Composite separation membrane including coating layer of graphene oxide/bile acid or salt thereof and method for manufacturing the same

Abstract

The present invention relates to a composite separation membrane that is applicable to carbon dioxide separation and recovery processes. The composite separation membrane includes a coating layer composed of graphene oxide and a bile acid or its salt on a porous polymer support. The composite separation membrane of the present invention, which includes a coating layer composed of graphene oxide and a bile acid or its salt, has both high carbon dioxide permeability and high selectivity for carbon dioxide over nitrogen, hydrogen or methane gas, is free of surface defects, and maintains a stable structure without deterioration of its performance even after long-term use. Due to these advantages, the composite separation membrane of the present invention can be applied to industrial fields involving carbon dioxide separation and recovery processes. The present invention also relates to a method for manufacturing the composite separation membrane.

Claims

1. A composite separation membrane comprising a porous polymer support and a coating layer formed on the porous polymer support wherein the coating layer is composed of graphene oxide and a bile acid or its salt.

2. The composite separation membrane according to claim 1, wherein the porous polymer support is made of a polymer selected from the group consisting of polysulfone, polyethersulfone, polyimide, polyetherimide, polyamide, polyacrylonitrile, cellulose acetate, cellulose triacetate, and polyvinylidene fluoride.

3. The composite separation membrane according to claim 1, wherein the porous polymer support has a pore size in the range of 10 nm to 100 nm.

4. The composite separation membrane according to claim 1, wherein the graphene oxide has a size in the range of 0.1 μm to 5 μm.

5. The composite separation membrane according to claim 1, wherein the graphene oxide is functionalized graphene oxide prepared by the conversion of the hydroxyl, carboxyl, carbonyl or epoxy groups present in the graphene oxide to ester, ether, amide or amino groups.

6. The composite separation membrane according to claim 1, wherein the bile acid or its salt is selected from the group consisting of cholic acid, glycocholic acid, taurocholic acid, lithocholic acid, deoxycholic acid, chenodeoxycholic acid, mixtures thereof, and sodium salts thereof.

7. The composite separation membrane according to claim 1, wherein the coating layer comprises a monolayer or multilayer structure of the graphene oxide.

8. The composite separation membrane according to claim 7, wherein the monolayer graphene oxide has a thickness in the range of 0.6 nm to 1 nm.

9. The composite separation membrane according to claim 1, wherein the coating layer is an ultrathin film having a thickness in the range of 1 nm to 10 nm.

10. A method for manufacturing a composite separation membrane, comprising: i) dispersing graphene oxide in distilled water to obtain a dispersion; ii) adding a bile acid or its salt to the dispersion and stirring the mixture at 25 to 60° C. for 30 min or more to obtain a mixed solution; and iii) coating the mixed solution on a porous polymer support to form a coating layer.

11. The method according to claim 10, wherein the graphene oxide has a size in the range of 0.1 μm to 5 μm.

12. The method according to claim 10, wherein the graphene oxide is functionalized graphene oxide prepared by the conversion of the hydroxyl, carboxyl, carbonyl or epoxy groups present in the graphene oxide to ester, ether, amide or amino groups.

13. The method according to claim 10, wherein the dispersion is an aqueous solution of 0.01 to 0.5% by weight of the graphene oxide whose pH is adjusted to 2.0 to 12.0 with a 1 M aqueous solution of sodium hydroxide.

14. The method according to claim 10, wherein the bile acid or its salt is selected from the group consisting of cholic acid, glycocholic acid, taurocholic acid, lithocholic acid, deoxycholic acid, chenodeoxycholic acid, mixtures thereof, and sodium salts thereof.

15. The method according to claim 10, wherein the bile acid or its salt is added at a concentration of 0.01 to 5% by weight.

16. The method according to claim 10, wherein the porous polymer support is made of a polymer selected from the group consisting of polysulfone, polyethersulfone, polyimide, polyetherimide, polyamide, polyacrylonitrile, cellulose acetate, cellulose triacetate, and polyvinylidene fluoride.

17. The method according to claim 10, wherein the porous polymer support has a pore size in the range of 10 nm to 100 nm.

18. The method according to claim 10, wherein the coating is performed by a process selected from the group consisting of direct evaporation, transfer, spin coating, and spray coating.

19. The method according to claim 18, wherein the spin coating is repeated between 3 and 10 times.

20. The method according to claim 10, wherein the coating layer comprises a monolayer or multilayer structure of the graphene oxide.

21. The method according to claim 20, wherein the monolayer graphene oxide has a thickness in the range of 0.6 nm to 1 nm.

22. The method according to claim 10, wherein the coating layer is an ultrathin film having a thickness in the range of 1 nm to 10 nm.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 shows the structures of graphene oxide and functionalized graphene oxide.

(2) FIG. 2 shows the planar and steric chemical structures of sodium deoxycholate.

(3) FIG. 3 shows a predicted structure in which sodium deoxycholate micelles are bound to graphene oxide.

(4) FIG. 4 is an image of a composite separation membrane manufactured in Example 1.

(5) FIG. 5 is a scanning electron microscopy image showing the surface of a composite separation membrane manufactured in Example 1.

(6) FIG. 6 is a scanning probe microscopy image showing the surface of a composite separation membrane manufactured in Example 1.

(7) FIG. 7 is a graph showing the effective coating thickness of a composite separation membrane manufactured in Example 1, as measured by ellipsometry.

(8) FIG. 8 is a graph showing the gas permeability tendencies of a porous support PES membrane without a coating layer, a composite membrane including a graphene oxide coating layer formed on a PES film, and a composite separation membrane manufactured in Example 1, which includes a graphene oxide/sodium deoxycholate coating layer.

(9) FIG. 9 is a graph showing the selectivities of a composite separation membrane manufactured in Example 1 for carbon dioxide over hydrogen, nitrogen, and methane gas.

(10) FIG. 10 is a graph showing the carbon dioxide and nitrogen permeabilities of a composite separation membrane manufactured in Example 1 and the selectivities of the composite separation membrane for carbon dioxide over nitrogen at different partial pressures of carbon dioxide from a carbon dioxide (10 mole %)/nitrogen (90 mole %) mixed gas.

(11) FIG. 11 is a graph showing the carbon dioxide and nitrogen permeabilities of a composite separation membrane manufactured in Example 1 and the selectivities of the composite separation membrane for carbon dioxide over nitrogen at different partial pressures of carbon dioxide from a carbon dioxide (50 mole %)/nitrogen (50 mole %) mixed gas.

(12) FIG. 12 is a graph showing the carbon dioxide and nitrogen permeabilities of a composite separation membrane manufactured in Example 1 and the selectivities of the composite separation membrane for carbon dioxide over nitrogen at different partial pressures of carbon dioxide from a carbon dioxide (80 mole %)/nitrogen (20 mole %) mixed gas.

(13) FIG. 13 is a graph showing the selectivities of a composite separation membrane manufactured in Example 1 for carbon dioxide over nitrogen at different partial pressures of carbon dioxide and different concentrations of carbon dioxide in carbon dioxide/nitrogen mixed gases.

BEST MODE FOR CARRYING OUT THE INVENTION

(14) The present invention will now be described in detail with reference to the accompanying drawings. The present invention provides a composite separation membrane including a coating layer composed of graphene oxide and a bile acid or its salt on a porous polymer support and a method for manufacturing the composite separation membrane.

(15) General gas separation membranes have an asymmetric structure consisting of a dense selective separation layer as a surface layer and an underlying porous support with minimum permeation resistance. This structure is advantageous from the viewpoint of selective gas separation, recovery, and concentration. The separation layer should be free of surface defects and be formed as thin as possible for high gas permeability. For these reasons, most gas separation membranes are in the form of composite membranes including a coating layer formed on a porous polymer support. Further, gas separation membranes are preferably in the form of composite membranes with high mechanical strength and excellent thermal and chemical properties taking into consideration their performance and long-term operation. In view of the foregoing, the composite membrane of the present invention uses a porous polymer support.

(16) The porous polymer support can function as a reinforcing material to support an overlying coating layer. The porous polymer support is in contact with the coating layer and is made of a polymeric material having pores whose size is large enough for a gas to penetrate therethrough. Specifically, the porous polymer support is made of a polymer selected from the group consisting of, but not limited to, polysulfone, polyethersulfone, polyimide, polyetherimide, polyamide, polyacrylonitrile, cellulose acetate, cellulose triacetate, and polyvinylidene fluoride. Polyethersulfone is more preferred as a material for the support.

(17) Preferably, the porous polymer support is microporous with a pore size in the range of 10 nm to 100 nm. Within this range, gas permeation resistance at the bottom of the separation membrane can be minimized and the overall permeability of the composite membrane can be improved by controlling the surface porosity and bulk porosity of the polymer support.

(18) Next, a detailed description will be given concerning the coating layer formed on the porous polymer support. The coating layer is composed of graphene oxide and a bile acid or its salt.

(19) Graphene oxide can be prepared on a large scale by oxidizing graphite with as an oxidizing agent and includes hydrophilic functional groups, such as hydroxyl, carboxyl, carbonyl or epoxy groups. The majority of graphene oxide is currently prepared by the Hummers method [Hummers, W. S. & Offeman, R. E. Preparation of graphite oxide. J. Am. Chem. Soc. 80. 1339(1958)] or its partially modified Hummers methods. Graphene oxide obtained by a modified Hummers method is used in the present invention. The gas permeability of the coating layer can be controlled by varying the size of the graphene oxide. If the graphene oxide is larger in size than 5 μm, the coating layer exhibits barrier properties. In contrast, as the size of the graphene oxide decreases from 5 μm to 0.1 μm, the gas permeability of the coating layer is gradually increased to a level suitable for gas separation. Thus, the size of the graphene oxide is preferably adjusted to the range of 0.1 μm to 5 μm, more preferably 0.3 μm to 1 μm.

(20) In the present invention, functionalized graphene oxide may also be used. The functionalized graphene oxide can be prepared by chemical reaction of the graphene oxide with another compound to convert the hydrophilic functional groups present in the graphene oxide, such as hydroxyl, carboxyl, carbonyl or epoxy groups, to ester, ether, amide or amino groups. For example, the carboxyl groups of the graphene oxide may be converted to ester groups by reaction of the graphene oxide with an alcohol, the hydroxyl groups of the graphene oxide may be converted to ether groups by reaction of the graphene oxide with an alkyl halide, the carboxyl groups of the graphene oxide may be converted to amide groups by reaction of the graphene oxide with an alkyl amine, or the epoxy groups of the graphene oxide may be converted to amino groups by ring-opening reaction of the graphene oxide with an alkyl amine. FIG. 1 shows the structures of graphene oxide prepared from graphite by the Hummers method and functionalized graphene oxide prepared by reaction of the graphene oxide with another compound.

(21) On the other hand, the coating layer formed on the porous polymer support is composed of graphene oxide and a bile acid or its salt. The bile acid salt acts as a surfactant but has a structure consisting of a hydrophobic side and a hydrophilic side, unlike general surfactants. Due to this unique structure, the bile acid salt is known to have a critical micelle concentration over a broad range from 10 mM to 300 mM. Specific examples of such bile acids or salts thereof include cholic acid, glycocholic acid, taurocholic acid, lithocholic acid, deoxycholic acid, chenodeoxycholic acid, and sodium salts thereof. FIG. 2 shows the structures of sodium deoxycholate as the bile acid salt.

(22) As the bile acid or its salt, there may be used an acid selected from the group consisting of cholic acid, glycocholic acid, taurocholic acid, lithocholic acid, deoxycholic acid, and chenodeoxycholic acid or its sodium salt. Particularly, sodium deoxycholate structurally similar to graphene oxide is more preferably used because when sodium deoxycholate is added to a solution of the graphene oxide, it is hydrogen bonded and interacts hydrophobically with the graphene oxide to form a stable structure. FIG. 3 shows a structure in which sodium deoxycholate micelles are bound to graphene oxide.

(23) The coating layer includes a monolayer or multilayer structure of the graphene oxide. The monolayer graphene oxide has a thickness in the range of 0.6 nm to 1 nm. The multilayer graphene oxide may be formed by laminating a plurality of monolayer graphene oxide sheets. The interlayer spacing between the graphene oxide sheets is as small as about 0.34 nm to about 0.5 nm. As a result, additional migration paths are formed between the grain boundaries and the separation selectivity of the coating layer for a particular substance can be improved by controlling the pore and channel sizes of the gaps between the grain boundaries. The multilayer graphene oxide can increase the ratio of the penetration rates of two substances to be separated because it increases the diffusion path lengths of the substances. Accordingly, an increase in the number of graphene oxide layers in the multilayer graphene oxide leads to an increase in the selectivity of the multilayer graphene oxide. Thus, it is more preferred that the coating layer includes a multilayer structure of graphene oxide.

(24) The present invention also provides a method for manufacturing a composite separation membrane, including: i) dispersing graphene oxide in distilled water to obtain a dispersion; ii) adding a bile acid or its salt to the dispersion and stirring the mixture at 25 to 60° C. for 30 min or more to obtain a mixed solution; and iii) coating the mixed solution on a porous polymer support to form a coating layer.

(25) Preferably, the graphene oxide used in step i) has a size in the range of 0.1 μm to 5 μm. Within this range, improved gas permeability is achieved.

(26) The graphene oxide used in step i) may also be functionalized graphene oxide prepared by the conversion of the hydroxyl, carboxyl, carbonyl or epoxy groups present in the graphene oxide to ester, ether, amide or amino groups.

(27) The dispersion obtained in step i) is an aqueous solution of 0.01 to 0.5% by weight of the graphene oxide whose pH is adjusted to 2.0 to 12.0 with a 1 M aqueous solution of sodium hydroxide. If the concentration of the graphene oxide in the aqueous solution is less than 0.01% by weight, a uniform coating layer is difficult to obtain. Meanwhile, if the concentration of the graphene oxide in the aqueous solution exceeds 0.5% by weight, the aqueous solution is too viscous, making the subsequent coating step difficult to carry out. It is thus preferred to adjust the concentration of the graphene oxide in the aqueous solution to 0.01 to 0.5% by weight.

(28) The bile acid or its salt used in step ii) is preferably selected from the group consisting of cholic acid, glycocholic acid, taurocholic acid, lithocholic acid, deoxycholic acid, chenodeoxycholic acid, mixtures thereof, and sodium salts thereof. The concentration of the bile acid or its salt is preferably from 0.01 to 5% weight. If the bile acid or its salt is added at a concentration of less than 0.01% by weight, it is difficult to expect a stable structure through hydrogen bonding and hydrophobic interaction with the graphene oxide. Meanwhile, if the bile acid or its salt is added at a concentration exceeding 5% by weight, the mixed solution is too viscous, making the subsequent coating step difficult to carry out.

(29) The porous polymer support used in step iii) is made of a polymer selected from the group consisting of polysulfone, polyethersulfone, polyimide, polyetherimide, polyamide, polyacrylonitrile, cellulose acetate, cellulose triacetate, and polyvinylidene fluoride. Preferably, the porous polymer support has a pore size in the range of 10 nm to 100 nm. Within this range, gas permeation resistance at the bottom of the separation membrane can be minimized.

(30) In step iii), any suitable process known in the art may be used to form the coating layer. Preferably, the coating is performed by a process selected from the group consisting of direct evaporation, transfer, spin coating, and spray coating. More preferred is spin coating by which a uniform coating layer can be obtained in a simple manner.

(31) The spin coating is preferably repeated between 3 and 10 times. If the number of times of the spin coating is less than 3, the function of the coating layer as a selective separation layer is difficult to expect. Meanwhile, if the number of times of the spin coating exceeds 10, the coating layer is too thick, resulting in considerable deterioration of permeability.

(32) The coating layer formed in step iii) may include a monolayer or multilayer structure of the graphene oxide. The monolayer graphene oxide has a thickness in the range of 0.6 nm to 1 nm.

MODE FOR CARRYING OUT THE INVENTION

(33) The present invention will be explained in detail with reference to the following examples.

Example 1

(34) 0.1 wt % of graphene oxide prepared by a modified Hummers method was dispersed in water using an ultrasonic homogenizer. The pH of the dispersion was adjusted to 10.0 with 0.1 wt % of a 1 M aqueous solution of sodium hydroxide. To the graphene oxide dispersion was added 0.1 wt % of sodium deoxycholate. The mixture was stirred at 40° C. for 3 h to obtain a homogeneous mixed solution. 1 mL of the mixed solution was spin coated 5 times on a polyethersulfone (PES) support to form a coating layer composed of graphene oxide and sodium deoxycholate, completing the manufacture of a composite separation membrane.

Measurement Examples

(35) An image of the composite separation membrane manufactured in Example 1 was taken with a camera and the coating layer was observed using a scanning electron microscope (SEM) and a scanning probe microscope (AFM). A coating layer was formed on a silicon wafer by the same procedure as in Example 1 and the thickness of the coating layer was measured by ellipsometry.

Test Examples

(36) The gas permeability and selectivity of the composite separation membrane manufactured in Example 1 were measured by a constant pressure/variable volume method.

(37) The image of the composite separation membrane shown in FIG. 4 reveals the formation of the coating layer composed of graphene oxide and sodium deoxycholate on the porous polyethersulfone support.

(38) FIGS. 5 and 6 are a scanning electron microscopy image and a scanning probe microscopy image showing the surface of the composite separation membrane manufactured in Example 1, respectively. The images reveal that the coating layer composed of graphene oxide and sodium deoxycholate was uniformly coated on the polyethersulfone porous support, leaving no defects on the surface.

(39) It can be seen from FIG. 7 that the coating layer (GO/SDC) composed of graphene oxide (GO) and sodium deoxycholate (SDC) on the polyethersulfone porous support had a thickness as ultrathin as about 3.7 nm. Composite separation membranes were manufactured in the same manner as in Example 1, except that the number of times of the spin coating was changed to 3, 4, and 6 to 10. As a result, most of the coating layers were measured to have thicknesses in the range of 1-10 nm, demonstrating that the ultrathin coating layers composed of graphene oxide and sodium deoxycholate were stably formed. The stable structures of the coating layers attributed to hydrogen bonding and hydrophobic interaction between graphene oxide and sodium deoxycholate prevents the separation performance of the composite separation membranes from deteriorating even after long-term use.

(40) FIG. 8 is a graph showing the gas permeability tendencies of a porous PES membrane without a coating layer, a composite membrane including a graphene oxide coating layer formed on a PES film, and the composite separation membrane manufactured in Example 1, which includes a graphene oxide/sodium deoxycholate coating layer. As expected, the permeabilities of the composite separation membranes including coating layers tended to be lower for most gases than those of the porous PES membrane without a coating layer (FIG. 8). On the other hand, the permeability of carbon dioxide through the porous PES membrane without a coating layer was lower than the permeabilities of helium, hydrogen, oxygen, nitrogen, and methane gas. In contrast, the permeability of carbon dioxide through the composite separation membrane (GO/SDC membrane) was much higher than the permeabilities of the other gases. As shown in FIG. 9, the selectivities of the composite separation membrane manufactured in Example 1 for carbon dioxide over nitrogen and methane gas were as high as 70 to 80.

(41) Particularly, the graphs of FIGS. 10-13 reveal that the composite separation membrane manufactured in Example 1 showed very high carbon dioxide permeabilities and very high selectivities for carbon dioxide over nitrogen at different partial pressures of carbon dioxide from carbon dioxide/nitrogen mixed gases. The same experiments were conducted on a hydrogen/carbon dioxide mixed gas and a methane gas/carbon dioxide mixed gas. As a result, the composite separation membrane manufactured in Example 1 was confirmed to have high selectivities for carbon dioxide.

(42) The composite separation membrane of the present invention, which includes a coating layer composed of graphene oxide and a bile acid or its salt on a porous polymer support, is free of surface defects and maintains a stable structure without deterioration of its performance even after long-term use. Due to these advantages, the composite separation membrane of the present invention is expected to be applicable to carbon dioxide separation processes in practical industrial fields.