BRIDGE CELL PHASE CHANGE MEMORY
20230200266 · 2023-06-22
Inventors
- Ruilong Xie (Niskayuna, NY, US)
- Carl Radens (LaGrangeville, NY, US)
- Juntao Li (Cohoes, NY, US)
- Kangguo Cheng (Schenectady, NY, US)
Cpc classification
H10N70/823
ELECTRICITY
H10N70/021
ELECTRICITY
H10N70/231
ELECTRICITY
International classification
Abstract
A phase change bridge memory cell includes: a first interlevel dielectric layer; a first electrode and a second electrode disposed in the first interlevel dielectric layer and separated by a portion of the first interlevel dielectric layer; an interlevel dielectric pillar on the portion of the first interlevel dielectric layer; a first phase change material on the interlevel dielectric pillar; and a second phase change material including two areas on opposite sides of the interlevel dielectric pillar and electrically connected by the first phase change material, wherein the second phase change material is connected to the first electrode and the second electrode.
Claims
1. A phase change bridge memory cell comprising: a first interlevel dielectric layer; a first electrode and a second electrode disposed in the first interlevel dielectric layer and separated by a portion of the first interlevel dielectric layer; an interlevel dielectric pillar on the portion of the first interlevel dielectric layer; a first phase change material on the interlevel dielectric pillar; and a second phase change material portion including two areas on opposite sides of the interlevel dielectric pillar and electrically connected by the first phase change material, wherein the second phase change material is connected to the first electrode and the second electrode.
2. The phase change bridge memory cell of claim 1, further comprising an interlevel dielectric fill disposed on sidewalls of the second phase change material.
3. The phase change bridge memory cell of claim 1, wherein a height of the first phase change material on the interlevel dielectric pillar is less than a width of the two areas of the second phase change material on sidewalls of the interlevel dielectric pillar.
4. The phase change bridge memory cell of claim 1, further comprising: a patterned hardmask on the first phase change material; and a first spacer around the patterned hardmask and on the second phase change material.
5. The phase change bridge memory cell of claim 1, wherein the second phase change material has a sloped sidewall opposite a sidewall of the interlevel dielectric pillar, where a thickness of the two areas of the second phase change material on sidewalls of the interlevel dielectric pillar is greater at the first electrode and the second electrode than at the first phase change material.
6. The phase change bridge memory cell of claim 1, wherein the interlevel dielectric pillar comprises: a plurality of first interlevel dielectric material layers; and a plurality of second interlevel dielectric material layers interleaved with the first interlevel dielectric material layers, wherein a first width the plurality of first interlevel dielectric material layers is less than a second width of the plurality of second interlevel dielectric material layers, and wherein the second phase change material has a sloped sidewall opposite a sidewall of the interlevel dielectric pillar that defines a plurality of neck portions in the second phase change material, where a thickness of the second phase change material on sidewalls of the interlevel dielectric pillar is greater at the first electrode and the second electrode than at the first phase change material.
7. The phase change bridge memory cell of claim 6, wherein the plurality of neck portions have thicknesses, and a first thickness of a first neck portion adjacent the first electrode and the second electrode is greater than a second thickness of a second neck portion adj acent the first phase change material, and wherein no thickness of the plurality of neck portions is greater than a third thickness of the first phase change material on the interlevel dielectric pillar.
8. The phase change bridge memory cell of claim 6, wherein the first width of the plurality of first interlevel dielectric material layers is greater than or equal to a third width of the portion of the first interlevel dielectric layer between the first electrode and the second electrode.
9. A phase change bridge memory cell comprising: a substrate; a first phase change material on the substrate; a second phase change material portion including two areas electrically connected by the first phase change material; a pillar on the portion on the first phase change material and separating the two areas of the second phase change material; and a first electrode and a second electrode on the two areas of the second phase change material and separated by the pillar.
10. The phase change bridge memory cell of claim 9, further comprising an interlevel dielectric fill disposed on sidewalls of the second phase change material and the first electrode and the second electrode.
11. The phase change bridge memory cell of claim 9, wherein a height of the first phase change material under the pillar is less than a width of the two areas of the second phase change material on sidewalls of the pillar.
12. The phase change bridge memory cell of claim 9, wherein the pillar comprises an interlevel dielectric pillar on the first phase change material and a hardmask on the interlevel dielectric pillar.
13. A method of manufacturing a phase change memory device comprising: providing a substrate; forming a first electrode and a second electrode; forming a first phase change material; forming an interlevel dielectric pillar; forming a second phase change material and a third phase change material connected by the first phase change material, wherein the second phase change material is connected to the first electrode and the third phase change material is connected to the second electrode; and forming an interlevel dielectric fill over the phase change memory device.
14. The method of claim 13, further comprising: forming a patterned interlevel dielectric layer, wherein the first electrode and the second electrode are formed in the patterned interlevel dielectric layer, and at least a portion of the patterned interlevel dielectric layer separates the first electrode from the second electrode.
15. The method of claim 13, further comprising: forming a patterned hardmask on the first phase change material; depositing an intermediate phase change material having a height sufficient to cover sidewalls of the first phase change material; and forming a first spacer around the patterned hardmask and on the intermediate phase change material, wherein forming the second phase change material and the third phase change material further comprises patterning the intermediate phase change material.
16. The method of claim 13, wherein forming the second phase change material and the third phase change material further comprises etching an intermediate phase change material to form sloped sidewalls of the second phase change material and the third phase change material.
17. The method of claim 13, wherein forming the interlevel dielectric pillar further comprises: depositing a stack comprising a plurality of first layers formed of a first interlevel dielectric material and a plurality of second layers formed of a second interlevel dielectric material interleaved with the first layers; depositing a first phase change material layer on the stack; forming a patterned hardmask on the first phase change material layer; and patterning the first phase change material layer and the stack to form the first phase change material and a plurality of first interlevel dielectric material layers and a plurality of second interlevel dielectric material layers interleaved with the first interlevel dielectric material layers.
18. The method of claim 17, further comprising: depositing an intermediate phase change material having a height sufficient to cover sidewalls of the first phase change material; and forming a first spacer around the patterned hardmask and on the intermediate phase change material, wherein forming the second phase change material and the third phase change material further comprises etching the intermediate phase change material.
19. The method of claim 18, wherein the etching of the intermediate phase change material comprising forming sloped sidewalls of the second phase change material and the third phase change material.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0015] Preferred embodiments of the present invention will be described below in more detail, with reference to the accompanying drawings:
[0016]
[0017]
[0018]
[0019]
[0020]
DETAILED DESCRIPTION
[0021] According to embodiments of the present invention, a “U” shaped two-state phase change bridge memory cell localizes switching within a phase change material bridging two separated phase change material pads connected to respective metal electrodes.
[0022] According to embodiments of the present invention, a multiple-state phase change bridge cell includes a horizontal phase change material bridging two separated phase change material segments with sloped sidewalls.
[0023] The present application will now be described in greater detail by referring to the following discussion and drawings that accompany the present application. It is noted that the drawings of the present application are provided for illustrative purposes only and, as such, the drawings are not drawn to scale. It is also noted that like and corresponding elements are referred to by like reference numerals.
[0024] In the following description, numerous specific details are set forth, such as particular structures, components, materials, dimensions, processing steps and techniques, in order to provide an understanding of the various embodiments of the present application. However, it will be appreciated by one of ordinary skill in the art that the various embodiments of the present application may be practiced without these specific details. In other instances, well-known structures or processing steps have not been described in detail in order to avoid obscuring the present application.
[0025] Semiconductor device manufacturing includes various steps of device patterning processes. For example, the manufacturing of a semiconductor chip may start with, for example, a plurality of CAD (computer aided design) generated device patterns, which is then followed by effort to replicate these device patterns in a substrate. The replication process may involve the use of various exposing techniques and a variety of subtractive (etching) and/or additive (deposition) material processing procedures. For example, in a photolithographic process, a layer of photo-resist material may first be applied on top of a substrate, and then be exposed selectively according to a pre-determined device pattern or patterns. Portions of the photo-resist that are exposed to light or other ionizing radiation (e.g., ultraviolet, electron beams, X-rays, etc.) may experience some changes in their solubility to certain solutions. The photo-resist may then be developed in a developer solution, thereby removing the non-irradiated (in a negative resist) or irradiated (in a positive resist) portions of the resist layer, to create a photo-resist pattern or photo-mask. The photo-resist pattern or photo-mask may subsequently be copied or transferred to the substrate underneath the photo-resist pattern.
[0026] There are numerous techniques used by those skilled in the art to remove material at various stages of creating a semiconductor structure. As used herein, these processes are referred to generically as “etching”. For example, etching includes techniques of wet etching, dry etching, chemical oxide removal (COR) etching, and reactive ion etching (RIE), which are all known techniques to remove select material(s) when forming a semiconductor structure. The Standard Clean 1 (SC1) contains a strong base, typically ammonium hydroxide, and hydrogen peroxide. The SC2 contains a strong acid such as hydrochloric acid and hydrogen peroxide. The techniques and application of etching is well understood by those skilled in the art and, as such, a more detailed description of such processes is not presented herein.
[0027] Although the overall fabrication method and the structures formed thereby are novel, certain individual processing steps required to implement the method may utilize conventional semiconductor fabrication techniques and conventional semiconductor fabrication tooling. These techniques and tooling will already be familiar to one having ordinary skill in the relevant arts given the teachings herein. It is emphasized that while some individual processing steps are set forth herein, those steps are merely illustrative, and one skilled in the art may be familiar with several equally suitable alternatives that would be applicable.
[0028] It is to be appreciated that the various layers and/or regions shown in the accompanying figures may not be drawn to scale. Furthermore, one or more semiconductor layers of a type commonly used in such integrated circuit devices may not be explicitly shown in a given figure for ease of explanation. This does not imply that the semiconductor layer(s) not explicitly shown are omitted in the actual integrated circuit device.
[0029] According to some embodiments, a method 100 of manufacturing a phase change memory device includes providing a substrate at step 101, forming a first electrode and a second electrode at step 102, forming a first phase change material at step 103, forming an interlevel dielectric (ILD) pillar at step 104, forming a second phase change material and a third phase change material connected by the first phase change material at step 105, wherein the second phase change material is connected to the first electrode and the third phase change material is connected to the second electrode, and forming an ILD fill over the phase change memory device at step 106.
[0030] It should be understood that the steps of
[0031] According to at least one embodiment, sidewalls of the second phase change material and the third phase change material are parallel, such that they form a “U” shaped two-state vertical phase change bridge memory cell localizing switching within the first phase change material bridging the second phase change material and the third phase change material.
[0032] According to one or more embodiments, sidewalls of the second phase change material and the third phase change material are parallel are sloped from a relatively narrow cross-section proximate to the first phase change material to a relatively wide cross-section away from the first phase change material, wherein the first phase change material bridges the second phase change material and the third phase change material. According to some embodiments, forming the ILD pillar at step 104 further includes forming the ILD pillar have a plurality of relatively narrow portions interleaved by a plurality of relatively thick portions, wherein the plurality of relatively thick portions and the slope of the second phase change material and the third phase change material define thickness of a plurality of neck portions in the second phase change material and the third phase change material.
[0033] Referring to at least one embodiments,
[0034] Referring to
[0035] Referring to
[0036] Referring to
[0037] Referring to
[0038] Referring to
[0039] According to some aspects, alternate phase change materials can be used. For example, the a phase change memory bridge cell according to some embodiments can include a phase change material such as germanium-antimony-tellurium (GST), gallium-antimony-tellurium (GaST), silver-iridium-antimony-telluride (AIST) material, germanium-tellurium compound material (GeTe), Si—Sb—Te (silicon-antimony-tellurium) alloys, Ga—Sb—Te (gallium-antimony-tellurium) alloys, Ge—Bi—Te (germanium-bismuth-tellurium) alloys, In—Se (indium-tellurium) alloys, As—Sb—Te (arsenic-antimony-tellurium) alloys, Ag—In—Sb—Te (silver-indium-antimony-tellurium) alloys, Ge—In—Sb—Te alloys, Ge—Sb alloys, Sb—Te alloys, Si—Sb alloys, Ge—Te alloys and combinations thereof.
[0040] According to example embodiments, the phase change material(s) can be doped (e.g., with one or more of oxygen (O), carbon C, nitrogen (N), silicon (Si), or titanium (Ti)).
[0041]
[0042] Referring to
[0043] Referring to
[0044] Referring to
[0045] According to one or more embodiments, the second patterned phase change material 901 has a height sufficient to fully encapsulate the patterned third phase change material 801. According to some embodiments, the height of the second patterned phase change material 901 is lower than a top most surface of the patterned fourth ILD layer 802.
[0046] Referring to
[0047] Referring to at least one embodiments,
[0048] Referring to
[0049] Referring to
[0050] Referring to
[0051] Referring to
[0052] Referring to
[0053] Referring to
[0054] According to some embodiments, stage 1 portion 1604, stage 2 portion 1605, stage 3 portion 1606, stage 4 portion 1607, and stage 5 portion 1608 have increasing functional dimensions (e.g., a height of the stage 1 portion 1604 between the patterned fourth dielectric B layer 1208 and the hardmask, is less than a width of the stage 2 portion 1605, which is turn is less than a width of the stage 3 portion 1606, etc.). As illustrated in
Recapitulation
[0055] According to embodiments of the present invention, a phase change bridge memory cell includes: a first interlevel dielectric layer (see first patterned ILD layer 202); a first electrode (203) and a second electrode (204) disposed in the first interlevel dielectric layer and separated by a portion of the first interlevel dielectric layer; an interlevel dielectric pillar (see patterned second ILD layer 301) on the portion of the first interlevel dielectric layer; a first phase change material (see 302) on the interlevel dielectric pillar; and a second phase change material (see patterned second phase change material 501) portion including two areas on opposite sides of the interlevel dielectric pillar and electrically connected by the first phase change material, wherein the second phase change material is connected to the first electrode and the second electrode.
[0056] According to at least one embodiment, the interlevel dielectric pillar includes: a plurality of first interlevel dielectric material layers (1301, 1302, 1303, 1304); and a plurality of second interlevel dielectric material layers (1202, 1204, 1206, 1208) interleaved with the first interlevel dielectric material layers, wherein a first width the plurality of first interlevel dielectric material layers is less than a second width of the plurality of second interlevel dielectric material layers, and wherein the second phase change material (1501, 1502) has a sloped sidewall opposite a sidewall of the interlevel dielectric pillar that defines a plurality of neck portions in the second phase change material, where a thickness of the second phase change material on sidewalls of the interlevel dielectric pillar is greater at the first electrode and the second electrode than at the first phase change material.
[0057] According to some embodiments, a phase change bridge memory cell includes: a substrate (see second substrate 701); a first phase change material (see patterned third phase change material 801) on the substrate; a second phase change material (see second patterned phase change material 901) portion including two areas electrically connected by the first phase change material; a pillar (see patterned fourth ILD layer 802, and patterned second hardmask 803) on the portion on the first phase change material and separating the two areas of the second phase change material; and a first electrode (see third electrode 1001) and a second electrode (see fourth electrode 1002) on the two areas of the second phase change material and separated by the pillar.
[0058] According to some embodiments, a method 100 of manufacturing a phase change memory device includes: providing a substrate at step 101; forming a first electrode and a second electrode at step 102; forming a first phase change material at step 103; forming an interlevel dielectric (ILD) pillar at step 104; forming a second phase change material and a third phase change material connected by the first phase change material at step 105, wherein the second phase change material is connected to the first electrode and the third phase change material is connected to the second electrode; and forming an ILD fill over the phase change memory device at step 106.
[0059] The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a,” “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates other-wise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
[0060] The corresponding structures, materials, acts, and equivalents of all means or step plus function elements in the claims below are intended to include any structure, material, or act for performing the function in combination with other claimed elements as specifically claimed. The descriptions of the various embodiments of the present invention have been presented for purposes of illustration, but are not intended to be exhaustive or limited to the embodiments disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments. The terminology used herein was chosen to best explain the principles of the embodiments, the practical application or technical improvement over technologies found in the marketplace, or to enable others of ordinary skill in the art to understand the embodiments disclosed herein.