Injected metal bead channel seal achieved through stamped plate features on fuel cell bipolar plates
09847536 · 2017-12-19
Assignee
Inventors
Cpc classification
Y02P70/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M2250/20
ELECTRICITY
Y02T90/40
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
H01M8/0271
ELECTRICITY
Abstract
A fuel cell system with reduced leakage and a method of assembling a fuel cell system. Bipolar plates within the system include reactant channels and coolant channels that are fluidly coupled to inlet and outlet flowpaths, all of which are formed within a coolant-engaging or reactant-engaging surface of the plate. One or more seals are also formed on the fluid-engaging surface to help reduce leakage by maintaining fluid isolation of the reactants and coolant as they flow through their respective channels and flowpaths that are defined between adjacently-placed plates. The seal—with its combination of in-plane and out-of-plane dimensions—forms a substantially hollow volume, into which a plug is placed to reduce the tendency of the seal to form a shunted flow of the coolant or reactant around the intended active area of the plate. A fluid port intersection is integrally formed with the seal and is formed to be fluidly cooperative with the volume, and is capable of accepting the introduction of a fluent precursor of the plug material such that upon curing, the precursor material forms a substantially rigid insert that continuously fills both the volume and intersection, thereby increasing the resistance of the plug to movement and the seal to shunted flow. In one form, the geometry of the fluent material injection site is such that it promotes plug anchoring within its intended location, while also providing a manufacturing aid to visually inspect for plug installation, as well as to serve as a bipolar plate stacking alignment locator and verification.
Claims
1. A fuel cell system defining a plurality of fuel cells arranged in a stacked configuration, each of the cells within the system comprising: a membrane electrode assembly; and a bipolar plate placed in fluid cooperation with the membrane electrode assembly, the plate defining a fluid-engaging surface and comprising: at least one of reactant channels and coolant channels defined in the fluid-engaging surface; inlet and outlet flowpaths defined in the fluid-engaging surface such that both are in fluid communication with a respective one of the reactant and coolant channels; at least one seal disposed on the fluid-engaging surface such that upon cooperative engagement with an adjacently-placed one of the plates, the seal provides substantial fluid isolation of a fluid that is being conveyed through a respective one of the reactant and coolant channels, the seal defining a substantially hollow volume and a fluent material introduction aperture formed therein; and a plug disposed within at least a portion of the volume that is adjacent the aperture, the plug defined by at least a portion of fluent material being introduced through the aperture such that upon curing the plug forms a substantially rigid insert that substantially blocks leakage flow through the volume, wherein the plug is defined by differing material hardness values at various locations within the at least one seal.
2. The fuel cell system of claim 1, wherein the cooperative engagement between the seal on a first of the stacked plates and an adjacently-placed second of the stacked plates comprises contact between the seal disposed on the first plate and a substantially planar surface of the second plate.
3. A vehicle comprising the fuel cell system of claim 1.
4. A fuel cell bipolar plate defining a substantially planar fluid-engaging surface, the plate comprising: at least one of reactant channels and coolant channels defined in the fluid-engaging surface; inlet and outlet flowpaths defined in the fluid-engaging surface such that both are in fluid communication with a respective one of the reactant and coolant channels; at least one seal disposed on the fluid-engaging surface such that upon cooperative engagement with an adjacently-placed one of the plates, the seal provides substantial fluid isolation of a fluid that is being conveyed through a respective one of the reactant and coolant channels, the seal defining a substantially hollow volume and a fluent material introduction aperture formed therein; and a plug disposed within at least a portion of the volume that is adjacent the aperture, the plug defined by at least a portion of fluent material being introduced through the aperture such that upon curing the plug forms a substantially rigid insert that substantially blocks leakage flow through the volume, wherein the plug is defined by differing material hardness values at various locations within the seal.
5. The plate of claim 4, wherein the fluid-engaging surface defines (a) an active region corresponding to the reactant and flowpath channels, and (b) a manifold region corresponding to the inlet and outlet flowpaths.
6. The plate of claim 5, wherein the seal comprises a plurality of seals, each forming a substantially peripheral path around one of the reactant and flowpath channels and the inlet and outlet flowpaths within respective active and manifold regions.
7. The plate of claim 4, wherein the seal is integrally formed as a part of the fluid-engaging surface.
8. The plate of claim 7, wherein the seal defines a substantially peripheral path around at least one of an active region and a manifold region that are defined within the fluid-engaging surface.
9. The plate of claim 8, wherein the aperture is defined in an intersection that is formed in the seal such that the intersection defines a laterally projecting additional volume in the seal.
10. The plate of claim 4, wherein the plate is formed of a laminate of at least two sheets such that a lower sheet defines a substantially planar lower surface and an upper plate defines the fluid-engaging surface so that the volume is defined by cooperative engagement of the two sheets.
11. A method of sealing a bipolar plate within a fuel cell system, the method comprising: placing at least a pair of plates on top of one another in a stacked configuration, at least one of the plates defining a fluid-engaging surface thereof and comprising: at least one of reactant channels and coolant channels defined therein; inlet and outlet flowpaths defined therein such that each are in fluid communication with a respective one of the reactant and coolant channels; and at least one seal disposed on the fluid-engaging surface such that upon cooperative engagement between the pair of plates, the seal provides substantial fluid isolation of a reactant or coolant that is being conveyed through a respective one of the reactant and coolant channels, the seal defining a substantially hollow volume therein; and introducing a fluent material into an aperture formed in the volume such that the volume occupies a substantial cross-sectional entirety defined by the volume at least in a region within the seal that is adjacent a location within the seal where the fluent material is introduced; and curing the material such that it forms a substantially rigid plug in the seal region, the plug defining differing material hardness values at various locations within the seal region.
12. The method of claim 11, wherein the fluid-engaging surface defines a coolant path.
13. The method of claim 11, wherein the fluid-engaging surface defines (a) an active region corresponding to the reactant and flowpath channels, and (b) a manifold region corresponding to the inlet and outlet flowpaths.
14. The method of claim 13, wherein the seal comprises a plurality of seals, each forming a substantially peripheral path around one of the reactant and flowpath channels and the inlet and outlet flowpaths within respective active and manifold regions.
15. The method of claim 14, wherein the aperture is defined in an intersection that is fluidly cooperative with the volume.
16. The method of claim 11, further comprising establishing visual indicia of a presence of the fluent material within the volume.
17. The method of claim 16, wherein the visual indicia is defined by the fluent material being formed with a pigment that provides a color contrast relative to the seal.
18. The method of claim 16, wherein establishing visual indicia comprises using a computer controlled vision system.
19. The method of claim 11, further comprising establishing visual indicia with the aperture to indicate alignment of the at least a pair of the plates within the stacked configuration.
20. The method of claim 19, wherein placing at least a pair of plates on top of one another in a stacked configuration comprises laser welding the plates together into a bipolar plate assembly prior to introducing the fluent material.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The following detailed description of the preferred embodiments of the present invention can be best understood when read in conjunction with the following drawings, where like structure is indicated with like reference numerals and in which the various components of the drawings are not necessarily illustrated to scale:
(2)
(3)
(4)
DETAILED DESCRIPTION OF THE EMBODIMENTS
(5) Referring initially to
(6) In addition to providing a substantially porous flowpath for reactant gases to reach the appropriate side of the proton exchange membrane 10, the diffusion layers 50 and 60 provide electrical contact between the electrode catalyst layers 20, 30 and a bipolar plate 70 that in turn acts as a current collector. Moreover, by its generally porous nature, the diffusion layers 50 and 60 also form a conduit for removal of product gases generated at the catalyst layers 20, 30. Furthermore, the cathode diffusion layer 60 generates significant quantities of water vapor in the cathode diffusion layer. Such feature is important for helping to keep the proton exchange membrane 10 hydrated. Water permeation in the diffusion layers can be adjusted through the introduction of small quantities of polytetrafluoroethylene (PTFE) or related material.
(7) Although shown notionally as having a thick-walled attributes, bipolar plates 70 preferably employ sheet-like or foil-like structure (as will be shown and described in more detail below); as such,
(8) In operation, a first gaseous reactant, such as H.sub.2, is delivered to the anode 20 side of the MEA 40 through the channels 72 from plate 70A, while a second gaseous reactant, such as O.sub.2 (typically in the form of air) is delivered to the cathode 30 side of the MEA 40 through the channels 72 from plate 70B. Catalytic reactions occur at the anode 20 and the cathode 30 respectively, producing respective protons at the anode 20 that migrate through the proton exchange membrane 10 and electrons at the cathode 30 that result in an electric current that may be transmitted through the diffusion layers 50 and 60 and bipolar plate 70 by virtue of contact between the lands 74B and the layers 50 and 60.
(9) In a manner generally similar to the shown reactant-conveying channels, related channels (not shown) may be used to convey coolant to help control temperatures produced by the fuel cell 1. Such plates may be formed on separate surfaces (for example, on the respective top and bottom surfaces) of the first and second plates 70A and 70B Likewise, the plates 70A, 70B may be formed of multiple built-up sheets (such as by the lamination of thinner stacked layers or the like); this may help facilitate the formation of a substantially enclosed volume within the seals, as will be discussed in more detail below. Regardless of the construction, such plate varieties (whether coolant-carrying or other fluid-carrying) are understood within the present context to otherwise include comparable features as their reactant-conveying plate counterparts; as such, structural details associated with the surface-defining features are deemed to be comparable. Furthermore, those skilled in the art will recognize that the channel sealing design that is described in the present invention is also applicable to non-fuel cell applications where a coolant flow is shunted through the back of a formed geometric sealing surface.
(10) Referring next to
(11) In the present context, the stacking axis of the fuel cell 1 may be along a substantially vertical (i.e., Z) Cartesean axis so that the majority of the surface of each of the bipolar plates 70 is in the X-Y plane. Regardless, it will be appreciated by those skilled in the art that the particular orientation of the cells 1, plates 70 and stack isn't critical, but rather provides a convenient way to visualize the landscape that is formed on the surfaces of the plates 70.
(12) Referring next to
(13) The seals 70.sub.S generally form peripheral racetrack-like features that project out of the XY plane of the plate 70 fluid-engaging surface along the Z-axis to give the plate 70 slightly three-dimensional attributes; when facingly-adjacent plates 70 are stacked relative to one another, the seals 70.sub.S come into contact with one another to provide enhanced resistance to coolant or reactant leakage across their boundary. In a similar fashion, the generally planar lower surface on an adjacently-placed plate 70 (not shown) may also be made to contact the top of seal 70.sub.S that projects along the Z-axis to produce a comparable contact; either contact variant is deemed to be within the scope of the present invention. Additionally, a microseal 90 may be formed along part of all of the length of seal 70.sub.S.
(14) In the version shown, an intersection 70.sub.I is formed lateral (i.e., along the Y-axis) relative to seals 70.sub.S at one or more locations along the axial length of the seals 70.sub.S. In the embodiment shown, the intersection 70.sub.I defines a side-branching T-shape, while the contiguous nature of its internal cavity and that of the volume 70.sub.V helps ensure that the material—upon curing into a plug 80—will have a shape or related geometric feature to promote its secure anchoring within the combined volume 70.sub.V to further reduce the tendency of the plug 80 to move axially in response to impingement by the pressurized reactant, coolant or other fluid agent. In one form, the intersection 70.sub.I may define an integral part of seal 70.sub.S, while its open cavity-like structure helps ensure a continuity with the volume 70.sub.V formed along the axial dimension of the seal 70.sub.S. In this way, intersection 70.sub.I forms a separate, dead-ended branch that accepts a continuous mass of fluent material that makes up the plug 80. Although shown presently as having a substantially perpendicular intersection such that a T-shaped connection is formed, the joining angle between seal 70.sub.S and intersection 70.sub.I may be varied, and all such forms are deemed to be within the scope of the present invention. The intersection 70.sub.I is constructed such to avoid interference with the sealing functionality of the seal 70.sub.S geometry. For example, the Z-axis of the intersection 70.sub.I is preferably no more than, and even more particularly less than the adjacent seal 70.sub.S. In addition, intersection 70.sub.I is preferably placed in non-sensitive portion of the perimeter of seal 70.sub.S; this is best depicted in
(15) With regard to such a configuration (not shown) where the intersection 70.sub.I is removed altogether, a direct injection site (via, for example, an aperture similar to aperture 70.sub.O but instead placed in the X-Y into the side of seal 70.sub.S) is formed. Even though there is technically no interference between the inner wall of seal 70.sub.S and the plug 80, when the elastomer is injected into the 70.sub.S, it would instead form a line-to-line fit. Depending upon the material, it could even contract during the curing process. Regardless, the geometric variation would occur along the axis of the flow passage (i.e., the X-axis direction as shown in
(16) The plug 80 is preferably made from an injectable, elastic, compliant material (such as the aforementioned silicone, elastomer, polymer or the like) that can be cured once injected. In addition to having a suitably high coefficient of friction, other desirable properties of the precursor material preferably include corrosion resistance, contamination avoidance, stiffness properties (durometer) as a function of the amount of mechanical deformation imparted during stack compression, and sufficient bonding with the metal surfaces of the internal volume of the bead channels that make up seals 70.sub.S to promote plug formation upon curing. Significantly, the presence of the plug 80 promotes a blocking action within the volume 70.sub.V such that it changes the so-called “path of least resistance” away from the seals 70.sub.S that could otherwise exist. In particular, the presence of the plug 80 within the volume 70.sub.V formed by seal 70.sub.S helps to reduce the tendency of the racetrack-like flowpath or channel that is defined by volume 70.sub.V to permit coolant or reactant flow to shunt (i.e., bypass) around the active region 70.sub.ACT. During the plug-forming operation, a sufficient quantity of the fluent sealant material would be injected to cause it to flow into the volume 70.sub.V and occupy a significant entirety of the cross-sectional area defined within the seal 70.sub.S such that it prevents (depending on which channels 72 within the bipolar plates 70 are being utilized) reactant or coolant that has entered the seal 70.sub.S from traveling along the axial length of seal 70.sub.S beyond where the plug 80 is placed.
(17) Although preferably made from a relatively compliant material, plug 80 may change the stiffness of the seal 70.sub.S; this may become a larger factor in configurations where the plug 80 is only injected over a short section of the seal 70.sub.S, where it can cause localized changes in stiffness and sealing properties that may not be present in configurations where the plug 80 is injected over the entire length of the seal 70.sub.S. In such circumstances, proper selection of the precursor material properties is beneficial in that a property (such as the durometer value for stiffness or hardness) is properly matched to the requirements of the seal 70.sub.S. Thus, along differing places within the volume 70.sub.V, the plug may be made up of differing material hardness values. In other embodiments (not shown) the geometry and sealing requirements for the seal 70.sub.S will vary over the surface of the bi-polar plate 70. In yet another embodiment, multiple different precursor materials may be injected in various locations (such as through various apertures 70.sub.O spread along the length or periphery of the seal 70.sub.S; in this way, the seal 70.sub.S and its sealing properties may be “tuned” in accordance with the bi-polar plate 70 geometry and material stiffness requirements at various positions around the plate 70. For example, the large seals seal 70.sub.S around the manifold area 70.sub.M may require different seal properties than the long passages along the active area 70.sub.ACT.
(18) As mentioned above, an aperture (i.e., opening) 70.sub.O is formed through either the intersection 70.sub.I (as shown) or a sidewall defined in seal 70.sub.S to define a port for injecting the precursor material that will become the channel plug 80; it also serves the additional functions of providing an access point to verify that the channel plug was created during the manufacturing process, as well as serving as a manufacturing locator to aid plate assembly and aligned stacking. This promotes ease of subsequent inspection activities (either visually, or by an automated detector coupled to a suitable computer or related controller). As additionally mentioned above, the plug 80 employs suitable material properties (such as mechanical strength, corrosion resistance, curing time or the like) commensurate with its intended function without interfering with the cell-to-cell seal 70.sub.S functional requirements related to compressibility, electrical conductivity or the like. In a preferred form, the fluent precursor material is injected via aperture 70.sub.O to fill both the T-shaped intersection 70.sub.I and at least an adjacent portion of the main channel or volume of seal 70.sub.S, thereby creating the desired anchoring and consequent blockage of the channel to leakage fluid flow. As mentioned above, the nature of such anchoring is secure enough (regardless of whether the additional anchoring due to the presence of additional contiguous material in the intersection 70.sub.I is present) to reduce the tendency of plug 80 to move under an axial fluid load that arises out of leakage into the channel (such as that of leaked coolant, reactant or the like). As mentioned above, in the configuration depicted in the figure, only the region immediately adjacent the aperture 70.sub.O where the material is introduced to the volume 70.sub.V need be used to achieve the desired blocking effect without the cost or complexity associated with completely filling the volume 70.sub.V over the entire flowpath length of seal 70.sub.S.
(19) Although not shown, one particular application for a system based on a stack of PEM fuel cells 1 could be an automobile or related vehicle. Within the present context, it will be appreciated that the term “vehicle” may apply to car, truck, van, sport utility vehicle (SUV) or other such automotive forms such as buses, aircraft, watercraft, spacecraft and motorcycles; all are deemed to be made cooperative with the present invention for the purposes of generating propulsive or motive power.
(20) It is noted that terms like “preferably”, “generally” and “typically” are not utilized herein to limit the scope of the claimed invention or to imply that certain features are critical, essential, or even important to the structure or function of the claimed invention. Rather, these terms are merely intended to highlight alternative or additional features that may or may not be utilized in a particular embodiment of the present invention.
(21) In the present context, the terms relating to the channels, flowpaths and other coolant-conveying or reactant-conveying features formed into or on the fluid-engaging surfaces of the bipolar plates 70 are interchangeably referred to in the singular or the plural. While the distinction between whether such refers to an individual channel or flowpath of a group of them aligned along a generally parallel flowpath is not critical to the seals 70.sub.S of the present invention; as such, any particular identification of one over the other will be apparent from the context, and either are deemed to be within the scope of the present invention.
(22) For the purposes of describing and defining the present invention, it is noted that the terms “substantially” and “approximately” and their variants are utilized herein to represent the inherent degree of uncertainty that may be attributed to any quantitative comparison, value, measurement or other representation. The term “substantially” is also utilized herein to represent the degree by which a quantitative representation may vary from a stated reference without resulting in a change in the basic function of the subject matter at issue.
(23) Having described the invention in detail and by reference to specific embodiments, it will nonetheless be apparent that modifications and variations are possible without departing from the scope of the invention defined in the appended claims. In particular it is contemplated that the scope of the present invention is not necessarily limited to stated preferred aspects and exemplified embodiments, but should be governed by the appended claims.