Memory system having thermally stable perpendicular magneto tunnel junction (MTJ) and a method of manufacturing same
11678586 · 2023-06-13
Assignee
Inventors
- Yiming Huai (Pleasanton, CA)
- Yuchen Zhou (San Jose, CA)
- Jing Zhang (Los Altos, CA, US)
- Roger Klas Malmhall (San Jose, CA, US)
- Ioan Tudosa (Milpitas, CA, US)
- Rajiv Yadav Ranjan (San Jose, CA)
Cpc classification
Y10T428/1107
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
G11C11/161
PHYSICS
Y10T428/1114
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
G11C11/16
PHYSICS
Abstract
A spin-transfer torque magnetic random access memory (STTMRAM) element employed to store a state based on the magnetic orientation of a free layer, the STTMRAM element is made of a first perpendicular free layer (PFL) including a first perpendicular enhancement layer (PEL). The first PFL is formed on top of a seed layer. The STTMRAM element further includes a barrier layer formed on top of the first PFL and a second perpendicular reference layer (PRL) that has a second PEL. The second PRL is formed on top of the barrier layer. The STTMRAM element further includes a capping layer that is formed on top of the second PRL.
Claims
1. A spin-transfer torque magnetic random access memory (STTMRAM) element comprising: a free layer including: a first and a second free sub-layers having a variable magnetization direction substantially perpendicular to layer planes thereof; and a first perpendicular enhancement layer (PEL) interposed between the first and second free sub-layers; a barrier layer formed adjacent to the free layer; and a reference layer formed adjacent to the barrier layer opposite the free layer, the reference layer including: a first and a second reference sub-layers having a first invariable magnetization direction; a second PEL interposed between the first and second reference sub-layers; an antiferromagnetic coupling layer formed adjacent to the second reference sub-layer opposite the second PEL; and a third reference sub-layer formed adjacent to the antiferromagnetic coupling layer opposite the second reference sub-layer and having a second invariable magnetization direction that is substantially perpendicular to a layer plane of the third reference sub-layer and opposite to the first invariable magnetization direction, wherein the first reference sub-layer comprises cobalt, iron, and boron.
2. The STTMRAM element, as recited in claim 1, wherein the free layer further includes a spin polarization enhanced layer (SPEL) in physical contact with the barrier layer and the first free sub-layer.
3. The STTMRAM element, as recited in claim 1, wherein the reference layer further includes a spin polarization enhanced layer (SPEL) in physical contact with the barrier layer and the first reference sub-layer comprising cobalt, iron, and boron.
4. The STTMRAM element, as recited in claim 1, wherein the first PEL is made of an elemental metal of molybdenum, tungsten, niobium, or yttrium.
5. The STTMRAM element, as recited in claim 1, wherein the first and second reference sub-layers are in physical contact with the second PEL.
6. A spin-transfer torque magnetic random access memory (STTMRAM) element comprising: a free layer including: a first and a second free sub-layers having a variable magnetization direction substantially perpendicular to layer planes thereof; and a first perpendicular enhancement layer (PEL) interposed between the first and second free sub-layers; a barrier layer formed adjacent to the free layer; and a reference layer formed adjacent to the barrier layer opposite the free layer, the reference layer including: a first and a second reference sub-layers having a first invariable magnetization direction; a second PEL interposed between the first and second reference sub-layers; an antiferromagnetic coupling layer formed adjacent to the second reference sub-layer opposite the second PEL; and a third reference sub-layer formed adjacent to the antiferromagnetic coupling layer opposite the second reference sub-layer and having a second invariable magnetization direction that is substantially perpendicular to a layer plane of the third reference sub-layer and opposite to the first invariable magnetization direction, wherein the first reference sub-layer comprises cobalt, iron, and boron, and wherein the first and second free sub-layers each comprise cobalt, iron, and boron.
7. A spin-transfer torque magnetic random access memory (STTMRAM) element comprising: a free layer including: a first and a second CoFeB free sub-layers having a variable magnetization direction substantially perpendicular to layer planes thereof; and a first perpendicular enhancement layer (PEL) made of an elemental metal of molybdenum or tungsten interposed between the first and second CoFeB free sub-layers; a barrier layer formed adjacent to the free layer; and a reference layer formed adjacent to the barrier layer opposite the free layer, the reference layer including: a first and a second reference sub-layers having a first invariable magnetization direction substantially perpendicular to layer planes thereof; a second PEL interposed between the first and second reference sub-layers; an antiferromagnetic coupling layer formed adjacent to the second reference sub-layer opposite the second PEL; and a third reference sub-layer formed adjacent to the antiferromagnetic coupling layer opposite the second reference sub-layer and having a second invariable magnetization direction that is substantially perpendicular to a layer plane of the third reference sub-layer and opposite to the first invariable magnetization direction, wherein the first reference sub-layer comprises cobalt, iron, and boron.
8. The STTMRAM element, as recited in claim 7, wherein the reference layer further includes a spin polarization enhanced layer (SPEL) in physical contact with the barrier layer and the first reference sub-layer comprising cobalt, iron, and boron.
9. The STTMRAM element, as recited in claim 7, wherein the free layer further includes a spin polarization enhanced layer (SPEL) in physical contact with the barrier layer and the first CoFeB free sub-layer.
10. The STTMRAM element, as recited in claim 7, wherein the second PEL is made of an elemental metal selected from tantalum (Ta), titanium (Ti), hafnium (Hf), niobium (Nb), vanadium (V), yttrium (Y), tungsten (W), chromium (Cr), and molybdenum (Mo).
11. The STTMRAM element, as recited in claim 7, wherein the first and second CoFeB free sub-layers are in physical contact with the first PEL.
12. The STTMRAM element, as recited in claim 7, wherein the first and second reference sub-layers are in physical contact with the second PEL.
13. The STTMRAM element, as recited in claim 7, wherein the second reference sub-layer comprises cobalt, iron, and boron.
Description
IN THE DRAWINGS
(1)
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DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
(8) In the following description of the embodiments, reference is made to the accompanying drawings that form a part hereof, and in which is shown by way of illustration of the specific embodiments in which the invention may be practiced. It is to be understood that other embodiments may be utilized because structural changes may be made without departing from the scope of the present invention. It should be noted that the figures discussed herein are not drawn to scale and thicknesses of lines are not indicative of actual sizes.
(9)
(10) Upon depositing the layer 104 on top of the layer 26, which includes deposition of a top surface layer 1041 which is part of layer 104, the temperature (also referred to herein as “first temperature”) being applied to the element 100 is increased followed by annealing at 110, preferably in-situ within the same deposition system without breaking the vacuum to avoid oxidization and contamination of the top surface layer of 104. Still at 110, in
(11) Each of the layers 102 and 104 can have an in-plane or a perpendicular magnetization relative to the film plane. In some embodiments, the layer 106 is made of magnetic material, in other embodiments, it is made of non-magnetic material and in still other embodiments, it is interlaced with magnetic and non-magnetic materials. In some embodiments, the layer 104 is composed of a multilayer structure with magnetic layer and non-magnetic layer where at least one of these magnetic layers interfaces with the layer 26. In some embodiments, the layer 104 is composed of a multilayer structure with magnetic layer and non-magnetic layer where at least one of these non-magnetic layers forms the top surface of layer 106, which can be any combination of, but not limited to, Ta, Pd, Ru, Mg, O, Hf, Tb, Pt, Ti, Cu, or Hf. In some embodiments, the layer 104 is made of a multilayer structure including at least one magnetic layer and at least one non-magnetic layer where at least one of these magnetic layers forms the top surface of the layer 106, and made of any combination, but not limited to, the following materials: Co, Fe, B, Ni, Ta, Pd, Ru, Mg, O, Tb, Pt, Ti, Cu, Zr, Mn, Ir, or Hf.
(12) The layer 102, in some embodiments, is made of underlying magnetic or non-magnetic layers that are not shown in
(13)
(14) The PRL 21 is analogous to the layer 104 combined with layer 106 of
(15) Exemplary materials of which the seed layer 15 is made are: tantalum (Ta), titanium (Ti), chromium (Cr), ruthenium (Ru), nickel chromium (NiCr), titanium chromium (TiCr), or MgO. In some of the embodiments where the layer 15 is made of ruthenium (Ru), layer 15 has a thickness of 1 nm to 10 nm. In some of the embodiments where the layer 15 is made of MgO, layer 15 has a thickness of 0.3 nm to 0.7 nm. Exemplary stack of the PFL 17 is composed of perpendicular ferromagnetic layers and PEL. Exemplary materials of which the PEL is made are tantalum (Ta), titanium (Ti), hafnium (Hf), niobium (Nb), vanadium (V), yttrium (Y), rhenium (Re), tungsten (W), chromium (Cr), molybdenum (Mo), and ruthenium (Ru). It is well known that the barrier layer 19 is typically made of magnesium oxide (MgO) or aluminum oxide (Al2O3). The PRL 21, in some embodiments, is a synthetic anti-ferromagnetic (SAF) pinned layer, composed of two antiferromagtically coupled perpendicular ferromagnetic layers separated by a non-magnetic exchange coupling layer. The capping layer 23 is made of Ta, Ru, Hf, Ti, or MgO in some embodiments of the present invention.
(16) The element 9 has a top structure defined by the PRL 21 being above the PFL 17. That is, the PRL 21 is essentially the “reference layer” (also referred to as the “pinned layer” or “fixed layer”) with a fixed magnetic orientation perpendicular to the film plane and the PFL 17 is essentially the “free layer” (also referred to as the “switching layer”) with a switchable perpendicular magnetic orientation that switches relative to the magnetic orientation of the PRL 21. A bottom structure configuration of the element 9 would have the PFL 17 formed above the PRL 21 (as shown in
(17) As noted by the direction of the arrows in the PFL 17 and the PRL 21, the anisotropy of each of the PFL 17 and PRL 21 is perpendicular to the plane of the substrate 13.
(18) Largely due to presence of the PFL 17 with PEL, the element 9 advantageously exhibits an improved perpendicular anisotropy.
(19)
(20) The substrate 11 is analogous to the substrate 13 and the layer 49 is analogous to the layer 23 of the element 9. In some embodiments, the layer 25 is made of Ta, Ti, Pt, Pd, TiCr, NiCr, Ru, or MgO. In some of the embodiments where the layer 25 is made of ruthenium (Ru), layer 25 has a thickness of 1 nm to 10 nm. In some of the embodiments the layer 25 is made of MgO and has a thickness of 0.3 nm to 0.7 nm. The free sub-layer 27 is made of the alloy cobalt-iron-boron (CoFeB) with the atomic percentage of the iron being greater than 20%. In some embodiments, the sub-layer 31 is made of the alloy cobalt-iron-boron (CoFeB) with the atomic percentage of Fe being greater than 40% and boron being within a range of 20 to 30 atomic percent. The layer 35 is analogous to the layer 19.
(21) In some embodiments, the layer 25 is 10-100 Angstroms in thickness.
(22) The free sub-layers 27 and 31 and the PFL layer 7 and the SPEL 33 collectively comprise the free layer PFL 51 and the SPEL 37, pinned sub-layer 39, PEL 41, SAF sub-layer 43, layer 45, and the SAF sub-layer 47 comprise the synthetic antiferromagnetic perpendicular reference layer (SAF PRL) 53, also commonly referred to as “synthetic reference layer” (SRL) 53, which remains fixed in its magnetic orientation after manufacturing of the element 29 whereas the free layer 51 switches its magnetic orientation relative to the magnetic orientation of the SRL 53 when the element 29 is used as a storage element.
(23) It is noted that the layer 35 is commonly referred to as the “tunnel layer” or “tunneling layer” and the layer 49 is commonly referred to as the “cap layer”. The layer 51, the layer 35 and the SAF PRL 53 collectively comprise the MTJ of the element 29.
(24) The function of each of the SPEL 33 and 37 is to enhance the tunneling magneto-resistance (TMR) of the MTJ through proper crystal structure orientation [bcc (001)] matching during the magnetic annealing process and higher spin polarization.
(25) The function of the layer 35 is to act as spin-filter layer for preserving the spin generated by neighboring layers for the spin tunneling of the MTJ which is important in achieving high TMR. More specifically, the layer 35 selectively filters the spin states of the polarized conduction electrons as they travel through the SRL 53 to the free layer 51 and vice versa. A detailed description of this can be found in the published paper, “Theory of Tunneling Magnetoresistance For Epitaxial Systems by W. H. Butler, X. G. Zhang, S. Vutukuri, M. Chchiev and T. C. Schulthess, IEEE Trans Mag., vol. 41, No. 10, October 2005”.
(26) The function of each of the free layer 51 is to switch between magnetic orientations (states) when current is applied to the element 29 thereby storing a state. The design and the material of choice used for making the free layer determines, at least in part, the device reliability, more specifically the thermal stability. The presence of the PEL 41 improves the perpendicular anisotropy of the SRL 53 of the element 29. The PEL 41 helps the perpendicular coupling between SAF sub layer 43 and pinned sub layer 39 by direct magnetic coupling, or/and magneto static coupling or/and interlayer exchange coupling. The enhanced coupling can be also attributed in some embodiments to improved crystalline structures of the PFL 51 and PRL 53 due to the presence of PEL layers 7 and 41.
(27) It is noted that the SAF sub-layer 43 and the SAF sub-layer 47 are anti-ferromagnetically coupled.
(28) The anisotropy of the free layer 51 and the SAF PRL 53 is generally and substantially perpendicular to the plane of the substrate 11. In operation, current is applied to the element 29, in a direction going either from the substrate 11 to the layer 49 or from the layer 49 to the substrate 11.
(29) In some embodiments, the SPEL 37 is made of the alloy CoFe with the atomic percentage of Fe being greater than 80% and the pinned sub-layer 39 is made of CoFeB with Fe having an atomic percentage of greater than 40 and B having an atomic percentage between 20 and 30, including 20 and 30. In some embodiments, the sub-layer 43 is made of a cobalt (Co) and/or chromium (Cr) based alloy, such as CoCrPt, CoCrTa, CoCrPd, CoTi, CoNiSm, CoCrTi, CoCrZr, CoCrAl, CoCrSi, CoSm, CoCrPt:SiOx, CoCrPd:SiOx where SiOx can be replaced with any one of the following material: TiOx, ZrOx and CrOx. The sub-layer 47 is made of the same material as that of the sub-layer 43. In some embodiments, the layer 45 is made of ruthenium (Ru), iridium (Ir), or copper (Cu).
(30) The sub-layer 43 with strong perpendicular anisotropy can be deposited on other layers in a vacuum system by physical sputtering technique on a room-temperature substrate.
(31) As shown by the arrows of
(32) In some embodiments of element 29, the free sub-layer 27 is formed on top of the seed layer 25 and underneath the PEL 7 and is made of a cobalt-chromium (CoCr)-based alloy, such as CoCrPt, CoCrTa, CoCrPd, CoTi, CoNiSm, CoCrTi, CoCrZr, CoCrAl, CoCrSi, CoSm, CoCrPt:SiOx, CoCrPd:SiOx where SiOx can be replaced with any one of the following material: TiOx, ZrOx and CrOx. The cobalt-chromium (CoCr)-based alloy of the free sub-layer 27 enhances the thermal reliability of the element 29.
(33) The layers sub-layer 27, PEL 7, sub-layer 31 and SPEL 33 collectively form the free layer 51 of the element 29 and the SPEL 37, pinned sub-layer 39, PEL 41, sub-layer 43, layer 45 and sub-layer 47 collectively form the SAF PRL 53 of the element 29. Accordingly, the free layer 51, layer 35 and SAF PRL 53 form the MTJ of the element 29.
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(35) The multi-layer 95 is a part of the layers of the free layer 129 of the element 119 in addition to the PEL 97, the free sub-layer 99 and the SPEL 101. The SAF PRL 131 of the element 119 is comprised of the SPEL 105, the sub-layer 107, the PEL 109, the SAF sub-layer 111, the exchange coupling layer 113 and the SAF sub-layer 115.
(36) In some embodiments, the multi-layer 95 is made of one or more bilayers, with each bilayer 126 comprised of a conducting ferromagnetic layer 122 and a non-magnetic conducting layer 124. In some embodiments, the layer 122 is formed on top of the layer 124, and in some embodiments, the layer 124 is formed on top of the layer 122. The multi-layer 95 finished by the conducting magnetic layer 122 adjacent to the PEL layer 97. The ‘n’ number of bilayers 126 comprises the layer 95 with ‘n’ being an integer value plus an additional 122 layer on the top. In some embodiments, ‘n’ is equal to a number within the range of two to twenty.
(37) In some embodiments, the layer 122 has a thickness within the range of 2 to 8 angstroms and the layer 124 has a thickness within the range of 2 to 20 angstroms.
(38) In some embodiments, the layer 122 is made of one of the following materials: Co, Fe, Ni or their alloys, or CoFeXY with X and Y being made of boron (B), vanadium (V), chromium (Cr), tantalum (Ta) or niobium (Nb).
(39) In some embodiments, the layer 124 is made of palladium (Pd) or platinum (Pt). Co/Pt and Co/Pd based perpendicular multilayers have advantages; it is easy to control their saturation magnetization Ms and perpendicular anisotropy Hk by adjusting bilayer number “n” and individual 122 and 124 layer thicknesses. Multilayers also have high corrosion resistance in the MTJ integration process. In addition, multilayers are comparatively easy to realize high perpendicular magnetic anisotropy on room temperature substrate in sputtering process, yet show high magnetic thermal stability.
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(41) The multi-layer 154, PEL 156, free sub-layer 158 and SPEL 160 collectively comprise the free layer 178 and the SPEL 164, the pinned sub-layer 166, the PEL 168, the SAF sub layer 170, the exchange coupling layer 172 and the multi-layer 174 collectively comprise the SAF PRL layer 180 with the layers 178, 162 and 180 forming the MTJ of the element 150.
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(43) The insertion layers 222 and 226, in some embodiments, are each made of cobalt and serve to enhance the RKKY coupling of the exchange coupling layer 224. The AFM layer 230 serves to enhance the pinning strength of the SAF PRL layer 236. The free sub-layer 204, the PEL 206, the free sub-layer 208 and the SPEL 210 collectively comprise the free layer of the element 200 and the SPEL 214, the pinned sub-layer 216, the PEL 218, the sub-layer 220, the layer 222, the exchange coupling layer 224, the layer 226, the sub-layer 228 and the AFM layer 230 comprise the SAF PRL 236.
(44) In some embodiments, the layer 230 is made of one of the following materials: PtMn, FeMn or IrMn and each of the layers 222 and 226 is made of Co or Co rich alloys, such as CoFe.
(45) It is understood that the embodiments of
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(47) Although the present invention has been described in terms of specific embodiment, it is anticipated that alterations and modifications thereof will no doubt become apparent to those more skilled in the art. It is therefore intended that the following claims be interpreted as covering all such alterations and modification as fall within the true spirit and scope of the invention.