FEEDER CAPABLE OF FEEDING ANODE AND PLATING APPARATUS
20170356098 · 2017-12-14
Inventors
Cpc classification
C25D17/001
CHEMISTRY; METALLURGY
International classification
Abstract
There is provided a feeder capable of reducing deterioration of the contact state between the feeder and an anode more than the prior art as dissolution of the anode progresses. The feeder can supply power to the anode 5 for use in plating a substrate in a plating tank. The feeder includes a main body portion 1 which can be disposed on an outer periphery of the anode 5 and a spring 88 which is disposed in the main body portion 1 and can apply a first force 100 to the main body portion 1 in a direction from the main body portion 1 toward a region 80 surrounded by the main body portion 1.
Claims
1. A feeder capable of feeding an anode for use in plating a substrate, the feeder comprising: a main body portion which can be disposed on an outer periphery of the anode; and a force applying member which is disposed in the main body portion and can apply a first force to the main body portion in a direction from the main body portion toward a region surrounded by the main body portion.
2. The feeder according to claim 1, wherein the force applying member includes an end member disposed in at least one of two end portions of the main body portion in an outer peripheral direction of the region, the end member can apply a second force to the two end portions so as to bring the two end portions close to each other, and by applying the second force to the two end portions, can apply the first force to the main body portion.
3. The feeder according to claim 2, wherein the force applying member includes a connecting member connecting at least two portions of the main body portion, and the connecting member is disposed in a direction crossing the region outside the region and can apply the first force to the at least two portions so as to bring the at least two end portions close to each other.
4. The feeder according to claim 1, comprising a conductor which can be disposed on an outer periphery of the anode, wherein the main body portion can be disposed on an outer periphery of the conductor.
5. The feeder according to claim 1, wherein a width of the main body portion in a thickness direction of the anode is smaller than a thickness of the anode.
6. A feeder capable of feeding an anode for use in plating a substrate, the feeder comprising: a main body portion which can be disposed on an outer periphery of the anode; and a force applying member which is disposed in the main body portion and can apply a first force to the main body portion in a direction from the main body portion toward a region surrounded by the main body portion, wherein the force applying member includes a connecting member connecting at least two portions of the main body portion, and the connecting member is disposed in a direction crossing the region outside the region and can apply the first force to the at least two portions so as to bring the at least two end portions close to each other.
7. A feeder capable of feeding an anode for use in plating a substrate, the feeder comprising: a conductor which can be disposed on an outer periphery of the anode, and a main body portion which can be disposed on an outer periphery of the conductor.
8. A feeder capable of feeding an anode for use in plating a substrate, the feeder comprising a main body portion which can be disposed on an outer periphery of the anode, wherein a width of the main body portion in a thickness direction of the anode is smaller than a thickness of the anode.
9. A feeder according to claim 1, wherein the anode is a soluble anode.
10. A plating apparatus comprising: a plating tank capable of containing a plating solution; a feeder according to claim 1, wherein the anode can be disposed, a substrate holder capable of holding the substrate; and a plating power supply capable of passing a current between the feeder and the substrate, wherein the substrate can be plated by immersing the substrate holder in the plating solution.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0056] Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings. In each of the following embodiments, the same reference numerals or characters are assigned to the same or similar members, and the duplicate description is omitted.
[0057]
[0058] As illustrated in
[0059] The treatment section 170B includes a stocker (wagon) 24 for storing and temporarily placing the substrate holder 18, a pre-wet tank 26 for immersing the substrate WF in pure water, a pre-soak tank 28 for removing by etching an oxide film on the surface of a seed layer or the like formed on the surface of the substrate WF, a first washing tank 30a for washing the surface of the substrate WF with pure water, a blow tank 32 for draining the substrate WF after washing, a second washing tank 30b, and a plating tank 34, which are arranged sequentially in this order from the substrate attaching/detaching section 20. The plating tank 34 includes a plurality of plating units 38 contained in an overflow tank 36. Each plating unit 38 includes one substrate holder 18 therein on which copper plating or the like is performed.
[0060] Further, the treatment section 170B includes a substrate holder transport unit 40 which uses, for example, a linear motor system and is located on a side of each of these devices to transport the substrate holder 18 together with the substrate WF to and from each of these devices. The substrate holder transport unit 40 includes a first transporter 42 and a second transporter 44. The first transporter 42 transports the substrate WF between the substrate attaching/detaching section 20 and the stocker 24. The second transporter 44 transports the substrate WF among the stocker 24, the pre-wet tank 26, the pre-soak tank 28, the washing tanks 30a and 30b, the blow tank 32, and the plating tank 34.
[0061] The treatment section 170B also includes a paddle drive device 46 which is disposed opposite to the substrate holder transport unit 40 with the overflow tank 36 therebetween. The paddle drive device 46 drives a paddle (unillustrated) which is located in each plating unit 38 and serves as a stirring bar for agitating the plating solution.
[0062] The substrate attaching/detaching section 20 includes two flat plate shaped placement plates 52 slidable along the rail 50. Each placement plate 52 has one substrate holder 18 thereon and a total of two substrate holders 18 are placed in parallel on the placement plates 52. The substrate WF is transferred between one substrate holder 18 of the two substrate holders 18 and the substrate transport device 22. Then, the placement plate 52 laterally slides, and the substrate WF is transferred between the other substrate holder 18 and the substrate transport device 22.
[0063] The placement plate 52 can move 90° to a vertical position and a horizontal position around a rotating shaft (unillustrated). The placement plate 52 is vertically rotated and then transfers the substrate holder 18 to the substrate holder transport unit 40.
[0064] When the plating process is performed on a substrate, the substrate holder 18 holds the substrate by sealing the end portion and the back surface of the substrate from the plating solution and exposing a to-be-plated surface of the substrate. Note that the substrate holder 18 may include a contact which contacts a peripheral edge portion of the to-be-plated surface of the substrate to receive power from an external power supply (plating power supply). Before the plating process, the substrate holder 18 is stored in the stocker 24. When the plating process starts, the substrate holder 18 is moved between the substrate transport device 22 and the plating treatment section by the substrate holder transport unit 40. After the plating process completes, the substrate holder 18 is stored in the wagon again. In the plating apparatus, the substrate held by the substrate holder 18 is vertically immersed in the plating solution of the plating tank 34, and then plating is performed while the plating solution is injected from the bottom of the plating tank 34 and overflows. As described above, the plating tank 34 preferably includes a plurality of plating units 38. In each plating unit 38, one substrate holder 18 holding one substrate is vertically immersed in the plating solution to be plated. Each plating unit 38 preferably includes an insertion portion of the substrate holder 18, a conducting portion to the substrate holder 18, an anode, a paddle stirrer, and a shielding plate. The anode is used by being held by an anode holder and the exposed surface of the anode facing the substrate is concentric with the substrate. The substrate held by the substrate holder 18 is treated with a processing fluid in each treatment tank in the plating treatment section.
[0065] For example, in the case of a plating apparatus using two plating solutions, each treatment tank may be arranged in the plating treatment section in the order of process such as a pre-washing tank, a pre-treatment tank, a rinse tank, a first plating tank, a rinse tank, a second plating tank, a rinse tank, and a blow tank, or may be arranged in another order. Each treatment tank is preferably arranged in the order of process to eliminate an extra transport path. The type of tanks, the number of tanks, and the arrangement of the tanks in the treatment section can be freely selected according to the treatment purpose of the substrate.
[0066] The first transporter 42 and the second transporter 44 of the substrate holder transport unit 40 include an arm suspending the substrate holder, and the arm includes a lifter for holding the substrate holder 18 in a vertical orientation. The substrate holder transport unit can move along a traveling shaft between the substrate attaching/detaching section 20 and the plating treatment section by a transport mechanism (unillustrated) such as a linear motor. The substrate holder transport unit 40 holds and transports the substrate holder 18 in a vertical orientation. The stocker storing the substrate holder can store a plurality of substrate holders 18 in a vertical state.
[0067] Here, the type of the plating solution is not particularly limited, but various plating solutions may be used depending on the application. For example, a plating solution for a through-silicon via (TSV) (Si through electrode) plating process may be used.
[0068] In addition, there may be used a plating solution containing cobalt-tungsten-boron (CoWB), cobalt-tungsten-phosphide (CoWP), and other compounds for use in forming a metal film on the substrate surface having a Cu wiring. Further, there may be used a plating solution containing, for example, CoWB or Ta (tantalum) compounds for use in forming a barrier film provided on the substrate surface or the surface of concave portions of the substrate before the Cu wiring is formed in order to prevent Cu from diffusing into an insulating film thereof.
[0069] The thus configured plating apparatus includes a controller (unillustrated) configured to control each of the aforementioned sections. The controller illustrates a memory (unillustrated) storing predetermined programs, a central processing unit (CPU) (unillustrated) executing the programs stored in the memory, and a control unit (unillustrated) implemented when the CPU executes the programs. The control unit can perform, for example, a transport control of the substrate transport device 22, a transport control of the substrate holder transport unit 40, a control of the plating current and the plating time in the plating tank 34, and other controls. In addition, the controller is configured to communicate with an unillustrated higher-level controller controlling the plating apparatus and other related devices and can exchange data to and from a database of the higher-level controller. Herein, a storage medium constituting the memory stores various setting data and various programs such as a plating process program to be described later. The storage medium may include a memory such as a computer-readable ROM and RAM, and a known disk-shaped storage medium such as a hard disk, a CD-ROM, a DVD-ROM, and a flexible disk.
[0070] Now, the description will focus on the detail of the feeding band (feeder). Before the feeding band according to an embodiment of the present invention is described, a feeding band as a comparative example will be described. The feeding band of the comparative example does not include a force applying member which can apply a force to the main body portion in a direction toward a region surrounded by the main body portion of the feeding band.
[0071] As illustrated in
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[0073] As illustrated in
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[0075] Then, an anode holder 156 holding the anode 5 and the main body portion 1 illustrated in
[0076] As illustrated in
[0077] As illustrated in
[0078] As illustrated in
[0079] Meanwhile, the anode mask 13 attached to the anode holder base 11 is an annular plate-like part whose center portion includes an opening 13a. The inner diameter of the opening 13a of the anode mask 13 is smaller than the outer diameter of the anode 5. The anode mask 13 covers (masks) the outer peripheral portion of the anode 5. The electric field on the surface of the anode 5 can be controlled by an opening diameter of the anode mask 13. The anode mask 13 is made of a material such as vinyl chloride, PEEK (polyether ether ketone), and PVDF (polyvinylidene fluoride).
[0080]
[0081] A temporary storage space (unillustrated) is disposed between the washing tank 30 and the plating tank 34 to replace and temporarily place the anode holder 156.
[0082] Meanwhile, as described above, the upper portion of the anode holder 156 includes a pair of substantially T-shaped hands 11b serving as a support portion for transporting or suspending and supporting the anode holder 156 (see
[0083] Now, the description will focus on the problems with the feeding band of the comparative example with reference to
[0084] On the periphery of the end portions 1a and 1b of the main body portion 1, the outer peripheral portion of the anode 5 is not covered with the main body portion 1. Not being covered, the outer peripheral portion of the anode 5 is exposed to the plating solution. The dissolution rate of the exposed portion of the anode 5 is greater than that of the other outer peripheral portion 75 of the anode 5 where the main body portion 1 contacts and covers the anode. Thus, an indentation 72 occurs. The contact state between the main body portion 1 and the anode 5 is deteriorated especially in the indentation 72 (problem B).
[0085] Meanwhile, when the plating starts, a center 76 in the thickness direction of the anode 5 coincides with a center 76 in the thickness direction of the main body portion 1. As the plating progresses, a center 78 in the thickness direction of the anode 5a moves to the back side of the anode 5 relative to the center 76. However, the center 76 in the thickness direction of the main body portion 1 is unchanged. As a result, the center 78 in the thickness direction of the dissolved anode 5a is displaced from the center 76 in the thickness direction of the main body portion 1. If the centers are displaced, the anode 5 is unstably tightened by the main body portion 1, resulting in an unstable contact state between the main body portion 1 and the anode 5 (problem C).
[0086] With reference to
[0087] The spring 82 is disposed in the end portion 1b of the two end portions 1a and 1b in the main body portion 1 in an outer periphery direction 84 of the region 80 with a washer 88 therebetween. The spring 82 applies a force (second force) 96 to the two end portions 1a and 1b so as to bring the two end portions 1a and 1b close to each other. The first force 100 can be applied to the main body portion 1 by applying the second force 96 to the two end portions. As a result, the spring 82 can apply the first force 100 to the main body portion 1 in the direction 86 from the main body portion 1 toward the region 80 surrounded by the main body portion 1. The magnitude of the force 96 is preferably 40 N or more and 80 N or less. For example, a force 96 of 49 N is applied to each of the two end portions 1a and 1b.
[0088] In the present embodiment, the spring 82 is provided in the end portion 1b, but may be provided in the end portion 1a. Alternatively, a total of two springs 82 may be provided, one for each of the two end portions 1a and 1b. Examples of available types of springs include a helical compression spring and a plate spring. Examples of the spring material include titanium alloy, stainless steel, piano wire, Hastelloy, and Inconel.
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[0090] With reference to
[0091] The connecting member 90 is disposed in a direction 94 crossing a region 80 outside the region 80 surrounded by the main body portion 1. The connecting member 90 can apply first forces 100a to 100h so as to bring the eight portions 92a to 92h close to each other.
[0092] This will be described. The connecting member 90 includes a center portion 120 and eight branch portions 122a to 122h branched from the center portion 120. One of the two end portions of each of the branch portions 122a to 122h is connected to the center portion 120, and the other is welded to the eight portions 92a to 92h.
[0093] The description will further move on to how the plate springs 126a to 126g and the plate springs 130a to 130h are formed by hollowing out with reference to
[0094] The hollowed portion 124e of the center portion 120 is cut at three sides 164a, 164c, and 164d of the four sides 164a, 164b, 164c, and 164d forming a rectangle. The side 164b is not cut but connected to the center portion 120. The cut plate spring 126e is bent toward the anode 5.
[0095] The hollowed portion 128h of the branch portion 122h is cut at three sides 162a, 162c, and 162d of the four sides 162a, 162b, 162c, and 162d forming a rectangle. The side 162b is not cut but connected to the branch portion 122h. The cut plate spring 130h is bent toward the anode 5.
[0096] The connecting member connecting the branch portions 122a to 122h and the center portion 120 has a corrugated cross section as illustrated in
[0097] Note that in the present embodiment, the plate springs 130a to 130h and the plate springs 126a, 126c, 126e, and 126g also contribute to the generation of the first forces 100a to 100e. This will be described. As illustrated in
[0098] After the anode 5 is attached, the free end 132 of the plate spring 126 and the plate spring 130 is bent by the back surface of the anode 5 as illustrated in
[0099] The first forces 100a to 100h are generated by the branch portions 122a to 122h and the center portion 120 as well as the plate springs 130a to 130h and the plate springs 126a, 126c, 126e, and 126g. Even if the outer diameter of the anode 5 is reduced as the plating progresses, each portion of the main body portion 1 is always pulled in a direction toward the inside of the region 80 so as to have a smaller inner diameter. Since the main body portion 1 is pulled into the region 80, even if the outer diameter of the anode 5 is reduced, a good contact state between the main body portion 1 and the anode 5 can be maintained.
[0100] Each magnitude of the first forces 100a to 100h is preferably 20 N or more, for example, 30 N. Note that a very large value (for example, 1000 N) of the tightening force is not preferable because consumption of a soluble anode as the plating process continues may destroy the soluble anode itself during the plating process.
[0101] Then, with reference to
[0102] Note that the thin conductor 142 which can be disposed on the outer periphery of the anode may be added to the embodiment illustrated in
[0103] Then, with reference to
[0104] Before the plating starts, the main body portion 1 is attached as closely as possible to the back side of the anode 5. The center in the thickness direction of the main body portion 1 is disposed closer to the back side of the anode 5 than the center in the thickness direction of the anode 5. In the present embodiment, the main body portion 1 is disposed on only half the back side of the anode 5 of the side surface of the anode 5. A spring 82 is attached to a fastening portion for use in winding the main body portion 1 around the outer periphery of the anode 5. When the diameter of the anode 5 is reduced by dissolution, a spring force is used to reduce the diameter of the main body portion 1.
[0105] As the plating progresses, the front side of the anode 5 dissolves and disappears, but the back side of the anode 5 does not dissolve. When the plating starts, the width 148 of the main body portion 1 in the thickness direction 146 of the anode 5 is less than the thickness 66 of the anode 5. Thus, even after the plating starts, the main body portion 1 has a larger width contacting the anode 5 than that of the prior art. As the plating progresses, the front side of the anode 5 dissolves, and the center in the thickness direction 146 of the anode 5 moves to the back side of the anode 5 and approaches the center in the thickness direction of the main body portion 1. Since the center in the thickness direction of the anode 5 approaches, the present embodiment can reduce the displacement between the center in the thickness direction of the anode 5 and the center in the thickness direction of the main body portion 1 more than the prior art. Further, the present embodiment can reduce an unstable contact state between the anode 5 and the main body portion 1 more than the prior art.
[0106] Hereinbefore, the examples of the embodiments of the present invention have been described. The embodiments of the invention described above are intended to facilitate understanding of the present invention, but not to limit the present invention. It is readily understood that the present invention can be modified or improved without departing from the spirit thereof, and that the present invention encompasses equivalents thereof. It should be noted that within a range capable of solving at least some of the above described problems or within a range of exerting at least some of the effects, any combination of the components described in the scope of claims and the description can be used or omitted. For example, the present invention may also be applied to a so-called cup-type electroplating apparatus.
[0107] This application claims priority under the Paris Convention to Japanese Patent Application No. 2016-116136 filed on Jun. 10, 2016. The entire disclosure of Japanese Patent No. 4,942,580 including specification, claims, drawings and summary is incorporated herein by reference in its entirety.
REFERENCE NUMERALS LIST
[0108] 1 main body portion
[0109] 2 conductive bracket
[0110] 3 contact portion
[0111] 5 anode
[0112] 6 bolt
[0113] 7 double nut
[0114] 18 substrate holder
[0115] 1a end portion
[0116] 1b end portion
[0117] 88 washer
[0118] 90 connecting member
[0119] 120 center portion
[0120] 126 plate spring
[0121] 156 anode holder