4-O2 3.50% γ.sub.1 [mPa .Math. s, 20° C.]: 94 CPY-3-O2 6.00% V.sub.0 [20° C., V]: 2.32 CY-3-O2 5.50% PY-3-O2 10.00% PYP-2-3 8.00% B—2O—O5 4.00% PP-1-2V1 4.00%
[0459] additionally comprises 0.03% of ST-8-1.
Example M85
[0460] The liquid-crystalline mixture
TABLE-US-00058 CC-3-V 42.50% Clearing point [° C.]: 75.0 CCP-3-1 4.50% Δn [589 nm, 20° C.]: 0.0984 CCY-3-O1 9.00% Δε [1 kHz, 20° C.]: −3.2 CCY-3-O2 11.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CPY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 13.5 CPY-2-O2 4.50% K.sub.3 [pN, 20° C.]: 15.1 CY-3-O2 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 81 PY-3-O2 13.50% V.sub.0 [20° C., V]: 2.29 B—2O—O5 4.00%
[0461] additionally comprises 0.025% of ST-8-1.
Example M86
[0462] The liquid-crystalline mixture
TABLE-US-00059 CC-3-V 45.00% Clearing point [° C.]: 75.0 CCP-3-1 3.00% Δn [589 nm, 20° C.]: 0.0991 CCY-3-O1 8.50% Δε [1 kHz, 20° C.]: −3.3 CCY-3-O2 11.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCY-4-O2 1.50% K.sub.1 [pN, 20° C.]: 13.8 CPY-3-O2 11.50% K.sub.3 [pN, 20° C.]: 15.3 PY-3-O2 12.50% γ.sub.1 [mPa .Math. s, 20° C.]: 80 B—2O—O5 4.00% V.sub.0 [20° C., V]: 2.28 B-3-O2 3.00%
[0463] additionally comprises 0.03% of ST-8-1.
Example M87
[0464] The liquid-crystalline mixture
TABLE-US-00060 CC-3-V1 8.00% Clearing point [° C.]: 74.0 CCH-23 18.00% Δn [589 nm, 20° C.]: 0.0978 CCH-34 3.00% Δε [1 kHz, 20° C.]: −3.4 CCH-35 4.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCP-3-1 14.00% K.sub.1 [pN, 20° C.]: 14.9 CCY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 16.1 CCY-3-O1 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 102 CPY-3-O2 11.00% V.sub.0 [20° C., V]: 2.28 CY-3-O2 10.50% PY-3-O2 12.50% B-2O-O5 3.00% Y-4O-O4 3.00%
[0465] additionally comprises 0.025% of ST-8-1.
TABLE-US-00061 Comparison VHR after UV M87 without stabiliser 83% M87 with stabiliser 90% (0.025% of ST-8-1)
Example M88
[0466] The liquid-crystalline mixture
TABLE-US-00062 CC-3-V1 8.00% Clearing point [° C.]: 74.0 CCH-23 18.00% Δn [589 nm, 20° C.]: 0.0978 CCH-34 3.00% Δε [1 kHz, 20° C.]: −3.4 CCH-35 4.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCP-3-1 14.00% K.sub.1 [pN, 20° C.]: 14.9 CCY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 16.1 CCY-3-O1 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 102 CPY-3-O2 11.00% V.sub.0 [20° C., V]: 2.28 CY-3-O2 10.50% PY-3-O2 12.50% B-2O-O5 3.00% Y-4O-O4 3.00%
[0467] additionally comprises 0.01% of ST-9-1.
TABLE-US-00063 Comparison VHR after UV M88 without stabiliser 83% M88 with stabiliser 89% (0.01% of ST-9-1)
Example M89
[0468] The liquid-crystalline mixture
TABLE-US-00064 CC-3-V1 7.00% Clearing point [° C.]: 73.0 CCH-23 18.00% Δn [589 nm, 20° C.]: 0.0969 CCH-34 3.00% Δε [1 kHz, 20° C.]: −3.4 CCH-35 4.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCP-3-1 14.00% K.sub.1 [pN, 20° C.]: 14.6 CCY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 15.8 CCY-3-O1 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 102 CPY-3-O2 11.00% V.sub.0 [20° C., V]: 2.29 CY-3-O2 12.00% PY-3-O2 11.00% Y-4O-O4 3.00% B-2-O2 3.00%
[0469] additionally comprises 0.01% of ST-9-1.
Example M90
[0470] For the preparation of a PS-VA mixture, 99.7% of the mixture according to Example M34 are mixed with 0.3% of the polymerisable compound of the formula
##STR00475##
Example M91
[0471] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M34 are mixed with 0.25% of the polymerisable compound of the formula
##STR00476##
Example M92
[0472] For the preparation of a PS-VA mixture, 99.8% of the mixture according to Example M35 are mixed with 0.2% of the polymerisable compound of the formula
##STR00477##
Example M93
[0473] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M63 are mixed with 0.25% of the polymerisable compound of the formula
##STR00478##
Example M94
[0474] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M63 are mixed with 0.25% of the polymerisable compound of the formula
##STR00479##
Example M95
[0475] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M63 are mixed with 0.3% of the polymerisable compound of the formula
##STR00480##
Example M96
[0476] For the preparation of a PS-VA mixture, 99.8% of the mixture according to Example M65 are mixed with 0.2% of the polymerisable compound of the formula
##STR00481##
Example M97
[0477] For the preparation of a PS-VA mixture, 99.8% of the mixture according to Example M70 are mixed with 0.2% of the polymerisable compound of the formula
##STR00482##
Example M98
[0478] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M71 are mixed with 0.25% of the polymerisable compound of the formula
##STR00483##
Example M99
[0479] For the preparation of a PS-VA mixture, 99.7% of the mixture according to Example M72 are mixed with 0.3% of the polymerisable compound of the formula
##STR00484##
Example M100
[0480] The liquid-crystalline mixture
TABLE-US-00065 CC-V-V 31.50% Clearing point [° C.]: 75.0 CCP-3-1 5.00% Δn 8 589 nm, 20° C.]: 0.0949 CCY-2-1 12.00% Δε [1 kHz, 20° C.]: −3.8 CCY-3-O1 7.50% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 11.4 CLY-3-O2 5.50% K.sub.3 [pN, 20° C.]: 14.2 CLY-3-O3 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 88 CPY-2-O2 4.50% V.sub.0 [20° C., V]: 2.04 CPY-3-O2 3.00% CY-3-O2 11.00% PY-1-O4 4.00% B-2O-O5 4.00%
[0481] additionally comprises 0.03% of ST-12.
Example M101
[0482] The liquid-crystalline mixture
TABLE-US-00066 CC-3-V 36.50% Clearing point [° C.]: 80.0 CCY-3-O1 6.00% Δn [589 nm, 20° C.]: 0.1028 CCY-3-O2 6.00% Δε [1 kHz, 20° C.]: −4.4 CCY-4-O2 2.50% ε.sub.|| [1 kHz, 20° C.]: 3.8 CLY-3-O2 7.00% K.sub.1 [pN, 20° C.]: 14.2 CLY-3-O3 3.00% K.sub.3 [pN, 20° C.]: 15.9 CPY-2-O2 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 108 CPY-3-O2 10.00% V.sub.0 [20° C., V]: 2.01 CY-3-O2 11.50% PY-3-O2 5.50% B-2O-O5 5.00%
[0483] additionally comprises 0.025% of ST-8-1.
Example M102
[0484] The liquid-crystalline mixture
TABLE-US-00067 CY-3-O2 9.00% Clearing point [° C.]: 87.0 CY-3-O4 7.00% Δn [589 nm, 20° C.]: 0.1026 PY-3-O2 3.00% Δε [1 kHz, 20° C.]: −4.9 CCY-3-O1 8.00% ε.sub.|| [1 kHz, 20° C.]: 3.9 CCY-3-O2 11.00% K.sub.1 [pN, 20° C.]: 14.5 CCY-4-O2 10.00% K.sub.3 [pN, 20° C.]: 16.7 CPY-2-O2 6.50% γ.sub.1 [mPa .Math. s, 20° C.]: 142 CPY-3-O2 12.00% V.sub.0 [20° C., V]: 1.95 CC-3-V 29.50% B-2O-O5 4.00%
[0485] additionally comprises 0.025% of ST-8-1.
Example M103
[0486] The liquid-crystalline mixture
TABLE-US-00068 CY-3-O2 12.50% Clearing point [° C.]: 87.0 CCY-3-O1 9.00% Δn [589 nm, 20° C.]: 0.1025 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −4.8 CCY-4-O2 7.00% ε.sub.|| [1 kHz, 20° C.]: 3.8 CPY-3-O2 3.00% K.sub.1 [pN, 20° C.]: 14.1 CC-3-V 31.00% K.sub.3 [pN, 20° C.]: 16.8 B-2O-O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 127 PY-V2-O2 5.50% V.sub.0 [20° C., V]: 1.97 CPY-V-O2 6.00% CPY-V-O4 5.00% CCY-V-O2 6.00%
[0487] additionally comprises 0.025% of ST-12.
Example M104
[0488] The liquid-crystalline mixture
TABLE-US-00069 CC-3-V 34.50% Clearing point [° C.]: 74.0 CC-3-V1 8.00% Δn [589 nm, 20° C.]: 0.1072 CCY-3-O1 5.50% Δε [1 kHz, 20° C.]: −3.0 CCY-3-O2 11.50% ε.sub.|| [1 kHz, 20° C.]: 3.5 PY-3-O2 7.50% K.sub.1 [pN, 20° C.]: 14.0 PP-1-2V1 7.00% K.sub.3 [pN, 20° C.]: 15.8 B-2O-O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 78 PY-V2-O2 5.00% V.sub.0 [20° C., V]: 2.43 CPY-V-O2 6.00% CPY-V-O4 5.00% CCY-V-O2 6.00%
[0489] additionally comprises 0.025% of ST-8-1.
Example M105
[0490] The liquid-crystalline mixture
TABLE-US-00070 CC-3-V 42.00% Clearing point [° C.]: 74.5 CCP-3-1 5.00% Δn [589 nm, 20° C.]: 0.0997 CCY-3-O1 3.00% Δε [1 kHz, 20° C.]: −3.3 CCY-3-O2 11.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCY-V-O2 6.00% K.sub.1 [pN, 20° C.]: 13.0 CPY-V-O2 6.50% K.sub.3 [pN, 20° C.]: 14.9 CPY-V-O4 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 75 CY-3-O2 3.50% V.sub.0 [20° C., V]: 2.26 PY-3-O2 5.00% B-2O-O5 4.00% PY-V2-O2 9.00%
[0491] additionally comprises 0.025% of ST-8-1.
Example M106
[0492] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.7% of the mixture according to Example M100 are mixed with 0.3% of the polymerisable compound of the formula
##STR00485##
Example M107
[0493] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M100 are mixed with 0.25% of the polymerisable compound of the formula
##STR00486##
Example M108
[0494] For the preparation of a PS-VA mixture, 99.8% of the mixture according to Example M101 are mixed with 0.2% of the polymerisable compound of the formula
##STR00487##
Example M109
[0495] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M102 are mixed with 0.25% of the polymerisable compound of the formula
##STR00488##
Example M110
[0496] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M102 are mixed with 0.25% of the polymerisable compound of the formula
##STR00489##
Example M111
[0497] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.7% of the mixture according to Example M102 are mixed with 0.3% of the polymerisable compound of the formula
##STR00490##
Example M112
[0498] For the preparation of a PS-VA mixture, 99.8% of the mixture according to Example M102 are mixed with 0.2% of the polymerisable compound of the formula
##STR00491##
Example M113
[0499] For the preparation of a PS-VA mixture, 99.8% of the mixture according to Example M103 are mixed with 0.2% of the polymerisable compound of the formula
##STR00492##
Example M114
[0500] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M104 are mixed with 0.25% of the polymerisable compound of the formula
##STR00493##
Example M115
[0501] For the preparation of a PS-VA mixture, 99.7% of the mixture according to Example M104 are mixed with 0.3% of the polymerisable compound of the formula
##STR00494##
Example M116
[0502] For the preparation of a PS-VA mixture, 99.7% of the mixture according to Example M104 are mixed with 0.3% of the polymerisable compound of the formula
##STR00495##
Example M117
[0503] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M104 are mixed with 0.25% of the polymerisable compound of the formula
##STR00496##
Example M118
[0504] For the preparation of a PS-VA mixture, 99.7% of the mixture according to Example M104 are mixed with 0.3% of the polymerisable compound of the formula
##STR00497##
Example M119
[0505] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M105 are mixed with 0.25% of the polymerisable compound of the formula
##STR00498##
Example M120
[0506] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M105 are mixed with 0.25% of the polymerisable compound of the formula
##STR00499##
Example M121
[0507] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M105 are mixed with 0.25% of the polymerisable compound of the formula
##STR00500##
Example M122
[0508] For the preparation of a PS-VA mixture, 99.75% of the mixture according to Example M105 are mixed with 0.25% of the polymerisable compound of the formula
##STR00501##
Example M123
[0509] For the preparation of a PS-VA mixture, 99.8% of the mixture according to Example M105 are mixed with 0.3% of the polymerisable compound of the formula
##STR00502##
Example M124
[0510] The liquid-crystalline mixture
TABLE-US-00071 CC-3-V 17.00% Clearing point [° C.]: 75.5 CC-V-V 20.00% Δn [589 nm, 20° C.]: 0.1079 CC-3-V1 8.00% ε.sub.|| [1 kHz, 20° C.]: 3.4 CCY-3-O1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.1 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −2.7 CCY-4-O2 2.50% K.sub.1 [pN, 20° C.]: 12.5 CPY-2-O2 5.50% K.sub.3 [pN, 20° C.]: 14.8 CPY-3-O2 11.50% V.sub.0 [pN, 20° C.]: 2.45 PY-3-O2 8.50% γ.sub.1 [mPa .Math. s, 20° C.]: 75 PYP-2-3 5.00% PP-1-2V1 3.00% B-3O-O5 3.00%
[0511] additionally comprises 0.025% of ST-8-1.
Example M125
[0512] The liquid-crystalline mixture
TABLE-US-00072 CC-3-V 20.50% Clearing point [° C.]: 74.5 CC-V-V 15.00% Δn [589 nm, 20° C.]: 0.1095 CC-3-V1 8.00% ε.sub.|| [1 kHz, 20° C.]: 3.5 CLY-3-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.3 CCY-3-O2 11.50% Δε [1 kHz, 20° C.]: −2.9 CCY-4-O2 4.00% K.sub.1 [pN, 20° C.]: 13.5 CPY-3-O2 7.50% K.sub.3 [pN, 20° C.]: 15.2 BCH-32 3.50% V.sub.0 [pN, 20° C.]: 2.43 PY-3-O2 11.50% γ.sub.1 [mPa .Math. s, 20° C.]: 77 PGIY-2-O4 4.50% PP-1-2V1 4.00% B-2O-O5 4.00%
[0513] additionally comprises 0.025% of ST-2a-1.
Example M126
[0514] The liquid-crystalline mixture
TABLE-US-00073 CC-V-V 36.00% Clearing point [° C.]: 75 CC-3-V1 8.00% Δn [589 nm, 20° C.]: 0.1076 CLY-3-O2 6.00% ε.sub.|| [1 kHz, 20° C.]: 3.4 CCY-3-O2 11.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.0 CCY-4-O2 5.00% Δε [1 kHz, 20° C.]: −2.7 CPY-3-O2 7.50% K.sub.1 [pN, 20° C.]: 12.0 BCH-32 7.00% K.sub.3 [pN, 20° C.]: 14.3 PY-3-O2 8.00% V.sub.0 [pN, 20° C.]: 2.46 PGIY-2-O4 4.50% γ.sub.1 [mPa .Math. s, 20° C.]: 70 PP-1-2V1 2.50% B-2O-O5 4.00%
[0515] additionally comprises 0.03% of ST-12.
Example M127
[0516] The liquid-crystalline mixture
TABLE-US-00074 CC-V-V 34.00% Clearing point [° C.]: 75.5 CC-3-V1 8.00% Δn [589 nm, 20° C.]: 0.1085 CCY-3-O1 7.00% ε.sub.|| [1 kHz, 20° C.]: 3.4 CCY-3-O2 11.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.1 CCY-4-O2 5.00% Δε [1 kHz, 20° C.]: −2.7 CPY-3-O2 7.50% K.sub.1 [pN, 20° C.]: 12.0 BCH-32 7.00% K.sub.3 [pN, 20° C.]: 14.4 PY-3-O2 8.00% V.sub.0 [pN, 20° C.]: 2.44 PGIY-2-O4 4.50% γ.sub.1 [mPa .Math. s, 20° C.]: 74 PP-1-2V1 3.50% B-2O-O5 4.00%
[0517] additionally comprises 0.025% of ST-8-1.
Example M128
[0518] The liquid-crystalline mixture
TABLE-US-00075 CC-3-V 9.50% Clearing point [° C.]: 74.0 CC—V—V 29.00% Δn [589 nm, 20° C.]: 0.0989 CCP-3-1 10.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCY-3-O1 8.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −3.2 CPY-2-O2 2.00% K.sub.1 [pN, 20° C.]: 11.8 CPY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 14.8 CY-3-O2 5.00% V.sub.0 [pN, 20° C.]: 2.28 PY-3-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 76 B—2O—O5 4.00%
[0519] additionally comprises 0.025% of ST-8-1.
Example M129
[0520] The liquid-crystalline mixture
TABLE-US-00076 CC-3-V 15.50% Clearing point [° C.]: 74.5 CC—V—V 20.00% Δn [589 nm, 20° C.]: 0.1075 CC-3-V1 8.00% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCY-3-O1 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.5 CCY-3-O2 11.50% Δε [1 kHz, 20° C.]: −3.0 CCY-4-O2 4.50% K.sub.1 [pN, 20° C.]: 12.9 CPY-3-O2 8.50% K.sub.3 [pN, 20° C.]: 15.0 PY-2-O2 6.50% V.sub.0 [pN, 20° C.]: 2.35 PGIY-2-O4 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 76 PP-1-2V1 6.50% LTS bulk [−20° C.]: >1000 h B(S)—2O—O5 3.00% B—2O—O5 3.00%
[0521] additionally comprises 0.1% of ST-8-1.
Example M130
[0522] The liquid-crystalline mixture
TABLE-US-00077 CC-3-V 17.50% Clearing point [° C.]: 74 CC—V—V 20.00% Δn [589 nm, 20° C.]: 0.1074 CC-3-V1 8.00% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCY-3-O1 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.4 CCY-3-O2 12.00% Δε [1 kHz, 20° C.]: −2.9 CPY-3-O2 12.00% K.sub.1 [pN, 20° C.]: 12.7 PY-2-O2 6.00% K.sub.3 [pN, 20° C.]: 15.1 PGIY-2-O4 4.50% V.sub.0 [pN, 20° C.]: 2.41 PP-1-2V1 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 72 B(S)—2O—O5 3.00% B—2O—O5 3.00%
[0523] additionally comprises 0.025% of ST-8-1.
Example M131
[0524] The liquid-crystalline mixture
TABLE-US-00078 CC-3-V 22.00% Clearing point [° C.]: 76 CC—V—V 20.00% Δn [589 nm, 20° C.]: 0.0946 CCY-3-O1 8.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCY-3-O2 12.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CCY-4-O2 2.50% Δε [1 kHz, 20° C.]: −3.9 CLY-3-O2 6.00% K.sub.1 [pN, 20° C.]: 12.4 CLY-3-O3 9.50% K.sub.3 [pN, 20° C.]: 14.3 CPY-3-O2 1.50% V.sub.0 [pN, 20° C.]: 2.04 CY-3-O2 2.50% γ.sub.1 [mPa .Math. s, 20° C.]: 78 B—2O—O5 3.00% B(S)—2O—O5 3.00% PY-2-O2 10.00%
[0525] additionally comprises 0.025% of ST-8-1.
Example M132
[0526] The liquid-crystalline mixture
TABLE-US-00079 CC-3-V 20.50% Clearing point [° C.]: 76 CC—V—V 20.00% Δn [589 nm, 20° C.]: 0.0945 CCY-3-O1 8.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCY-3-O2 11.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CCY-4-O2 4.00% Δε [1 kHz, 20° C.]: −3.9 CPY-2-O2 6.00% K.sub.1 [pN, 20° C.]: 11.9 CPY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 14.7 CY-3-O2 13.50% V.sub.0 [pN, 20° C.]: 2.05 B—2O—O5 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 84 B(S)—2O—O5 2.50%
[0527] additionally comprises 0.025% of ST-8-1.
Example M133
[0528] The liquid-crystalline mixture
TABLE-US-00080 CC-3-V 19.50% Clearing point [° C.]: 75.5 CC—V—V 23.00% Δn [589 nm, 20° C.]: 0.0989 CCP-3-1 5.50% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCY-3-O1 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.6 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −3.1 CCY-4-O2 4.00% K.sub.1 [pN, 20° C.]: 12.2 CPY-3-O2 12.00% K.sub.3 [pN, 20° C.]: 14.8 PY-3-O2 13.00% V.sub.0 [pN, 20° C.]: 2.30 B—2O—O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 75
[0529] additionally comprises 0.025% of ST-8-1.
Example M134
[0530] The liquid-crystalline mixture
TABLE-US-00081 CC—V—V 15.00% Clearing point [° C.]: 74.5 CC-3-V1 7.00% Δn [589 nm, 20° C.]: 0.1071 CCH-23 6.50% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCH-34 4.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCP-3-1 16.00% Δε [1 kHz, 20° C.]: −3.2 CCY-3-O1 4.50% K.sub.1 [pN, 20° C.]: 13.4 CCY-3-O2 12.00% K.sub.3 [pN, 20° C.]: 15.0 CY-3-O2 8.50% V.sub.0 [pN, 20° C.]: 2.29 PY-3-O2 11.50% γ.sub.1 [mPa .Math. s, 20° C.]: 88 PYP-2-3 8.00% B—2O—O5 4.00% B(S)—2O—O5 3.00%
[0531] additionally comprises 0.025% of ST-8-1.
Example M135
[0532] The liquid-crystalline mixture
TABLE-US-00082 CC-3-V 23.00% Clearing point [° C.]: 74.5 CC—V—V 20.00% Δn [589 nm, 20° C.]: 0.0974 CCP-3-1 5.00% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCY-3-O1 7.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.6 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −3.1 CCY-4-O2 5.00% K.sub.1 [pN, 20° C.]: 12.3 CPY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 14.7 PY-3-O2 13.50% V.sub.0 [pN, 20° C.]: 2.30 B—2O—O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 74
[0533] additionally comprises 0.025% of ST-8-1.
Example M136
[0534] The liquid-crystalline mixture
TABLE-US-00083 BCH-32 8.50% Clearing point [° C.]: 73.0 CC-3-V 15.00% Δn [589 nm, 20° C.]: 0.1052 CC—V—V 14.00% ε.sub.∥ [1 kHz, 20° C.]: 3.4 CCP-3-1 11.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.0 CCY-3-O1 7.00% Δε [1 kHz, 20° C.]: −2.6 CCY-3-O2 8.50% K.sub.1 [pN, 20° C.]: 12.5 CPY-3-O2 7.00% K.sub.3 [pN, 20° C.]: 14.7 CY-3-O2 17.00% V.sub.0 [pN, 20° C.]: 2.53 PP-1-3 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 79 B—2O—O5 4.00% PYP-2-3 1.00%
[0535] additionally comprises 0.025% of ST-8-1.
Example M137
[0536] The liquid-crystalline mixture
TABLE-US-00084 CC—V—V 31.50% Clearing point [° C.]: 75.0 CCP-3-1 5.00% Δn [589 nm, 20° C.]: 0.0949 CCY-2-1 12.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCY-3-O1 7.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CCY-3-O2 8.00% Δε [1 kHz, 20° C.]: −3.8 CLY-3-O2 5.50% K.sub.1 [pN, 20° C.]: 11.4 CLY-3-O3 4.00% K.sub.3 [pN, 20° C.]: 14.2 CPY-2-O2 4.50% V.sub.0 [pN, 20° C.]: 2.04 CPY-3-O2 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 88 CY-3-O2 11.00% PY-1-O4 4.00% B—2O—O5 4.00%
[0537] additionally comprises 0.025% of ST-8-1.
Example M138
[0538] The liquid-crystalline mixture
TABLE-US-00085 CC—V—V 31.50% Clearing point [° C.]: 74.5 CCP-3-1 4.00% Δn [589 nm, 20° C.]: 0.0945 CCY-2-1 12.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCY-3-O1 7.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CCY-3-O2 11.50% Δε [1 kHz, 20° C.]: −3.8 CLY-3-O2 5.00% K.sub.1 [pN, 20° C.]: 11.2 CPY-3-O2 4.50% K.sub.3 [pN, 20° C.]: 14.4 CY-3-O2 14.00% V.sub.0 [pN, 20° C.]: 2.05 PY-4-O2 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 90 PGIY-2-O4 3.00% B—2O—O5 4.00% CCPC-33 1.00%
[0539] additionally comprises 0.025% of ST-8-1.
Example M139
[0540] The liquid-crystalline mixture
TABLE-US-00086 CC-3-V 14.50% Clearing point [° C.]: 74 CC—V—V 20.00% Δn [589 nm, 20° C.]: 0.1074 CC-3-V1 8.00% Δε [ 1 kHz, 20° C.]: −3.0 CCY-3-O1 5.50% K.sub.1 [pN, 20° C.]: 12.7 CCY-3-O2 11.50% K.sub.3 [pN, 20° C.]: 15.4 CPY-3-O2 4.00% V.sub.0 [pN, 20° C.]: 2.42 PY-3-O2 3.50% γ.sub.1 [mPa .Math. s, 20° C.]: 73 PP-1-2V1 7.00% B—2O—O5 4.00% PY-V2-O2 5.00% CPY—V—O2 6.00% CPY—V—O4 5.00% CCY—V—O2 6.00%
[0541] additionally comprises 0.025% of ST-8-1.
Example M140
[0542] The liquid-crystalline mixture
TABLE-US-00087 CCP—V-1 4.00% Clearing point [° C.]: 92.5 CCY-3-O2 7.50% Δn [589 nm, 20° C.]: 0.1074 CLY-3-O2 8.00% Δε [1 kHz, 20° C.]: −2.5 CLY-3-O3 5.00% ε.sub.∥ [1 kHz, 20° C.]: 3.2 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 5.7 PGIY-2-O4 5.00% K.sub.1 [pN, 20° C.]: 16.4 PYP-2-3 6.00% K.sub.3 [pN, 20° C.]: 18.0 B—2O—O5 5.00% V.sub.0 [pN, 20° C.]: 2.82 CC-3-V 41.50% γ.sub.1 [mPa .Math. s, 20° C.]: 96 CC-3-V1 8.00%
[0543] additionally comprises 0.025% of ST-8-1.
Example M141
[0544] The liquid-crystalline mixture
TABLE-US-00088 CLY-3-O2 10.00% Clearing point [° C.]: 80 CLY-3-O3 1.50% Δn [589 nm, 20° C.]: 0.1080 CPY-2-O2 4.00% Δε [1 kHz, 20° C.]: −2.4 CPY-3-O2 10.00% ε.sub.∥ [1 kHz, 20° C.]: 3.3 PGIY-2-O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 5.7 PYP-2-3 8.00% K.sub.1 [pN, 20° C.]: 14.0 B—2O—O5 4.50% K.sub.3 [pN, 20° C.]: 15.8 CC-3-V 44.50% V.sub.0 [pN, 20° C.]: 2.68 CC-3-V1 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 80 CY-3-O2 2.50% CY-5-O2 2.00%
[0545] additionally comprises 0.025% of ST-8-1.
Example M141
[0546] The liquid-crystalline mixture
TABLE-US-00089 CCP—V2-1 5.00% Clearing point [° C.]: 79.5 CLY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1079 CPY-3-O2 9.00% Δε [1 kHz, 20° C.]: −2.0 PGIY-2-O4 2.50% ε.sub.∥ [1 kHz, 20° C.]: 3.2 PYP-2-3 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 5.3 PYP-2-4 5.00% K.sub.1 [pN, 20° C.]: 14.4 B—2O—O5 4.00% K.sub.3 [pN, 20° C.]: 15.5 CC-3-V 43.00% V.sub.0 [pN, 20° C.]: 2.92 CC-3-V1 7.50% γ.sub.1 [mPa .Math. s, 20° C.]: 75 CY-3-O2 6.00%
[0547] additionally comprises 0.025% of ST-8-1.
Example M143
[0548] The liquid-crystalline mixture
TABLE-US-00090 CCY-3-O1 4.00% Clearing point [° C.]: 79.8 CCY-3-O2 8.50% Δn [589 nm, 20° C.]: 0.1013 CCY-4-O2 5.00% Δε [1 kHz, 20° C.]: −3.7 CLY-3-O2 10.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CLY-3-O3 4.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 PGIY-2-O4 5.00% K.sub.1 [pN, 20° C.]: 14.7 PYP-2-3 1.00% K.sub.3 [pN, 20° C.]: 16.3 B-2O-O5 5.00% V.sub.0 [pN, 20° C.]: 2.20 CC-3-V 34.50% γ.sub.1 [mPa .Math. s, 20° C.]: 97 CC-3-V1 8.50% CY-3-O2 5.00% PY-3-O2 9.50%
[0549] additionally comprises 0.02% of ST-9-1.
Example M144
[0550] The liquid-crystalline mixture
TABLE-US-00091 CCY-3-O2 7.00% Clearing point [° C.]: 80 CCY-4-O2 2.00% Δn [589 nm, 20° C.]: 0.1009 CLY-3-O2 8.00% Δε [1 kHz, 20° C.]: −3.7 CLY-3-O3 4.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-2-O2 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CPY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 14.4 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 16.4 PYP-2-3 1.00% V.sub.0 [pN, 20° C.]: 2.21 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 99 CC-3-V 35.00% CC-3-V1 8.00% CY-3-O2 12.00% CY-5-O2 2.00%
[0551] additionally comprises 0.025% of ST-8-1.
Example M145
[0552] The liquid-crystalline mixture
TABLE-US-00092 CY-3-O2 4.00% Clearing point [° C.]: 100 CY-3-O4 18.00% Δn [589 nm, 20° C.]: 0.0955 CCY-3-O1 5.00% Δε [1 kHz, 20° C.]: −5.0 CCY-3-O2 6.00% ε.sub.|| [1 kHz, 20° C.]: 3.8 CCY-3-O3 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.8 CCY-4-O2 6.00% K.sub.1 [pN, 20° C.]: 15.2 CLY-3-O2 2.50% K.sub.3 [pN, 20° C.]: 16.0 CPY-2-O2 8.00% V.sub.0 [pN, 20° C.]: 1.90 CC-4-V 18.00% γ.sub.1 [mPa .Math. s, 20° C.]: 226 CC-5-V 4.00% CH-33 3.00% CH-35 3.00% CCPC-33 4.50% CCPC-34 4.50% B-2O-O5 7.50%
[0553] additionally comprises 0.025% of ST-8-1.
Example M146
[0554] The liquid-crystalline mixture
TABLE-US-00093 CCY-3-O1 8.00% Clearing point [° C.]: 81.5 CCY-4-O2 6.00% Δn [589 nm, 20° C.]: 0.1075 CLY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.1 CPY-3-O2 10.50% ε.sub.|| [1 kHz, 20° C.]: 3.5 PYP-2-3 9.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.6 B-2O-O5 5.00% K.sub.1 [pN, 20° C.]: 14.3 CC-3-V 45.00% K.sub.3 [pN, 20° C.]: 15.7 PY-3-O2 5.00% V.sub.0 [pN, 20° C.]: 2.38 Y-4O-O4 1.50% γ.sub.1 [mPa .Math. s, 20° C.]: 90
[0555] additionally comprises 0.025% of ST-8-1.
Example M147
[0556] The liquid-crystalline mixture
TABLE-US-00094 CC-3-V 35.00% Clearing point [° C.]: 86 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1208 CCY-3-O2 7.50% Δε [1 kHz, 20° C.]: −4.2 CLY-3-O2 8.00% ε.sub.|| [1 kHz, 20° C.]: 3.8 CPY-2-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.0 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.3 PY-3-O2 12.50% K.sub.3 [pN, 20° C.]: 15.6 PGIY-2-O4 8.00% V.sub.0 [pN, 20° C.]: 2.04 B-2O-O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 129
[0557] additionally comprises 0.025% of ST-8-1.
Example M148
[0558] The liquid-crystalline mixture
TABLE-US-00095 CCY-3-O1 7.00% Clearing point [° C.]: 80 CLY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1141 CPY-2-O2 10.00% Δε [1 kHz, 20° C.]: −4.0 CPY-3-O2 10.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 PYP-2-3 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 B-2O-O5 4.00% K.sub.1 [pN, 20° C.]: 14.9 CC-3-V 38.00% K.sub.3 [pN, 20° C.]: 15.6 PY-1-O4 10.00% V.sub.0 [pN, 20° C.]: 2.09 PY-3-O2 4.50% γ.sub.1 [mPa .Math. s, 20° C.]: 108 CCY-3-O2 3.50%
[0559] additionally comprises 0.025% of ST-8-1.
Example M149
[0560] The liquid-crystalline mixture
TABLE-US-00096 CCY-3-O1 7.00% Clearing point [° C.]: 90 CCY-4-O2 4.00% Δn [589 nm, 20° C.]: 0.1139 CLY-3-O2 10.00% Δε [1 kHz, 20° C.]: −4.2 CPY-2-O2 10.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.9 PYP-2-3 2.50% K.sub.1 [pN, 20° C.]: 16.2 B-2O-O5 4.00% K.sub.3 [pN, 20° C.]: 17.0 CC-3-V 35.50% V.sub.0 [pN, 20° C.]: 2.12 PY-1-O4 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 131 PY-3-O2 1.00% CCY-3-O2 6.00%
[0561] additionally comprises 0.025% of ST-12.
Example M150
[0562] The liquid-crystalline mixture
TABLE-US-00097 B-2O-O5 5.00% Clearing point [° C.]: 80.1 BCH-32 7.00% Δn [589 nm, 20° C.]: 0.1121 CC-3-V 34.50% Δε [1 kHz, 20° C.]: −3.9 CCP-V-1 2.00% K.sub.1 [pN, 20° C.]: 14.0 CCY-3-O1 5.00% K.sub.3 [pN, 20° C.]: 14.5 CCY-3-O2 4.00% V.sub.0 [pN, 20° C.]: 2.03 CCY-4-O2 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 104 CLY-3-O2 8.00% CPY-2-O2 10.00% CPY-3-O2 7.00% PGIY-2-O4 6.00% PY-3-O2 2.00% Y-4O-O4 7.50%
[0563] additionally comprises 0.025% of ST-8-1.
Example M151
[0564] The liquid-crystalline mixture
TABLE-US-00098 CCY-3-O1 7.00% Clearing point [° C.]: 80.5 CCY-4-O2 1.50% Δn [589 nm, 20° C.]: 0.1070 CLY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.9 CPY-2-O2 9.50% K.sub.1 [pN, 20° C.]: 15.0 CPY-3-O2 8.00% K.sub.3 [pN, 20° C.]: 15.7 B-2O-O5 4.00% V.sub.0 [pN, 20° C.]: 2.12 CC-3-V 40.00% γ.sub.1 [mPa .Math. s, 20° C.]: 104 PY-1-O4 9.50% PY-3-O2 4.50% CCY-3-O2 6.00%
[0565] additionally comprises 0.025% of ST-12.
Example M152
[0566] The liquid-crystalline mixture
TABLE-US-00099 CCY-3-O1 7.00% Clearing point [° C.]: 80.5 CLY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1140 CPY-2-O2 10.00% Δε [1 kHz, 20° C.]: −4.0 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.8 PYP-2-3 3.00% K.sub.3 [pN, 20° C.]: 15.6 B-2O-O5 5.00% V.sub.0 [pN, 20° C.]: 2.09 CC-3-V 38.50% γ.sub.1 [mPa .Math. s, 20° C.]: 107 PY-1-O4 10.00% PY-3-O2 3.00% CCY-3-O2 3.50%
[0567] additionally comprises 0.025% of ST-8-1.
Example M153
[0568] The liquid-crystalline mixture
TABLE-US-00100 CCY-3-O1 7.00% Clearing point [° C.]: 78.5 CLY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1142 CPY-2-O2 10.00% Δε [1 kHz, 20° C.]: −4.0 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.3 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 14.8 PYP-2-3 1.00% V.sub.0 [pN, 20° C.]: 45.66 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 103 CC-3-V 39.50% PY-1-O4 10.00% Y-4O-O4 1.50% CCY-3-O2 1.00%
[0569] additionally comprises 0.025% of ST-8-1.
Example M154
[0570] The liquid-crystalline mixture
TABLE-US-00101 CCY-3-O1 7.00% Clearing point [° C.]: 74.5 CLY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1014 CPY-2-O2 10.50% Δε [1 kHz, 20° C.]: −3.7 CPY-3-O2 9.50% γ.sub.1 [mPa .Math. s, 20° C.]: 89 B-2O-O5 3.50% CC-3-V 42.00% PY-1-O4 10.00% Y-4O-O4 3.50% CCY-3-O2 4.00%
[0571] additionally comprises 0.025% of ST-8-1.
Example M155
[0572] The liquid-crystalline mixture
TABLE-US-00102 CCY-3-O1 7.00% Clearing point [° C.]: 76.5 CLY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1003 CPY-2-O2 10.50% Δε [1 kHz, 20° C.]: −3.7 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.0 B-2O-O5 5.00% K.sub.3 [pN, 20° C.]: 14.7 CC-3-V 43.50% V.sub.0 [pN, 20° C.]: 2.09 PY-1-O4 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 89 Y-4O-O4 4.00% CCY-3-O2 4.00%
[0573] additionally comprises 0.025% of ST-8-1.
Example M156
[0574] The liquid-crystalline mixture
TABLE-US-00103 B-2O-O5 5.00% Clearing point [° C.]: 80 CC-3-V 37.00% Δn [589 nm, 20° C.]: 0.1094 CCP-V-1 4.50% Δε [1 kHz, 20° C.]: −3.7 CCY-3-O1 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CCY-4-O2 5.00% K.sub.1 [pN, 20° C.]: 13.9 CLY-3-O2 8.00% K.sub.3 [pN, 20° C.]: 14.4 CPY-2-O2 9.50% V.sub.0 [pN, 20° C.]: 2.09 PGIY-2-O4 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 106 PY-3-O2 14.00%
[0575] additionally comprises 0.025% of ST-8-1.
Example M157
[0576] The liquid-crystalline mixture
TABLE-US-00104 CCY-3-O1 7.00% Clearing point [° C.]: 90 CCY-4-O2 4.00% Δn [589 nm, 20° C.]: 0.1139 CLY-3-O2 10.00% Δε [1 kHz, 20° C.]: −4.2 CPY-2-O2 10.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.9 PYP-2-3 2.50% K.sub.1 [pN, 20° C.]: 16.2 B-2O-O5 4.00% K.sub.3 [pN, 20° C.]: 17.0 CC-3-V 35.50% V.sub.0 [pN, 20° C.]: 2.12 PY-1-O4 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 131 PY-3-O2 1.00% CCY-3-O2 6.00%
[0577] additionally comprises 0.025% of ST-8-1.
Example M158
[0578] The liquid-crystalline mixture
TABLE-US-00105 CC-3-V 35.50% Clearing point [° C.]: 75.1 CC-3-V1 10.00% Δn [589 nm, 20° C.]: 0.1096 CCP-3-1 1.50% Δε [1 kHz, 20° C.]: −3.2 CLY-3-O2 10.00% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-3-O3 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CPY-2-O2 9.00% K.sub.1 [pN, 20° C.]: 14.3 CPY-3-O2 10.50% K.sub.3 [pN, 20° C.]: 15.9 PY-3-O2 16.50% V.sub.0 [pN, 20° C.]: 2.37 PYP-2-3 1.00% γ.sub.1 [mPa .Math. s, 20° C.]: 84 B-2O-O5 3.00%
[0579] additionally comprises 0.025% of ST-8-1.
Example M159
[0580] For the preparation of a PS-VA mixture, 99.9% of the mixture according to Example M158 are mixed with 0.1% of the polymerisable compound of the formula
##STR00503##
Example M160
[0581] For the preparation of a PS-VA mixture, 99.6% of the mixture according to Example M158 are mixed with 0.4% of the polymerisable compound of the formula
##STR00504##
Example M161
[0582] For the preparation of a PS-VA mixture, 99.7% of the mixture according to Example M158 are mixed with 0.3% of the polymerisable compound of the formula
##STR00505##
Example M162
[0583] For the preparation of a PS-VA mixture, 99.8% of the mixture according to Example M158 are mixed with 0.2% of the polymerisable compound of the formula
##STR00506##
Example M163
[0584] The liquid-crystalline mixture
TABLE-US-00106 CC-3-V 35.50% Clearing point [° C.]: 75.1 CC-3-V1 10.00% Δn [589 nm, 20° C.]: 0.1096 CCP-3-1 1.50% Δε [1 kHz, 20° C.]: −3.2 CLY-3-O2 10.00% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-3-O3 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CPY-2-O2 9.00% K.sub.1 [pN, 20° C.]: 14.3 CPY-3-O2 10.50% K.sub.3 [pN, 20° C.]: 15.9 PY-3-O2 16.50% V.sub.0 [pN, 20° C.]: 2.37 PYP-2-3 1.00% γ.sub.1 [mPa .Math. s, 20° C.]: 84 B-2O-O5 3.00%
[0585] additionally comprises 0.025% of ST-12.
Example M164
[0586] For the preparation of a PS-VA mixture, 99.9% of the mixture according to Example M163 are mixed with 0.1% of the polymerisable compound of the formula
##STR00507##
Example M165
[0587] For the preparation of a PS-VA mixture, 99.6% of the mixture according to Example M163 are mixed with 0.4% of the polymerisable compound of the formula
##STR00508##
Example M166
[0588] For the preparation of a PS-VA mixture, 99.7% of the mixture according to Example M163 are mixed with 0.3% of the polymerisable compound of the formula
##STR00509##
Example M167
[0589] For the preparation of a PS-VA mixture, 99.8% of the mixture according to Example M163 are mixed with 0.2% of the polymerisable compound of the formula
##STR00510##
Example M168
[0590] The liquid-crystalline mixture
TABLE-US-00107 CC-3-V 36.50% Clearing point [° C.]: 74.1 CC-3-V1 6.00% Δn [589 nm, 20° C.]: 0.1087 CCY-3-O1 7.00% Δε [1 kHz, 20° C.]: −3.2 CCY-3-O2 9.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCY-5-O2 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.8 CLY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.1 PY-1-O4 3.00% K.sub.3 [pN, 20° C.]: 15.7 PY-3-O2 14.00% V.sub.0 [pN, 20° C.]: 2.33 PYP-2-3 9.50% γ.sub.1 [mPa .Math. s, 20° C.]: 87 B-2O-O5 3.00%
[0591] additionally comprises 0.025% of ST-8-1.
Example M169
[0592] The liquid-crystalline mixture
TABLE-US-00108 CY-3-O2 3.50% Clearing point [° C.]: 74.3 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1096 CCY-3-O2 2.50% Δε [1 kHz, 20° C.]: −4.0 CPY-2-O2 8.00% ε.sub.∥ [1 kHz, 20° C.]: 4.0 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.0 PYP-2-3 4.00% K.sub.1 [pN, 20° C.]: 13.0 CLY-3-O2 7.00% K.sub.3 [pN, 20° C.]: 13.7 CLY-3-O3 4.00% V.sub.0 [pN, 20° C.]: 1.94 Y-4O-O4 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 96 PGIY-2-O4 7.00% B-2O-O5 4.00% CC-3-V 38.00%
[0593] additionally comprises 0.025% of ST-8-1.
Example M170
[0594] The liquid-crystalline mixture
TABLE-US-00109 CCY-3-O1 6.00% Clearing point [° C.]: 80 CCY-3-O2 8.00% Δn [589 nm, 20° C.]: 0.1010 CCY-4-O2 4.00% Δε [1 kHz, 20° C.]: −3.7 CCY-5-O2 2.50% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CLY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CLY-3-O3 4.00% K.sub.1 [pN, 20° C.]: 15.0 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 16.3 B-2O-O5 4.00% V.sub.0 [pN, 20° C.]: 2.20 CC-3-V 36.00% γ.sub.1 [mPa .Math. s, 20° C.]: 98 CC-3-V1 7.50% CY-3-O2 2.00% PY-3-O2 12.00%
[0595] additionally comprises 0.025% of ST-8-1.
Example M171
[0596] The liquid-crystalline mixture
TABLE-US-00110 CCY-3-O2 6.00% Clearing point [° C.]: 80.4 CCY-4-O2 3.00% Δn [589 nm, 20° C.]: 0.1014 CLY-3-O2 8.00% Δε [1 kHz, 20° C.]: −3.7 CLY-3-O3 2.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CPY-2-O2 6.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CPY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 13.9 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 15.8 B-2O-O5 5.00% V.sub.0 [pN, 20° C.]: 2.20 CC-3-V 36.00% γ.sub.1 [mPa .Math. s, 20° C.]: 99 CC-3-V1 7.50% CY-3-O2 11.00% CY-5-O2 2.00%
[0597] additionally comprises 0.01% of ST-8-1.
Example M172
[0598] The liquid-crystalline mixture
TABLE-US-00111 BCH-32 3.00% Clearing point [° C.]: 74.7 CC-3-V 15.00% Δn [589 nm, 20° C.]: 0.1086 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.2 CCH-34 4.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCH-35 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCP-3-1 8.00% K.sub.1 [pN, 20° C.]: 13.4 CCP-3-3 5.00% K.sub.3 [pN, 20° C.]: 15.6 CPY-2-O2 10.50% V.sub.0 [pN, 20° C.]: 2.31 CPY-3-O2 10.50% γ.sub.1 [mPa .Math. s, 20° C.]: 109 CY-3-O2 15.00% PY-3-O2 12.00% B-2O-O5 3.00%
[0599] additionally comprises 0.025% of ST-8-1.
Example M173
[0600] The liquid-crystalline mixture
TABLE-US-00112 BCH-32 2.50% Clearing point [° C.]: 74.4 CCP-3-1 8.00% Δn [589 nm, 20° C.]: 0.1093 CCY-3-O1 8.00% Δε [1 kHz, 20° C.]: −3.1 CCY-3-O2 11.00% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCY-5-O2 1.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.6 PGIY-2-O4 5.00% K.sub.1 [pN, 20° C.]: 15.3 B-2O-O5 4.00% K.sub.3 [pN, 20° C.]: 15.8 CC-3-V 5.00% V.sub.0 [pN, 20° C.]: 2.37 CC-3-V1 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 105 CCH-23 11.00% CCH-34 9.00% CCH-35 2.00% CY-3-O2 2.50% PCH-301 1.00% PP-1-2V1 4.50% PY-3-O2 18.00%
[0601] additionally comprises 0.025% of ST-8-1.
Example M174
[0602] The liquid-crystalline mixture
TABLE-US-00113 BCH-32 6.50% Clearing point [° C.]: 74.2 CCP-3-1 8.00% Δn [589 nm, 20° C.]: 0.1086 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −3.2 CCY-5-O2 7.50% ε.sub.∥ [1 kHz, 20° C.]: 3.6 PGIY-2-O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.8 B-2O-O5 3.00% K.sub.1 [pN, 20° C.]: 14.2 CC-3-V 10.00% K.sub.3 [pN, 20° C.]: 15.9 CC-3-V1 8.00% V.sub.0 [pN, 20° C.]: 2.35 CCH-23 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 105 CCH-34 3.00% CY-3-O2 9.00% PCH-301 1.50% PP-1-2V1 1.50% PY-3-O2 16.00%
[0603] additionally comprises 0.025% of ST-8-1.
Example M175
[0604] The liquid-crystalline mixture
TABLE-US-00114 B-2O-O5 3.00% Clearing point [° C.]: 74.5 CC-3-V 15.00% Δn [589 nm, 20° C.]: 0.1092 CC-3-V1 10.00% Δε [1 kHz, 20° C.]: −3.3 CCH-34 9.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCP-3-1 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.9 CCP-3-3 6.00% K.sub.1 [pN, 20° C.]: 14.0 CPY-2-O2 8.50% K.sub.3 [pN, 20° C.]: 15.7 CPY-3-O2 11.00% V.sub.0 [pN, 20° C.]: 2.31 CY-3-O2 15.00% γ.sub.1 [mPa .Math. s, 20° C.]: 102 PGIY-2-O4 4.00% PY-3-O2 10.50%
[0605] additionally comprises 0.025% of ST-8-1.
Example M176
[0606] The liquid-crystalline mixture
TABLE-US-00115 B-2O-O5 3.00% Clearing point [° C.]: 74.5 BCH-32 2.00% Δn [589 nm, 20° C.]: 0.1090 CC-3-V 37.00% Δε [1 kHz, 20° C.]: −3.2 CC-3-V1 6.50% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCY-3-O1 6.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.8 CCY-3-O2 3.50% K.sub.1 [pN, 20° C.]: 14.1 CLY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 15.9 CPY-3-O2 10.50% V.sub.0 [pN, 20° C.]: 2.35 PY-3-O2 18.00% γ.sub.1 [mPa .Math. s, 20° C.]: 86 PYP-2-3 3.00%
[0607] additionally comprises 0.025% of ST-12.
Example M177
[0608] The liquid-crystalline mixture
TABLE-US-00116 B-2O-O5 3.00% Clearing point [° C.]: 74.6 CC-3-V 36.50% Δn [589 nm, 20° C.]: 0.1092 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.2 CCY-3-O1 5.50% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CPY-2-O2 6.50% K.sub.1 [pN, 20° C.]: 14.2 CPY-3-O2 10.50% K.sub.3 [pN, 20° C.]: 15.7 PY-3-O2 16.00% V.sub.0 [pN, 20° C.]: 2.34 PYP-2-3 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 86
[0609] additionally comprises 0.025% of ST-8-1.
Example M178
[0610] The liquid-crystalline mixture
TABLE-US-00117 B-2O-O5 4.00% Clearing point [° C.]: 74.6 BCH-32 0.50% Δn [589 nm, 20° C.]: 0.1036 CC-3-V 33.00% Δε [1 kHz, 20° C.]: −3.4 CC-3-V1 8.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCH-301 1.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CCY-3-1 2.50% K.sub.1 [pN, 20° C.]: 13.4 CCY-3-O1 9.00% K.sub.3 [pN, 20° C.]: 14.9 CCY-4-O2 5.00% V.sub.0 [pN, 20° C.]: 2.21 CPY-2-O2 5.50% γ.sub.1 [mPa .Math. s, 20° C.]: 92 CPY-3-O2 12.50% CY-3-O2 7.00% PY-1-O4 1.50% PY-3-O2 8.00% PYP-2-3 2.50%
[0611] additionally comprises 0.025% of ST-8-1.
Example M179
[0612] The liquid-crystalline mixture
TABLE-US-00118 CC-3-V 34.50% Clearing point [° C.]: 74.7 CC-3-V1 10.00% Δn [589 nm, 20° C.]: 0.1094 CCP-3-1 1.00% Δε [1 kHz, 20° C.]: −3.2 CLY-3-O2 10.00% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-3-O3 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.8 CPY-2-O2 8.00% K.sub.1 [pN, 20° C.]: 13.9 CPY-3-O2 10.50% K.sub.3 [pN, 20° C.]: 15.8 CY-3-O2 4.50% V.sub.0 [pN, 20° C.]: 2.34 PY-3-O2 12.50% γ.sub.1 [mPa .Math. s, 20° C.]: 87 PYP-2-3 3.00% B-2O-O5 3.00%
[0613] additionally comprises 0.04% of ST-3b-1 and 0.02% of ST-9-1.
Example M180
[0614] The liquid-crystalline mixture
TABLE-US-00119 B-2O-O5 3.00% Clearing point [° C.]: 74.8 BCH-32 2.50% Δn [589 nm, 20° C.]: 0.1096 CC-3-V 42.00% Δε [1 kHz, 20° C.]: −3.2 CC-3-V1 1.00% ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCY-3-O2 9.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CLY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.1 CPY-2-O2 2.00% K.sub.3 [pN, 20° C.]: 15.7 CPY-3-O2 10.50% V.sub.0 [pN, 20° C.]: 2.34 PY-3-O2 17.00% γ.sub.1 [mPa .Math. s, 20° C.]: 85 PYP-2-3 3.00%
[0615] additionally comprises 0.025% of ST-8-1.
Example M181
[0616] The liquid-crystalline mixture
TABLE-US-00120 CY-3-O2 3.00% Clearing point [° C.]: 74.9 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1032 CCY-3-O2 4.50% Δε [1 kHz, 20° C.]: −4.0 CPY-2-O2 8.00% ε.sub.∥ [1 kHz, 20° C.]: 3.9 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.9 CLY-3-O2 7.00% K.sub.1 [pN, 20° C.]: 13.2 CLY-3-O3 4.00% K.sub.3 [pN, 20° C.]: 13.9 Y—4O—O4 7.00% V.sub.0 [pN, 20° C.]: 1.96 PGIY-2-O4 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 92 B—2O—O5 4.00% CC-3-V 40.50%
[0617] additionally comprises 0.025% of ST-8-1.
Example M182
[0618] The liquid-crystalline mixture
TABLE-US-00121 CC-3-V 37.50% CCY-3-O1 5.00% CCY-3-O2 13.75% CCY-4-O2 4.25% CPY-3-O2 13.50% CY-3-O2 7.50% PY-3-O2 15.50% B—2O—O4 3.00%
[0619] additionally comprises 0.025% of ST-8-1.
Example M183
[0620] The liquid-crystalline mixture
TABLE-US-00122 CCP—V-1 2.00% Clearing point [° C.]: 75 CCY-3-O1 7.00% Δn [589 nm, 20° C.]: 0.1050 CCY-3-O2 7.00% Δε [1 kHz, 20° C.]: −3.7 CCY-4-O2 3.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCY-5-O2 1.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 14.8 CLY-3-O3 2.00% K.sub.3 [pN, 20° C.]: 15.4 PGIY-2-O4 5.00% V.sub.0 [pN, 20° C.]: 2.15 B—2O—O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 93 CC-3-V 34.00% CC-3-V1 8.00% PY-1-O4 3.50% PY-3-O2 14.00%
[0621] additionally comprises 0.025% of ST-8-1.
Example M184
[0622] The liquid-crystalline mixture
TABLE-US-00123 CCP—V-1 2.00% Clearing point [° C.]: 75 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1013 CCY-3-O2 7.50% Δε [1 kHz, 20° C.]: −3.7 CCY-4-O2 3.50% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CLY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CLY-3-O3 2.00% K.sub.1 [pN, 20° C.]: 14.4 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 15.5 B—2O—O5 5.00% V.sub.0 [pN, 20° C.]: 2.15 CC-3-V 34.00% γ.sub.1 [mPa .Math. s, 20° C.]: 91 CC-3-V1 8.00% CY-3-O2 6.00% PY-3-O2 12.00%
[0623] additionally comprises 0.025% of ST-8-1.
Example M185
[0624] The liquid-crystalline mixture
TABLE-US-00124 CCP—V-1 1.00% Clearing point [° C.]: 75 CCY-3-O1 7.00% Δn [589 nm, 20° C.]: 0.1081 CCY-3-O2 7.00% Δε [1 kHz, 20° C.]: −3.7 CCY-4-O2 3.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCY-5-O2 1.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 14.5 CLY-3-O3 2.00% K.sub.3 [pN, 20° C.]: 15.2 PGIY-2-O4 5.00% V.sub.0 [pN, 20° C.]: 2.14 PYP-2-3 2.50% γ.sub.1 [mPa .Math. s, 20° C.]: 93 B—2O—O5 5.00% CC-3-V 34.00% CC-3-V1 7.50% PY-1-O4 2.00% PY-3-O2 15.00%
[0625] additionally comprises 0.025% of ST-8-1.
Example M186
[0626] The liquid-crystalline mixture
TABLE-US-00125 CY-3-O2 3.00% Clearing point [° C.]: 75.1 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1021 CCY-3-O2 3.00% Δε [1 kHz, 20° C.]: −3.7 CPY-2-O2 8.00% ε.sub.∥ [1 kHz, 20° C.]: 3.8 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CLY-3-O2 7.00% K.sub.1 [pN, 20° C.]: 13.3 CLY-3-O3 4.00% K.sub.3 [pN, 20° C.]: 14.0 Y—4O—O4 6.00% V.sub.0 [pN, 20° C.]: 2.04 PGIY-2-O4 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 87 B—2O—O5 4.00% CC-3-V 43.00%
[0627] additionally comprises 0.025% of ST-8-1.
Example M187
[0628] The liquid-crystalline mixture
TABLE-US-00126 CCY-3-O1 8.00% Clearing point [° C.]: 75.5 CCY-4-O2 3.00% Δn [589 nm, 20° C.]: 0.1024 CLY-3-O2 8.00% Δε [1 kHz, 20° C.]: −3.8 CLY-3-O3 4.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CPY-2-O2 7.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CPY-3-O2 3.00% B—2O—O5 4.00% CC-3-V 41.50% PY-1-O4 5.00% PY-3-O2 11.50% CCY-3-O2 4.50%
[0629] additionally comprises 0.025% of ST-8-1.
Example M188
[0630] The liquid-crystalline mixture
TABLE-US-00127 CCY-3-O1 6.50% Clearing point [° C.]: 79.5 CLY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1070 CPY-2-O2 10.00% Δε [1 kHz, 20° C.]: −3.9 CPY-3-O2 10.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 PYP-2-3 5.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.6 B—2O—O5 4.00% K.sub.1 [pN, 20° C.]: 13.9 CC-3-V 37.00% K.sub.3 [pN, 20° C.]: 15.5 CY-3-O2 14.00% V.sub.0 [pN, 20° C.]: 2.09 CCY-3-O2 1.50% γ.sub.1 [mPa .Math. s, 20° C.]: 104 CY-5-O2 1.50%
[0631] additionally comprises 0.02% of ST-12.
Example M189
[0632] The liquid-crystalline mixture
TABLE-US-00128 CCP—V2-1 5.00% Clearing point [° C.]: 79.5 CLY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1079 CPY-3-O2 9.00% Δε [1 kHz, 20° C.]: −2.0 PGIY-2-O4 2.50% ε.sub.∥ [1 kHz, 20° C.]: 3.2 PYP-2-3 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 5.3 PYP-2-4 5.00% K.sub.1 [pN, 20° C.]: 14.4 B—2O—O5 4.00% K.sub.3 [pN, 20° C.]: 15.5 CC-3-V 43.00% V.sub.0 [pN, 20° C.]: 2.92 CC-3-V1 7.50% γ.sub.1 [mPa .Math. s, 20° C.]: 75 CY-3-O2 6.00%
[0633] additionally comprises 0.03% of ST-2a-1.
Example M190
[0634] The liquid-crystalline mixture
TABLE-US-00129 CCY-3-O1 1.00% Clearing point [° C.]: 79.5 CLY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1151 CLY-3-O3 1.50% Δε [1 kHz, 20° C.]: −4.0 CPY-2-O2 10.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 PGIY-2-O4 5.00% K.sub.1 [pN, 20° C.]: 14.4 PYP-2-3 6.00% K.sub.3 [pN, 20° C.]: 15.7 B—2O—O5 2.50% V.sub.0 [pN, 20° C.]: 2.09 CC-3-V 27.00% γ.sub.1 [mPa .Math. s, 20° C.]: 115 CC-3-V1 8.00% CY-3-O2 11.00% CY-5-O2 6.50% CY-3-O4 1.50%
[0635] additionally comprises 0.025% of ST-8-1.
Example M191
[0636] The liquid-crystalline mixture
TABLE-US-00130 CLY-3-O2 10.00% Clearing point [° C.]: 79.5 CLY-3-O3 2.00% Δn [589 nm, 20° C.]: 0.1157 CPY-2-O2 10.50% Δε [1 kHz, 20° C.]: −4.0 CPY-3-O2 9.50% ε.sub.∥ [1 kHz, 20° C.]: 3.7 PGIY-2-O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 PYP-2-3 5.50% K.sub.1 [pN, 20° C.]: 14.6 B—2O—O5 5.00% K.sub.3 [pN, 20° C.]: 15.5 CC-3-V 30.00% V.sub.0 [pN, 20° C.]: 2.07 CC-3-V1 7.50% γ.sub.1 [mPa .Math. s, 20° C.]: 111 CY-3-O2 11.00% CY-5-O2 4.00%
[0637] additionally comprises 0.025% of ST-8-1.
Example M192
[0638] The liquid-crystalline mixture
TABLE-US-00131 CCY-3-O1 4.00% Clearing point [° C.]: 79.8 CCY-3-O2 8.50% Δn [589 nm, 20° C.]: 0.1013 CCY-4-O2 5.00% Δε [1 kHz, 20° C.]: −3.7 CLY-3-O2 10.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CLY-3-O3 4.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 PGIY-2-O4 5.00% K.sub.1 [pN, 20° C.]: 14.7 PYP-2-3 1.00% K.sub.3 [pN, 20° C.]: 16.3 B—2O—O5 5.00% V.sub.0 [pN, 20° C.]: 2.20 CC-3-V 34.50% γ.sub.1 [mPa .Math. s, 20° C.]: 97 CC-3-V1 8.50% CY-3-O2 5.00% PY-3-O2 9.50%
[0639] additionally comprises 0.025% of ST-8-1.
Example M193
[0640] The liquid-crystalline mixture
TABLE-US-00132 B—2O—O5 4.00% Clearing point [° C.]: 79.9 CC-3-V 32.00% Δn [589 nm, 20° C.]: 0.1036 CCP-3-1 2.00% Δε [1 kHz, 20° C.]: −4.4 CCY-3-O2 8.00% ε.sub.∥ [1 kHz, 20° C.]: 4.0 CCY-4-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.3 CLY-3-O2 6.50% K.sub.1 [pN, 20° C.]: 13.4 CLY-3-O3 6.50% K.sub.3 [pN, 20° C.]: 14.4 CPY-2-O2 8.00% V.sub.0 [pN, 20° C.]: 1.92 CPY-3-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 89 CY-3-O2 2.00% PY-3-O2 10.00% Y—4O—O4 5.00%
[0641] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M194
[0642] The liquid-crystalline mixture
TABLE-US-00133 B—2O—O5 4.00% Clearing point [° C.]: 79.9 CC-3-V 32.00% Δn [589 nm, 20° C.]: 0.1058 CCP-3-1 2.00% Δε [1 kHz, 20° C.]: −4.6 CCY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 14.3 CCY-4-O2 8.00% K.sub.3 [pN, 20° C.]: 15.1 CLY-3-O2 6.50% V.sub.0 [pN, 20° C.]: 1.91 CLY-3-O3 6.50% γ.sub.1 [mPa .Math. s, 20° C.]: 113 CPY-2-O2 8.00% CPY-3-O2 8.00% CY-3-O2 2.00% PY-3-O2 10.00% Y—4O—O4 5.00%
[0643] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M195
[0644] The liquid-crystalline mixture
TABLE-US-00134 CC-3-V 22.00% CC-3-V1 7.00% COY-3-O1 4.00% COY-3-O2 6.00% COY—1V—O2 4.00% CPP—V-3 6.50% BCH-32 5.00% PYP-2-3 8.00% CCOY—V—O2 2.50% CCOY-2-O2 10.00% BCH-52 4.00% CCOY—V—O3 3.00% CCOY-3-O2 11.00% CCOY—1V—O2 4.00% B—2O—O5 3.00%
[0645] additionally comprises 0.03% of ST-3a-1.
Example M196
[0646] The liquid-crystalline mixture
TABLE-US-00135 B-2O-O5 5.00% Clearing point [° C.]: 80 CC-3-V 37.00% Δn [589 nm, 20° C.]: 0.1094 CCP-V-1 4.50% Δε [1 kHz, 20° C.]: −3.7 CCY-3-O1 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CCY-4-O2 5.00% K.sub.1 [pN, 20° C.]: 13.9 CLY-3-O2 8.00% K.sub.3 [pN, 20° C.]: 14.4 CPY-2-O2 9.50% V.sub.0 [pN, 20° C.]: 2.09 PGIY-2-O4 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 106 PY-3-O2 14.00%
[0647] additionally comprises 0.025% of ST-8-1.
Example M197
[0648] The liquid-crystalline mixture
TABLE-US-00136 B-2O-O5 5.00% Clearing point [° C.]: 80.1 BCH-32 7.00% Δn [589 nm, 20° C.]: 0.1096 CC-3-V 34.50% Δε [1 kHz, 20° C.]: −3.7 CCP-V-1 2.00% ε.sub.|| [1 kHz, 20° C.]: 3.9 CCY-3-O1 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CCY-3-O2 4.00% K.sub.1 [pN, 20° C.]: 13.3 CCY-4-O2 2.00% K.sub.3 [pN, 20° C.]: 13.7 CLY-3-O2 8.00% V.sub.0 [pN, 20° C.]: 2.04 CPY-2-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 104 CPY-3-O2 7.00% PGIY-2-O4 6.00% PY-3-O2 2.00% Y-4O-O4 7.50%
[0649] additionally comprises 0.025% of ST-8-1.
Example M198
[0650] The liquid-crystalline mixture
TABLE-US-00137 CCY-3-O1 7.00% Clearing point [° C.]: 80 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1073 CCY-4-O2 6.50% Δε [1 kHz, 20° C.]: −3.9 CCY-5-O2 3.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CLY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.6 PGIY-2-O4 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 90 PYP-2-3 2.00% B-2O-O5 5.00% CC-3-V 33.50% CC-3-V1 7.00% PY-1-O4 5.00% PY-3-O2 10.00%
[0651] additionally comprises 0.025% of ST-8-1.
Example M199
[0652] The liquid-crystalline mixture
TABLE-US-00138 CLY-3-O2 10.00% Clearing point [° C.]: 80 CLY-3-O3 1.50% Δn [589 nm, 20° C.]: 0.1080 CPY-2-O2 4.00% Δε [1 kHz, 20° C.]: −2.4 CPY-3-O2 10.00% ε.sub.|| [1 kHz, 20° C.]: 3.3 PGIY-2-O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 5.7 PYP-2-3 8.00% K.sub.1 [pN, 20° C.]: 14.0 B-2O-O5 4.50% K.sub.3 [pN, 20° C.]: 15.8 CC-3-V 44.50% V.sub.0 [pN, 20° C.]: 2.68 CC-3-V1 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 80 CY-3-O2 2.50% CY-5-O2 2.00%
[0653] additionally comprises 0.025% of ST-8-1.
Example M200
[0654] The liquid-crystalline mixture
TABLE-US-00139 CCY-3-O2 7.00% Clearing point [° C.]: 80 CCY-4-O2 2.00% Δn [589 nm, 20° C.]: 0.1009 CLY-3-O2 8.00% Δε [1 kHz, 20° C.]: −3.7 CLY-3-O3 4.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-2-O2 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CPY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 14.4 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 16.4 PYP-2-3 1.00% V.sub.0 [pN, 20° C.]: 2.21 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 99 CC-3-V 35.00% CC-3-V1 8.00% CY-3-O2 12.00% CY-5-O2 2.00%
[0655] additionally comprises 0.025% of ST-8-1.
Example M201
[0656] The liquid-crystalline mixture
TABLE-US-00140 CC-3-V 37.50% Clearing point [° C.]: 80.2 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1097 CCY-3-O2 3.00% Δε [1 kHz, 20° C.]: −3.9 CCY-4-O2 7.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CLY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 13.5 CPY-3-O2 8.00% K.sub.3 [pN, 20° C.]: 14.5 PY-1-O4 3.50% V.sub.0 [pN, 20° C.]: 1.08 PY-3-O2 12.00% γ.sub.1 [mPa .Math. s, 20° C.]: 110 PGIY-2-O4 2.00% B-2O-O5 4.00%
[0657] additionally comprises 0.025% of ST-8-1.
Example M202
[0658] The liquid-crystalline mixture
TABLE-US-00141 B-2O-O5 4.00% Clearing point [° C.]: 80.4 CC-3-V 24.50% Δn [589 nm, 20° C.]: 0.1030 CC-3-V1 5.00% Δε [1 kHz, 20° C.]: −4.4 CCP-3-1 3.00% ε.sub.|| [1 kHz, 20° C.]: 4.0 CCY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.4 CCY-4-O2 8.00% K.sub.1 [pN, 20° C.]: 13.3 CLY-3-O2 6.00% K.sub.3 [pN, 20° C.]: 14.3 CLY-3-O3 6.00% V.sub.0 [pN, 20° C.]: 1.91 CPY-2-O2 6.50% γ.sub.1 [mPa .Math. s, 20° C.]: 96 CPY-3-O2 8.00% CY-3-O2 8.00% PYP-2-3 5.00% Y-4O-O4 8.00%
[0659] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M203
[0660] The liquid-crystalline mixture
TABLE-US-00142 BCH-32 0.50% Clearing point [° C.]: 80.4 CC-3-V 37.00% Δn [589 nm, 20° C.]: 0.1195 CCY-3-O1 5.00% Δε [1 kHz, 20° C.]: −3.9 CCY-3-O2 3.50% ε.sub.|| [1 kHz, 20° C.]: 3.8 CLY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 13.5 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.5 PY-3-O2 14.00% V.sub.0 [pN, 20° C.]: 2.04 PGIY-2-O4 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 114 B-2O-O5 4.00%
[0661] additionally comprises 0.01% of ST-8-1.
Example M204
[0662] The liquid-crystalline mixture
TABLE-US-00143 CCY-3-O2 6.00% Clearing point [° C.]: 80.4 CCY-4-O2 3.00% Δn [589 nm, 20° C.]: 0.1014 CLY-3-O2 8.00% Δε [1 kHz, 20° C.]: −3.7 CLY-3-O3 2.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-2-O2 6.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CPY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 13.9 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 15.8 B-2O-O5 5.00% V.sub.0 [pN, 20° C.]: 2.20 CC-3-V 36.00% γ.sub.1 [mPa .Math. s, 20° C.]: 99 CC-3-V1 7.50% CY-3-O2 11.00% CY-5-O2 2.00%
[0663] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M205
[0664] The liquid-crystalline mixture
TABLE-US-00144 CC-3-V 25.00% Clearing point [° C.]: 80.5 CC-3-V1 7.00% Δn [589 nm, 20° C.]: 0.0995 CCP-3-1 7.00% Δε [1 kHz, 20° C.]: −3.8 CCY-3-O1 4.50% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 6.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CCY-4-O2 5.00% K.sub.1 [pN, 20° C.]: 13.7 CCY-5-O2 4.00% K.sub.3 [pN, 20° C.]: 15.8 CLY-3-O2 8.00% V.sub.0 [pN, 20° C.]: 2.12 CY-3-O2 12.00% γ.sub.1 [mPa .Math. s, 20° C.]: 111 CY-3-O4 4.00% PY-3-O2 7.00% PGIY-2-O4 6.00% B-2O-O5 4.00%
[0665] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M206
[0666] The liquid-crystalline mixture
TABLE-US-00145 CC-3-V 26.00% Clearing point [° C.]: 80.8 CC-3-V1 7.00% Δn [589 nm, 20° C.]: 0.1099 CCP-3-1 6.00% Δε [1 kHz, 20° C.]: −3.9 CCY-3-O1 2.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 7.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CCY-4-O2 7.00% K.sub.1 [pN, 20° C.]: 14.2 CCY-5-O2 4.00% K.sub.3 [pN, 20° C.]: 15.6 CLY-3-O2 8.00% V.sub.0 [pN, 20° C.]: 2.12 CY-3-O2 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 121 PY-1-O4 5.00% PY-3-O2 12.00% PGIY-2-O4 8.00% B-2O-O5 4.00%
[0667] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M207
[0668] The liquid-crystalline mixture
TABLE-US-00146 CC-3-V 44.50% Clearing point [° C.]: 73.5 CCY-3-O1 3.00% Δn [589 nm, 20° C.]: 0.1009 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −3.5 CCY-4-O2 3.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-2-O2 9.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.1 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 13.1 CY-3-O2 3.50% K.sub.3 [pN, 20° C.]: 14.4 PY-3-O2 11.00% V.sub.0 [pN, 20° C.]: 2.16 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 81
[0669] additionally comprises 0.025% of ST-8-1.
TABLE-US-00147 Comparison VHR after UV M207 without stabiliser 54% M207 with stabiliser 76% (0.025% of ST-8-1)
Example M208
[0670] The liquid-crystalline mixture
TABLE-US-00148 CCY-3-O1 8.00% Clearing point [° C.]: 82 CCY-3-O2 1.00% Δn [589 nm, 20° C.]: 0.1081 CLY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.5 CPY-2-O2 9.50% ε.sub.|| [1 kHz, 20° C.]: 3.6 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.2 PGIY-2-O4 5.00% K.sub.1 [pN, 20° C.]: 14.4 PYP-2-3 1.00% K.sub.3 [pN, 20° C.]: 15.3 B-2O-O5 5.00% V.sub.0 [pN, 20° C.]: 2.20 CC-3-V 44.50% γ.sub.1 [mPa .Math. s, 20° C.]: 95 PY-1-O4 4.00% Y-4O-O4 2.00%
[0671] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M209
[0672] The liquid-crystalline mixture
TABLE-US-00149 B-2O-O5 4.00% Clearing point [° C.]: 84.6 CC-3-V 31.00% Δn [589 nm, 20° C.]: 0.1069 CC-3-V1 4.00% Δε [1 kHz, 20° C.]: −3.8 CCP-3-1 3.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 8.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CCY-4-O2 6.00% K.sub.1 [pN, 20° C.]: 14.1 CLY-3-O2 6.00% K.sub.3 [pN, 20° C.]: 15.0 CLY-3-O3 6.00% V.sub.0 [pN, 20° C.]: 2.09 CPY-2-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 88 CPY-3-O2 8.00% PY-3-O2 8.00% PY-4-O2 3.00% PYP-2-4 1.50% Y-4O-O4 3.00%
[0673] additionally comprises 0.04% of ST-3b-1 and 0.015% of ST-9-1.
Example M210
[0674] The liquid-crystalline mixture
TABLE-US-00150 CCY-3-O2 10.00% Clearing point [° C.]: 85 CCY-5-O2 7.00% Δn [589 nm, 20° C.]: 0.1047 CPY-2-O2 10.00% Δε [1 kHz, 20° C.]: −3.4 CPY-3-O2 10.00% ε.sub.|| [1 kHz, 20° C.]: 3.5 PYP-2-3 5.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.9 B-2O-O5 4.00% K.sub.1 [pN, 20° C.]: 14.6 CC-3-V 32.00% K.sub.3 [pN, 20° C.]: 17.4 CC-3-V1 10.00% V.sub.0 [pN, 20° C.]: 2.37 CY-3-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 108 CY-5-O2 1.50%
[0675] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M211
[0676] The liquid-crystalline mixture
TABLE-US-00151 CC-3-V 35.00% Clearing point [° C.]: 86 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1208 CCY-3-O2 7.50% Δε [1 kHz, 20° C.]: −4.2 CLY-3-O2 8.00% ε.sub.|| [1 kHz, 20° C.]: 3.8 CPY-2-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.0 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.3 PY-3-O2 12.50% K.sub.3 [pN, 20° C.]: 15.6 PGIY-2-O4 8.00% V.sub.0 [pN, 20° C.]: 2.04 B-2O-O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 129
[0677] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M212
[0678] The liquid-crystalline mixture
TABLE-US-00152 CC-3-V 35.00% Clearing point [° C.]: 86.1 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1103 CCY-3-O2 6.00% Δε [1 kHz, 20° C.]: −4.1 CCY-3-O3 2.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-4-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.8 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 14.2 CPY-2-O2 10.00% K.sub.3 [pN, 20° C.]: 15.7 CPY-3-O2 9.50% V.sub.0 [pN, 20° C.]: 2.06 PY-1-O4 3.50% γ.sub.1 [mPa .Math. s, 20° C.]: 125 PY-3-O2 11.00% B-2O-O5 4.00%
[0679] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M213
[0680] The liquid-crystalline mixture
TABLE-US-00153 CCY-3-O1 3.50% Clearing point [° C.]: 86.5 CCY-3-O2 4.50% Δn [589 nm, 20° C.]: 0.1053 CLY-3-O2 9.00% Δε [1 kHz, 20° C.]: −3.4 CPY-2-O2 10.50% ε.sub.|| [1 kHz, 20° C.]: 3.5 CPY-3-O2 11.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.9 PYP-2-3 3.50% K.sub.1 [pN, 20° C.]: 14.8 CC-3-V 32.00% K.sub.3 [pN, 20° C.]: 17.8 CC-3-V1 12.00% V.sub.0 [pN, 20° C.]: 2.41 CY-3-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 105 B-2O-O5 4.00%
[0681] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M214
[0682] The liquid-crystalline mixture
TABLE-US-00154 CC-3-V 22.50% Clearing point [° C.]: 97.2 CC-3-V1 7.00% Δn [589 nm, 20° C.]: 0.1005 CCP-3-1 2.00% Δε [1 kHz, 20° C.]: −4.6 CCY-3-O1 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCY-3-O2 7.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.2 CCY-3-O3 5.00% K.sub.1 [pN, 20° C.]: 15.8 CCY-4-O2 7.00% K.sub.3 [pN, 20° C.]: 18.6 CCY-5-O2 5.00% V.sub.0 [pN, 20° C.]: 2.13 CLY-3-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 172 CPY-3-O2 8.00% CY-3-O2 12.00% CY-5-O2 4.50% PGIY-2-O4 3.00% B-2O-O5 4.00%
[0683] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M215
[0684] The liquid-crystalline mixture
TABLE-US-00155 CC-3-V 21.50% Clearing point [° C.]: 98.6 CC-3-V1 7.00% Δn [589 nm, 20° C.]: 0.1103 CCP-3-1 3.00% Δε [1 kHz, 20° C.]: −4.6 CCY-3-O1 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 7.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.3 CCY-4-O2 7.00% K.sub.1 [pN, 20° C.]: 16.3 CCY-5-O2 4.00% K.sub.3 [pN, 20° C.]: 18.7 CLY-3-O2 8.00% V.sub.0 [pN, 20° C.]: 2.12 CPY-3-O2 10.50% γ.sub.1 [mPa .Math. s, 20° C.]: 175 CY-3-O2 12.00% CY-5-O2 3.00% PGIY-2-O4 8.00% B-2O-O5 4.00%
[0685] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M216
[0686] The liquid-crystalline mixture
TABLE-US-00156 CC-3-V1 7.00% Clearing point [° C.]: 109 CCP-3-1 10.00% Δn [589 nm, 20° C.]: 0.1012 CCP-3-3 6.50% Δε [1 kHz, 20° C.]: −5.2 CCY-3-O1 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.9 CCY-3-O3 7.50% K.sub.1 [pN, 20° C.]: 18.2 CCY-4-O2 8.00% K.sub.3 [pN, 20° C.]: 21.4 CCY-5-O2 4.00% V.sub.0 [pN, 20° C.]: 2.13 CCY-3-1 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 287 CLY-3-O2 8.00% CY-3-O2 12.00% CY-3-O4 14.00% B-2O-O5 4.00%
[0687] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M217
[0688] The liquid-crystalline mixture
TABLE-US-00157 CC-3-V 10.75% Clearing point [° C.]: 111.8 CC-3-V1 3.50% Δn [589 nm, 20° C.]: 0.1104 CCP-3-1 7.50% Δε [1 kHz, 20° C.]: −5.2 CCY-3-O1 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 7.50% ε.sub.⊥ [1 kHz, 20° C.]: 8.9 CCY-4-O2 7.50% K.sub.1 [pN, 20° C.]: 17.9 CCY-5-O2 4.50% K.sub.3 [pN, 20° C.]: 21.0 CLY-3-O2 8.00% V.sub.0 [pN, 20° C.]: 2.13 CPY-3-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 267 CY-3-O2 12.00% CY-5-O2 5.00% PGIY-2-O4 4.00% B-2O-O5 4.00% CCP-3-3 1.75% CCY-3-O3 3.00% CCY-2-1 4.00% CCY-3-1 4.00%
[0689] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M218
[0690] The liquid-crystalline mixture
TABLE-US-00158 CCP-3-1 12.00% Clearing point [° C.]: 126 CCP-3-3 3.50% Δn [589 nm, 20° C.]: 0.1103 CCY-3-O1 5.00% Δε [1 kHz, 20° C.]: −5.8 CCY-3-O2 8.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O3 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 9.5 CCY-4-O2 8.00% K.sub.1 [pN, 20° C.]: 20.3 CCY-5-O2 5.00% K.sub.3 [pN, 20° C.]: 23.8 CCY-2-1 8.00% V.sub.0 [pN, 20° C.]: 2.14 CCY-3-1 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 422 CLY-3-O2 8.00% CPY-3-O2 5.50% CY-3-O2 12.00% CY-5-O2 7.00% B-2O-O5 4.00%
[0691] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M219
[0692] The liquid-crystalline mixture
TABLE-US-00159 CC-3-V 12.50% Clearing point [° C.]: 110.3 CC-3-V1 6.50% Δn [589 nm, 20° C.]: 0.1100 CCP-3-1 12.50% Δε [1 kHz, 20° C.]: −4.8 CCY-3-O1 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCY-3-O2 7.50% ε.sub.⊥ [1 kHz, 20° C.]: 8.4 CCY-4-O2 3.00% K.sub.1 [pN, 20° C.]: 17.9 CCY-5-O2 3.50% K.sub.3 [pN, 20° C.]: 20.8 CLY-2-O4 5.00% V.sub.0 [pN, 20° C.]: 2.22 CLY-3-O2 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 233 CLY-3-O3 6.00% CPY-3-O2 8.00% CY-3-O2 12.00% CY-5-O2 4.00% PGIY-2-O4 3.50% B-2O-O5 4.00%
[0693] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M220
[0694] The liquid-crystalline mixture
TABLE-US-00160 CC-3-V 14.00% Clearing point [° C.]: 111 CC-3-V1 6.00% Δn [589 nm, 20° C.]: 0.1102 CCP-3-1 7.00% Δε [1 kHz, 20° C.]: −5.2 CCY-3-O1 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.9 CCY-4-O2 5.50% K.sub.1 [pN, 20° C.]: 18.5 CCY-5-O2 2.00% K.sub.3 [pN, 20° C.]: 20.5 CLY-2-O4 7.00% V.sub.0 [pN, 20° C.]: 2.10 CLY-3-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 241 CLY-3-O3 7.00% CPY-3-O2 10.00% CY-3-O2 12.00% CY-5-O2 2.50% PGIY-2-O4 2.00% B-2O-O5 4.00%
Example M221
[0695] The liquid-crystalline mixture
TABLE-US-00161 CC-3-V 12.25% Clearing point [° C.]: 110.9 CC-3-V1 6.00% Δn [589 nm, 20° C.]: 0.1101 CCP-3-1 11.00% Δε [1 kHz, 20° C.]: −5.0 CCY-3-O1 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCY-3-O2 7.75% ε.sub.⊥ [1 kHz, 20° C.]: 8.6 CCY-4-O2 5.00% K.sub.1 [pN, 20° C.]: 18.5 CCY-5-O2 3.50% K.sub.3 [pN, 20° C.]: 20.8 CLY-2-O4 5.00% V.sub.0 [pN, 20° C.]: 2.16 CLY-3-O2 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 240 CLY-3-O3 6.00% CPY-3-O2 8.00% CY-3-O2 12.00% CY-5-O2 4.25% PGIY-2-O4 3.25% B-2O-O5 4.00%
[0696] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M222
[0697] The liquid-crystalline mixture
TABLE-US-00162 CC-3-V 12.00% Clearing point [° C.]: 111.6 CC-3-V1 5.50% Δn [589 nm, 20° C.]: 0.1101 CCP-3-1 9.50% Δε [1 kHz, 20° C.]: −5.2 CCY-3-O1 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.9 CCY-4-O2 7.00% K.sub.1 [pN, 20° C.]: 18.6 CCY-5-O2 3.50% K.sub.3 [pN, 20° C.]: 20.6 CLY-2-O4 5.00% V.sub.0 [pN, 20° C.]: 2.11 CLY-3-O2 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 252 CLY-3-O3 6.00% CPY-3-O2 8.00% CY-3-O2 12.00% CY-5-O2 4.50% PGIY-2-O4 3.00% B-2O-O5 4.00%
[0698] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M223
[0699] The liquid-crystalline mixture
TABLE-US-00163 CC-3-V1 8.50% Clearing point [° C.]: 74 CCH-23 18.00% Δn [589 nm, 20° C.]: 0.0975 CCH-34 3.00% Δε [1 kHz, 20° C.]: −3.4 CCH-35 6.00% ε.sub.|| [1 kHz, 20° C.]: 3.5 CCP-3-1 10.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.9 CCY-3-O2 11.00% K.sub.1 [pN, 20° C.]: 15.1 CCY-3-O1 9.00% K.sub.3 [pN, 20° C.]: 15.5 CPY-3-O2 4.50% V.sub.0 [pN, 20° C.]: 2.27 CY-3-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 101 PY-3-O2 13.00% PY-4-O2 5.50% B-2O-O5 3.00%
[0700] additionally comprises 0.025% of ST-8-1.
TABLE-US-00164 Comparison VHR after UV M223 without stabiliser 88% M223 with stabiliser 92% (0.025% of ST-8-1)
Example M224
[0701] The liquid-crystalline mixture
TABLE-US-00165 CC-3-V1 8.50% Clearing point [° C.]: 74 CCH-23 18.00% Δn [589 nm, 20° C.]: 0.0975 CCH-34 3.00% Δε [1 kHz, 20° C.]: −3.4 CCH-35 6.00% ε.sub.|| [1 kHz, 20° C.]: 3.5 CCP-3-1 10.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.9 CCY-3-O2 11.00% K.sub.1 [pN, 20° C.]: 15.1 CCY-3-O1 9.00% K.sub.3 [pN, 20° C.]: 15.5 CPY-3-O2 4.50% V.sub.0 [pN, 20° C.]: 2.27 CY-3-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 101 PY-3-O2 13.00% PY-4-O2 5.50% B-2O-O5 3.00%
[0702] additionally comprises 0.01% of ST-9-1.
TABLE-US-00166 Comparison VHR after UV M224 without stabiliser 88% M224 with stabiliser 93% (0.025% of ST-9-1)
Example M225
[0703] The liquid-crystalline mixture
TABLE-US-00167 CY-3-O2 3.00% Clearing point [° C.]: 75.1 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.10215 CCY-3-O2 3.00% Δε [1 kHz, 20° C.]: −3.7 CPY-2-O2 8.00% ε.sub.|| [1 kHz, 20° C.]: 3.8 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CLY-3-O2 7.00% K.sub.1 [pN, 20° C.]: 13.3 CLY-3-O3 4.00% K.sub.3 [pN, 20° C.]: 14.0 Y-4O-O4 6.00% V.sub.0 [pN, 20° C.]: 2.04 PGIY-2-O4 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 87 B-2O-O5 4.00% CC-3-V 43.00%
[0704] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M226
[0705] The liquid-crystalline mixture
TABLE-US-00168 CY-3-O2 3.00% Clearing point [° C.]: 74.9 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1032 CCY-3-O2 4.50% Δε [1 kHz, 20° C.]: −4.0 CPY-2-O2 8.00% ε.sub.|| [1 kHz, 20° C.]: 3.9 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.9 CLY-3-O2 7.00% K.sub.1 [pN, 20° C.]: 13.2 CLY-3-O3 4.00% K.sub.3 [pN, 20° C.]: 13.9 Y-4O-O4 7.00% V.sub.0 [pN, 20° C.]: 1.96 PGIY-2-O4 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 92 B-2O-O5 4.00% CC-3-V 40.50%
[0706] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M227
[0707] The liquid-crystalline mixture
TABLE-US-00169 CY-3-O2 3.50% Clearing point [° C.]: 74.3 CCY-3-O1 5.00% Δn [589 nm, 20° C.]: 0.1096 CCY-3-O2 2.50% Δε [1 kHz, 20° C.]: −4.0 CPY-2-O2 8.00% ε.sub.|| [1 kHz, 20° C.]: 4.0 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.0 PYP-2-3 4.00% K.sub.1 [pN, 20° C.]: 13.0 CLY-3-O2 7.00% K.sub.3 [pN, 20° C.]: 13.7 CLY-3-O3 4.00% V.sub.0 [pN, 20° C.]: 1.94 Y-4O-O4 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 96 PGIY-2-O4 7.00% B-2O-O5 4.00% CC-3-V 38.00%
[0708] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M228
[0709] The liquid-crystalline mixture
TABLE-US-00170 B-2O-O5 4.00% Clearing point [° C.]: 84.6 CC-3-V 31.00% Δn [589 nm, 20° C.]: 0.1069 CC-3-V1 4.00% Δε [1 kHz, 20° C.]: −3.8 CCP-3-1 3.00% ε.sub.|| [1 kHz, 20° C.]: 3.7 CCY-3-O2 8.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CCY-4-O2 6.00% K.sub.1 [pN, 20° C.]: 14.1 CLY-3-O2 6.00% K.sub.3 [pN, 20° C.]: 15.0 CLY-3-O3 6.00% V.sub.0 [pN, 20° C.]: 2.09 CPY-2-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 88 CPY-3-O2 8.00% PY-3-O2 8.00% PY-4-O2 3.00% PYP-2-4 1.50% Y-4O-O4 3.00%
[0710] additionally comprises 0.04% of ST-3b-1 and 0.015% ST-9-1.
Example M229
[0711] The liquid-crystalline mixture
TABLE-US-00171 CC-3-V 5.00% Clearing point [° C.]: 75.5 CC-3-V1 8.00% Δn [589 nm, 20° C.]: 0.1082 CCH-23 11.50% Δε [1 kHz, 20° C.]: −3.3 CCH-34 5.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCP-3-1 10.00% K.sub.1 [pN, 20° C.]: 15.2 CCP-3-3 5.00% K.sub.3 [pN, 20° C.]: 16.0 CCY-3-O1 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 104 CCY-3-O2 11.50% V.sub.0 [20° C., V]: 2.31 CY-3-O2 14.50% PY-3-O2 8.00% PYP-2-3 8.00% B-2O-O5 3.50% B(S)-2O-O5 3.50% PP-1-2V1 2.50%
[0712] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M230
[0713] The liquid-crystalline mixture
TABLE-US-00172 CC-3-V 20.00% Clearing point [° C.]: 99 CC-3-V1 6.00% Δn [589 nm, 20° C.]: 0.1008 CCP-3-1 5.50% Δε [1 kHz, 20° C.]: −4.7 CCY-3-O1 4.00% ε.sub.|| [1 kHz, 20° C.]: 3.6 CCY-3-O2 5.00% K.sub.1 [pN, 20° C.]: 16.4 CCY-3-O3 4.00% K.sub.3 [pN, 20° C.]: 18.6 CCY-4-O2 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 183 CCY-5-O2 3.00% V.sub.0 [20° C., V]: 2.12 CLY-2-O4 4.00% CLY-3-O2 7.00% CLY-3-O3 5.00% CPY-3-O2 10.00% CY-3-O2 10.00% CY-5-O2 8.00% B-2O-O5 4.00%
[0714] additionally comprises 0.04% of ST-3b-1 and 0.01% of ST-9-1.
Example M231
[0715] For the preparation of a PS (polymer-stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.7% of the mixture according to Example M230 are mixed with 0.001% of Irganox 1076 and 0.3% of the polymerisable compound of the formula
##STR00511##
Example M232
[0716] The liquid-crystalline mixture
TABLE-US-00173 CC-3-V 42.00% Clearing point [° C.]: 74 CCY-3-O2 11.00% Δn [589 nm, 20° C.]: 0.1008 CPY-2-O2 10.00% Δε [1 kHz, 20° C.]: −3.7 CPY-3-O2 11.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CY-3-O2 17.00% K.sub.1 [pN, 20° C.]: 12.8 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 14.6 B(S)-2O-O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 86 V.sub.0 [20° C., V]: 2.11
[0717] additionally comprises 0.03% of ST-8-1.
Example M233
[0718] The liquid-crystalline mixture
TABLE-US-00174 CY-3-O2 17.00% Clearing point [° C.]: 74.4 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1116 CLY-3-O2 7.00% Δε [1 kHz, 20° C.]: −3.7 CPY-2-O2 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 13.5 PYP-2-3 6.50% K.sub.3 [pN, 20° C.]: 15.2 PGIY-2-O4 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 97 B-2O-O5 4.00% V.sub.0 [20° C., V]: 2.14 CC-3-V 33.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CC-3-V1 6.50%
[0719] additionally comprises 0.025% of ST-8-1.
Example M234
[0720] The liquid-crystalline mixture
TABLE-US-00175 CY-3-O2 15.00% Clearing point [° C.]: 80.1 CY-5-O2 3.50% Δn [589 nm, 20° C.]: 0.0951 CCY-3-O1 5.00% Δε [1 kHz, 20° C.]: −4.0 CCY-3-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 CCY-3-O3 5.50% K.sub.1 [pN, 20° C.]: 13.9 CCY-4-O2 6.00% K.sub.3 [pN, 20° C.]: 15.5 PYP-2-3 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 111 CLY-3-O2 7.00% V.sub.0 [20° C., V]: 2.05 CLY-3-O3 7.00% B-2O-O5 4.00% CC-3-V 35.00%
[0721] additionally comprises 0.015% of ST-9-1.
Example M235
[0722] The liquid-crystalline mixture
TABLE-US-00176 B-2O-O5 4.00% Clearing point [° C.]: 74.2 BCH-32 8.00% Δn [589 nm, 20° C.]: 0.1091 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.1 CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-34 8.00% K.sub.1 [pN, 20° C.]: 14.5 CCH-35 7.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-3-1 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 108 CCP-V2-1 5.00% V.sub.0 [20° C., V]: 2.41 CCY-3-O2 10.50% CLY-3-O2 1.00% CPY-3-O2 2.50% CY-3-O2 11.50% PCH-301 5.50% PY-3-O2 18.00%
[0723] additionally comprises 0.005% of ST-3a-1.
Example M235a
[0724] For the preparation of a PS (polymer stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.65% of the mixture according to Example M235 are mixed with 0.35% of the polymerisable compound of the formula
##STR00512##
Example M236
[0725] The liquid-crystalline mixture
TABLE-US-00177 CLY-2-O4 2.00% Clearing point [° C.]: 79.5 CLY-3-O2 7.50% Δn [589 nm, 20° C.]: 0.1151 CLY-3-O3 4.50% Δε [1 kHz, 20° C.]: −4.0 CPY-2-O2 10.00% ε.sub.|| [1 kHz, 20° C.]: CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 PGIY-2-O4 8.00% K.sub.1 [pN, 20° C.]: 14.3 PYP-2-3 3.00% K.sub.3 [pN, 20° C.]: 14.9 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 107 CC-3-V 38.50% V.sub.0 [20° C., V]: 2.02 CY-3-O2 11.50%
[0726] additionally comprises 0.015% of ST-3a-1.
Example M236
[0727] For the preparation of a PS (polymer stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.75% of the mixture according to Example M236 are mixed with 0.25% of the polymerisable compound of the formula
##STR00513##
Example M237
[0728] The liquid-crystalline mixture
TABLE-US-00178 CCY-3-O1 3.50% Clearing point [° C.]: 84.5 CCY-3-O2 7.50% Δn [589 nm, 20° C.]: 0.1184 CCY-4-O2 8.00% Δε [1 kHz, 20° C.]: −4.8 CCY-5-O2 7.50% ε.sub.⊥ [1 kHz, 20° C.]: 8.7 CLY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 16.7 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 17.3 PYP-2-3 3.00% V.sub.0 [20° C., V]: 1.99 B-2O-O5 5.00% CC-3-V 23.00% CC-3-V1 8.00% PY-1-O4 5.50% PY-3-O2 14.00%
[0729] additionally comprises 0.03% of ST-3a-1.
Example M238
[0730] The liquid-crystalline mixture
TABLE-US-00179 CCY-3-O1 3.00% Clearing point [° C.]: 84.5 CCY-3-O2 8.00% Δn [589 nm, 20° C.]: 0.1223 CCY-4-O2 8.00% Δε [1 kHz, 20° C.]: −4.9 CCY-5-O2 7.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.8 CLY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 16.7 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 17.3 PYP-2-3 4.50% V.sub.0 [20° C., V]: 1.98 B-2O-O5 5.00% CC-3-V 21.50% CC-3-V1 8.00% PY-1-O4 5.00% PY-3-O2 15.00%
[0731] additionally comprises 0.03% of ST-3a-1.
Example M239
[0732] The liquid-crystalline mixture
TABLE-US-00180 CCY-3-O2 8.50% Clearing point [° C.]: 79.0 CCY-4-O2 8.00% Δn [589 nm, 20° C.]: 0.1125 CLY-2-O4 5.00% Δε [1 kHz, 20° C.]: −4.5 CLY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.3 CLY-3-O3 5.00% K.sub.1 [pN, 20° C.]: 15.6 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 15.6 PYP-2-3 1.00% γ.sub.1 [mPa .Math. s, 20° C.]: 116 B-2O-O5 5.00% V.sub.0 [20° C., V]: 1.96 CC-3-V 27.50% CC-3-V1 8.00% PY-1-O4 4.00% PY-3-O2 15.00%
[0733] additionally comprises 0.025% of ST-3a-1.
Example M240
[0734] The liquid-crystalline mixture
TABLE-US-00181 CCY-3-O1 5.00% Clearing point [° C.]: 79.5 CCY-3-O2 8.00% Δn [589 nm, 20° C.]: 0.1047 CCY-4-O2 8.00% Δε [1 kHz, 20° C.]: −4.4 CLY-2-O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.2 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 15.5 CLY-3-O3 5.00% K.sub.3 [pN, 20° C.]: 15.9 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 115 CC-3-V 28.50% V.sub.0 [20° C., V]: 1.99 CC-3-V1 7.50% PY-1-O4 5.00% PY-3-O2 15.00%
[0735] additionally comprises 0.025% of ST-3a-1.
Example M241
[0736] The liquid-crystalline mixture
TABLE-US-00182 CCY-3-O1 2.00% Clearing point [° C.]: 79.0 CCY-3-O2 8.00% Δn [589 nm, 20° C.]: 0.1048 CCY-4-O2 8.00% Δε [1 kHz, 20° C.]: −4.1 CLY-2-O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.9 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 15.6 CLY-3-O3 5.00% K.sub.3 [pN, 20° C.]: 15.7 PGIY-2-O4 2.50% γ.sub.1 [mPa .Math. s, 20° C.]: 107 B-2O-O5 5.00% CC-3-V 31.00% CC-3-V1 8.00% PY-1-O4 2.50% PY-3-O2 15.00%
[0737] additionally comprises 0.02% of ST-2a-1.
Example M242
[0738] The liquid-crystalline mixture
TABLE-US-00183 CCY-3-O2 8.00% Clearing point [° C.]: 79.5 CCY-4-O2 3.50% Δn [589 nm, 20° C.]: 0.1050 CCY-5-O2 3.50% Δε [1 kHz, 20° C.]: −3.8 CLY-2-O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 15.6 CLY-3-O3 5.00% K.sub.3 [pN, 20° C.]: 15.8 PGIY-2-O4 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 102 B-2O-O5 5.00% V.sub.0 [20° C., V]: 2.13 CC-3-V 34.00% CC-3-V1 8.00% PY-3-O2 15.00%
[0739] additionally comprises 0.025% of ST-3a-1.
Example M243
[0740] The liquid-crystalline mixture
TABLE-US-00184 CCY-3-O2 8.00% Clearing point [° C.]: 75.0 CCY-4-O2 8.00% Δn [589 nm, 20° C.]: 0.1047 CLY-2-O4 5.00% Δε [1 kHz, 20° C.]: −4.2 CLY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.0 CLY-3-O3 5.00% K.sub.1 [pN, 20° C.]: 15.0 PGIY-2-O4 2.00% K.sub.3 [pN, 20° C.]: 15.2 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 105 CC-3-V 30.00% V.sub.0 [20° C., V]: 1.99 CC-3-V1 8.00% CY-5-O2 2.00% PY-1-O4 4.00% PY-3-O2 15.00%
[0741] additionally comprises 0.03% of ST-3a-1.
Example M244
[0742] The liquid-crystalline mixture
TABLE-US-00185 CCP-3-1 7.00% Clearing point [° C.]: 75.5 CLY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.0992 CPY-2-O2 9.50% Δε [1 kHz, 20° C.]: −3.2 CPY-3-O2 10.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 B-2O-O5 5.00% K.sub.1 [pN, 20° C.]: 13.1 CC-3-V 42.50% K.sub.3 [pN, 20° C.]: 15.4 CY-3-O2 12.00% γ.sub.1 [mPa .Math. s, 20° C.]: 85 PY-3-O2 3.50% V.sub.0 [20° C., V]: 2.32
[0743] additionally comprises 0.03% of ST-3a-1.
Example M245
[0744] The liquid-crystalline mixture
TABLE-US-00186 CC-3-V 32.50% Clearing point [° C.]: 79.8 CC-3-V1 2.00% Δn [589 nm, 20° C.]: 0.1043 CCP-3-1 2.50% Δε [1 kHz, 20° C.]: −3.5 CCY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 13.7 CCY-4-O2 3.00% K.sub.3 [pN, 20° C.]: 14.8 CLY-3-O2 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 102 CLY-3-O3 6.00% V.sub.0 [20° C., V]: 2.16 CPY-2-O2 8.00% CPY-3-O2 8.00% CY-3-O2 9.00% PYP-2-3 6.00% PYP-2-4 3.00% Y-4O-O4 6.00%
[0745] additionally comprises 0.04% of ST-3b-1 and 0.015% of ST-9-1.
Example M246
[0746] The liquid-crystalline mixture
TABLE-US-00187 CY-3-O2 10.00% Clearing point [° C.]: 69.7 PY-3-O2 13.50% Δn [589 nm, 20° C.]: 0.1077 CLY-3-O2 8.00% Δε [1 kHz, 20° C.]: −3.8 CLY-3-O3 4.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 12.3 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 13.7 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 76 CC-3-V 32.00% V.sub.0 [20° C., V]: 1.98 CC-3-V1 4.00% CCP-3-1 2.50% BCH-32 1.00%
[0747] additionally comprises 0.02% of ST-3a-1.
Example M247
[0748] The liquid-crystalline mixture
TABLE-US-00188 PY-3-O2 16.00% Clearing point [° C.]: 69.8 PY-4-O2 6.50% Δn [589 nm, 20° C.]: 0.1075 CCY-3-O1 4.00% Δε [1 kHz, 20° C.]: −3.9 CCY-3-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.8 CPY-4-O2 6.00% K.sub.1 [pN, 20° C.]: 12.6 CLY-3-O2 8.00% K.sub.3 [pN, 20° C.]: 13.0 CLY-3-O3 4.00% V.sub.0 [20° C., V]: 2.17 B-2O-O5 5.00% PGIY-2-O4 6.00% CC-3-V 32.00% CC-3-V1 5.50% BCH-32 1.00%
[0749] additionally comprises 0.02% of ST-3a-1.
Example M248
[0750] The liquid-crystalline mixture
TABLE-US-00189 CY-3-O2 12.00% Clearing point [° C.]: 75.6 CY-5-O2 8.00% Δn [589 nm, 20° C.]: 0.1024 CCY-3-O2 5.00% Δε [1 kHz, 20° C.]: −4.0 CCY-4-O2 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.9 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 12.5 CPY-2-O2 10.00% K.sub.3 [pN, 20° C.]: 14.0 CPY-3-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 83 B-2O-O5 4.00% V.sub.0 [20° C., V]: 1.96 PGIY-2-O4 5.00% CC-3-V 36.00%
[0751] additionally comprises 0.02% of ST-3a-1 and 0.05% of ST-3b-1.
Example M249
[0752] The liquid-crystalline mixture
TABLE-US-00190 B-O2-O5 5.00% Clearing point [° C.]: 74.5 BCH-52 8.00% Δn [589 nm, 20° C.]: 0.1033 CC-3-V 22.50% Δε [1 kHz, 20° C.]: −3.0 CCH-13 9.40% ε.sub.⊥ [1 kHz, 20° C.]: 6.5 CCH-34 5.50% K.sub.1 [pN, 20° C.]: 13.4 CCY-3-O1 8.20% K.sub.3 [pN, 20° C.]: 13.5 CCY-3-O2 8.80% γ.sub.1 [mPa .Math. s, 20° C.]: 96 CCY-4-O2 11.60% V.sub.0 [20° C., V]: 2.26 PP-1-2V1 2.00% PY-3-O2 15.00% PY-4-O2 1.00% PYP-2-3 3.00%
[0753] additionally comprises 0.02% of ST-3a-1.
Example M249a
[0754] For the preparation of a PS (polymer stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.7% of the mixture according to Example M249 are mixed with 0.001% of Irganox 1076 and 0.3% of the polymerisable compound of the formula
##STR00514##
Example M250
[0755] The liquid-crystalline mixture
TABLE-US-00191 CY-3-O2 17.00% Clearing point [° C.]: 74.4 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1116 CLY-3-O2 7.00% Δε [1 kHz, 20° C.]: −3.7 CPY-2-O2 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 13.5 PYP-2-3 6.50% K.sub.3 [pN, 20° C.]: 15.2 PGIY-2-O4 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 97 B2O-O5 4.00% V.sub.0 [20° C., V]: 2.14 CC-3-V 33.00% CC-3-V1 6.50%
[0756] additionally comprises 0.02% of ST-3a-1.
Example M251
[0757] The liquid-crystalline mixture
TABLE-US-00192 B-2O-O5 4.00% Clearing point [° C.]: 75.2 BCH-32 7.00% Δn [589 nm, 20° C.]: 0.1040 CC-3-V 35.00% Δε [1 kHz, 20° C.]: −3.3 CCY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CCY-4-O2 8.00% K.sub.1 [pN, 20° C.]: 13.0 CLY-3-O2 6.00% K.sub.3 [pN, 20° C.]: 13.7 CLY-3-O3 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 76 CY-3-O2 5.50% V.sub.0 [20° C., V]: 2.14 CY-5-O2 3.00% PY-3-O2 13.00% PYP-2-3 4.50%
[0758] additionally comprises 0.02% of ST-3a-1.
Example M252
[0759] The liquid-crystalline mixture
TABLE-US-00193 CC-3-V 42.00% Clearing point [° C.]: 74.0 CCY-3-O2 11.00% Δn [589 nm, 20° C.]: 0.1008 CPY-2-O2 10.00% Δε [1 kHz, 20° C.]: −3.7 CPY-3-O2 11.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CY-3-O2 17.00% K.sub.1 [pN, 20° C.]: 12.8 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 14.6 B(S)-2O-O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 86 V.sub.0 [20° C., V]: 2.11
[0760] additionally comprises 0.025% of ST-3a-1.
Example M253
[0761] The liquid-crystalline mixture
TABLE-US-00194 B-2O-O5 4.00% Clearing point [° C.]: 89.6 BCH-32 3.50% Δn [589 nm, 20° C.]: 0.1096 CC-3-V 25.00% Δε [1 kHz, 20° C.]: −4.2 CCP-3-1 11.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.8 CCY-3-O1 3.00% K.sub.1 [pN, 20° C.]: 16.3 CCY-3-O2 8.00% K.sub.3 [pN, 20° C.]: 17.6 CCY-4-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 139 CLY-3-O2 6.50% V.sub.0 [20° C., V]: 2.17 CLY-3-O3 6.50% CY-3-O2 8.50% PGIY-2-O4 3.00% PY-3-O2 13.00%
[0762] additionally comprises 0.025% of ST-9-1.
Example M254
[0763] The liquid-crystalline mixture
TABLE-US-00195 CC-3-V 37.00% Clearing point [° C.]: 80.0 CY-3-O2 15.00% Δn [589 nm, 20° C.]: 0.1079 CCY-3-O1 5.00% Δε [1 kHz, 20° C.]: −3.7 CCY-3-O2 11.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CPY-2-O2 9.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CPY-3-O2 10.50% K.sub.1 [pN, 20° C.]: 13.5 PYP-2-3 4.00% K.sub.3 [pN, 20° C.]: 15.3 PGIY-2-O4 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 104 B(S)-1-O5 4.00% V.sub.0 [20° C., V]: 2.14 LTS [bulk, −20° C.]: >1000 h
[0764] additionally comprises 0.02% of ST-3a-1.
Example M255
[0765] The liquid-crystalline mixture
TABLE-US-00196 CC-3-V 37.00% Clearing point [° C.]: 80.0 CY-3-O2 14.50% Δn [589 nm, 20° C.]: 0.1077 CCY-3-O1 5.00% Δε [1 kHz, 20° C.]: −3.7 CCY-3-O2 11.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CPY-2-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CPY-3-O2 10.50% K.sub.1 [pN, 20° C.]: 13.4 PYP-2-3 4.00% K.sub.3 [pN, 20° C.]: 15.2 PGIY-2-O4 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 104 B(S)-2-O5 4.00% V.sub.0 [20° C., V]: 2.14 LTS [bulk, −20° C.]: >1000 h
[0766] additionally comprises 0.02% of ST-3a-1 and 0.01% of ST-8-1.
Example M256
[0767] The liquid-crystalline mixture
TABLE-US-00197 CC-3-V 40.00% Clearing point [° C.]: 80.5 CY-3-O2 10.50% Δn [589 nm, 20° C.]: 0.1076 CCY-3-O1 5.00% Δε [1 kHz, 20° C.]: −3.6 CCY-3-O2 11.00% ε.sub.∥ [1 kHz, 20° C.]: 3.6 CPY-2-O2 7.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.2 CPY-3-O2 11.00% K.sub.1 [pN, 20° C.]: 14.2 PYP-2-3 3.00% K.sub.3 [pN, 20° C.]: 15.5 PGIY-2-O4 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 99 B(S)-5-O3 4.00% V.sub.0 [20° C., V]: 2.20 B(S)-5-O4 4.00% LTS [bulk, −20° C.]: >1000 h
[0768] additionally comprises 0.02% of ST-3a-1.
Example M257
[0769] The liquid-crystalline mixture
TABLE-US-00198 CC-3-V 38.00% Clearing point [° C.]: 79.0 CY-3-O2 7.50% Δn [589 nm, 20° C.]: 0.1075 CCY-3-O1 5.00% Δε [1 kHz, 20° C.]: −3.5 CCY-3-O2 11.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCY-4-O2 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.2 CPY-2-O2 9.00% K.sub.1 [pN, 20° C.]: 13.4 CPY-3-O2 11.00% K.sub.3 [pN, 20° C.]: 14.7 PGIY-2-O4 4.50% γ.sub.1 [mPa .Math. s, 20° C.]: 103 B(S)-2-3 11.00% V.sub.0 [20° C., V]: 2.17 LTS [bulk, −20° C.]: >1000 h
[0770] additionally comprises 0.02% of ST-3a-1.
Example M258
[0771] The liquid-crystalline mixture
TABLE-US-00199 B—2O—O5 4.00% Clearing point [° C.]: 74.3 BCH-32 11.00% Δn [589 nm, 20° C.]: 0.1108 CC-3-V1 7.00% Δε [1 kHz, 20° C.]: −3.5 CCH-301 8.00% ε.sub.∥ [1 kHz, 20° C.]: CCH-34 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.2 CCH-35 4.50% K.sub.1 [pN, 20° C.]: 13.7 CCY-4-O2 10.50% K.sub.3 [pN, 20° C.]: 13.4 CLY-2-O4 1.00% γ.sub.1 [mPa .Math. s, 20° C.]: 121 CPY-2-O2 11.00% CPY-3-O2 6.00% CY-3-O2 9.50% PCH-301 6.00% PY-3-O2 3.00% PY-4-O2 8.50%
[0772] additionally comprises 0.02% of ST-3a-1 and 0.01% of ST-8-1.
Example M259
[0773] The liquid-crystalline mixture
TABLE-US-00200 B—2O—O5 4.00% Clearing point [° C.]: 74.6 BCH-32 8.00% Δn [589 nm, 20° C.]: 0.1090 CC-3-V1 7.00% Δε [1 kHz, 20° C.]: −3.1 CCH-34 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-35 7.00% K.sub.1 [pN, 20° C.]: 14.2 CCP-3-1 8.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-V2-1 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 112 CCY-3-O2 8.50% V.sub.0 [20° C., V]: 2.42 CCY-4-O2 1.50% CLY-3-O2 5.00% CY-3-O2 11.00% PCH-301 10.00% PY-3-O2 17.00%
[0774] additionally comprises 0.01% of ST-3a-1.
Example M259a
[0775] For the preparation of a PS (polymer stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.65% of the mixture according to Example M259 are mixed with 0.35% of the polymerisable compound of the formula
##STR00515##
Example M260
[0776] The liquid-crystalline mixture
TABLE-US-00201 CLY-3-O2 8.00% Clearing point [° C.]: 81.5 CLY-5-O2 6.00% Δn [589 nm, 20° C.]: 0.1017 CPY-3-O2 10.00% Δε [1 kHz, 20° C.]: −4.1 B(S)—2O—O4 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 B(S)—2O—O5 6.00% K.sub.1 [pN, 20° C.]: 15.5 CC-3-V 36.00% K.sub.3 [pN, 20° C.]: 17.0 CC-3-V1 9.00% γ.sub.1 [mPa .Math. s, 20° C.]: 98 CY-3-O2 13.00% V.sub.0 [20° C., V]: 2.15 PGIY-2-O4 1.00% CCY-3-O2 5.00%
[0777] additionally comprises 0.03% of ST-3a-1.
Example M261
[0778] The liquid-crystalline mixture
TABLE-US-00202 CC-3-V 30.00% Clearing point [° C.]: 87.0 CC-3-V1 10.00% Δn [589 nm, 20° C.]: 0.1019 CCH-34 2.50% Δε [1 kHz, 20° C.]: −3.7 CCP—V-1 1.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.1 PGIY-2-O4 4.00% K.sub.1 [pN, 20° C.]: 15.2 CCY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 18.0 CCY-5-O2 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 112 CLY-3-O2 8.00% V.sub.0 [20° C., V]: 2.35 CPY-2-O2 6.00% CPY-3-O2 10.00% CY-3-O2 12.00% B—2O—O5 4.00%
[0779] additionally comprises 0.15% of ST-12.
Example M262
[0780] The liquid-crystalline mixture
TABLE-US-00203 CCY-3-O2 6.00% Clearing point [° C.]: 84.0 CCY-5-O2 6.00% Δn [589 nm, 20° C.]: 0.1018 CLY-3-O2 8.00% Δε [1 kHz, 20° C.]: −3.6 CLY-3-O3 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 15.1 PGIY-2-O4 2.00% K.sub.3 [pN, 20° C.]: 18.2 B—2O—O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 107 CC-3-V 29.50% V.sub.0 [20° C., V]: 2.38 CC-3-V1 10.00% CY-3-O2 12.00% PP-1-3 4.50%
[0781] additionally comprises 0.03% of ST-3a-1.
Example M263
[0782] The liquid-crystalline mixture
TABLE-US-00204 CY-3-O2 4.00% Clearing point [° C.]: 80.4 CCY-3-O1 3.50% Δn [589 nm, 20° C.]: 0.1007 CCY-3-O2 6.00% Δε [1 kHz, 20° C.]: −4.0 CCY-4-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.8 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.9 PYP-2-3 1.00% K.sub.3 [pN, 20° C.]: 15.7 CLY-3-O2 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 101 CLY-3-O3 6.00% V.sub.0 [20° C., V]: 2.07 Y—4O—O4 6.00% PGIY-2-O4 5.50% B—2O—O5 5.00% CC-3-V 33.00% CC-3-V1 8.00%
[0783] additionally comprises 0.015% of ST-9-1.
Example M264
[0784] The liquid-crystalline mixture
TABLE-US-00205 CCY-3-O1 6.50% Clearing point [° C.]: 84.5 CCY-3-O2 9.00% Δn [589 nm, 20° C.]: 0.1106 CCY-4-O2 4.00% Δε [1 kHz, 20° C.]: −4.5 CCY-5-O2 4.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.3 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 15.6 CLY-3-O3 7.00% K.sub.3 [pN, 20° C.]: 16.2 PGIY-2-O4 5.50% γ.sub.1 [mPa .Math. s, 20° C.]: 127 PGP-2-3 1.00% V.sub.0 [20° C., V]: 2.01 B—2O—O5 5.00% CC-3-V 33.50% CC-3-V1 1.00% PY-2-O4 5.00% PY-3-O2 10.50%
[0785] additionally comprises 0.02% of ST-3a-1.
Example M265
[0786] The liquid-crystalline mixture
TABLE-US-00206 B—2O—O5 4.00% Clearing point [° C.]: 75 BCH-32 3.00% Δn [589 nm, 20° C.]: 0.1096 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.1 CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.6 CCH-34 8.00% K.sub.1 [pN, 20° C.]: 13.6 CCH-35 8.00% K.sub.3 [pN, 20° C.]: 16.3 CCP—V2-1 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 109 CCY-3-O2 1.50% V.sub.0 [20° C., V]: 2.39 CLY-3-O2 10.00% CPY-2-O2 8.00% CPY-3-O2 8.00% CY-3-O2 6.50% PCH-301 17.50% PY-3-O2 9.50%
[0787] additionally comprises 0.02% of ST-3a-1 and 0.3% of the compound of the formula
##STR00516##
Example M265a
[0788] For the preparation of a PS (polymer stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.65% of the mixture according to Example M265 are mixed with 0.35% of the polymerisable compound of the formula
##STR00517##
Example M266
[0789] The liquid-crystalline mixture
TABLE-US-00207 B—2O—O5 4.00% Clearing point [° C.]: 74.4 BCH-32 8.00% Δn [589 nm, 20° C.]: 0.1087 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.1 CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.6 CCH-34 8.00% K.sub.1 [pN, 20° C.]: 14.3 CCH-35 7.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-3-1 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 107 CCY-3-O2 4.00% V.sub.0 [20° C., V]: 2.42 CCY-4-O2 2.50% CLY-3-O2 10.00% CPY-3-O2 2.00% CY-3-O2 8.50% PCH-301 11.00% PY-3-O2 16.00%
[0790] additionally comprises 0.02% of ST-3a-1.
Example M267
[0791] The liquid-crystalline mixture
TABLE-US-00208 B—2O—O5 4.00% Clearing point [° C.]: 74.1 BCH-32 3.00% Δn [589 nm, 20° C.]: 0.1090 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.1 CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-34 8.00% K.sub.1 [pN, 20° C.]: 14.2 CCH-35 8.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-3-1 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 109 CCY-3-O2 1.50% V.sub.0 [20° C., V]: 2.43 CPY-3-O2 10.00% CY-3-O2 8.00% PCH-301 8.00% PY-3-O2 6.50%
[0792] additionally comprises 0.01% of ST-8-1.
Example M268
[0793] The liquid-crystalline mixture
TABLE-US-00209 B—2O—O5 4.00% Clearing point [° C.]: 74.2 BCH-32 8.00% Δn [589 nm, 20° C.]: 0.1088 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.1 CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-34 9.00% K.sub.1 [pN, 20° C.]: 14.1 CCH-35 7.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-3-1 8.50% γ.sub.1 [mPa .Math. s, 20° C.]: 109 CCY-3-O2 11.49% V.sub.0 [20° C., V]: 2.43 CLY-3-O2 0.01% CPY-3-O2 6.50% CY-3-O2 10.00% PCH-301 9.00% PY-3-O2 15.50%
[0794] additionally comprises 0.01% of ST-3a-1.
Example M269
[0795] The liquid-crystalline mixture
TABLE-US-00210 B-2O-O5 4.00% Clearing point [° C.]: 74.2 BCH-32 8.00% Δn [589 nm, 20° C.]: 0.1085 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.1 CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-34 9.00% K.sub.1 [pN, 20° C.]: 14.2 CCH-35 7.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-3-1 8.50% γ.sub.1 [mPa .Math. s, 20° C.]: 109 CCY-3-O2 11.45% V.sub.0 [20° C., V]: 2.42 CLY-3-O2 0.05% CPY-3-O2 6.50% CY-3-O2 10.00% PCH-301 9.00% PY-3-O2 15.50%
[0796] additionally comprises 0.03% of ST-3a-1.
Example M270
[0797] The liquid-crystalline mixture
TABLE-US-00211 B-2O-O5 4.00% Clearing point [° C.]: 74.2 BCH-32 8.00% Δn [589 nm, 20° C.]: 0.1088 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.1 CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-34 9.00% K.sub.1 [pN, 20° C.]: 14.2 CCH-35 7.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-3-1 8.50% γ.sub.1 [mPa .Math. s, 20° C.]: 109 CCY-3-O2 11.40% V.sub.0 [20° C., V]: 2.43 CLY-3-O2 0.10% CPY-3-O2 6.50% CY-3-O2 10.00% PCH-301 9.00% PY-3-O2 15.50%
[0798] additionally comprises 0.01% of ST-17.
Example M271
[0799] The liquid-crystalline mixture
TABLE-US-00212 B-2O-O5 4.00% Clearing point [° C.]: 74.2 BCH-32 8.00% Δn [589 nm, 20° C.]: 0.1091 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.1 CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-34 8.00% K.sub.1 [pN, 20° C.]: 14.5 CCH-35 7.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-3-1 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 108 CCP-V2-1 5.00% V.sub.0 [20° C., V]: 2.41 CCY-3-O2 10.50% CLY-3-O2 1.00% CPY-3-O2 2.50% CY-3-O2 11.50% PCH-301 5.50% PY-3-O2 18.00%
[0800] additionally comprises 0.02% of ST-3a-1 and 0.3% of the compound of the formula
##STR00518##
Example M271a
[0801] For the preparation of a PS (polymer stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.65% of the mixture according to Example M271 are mixed with 0.35% of the polymerisable compound of the formula
##STR00519##
Example M272
[0802] The liquid-crystalline mixture
TABLE-US-00213 B-2O-O5 2.00% Clearing point [° C.]: 100.0 BCH-32 2.00% Δn [589 nm, 20° C.]: 0.1166 CC-3-V 29.00% Δε [1 kHz, 20° C.]: −3.4 CCP-3-1 7.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.9 CCY-3-O1 4.00% K.sub.1 [pN, 20° C.]: 15.9 CCY-3-O2 6.50% K.sub.3 [pN, 20° C.]: 17.4 CCY-4-O2 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 116 CLY-3-O2 4.00% V.sub.0 [20° C., V]: 2.41 CPY-2-O2 7.50% CPY-3-O2 10.00% CY-3-O2 10.00% PGIY-2-O4 4.00% PYP-2-3 7.50%
[0803] additionally comprises 0.02% of ST-3a-1.
Example M273
[0804] The liquid-crystalline mixture
TABLE-US-00214 B-2O-O5 2.00% Clearing point [° C.]: 100.4 BCH-32 4.00% Δn [589 nm, 20° C.]: 0.1146 CC-3-V 22.00% Δε [1 kHz, 20° C.]: −4.1 CC-3V-1 4.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 CCP-V-1 4.00% K.sub.1 [pN, 20° C.]: 16.4 CCY-3-O1 5.00% K.sub.3 [pN, 20° C.]: 18.4 CCY-3-O2 9.00% γ.sub.1 [mPa .Math. s, 20° C.]: 170 CCY-4-O2 5.00% V.sub.0 [20° C., V]: 2.23 CCY-5-O2 4.50% CLY-2-O4 5.00% CPY-2-O2 8.00% CPY-3-O2 8.00% CY-3-O2 13.00% PGIY-2-O4 2.00% PYP-2-3 3.00% PYP-2-4 1.50%
[0805] additionally comprises 0.03% of ST-3a-1.
Example M274
[0806] The liquid-crystalline mixture
TABLE-US-00215 CLY-3-O2 7.00% Clearing point [° C.]: 71.1 CLY-3-O3 5.00% Δn [589 nm, 20° C.]: 0.1079 CPY-3-O2 11.00% Δε [1 kHz, 20° C.]: −2.6 PGIY-2-O4 7.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.1 PYP-2-3 9.50% K.sub.1 [pN, 20° C.]: 13.1 B-2O-O5 4.00% K.sub.3 [pN, 20° C.]: 13.7 CC-3-V 41.50% γ.sub.1 [mPa .Math. s, 20° C.]: 70 CC-3-V1 9.00% V.sub.0 [20° C., V]: 2.41 Y-4O-O4 6.00%
[0807] additionally comprises 0.03% of ST-3a-1.
Example M274a
[0808] For the preparation of a PS (polymer stabilised) mixture, for example for PS-IPS, PS-VA, PS-FFS applications, 99.55% of the mixture according to Example M274 are mixed with 0.25% of the polymerisable compound of the formula
##STR00520##
[0809] and with 0.20% of the compound of the formula
##STR00521##
Example M275
[0810] The liquid-crystalline mixture
TABLE-US-00216 CY-3-O2 8.00% Clearing point [° C.]: 89.5 CY-3-O4 10.00% Δn [589 nm, 20° C.]: 0.1050 CCY-3-O1 4.00% Δε [1 kHz, 20° C.]: −4.3 CCY-3-O2 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.0 CCY-4-O2 4.00% K.sub.1 [pN, 20° C.]: 15.7 CLY-3-O2 8.00% K.sub.3 [pN, 20° C.]: 17.0 CLY-3-O3 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 141 CPY-3-O2 2.00% V.sub.0 [20° C., V]: 2.11 PYP-2-3 2.00% B-2O-O5 5.00% PGIY-2-O4 6.00% CC-3-V 27.00% CCP-3-1 11.00%
[0811] additionally comprises 0.03% of ST-3a-1.
Example M276
[0812] The liquid-crystalline mixture
TABLE-US-00217 CCY-3-O2 6.00% Clearing point [° C.]: 75.0 CLY-3-O2 8.00% Δn [589 nm, 20° C.]: 0.1019 CLY-3-O3 3.50% Δε [1 kHz, 20° C.]: −3.6 CPY-2-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.1 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.1 B-2O-O5 5.00% K.sub.3 [pN, 20° C.]: 15.2 CC-3-V 33.50% γ.sub.1 [mPa .Math. s, 20° C.]: 97 CC-3-V1 5.50% V.sub.0 [20° C., V]: 2.17 CY-3-O4 10.00% CY-5-O4 4.50% PP-1-3 4.00%
[0813] additionally comprises 0.03% of ST-9-1.
Example M277
[0814] The liquid-crystalline mixture
TABLE-US-00218 CC-3-V 28.00% Clearing point [° C.]: 84.8 CC-3-V1 6.50% Δn [589 nm, 20° C.]: 0.1111 CCY-3-O1 5.50% Δε [1 kHz, 20° C.]: −4.0 CCY-3-O2 7.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 CCY-4-O2 7.00% K.sub.1 [pN, 20° C.]: 14.4 CPY-2-O2 8.00% K.sub.3 [pN, 20° C.]: 16.5 CPY-3-O2 11.00% γ.sub.1 [mPa .Math. s, 20° C.]: 124 PYP-2-3 8.50% V.sub.0 [20° C., V]: 2.15 CY-3-O2 14.50% B-2O-O5 4.00%
[0815] additionally comprises 0.015% of ST-9-1.
Example M278
[0816] The liquid-crystalline mixture
TABLE-US-00219 CY-3-O2 8.00% Clearing point [° C.]: 89.6 CY-3-O4 10.00% Δn [589 nm, 20° C.]: 0.1030 CCY-3-O2 3.00% Δε [1 kHz, 20° C.]: −3.4 CCY-4-O2 1.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 14.8 CLY-3-O3 8.00% K.sub.3 [pN, 20° C.]: 16.7 CPY-3-O2 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 97 B-2O-O5 5.00% V.sub.0 [20° C., V]: 2.32 PGIY-2-O4 6.00% CC-3-V 22.00% CC-3-V1 6.00% CCP-V-1 14.00% CCP-V2-1 4.50%
[0817] additionally comprises 0.01% of ST-8-1.
Example M279
[0818] The liquid-crystalline mixture
TABLE-US-00220 CCY-3-O2 6.00% Clearing point [° C.]: 75.5 CLY-3-O2 8.00% Δn [589 nm, 20° C.]: 0.1014 CLY-3-O3 4.00% Δε [1 kHz, 20° C.]: −3.8 CPY-2-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 13.7 PGIY-2-O4 1.00% K.sub.3 [pN, 20° C.]: 14.7 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 99 CC-3-V 38.50% V.sub.0 [20° C., V]: 2.09 CY-3-O4 10.00% CY-5-O4 5.00% PP-1-3 2.50%
[0819] additionally comprises 0.03% of ST-3a-1.
Example M280
[0820] The liquid-crystalline mixture
TABLE-US-00221 CCY-3-O2 8.00% Clearing point [° C.]: 84.5 CLY-2-O4 3.50% Δn [589 nm, 20° C.]: 0.1020 CLY-3-O2 8.00% Δε [1 kHz, 20° C.]: −3.8 CLY-3-O3 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 15.7 PGIY-2-O4 5.00% K.sub.3 [pN, 20° C.]: 17.2 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 109 CC-3-V 27.00% V.sub.0 [20° C., V]: 2.24 CC-3-V1 10.00% CCH-34 5.00% CY-3-O2 12.50% PP-1-3 1.00%
[0821] additionally comprises 0.03% of ST-3a-1.
Example M281
[0822] The liquid-crystalline mixture
TABLE-US-00222 CCY-3-O2 6.00% Clearing point [° C.]: 75.0 CLY-3-O2 8.00% Δn [589 nm, 20° C.]: 0.1019 CLY-3-O3 3.50% Δε [1 kHz, 20° C.]: −3.6 CPY-2-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.1 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.1 B-2O-O5 5.00% K.sub.3 [pN, 20° C.]: 15.2 CC-3-V 33.50% γ.sub.1 [mPa .Math. s, 20° C.]: 97 CC-3-V1 5.50% V.sub.0 [20° C., V]: 2.17 CY-3-O4 10.00% CY-5-O4 4.50% PP-1-3 4.00%
[0823] additionally comprises 0.03% of ST-3a-1.
Example M282
[0824] The liquid-crystalline mixture
TABLE-US-00223 CY-3-O2 8.00% Clearing point [° C.]: 70.6 CY-5-O2 6.00% Δn [589 nm, 20° C.]: 0.1079 PY-3-O2 12.00% Δε [1 kHz, 20° C.]: −4.1 CLY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.0 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 12.6 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.1 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 80 CCY-3-1 4.00% V.sub.0 [20° C., V]: 1.94 CC-3-V 28.00% CC-3-V1 4.00% CCP-3-1 3.00%
[0825] additionally comprises 0.02% of ST-9-1.
Example M283
[0826] The liquid-crystalline mixture
TABLE-US-00224 CY-3-O2 10.00% Clearing point [° C.]: 70.3 CY-5-O2 8.00% Δn [589 nm, 20° C.]: 0.1105 PY-3-O2 10.00% Δε [1 kHz, 20° C.]: −4.4 CLY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.3 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 13.4 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.9 B-2O-O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 106 CC-3-V 26.00% V.sub.0 [20° C., V]: 1.96 CC-3-V1 5.00% CCP-3-1 4.00% BCH-32 2.00%
[0827] additionally comprises 0.02% of ST-9-1.
Example M284
[0828] The liquid-crystalline mixture
TABLE-US-00225 CY-3-O2 8.00% Clearing point [° C.]: 70.0 CY-5-O2 8.00% Δn [589 nm, 20° C.]: 0.1106 PY-3-O2 12.00% Δε [1 kHz, 20° C.]: −4.4 CLY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.3 CPY-2-O2 10.00% K.sub.1 [pN, 20° C.]: 13.4 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 15.0 B—2O—O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 106 CC-3-V 27.00% CC-3-V1 4.00% CCP-3-1 6.00%
[0829] additionally comprises 0.03% of ST-3a-1 and 0.01% of ST-8-1.
Example M285
[0830] The liquid-crystalline mixture
TABLE-US-00226 CCP—V-1 7.50% Clearing point [° C.]: 88.0 CCY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1020 CCY-5-O2 3.50% Δε [1 kHz, 20° C.]: −3.6 CLY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.2 CPY-2-O2 3.50% K.sub.1 [pN, 20° C.]: 15.2 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 18.1 PGIY-2-O4 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 112 B—O2—O5 4.00% V.sub.0 [20° C., V]: 2.36 CC-3-V 26.50% CC-3-V1 10.00% CCH-34 2.00% CY-3-O2 7.00% Y—4O—O4 4.00%
[0831] additionally comprises 0.05% of ST-3b-1 and 0.15% of ST-12.
Example M286
[0832]
TABLE-US-00227 B(S)—2O—O4 4.00% B(S)—2O—O5 4.00% CC-3-V 35.00% CCP-3-1 4.50% CCY-3-O2 7.00% CCY-4-O2 4.50% CLY-3-O2 6.00% CLY-3-O3 6.00% CPY-3-O2 10.00% CY-3-O2 13.00% PYP-2-4 6.00%
[0833] additionally comprises 0.05% of ST-3b-1 and 0.15% of ST-12.
Example M287
[0834] The liquid-crystalline mixture
TABLE-US-00228 B(S)—2O—O4 4.00% B(S)—2O—O5 4.00% BCH-32 5.50% CC-3-V 35.00% CCP-3-1 6.00% CCY-3-O2 8.00% CLY-3-O2 6.00% CLY-3-O3 6.00% CPY-3-O2 10.00% CY-3-O2 13.00% PYP-2-4 2.50%
[0835] additionally comprises 0.03% of ST-3a-1.
Example M288
[0836] The liquid-crystalline mixture
TABLE-US-00229 B(S)—2O—O4 4.00% B(S)—2O—O5 4.00% CC-3-V 36.50% CC-3-V1 4.00% CCP-3-1 3.00% CCY-3-O2 5.50% CLY-3-O2 6.00% CLY-3-O3 6.00% CPY-2-O2 8.00% CPY-3-O2 8.00% CY-3-O2 5.00% PGIY-2-O4 5.00% Y—4O—O4 5.00%
[0837] additionally comprises 0.03% of ST-3a-1.
Example M289
[0838] The liquid-crystalline mixture
TABLE-US-00230 B(S)—2O—O4 4.00% B(S)—2O—O5 4.00% BCH-32 6.00% CC-3-V 35.50% CCP-3-1 4.50% CCY-3-O2 5.50% CLY-3-O2 6.00% CLY-3-O3 6.00% CPY-3-O2 9.00% CY-3-O2 13.00% CY-5-O2 2.50% PYP-2-O4 4.00%
[0839] additionally comprises 0.03% of ST-3a-1.
Example M290
[0840] The liquid-crystalline mixture
TABLE-US-00231 CCY-3-O1 2.00% Clearing point [° C.]: 80.0 CCY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.1065 CCY-4-O2 5.00% Δε [1 kHz, 20° C.]: −3.8 CLY-2-O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 15.5 CLY-3-O3 5.00% K.sub.3 [pN, 20° C.]: 15.0 PGIY-2-O4 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 93 B(S)—2O—O5 4.00% V.sub.0 [20° C., V]: 2.08 B(S)—2O—O4 4.00% CC-3-V 39.50% CC-3-V1 4.00% PY-3-O2 12.50%
[0841] additionally comprises 0.03% of ST-3a-1.
Example M291
[0842] The liquid-crystalline mixture
TABLE-US-00232 CLY-2-O4 3.50% CLY-3-O2 8.00% CLY-3-O3 5.00% B(S)—2O—O5 4.00% B(S)—2O—O4 4.00% CC-3-V 35.00% CC-3-V1 6.50% CY-3-O4 12.00% CY-5-O4 1.50% CPY-3-O2 8.00% CPY-2-O2 8.00% PYP-2-3 4.50%
[0843] additionally comprises 0.03% of ST-3a-1.
Example M292
[0844] The liquid-crystalline mixture
TABLE-US-00233 B(S)—2O—O4 4.50% Clearing point [° C.]: 74.6 B(S)—2O—O5 4.00% Δn [589 nm, 20° C.]: 0.1096 BCH-32 7.00% Δε [1 kHz, 20° C.]: −3.1 CC-3-V1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 14.1 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 16.2 CCH-35 7.50% γ.sub.1 [mPa .Math. s, 20° C.]: 104 CCP-3-1 8.00% V.sub.0 [20° C., V]: 2.39 CCP-V2-1 5.00% CCY-3-O2 11.00% CLY-3-O2 1.00% CY-3-O2 8.00% PCH-301 13.00% PY-3-O2 15.00%
[0845] additionally comprises 0.02% of ST-3a-1.
Example M293
[0846] The liquid-crystalline mixture
TABLE-US-00234 B(S)—2O—O4 4.50% Clearing point [° C.]: 75.0 B(S)—2O—O5 4.00% Δn [589 nm, 20° C.]: 0.1088 BCH-32 6.50% Δε [1 kHz, 20° C.]: −3.1 CC-3-V1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.6 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 14.1 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 16.3 CCH-35 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 108 CCP-3-1 8.00% V.sub.0 [20° C., V]: 2.41 CCP-3-3 3.00% CCY-3-O2 11.00% CLY-3-O2 1.00% CPY-3-O2 2.50% CY-3-O2 7.50% PCH-301 15.00% PY-3-O2 13.00%
[0847] additionally comprises 0.02% of ST-3a-1.
Example M294
[0848] The liquid-crystalline mixture
TABLE-US-00235 B(S)—2O—O4 4.00% Clearing point [° C.]: 74.5 B(S)—2O—O5 4.00% Δn [589 nm, 20° C.]: 0.1092 BCH-32 2.50% Δε [1 kHz, 20° C.]: −3.1 CC-3-V1 6.00% ε.sub.∥ [1 kHz, 20° C.]: CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-34 8.00% K.sub.1 [pN, 20° C.]: 14.0 CCH-35 8.00% K.sub.3 [pN, 20° C.]: 16.1 CCP-3-1 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 106 CCP-3-3 6.00% CCY-3-O2 11.00% CLY-3-O2 1.00% CPY-3-O2 4.50% CY-3-O2 3.00% PCH-301 15.00% PY-3-O2 8.00% PY-2-O2 9.00%
[0849] additionally comprises 0.02% of ST-17.
Example M295
[0850] The liquid-crystalline mixture
TABLE-US-00236 B(S)—2O—O4 4.00% Clearing point [° C.]: 74.4 B(S)—2O—O5 4.00% Δn [589 nm, 20° C.]: 0.1093 BCH-32 3.00% Δε [1 kHz, 20° C.]: −3.1 CC-3-V1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 14.0 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 16.0 CCH-35 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 104 CCP-3-1 8.00% V.sub.0 [20° C., V]: 2.38 CCP-3-3 6.00% CCY-3-O2 11.00% CLY-3-O2 1.00% CPY-3-O2 4.00% CY-3-O2 3.00% PCH-301 15.00% PY-3-O2 7.00% PY-2-O2 10.00%
[0851] additionally comprises 0.02% of ST-3a-1.
Example M296
[0852] The liquid-crystalline mixture
TABLE-US-00237 B(S)—2O—O4 4.50% Clearing point [° C.]: 74.3 B(S)—2O—O5 4.00% Δn [589 nm, 20° C.]: 0.1093 BCH-32 3.50% Δε [1 kHz, 20° C.]: −3.3 CC-3-V1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 13.7 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 16.0 CCH-35 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 108 CCP-3-1 8.00% V.sub.0 [20° C., V]: 2.30 CCP-3-3 3.00% CCY-3-O2 11.00% CLY-3-O2 1.00% CPY-3-O2 6.00% CY-3-O2 6.50% PCH-301 15.00% PY-3-O2 4.00% PY-2-O2 9.50%
[0853] additionally comprises 0.02% of ST-3a-1.
Example M297
[0854] The liquid-crystalline mixture
TABLE-US-00238 B(S)—2O—O4 4.00% Clearing point [° C.]: 74.3 B(S)—2O—O5 4.00% Δn [589 nm, 20° C.]: 0.1089 BCH-32 1.50% Δε [1 kHz, 20° C.]: −3.3 CC-3-V1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 14.0 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 16.0 CCH-35 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 108 CCP-3-1 8.00% V.sub.0 [20° C., V]: 2.31 CCP-3-3 5.00% CCY-3-O1 2.50% CCY-3-O2 11.00% CLY-3-O2 1.00% CPY-3-O2 4.00% CY-3-O2 3.00% PCH-301 14.50% PY-3-O2 7.50% PY-2-O2 10.00%
[0855] additionally comprises 0.02% of ST-3a-1.
Example M298
[0856] The liquid-crystalline mixture
TABLE-US-00239 CC-3-V 30.00% CC-3-V1 8.00% CCP—V-1 10.00% CCY-3-O2 5.00% CLY-3-O2 8.00% CLY-4-O2 5.00% CLY-5-O2 6.00% CY-3-O2 12.00% CY-5-O2 2.50% PYP-2-3 3.50% B(S)—2O—O4 5.00% B(S)—2O—O5 5.00%
[0857] additionally comprises 0.02% of ST-3a-1.
Example M299
[0858] The liquid-crystalline mixture
TABLE-US-00240 CC-3-V 30.00% CC-3-V1 8.50% CCP—V-1 10.00% CCY-3-O2 5.00% CCY-5-O2 4.00% CLY-3-O2 9.00% CPY-3-O2 8.00% CY-3-O2 8.50% CY-5-O2 5.50% PYP-2-3 1.50% B(S)—2O—O4 5.00% B(S)—2O—O5 5.00%
[0859] additionally comprises 0.02% of ST-3a-1.
Example M300
[0860] The liquid-crystalline mixture
TABLE-US-00241 CC-3-V 30.00% Clearing point [° C.]: 93 CC-3-V1 8.00% Δn [589 nm, 20° C.]: 0.0993 CCP—V2-1 3.50% Δε [1 kHz, 20° C.]: −4.2 CCY-3-O2 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 CCY-5-O2 6.00% K.sub.1 [pN, 20° C.]: 17.3 CLY-3-O2 8.00% K.sub.3 [pN, 20° C.]: 18.6 CLY-4-O2 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 2.21 CLY-5-O2 8.00% V.sub.0 [20° C., V]: 118 CY-3-O2 11.50% CPY-3-O2 1.50% B(S)—2O—O4 5.50% B(S)—2O—O5 5.00%
[0861] additionally comprises 0.03% of ST-3a-1.
Example M301
[0862] The liquid-crystalline mixture
TABLE-US-00242 CC-3-V 40.00% CC-3-V1 7.50% CCP—V-1 1.50% PGIY-2-O4 2.00% CCY-3-O2 2.00% CLY-3-O2 8.00% CLY-4-O2 4.00% CLY-5-O2 7.00% CY-3-O2 8.00% CPY-3-O2 10.00% B(S)—2O—O4 5.00% B(S)—2O—O5 5.00%
[0863] additionally comprises 0.03% of ST-3a-1.
Example M302
[0864] The liquid-crystalline mixture
TABLE-US-00243 CC-3-V 38.00% CC-3-V1 8.00% CCP—V-1 2.50% CCY-3-O2 5.00% CCY-5-O2 6.00% CLY-3-O2 8.00% CPY-3-O2 9.50% CY-3-O2 9.00% PGIY-2-O4 4.00% B(S)—2O—O4 5.00% B(S)—2O—O5 5.00%
[0865] additionally comprises 0.03% of ST-3a-1.
Example M303
[0866] The liquid-crystalline mixture
TABLE-US-00244 CC-3-V 30.00% CC-3-V1 8.00% CCY-3-O2 6.00% CCY-5-O2 5.00% CLY-3-O2 9.00% CLY-4-O2 9.00% CLY-5-O2 9.50% CY-3-O2 10.00% CPY-3-O2 3.00% B(S)—2O—O4 5.00% B(S)—2O—O5 5.00%
[0867] additionally comprises 0.03% of ST-3a-1.
Example M304
[0868] The liquid-crystalline mixture
TABLE-US-00245 CLY-3-O2 8.00% Clearing point [° C.]: 82.0 CLY-5-O2 6.50% Δn [589 nm, 20° C.]: 10.19 CPY-3-O2 10.00% Δε [1 kHz, 20° C.]: −4.2 B(S)—2O—O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.8 B(S)—2O—O5 5.00% K.sub.1 [pN, 20° C.]: 15.5 CC-3-V 35.00% K.sub.3 [pN, 20° C.]: 17.3 CC-3-V1 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 2.15 CY-3-O2 14.50% V.sub.0 [20° C., V]: 102 PGIY-2-O2 2.00% CCY-3-O2 6.00%
[0869] additionally comprises 0.03% of ST-3a-1.
Example M305
[0870] The liquid-crystalline mixture
TABLE-US-00246 CLY-3-O2 8.00% CPY-3-O2 10.00% B(S)—2O—O4 5.00% B(S)—2O—O5 5.00% CC-3-V 34.00% CC-3-V1 7.50% CCP—V-1 1.50% CY-3-O2 14.50% CCY-3-O2 6.00% CCY-5-O2 6.00% PGIY-2-O4 2.50%
[0871] additionally comprises 0.03% of ST-3a-1.
Example M306
[0872] The liquid-crystalline mixture
TABLE-US-00247 CLY-3-O2 8.00% CLY-4-O2 1.50% CLY-5-O2 5.00% CPY-3-O2 10.00% B(S)—2O—O4 5.00% B(S)—2O—O5 5.00% CC-3-V 35.00% CC-3-V1 8.00% CY-3-O2 14.50% CCY-3-O2 6.00% PGIY-2-O4 2.00%
[0873] additionally comprises 0.03% of ST-3a-1.
Example M307
[0874] The liquid-crystalline mixture
TABLE-US-00248 CLY-3-O2 8.00% Clearing point [° C.]: 81.5 CLY-5-O2 6.00% Δn [589 nm, 20° C.]: 0.1015 CPY-3-O2 10.00% Δε [1 kHz, 20° C.]: −4.1 B(S)—2O—O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 B(S)—2O—O5 5.00% K.sub.1 [pN, 20° C.]: 15.7 B—2O—O5 2.00% K.sub.3 [pN, 20° C.]: 17.1 CC-3-V 37.00% γ.sub.1 [mPa .Math. s, 20° C.]: 98 CC-3-V1 8.00% V.sub.0 [20° C., V]: 2.14 CY-3-O2 12.00% CCY-3-O2 6.00% PGIY-2-O4 1.00%
[0875] additionally comprises 0.02% of ST-8-1.
Example M308
[0876] The liquid-crystalline mixture
TABLE-US-00249 CCY-3-O2 8.00% Clearing point [° C.]: 80.0 CCY-5-O2 6.00% Δn [589 nm, 20° C.]: 0.1071 CLY-2-O4 10.00% Δε [1 kHz, 20° C.]: −3.8 CLY-3-O2 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CLY-3-O3 5.00% K.sub.1 [pN, 20° C.]: 16.0 PGIY-2-O4 2.00% K.sub.3 [pN, 20° C.]: 15.3 B(S)—2O—O5 37.00% γ.sub.1 [mPa .Math. s, 20° C.]: 90 B(S)—2O—O4 8.00% V.sub.0 [20° C., V]: 2.11 CC-3-V 12.00% CC-3-V1 6.00% PY-3-O2 1.00%
[0877] additionally comprises 0.03% of ST-3a-1.
Example M309
[0878] The liquid-crystalline mixture
TABLE-US-00250 CLY-3-O2 8.00% Clearing point [° C.]: 84.0 CLY-4-O2 3.00% Δn [589 nm, 20° C.]: 0.1016 CLY-5-O2 5.00% Δε [1 kHz, 20° C.]: −4.2 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 B(S)—2O—O4 5.00% K.sub.1 [pN, 20° C.]: 15.9 B(S)—2O—O5 5.00% K.sub.3 [pN, 20° C.]: 17.5 CC-3-V 35.00% γ.sub.1 [mPa .Math. s, 20° C.]: 104 CC-3-V1 8.00% V.sub.0 [20° C., V]: 2.16 CY-3-O2 13.50% CCY-3-O2 6.00% PGIY-2-O4 1.50%
[0879] additionally comprises 0.02% of ST-3b-1.
Example M309a
[0880] For the preparation of a PS-VA mixture, 99.7% of the mixture according to Example M309 are mixed with 0.3% of the polymerisable compound of the formula
##STR00522##
Example M310
[0881] The liquid-crystalline mixture
TABLE-US-00251 CLY-3-O2 8.00% CLY-4-O2 1.50% CLY-5-O2 6.00% CPY-3-O2 10.00% B(S)—2O—O4 5.00% B(S)—2O—O5 5.00% B—2O—O5 2.50% CC-3-V 37.00% CC-3-V1 8.00% CY-3-O2 11.00% CCY-3-O2 6.00%
[0882] additionally comprises 0.03% of ST-3a-1.
Example M311
[0883] The liquid-crystalline mixture
TABLE-US-00252 CLY-3-O2 8.00% Clearing point [° C.]: 83.0 CLY-5-O2 6.50% Δn [589 nm, 20° C.]: 0.1017 CPY-3-O2 10.50% Δε [1 kHz, 20° C.]: −4.1 B(S)—2O—O4 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 B(S)—2O—O5 6.00% K.sub.1 [pN, 20° C.]: 15.6 CC-3-V 36.50% K.sub.3 [pN, 20° C.]: 17.5 CC-3-V1 8.50% γ.sub.1 [mPa .Math. s, 20° C.]: 2.18 CY-3-O2 12.00% V.sub.0 [20° C., V]: 100 CCY-3-O2 5.50% PGIY-2-O4 0.50%
[0884] additionally comprises 0.03% of ST-3a-1.
Example M312
[0885] The liquid-crystalline mixture
TABLE-US-00253 CCY-3-O2 6.00% CPY-3-O2 5.50% CCY-4-O2 4.00% CLY-2-O4 5.00% CLY-3-O2 8.00% CLY-3-O3 5.00% PGIY-2-O4 5.00% B(S)—2O—O5 5.00% B(S)—2O—O4 5.00% CC-3-V 30.00% CY-5-O2 6.50% CY-3-O2 15.00%
[0886] additionally comprises 0.03% of ST-3a-1.
Example M313
[0887] The liquid-crystalline mixture
TABLE-US-00254 CC-3-V 6.00% B(S)—2O—O5 5.50% B(S)—2O—O4 4.00% CLY-2-O4 5.00% CLY-3-O2 8.00% CLY-3-O3 5.00% CY-3-O4 5.00% CY-5-O4 5.00% CPY-2-O2 5.00% CPY-3-O2 30.00% CCY-3-O1 6.50%
[0888] additionally comprises 0.015% of ST-3a-1.
Example M314
[0889] The liquid-crystalline mixture
TABLE-US-00255 CLY-3-O2 7.00% Clearing point [° C.]: 82.0 CLY-5-O2 5.00% Δn [589 nm, 20° C.]: 0.1016 CLY-4-O2 4.00% Δε [1 kHz, 20° C.]: −4.1 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 B(S)—2O—O4 5.00% K.sub.1 [pN, 20° C.]: 15.7 B(S)—2O—O5 5.00% K.sub.3 [pN, 20° C.]: 17.2 CC-3-V 36.00% γ.sub.1 [mPa .Math. s, 20° C.]: 101 CC-3-V1 7.50% CY-3-O2 14.00% PGIY-2-O4 2.00% CCY-3-O2 4.50%
[0890] additionally comprises 0.03% of ST-3a-1.
Example M315
[0891] The liquid-crystalline mixture
TABLE-US-00256 CLY-3-O2 7.00% Clearing point [° C.]: 82.0 CLY-4-O2 4.50% Δn [589 nm, 20° C.]: 0.1016 CLY-5-O2 5.00% Δε [1 kHz, 20° C.]: −4.1 CPY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.7 B(S)—2O—O4 5.00% K.sub.1 [pN, 20° C.]: 15.8 B(S)—2O—O5 5.00% K.sub.3 [pN, 20° C.]: 17.2 CC-3-V 35.50% γ.sub.1 [mPa .Math. s, 20° C.]: 102 CC-3-V1 8.00% V.sub.0 [20° C., V]: 2.16 CY-3-O2 13.50% CCY-3-O2 5.00% PGIY-2-O4 1.50%
[0892] additionally comprises 0.03% of ST-3a-1.
Example M316
[0893] The liquid-crystalline mixture
TABLE-US-00257 CCY-3-O2 6.00% Clearing point [° C.]: 79.5 CPY-3-O2 8.00% Δn [589 nm, 20° C.]: 0.1066 CPY-2-O2 6.00% Δε [1 kHz, 20° C.]: −5.5 CLY-2-O4 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 9.5 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 17.7 CLY-3-O3 5.00% K.sub.3 [pN, 20° C.]: 15.5 B(S)—2O—O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 127 B(S)—2O—O4 5.00% V.sub.0 [20° C., V]: 1.76 CC-3-V 30.00% CY-5-O2 7.00% CY-3-O2 15.00%
[0894] additionally comprises 0.03% of ST-3a-1.
Example M317
[0895] The liquid-crystalline mixture
TABLE-US-00258 CCY-3-O2 6.00% CPY-2-O2 6.00% CPY-3-O2 8.00% CLY-2-O4 5.00% CLY-3-O2 8.00% CLY-3-O3 5.00% B(S)—2O—O5 5.00% B(S)—2O—O4 5.00% CC-3-V 30.00% CY-5-O2 7.00% CY-3-O2 15.00%
[0896] additionally comprises 0.03% of ST-3a-1.
Example M318
[0897] The liquid-crystalline mixture
TABLE-US-00259 CCY-3-O2 6.00% Clearing point [° C.]: 79.0 CCY-4-O2 5.50% Δn [589 nm, 20° C.]: 10.65 CPY-3-O2 8.00% Δε [1 kHz, 20° C.]: −5.2 CPY-2-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 9.1 CLY-2-O4 5.00% K.sub.1 [pN, 20° C.]: 14.1 CLY-3-O3 5.00% K.sub.3 [pN, 20° C.]: 14.8 B(S)—2O—O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 121 B(S)—2O—O4 5.00% V.sub.0 [20° C., V]: 1.78 CC-3-V 31.50% CY-5-O2 4.50% CY-3-O2 15.00% PYP-2-3 1.50%
[0898] additionally comprises 0.03% of ST-3a-1.
Example M319
[0899] The liquid-crystalline mixture
TABLE-US-00260 B(S)—2O—O4 4.00% BCH-32 8.00% CC-3-V1 9.00% CCH-301 2.00% CCH-34 8.00% CCH-35 7.00% CCP-3-1 8.00% CCP—V2-1 5.00% CCY-3-O2 10.50% CLY-3-O2 1.00% CPY-3-O2 2.50% CY-3-O2 11.50% PCH-301 5.00% PY-3-O2 18.00%
[0900] additionally comprises 0.015% of ST-3a-1.
Example M320
[0901] The liquid-crystalline mixture
TABLE-US-00261 B(S)—2O—O4 2.00% B(S)—2O—O5 2.00% BCH-32 8.00% CC-3-V1 9.00% CCH-301 2.00% CCH-34 8.00% CCH-35 7.00% CCP-3-1 8.00% CCP—V2-1 5.00% CCY-3-O2 10.50% CLY-3-O2 1.00% CPY-3-O2 2.50% CY-3-O2 11.50% PCH-301 5.50% PY-3-O2 18.00%
[0902] additionally comprises 0.03% of ST-3a-1.
Example M321
[0903] The liquid-crystalline mixture
TABLE-US-00262 B(S)—2O—O4 4.00% Clearing point [° C.]: 74.2 B(S)—2O—O5 4.00% Δn [589 nm, 20° C.]: 0.1096 BCH-32 2.50% Δε [1 kHz, 20° C.]: −3.1 CC-3-V1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.6 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 14.2 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 16.5 CCH-35 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 105 CCP-3-1 8.00% V.sub.0 [20° C., V]: 2.43 CCP-3-3 1.50% CCP—V2-1 5.00% CCY-3-O2 11.00% CLY-3-O2 1.00% CPY-3-O2 2.50% CY-3-O2 3.00% PCH-301 15.50% PY-3-O2 18.00%
[0904] additionally comprises 0.03% of ST-3a-1.
Example M322
[0905] The liquid-crystalline mixture
TABLE-US-00263 B(S)—2O—O4 5.00% Clearing point [° C.]: 74.8 B(S)—2O—O5 3.00% Δn [589 nm, 20° C.]: 0.1092 BCH-32 4.50% Δε [1 kHz, 20° C.]: −3.0 CC-3-V1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.6 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 13.7 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 15.8 CCH-35 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 101 CCP-3-1 8.00% V.sub.0 [20° C., V]: 2.42 CCP-3-3 6.00% CCY-3-O2 11.00% CLY-3-O2 1.00% CPY-3-O2 3.00% CY-3-O2 3.00% PCH-301 15.00% PY-3-O2 4.00% PY-2-O2 12.50%
[0906] additionally comprises 0.015% of ST-3a-1.
Example M323
[0907] The liquid-crystalline mixture
TABLE-US-00264 B(S)—2O—O4 4.00% Clearing point [° C.]: 74.7 B(S)—2O—O5 4.00% Δn [589 nm, 20° C.]: 0.1095 BCH-32 5.00% Δε [1 kHz, 20° C.]: −3.5 CC-3-V1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.1 CCH-34 9.00% K.sub.1 [pN, 20° C.]: 14.1 CCH-35 7.00% K.sub.3 [pN, 20° C.]: 16.0 CCP-3-1 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 111 CCP-3-3 3.50% V.sub.0 [20° C., V]: 2.26 CCY-3-O2 10.50% CLY-3-O2 1.00% CPY-3-O2 5.50% CY-3-O2 11.50% PCH-301 13.00% PY-3-O2 2.00% PY-2-O2 10.00%
[0908] additionally comprises 0.015% of ST-3a-1.
Example M324
[0909] The liquid-crystalline mixture
TABLE-US-00265 CCY-3-O2 6.00% CCY-3-O1 7.00% CCY-4-O2 6.00% CLY-2-O4 5.00% CLY-3-O2 8.00% CLY-3-O3 5.00% PGIY-2-O4 3.50% B(S)—2O—O5 4.00% B(S)—2O—O4 4.00% CC-3-V 28.00% PY-3-O2 8.50% CY-3-O2 15.00%
[0910] additionally comprises 0.03% of ST-3a-1.
Example M325
[0911] The liquid-crystalline mixture
TABLE-US-00266 B(S)—2O—O4 5.00% Clearing point [° C.]: 74.2 B(S)—2O—O5 3.00% Δn [589 nm, 20° C.]: 0.1090 BCH-32 6.00% Δε [1 kHz, 20° C.]: −3.1 CC-3-V1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 14.4 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 16.3 CCH-35 8.50% γ.sub.1 [mPa .Math. s, 20° C.]: 104 CCP-3-1 7.50% V.sub.0 [20° C., V]: 2.40 CCP—V2-1 5.00% CCY-3-O2 12.00% CLY-3-O2 1.00% CY-3-O2 6.50% PCH-301 13.00% PY-3-O2 16.50%
[0912] additionally comprises 0.015% of ST-3a-1.
Example M326
[0913] The liquid-crystalline mixture
TABLE-US-00267 B(S)—2O—O4 3.50% Clearing point [° C.]: 75.2 B(S)—2O—O5 4.00% Δn [589 nm, 20° C.]: 0.1101 CC-3-V1 6.00% Δε [1 kHz, 20° C.]: −3.1 CCH-34 9.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-35 8.50% K.sub.1 [pN, 20° C.]: 14.0 CCP-3-1 8.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-3-3 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 107 CCY-3-O2 11.50% V.sub.0 [20° C., V]: 2.42 CLY-3-O2 1.00% CPY-3-O2 6.50% PCH-301 17.50% PY-3-O2 8.50% PY-2-O2 10.00%
[0914] additionally comprises 0.015% of ST-3a-1.
Example M327
[0915] The liquid-crystalline mixture
TABLE-US-00268 B(S)—2O—O4 3.50% Clearing point [° C.]: 75.0 B(S)—2O—O5 5.00% Δn [589 nm, 20° C.]: 0.1094 CC-3-V1 6.00% Δε [1 kHz, 20° C.]: −3.4 CCH-301 3.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CCH-34 9.00% K.sub.1 [pN, 20° C.]: 13.9 CCH-35 8.00% K.sub.3 [pN, 20° C.]: 16.4 CCP-3-1 8.50% γ.sub.1 [mPa .Math. s, 20° C.]: 108 CCY-3-O2 11.50% V.sub.0 [20° C., V]: 2.32 CLY-3-O2 1.00% CPY-3-O2 11.50% CY-3-O2 1.50% PCH-301 18.50% PY-3-O2 4.00% PY-2-O2 9.50%
[0916] additionally comprises 0.015% of ST-3a-1.
Example M328
[0917] The liquid-crystalline mixture
TABLE-US-00269 B(S)—2O—O4 5.00% Clearing point [° C.]: 74.4 B(S)—2O—O5 5.00% Δn [589 nm, 20° C.]: 0.1089 BCH-32 1.00% Δε [1 kHz, 20° C.]: −3.4 CC-3-V1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CCH-301 3.00% K.sub.1 [pN, 20° C.]: 14.3 CCH-34 9.00% K.sub.3 [pN, 20° C.]: 16.5 CCH-35 8.00% γ.sub.1 [mPa .Math. s, 20° C.]: 109 CCP-3-1 7.00% V.sub.0 [20° C., V]: 2.31 CCP-3-3 2.50% CCY-3-O2 12.00% CLY-3-O2 1.00% CPY-3-O2 6.50% CY-3-O2 3.00% PCH-301 17.50% PY-3-O2 13.50%
[0918] additionally comprises 0.015% of ST-3a-1.
Example M329
[0919] The liquid-crystalline mixture
TABLE-US-00270 CY-3-O2 15.00% PY-3-O2 5.50% CCY-3-O1 7.50% CCY-3-O2 11.00% CCY-4-O2 6.00% CPY-3-O2 11.00% CC-3-V 34.00% B(S)—2O—O5 3.00% B(S)—2O—O4 3.00% B—2O—O5 4.00%
[0920] additionally comprises 0.03% of ST-3a-1.
Example M330
[0921] The liquid-crystalline mixture
TABLE-US-00271 CY-3-O2 10.00% Clearing point [° C.]: 75.5 CCY-3-O1 7.50% Δn [589 nm, 20° C.]: 0.1019 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −5.1 CCY-4-O2 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 9.3 CPY-3-O2 11.50% K.sub.1 [pN, 20° C.]: 14.0 CC-3-V 36.00% K.sub.3 [pN, 20° C.]: 14.7 B(S)—2O—O5 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 103 B(S)—2O—O4 3.00% V.sub.0 [20° C., V]: 1.79 B—2O—O5 4.00% LTS [bulk, −20° C.]: >1000 h PGIY-2O—O4 4.50% Y—4O—O4 4.50%
[0922] additionally comprises 0.03% of ST-3a-1.
Example M331
[0923] The liquid-crystalline mixture
TABLE-US-00272 B(S)—2O—O4 5.00% B(S)—2O—O5 5.00% B—2O—O5 3.50% BCH-52 12.00% CCY-5-O2 12.00% CCH-301 6.50% CCH-34 23.00% PCH-302 12.00% PCH-53 13.00% PGIY-2-O4 8.00% PCH-301 17.50% PY-3-O2 13.50%
[0924] additionally comprises 0.03% of ST-3a-1.
Example M332
[0925] The liquid-crystalline mixture
TABLE-US-00273 CCY-3-O1 1.00% Clearing point [° C.]: 96.5 CLY-4-O2 5.50% Δn [589 nm, 20° C.]: 0.1039 CLY-3-O2 9.00% Δε [1 kHz, 20° C.]: −3.9 CLY-3-O3 5.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 17.7 CLY-5-O2 10.00% K.sub.3 [pN, 20° C.]: 18.8 CC-3-V 35.00% γ.sub.1 [mPa .Math. s, 20° C.]: 122 CC-3-V1 7.00% V.sub.0 [20° C., V]: 2.31 CY-3-O2 8.00% B(S)—2O—O4 3.00% B(S)—2O—O5 4.00% PGIY-2-O4 2.00%
[0926] additionally comprises 0.03% of ST-3a-1.
Example M333
[0927] The liquid-crystalline mixture
TABLE-US-00274 CC-3-V 42.50% Clearing point [° C.]: 80.0 B(S)—2O—O5 4.00% Δn [589 nm, 20° C.]: 0.1078 B(S)—2O—O4 4.00% Δε [1 kHz, 20° C.]: −3.9 CY-3-O2 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CCY-3-O2 7.00% K.sub.1 [pN, 20° C.]: 15.1 CLY-2-O4 4.00% K.sub.3 [pN, 20° C.]: 15.0 CLY-3-O2 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 92 CLY-3-O3 5.00% V.sub.0 [20° C., V]: 2.08 CLY-4-O2 4.00% LTS [bulk, −20° C.]: >1000 h CLY-5-O2 4.00% PGIY-2-O4 5.00% PYP-2-3 2.00% PY-3-O2 10.50%
[0928] additionally comprises 0.03% of ST-3a-1.
Example M334
[0929] The liquid-crystalline mixture
TABLE-US-00275 CC-3-V 40.50% Clearing point [° C.]: 80.0 CCP—V-1 7.00% Δn [589 nm, 20° C.]: 0.1020 CLY-2-O4 4.00% Δε [1 kHz, 20° C.]: −3.6 CLY-3-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CLY-3-O3 5.00% K.sub.1 [pN, 20° C.]: 14.1 CLY-4-O2 4.00% K.sub.3 [pN, 20° C.]: 14.8 CLY-5-O2 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 79 CPY-3-O2 3.50% V.sub.0 [20° C., V]: 2.14 CY-3-O2 6.00% PY-3-O2 4.00% PY-1-O2 8.00% B(S)—2O—O5 4.00% B(S)—2O—O4 4.00%
[0930] additionally comprises 0.03% of ST-3a-1.
Example M335
[0931] The liquid-crystalline mixture
TABLE-US-00276 B—2O—O5 4.50% Clearing point [° C.]: 75.5 CC-3-V 34.50% Δn [589 nm, 20° C.]: 0.1014 CCP-3-1 3.00% Δε [1 kHz, 20° C.]: −5.1 CLY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 9.2 CLY-3-O3 6.00% K.sub.1 [pN, 20° C.]: 14.2 CLY-5-O2 6.00% K.sub.3 [pN, 20° C.]: 14.8 CLY-4-O2 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 100 CPY-3-O2 8.50% V.sub.0 [20° C., V]: 1.80 Y—4O—O4 5.00% CY-3-O2 12.00% B(S)—2O—O5 4.00% B(S)—2O—O4 3.00%
[0932] additionally comprises 0.03% of ST-3a-1.
Example M336
[0933] The liquid-crystalline mixture
TABLE-US-00277 CC-3-V 40.00% Clearing point [° C.]: 76.0 CCP—V-1 6.50% Δn [589 nm, 20° C.]: 0.1017 CLY-2-O4 4.00% Δε [1 kHz, 20° C.]: −3.6 CLY-3-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CLY-3-O3 5.00% K.sub.1 [pN, 20° C.]: 14.2 CLY-4-O2 4.00% K.sub.3 [pN, 20° C.]: 14.7 CLY-5-O2 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 83 CPY-3-O2 4.50% V.sub.0 [20° C., V]: 2.12 CY-3-O2 7.00% PY-3-O2 11.00% B(S)—2O—O5 4.00% B(S)—2O—O4 4.00%
[0934] additionally comprises 0.03% of ST-3a-1.
Example M337
[0935] The liquid-crystalline mixture
TABLE-US-00278 CC-3-V 39.00% Clearing point [° C.]: 75.5 CCP—V-1 8.50% Δn [589 nm, 20° C.]: 0.1011 CLY-2-O4 4.00% Δε [1 kHz, 20° C.]: −3.6 CLY-3-O2 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.2 CLY-3-O3 5.00% K.sub.1 [pN, 20° C.]: 13.8 CLY-4-O2 4.00% K.sub.3 [pN, 20° C.]: 14.4 CLY-5-O2 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 79 CPY-3-O2 3.50% V.sub.0 [20° C., V]: 2.12 CY-3-O2 6.50% LTS [bulk, −20° C.]: >1000 h PY-3-O2 3.50% PY-2-O2 8.00% B(S)—2O—O5 4.00% B(S)—2O—O4 4.00%
[0936] additionally comprises 0.03% of ST-3a-1.
Example M338
[0937] The liquid-crystalline mixture
TABLE-US-00279 CCY-3-O1 0.50% Clearing point [° C.]: 96.5 CLY-4-O2 5.50% Δn [589 nm, 20° C.]: 0.1041 CLY-3-O2 9.00% Δε [1 kHz, 20° C.]: −4.0 CLY-3-O3 5.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CLY-5-O2 10.00% K.sub.1 [pN, 20° C.]: 17.7 CPY-3-O2 10.50% K.sub.3 [pN, 20° C.]: 18.9 CC-3-V 35.50% γ.sub.1 [mPa .Math. s, 20° C.]: 119 CC-3-V1 7.00% V.sub.0 [20° C., V]: 2.31 CY-3-O2 7.50% LTS [bulk, −20° C.]: >1000 h B(S)—2O—O5 4.00% B(S)—2O—O4 4.00% PGIY-2-O4 1.00%
[0938] additionally comprises 0.02% of ST-3a-1.
Example M339
[0939] The liquid-crystalline mixture
TABLE-US-00280 CLY-4-O2 5.50% Clearing point [° C.]: 96.5 CLY-3-O2 9.00% Δn [589 nm, 20° C.]: 0.1039 CLY-3-O3 5.50% Δε [1 kHz, 20° C.]: −4.0 CLY-5-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CPY-2-O2 2.00% K.sub.1 [pN, 20° C.]: 17.5 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 18.7 CC-3-V 35.50% γ.sub.1 [mPa .Math. s, 20° C.]: 119 CC-3-V1 7.00% V.sub.0 [20° C., V]: 2.30 CY-3-O2 7.50% B(S)—2O—O5 4.00% B(S)—2O—O4 4.00%
[0940] additionally comprises 0.03% of ST-3a-1 and 0.01% of ST-8-1.
Example M340
[0941] The liquid-crystalline mixture
TABLE-US-00281 CLY-4-O2 5.00% Clearing point [° C.]: 93.5 CLY-3-O2 9.00% Δn [589 nm, 20° C.]: 0.1041 CLY-3-O3 5.50% Δε [1 kHz, 20° C.]: −3.9 CLY-5-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CPY-3-O2 8.50% K.sub.1 [pN, 20° C.]: 17.2 CC-3-V 36.00% K.sub.3 [pN, 20° C.]: 18.3 CC-3-V1 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 113 CY-3-O2 8.50% V.sub.0 [20° C., V]: 2.28 B(S)—2O—O4 4.00% B(S)—2O—O5 4.00% PGIY-2-O4 2.50%
[0942] additionally comprises 0.02% of ST-8-1.
Example M341
[0943] The liquid-crystalline mixture
TABLE-US-00282 CC-3-V 18.50% CC-3-V1 7.00% CCP-3-1 11.00% CCY-3-O1 5.00% CCY-3-O2 8.00% CCY-4-O2 2.50% CLY-2-O4 4.50% CLY-3-O2 7.50% CLY-3-O3 6.50% CPY-3-O2 8.00% CY-3-O2 11.50% PGIY-2-O4 3.00% B(S)—2O—O4 4.00% B(S)—2O—O5 3.00%
[0944] additionally comprises 0.02% of ST-3a-1.
Example M342
[0945] The liquid-crystalline mixture
TABLE-US-00283 CC-3-V 35.50% CCP-3-1 2.50% CCY-3-O2 9.50% CLY-3-O2 8.00% CPY-2-O2 4.50% CPY-3-O2 10.50% CY-3-O2 14.50% PGIY-2-O4 6.00% PYP-2-3 2.00% B(S)—2O—O4 4.00% B(S)—2O—O5 3.00%
[0946] additionally comprises 0.03% of ST-3a-1.
Example M343
[0947] The liquid-crystalline mixture
TABLE-US-00284 B(S)—2O—O5 4.00% Clearing point [° C.]: 74.5 B(S)—2O—O4 3.00% Δn [589 nm, 20° C.]: 0.1091 BCH-32 8.00% Δε [1 kHz, 20° C.]: −3.1 CC-3-V1 9.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 15.2 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 16.2 CCH-35 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 100 CCP-3-1 11.00% V.sub.0 [20° C., V]: 2.41 CCP—V2-1 5.00% LTS [bulk, −20° C.]: >1000 h CCY-3-O2 7.00% CLY-3-O2 1.00% CY-3-O2 13.00% PCH-301 5.50% PY-3-O2 16.50%
[0948] additionally comprises 0.015% of ST-3a-1.
Example M344
[0949] The liquid-crystalline mixture
TABLE-US-00285 CY-3-O2 7.50% Clearing point [° C.]: 74.5 CCY-3-O1 6.00% Δn [589 nm, 20° C.]: 0.1031 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −5.0 CCY-4-O2 4.50% ε.sub.⊥ [1 kHz, 20° C.]: 9.1 CPY-3-O2 10.50% K.sub.1 [pN, 20° C.]: 13.5 CC-3-V 39.00% K.sub.3 [pN, 20° C.]: 14.4 B(S)-2O-O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 95 B(S)-2O-O4 4.00% V.sub.0 [20° C., V]: 1.79 B-2O-O5 5.00% PGIY-2-O4 4.50% Y-4O-O4 4.00%
[0950] additionally comprises 0.025% of ST-3a-1.
Example M345
[0951] The liquid-crystalline mixture
TABLE-US-00286 CY-3-O2 2.50% Clearing point [° C.]: 80.1 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1104 CCY-4-O2 1.50% Δε [1 kHz, 20° C.]: −4.0 CPY-2-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.8 CPY-3-O2 10.00% K.sub.1 [pN, 20° C.]: 14.5 PYP-2-3 3.00% K.sub.3 [pN, 20° C.]: 15.3 CLY-3-O2 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 102 CLY-3-O3 6.00% V.sub.0 [20° C., V]: 2.05 Y-4O-O4 6.00% PGIY-2-O4 6.00% B-2O-O5 5.00% CC-3-V 32.00% CC-3-V1 8.00%
[0952] additionally comprises 0.015% of ST-9-1.
Example M346
[0953] The liquid-crystalline mixture
TABLE-US-00287 B-2O-O5 5.00% Clearing point [° C.]: 75.5 CC-3-V 39.00% Δn [589 nm, 20° C.]: 0.1047 CCY-3-O2 11.00% Δε [1 kHz, 20° C.]: −5.9 CCY-3-O1 6.00% ε.sub.⊥ [1 kHz, 20° C.]: 10.2 CCY-4-O2 4.50% K.sub.1 [pN, 20° C.]: 14.8 CLY-3-O2 3.00% K.sub.3 [pN, 20° C.]: 14.4 CPY-3-O2 7.50% γ.sub.1 [mPa .Math. s, 20° C.]: 96 Y-4O-O4 5.00% V.sub.0 [20° C., V]: 1.65 B(S)-2O-O5 8.00% B(S)-2O-O4 8.00% CY-3-O2 3.00%
[0954] additionally comprises 0.03% of ST-3a-1.
Example M347
[0955] The liquid-crystalline mixture
TABLE-US-00288 B(S)-2O-O5 4.00% B(S)-2O-O4 3.00% BCH-32 8.00% CC-3-V 15.00% CC-3-V1 9.00% CCP-3-1 8.00% CCY-3-O1 7.00% CCY-3-O2 11.50% CLY-3-O2 1.00% CY-3-O2 15.00% PCH-301 5.00% PY-3-O2 13.50%
[0956] additionally comprises 0.025% of ST-3a-1.
Example M348
[0957] The liquid-crystalline mixture
TABLE-US-00289 B(S)-2O-O5 4.00% B(S)-2O-O4 3.00% BCH-32 8.00% CC-3-V 15.00% CC-3-V1 9.00% CCP-3-1 7.00% CCY-3-O1 7.00% CCY-3-O2 11.00% CCY-4-O2 2.50% CLY-3-O2 1.00% CY-3-O2 14.00% PCH-301 5.00% PY-1-O2 6.50% PY-2-O2 7.00%
Example M349
[0958] The liquid-crystalline mixture
TABLE-US-00290 B(S)-2O-O5 4.00% Clearing point [° C.]: 74.0 B(S)-2O-O4 3.00% Δn [589 nm, 20° C.]: 0.1094 BCH-32 8.00% Δε [1 kHz, 20° C.]: −3.7 CC-3-V1 9.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 14.6 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 16.0 CCH-35 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 107 CCP-3-1 9.50% V.sub.0 [20° C., V]: 2.20 CCY-3-O1 3.50% CCY-3-O2 11.00% CLY-3-O2 1.00% CY-3-O2 12.50% PCH-301 5.50% PY-1-O2 8.00% PY-2-O2 8.00%
[0959] additionally comprises 0.02% of ST-3a-1.
Example M350
[0960] The liquid-crystalline mixture
TABLE-US-00291 B(S)-2O-O5 4.00% B(S)-2O-O4 4.00% BCH-32 16.00% CCH-23 19.00% CCH-301 6.50% CCH-34 5.00% CCH-35 5.00% CCP-3-1 11.50% CLY-3-O2 8.00% PY-3-O2 10.00% PYP-2-3 4.00% Y-4O-O4 7.00%
[0961] additionally comprises 0.025% of ST-2a-1.
Example M351
[0962] The liquid-crystalline mixture
TABLE-US-00292 CC-3-V 47.00% CC-3-V1 6.50% CC-3-2V1 1.00% CCP-V-1 6.50% PGP-2-2V 13.00% PGP-3-2V 3.50% PGU-2-F 6.00% PGUQU-3-F 4.50% CLP-3-T 5.00% B(S)-2O-O5 3.50% B(S)-2O-O4 3.50%
[0963] additionally comprises 0.025% of ST-2a-1.
Example M352
[0964] The liquid-crystalline mixture
TABLE-US-00293 B(S)-2O-O5 4.00% B(S)-2O-O4 4.00% BCH-32 16.00% CCH-23 19.50% CCH-301 7.00% CCH-34 5.00% CCH-35 5.00% CCP-3-1 11.00% CLY-3-O2 8.00% PYP-3-O2 5.50% Y-4O-O4 7.00% PY-1-O2 4.00% PY-2-O2 4.00%
[0965] additionally comprises 0.025% of ST-3b-1.
Example M353
[0966] The liquid-crystalline mixture
TABLE-US-00294 B(S)-2O-O5 4.00% B(S)-2O-O4 4.00% BCH-32 16.00% CCH-23 18.00% CCH-301 3.00% CCH-34 4.00% CCH-35 4.00% CCP-3-1 13.50% CCP-3-3 4.00% CLY-3-O2 8.00% CPY-3-O2 1.50% PY-3-O2 2.00% PYP-2-3 5.50% Y-4O-O4 12.50%
[0967] additionally comprises 0.025% of ST-3b-1.
Example M354
[0968] The liquid-crystalline mixture
TABLE-US-00295 B(S)-2O-O5 4.00% B(S)-2O-O4 4.00% BCH-32 14.00% CCH-23 18.00% CCH-301 2.00% CCH-34 4.50% CCH-35 3.00% CCP-3-1 15.50% CCP-3-3 6.00% CLY-3-O2 8.00% PY-1-O2 4.00% PY-2-O2 4.00% PYP-2-3 3.00% Y-4O-O4 10.00%
[0969] additionally comprises 0.025% of ST-3b-1.
Example M355
[0970] The liquid-crystalline mixture
TABLE-US-00296 CCY-3-O1 7.00% Clearing point [° C.]: 92.5 CCY-3-O2 11.00% Δn [589 nm, 20° C.]: 0.0992 CCY-4-O2 5.00% Δε [1 kHz, 20° C.]: −4.5 CLY-3-O2 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.1 CLY-3-O3 5.00% K.sub.1 [pN, 20° C.]: 16.0 CLY-5-O2 5.00% K.sub.3 [pN, 20° C.]: 17.8 CPY-3-O2 2.50% γ.sub.1 [mPa .Math. s, 20° C.]: 124 PGIY-2-O4 4.00% V.sub.0 [20° C., V]: 2.10 CC-3-V 37.00% CY-3-O2 11.50% B(S)-2O-O5 4.00% B(S)-2O-O4 3.00%
[0971] additionally comprises 0.03% of ST-3a-1.
Example M356
[0972] The liquid-crystalline mixture
TABLE-US-00297 CCY-3-O1 6.50% Clearing point [° C.]: 91.5 CCY-3-O2 11.00% Δn [589 nm, 20° C.]: 0.0995 CLY-3-O2 5.00% Δε [1 kHz, 20° C.]: −4.5 CLY-3-O3 5.00% ε.sub.⊥ [1 kHz, 20° C.]: 8.1 CLY-4-O2 5.00% K.sub.1 [pN, 20° C.]: 16.1 CLY-5-O2 5.00% K.sub.3 [pN, 20° C.]: 17.5 CPY-3-O2 2.00% γ.sub.1 [mPa .Math. s, 20° C.]: 120 PGIY-2-O4 4.00% V.sub.0 [20° C., V]: 2.09 CC-3-V 37.50% CY-3-O2 12.00% B(S)-2O-O5 4.00% B(S)-2O-O4 3.00%
[0973] additionally comprises 0.03% of ST-3a-1.
Example M357
[0974] The liquid-crystalline mixture
TABLE-US-00298 B(S)-2O-O5 4.00% Clearing point [° C.]: 74.5 B(S)-2O-O4 3.00% Δn [589 nm, 20° C.]: 0.1094 BCH-32 8.00% Δε [1 kHz, 20° C.]: −3.4 CC-3-V1 9.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.1 CCH-301 2.00% K.sub.1 [pN, 20° C.]: 15.4 CCH-34 8.00% K.sub.3 [pN, 20° C.]: 16.4 CCH-35 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 104 CCP-3-1 12.00% V.sub.0 [20° C., V]: 2.31 CCY-3-O2 11.00% CLY-3-O2 1.00% CY-3-O2 13.00% PCH-301 5.50% PY-2-3 16.50%
[0975] additionally comprises 0.02% of ST-3a-1.
Example M358
[0976] The liquid-crystalline mixture
TABLE-US-00299 CC-3-V 45.50% Clearing point [° C.]: 76.0 CCY-3-O2 1.00% Δn [589 nm, 20° C.]: 0.1036 CLY-3-O2 7.00% Δε [1 kHz, 20° C.]: −3.5 CLY-3-O3 7.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.1 CPY-3-O2 11.00% K.sub.1 [pN, 20° C.]: 13.5 CY-3-O2 13.00% K.sub.3 [pN, 20° C.]: 14.6 B(S)-2O-O4 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 80 B(S)-2O-O5 4.00% V.sub.0 [20° C., V]: 2.16 PGIY-2-O4 7.50% PYP-2-3 1.50%
[0977] additionally comprises 0.03% of ST-3a-1.
Example M359
[0978] The liquid-crystalline mixture
TABLE-US-00300 CC-3-V 44.00% Clearing point [° C.]: 75.0 CCY-3-O2 7.50% Δn [589 nm, 20° C.]: 0.1035 CLY-3-O2 7.00% Δε [1 kHz, 20° C.]: −3.7 CPY-3-O2 11.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.3 CY-3-O2 15.00% K.sub.1 [pN, 20° C.]: 13.4 B(S)—2O—O4 3.00% K.sub.3 [pN, 20° C.]: 14.9 B(S)—2O—O5 4.00% γ.sub.1 [mPa .Math. s, 20° C.]: 82 PGIY-2-O4 7.00% V.sub.0 [20° C., V]: 2.13 PYP-2-3 1.50%
[0979] additionally comprises 0.03% of ST-3a-1.
Example M360
[0980] The liquid-crystalline mixture
TABLE-US-00301 CC-3-V 41.00% Clearing point [° C.]: 74 CCY-3-O1 3.00% Δn [589 nm, 20° C.]: 0.1007 CCY-3-O2 10.00% Δε [1 kHz, 20° C.]: −3.8 CPY-2-O2 10.50% ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CPY-3-O2 11.00% K.sub.1 [pN, 20° C.]: 12.7 CY-3-O2 16.00% K.sub.3 [pN, 20° C.]: 14.6 PGIY-2-O4 4.50% γ.sub.1 [mPa .Math. s, 20° C.]: 90 B—2O—O5 4.00% V.sub.0 [20° C., V]: 2.07
[0981] additionally comprises 0.03% of ST-3a-1.
Example M361
[0982] The liquid-crystalline mixture
TABLE-US-00302 B—2O—O5 4.00% Clearing point [° C.]: 109.8 BCH-32 2.00% Δn [589 nm, 20° C.]: 0.1059 CC-3-V 25.00% Δε [1 kHz, 20° C.]: −4.1 CC-3-V1 4.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CCP-3-1 4.00% K.sub.1 [pN, 20° C.]: 19.0 CCY-3-O1 5.00% K.sub.3 [pN, 20° C.]: 18.9 CCY-3-O2 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: 145 CCY-4-O2 6.00% V.sub.0 [20° C., V]: 2.28 CCY-5-O2 6.00% CLY-3-O2 6.00% CLY-3-O3 6.00% CPY-2-O2 9.00% CPY-3-O2 9.00% CY-5-O4 8.00%
[0983] additionally comprises 0.04% of ST-3b-1.
Example M362
[0984] The liquid-crystalline mixture
TABLE-US-00303 B—2O—O5 4.00% Clearing point [° C.]: CC-3-V 37.00% Δn [589 nm, 20° C.]: CCP-3-1 4.00% Δε [1 kHz, 20° C.]: CCY-3-O2 8.00% ε.sub.⊥ [1 kHz, 20° C.]: CCY-4-O2 3.00% K.sub.1 [pN, 20° C.]: CLY-3-O2 6.00% K.sub.3 [pN, 20° C.]: CLY-3-O3 6.00% γ.sub.1 [mPa .Math. s, 20° C.]: CPY-3-O2 9.50% V.sub.0 [20° C., V]: CY-3-O2 13.00% PGIY-2-O4 2.00% PYP-2-3 4.00% PYP-2-4 3.50%
[0985] additionally comprises 0.03% of ST-3a-1.
Example M363
[0986] The liquid-crystalline mixture
TABLE-US-00304 B—2O—O5 4.00% Clearing point [° C.]: 104 CC-3-V 14.00% Δn [589 nm, 20° C.]: 0.1059 CC-3-V1 5.00% Δε [1 kHz, 20° C.]: −5.2 CCP-3-1 7.00% ε.sub.⊥ [1 kHz, 20° C.]: 9.0 CCY-3-O1 6.00% K.sub.1 [pN, 20° C.]: 17.5 CCY-3-O2 7.50% K.sub.3 [pN, 20° C.]: 19.0 CCY-4-O2 7.00% γ.sub.1 [mPa .Math. s, 20° C.]: 171 CCY-5-O2 4.00% V.sub.0 [20° C., V]: 2.02 CLY-2-O4 4.00% CLY-3-O2 6.00% CLY-3-O3 6.00% CPY-3-O2 8.00% CY-3-O2 12.00% CY-5-O4 7.50% PGIY-2-O4 2.00%
[0987] additionally comprises 0.04% of ST-3b-1.
Example M364
[0988] The liquid-crystalline mixture
TABLE-US-00305 B—2O—O5 3.00% Clearing point [° C.]: 75.4 CC-3-V 39.00% Δn [589 nm, 20° C.]: 0.1074 CC-3-V1 8.00% Δε [1 kHz, 20° C.]: −2.7 CCP—V-1 4.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.2 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 13.7 CPY-2-O2 10.00% K.sub.3 [pN, 20° C.]: 14.3 CPY-3-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 77 PGIY-2-O4 6.00% V.sub.0 [20° C., V]: 2.44 PYP-2-3 3.50% PYP-2-4 2.00% Y—4O—O4 6.00%
[0989] additionally comprises 0.03% of ST-3a-1.
Example M365
[0990] The liquid-crystalline mixture
TABLE-US-00306 B—2O—O5 4.00% Clearing point [° C.]: 70.6 CC-3-V 40.00% Δn [589 nm, 20° C.]: 0.1072 CC-3-V1 1.50% Δε [1 kHz, 20° C.]: −2.5 CC-4-V 10.50% ε.sub.⊥ [1 kHz, 20° C.]: 5.9 CLY-3-O2 8.00% K.sub.1 [pN, 20° C.]: 13.1 CPY-2-O2 6.50% K.sub.3 [pN, 20° C.]: 13.1 CPY-3-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 70 PGIY-2-O4 6.00% V.sub.0 [20° C., V]: 2.40 PY-3-O2 9.50% PYP-2-3 4.00%
[0991] additionally comprises 0.03% of ST-3a-1.
Example M366
[0992] The liquid-crystalline mixture
TABLE-US-00307 B—2O—O5 4.00% Clearing point [° C.]: 75.5 CC-3-V 40.00% Δn [589 nm, 20° C.]: 0.1083 CC-3-V1 3.00% Δε [1 kHz, 20° C.]: −2.7 CC-4-V 6.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.1 CCP—V-1 2.50% K.sub.1 [pN, 20° C.]: 13.7 CLY-3-O2 8.00% K.sub.3 [pN, 20° C.]: 14.2 CPY-2-O2 10.00% γ.sub.1 [mPa .Math. s, 20° C.]: 76 CPY-3-O2 10.00% V.sub.0 [20° C., V]: 2.42 PGIY-2-O4 6.00% PY-3-O2 9.00% PYP-2-3 1.00%
[0993] additionally comprises 0.02% of ST-2a-1.
Example M367
[0994] The liquid-crystalline mixture
TABLE-US-00308 B—2O—O5 4.00% Clearing point [° C.]: 70.2 CC-3-V 40.00% Δn [589 nm, 20° C.]: 0.1066 CC-3-V1 6.00% Δε [1 kHz, 20° C.]: −2.5 CC-4-V 3.50% ε.sub.⊥ [1 kHz, 20° C.]: 6.0 CCP—V-1 3.00% K.sub.1 [pN, 20° C.]: 12.8 CLY-3-O2 8.00% K.sub.3 [pN, 20° C.]: 13.2 CPY-2-O2 4.50% γ.sub.1 [mPa .Math. s, 20° C.]: 69 CPY-3-O2 10.00% V.sub.0 [20° C., V]: 2.43 PGIY-2-O4 6.00% PYP-2-3 9.00% Y—4O—O4 6.00%
[0995] additionally comprises 0.03% of ST-3a-1.
Example M368
[0996] The liquid-crystalline mixture
TABLE-US-00309 CY-3-O2 12.00% Clearing point [° C.]: 74.8 CY-5-O2 12.00% Δn [589 nm, 20° C.]: 0.1026 CCY-3-O2 3.50% Δε [1 kHz, 20° C.]: −4.0 CLY-3-O2 10.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.9 CPY-2-O21 10.00% K.sub.1 [pN, 20° C.]: 12.8 CPY-3-O2 10.00% K.sub.3 [pN, 20° C.]: 14.2 B—2O—O5 5.00% γ.sub.1 [mPa .Math. s, 20° C.]: 83 CC-3-V 32.00% V.sub.0 [20° C., V]: 1.98 BCH-32 5.50%
[0997] additionally comprises 0.03% of ST-3a-1.
Example M369
[0998] The liquid-crystalline mixture
TABLE-US-00310 B—2O—O5 4.00% Clearing point [° C.]: 74.2 BCH-32 8.00% Δn [589 nm, 20° C.]: 0.1089 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.1 CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-34 9.00% K.sub.1 [pN, 20° C.]: 14.1 CCH-35 7.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-3-1 8.50% γ.sub.1 [mPa .Math. s, 20° C.]: 109 CCY-3-O2 11.00% V.sub.0 [20° C., V]: 2.43 CLY-3-O2 0.50% CPY-3-O2 6.50% CY-3-O2 10.00% PCH-301 9.00% PY-3-O2 15.50%
[0999] additionally comprises 0.015% of ST-3a-1.
Example M370
[1000] The liquid-crystalline mixture
TABLE-US-00311 B—2O—O5 4.00% Clearing point [° C.]: 74.2 BCH-32 8.00% Δn [589 nm, 20° C.]: 0.1094 CC-3-V1 9.00% Δε [1 kHz, 20° C.]: −3.1 CCH-301 2.00% ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCH-34 9.00% K.sub.1 [pN, 20° C.]: 14.2 CCH-35 7.00% K.sub.3 [pN, 20° C.]: 16.5 CCP-3-1 8.50% γ.sub.1 [mPa .Math. s, 20° C.]: 108 CCY-3-O2 10.00% V.sub.0 [20° C., V]: 2.43 CLY-3-O2 1.50% CPY-3-O2 6.50% CY-3-O2 10.00% PCH-301 9.00% PY-3-O2 15.50%
[1001] additionally comprises 0.015% of ST-3a-1.
Example M371
[1002] The liquid-crystalline mixture
TABLE-US-00312 CC-3-V 44.50% Clearing point [° C.]: 74.0 CCY-3-O2 11.00% Δn [589 nm, 20° C.]: 0.1010 CPY-2-O2 9.50% Δε [1 kHz, 20° C.]: −3.7 CPY-3-O2 11.00% ε.sub.∥ [1 kHz, 20° C.]: 3.7 CY-3-O2 13.00% ε.sub.⊥ [1 kHz, 20° C.]: 7.4 PGIY-2-O4 4.00% K.sub.1 [pN, 20° C.]: 13.0 B—2O—O5 4.00% K.sub.3 [pN, 20° C.]: 14.5 B(S)—2O—O4 3.00% γ.sub.1 [mPa .Math. s, 20° C.]: 83 V.sub.0 [20° C., V]: 2.09
[1003] additionally comprises 0.02% of ST-8-1.
[1004] The mixtures of Examples M1 to M371 comprising one or more stabilisers are distinguished by very good reliability.