Trapezoidal-Duct Assisting Poulty Ammonia Gas, Hydrogen Sulfide Gas, and Dust Removal System
20230191310 · 2023-06-22
Inventors
Cpc classification
A01K1/0047
HUMAN NECESSITIES
B01D53/0446
PERFORMING OPERATIONS; TRANSPORTING
B01D53/18
PERFORMING OPERATIONS; TRANSPORTING
International classification
B01D46/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The present invention involves a fabrication of a trapezoidal-duct assisting poultry ammonia gas, hydrogen sulfide gas, and dust removal system to be used for removing of the poultry ammonia gas, hydrogen sulfide gas, and dust from the exhausted air stream emitting from the poultry houses and litter storages, comprising a poultry ammonia gas removal tube-screen-scrubber device invented in the present invention, hydrogen sulfide gas adsorber, dust filter, air-speed-acceleration trapezoidal-duct, ventilation-fan, and auxiliary system. The poultry ammonia gas removal tube-screen-scrubber equipped in the poultry ammonia gas removal tube-screen-scrubber device is invented in the present invention using the tube-screen-fill pack patented by the present inventor for use in the water cooling tower. The air-speed-acceleration controller trapezoidal-duct is applied for connecting of the large air outlet cross section of the tube-screen-scrubber device and the small air inlet cross section of the ventilation fan.
Claims
1. A trapezoidal-duct assisting poultry ammonia gas, hydrogen sulfide gas, and dust removal system for removing of poultry ammonia gas, hydrogen sulfide gas, and dust-particles from an exhausted air stream emitting from poultry production houses and litter storages comprises; (a) a tube-screen-scrubber device for removing of the ammonia gas from an exhausted air stream by contacting of the exhausted air and working solution streams on the surfaces of tubes equipped in the tube-screen-scrubber device; (b) a hydrogen sulfide gas adsorber device for removing of the hydrogen sulfide gas from the exhausted air stream by adsorbing the hydrogen sulfide gas on the surfaces of hydrogen sulfide adsorbent pellets loaded in the device; (c) a dust filter device for removal of the dust particles to protect local residential healths and for safe operations of the hydrogen sulfide adsorber and ammonia gas removal tube-screen-scrubber devices; (d) a trapezoidal-duct adjusting to deliver a high flow rate in high speed of air stream passing the ventilation fan to a low speed of air passing a large cross section of the tube-screen-scrubber device to deliver a same flow rate of air; (e) a ventilation fan blowing air contaminated with poultry ammonia gas, hydrogen sulfide gas, and dust out of the poultry houses and litter storages; (f) an auxiliary system controlling to circulate working solution through the expanded poultry ammonia gas removal tube-screen-scrubber device equipped in the poultry ammonia gas, hydrogen sulfide gas, and dust removal system.
2. The tube-screen-scrubber device comprising a tube-screen-scrubber pack, working solution supply box, and working solution collection sump, wherein the working solution supply box and the working solution collection sump are attached on the top and bottom of tube-screen-scrubber pack, and wherein the working solution supply box consists the working solution supply box cover with working solution supplying port on top and the bottom mesh net with working solution uniform distributer placed on the mesh net, and wherein the working solution collection sump consists a square box with open top and upper rim of the sump able to be fit with the bottom square plate of the tube-screen-scrubber pack and a working solution outlet port on the bottom plate of the sump.
3. The tube-screen-scrubber pack comprising top and bottom ring-shaped hole perforated plates and a plurality of tubes vertically suspended between the top and bottom ring-shaped hole perforated plates and fixed through the ring-shaped holes on the ring-shaped hole perforated plates, wherein the ring-shaped holes on the top and bottom perforated plates and the tubes suspended in the tube-screen-scrubber pack are lined up transversely to the air flowing direction and the ring holes and tubes are arranged in zigzag shapes along the air flowing direction, and wherein the tube-screen-scrubber pack is assembled side by side of a plenty of tube-screen-scrubbers.
4. The tube-screen-scrubber comprising top and bottom ring-shaped hole perforated frames and multiple tubes suspended between the top and bottom ring-shaped hole perforated frames, wherein the ring-shaped holes on the ring-shaped hole perforated frame are formed by surrounding the end plugged portion of the tubes positioned at the center of the ring-shaped holes and lined up along the longitudinal axis of frame are placed at a tube regular spacing between the adjacent tubes along the ring-shaped hole perforated frame, and wherein the tube near the one edge of the tube-screen-scrubber frame is apart from the edge of the frame by a quarter length of the tube regular spacing, while the one near the other side edge apart by three quarter length of the tube regular spacing, and the other tubes in the middle frame are apart from each other by the tube regular spacing.
5. A trapezoidal-duct assisting poultry ammonia gas, hydrogen sulfide gas, and dust removal system of claim 1, wherein the trapezoidal-duct is in a shape of a square duct reducer consisting an air inlet large square open cross section and an air outlet small square open cross section, wherein the air inlet large square open cross section and the outlet small square open cross section of the trapezoidal-duct are same with the air outlet cross section of the tube-screen-scrubber device and the air inlet cross section of a ventilation fan, respectively, and wherein the height of the trapezoidal-duct is as long as possible.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0050]
DESCRIPTION OF NUMBERS IN THE DRAWINGS
[0051] 1 tube-screen-scrubber device (poultry NH.sub.3 gas removal tube-screen-scrubber device), 2 working solution inlet port, 3 inlet working solution distributer, 4 working solution supplying box cover, 5 working solution spray nozzle, 6 working solution uniform distributer, 7 steel mesh plate, 8 top ring-hole perforated plate with plugged tubes set in holes, 9 tube, 10 tube-screen-scrubber pack, 11 bottom ring-hole perforated plate, 12 working solution collection sump attached open-box-shape supporter, 12-1 open-box-shape-supporter, 12-2 side wall supporting tube-screen-scrubber, 12-3 plate bar supporter, 13 working solution outlet port, 14 rim, 15 working solution supply box, 16 ring-hole surrounding plugged tube, 17 plate-shape tube-screen-scrubber, 18 top ring-hole perforated frame, 19 plugged tube, 19-1 front side of plugged tube, 20 tubes row, 21 working solution distribution box with water solution uniform distributer on bottom, 22 working solution outlet hole, 23 pitch distance between tube-centers of adjacent tubes (equilateral triangle formed in the zigzag arrangement of tubes in packing bed), 24 distance between tube rows computed from using 1.7321×half of tube center interval, 25 gap between adjacent ring hole, 26 interval between adjacent tube surfaces, 0.435 inches, 26-1 a cross sectional area of a channel of air stream made of by three adjacent tubes in the tube-screen-scrubber, 27 direction of inlet-air flowing, 28 smooth flowing air stream before entering the tube-screen-scrubber pack, 28-1 and 28-2 inner- and outer-layer air streams flowing to the front side of the adjacent tube on slanted lines at respective lower and upper incidence angle 30° C. to the forward direction of the slowing air stream after passing through the round tubes, 29 standard poultry AHD removal equipment, 30 clean air outlet side of tube-scree-scrubber (standard poultry AHD removal equipment), 31 air inlet side of standard poultry AHD removal equipment (filter device), 32 filter device, 33 H.sub.2S adsorber device, 34 H.sub.2S adsorbent pellet box, 35 air outlet side of H.sub.2S adsorber device, 36 front mash plate, 37 H.sub.2S adsorbent pellets, 38 poultry dust filter device, 39 dust filter box, 40 air inlet side of poultry dust filter device, 41 large dust filter, 42 medium dust filter, 43 fine dust filter, 44 standard poultry AHD removal system, 45 working solution major system supply inlet circulation pipe (working-solution-major-system-inlet-circulation-pipe), 46 working solution major system returning outlet circulation pipe (working-solution-major-system-outlet-circulation-pipe), 47 two way valve, 47-1 three way valve, 48 small or medium size ventilation fan, 49 side wall of litter storage, 50 expanded poultry AHD removal equipment, 51 expansion line for increasing 4.5 ft height of standard equipment to 7 ft height of expanded equipment, 52 expanded filter device, 53 expanded H.sub.2S adsorber device, 54 expanded (NH.sub.3 gas removal) tube-screen-scrubber device, 55 expanded (NH.sub.3 gas removal) tube-screen-scrubber pack, 56 clean air outlet side of expanded tube-screen-scrubber pack (expanded poultry AHD removal equipment), 57 air speed of 500 ft/min and air flow rate of 5500-8000 ft.sup.3/min, 58 air speed 500 ft/min and air flow rate 178,000-23,000 ft.sup.3/min, 59 square trapezoidal-duct, 60 trapezoidal top, 4.5(H)×4.5(W) ft.sup.2, of square trapezoidal-duct, 61 trapezoidal base, 7(H)×6.6(W) ft.sup.2, of square trapezoidal-duct, 62 height, 6.6 ft, of square trapezoidal-duct, 63 velocity and flow rate of flowing air entering the square trapezoidal-duct through large base cross section are 500 ft/min and 17,800-23,000 ft.sup.3/min, 64 velocity and flow rate of flowing air leaving the square trapezoidal-duct through small top cross section are 1300-1500 ft/min and 17,800-23,000 ft.sup.3/min, 65 large ventilation fan blowing of air speed 1300-1500 ft/min and flow rate of 17,800-23,000 ft.sup.3/min, 66 trapezoidal-duct assisting expanded poultry AHD removal equipment, 67 single unit main system of trapezoidal-duct assisting expanded poultry AHD removal system, 68 auxiliary system, 68-1 working solution inlet port of auxiliary system (auxiliary inlet port), 68-2 working solution outlet port of auxiliary system (auxiliary outlet port), 69 wet-fine-dust-filter cartridge, 70 auto-tap-water-valve, 71 working solution reservoir tank, 72 working solution circulation pump, 73 ion exchanger column, 74 phosphoric acid solution tank, 75 phosphoric acid solution supply pump, 76 monoam0nium phosphate salt (fertilizer) collection tank. 77 HCl solution tank, 77-1 HCl solution supply pipe, 78 HCl solution supply pump, 79 open and close valve, 80 trapezoidal-duct assisting expanded poultry AHD removal system (six units), 81 working solution distribution pipe, 82 main system of trapezoidal-duct assisting expanded poultry AHD removal system (six units) (main system), 82-1 main system outlet port, 83 picture reduction line, 84 trapezoidal-duct assisting expanded poultry AHD removal system (removal system) installed at huge poultry house of 10(H)×66(W)×600(L) (eighteen units), 84-1 major system (including three subsystems without auxiliary system), 85 subsystem, 85-1 subsystem outlet port, 86 four way controlling valve, 86-1 major system inlet port, 86-2 major system outlet port, 87 working solution subsystem supply pipe, 88 working solution subsystem supply port, 89 working solution subsystem outlet pipe attached to trapezoidal-duct assisting expanded poultry AHD removal system (eighteen units), 90 end-side-wall of huge poultry house of 10(H)×66(W)×600(L), 91 subsystem working solution collection sump, 92 side-wall of poultry house, 93 auxiliary circulation pipe-one, 94 auxiliary circulation pipe-two, 95 auxiliary circulation pipe-three, 96 auxiliary circulation pipe-four, 97 auxiliary circulation pipe.
DESCRIPTION OF SPECIFIC TERMS USED
[0052] AHD: abbreviation of Ammonia gas, Hydrogen sulfide gas, and Dust-particles.
[0053] Cavity partial-mold 4: cavity partial-mold allows for PTSF cavity to be formed surrounding the cavity partial-mold by covering the upper and lower cavity partial-mold halves with the hollowed-out PTSF cavity halves on the inner surfaces of the upper and lower partial molds.
[0054] Hollowed-out tube cavity halves 43-1: tube cavity halves are hollowed-out on the inner surfaces of the molds, which are provided between the imaginary top and bottom frames.
[0055] Hollowed-out PTSF cavity half 43: plastic-tube-screen-fill cavity half is hollowed out on the inner surface of the mold.
[0056] Hollowed-out inner surfaces: Inner surface hollowed-out of the PTSF cavity halves on upper and lower partial-molds.
[0057] MRS bottom frame 16-1: Metal-Rod-filled-tube-Screen (MRS) attached bottom frame made up by attaching MRS on the bottom frame to be in one single structure as shown in
[0058] MRS bottom frame cavity 17-1: partial PTSF cavity without top frame cavity comprising cavity surrounding the MRS and bottom frame cavity shown in
[0059] MRSF 29: Metal-Rod-Filled-Tube-Screen-Fill comprising top and bottom frames and metal-rod-tube-screen between them.
[0060] Metal-rod-filled-tube 23: tube is filled with metal rod.
[0061] Plastic-tube-screen-fill (PTSF) 29: a plurality of tubes are vertically installed in the shape of a flat-plate rectangular string screen between the top and bottom ring-shaped holes perforated frames by attaching their both ends on the inner circles of the ring-shaped holes provided on the inner surfaces along the axes of the frames at a tube-regular-spacing between the adjacent tubes on the frames, referred to U.S. Pat. No. 10,046,502 B2.
[0062] Poultry AHD: poultry ammonia gas, hydrogen sulfide gas, and dust-particles produced from poultry production activities.
[0063] PTSF cavity 28-1: PTSF-shape space formed surrounding the MRSF within the cavity partial-mold.
[0064] SSA: abbreviation of Specific Surface Area defining a ratio of surface area of total tubes in a unit volume of cubic feet, ft.sup.2/ft.sup.3.
[0065] Tube cavity 25: tube-shape space formed surrounding the metal-rod-filled-tube surface by covering the upper and lower metal-rod-filled-tube halves with hollowed-out tube cavity halves on the inner surfaces of the upper and lower partial-molds.
DETAILED DESCRIPTION OF THE PREFERED EMBODIMENT
[0066] The poultry production facilities include naturally ventilating open-litter-storage and poultry house ventilated by ventilation fans. To collect and remove the poultry AHD released from the stacked litter in the open-litter-storage, the open-litter-storage needs adjusting of the open storage into an enclosed storage like the poultry house. As the poultry house uses large and standard ventilation fans for ventilation of poultry AHD in the poultry house and the litter storage uses natural ventilation for removal of the poultry AHD produced from the stacked litter, their installations of the poultry AHD removal systems are different. The poultry AHD removal equipment shown in
[0067] <Installation of Standard Poultry AHD Removal Equipment at Litter Storage> In order to collect and remove the poultry AHD emitted from the current stacked litter in the open-litter-storages, the open-litter-storages are needed to be adjusted into enclosed storages like the poultry house and then the standard poultry AHD removal equipment shown in
[0068] <Installation of Trapezoidal-Duct Assisting Expanded Poultry AHD Removal System at Poultry Houses> Since current commercial poultry houses are in various sizes up to a huge house of 10(H)×66(W)×600(L) ft.sup.3, two poultry houses of small 10(H)×40(W)×400(L) ft.sup.3 and huge 10(H)×66(W)×600(L) ft.sup.3 are selected to show how the trapezoidal-duct assisting expanded poultry AHD removal systems at the small and huge poultry houses, because their installations are different. The selected poultry houses need six and eighteen ventilation fans whose air flowing rates and fan blade sizes are same as 23,000 cfm and 54″, respectively. For the poultry house of 10(H)×40(W)×400(L) ft.sup.3, six trapezoidal-duct assisting expanded poultry AHD removal equipments are installed on the end side wall of the poultry house as shown in
[0069] <Operation of the Trapezoidal-Duct Assisting Expanded Poultry AHD Removal System Installed at Huge Poultry House> The trapezoidal-duct assisting expanded poultry AHD removal system 84 installed at the huge poultry house of 10(H)×66(W)×600(L) ft.sup.3 is schematically illustrated as shown in
[0070] <Functions of Auxiliary System> The auxiliary system 68 has a main function of circulating the working solution through the expanded poultry NH.sub.3 gas removal tube-screen-scrubber device 54 equipped in the trapezoidal-duct assisting expanded poultry AHD removal system 84 using the working-solution-major-system-circulation-pipes 45, 46 connecting the major system 84-1 of the trapezoidal-duct assisting expanded poultry AHD removal system and the auxiliary system and the working solution circulation pump 75 in the auxiliary system 68. The auxiliary system 68 includes primary and secondary components. The primary components are a wet-fine-dust filter 69, working-solution-reservoir-tank 71, working-solution-circulation-pump 72, and ion-exchanger-column 73, which are sequentially connected along with the working-solution-auxiliary-circulation-pipe 97 and secondary components of HCl-solution-tank 77, HCl-solution-supply-pump 78, phosphoric-acid-solution-tank 74, phosphoric-acid-solution-supply-pump 75, ion-exchanger-regenerated-MAP-salt-solution reservoir tank 76, and automatic-tap-water-supplier 70 are directly or indirectly connected to the working-solution-circulation-pipe 45, 46 running throughout the auxiliary system 68 as shown in
[0071] <Cross-Current Contacting of NH.sub.3 Gas Contaminated Air and Working Solution Streams in Tube-Screen-Scrubber Device> After passing the dust filter 52 and H.sub.2S gas adsorber 53 devices equipped in the expanded poultry AHD removal equipments 66, the poultry AHD contaminated air streams contain the NH.sub.3 gas and a small amount of remaining fine dust particles unable to be filtered in the dust filter device and then horizontally enter the expanded NH.sub.3 gas removal tube-screen-scrubber devices 54 in which the working solution has been flowing down over the surfaces of the vertical long-tubes 9 vertically installed in the device 54. The NH.sub.3 gas and fine dust particle contaminated air streams pass transversely through the vertical long-tubes 9 vertically installed in the tube-screen-scrubber devices 54 to cross-currently contact with the film-shape working solutions containing H.sup.+ and Cl.sup.− ions flowing down over the surfaces of the vertical long-tubes 9. During cross-currently contacting each other of the NH.sub.3 gas and fine dust particle contaminated air stream and working solution stream on the surfaces of the film-shape working solution flowing down over the vertical long-tubes 9, the NH.sub.3 gas and remaining fine-dust-particles in the air stream are respectively dissolved and transferred into the working solution. The NH.sub.3 gas dissolved in the working solution is reformed into the liquid phase ammonia gas, NH.sub.3(aq), in the working solution. The liquid phase NH.sub.3(aq) is immediately and completely trapped by being converted to liquid phase, NH.sub.4.sup.+(aq), due to chemical reaction with acid, H.sup.+, in the working solution. Such a cross-current contact of the contaminated air stream passing transversely through the vertical long-tubes 9 and the working solution stream vertically flowing down over the surface of the vertical long-tubes 9 continuously occurs on the surfaces of all long-tubes 9 arranged in the zigzag configuration within the device 54 until both of the air and working solution streams completely pass out of the tube-screen-scrubber device 54. Hence, the NH.sub.3 gas and fine dust-particles in the air stream are completely removed into the working solution stream, which means that the clean air is discharged into the environment surrounding the poultry houses and that the working solution passed through the tube-screen-scrubber devices 54 containing the base ions of H.sup.+ and Cl.sup.− and liquid phase NH.sub.4.sup.+ ions and small amount of fine dust-particles is circuited into the three. subsystems 85 of the major system 84-1 after passing through the auxiliary components of the wet-fine-dust-filter-cartridge 69, working solution reservoir tank 71, working solution circulation pump 75, and ion exchanger column 73, which are consecutively connected on along the working solution pipe 45 in the auxiliary system 68 as shown in
[0072] <Variation of Chemical Components in Working Solution While Working Solution Circulates through Circulation Pipe> The working solution is the hydrochloride acid water which is made of by adding HCl solution in water. So, the fresh working solution in the working solution reservoir tank 71 at the initial time contains hydrogen cation H.sup.+ and chloride anion Cl.sup.− in water with no any other chemical components. The fresh working solution circulating through the main system 84 contacts for the first time with the NH.sub.3 gas and small amount of fine dust-particles remained in the exhausted air stream on the surfaces of the tubes 9 vertically suspended in the NH.sub.3 gas removal tube-screen-scrubber device 54 equipped in the trapezoidal-duct assisting expanded poultry AHD removal equipment 66. The NH.sub.3 gas present in the air stream dissolves into the working solution stream by penetrating through the interfaces between the NH.sub.3 gas contaminated air and working solution streams. When the NH.sub.3 gas dissolves in the working solution, the chemical components present in the working solution are H.sub.2O, NH.sub.4.sup.+(aq), and CL.sup.− as follows.
H.sub.2O+H.sup.++Cl.sup.−+NH.sub.3(g) .Math. H.sub.2O+H.sup.++Cl.sup.−+NH.sub.3(aq) .Math. H.sub.2O+NH.sub.4.sup.+(aq)+Cl.sup.− (4)
[0073] The small amount of fine dust-particles remained in the air stream is quickly transferred to the working solution as the dust-particles are easily absorbed into the water. Therefore, the working solution passed through the NH.sub.3 gas removal tube-screen-scrubber devices 54 contains NH.sub.4.sup.+, Cl.sup.−, and fine dust-particles, which continuously flows through the working solution outlet circulation pipes 89 and working solution return inlet circulation pipe 46 to reach the circulation solution reservoir tank 71 after filtering the fine dust-particles through the wet-fine-dust-filter cartridge 69 on the circulation pipe 46 as shown in
NH.sub.4.sup.++Cl.sup.−+R—H.sup.+.fwdarw.H.sup.++Cl.sup.−+R—NH.sub.4.sup.+ (5)
where R—H is the H.sup.+ form ion exchanger resin and R—NH.sub.4.sup.+ is the NH.sub.4.sup.+ form ion exchanger resin. The NH.sub.4.sup.+ chemical bonded on the ion exchanger bead is not replaced by H.sup.+ itself because of weaker chemical affinity of the H.sup.+ ion than that of the NH.sub.4.sup.+ ion, so that the chemical reaction between the NH.sub.4.sup.+ and R—H.sup.+ occurs in one direction as shown in Eq. (5) until their equilibrium state is reached. Hence, the working solution passed the ion exchanger column 73 contains hydrogen cation H.sup.+ and chloride anion Cl.sup.−. Consequently, the working solution after passing the ion exchanger column 73 contains H.sup.+ and Cl.sup.− as in the initial chemical state of the working solution and the H.sup.+ is used again to capture the NH.sub.3 gas from the exhausted air stream. Likewise, the amount of hydrochloride in the working solution does not change and the NH.sub.3 gas absorbed from the exhausted air stream emitted from the poultry facilities is stored in the ion exchanger after converting the NH.sub.3(aq) to NH.sub.4.sup.+ ion by capturing the NH.sub.3(aq) with H.sup.+ in the working solution.
[0074] <Regeneration of Ion Exchanger Column> While operating of the main system of the trapezoidal-duct assisting expanded poultry AHD removal system 84, when an allowable threshold concentration limit (e.g. reaching to an equilibrium state between the liquid phase NH.sub.4.sup.+ ions in the working solution and resin phase NH.sub.4.sup.+ in the ion exchanger resins) is passed or an adsorption capability of the ion exchanger resin for liquid phase NH.sub.4.sup.+ions in the working solution is significantly dropped off, the operation of the main system is stopped and the ion exchanger resin column is necessary to be regenerated. Namely, the chemical state of significantly dropping off of adsorption capability of the ion exchanger resin for the liquid phase NH.sub.4.sup.+ ions indicates close to an equilibrium state between the liquid phase and resin phase NH.sub.4+ ions as shown in Eq. (6) given below. The chemical components present in the working solution and ion exchanger resin in the ion exchanger column are small amount of NH.sub.4.sup.+(aq) and R—H.sup.+ and large amount of HCL and R—NH.sub.4.sup.+, which are in equilibrium state as shown in Eq. (6).
NH.sub.4.sup.++Cl.sup.−+R—H.sup.+ .Math. H.sup.++Cl.sup.−+R—NH.sub.4.sup.+ (6)
where R—NH.sub.4.sup.+ and NH.sub.4.sup.+ are in resin and liquid phases, respectively. If the adsorption capability of the liquid phase NH.sub.4.sup.+ ions of the ion exchanger resin is in an enough room, the HCl solution is added to the working solution from the HCl solution tank by operating the working solution supply pump as shown in the auxiliary system shown in
R—NH.sub.4+HCl+H.sup.++H.sub.2PO.sub.4.sup.−.fwdarw.R—H+NH.sub.4.sup.+(aq)+HCl+H.sub.2PO.sub.4.sup.−.fwdarw.R—H+HCL+NH.sub.4(H.sub.2PO.sub.4) ↓ (7)
three steps of chemical reactions between the regeneration H.sub.3PO.sub.4 acid solution and NH.sub.4.sup.+ form ion exchanger resin to produce the MAP salt fertilizer and to change the NH.sub.4.sup.+ form ion exchanger resin into H.sup.+ form. These chemical processes occur while passing of the regeneration H.sub.3PO.sub.4 acid solution through the ion exchanger column. The spent regeneration H.sub.3PO.sub.4 acid solution passed out of the ion exchanger column contains HCl solution and MAP salt, which is collected in the MAP salt collection tank. Since the NH.sub.4.sup.+ form ion exchanger resin is regenerated by once-through-passing of the regeneration solution through the ion exchanger column, the NH.sub.4.sup.+ form ion exchanger resin is contacted with fresh regeneration solution all through the processing of the ion exchanger regeneration. Hence, the NH.sub.4.sup.+ form ion exchanger resin in the ion exchanger column is completely regenerated to be in the H.sup.+ form ion exchanger resin, which is ready for next operation of the standard and trapezoidal-duct assisting expanded poultry AHD removal systems.
[0075] <Production of MonoAmmonium Phosphate Fertilizer> To regenerate the NH.sub.4.sup.+ formed ion exchanger resin contained in the ion exchanger column 73, firstly, on/off valves 79 on the working solution circulation pipes connected to the bottom and top portion of the ion exchanger column are closed and the on/off valves on regeneration H.sub.3PO.sub.4 acid solution supplying pipe 73-1 attached to the bottom portion of the ion exchanger column and spent regeneration solution discharging pipe 73-2 respectively connected to the bottom and top portions of the ion exchanger column 73 are open. Then, the regeneration H.sub.3PO.sub.4 acid solution is supplied into the ion exchanger column73 through the regeneration supply pipe 73-1 from the H.sub.3PO.sub.4 acid solution tank 74 by operating of the regeneration solution supply pump 75 as shown in the auxiliary system 68 shown in
[0076] The tube-screen-scrubber device of the present invention is invented for removing of the poultry ammonia gas from the exhausted air stream emitting from the poultry production facilities, supplementing the disadvantages of the current wet-scrubber devices. The tube-screen-scrubber pack being employed in the tube-screen-scrubber device satisfactorily meets the well-known three grouped requirements of packing materials necessary to effectively perform scrubbing of gas described in the section of <Disadvantages of Current Commercializing Cross-Current-Type Packed Bed>. The structured packing material of the tube-screen-scrubber pack is same with that of the tube-screen-fill pack patented by the present inventor for improving the drawbacks of the current cooling tower fill pack. The tube-screen-scrubber pack has been verified by operating of the prototype cooling tower for the performance-testing of the tube-screen-fill pack and current cooling tower PVC film fill pack, having obtained a 30% higher water cooling efficiency compared to that of the current cooling tower PVC film fill pack and a specific surface area of 24 ft.sup.2/ft.sup.3 compared to 55 ft.sup.2/ft.sup.3 for cooling tower PVC film fill pack. Applying such approved tube-screen-scrubber packs in the poultry NH.sub.3 gas removal tube-screen-scrubber device invented in the present invention, it is believed that the trapezoidal-duct assisting poultry AHD removal system uniquely applied and invented in the present invention removes all sources emitting from the poultry farms providing major causes to the environmental problems and to the opposition of the residential communities surrounding the poultry farms against the expansion of the existing poultry farms.
[0077] While only specific embodiments of the invention has been described and shown, this invention may be further modified and altered within the concept and scope of this disclosure. This application is therefore intended to cover any modifications, alterations, variations, adaptations, or use of the invention using its general principles. Further, it is intended to include all such modifications and alterations insofar as they come within the scope of the appended claims or the equivalent thereof.