Fuel cell having a modular base active area
11682782 · 2023-06-20
Assignee
Inventors
- Filippo Gambini (Boston, MA, US)
- Amedeo Conti (Somerville, MA, US)
- Scott Blanchet (Chelmsford, MA, US)
Cpc classification
Y02P70/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/249
ELECTRICITY
International classification
Abstract
A modular fuel cell includes a membrane electrode assembly interposed between a pair of bipolar plates, and the membrane electrode assembly has a total active area measured in an x-y plane that is generally perpendicular to the z-axis. Each bipolar plate includes a plurality of common passages extending generally parallel to the z-axis. The total active area of the membrane electrode assembly includes a plurality of base active areas arranged co-planar in the x-y plane along an x-axis.
Claims
1. A method of manufacturing a fuel cell, the method comprising: calculating a total active area for the fuel cell based on a specification for an application, wherein the specification includes at least one of a fuel cell voltage, a fuel cell current, a fuel cell weight, and a fuel cell volume; selecting a base active area, wherein the base active area is configured for co-planar arrangement along a single axis; providing a membrane electrode assembly having the total active area, wherein the total active area comprises a multiple of the base active areas arranged co-planar along at least a single axis; and placing a pair of bipolar plates adjacent to both sides of the membrane electrode assembly, wherein each bipolar plate is comprised of sections and each section includes common passages, and the number of sections is equal to the number of base active areas forming the total active area of the membrane electrode assembly, wherein, the total active area comprising the base active areas arranged co-planar in a x-y plane along an x-axis; and wherein common passages comprise: at least one first feed passage and at least one second feed passage per base active area; at least one first discharge passage and at least one second discharge passage per base active area; and at least one first coolant passage and at least one second coolant passage.
2. The method of manufacturing of claim 1, wherein a height measured along a y-axis of the total active area is equal to height measured along the y-axis of the base active areas; and a length measured along the x-axis of the total active area is equal to a multiple of a length measured along the x-axis of base active areas.
3. The method of manufacturing of claim 1, further comprising at least one tie rod passage, wherein the number of tie rod passages is a multiple of a total number the base active areas forming the total active area.
4. The method of manufacturing of claim 1, wherein the feed passages and discharge passages are distributed along an upper and lower border region extending along the x-axis of each bipolar plate, and the coolant passages are distributed evenly along a left and a right border region extending along the y-axis of each bipolar plate.
5. The method of manufacturing of claim 1, wherein the feed passages are sized to supply sufficient quantities of gaseous reactant and discharge passages are sized to discharge sufficient quantities of reactant products to and from the base active area of the membrane electrode assembly to allow for efficient fuel cell performance.
6. The method of manufacturing of claim 1, wherein each bipolar plate further comprises: two side sections and at least one inner section; wherein each of the side sections and the at least one inner section delimits a portion of the total active area substantially equal to one of the base active areas; and wherein each of the sides sections and the inner section includes a separate first feed passage, second feed passage, first discharge passage, and second discharge passage.
7. The method of manufacturing of claim 6, wherein each side section is a mirror reflection of the other side section and comprises at least one feed passage, at least one discharge passage, and at least one tie rod passage.
8. The method of manufacturing of claim 7, wherein each inner section comprises at least one feed passage, at least one discharge passage, and a portion of a tie rod passage.
9. The method of manufacturing of claim 8, wherein the portion of a tie rod passage is aligned with another portion of a tie rod passage that is part of an adjacent section to form a complete tie rod passage.
10. The method of manufacturing of claim 6, wherein the total number of the side sections and the at least one inner sections that form each of the bipolar plates is equal to the number of base active areas combined to form the total active area.
11. The method of manufacturing of claim 6, wherein the side sections and at least one inner section are configured for co-planar attachment parallel to the x-y plane and extending along the x-axis.
12. The method of manufacturing of claim 1, wherein the fuel cell stack is configured to be compressed by an external compression system.
13. The method of manufacturing of claim 1, wherein the base active areas arranged co-planar in the x-y plane along an x-axis for a continuous total active area.
Description
(1) The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments of the present disclosure and together with the description, serve to explain the principles of the disclosure.
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(11) Reference will now be made in detail to the present exemplary embodiments of the present disclosure, examples of which are illustrated in the accompanying drawings. Wherever possible, the same reference numbers will be used throughout the drawings to refer to the same or like parts. Although described in relation to a fuel cell employing hydrogen, oxygen, and water, it is understood that the devices and methods of the present disclosure can be employed with various types of fuel cells and electrochemical cells, including, but not limited to electrolysis cells, hydrogen purifiers, hydrogen expanders, and hydrogen compressors.
(12) Throughout the specification the terms “generally parallel” and “generally perpendicular” may be used to describe the arrangement of one or more components in relation to an axis, plane, or other component. The degree of offset from parallel and perpendicular that can be tolerated when describing an arrangement as “generally parallel” or “generally perpendicular” can vary. The allowable offset may be, for example, less than about 20 degrees off, such as an offset less than about 10 degrees, an offset of less than about 5 degrees, and offset of less than about 3 degrees, an offset of less than about 2 degrees, and an offset of less than about 1 degree.
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(14) Fuel cell 100 can comprise two bipolar plates 150, 160. MEA 140 can be interposed between bipolar plates 150, 160. Bipolar plates 150, 160 can act as current collectors, provide access channels to the respective electrode surfaces for the fuel and the oxidant, and provide channels for the removal of water formed during operation of fuel cell 100. Bipolar plates 150, 160 can also provide access channels for cooling fluid (i.e., water, glycol, or water glycol mixture). The bipolar plates can be made from aluminum, steel, stainless steel, titanium, copper, Ni—Cr alloy, graphite or any other electrically conductive material. Bipolar plates 150, 160 can separate PEM fuel cell 100 from the neighboring fuel cells in the fuel cell stack (not shown). In some embodiments, two adjacent fuel cells in a fuel cell stack can share a bipolar plate (not shown in
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(16) In the embodiment shown in
(17) Proper management of gaseous reactants, reactant products, and water/humidity can be fundamental to achieving proper performance of fuel cell 100. In order to achieve consistent performance, several parameters can be optimized. For example, the flow rate and pressure of the gaseous reactants (i.e., hydrogen and oxygen) to the MEA through the common feed passages can be optimized to achieve efficient power production. In addition, reactant products (i.e., depleted hydrogen and depleted oxygen) and liquid (water/humidity) removal from the MEA through the common discharge passages can be optimized to achieve efficient power production. Accordingly, these parameters can be optimized for a single base active area 210. Particular attention can be given to the optimization of the pressure drops through the cell in order to meet the requirements for an application.
(18) Subsequently, by adding multiples of base active area 210 together during the design of total active area 200, the performance of total active area 200 can be projected. This analysis can be easier and more accurate based on the known optimized performance of the base active area 210. Based on the typical fuel cell design, changing the vertical dimension can alter the fluid dynamics, and thus performance and power efficiency. However, by repeating base active area 210 along the horizontal x-axis, the vertical dimension of total active area 200 remains unchanged regardless the number of base active areas 210 forming total active area 200. This allows the fluid dynamics and mechanical properties to remain substantially unchanged. In order for total active area 200 to substantially maintain the same fluid dynamics and mechanical properties as base active area 210, the common passages supplying and discharging gaseous reactants and reactant products can be modularly repeated as the base active area 210 is repeated.
(19) It is understood that MEA 140 having a total active area 200, although made up of multiple base active areas 210, can be formed from a single continuous MEA having an area equal to total active area 200. Plates, electrodes, gaskets and other components of fuel cell 100 can similarly be formed of a single piece covering or encompassing total active area 200.
(20) Bipolar plates 150, 160 can be configured to be similarly modular like base active area 210.
(21) According to an exemplary embodiment, bipolar plate 150 shown in
(22) In various embodiments, bipolar plate 150 can be divided into co-planar modular sections, configured for placement adjacent to one or more sections, extending along the x-axis. In this particular exemplary embodiment, bipolar plate 150 can be divided into three sections, an inner section 280 and two side sections 260, 270. Side section 270 can be configured to be a mirror reflection of side section 260. This can allow for the design and construction of side sections 260, 270 to be substantially the same. A difference could be the orientation when forming bipolar plate 150. For example, rotating side section 260 by 180 degrees orients side section 260 such that it can become side section 270. And side section 270 can be rotated 180 degrees such that it can become side section 260. It is understood that all the properties, aspects, and characteristics of side section 260 can be the same for side section 270.
(23) Inner section 280 can be configured to be interposed between side sections 260, 270. Inner section 280 and side section 260, 270 are similarly modular like base active area 210 and each section can correspond to one of the base active area 210. Accordingly, for each modular base active area 210 that makes up total active area 200 fuel cell 100 can have a corresponding modular inner section 280 or side section 260, 270.
(24) In various embodiments, fuel cell 100 can be comprised of any number of base active area and corresponding bipolar plate sections. For example,
(25) In another embodiment, as shown in
(26) In alternate embodiments, bipolar plates can be formed of a single structure instead of one or more sections. To accommodate the differing size of the total active area different size single structure bipolar plates can be constructed. For example, there can be bipolar plates sized for a single base active area, two base active areas, three base active area, four base active area, etc. Although comprised of a single structure, the bipolar plates design can still utilize modular sections with modularly repeated common passages as part of the designing phase.
(27) It is understood that the base active area 210 and the bipolar plate 150 sections (inner section 280 and side sections 260, 270) that can be configured for co-planar placement adjacent to another can refer to placement taking place during the design, manufacture or assembly phase for fuel cell 100.
(28) In accordance with an exemplary embodiment,
(29) Bipolar plates 150, 160 can be comprised of a plurality of common passages 430 for feeding gaseous reactants to MEA 140 and discharging reactant products from MEA 140. The plurality of common passages 430 can extend generally parallel at least part of the length of fuel cell stack 400 along the z-axis. At each end of fuel cell stack 400 can be an end plate 440 configured to distribute and consolidate the plurality of common passages. For example, the end plate can receive an incoming flow of hydrogen and an incoming flow of oxygen gas and be configured to distribute the flows to the one or more common passages configured to distribute the hydrogen and oxygen gas to each fuel cell. In addition, the end plate can also be configured to consolidate the one or more reactant product flows into a discharge flow of depleted fuel and a discharge flow of depleted oxygen.
(30) In addition, to the common passages each bipolar plate 150, 160 can be comprised one or more tie rod passages 243 configured for receiving one or more stack tie rods 410. Tie rod passages 243 can be configured so the stack tie rods 410 pass through corresponding tie rod passages within bipolar plates 150, 160 of fuel cell stack 400. The stack tide rods 410 can be used to compress the entire fuel cell stack 400 by tightening at least one pair of fasteners 420 at each end of fuel cell stack 400.
(31) According to an exemplary embodiment, as shown in
(32) In an alternate embodiment shown in
(33) With MEA 140 positioned on bipolar plate 150 as shown in
(34) Lower wall 230 can be comprised of at least one of a first discharge passage 263 and at least one of a second discharge passage 264 within each section of bipolar plate 150. First discharge passage 263 and second discharged passage 264 can be configured for discharging reactant products from MEA 140. First discharge passage 263 and second discharge passage 264 within each section of bipolar plate 150 can be adjacent to one another and distributed generally evenly along the x-axis within lower wall 230. Reactant products from MEA 140 can include depleted oxygen, water, depleted fuel or combination of the products. For example, first discharge passage 263 can discharge depleted oxygen and water and second discharge passage 264 can discharge depleted fuel. Each first discharge passage 263 and second discharge passage 264 within each section of bipolar plate 150 can be sized to discharge suitable amounts of reactant products from base active area 210 encompassed by the corresponding section. For example, first discharge passage 263 and second discharge passage 264 along with the bipolar plate channels (not shown) within left section 260 can be sized to discharge optimal amounts of reactant products from base active area 210 encompassed by side section 260.
(35) The shape of each first feed passage 261, second feed passage 262, first discharge passage 263, and second discharge passage 264 can be a rectangle, square, quadrilateral, oval, circular, or other various shapes. The dimensions of each first feed passage 261, second feed passage 262, first discharge passage 263, and second discharge passage 264 can be sized to allow for optimal gas and water management of each base active area 210 encompassed within the corresponding section.
(36) Supplying too little gas to MEA 140 can cause the fuel cell 100 to operate below maximum efficiency, while supplying too much gas can cause drying out of MEA 140.
(37) In this particular exemplary embodiment the feed passages are formed in upper wall 220 while the discharge passages are formed in lower wall 230. However, in alternate embodiments the configuration of the feed passages and discharge passages can be varied such that at least one feed passage and at least one discharge passage is formed in upper wall 220 and at least one feed passage and at least one discharge passage is formed in lower wall 230. Yet another possible configuration can include all feed passages formed in lower wall 230 and all discharge passages formed in upper wall 220.
(38) Each first feed passage 261, second feed passage 262, first discharge passage 263, and second discharge passage 264 can be configured to connect with channels (not shown) on the face of bipolar plates 150, 160 that define paths for the gaseous reactants to be carried from the feed passages to the electrodes within MEA 140 and define paths for the reactant products to be carried from the electrodes within MEA 140 to the discharge passages. The channels, like the feed and discharge passages, can be modularly repeated based on the number of base active area 210 making up the total active area 200.
(39) According to an exemplary embodiment, left wall 240 and right wall 250 can each comprise at least one of a first coolant passage 241 and at least one of a second coolant passage 242. First coolant passage 241 and second coolant passage 242 can be configured to allow coolant fluid to be pumped through the passages to remove the heat generated in MEA 140 during the operation of fuel cell 100. First coolant passage 241 and second coolant passage 242 can be distributed evenly in left wall 240 and right wall 250 extending parallel along the y-axis.
(40) The shape of first coolant passage 241 and second coolant passage 242 can be a rectangle, square, quadrilateral, oval, circular, or other various shapes. The shape selected can be configured to maximize surface interaction with MEA 140 to enhance heat transfer. The dimensions of first coolant passage 241 and second coolant passage 242 can be sized to allow adequate flow of coolant fluid so proper temperature control of fuel cell 100 can be maintained limiting the possibility of overheating.
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(42) In an additional embodiment illustrated in
(43) In alternate embodiments, fuel cell 100 can be cooled by conductive cooling, convective cooling or other means that do not require a coolant flowing through first coolant passage 241 and second coolant passage 242 of the bipolar plates 150, 160. Therefore, in these alternate embodiments the coolant passages can be removed from bipolar plates 150, 160.
(44) As shown in
(45) Generally, the combined capacity of the feed passages and discharge passages in all the sections of bipolar plates 150, 160 can be sufficient for the total active area 200 of MEA 140. As described above, this can be achieved by modularly repeating additional feed passages and discharges passages sized for each additional base active area.
(46) Similarly to the feed and discharge passage configuration, passages for the tie rods can also be configured to modularly scale based on the number of base active area 210. According to an exemplary embodiment, as shown in
(47) In alternate embodiments, the cross-sectional area of the feed passages and discharge passages can be sized based on both the size of the base active area and the number of fuel cells within the fuel cell stack. Since common feed passages and discharge passages can be used to supply all the fuel cells in the stack, the number of cells can affect the overall flow rate capacity of the common passages. For example, a fuel cell stack comprised of 100 fuel cells can have passages with a greater cross-sectional area capable of higher flow rates than that of a fuel cell stack with 10 of the same fuel cells. By further optimizing the cross-sectional area of the common passages based on the number of cells the overall volume of the fuel cell can be optimized. Optimizing the dimensions of the feed passages and discharge passages based on the number of fuel cells can include modifying only the vertical dimensions and leaving the horizontal dimensions fixed.
(48) In alternate embodiments, the coolant passages 241, 242 within side sections 260, 270 can be sized depending on the number of base active area and corresponding inner sections separating the side sections. For example, the greater the number of base active area and corresponding inner sections the further the heat has to travel to reach the side section where it can be discharged. Therefore, the coolant passages can increase in size and cooling capacity based on the number of inner sections. In yet another embodiment, instead of varying the size of the coolant passages the temperature and the flow rate of the coolant can be adjusted to compensate for the number of base active area and corresponding inner sections.
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(50) Following step S710, step S720 can comprise selecting a base active area. The base active area can be configured for co-planar arrangement along at least a single axis. For example, the embodiments described above the base active area can be arranged along the x-axis as illustrated in
(51) Following step S730, step S740 can comprise placing a pair of bipolar plates for placement adjacent to both sides of the MEA. The pair of bipolar plates can be sized to correspond to the size of the MEA. The pair of bipolar plates can be comprised of sections as described above according to exemplary embodiments. Each section can include common passages. The number of sections can be based on the number of base active area used to form the total active area of the MEA. For example, if the total active area is made up of two base active area than each of the pair of bipolar plates can be assembled using two sections wherein each section includes common passages. Similarly, if the total active area includes three base active areas than each pair of bipolar plates can be assembled using three sections (i.e., one inner section and two side sections).
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(53) Following step S810, step S820 can comprise selecting a base active area. The base active area can be configured for co-planar arrangement along at least a single axis. For example, the embodiments described above the base active area can be arranged along the x-axis as illustrated in
(54) Following step S830, step S840 can comprise inserting a plurality of bipolar plates between adjacent MEAs. Each bipolar plate can be sized to correspond to the size of the MEA. The pair of bipolar plates can comprise sections as described above according to exemplary embodiments. Each section can include common passages. The number of sections can be based on the number of base active area used to form the total active area of the MEA.
(55) Other embodiments of the present disclosure will be apparent to those skilled in the art from consideration of the specification and practice of the present disclosure herein. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the present disclosure being indicated by the following claims.