DYE COMPOSITION COMPRISING A PARA-PHENYLENEDIAMINE OXIDATION BASE, AN AMPHOTERIC SURFACTANT IN A MEDIUM RICH IN FATTY SUBSTANCES

Abstract

The present invention relates to a composition for dyeing keratin fibres, in particular human keratin fibres such as the hair, comprising: a) at least one oxidation base 3-(2,5-diaminophenyl)-1-propanol and/or acid salts thereof or solvates thereof such as hydrates; b) at least one coupler; c) at least 10% by weight of the total weight of the composition of a fatty substance which is preferably liquid and non-silicone-based; d) at least one amphoteric surfactant; e) optionally at least one basifying agent; and f) optionally at least one chemical oxidizing agent. The invention also relates to a process for dyeing keratin fibres such as the hair using the composition of the invention, and to a multi-compartment device for using the composition of the invention.

Claims

1. Composition comprising: a) at least one oxidation base 3-(2,5-diaminophenyl)-1-propanol and/or acid salts thereof and/or solvates thereof such as hydrates; b) at least one coupler; c) at least 10% by weight of the total weight of the composition of a fatty substance; d) at least one amphoteric surfactant; e) optionally at least one basifying agent; and f) optionally at least one chemical oxidizing agent.

2. Composition according to the preceding claim, characterized in that the fatty substance(s) are chosen from C.sub.6-C.sub.16 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, non-silicone oils of animal origin, plant oils of triglyceride type, synthetic triglycerides, fluoro oils, fatty alcohols, esters of fatty acids and/or of fatty alcohols other than triglycerides and plant waxes, non-silicone waxes and silicones.

3. Composition according to any one of the preceding claims, characterized in that the fatty substance(s) are liquid at room temperature and at atmospheric pressure, and are preferably non-silicone-based.

4. Composition according to any one of the preceding claims, characterized in that the fatty substances are chosen from C.sub.6-C.sub.16 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, triglycerides, fatty alcohols, esters of fatty acids and/or of fatty alcohols other than triglycerides, or mixtures thereof, and preferably from liquid petroleum jelly, polydecenes, liquid fatty alcohols, liquid esters of fatty acids and/or of fatty alcohols, or mixtures thereof.

5. Composition according to any one of the preceding claims, characterized in that the concentration of fatty substances ranges from 15% to 80% by weight, preferably from 25% to 75% by weight, in particular from 30% to 70% by weight and advantageously from 30% to 60% by weight relative to the total weight of the composition.

6. Composition according to any one of the preceding claims, in which the amphoteric surfactant(s) are chosen from (C.sub.8-C.sub.20)alkyl betaines, sulfobetaines, (C.sub.8-C.sub.20)alkylamido(C.sub.3-C.sub.8)alkyl betaines and (C.sub.8-C.sub.20)alkylamido(C.sub.6-C.sub.8)alkyl sulfobetaines, (C.sub.8-C.sub.20)alkyl amphoacetates and (C.sub.8-C.sub.20)alkyl amphodiacetates; particularly chosen from (C.sub.8-C.sub.20)alkyl betaines, (C.sub.8-C.sub.20)alkylamido(C.sub.3-C.sub.8)alkyl betaines and (C.sub.8-C.sub.20)alkyl amphodiacetates.

7. Composition according to any one of the preceding claims, in which the amphoteric surfactant is chosen from (C.sub.8-C.sub.20)alkyl betaines and (C.sub.8-C.sub.20)alkylamido(C.sub.3-C.sub.8)alkyl betaines.

8. Composition according to any one of the preceding claims, in which the amount of the amphoteric surfactant(s) preferably ranges from 0.1% to 50% by weight and better still from 0.5% to 20% by weight relative to the total weight of the composition.

9. Composition according to any one of the preceding claims, in which the oxidation base(s) chosen from 3-(2,5-diaminophenyl)-1-propanol, the acid salts thereof or the solvates thereof such as hydrates, are in an amount ranging from 0.0001% to 20% by weight relative to the total weight of the composition, preferably from 0.005% to 10% by weight and in particular from 0.01% to 10% by weight relative to the total weight of the composition.

10. Composition according to any one of the preceding claims, in which the coupler is chosen from meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene-based couplers and heterocyclic couplers, and the addition salts thereof.

11. Composition according to any one of the preceding claims, which comprises at least one basifying agent chosen from ammonia, alkali metal carbonates or bicarbonates, sodium hydroxide or potassium hydroxide, organic amines chosen from alkanolamines, oxyethylenated and/or oxypropylenated ethylenediamines, amino acids and the compounds of formula (II), or mixtures thereof: ##STR00003## in which formula (II) W is a divalent C.sub.1-C.sub.6 alkylene radical optionally substituted with one or more hydroxyl groups or a C.sub.1-C.sub.6 alkyl radical, and/or optionally interrupted with one or more heteroatoms such as O, or NR.sub.u; R.sub.x, R.sub.y, R.sub.z, R.sub.t and R.sub.u, which may be identical or different, represent a hydrogen atom or a C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 hydroxyalkyl or C.sub.1-C.sub.6 aminoalkyl radical.

12. Composition according to any one of the preceding claims, in which the basifying agent is chosen from ammonia or alkanolamines, preferably monoethanolamine, and neutral or ionic amino acids.

13. Composition according to any one of the preceding claims, which comprises a chemical oxidizing agent, preferably hydrogen peroxide.

14. Process for dyeing keratin fibres, in particular the hair, comprising the application to the keratin fibres of the composition as defined according to any one of the preceding claims.

15. Process according to the preceding claim, in which the composition as described according to any one of claims 1 to 13 is obtained by mixing at least two compositions, a first composition (A) which comprises the oxidation base 3-(2,5-diaminophenyl)-1-propanol and/or one of acid salts or solvates and a second composition (B) which comprises at least one chemical oxidizing agent, it being understood that: at least one of the compositions (A) or (B) comprises the fatty substance(s) and the amphoteric surfactant as defined previously such that the fatty substance content of the composition resulting from the mixing of compositions (A) and (B) is at least 10%, preferably greater than 25%, preferably greater than 30% by weight, relative to the weight of the composition derived from the mixing of (A) and (B).

16. Process according to claim 15, in which the composition applied to the fibres is obtained from composition (A), from composition (B) and from a third composition at least partly comprising the fatty substance(s), this third composition preferably being anhydrous.

17. Multi-compartment device comprising a first compartment containing composition (A) which comprises the oxidation base 3-(2,5-diaminophenyl)-1-propanol and/or one of acid salts or solvates and a second compartment containing composition (B) which comprises at least one chemical oxidizing agent, it being understood that at least one of the compositions (A) or (B) comprises the fatty substance(s) and the amphoteric surfactant as defined previously such that the fatty substance content of the composition resulting from the mixing of compositions (A) and (B) is at least 10%, preferably greater than 25%, preferably greater than 30% by weight, relative to the weight of the composition derived from the mixing of (A) and (B).

Description

EXAMPLES

Example 1

[0194] The following compositions are prepared in which the amounts are expressed in grams of active materials.

TABLE-US-00001 Ingredients A1 Resorcinol 0.5 Ethanolamine 5 Sodium laureth sulfate containing 2 OE 1.75 Hydroxypropyl guar 1 Ascorbic acid 0.5 6-Hydroxybenzomorpholine 0.04 1-β-Hydroxyethyloxy-2,4-diaminobenzene 0.03 dihydrochloride 1,3-Dihydroxybenzene (resorcinol) 0.85 1-Hydroxy-3-aminobenzene 0.14 3-(2,5-Diaminophenyl)propan-1-ol hydrochloride 2.2 EDTA 0.2 Cocoyl betaine 3 Sodium chloride 0.65 Sodium metabisulfite 0.5 Mineral oil (Mineral Oil INCI NAME) 60 PEG-40 hydrogenated castor oil 1 Water qs 100 100

TABLE-US-00002 Oxidizing composition Ingredients B1 Tocopherol 0.1 Sodium stannate 0.04 Pentasodium pentetate 0.06 Polyquaternium-6 0.2 Glycerol 0.5 Cetearyl alcohol 6 Hexadimethrine chloride 0.15 Hydrogen peroxide 6 Tetrasodium pyrophosphate 0.03 Mineral oil 20 PEG-4 rapeseedamide 1.19 Steareth-20 5 Phosphoric acid qs pH 2.2 Water qs 100

[0195] The mixtures thus obtained are applied to natural grey hair. The leave-on time is 35 minutes. After the leave-on time, the hair is rinsed with clean water and a conditioning shampoo is then applied.

[0196] After drying, hair with a beautiful natural light-chestnut shade is obtained.

Example 2

[0197]

TABLE-US-00003 Dye composition Ingredients C1 (AM) Liquid petroleum jelly (Mineral Oil INCI NAME) 60 Oxyethylenated (40 OE) hydrogenated castor oil 1 Cocoyl betaine in aqueous solution 10 1-Methyl-2-hydroxy-4-β-hydroxyethylaminobenzene 0.52 1-Methyl-2-hydroxy-4-aminobenzene 0.58 1,3-Dihydroxybenzene (resorcinol) 0.22 2,3-Diamino-6,7-dihydro-1H,5H-pyrazolo[1,2- 0.47 a]pyrazol-1-one dimethanesulfonate 1-Hydroxy-4-aminobenzene 0.44 3-(2,5-Diaminophenyl)propan-1-ol-hydrochloride 0.82 Pure monoethanolamine 5.16 Hydroxyethylcellulose (MW: 1 300 000) 2.5 Oxyethylenated (2 OE) stearyl alcohol 0.1 Oxyethylenated (20 OE) stearyl alcohol 0.1 Sodium lauryl ether sulfate (2.2 OE) in aqueous 2.5 solution Sequestrant 2 Reducing agent 0.5 Antioxidant 0.5 Deionized water qs 100

[0198] The dye formulation C1 is mixed with the oxidizing formulation D1 in a 1:1 ratio.

TABLE-US-00004 Oxidizing composition Ingredients D1 50% hydrogen peroxide solution (200-vol. aqueous 6 hydrogen peroxide solution) Etidronic acid, tetrasodium salt, as an aqueous 30% 0.2 solution Tetrasodium pyrophosphate decahydrate 0.04 Sodium salicylate 0.035 Dimethyldiallylammonium chloride/acrylic acid copolymer 0.74 (80/20) in protected aqueous solution Glycerol 4 Caprylyl/capryl glucoside ((50/50 C8/C10)alkyl 3 polyglucoside (2) as a buffered aqueous 60% solution) Deionized water qs 100

[0199] The mixtures thus obtained are applied to natural grey hair. The leave-on time is 35 minutes. After the leave-on time, the hair is rinsed with clean water and a conditioning shampoo is then applied.

[0200] After rinsing, a beautiful light-chestnut mahogany-red shade is obtained.

Example 3

[0201] The following compositions have been prepared in which the amounts are expressed in grams of active materials.

TABLE-US-00005 C C′ (inv) (comp) Ethanolamine 4 4 Sodium LAURYL ETHER SULFATE (2.2 EO) 2.5 2.5 in an aqueous solution (70%) HYDROXYETHYL CELLULOSE (PM: 2.5 2.5 1.300.000) ANTI-OXYDANT 0.5 0.5 1-METHYL-2-HYDROXY-4-BETA- 0.5 0.5 HYDROXYETHYLAMINOBENZENE 1-METHYL-2-HYDROXY-4-AMINO- 0.5 0.5 BENZENE 1,3-DIHYDROXYBENZENE (RESORCINOL) 0.2 0.2 2,3-DIAMINO-6,7-DIHYDRO-1H,5H- 4.04 .Math. 4.04 .Math. PYRAZOLO[1,2-A]PYRAZOL-1-ONE 10.sup.−3 mol 10.sup.−3 mol DIMETHANESULFONATE 3-(2,5-DIAMINOPHENYL)PROPAN-1-OL- 3.43 × — HYDROCHLORIDE 10.sup.−3 mol (2,5-diaminophenyl)ethanol — 3.43 × 10.sup.−3 mol SEQUESTRANT 2 2 Coco-betaine 3 ma 3 ma REDUCTEUR (Sodium meta bisulphite) 0.5 0.5 Mineral Oil 60 60 PEG-40 hydrogenated castor oil 1 1 water Qsp 100 Qsp 100

TABLE-US-00006 Oxyidizing composition Ox2 Hydrogen peroxide in an aqueous solution 50% 6 ETIDRONIC Acid, TETRA sodium salt in an aqueous 0.2 solution (30%) Tetra sodium PYROPHOSPHATE, 10 H.sub.2O 0.04 SODIUM Salycilate 0.035 DIMETHYL DIALLYL AMMONIUM CHLORIDE/ACRYLIC 0.74 ACID COPOLYMERE (80/20) IN AN AQUEOUS SOLUTION (Merquat 280) GLYCEROL 4 CAPRYLYL/CAPRYL GLUCOSIDE (ALKYL (C8/C10 50/50) 3 POLYGLUCOSIDE IN AN AQUEOUS SOLUTION (60%) WATER qsp 100

[0202] At the time of use, each composition C′ and C is mixed with the oxidizing composition Ox2 at a weight ratio of 1/1.

[0203] The resulting mixture are each applied on natural locks with 90% of white hair (BN) and on permed hair locks with 90% of white hair (BP in an amount of 10 g of the resulting mixture per 1 g of hair, and left for 35 minutes at room temperature (25° C.).

[0204] Then the hair was rinsed with water, washed with the “Pro Classics concentrated” shampoo (L′Oreal Professionnel), diluted at 10%, and dried.

[0205] Selectivity Evaluation

[0206] The color of the hair was determined using the CIE L*a*b* system with a Minolta CM2006D spectrophotometer (illuminant D65, angle 10°, specular component included) in the CIELab system.

[0207] According to this system, L* indicates the lightness of the color of the hair.

[0208] The chromaticity coordinates are expressed by the parameters a* and b*, a* indicating the axis of red/green shades and b* the axis of yellow/blue shades.

[0209] The selectivity of the dyeing is measured by calculating the variation of ΔE according to the formula :

ΔE=√{square root over ((L*−L.sub.0*).sup.2+(a*−a.sub.0*).sup.2+(b*−b.sub.0*).sup.2)}

[0210] In which L, a* and b* represent the values measured on permed hair and L0*, a0* and b0* represent the values measured on natural hair.

[0211] The selectivity is represented by the difference of color between the colored natural hair representative of the hair roots and permed hair representative of hair tips: the more is the ΔE value, the more the difference of color between natural and permed hair is important. A lesser selectivity is representative of an homogeneity of the coloration between the roots and the tips along the lock of hair.

[0212] The following results are obtained:

TABLE-US-00007 Hair type L* a* b* ΔE C + O2 BN 26.9 15.2 10.6 9.3 (inv) BP 20.9 10.6 5.0 C′ + O2 BN 29.6 18.4 13.7 12 (comp) BP 21.8 12.8 6.5

[0213] The resulting composition C+O2 according to the invention exhibits a ΔE value lesser than the one obtained with the C′+O2 comparative mixture. The hair coloration resulting from the use of C+O2 provides on hair an improved homogeny coloration along the hair fibers.