LIGHT EMITTING DEVICE WITH TRENCH BENEATH A TOP CONTACT
20170358707 · 2017-12-14
Inventors
Cpc classification
H01L33/10
ELECTRICITY
H01L33/06
ELECTRICITY
International classification
H01L33/10
ELECTRICITY
H01L33/20
ELECTRICITY
H01L33/06
ELECTRICITY
Abstract
Embodiments of the invention are directed to structures in a vertical light emitting device that prevent light from being generated beneath absorbing structures, and/or direct light away from absorbing structures. Embodiments of the invention include a semiconductor structure including a light emitting layer disposed between an n-type region and a p-type region. A bottom contact is disposed on a bottom surface of the semiconductor structure. The bottom contact is electrically connected to one of the n-type region and the p-type region. A top contact is disposed on a top surface of the semiconductor structure. The top contact is electrically connected to the other of the n-type region and the p-type region. The top contact includes a first side and a second side opposite the first side. A first trench is formed in the semiconductor structure beneath the first side of the top contact. A second trench is formed in the seminconductor structure beneath the second side of the top contact.
Claims
1. A device comprising: a semiconductor structure comprising a light emitting layer disposed between an upper region and a lower region of opposite conductivity; a top contact disposed on a top surface of the semiconductor structure, the top contact being electrically connected to the upper region; and a trench formed in a bottom surface of the semiconductor structure beneath the top contact, the trench extending from the bottom surface without penetrating the light emitting layer; a reflective layer disposed over the bottom surface and in the trench, the reflective layer in the trench forming at least part of a mirror that reflects light away from the top contact; and. a filler material disposed in a void where the reflective layer does not completely fill the trench.
2. The device of claim 1 wherein the trench is aligned with and disposed beneath the top contact and at least a portion of the trench is substantially the same width as the top contact overlying the trench.
3. (canceled)
4. The device of claim 1 wherein the light emitting layer is a III-nitride material.
5. The device of claim 1 wherein the light emitting layer is AlInGaP.
6. The device of claim 1 further comprising a dielectric layer lining the bottom surface and the trench, the dielectric layer in the trench forming part of the mirror that reflects light away from the top contact, the reflective layer being disposed on the dielectric layer over the bottom surface and in the trench, the reflective layer being electrically isolated from the semiconductor structure by the dielectric layer.
7. The device of claim 1 wherein at least one sidewall of the trench is angled 30° to 90° relative to a normal to the top surface of the semiconductor structure.
8. The device of claim 1 wherein: the upper region is an n-type region; the top contact is electrically connected to the n-type region; the lower region is a p-type region; and a deepest point of the trench is disposed in the p-type region.
9. The device of claim 1 wherein: the upper region is a p-type region; the top contact is electrically connected to the p-type region; the lower region is an n-type region; and a deepest point of the trench is disposed in the n-type region.
10. A device comprising: a semiconductor structure comprising a light emitting layer disposed between an upper region and a lower region of opposite conductivity; a top contact disposed on a top surface of the semiconductor structure, the top contact being electrically connected to the upper region, the top contact comprising a first edge and a second edge opposite the first edge; a first trench formed in a bottom surface of the semiconductor structure beneath the first edge of the top contact:, a second trench formed in the bottom surface of the semiconductor structure beneath the second edge of the top contact; and a dielectric layer lining the bottom surface, the first trench, and the second trench, the dielectric layer in the first trench and the second trench forming at least part of mirrors that reflect light away from the top contact.
11. The device of claim 10 further comprising a reflective layer disposed on the dielectric layer over the bottom surface and in the first trench and the second trench, the reflective layer in the first trench and second trench forming part of the mirrors that reflect light away from the top contact, the reflective layer being electrically isolated from the semiconductor structure by the dielectric layer.
12. The device of claim 10 wherein: the upper region is an n-type region; and the first trench and the second trench each extend from the bottom surface and a deepest point of each of the first and second trenches is within the n-type region.
13. (canceled)
14. The device of claim 10 wherein the light emitting layer is a III-nitride material.
15. The device of claim 10 wherein at least one sidewall of each of the first and second trenches is angled 30° to 90° relative to a normal to the top surface of the semiconductor structure.
16. The device of claim 6 further comprising contact metals in the dielectric layer to electrically contact the bottom surface, the reflective material being electrically conductive and in electrical contact with the contact metals.
17. The device of claim 10 further comprising a filler material disposed in voids where the reflective layer does not completely fill the first trench and the second trench.
18. The device of claim 11 further comprising contact metals in the dielectric layer to electrically contact the bottom surface, the reflective material being electrically conductive and in electrical contact with the contact metals.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0012]
[0013]
[0014]
[0015]
DETAILED DESCRIPTION
[0016] In the structure illustrated in
[0017] Embodiments of the invention are directed to structures in a vertical light emitting device that prevent light from being generated beneath absorbing structures such as the top n-contact, and/or direct light away from absorbing structures, without suffering from the drawbacks of the
[0018] Depending on the context, as used herein, “AlGaInP” or “AlInGaP” may refer in particular to a quaternary alloy of aluminum, indium, gallium, and phosphorus, or in general to any binary, ternary, or quaternary alloy of aluminum, indium, gallium, and phosphorus. “III-nitride” may refer to a binary, ternary, or quaternary alloy of any group III atom (such as aluminum, indium, and gallium) and nitrogen. Depending on the context, as used herein, “contact” may refer in particular to a metal electrode, or in general to the combination of a semiconductor contact layer, a metal electrode, and any structures disposed between the semiconductor contact layer and the metal electrode. Though in the examples below the semiconductor light emitting device are AlInGaP LEDs, semiconductor light emitting devices besides LEDs such as laser diodes and semiconductor light emitting devices made from other materials systems such as other III-V materials, III-nitride, III-phosphide, III-arsenide, II-VI materials, ZnO, or Si-based materials may be used.
[0019]
[0020] The n-contact includes a large contact pad 20, and one or more narrower contact arms 22. In the configuration illustrated in
[0021] The p-contact structures are formed on the bottom surface of the device. Because a majority of light is extracted from the device through the top surface, light emitted in the direction of the bottom surface is preferably reflected toward the top surface. However, the materials typically used for p-contacts in AlInGaP devices are absorbing, not reflective. Accordingly, in order to minimize the area of the p-contact, the p-contact is distributed over many small areas 24. The bottom surface of the device 23 between the p-contact areas 24 is made reflective. P-contact areas 24 are formed in an area 27 inside the square formed by the n-contact arms 22a, 22b, 22c, and 22d, and in an area 29 outside the square formed by the re-contact arms 22. The n-contact arms 22a, 22b, 22c, and 22d have an inner wall 32 and an outer wall 30, described below.
[0022]
[0023] The device layers 71, including at least one light emitting layer in a light emitting region sandwiched between an n-type region and a p-type region, are grown over the etch stop layer, starting with n-type region 70. The thickness and doping concentration of n-type region 70 are selected for low electrical resistance and good current distribution. For example, n-type region 70 may include an AlGaInP layer at least 1 μm in some embodiments, no more than 10 μm thick in some embodiments, at least 3 μm thick in some embodiments, and no more than 5 μm thick in some embodiments. The AlGaInP layer may be doped with Te or Si to a concentration of at least 5×10.sup.17 cm.sup.3 in some embodiments and no more than 5×10.sup.18 cm.sup.3 in some embodiments. An AlGaInP n-type region 70 is usually lattice-matched to GaAs. At higher dopant concentrations, the same current distribution may be achievable with a thinner layer; however, undesirable free carrier absorption may increase at higher dopant concentrations. N-type region 70 may therefore include a non-uniform doping concentration, such as one or more thick regions doped to a concentration of at least 5×10.sup.17 cm.sup.3 in some embodiments and no more than 5×10.sup.18 cm.sup.3 in some embodiments, and one or more thin regions that are doped more heavily, up to, for example, 1×10.sup.19 cm.sup.−3. These highly doped regions may be doped with Te, Si, S, or other suitable dopants, and the high doping concentration can be achieved either by epitaxial growth, by dopant diffusion, or both. In one example, the composition of n-type region 70 in a device with a light emitting region configured to emit red light is (Al.sub.0.04Ga.sub.0.60).sub.0.5In.sub.0.5P
[0024] A light emitting or active region 72 is grown over n-type region 70. Examples of suitable light emitting regions include a single light emitting layer, and a multiple quantum well light emitting region, in which multiple thick or thin light emitting wells are separated by barrier layers. In one example, the light emitting region 72 of a device configured to emit red light includes (Al.sub.0.06Ga.sub.0.94).sub.0.5In.sub.0.5P light emitting layers separated by (Al.sub.0.65Ga.sub.0.35).sub.0.5In.sub.0.5P barriers. The light emitting layers and the barriers may each have a thickness between, for example, 20 and 200 Å. The total thickness of the light emitting region may be, for example, between 500 Å and 3 μm.
[0025] A p-type region 74 is grown over light emitting region 72. P-type region 74 is configured to confine carriers in light emitting region 72. In one example, p-type region 74 is (Al.sub.0.65Ga.sub.0.35).sub.0.5In.sub.0.5P and includes a thin layer of high Al composition to confine electrons. The thickness of p-type region 74 may be on the order of microns; for example, between 0.5 and 3 μm. The proximity of the light emitting layers of the light emitting region to the p-contact through a thin p-type region 74 may also reduce the thermal impedance of the device.
[0026] A p-type contact layer 76 is grown over p-type region 74. P-type contact layer 76 may be highly doped and transparent to light emitted by the light emitting region 72. For example, p-type contact layer 76 may be doped to a hole concentration of at least 5×10.sup.18 cm.sup.−3 in some embodiments, and at least 1×10.sup.19 cm.sup.−3 in some embodiments. In this case, p-type contact layer 76 may have a thickness between 100 Å and 1000 Å. If the p-type contact layer 76 is not highly doped then the thickness may be increased to as much as 2 μm. P-type contact layer 76 may be GaP or any other suitable material.
[0027] In some embodiments, p-type contact layer 76 is highly doped GaP. For example, a GaP contact layer 76 grown by metal organic chemical vapor deposition may be doped with Mg or Zn, activated to a hole concentration of between 5×10.sup.17 and 5×10.sup.18 cm.sup.−3. The GaP layer may be grown at low growth temperature and low growth rate; for example, at growth temperatures approximately 50 to 200° C. below typical GaP growth temperatures of ˜850° C., and at growth rates of approximately 1% to 10% of typical GaP growth rates of ˜5 μm/hr. A GaP contact grown by molecular beam epitaxy may be doped with C to a concentration of at least 1×10.sup.19 cm.sup.−3.
[0028] As an alternative to incorporating dopants during growth, the p-type contact layer 76 may be grown, then the dopants may be diffused into the p-type contact layer from a vapor source after growth, for example by providing a high pressure dopant source in a diffusion furnace or in the growth reactor, as is known in the art. Dopants may be diffused from a vapor source into the entire area of the surface of p-type contact layer 76, or in discrete regions of p-type contact layer 76, for example by masking parts of p-type contact layer 76 with, for example, a dielectric layer, prior to dopant diffusion.
[0029] In some embodiments, p-type contact layer 76 is a highly doped GaP or lattice-matched AlGaInP layer. The layer is doped by growing the semiconductor material, then depositing a layer, including a dopant source, over the grown layer. For example, the dopant source layer may be elemental Zn, a AuZn alloy, or a doped dielectric layer. The layer including the dopant source may optionally be capped with a diffusion blocking layer. The structure is annealed such that the dopants diffuse into the semiconductor from the dopant source layer. The diffusion blocking layer and remaining dopant source layer may then be stripped off. In one example, 3000 Å to 5000 Å of a AuZn alloy containing 4% Zn is deposited over a GaP layer, followed by a TiW diffusion blocking layer. The structure is heated, then the remaining TiW and AuZn are stripped. In another example, the patterned AuZn layer is left in place as the contact metal in p-contact areas 24 shown in, for example,
[0030] In some embodiments, p-type contact layer 76 is highly doped InGaP or AlGaInP layer that is not lattice-matched to GaAs. The layer may be between 100 Å and 300 Å thick and doped with Mg or Zn to a hole concentration of at least 1×10.sup.19 cm.sup.−3.
[0031] In some embodiments, the order of the semiconductor layers illustrated in
[0032] The trenches illustrated in
[0033] In
[0034] In various embodiments, trenches 80A and 80B may have angled or straight sidewalls. Sidewalls are angled 30° to 90° relative to a normal to the top surface of the semiconductor structure in some embodiments and 45° relative to a normal to the top surface of the semiconductor structure in some embodiments. Angled sidewalls may be formed, for example, by heating a photoresist mask such that it reflows to form a sloped sidewall. The shape of the sloped sidewall is transferred to the semiconductor by dry-etching.
[0035] The width 81 of trenches 80A and 80B is defined at the bottom surface of the semiconductor structure. The width is chosen such that the sum of the two trench 80A and 80B widths 81, plus the gap 25 between the trenches 80A and 80B, is approximately equal to the width of the contact arm (2×81+25≈22a). The minimum width 81 of the trench depends on the lithographic and etch capabilities but may be at least 0.5 μm wide in some embodiments and no more than 10 μm wide in some embodiments. In general, smaller trench widths 81 are desirable. The width at the top of the trench in the orientation illustrated in
[0036] In
[0037] In some embodiments, trench 90 extends through p-type contact layer 76 and into p-type region 74 as illustrated in
[0038] After forming the trenches, trenches 80A and 80B or trench 90, and the top surface of p-type contact layer 76, are lined with a dielectric material 78. Dielectric material 78 may be any suitable material formed by any suitable technique. Dielectric material 78 may be, for example, SiO.sub.2 formed by, for example, plasma-enhanced chemical vapor deposition. Dielectric material 78 may be a single layer of material or multiple layers of the same or different materials. In some embodiments, the thickness of dielectric layer 78 is sufficient to ensure total internal reflection (TIR) of light incident on the dielectric layer. The minimum necessary thickness for TIR is a fraction of an optical wavelength, and depends on the refractive index of the dielectric. For example, with a SiO.sub.2 dielectric layer 78, a thickness of at least 50 nm would be suitable, and a thickness as large as one or several microns could be used.
[0039] Small holes are etched in dielectric layer 78 where electrical contact to p-type contact layer 76 is desired. In
[0040] A reflective layer 82 is formed on dielectric layer 78 and p-contacts 24. Reflective layer 82 lines the trenches. Reflective layer 82 may fill the trenches, as illustrated in
[0041] The reflective layer 82 may be patterned as is known in the art to remove reflective layer from areas where it is not wanted, such as the edges of the device. A guard material (not shown) such as, for example, TiW may be formed over the reflective layer 82 and next to the reflective layer 82 at the edges of the device. The guard material may seal the reflective layer in place, which may reduce or prevent problems such as electromigration or oxidation of a silver reflective layer 82. The guard material may be a single layer of material or multiple layers of the same or different materials. The guard material may be electrically conductive in some embodiments.
[0042] One or more bonding layers 84 are disposed between the device and the mount 86. One bonding layer may be formed on reflective metal 82, and one bonding layer may be formed on mount 86.
[0043] A bonding layer 84 formed over the reflective metal 82 may be, for example, Au or Ag, or a solder Alloy such as Auln or AuSn alloy, and may be formed by, for example, evaporation or sputtering. Each bonding layer 84 may be a single layer of material or multiple layers of the same or different materials. In embodiments where the reflective metal 82 does not completely fill the trenches, the bonding layer material or another material may be deposited to fill the void spaces in the trenches 80A and 80B or to fill the void space 92 in trench 90.
[0044] The device is then connected to a mount 86 through bonding layers 84. (The bonding layers maybe applied to the device wafer and/or to the mount wafer before bonding.) Mount 86 may be selected to have a coefficient of thermal expansion (CTE) that is reasonably closely matched to the CTE of the semiconductor layers. Mount 86 may be, for example, GaAs, Si, Ge, a metal such as molybdenum, or any other suitable material. The bonding layer formed on mount 86 may be, for example, Au or any other suitable material. A bond is formed between the two bonding layers by, for example, thermocompression bonding, or any other suitable technique. Electrical contact to the p-type region is made, for example, through a contact (not shown) on the bottom of mount 86. Mount 86 may be conductive or may include a conductive region or trace that electrically connects the contact on the bottom to p-contacts 24 through reflective conductive layer 82, bonding layers 84, and any intervening layers. As an alternative to bonding the device to the mount, a thick mount can be grown on the device wafer by, for example, electroplating techniques.
[0045] After attaching the device to the mount, the growth substrate (not shown) is removed by a technique suitable to the growth substrate material. For example, a GaAs growth substrate may be removed by a wet etch that terminates on an etch-stop layer grown over the growth substrate before the device layers. The semiconductor structure may optionally be thinned
[0046] N-contact metal, such as, for example, Au/Ge/Au or any other suitable contact metal or metals, may be deposited then patterned to form n-contact arms 22a-22d and bonding pad 20. The structure may be heated, for example to anneal n-contacts 20 and 22a-22d and/or p-contacts 24. The surface 34 of n-type region 70 exposed by removing the growth substrate may be roughened to improve light extraction, for example by photoelectrochemical, plasma etching, or patterned by, for example, nanoimprint lithography to form a photonic crystal or other light scattering structure. In other embodiments, a light-extracting feature is buried in the structure. The light extracting feature may be, for example, a variation in index of refraction in a direction parallel to the top surface of the device (i.e. perpendicular to the growth direction of the semiconductor layers). In some embodiments, the surface of the p-type contact layer may be roughened or patterned prior to forming dielectric layer 78. In some embodiments, before or during growth of the semiconductor structure, a layer of low index of material is deposited on the growth substrate or on a semiconductor layer and patterned to form openings in the low index material or posts of low index material. Semiconductor material is then grown over the patterned low index layer to form a variation in index of refraction that is disposed within the semiconductor structure.
[0047] A wafer of devices may then be tested and singulated into individual devices. Individual devices may be placed in packages, and an electric contact such as a wire bond may be formed on the bonding pad 20 of the device to connect the n-contact to a part of the package such as a lead.
[0048] In operation, current is injected in the p-type region by contacts 24 via the mount 86. Current is injected in the n-type region by bonding pad 20, on the top surface of the device. Current is injected from bonding pad 20 to n-contact arms 22a-22d into n-type region 70.
[0049] When the active region 72 is emitting light, light incident on the sidewalls of the trenches 80A, 80B, and 90 at large angles is totally internally reflected by dielectric layer 78. Light incident on the sidewalls of the trenches 80A, 80B, and 90 at small angles passes through the dielectric layer 78 and is reflected by reflective layer 82. The trenches direct light away from n-contact arms 22. Trenches may similarly be formed beneath n-contact pad 20, to direct light away from n-contact pad 20. The trenches, the dielectric material disposed in the trenches, and the reflective material disposed on the dielectric material, form mirrors to direct light away from one or both of the n-contact pad 20 and n-contact arms 22a-22d.
[0050] The devices illustrated in
[0051] The structures described herein may offer advantages.
[0052] For example, replacing the large wide void space of the trench of
[0053] Replacing a deep trench that extends through the active region as in
[0054] Finally, replacing the thermally resistant void space of the wide, deep trench of
[0055] Having described the invention in detail, those skilled in the art will appreciate that, given the present disclosure, modifications may be made to the invention without departing from the spirit of the inventive concept described herein. Therefore, it is not intended that the scope of the invention be limited to the specific embodiments illustrated and described.