One-piece, hollow micromechanical part with several functional levels formed of a synthetic carbon allotrope based material
11673801 · 2023-06-13
Assignee
Inventors
- Philippe Dubois (Marin, CH)
- Sebastiano Merzaghi (Lausanne, CH)
- Christian Charbon (Chezard-St-Martin, CH)
Cpc classification
B81C99/0085
PERFORMING OPERATIONS; TRANSPORTING
G04B19/042
PHYSICS
G04B15/14
PHYSICS
G04B37/22
PHYSICS
International classification
B81C99/00
PERFORMING OPERATIONS; TRANSPORTING
G04B15/14
PHYSICS
G04B37/22
PHYSICS
Abstract
A method for fabrication of a micromechanical part made of a one-piece synthetic carbon allotrope based material, the method including: forming a substrate with a negative cavity of the micromechanical part to be fabricated; coating the negative cavity of the substrate with a layer of the synthetic carbon allotrope based material in a smaller thickness than the depth of the negative cavity; and removing the substrate to release the one-piece micromechanical part formed in the negative cavity.
Claims
1. A wheel set, comprising: a plurality of functional levels, at least two of the functional levels being formed in a one-piece manner of a synthetic carbon allotrope based material, wherein the carbon allotrope based material is in a carbon allotrope layer of thickness in a range of from 0.2 to 20 μm, wherein the carbon allotrope layer has a height greater than its thickness, wherein the wheel set has a hollow space containing a volume forming several perfectly referenced functional levels able to directly comprise a pivot axis, wherein an external surface of the wheel set comprises a first toothing, wherein a first level of the plurality of the functional levels comprises a first discoid plate extending in a height direction, orthogonal to a plane formed by the first discoid plate, and comprising a first hole and a first part of the volume, wherein the first hole communicates with a second level of the plurality of functional levels, wherein, from the first level extends a first hub, coaxially to the first hole, connecting a plurality of arms to a felloe of the first discoid plate, wherein the first toothing projects orthogonally from an outer periphery of the felloe, wherein the first part of the volume of the first level is at least partially filled with a second material, wherein the second material projects from in the height direction of the external surface to form an additional functional element of the wheel sets wherein the second level of the plurality of the functional levels comprises a second discoid plate extending in the height direction and comprising a second hole and a second part of the volume, wherein from the second level extends a second hub, coaxially to the second hole, from a periphery of a second toothing connected to the second hub, and wherein the first discoid plate is connected to the second discoid plate via the plurality of arms.
2. The wheel set of claim 1, wherein the second material comprises a metal.
3. The wheel set of claim 1, wherein the second hole is configured to cooperate with an arbor.
4. The wheel set of claim 1, wherein the second part of the volume, from the second level, is at least partially filled with the second material.
5. The wheel set of claim 1, wherein the first hole cooperates with an arbor.
6. The wheel set of claim 5, wherein from the first level extends a first hub, coaxially to the first hole, from a periphery of the first toothing connected to the first hub.
7. The wheel set of claim 6, wherein the second hole communicates with the first level.
8. The wheel set of claim 7, wherein the second toothing projects orthogonally outward from the second discoid plate.
9. The wheel set of claim 1, further comprising: a third level of the plurality of functional levels, formed exclusively of the second material, wherein the third level comprises: (i) a third discoid plate extending in the height direction and comprising a third hole, the third hole communicating with the second level; and (ii) a peripheral third toothing.
10. A timepiece, comprising: the wheel set of claim 1.
11. The wheel set of claim 1, wherein the second material comprises a metal alloy.
12. The Wheel set of claim 1, wherein the first and the second level, together, have a height in a range of from 20 to 1000 μm.
13. The wheel set of claim 1, comprising three levels of toothing across its height.
14. The wheel set of claim 1, wherein the plurality of arms have an upper side and a lower side, opposite the upper side, the timepiece comprising: the first toothing, projecting orthogonally from the periphery of the felloe on the upper side of the plurality of arms; and the second toothing, projecting orthogonally from the periphery of the felloe on the lower side of the plurality of arms.
15. The wheel set of claim 1, wherein the first and second levels are formed in a one-piece manner of a synthetic carbon allotrope based material.
16. The wheel set of claim 1, wherein the plurality of arms comprise strengthening structures which are radial or ribbed.
17. The wheel set of claim 1, wherein the synthetic carbon allotrope based material is diamond.
18. The wheel set of claim 1, wherein the synthetic carbon allotrope based material is diamond-like carbon.
19. The wheel set of claim 1, wherein the synthetic carbon allotrope based material is graphene.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Other features and advantages will appear clearly from the following description, given by way of non-limiting illustration, with reference to the annexed drawings, in which:
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DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
(12) The invention relates to a method for fabrication of a one-piece micromechanical part with several functional levels formed of a synthetic carbon allotrope based material in crystalline form, such as diamond or one or more layers of graphene, or in amorphous form, such as diamond-like-carbon (DLC).
(13) Of course, advantageously according to the invention, other types of materials, which can be deposited in layers and which have tribological advantages, may be used as an alternative to a synthetic carbon allotrope based material. This alternative material may be, for example, a silicon based compound, i.e. for example silicon nitride, silicon oxide or silicon carbide.
(14) This micromechanical part was devised for applications within the field of horology. However, other domains may very well be envisaged, such as, in particular, aeronautics, jewelry or the automobile industry.
(15) In the field of horology, this micromechanical part may, for example, form part of the exterior of a watch, or part of the timepiece movement. The micromechanical part may thus form all or part of a crystal, a case, a push-piece, a crown, a bracelet or watchband, a dial, a display member, a balance spring, a balance wheel, a pallets, a bridge, a main plate, a wheel set or an escape wheel.
(16) A first embodiment of the method for fabrication of such a micromechanical part is presented in
(17) By way of example,
(18) Thus, in a first alternative of step a illustrated in
(19) The first alternative of step a therefore uses several masks in order to obtain several etching patterns with different depths. Thus, a first phase a1 of step a is intended to form, on substrate 1, a first mask including a first pattern. A second phase a2 is intended to form, on the surface of said substrate and of the first mask, a second mask including a second pattern that is smaller than the first pattern of said first mask in order to etch two distinct patterns in the substrate.
(20) The first alternative of step a continues with the third phase a3 of performing an anisotropic etch (such as, for example, deep reactive ion etching or “DRIE”) to etch the second pattern in a first thickness of the substrate, then a fourth phase a4 intended to remove the second mask. In a variant, the thickness and material of the second mask may be selected so that the second mask is etched at the same time as the substrate so as to combine the above phases a3 and a4 in one phase. It is understood that the pattern that will be etched on level N.sub.2 is, for the moment, only etched on level N.sub.1.
(21) The first alternative of step a continues with the fifth phase a5, consisting in performing a second anisotropic etch to continue the etch of the second pattern, already performed in level N.sub.1, in level N.sub.2 and to start the etch of the first pattern in level N.sub.1 of substrate 1, i.e. to expand the etch of the second pattern towards the first pattern in level N.sub.1. The first alternative of step a ends, in the case of an etch on two levels, with a last phase a6 intended to remove the first mask in order to form substrate 1 including a negative cavity 3 on at least two levels N.sub.1, N.sub.2.
(22) In a variant, the substrate could be an SOI, i.e. it could include two silicon layers connected by a layer of silicon dioxide. One of the silicon layers could then undergo step a and the bottom of negative cavity 3 on at least two levels N.sub.1, N.sub.2 could be formed by the silicon dioxide layer in a more precise manner. Indeed, since the etch in step a is very selective, it cannot etch the silicon dioxide layer. It is understood that the bottom of the cavity will be easier to control.
(23) In a second alternative of step a illustrated in
(24) The second alternative of step a thus uses several wafers directly etched with the pattern required for the associated level N.sub.1, N.sub.2, N.sub.x. Thus, in the second alternative of step a on two levels N.sub.1, N.sub.2, a first phase a7 is intended to form a first wafer 102 including at least a first pattern 105 that is etched through, and a second phase a8 of forming a second wafer 104 including at least a second pattern 107 that is not etched through. In a last phase a9, step a according to the second alternative ends with bonding the first 102 and second 104 wafers to form substrate 101 including a negative cavity 103 on at least two levels N.sub.1, N.sub.2, respectively formed of first pattern 105 and second pattern 107. Preferably, bonding phase a9 is achieved by fusion bonding and forms a layer 108.
(25) After one of the two step a alternatives, the first embodiment continues with step b, in which negative cavity 3, 103 of substrate 1, 101 is coated with a layer 15, 17 of synthetic carbon allotrope based material of smaller thickness e.sub.1 than the depth of each of said at least two levels N.sub.1, N.sub.2, N.sub.x, of said cavity 3, 103.
(26) Advantageously according to the invention, step b may also have two alternatives depending on the geometric complexity required for layer 15, 17 of the synthetic carbon allotrope based material.
(27) In a first alternative of second step b illustrated in the left part of
(28) As illustrated in
(29) Particles 13 are used as nucleation sites. In this regard, the particles may be impurities with respect to the material of the subsequent deposition, just as they may be of the same nature as the material of the subsequent deposition. Preferably, the diameter of the particles is comprised between several nanometres and several tens of nanometres.
(30) Phase b2 continues with a second stage of removing the solvent from the solution to form particles 13 on substrate 1. This second stage may be achieved for example by evaporating the solvent.
(31) Second phase b2 is followed by a third phase b3 illustrated in
(32) A fourth phase b4 of the first alternative of second step b is intended to deposit a material 15 by chemical vapour phase deposition so that it is deposited exclusively where particles 13 remain. At the end of step b, as illustrated in
(33) In a second alternative of second step b illustrated in the right part of
(34) Whichever alternative is used for second step b, the method according to the invention, as illustrated in
(35) Further, it is also seen that step d may be equivalent to phases b1, b5 and b3, b7 to confine layer 15, 17 within cavity 3. Indeed, the same result can be obtained simply by forming a sacrificial layer 11 over the entire substrate 1, with the exception of cavity 3.
(36) In a last step c of the first embodiment, the method consists in removing substrate 1 so as to release the micromechanical part with several functional levels F.sub.1, F.sub.2, F.sub.x, formed at least partially in cavity 3. Consequently, in the above example in which substrate 1 is made of silicon, step d may consist of a selective etch of the silicon. This may, for example, be obtained by a chemical etch using a bath comprising tetramethylammonium hydroxide (known by the abbreviations TMAH and TMAOH). In a variant, a potassium hydroxide chemical etch may also be envisaged (known by the abbreviation KOH).
(37) In the two examples illustrated in
(38) Finally, for a height e.sub.3 of the micromechanical part with two levels comprised between 20 μm and 1000 μm, a thickness e.sub.1 of layer 15, 17 of only 0.2 μm to 20 μm is deposited. The savings in material and production costs due to the shortened time of deposition step b are thus immediately clear.
(39) Therefore, regardless of the complexity of the micromechanical part, the method is not more difficult to implement. By way of example, there is no increased difficulty in forming a toothing on a wall of cavity 3, which will form a matching toothing on the micromechanical part.
(40) By way of non-limiting example, in which the first alternative of second step b is applied, it is possible to obtain a micromechanical part 21 as shown in
(41) Further, micromechanical part 21 includes a second functional level F.sub.2 formed of a second substantially discoid plate 33 whose centre includes a hole 32 for cooperation with an arbor. Further, coaxially to hole 32, second functional level F.sub.2 there extends a hub 34 from the periphery of which there projects orthogonally a toothing 37 joining hub 24 of first functional level F.sub.1.
(42) Advantageously according to the invention, the material is deposited selectively by depositing only the amount of material necessary for the final coating, with no requirement for any subsequent finishing operation. This results in a reduction in the scrap rate which was due to the operation of removing material (damage to substrate 1, slivers on deposition 15, 17, etc.). This also reduces production costs, due to the shortening of deposition step b, the use of less material 15, 17 and the absence of any mechanical lapping operation on the contact areas provided.
(43) A second embodiment is shown in
(44) However, as illustrated in
(45) According to a first alternative shown in the right portion of
(46) According to a second alternative shown in the left portion of
(47) Preferably, step e of filling the hollows is achieved by electroplating or hot working. Electroplating is easier to perform if the substrate is made of a conductive material such as strongly doped silicon. The second material is preferably a metal or metal alloy which may or may not be amorphous. However, alternatively, there is nothing to prevent the type of deposition and/or nature of the deposited material from being changed. Likewise, electroplating may be facilitated by making synthetic carbon allotrope based material 45, 47 electrically conductive, i.e., for example, by depositing boron doped diamond in step b to make it electrically conductive.
(48) Consequently, in this second embodiment, optional step d may be used not only to limit the thickness of layer 45, 47 in negative cavity 43, 47 on several levels N.sub.1, N.sub.2, N.sub.x, but also to make the deposition of the second material 46, 48 flat with respect to said limited portion.
(49) Thus, possibly after optional step d and after step c, which are similar to the first embodiment, illustrated in
(50) According to another advantage of the invention, it is henceforth possible to coat parts having several functional layers F.sub.1, F.sub.2, F.sub.x with thin layers, which was impossible to fabricate previously due to the particular conditions required for thin layer deposition, such as, for example, the pressure, temperature or compounds used. In a non-limiting manner and advantageously according to the invention, it is thus possible to form a mainly metallic part with several functional levels F.sub.1, F.sub.2, F.sub.x from the second material 46, 48, which is coated with a layer of a synthetic carbon allotrope based material from layer 45, 47, whereas currently, it remains difficult, to the Applicant's knowledge, to coat a metallic part with diamond.
(51) It is also clear that it is possible to obtain a micromechanical part with the same complexities as the first embodiment. By way of non-limiting example,
(52) Further, micromechanical part 51 includes a second functional level F.sub.2 formed of a second substantially discoid plate 63 whose centre includes a hole 62 for cooperation with an arbor. Further, coaxially to hole 62, second functional level F.sub.2, there extends a hub 64 from the periphery of which there projects orthogonally a toothing 67 joining the hub of first functional level F.sub.1. Finally, the rest of the second functional level F.sub.2 is filled with second material 54, with the exception of the empty space formed by through hole 62.
(53) In a variant, part 51 could advantageously include strengthening structures for portions 55. Typically, these structures could for example strengthen the bending of portions 55. Various forms of structures, such as radial or ribbed structures, could provide increased stiffness and be formed in the substrate by means of the first mask.
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(55) Thus, in the third embodiment after steps a, b and possibly step d, the method includes a prior phase e.sub.−1, similar to that of the second embodiment, of forming a sacrificial volume 79 intended to create a level above level N.sub.3 exclusively for the second material 76, 78 and, possibly, a rod 74 in order to form a hole 72, as in the second embodiment.
(56) As illustrated in
(57) It is also clear that it is possible to obtain a micromechanical part with the same complexities as in the first two embodiments. By way of non-limiting example,
(58) Micromechanical part 81 includes a second functional level F.sub.2 formed of a second substantially discoid plate 83 whose centre includes a hole communicating with first functional level F.sub.1. Moreover, coaxially to hole 2, second functional level F.sub.2 there extends a hub connecting several arms 85 to the felloe 86. A toothing 87 projects orthogonally from the periphery of the felloe. Finally, the rest of the second functional level F.sub.2 is filled with second material 84, with the exception of the empty space formed by through hole 92.
(59) Advantageously according to the third embodiment, micromechanical part 81 includes a third functional level F.sub.3 formed of a substantially discoid third plate 95 whose centre includes a hole communicating with the second functional level F.sub.2. The third functional level F.sub.3 is formed exclusively of second material 84, with the exception of the empty space formed by through hole 92, and includes a peripheral toothing 96.
(60) The three embodiments of
(61) It is understood, however, that the three embodiments of
(62) By way of non-limiting example, fourth and fifth embodiments are shown in
(63) The fourth and fifth embodiments according to the invention both use a modification of the second alternative of step a illustrated in
(64) According to a variant mentioned above, one of the wafers could also be replaced by an SOI, so that the bottom of the cavity is formed by the silicon dioxide layer.
(65) According to a first alternative of step a of the fourth embodiment illustrated to the left of
(66) After step a, the first alternative of the fourth embodiment continues with step b, in which negative cavity 203 of substrate 201 is coated with a layer 215 of synthetic carbon allotrope based material of smaller thickness e.sub.1 than the depth of each of said at least three levels N.sub.1, N.sub.2 of said cavity 203.
(67) The first alternative of the fourth embodiment of the method of the invention may also include an optional third step d or similar phases to phases b1, b5 and b3, b7 to confine layer 215 within cavity 203. Likewise, another optional step e may be performed before step c, which consists in filling cavity 203, coated with synthetic carbon allotrope based material 215, with a second material so as to obtain, after step c, a micromechanical part made of a synthetic carbon allotrope based material 215 which is strengthened by and/or decorated with a second material, as in the aforecited second and third embodiments.
(68) In a last step c of the first alternative of the fourth embodiment, the method consists in removing substrate 201, so as to release the micromechanical part with several functional levels F.sub.1, F.sub.2, at least partially formed in cavity 203, with the same variants and advantages as in the three first embodiments.
(69) In the first alternative illustrated to the left of
(70) In the example illustrated to the left of
(71) According to a second alternative of step a of the fourth embodiment illustrated to the right of
(72) After step a, the second alternative of the fourth embodiment continues with step b, in which negative cavity 303 of substrate 301 is coated with a layer 315 of synthetic carbon allotrope based material of smaller thickness e.sub.1 than the depth of each of said three levels N.sub.1, N.sub.2, N.sub.3 of said cavity 303.
(73) The second alternative of the fourth embodiment of the method of the invention may also include an optional third step d or similar phases to phases b1, b5 and b3, b7 to confine layer 315 within cavity 303. Likewise, another optional step e may be performed before step c, which consists in filling cavity 303, coated with synthetic carbon allotrope based material 315, with a second material so as to obtain, after step c, a micromechanical part made of a synthetic carbon allotrope based material 315 which is strengthened by and/or decorated with a second material, as in the aforecited second and third embodiments.
(74) In a last step c of the second alternative of the fourth embodiment, the method consists in removing substrate 301, to release the micromechanical part with several functional levels F.sub.1, F.sub.2, F.sub.3, at least partially formed in cavity 303, with the same variants and advantages as in the first three embodiments.
(75) In the second alternative illustrated to the right of
(76) In the example illustrated to the right of
(77) In step a of the fifth embodiment illustrated in
(78) After step a, the fifth embodiment continues with step b, in which negative cavity 403 of substrate 401 is coated with a layer 415 of synthetic carbon allotrope based material of smaller thickness e.sub.1 than the depth of each of said three levels N.sub.1, N.sub.2, N.sub.3, of said cavity 403.
(79) The fifth embodiment of the method of the invention may also include an optional third step d or similar phases to phases b1, b5 and b3, b7 to confine layer 415 within cavity 403. Likewise, another optional step e may be performed before step c, which consists in filling cavity 403, coated with synthetic carbon allotrope based material 415, with a second material so as to obtain, after step c, a micromechanical part made of a synthetic carbon allotrope based material 415 which is strengthened by and/or decorated with a second material, as in the aforecited second and third embodiments.
(80) In a last step c of the fifth embodiment, the method consists in removing substrate 401, so as to release the micromechanical part with several functional levels F.sub.1, F.sub.2, F.sub.3 at least partially formed in cavity 403, with the same variants and advantages as in the three first embodiments.
(81) In the example illustrated in
(82) In the example illustrated in
(83) Consequently, it is understood that the method makes it possible to form a micromechanical part comprising several functional levels F.sub.1, F.sub.2, F.sub.3, F.sub.x, with no height limitation. By way of non-limiting example illustrated in
(84) Of course, this invention is not limited to the illustrated example but is capable of various variants and modifications that will appear to those skilled in the art. In particular, several micromechanical parts 21, 51, 81, 221, 321, 421, 523, 525, which may or may not be of identical design, may be fabricated at the same time on the same substrate 1, 41, 71, 101, 201, 301, 401 and possibly even an SOI.
(85) Consequently, it is not only possible for several identical or non-identical cavities 3, 43, 73, 103, 203, 303, 403 to be formed on the substrate 1, 41, 71, 101, 201, 301, 401, but they may also be formed on several faces of the substrate 1, 41, 71, 101, 201, 301, 401, i.e. the steps of the various embodiments of the method can be applied to several faces of the substrate 1, 41, 71, 101, 201, 301, 401.