BONDED STRUCTURE, METHOD FOR MANUFACTURING THE SAME, AND BONDING STATE DETECTION METHOD
20170341340 · 2017-11-30
Inventors
- Nozomi SAITO (Tokyo, JP)
- Takayuki Shimizu (Tokyo, JP)
- Toshio ABE (Tokyo, JP)
- Shu MINAKUCHI (Tokyo, JP)
- Nobuo TAKEDA (Tokyo, JP)
- Yutaka TERADA (Tokyo, JP)
Cpc classification
G01N19/04
PHYSICS
B32B3/263
PERFORMING OPERATIONS; TRANSPORTING
B32B3/28
PERFORMING OPERATIONS; TRANSPORTING
B32B27/06
PERFORMING OPERATIONS; TRANSPORTING
G02B6/022
PHYSICS
B32B15/20
PERFORMING OPERATIONS; TRANSPORTING
G01M11/086
PHYSICS
G01L1/24
PHYSICS
B32B9/007
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/546
PERFORMING OPERATIONS; TRANSPORTING
C09J5/00
CHEMISTRY; METALLURGY
B32B2250/40
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B3/085
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
The purpose of the present invention is to provide a bonded structure, a method for manufacturing the same, and a bonding state detection method which are capable of determining whether or not members are bonded together appropriately. A bonded structure 10 includes a laminated sheet 12A, a laminated sheet 12B, an adhesive 14 that bonds the laminated sheet 12A and the laminated sheet 12B together, and a distributed optical fiber 16 sandwiched between the laminated sheet 12A and the laminated sheet 12B. The cross-sectional shape of the distributed optical fiber 16 is deformed in accordance with the bonding state.
Claims
1. A bonded structure comprising: a first member, a second member, an adhesive that bonds the first member and the second member together, and a distributed optical fiber sandwiched between the first member and the second member and used as a pressure sensor, wherein a cross-sectional shape of the distributed optical fiber deforms in accordance with a bonding state.
2. The bonded structure according to claim 1, wherein a bonding state between the first member and the second member is detected based on an axial deformation in the distributed optical fiber converted from a radial deformation in the distributed optical fiber.
3. The bonded structure according to claim 1, wherein the distributed optical fiber has a property of contracting or expanding when the first member and the second member reach a bonded state compared with a case where the first member and the second member are in an unbonded state.
4. The bonded structure according to claim 3, wherein when the first member and the second member are in an unbonded state, the distributed optical fiber is arranged in a wave-like shape relative to a direction of the first member and the second member.
5. The bonded structure according to claim 4, wherein the distributed optical fiber is sandwiched between the first member and the second member via a wave-like member having a wave-like surface.
6. The bonded structure according to claim 4, wherein a surface of the adhesive that contacts the distributed optical fiber has a wave-like shape.
7. The bonded structure according to claim 4, wherein at least one of the first member and the second member has a wave-like surface that contacts the distributed optical fiber.
8. The bonded structure according to claim 3, wherein a cladding that coats a core of the distributed optical fiber is formed with repeating large diameter sections and small diameter sections.
9. The bonded structure according to claim 4, wherein the distributed optical fiber is sandwiched between the first member and the second member in a state embedded in a flexible member, the flexible member has an optical fiber embedment portion in which the distributed optical fiber is embedded, and a plurality of feet protruding from the optical fiber embedment portion, and the plurality of feet are arranged with spaces therebetween.
10. A method for manufacturing a bonded structure, comprising: a step of applying an adhesive to at least one of a first member and a second member, and a step of sandwiching a distributed optical fiber used as a pressure sensor between the first member and the second member to which the adhesive has been applied, and applying pressure, thereby deforming a cross-sectional shape of the distributed optical fiber and bonding the first member and the second member together.
11. The method for manufacturing a bonded structure according to claim 10, wherein a radial deformation in the distributed optical fiber that occurs as a result of the pressure application is converted to an axial deformation, and a bonding state between the first member and the second member is detected based on the axial deformation.
12. The method for manufacturing a bonded structure according to claim 10, wherein the distributed optical fiber is formed from a material that has a property of contracting or expanding when the first member and the second member reach a bonded state compared with a case where the first member and the second member are in an unbonded state.
13. The method for manufacturing a bonded structure according to claim 12, wherein when the first member and the second member are in an unbonded state, the distributed optical fiber is arranged in a wave-like shape relative to a direction of the first member and the second member.
14. The method for manufacturing a bonded structure according to claim 12, wherein the distributed optical fiber is sandwiched between the first member and the second member via a wave-like member having a wave-like surface.
15. The method for manufacturing a bonded structure according to claim 12, wherein a surface of the adhesive that contacts the distributed optical fiber has a wave-like shape.
16. The method for manufacturing a bonded structure according to claim 12, wherein at least one of the first member and the second member is formed with a wave-like surface that contacts the distributed optical fiber.
17. The method for manufacturing a bonded structure according to claim 12, wherein the distributed optical fiber is sandwiched between the first member and the second member via a flexible member having an optical fiber embedment portion in which the distributed optical fiber is embedded and a plurality of feet protruding from the optical fiber embedment portion and arranged with spaces therebetween.
18. A bonding state detection method comprising: a first step of bonding a first member and a second member with an adhesive while sandwiching a distributed optical fiber used as a pressure sensor between the members, and a second step of detecting a bonding state between the first member and the second member based on an axial deformation in the distributed optical fiber converted from a radial deformation in the distributed optical fiber.
19. The bonding state detection method according to claim 18, wherein the distributed optical fiber is arranged on the first member, a release film, the adhesive and the second member are then stacked thereon and pressure is applied, and the appropriateness of the pressure is detected by the distributed optical fiber.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DESCRIPTION OF EMBODIMENTS
[0067] Embodiments of the bonded structure and the bonding state detection method of the present invention are described below with reference to the drawings.
First Embodiment
[0068] A first embodiment of the present invention is described below.
[0069]
[0070] The bonded structure 10 includes a laminated sheet 12A, a laminated sheet 12B, an adhesive 14 that bonds the laminated sheet 12A and the laminated sheet 12B, and a distributed optical fiber 16 that is sandwiched between the laminated sheet 12A and the laminated sheet 12B. The distributed optical fiber 16 is used as a pressure sensor for detecting the bonding state between the laminated sheet 12A and the laminated sheet 12B based on the axial deformation of the optical fiber. Details concerning the axial deformation are described below. The distributed optical fiber 16 is, for example, a single-mode fiber having a cladding diameter of 125 μm and having a circular cross-sectional shape.
[0071] The distributed optical fiber 16 has a property of contracting or expanding when the laminated sheet 12A and the laminated sheet 12B reach a bonded state compared with the case where the laminated sheet 12A and the laminated sheet 12B are in an unbonded state. The cross-sectional shape of the distributed optical fiber 16 (the transverse sectional shape perpendicular to the axial direction of the distributed optical fiber 16) when the laminated sheet 12A and the laminated sheet 12B reach a bonded state is an elliptical shape. The transverse sectional shape describes the cross-sectional shape when the distributed optical fiber 16 is cut across the length of the fiber.
[0072] The adhesive 14 is used, for example, in the form of an adhesive layer. There are no particular limitations on the type of adhesive 14 used, and for example an epoxy resin-based adhesive may be used.
[0073] Prior to bonding with the adhesive 14, at least one of the laminated sheets 12A and 12B has been cured.
[0074] The planar shapes of the laminated sheets 12A and 12B illustrated in
[0075] The distributed optical fiber 16 illustrated in
[0076] As illustrated in
[0077] The laminated sheets 12A and 12B are bonded together by applying pressure with the adhesive 14 sandwiched between the sheets. When pressure is applied to the laminated sheets 12A and 12B, pressure is also applied to the distributed optical fiber 16. In the following description, the application of pressure to the laminated sheets 12A and 12B is also referred to as “compression”.
[0078] Birefringence in an optical fiber 15 is described below with reference to
[0079] In a state where no pressure is applied to the optical fiber 15, the optical spectrum has a single peak, as illustrated in
[0080] Examples of the optical fiber 15 include multipoint optical fibers and the distributed optical fiber 16 used in the first embodiment.
[0081] In multipoint optical fibers, a diffraction grating provided in a non-continuous manner in the core functions as a sensor. In multipoint optical fibers, the optical spectrum is sensitive to radial deformation in the multipoint optical fiber. In other words, when pressure is applied, the optical spectrum output from the multipoint optical fiber changes in the manner described using
[0082] However, if a multipoint optical fiber is used as a pressure sensor, then pressure detection can only be conducted at locations where the grating is provided. In other words, the bonding state can only be detected at non-continuous locations along the axial direction of the multipoint optical fiber. As a result, locations where the grating is not provided are excluded from detection of the bonding state.
[0083] On the other hand, the distributed optical fiber 16 used in the first embodiment functions as a sensor along the entire length of the fiber in the axial direction. Changes in the optical spectrum in the distributed optical fiber 16 are relatively insensitive to radial deformation of the distributed optical fiber, but very sensitive to axial deformation.
[0084] Accordingly, in order to detect the bonding state between the laminated sheet 12A and the laminated sheet 12B using the distributed optical fiber 16 that is sensitive to axial deformation, the bonded structure 10 according to the first embodiment converts radial deformation in the distributed optical fiber 16 into axial deformation, as illustrated in
[0085] When the distributed optical fiber 16 deforms in the axial direction, namely contracts or expands, the peak position of the reflected light differs from the position prior to contraction or expansion. Accordingly, by measuring the displacement in the peak position of the reflected light before and after the contraction or expansion, the amount of deformation (amount of strain) in the axial direction of the distributed optical fiber 16 can be detected. As described above, the amount of deformation (amount of strain) in the axial direction indicates the bonding state between the laminated sheets 12A and 12B.
[0086] Accordingly, in the bonded structure 10 used in the first embodiment, axial deformation in the distributed optical fiber 16 can be used to detect the bonding state between the laminated sheet 12A and the laminated sheet 12B continuously along the axial direction of the distributed optical fiber 16.
[0087] In the first embodiment, in which the members to be bonded are the laminated sheets 12A and 12B of a carbon composite material, when the pressure device (in the first embodiment, an autoclave is one possible example) is used to bond the laminated sheets 12A and 12B, the bonding state is detected by the distributed optical fiber 16. Accordingly, in the first embodiment, when the laminated sheets 12A and 12B of a carbon composite material are bonded together as members, a determination can be made as to whether or not the members have been bonded together appropriately.
[0088] Next is a description of specific methods for converting radial deformation in the distributed optical fiber 16 into axial deformation.
[0089] The distributed optical fiber 16 according to the first embodiment is arranged so that when the laminated sheet 12A and the laminated sheet 12B reach a bonded state, the optical fiber contracts or expands compared with the case where the laminated sheet 12A and the laminated sheet 12B are in an unbonded state.
[0090] When the laminated sheet 12A and the laminated sheet 12B reach a bonded state, the contraction or expansion of the distributed optical fiber 16 accompanying the application of pressure in the radial direction of the distributed optical fiber 16 means that radial deformation in the distributed optical fiber 16 has been converted to axial deformation.
[0091]
[0092]
[0093] When the laminated sheet 12A and the laminated sheet 12B are in an unbonded state, the distributed optical fiber 16 is arranged in a wave-like shape relative to the direction of the laminated sheet 12A and the laminated sheet 12B. In other words, the distributed optical fiber 16 is arranged so that the direction of the curves (the inflection points) of the optical fiber is along the lamination direction of the laminated sheet 12A and the laminated sheet 12B.
[0094]
[0095] As illustrated in
[0096]
[0097] This wave-like shape could also be described as a shape having continuous undulations. The wave-like shape may have arc shaped undulations as illustrated in the example of
[0098] The sensitivity improvement element 30 may, for example, be a cured adhesive of an adhesive such as a chemical-curing, thermosetting or thermoplastic adhesive.
[0099] A chemical-curing adhesive is an adhesive in which, for example, the curing reaction is initiated by mixing two liquids composed of a main agent and a curing agent respectively. An example of a chemical-curing adhesive is EA9394 manufactured by Henkel Corporation.
[0100] A thermosetting adhesive is an adhesive that undergoes a curing reaction by application of external heat to the adhesive. An example of a thermosetting adhesive is FM300-2 manufactured by Cytec Solvay Group.
[0101] A thermoplastic adhesive is an adhesive in which a polymerization reaction is initiated by applying heat to the adhesive, and the curing reaction then proceeds upon heat dissipation. An example of a thermoplastic adhesive is PPS resin (Poly Phenylene Sulfide resin).
[0102] A shim of an uncured prepreg or the like used for regulating the space between the bonded portions may be used as the sensitivity improvement element 30.
[0103] In the first embodiment, an element prepared by curing the aforementioned FM300-2 manufactured by Cytec Solvay Group was used as one example of the sensitivity improvement element 30. In one example of the first embodiment, FM300-2 manufactured by Cytec Solvay Group was also used as the adhesive 14.
[0104] In this manner, by forming the sensitivity improvement element 30 by curing the same adhesive as that used for the adhesive 14, the sensitivity improvement element 30 and the adhesive 14 can be integrated (assimilated) during the bonding process for the bonded structure 10, meaning the sensitivity improvement element 30 does not become an impurity within the bonded structure 10. As a result, the strength does not deteriorate near the locations where the sensitivity improvement element 30 has been inserted.
[0105] Which of a chemical-curing adhesive, a thermosetting adhesive and a thermoplastic adhesive is selected for the sensitivity improvement element 30 can be determined as appropriate based on factors such as the shape of the sensitivity improvement element 30 and the type of adhesive 14 used.
[0106]
[0107] The “Length (m)” shown along the horizontal axis of
[0108] In the test, the portion where pressure was applied to the bonded structure 10 (hereafter referred to as the “compressed portion”) is from about 6.5 m to 6.6 m. The pressure applied to the bonded structure 10 in the test was 0.1 MPa (dashed line a and solid line A) or 0.4 MPa (dashed line b and solid line B).
[0109] In
[0110] The dashed lines a and b indicating the test results for the bonded structure 10 not using the sensitivity improvement element 30 displayed slight fluctuations in the axial strain in the compressed portion, but the changes did not exhibit good sensitivity to the pressure.
[0111] On the other hand, the solid lines A and B representing the test results for the bonded structure 10 using the sensitivity improvement element 30 show large changes in the negative value of the axial strain in the compressed portion. The changes in the solid line B (0.4 MPa) that indicates the test conducted at higher pressure were larger than the changes in the solid line A (0.1 MPa).
[0112] In the solid lines A and B, based on the fact that a negative change in the axial strain occurs continuously in the compressed portion, it is evident that the bonded structure 10 using the sensitivity improvement element 30 is continuously detecting the bonding state.
[0113] By preparing in advance information (for example, tabulated information) indicating the relationship between the size of the axial strain and the pressure, and then referencing the tabulated information against actually measured axial strain values, the pressure applied to the bonded structure 10 can be determined from the measured axial strain.
[0114] As described above, the bonded structure 10 according to the first embodiment includes the laminated sheet 12A, the laminated sheet 12B, the adhesive 14 that bonds the laminated sheet 12A and the laminated sheet 12B together, and the distributed optical fiber 16 sandwiched between the laminated sheet 12A and the laminated sheet 12B. The bonding state between the laminated sheet 12A and the laminated sheet 12B is detected on the basis of the axial deformation in the distributed optical fiber 16 converted from the radial deformation.
[0115] In this manner, in the bonded structure 10 according to the first embodiment, the bonding state can be detected continuously along the axial direction of the distributed optical fiber 16 by converting the radial deformation in the distributed optical fiber 16 to axial deformation, and therefore a determination can be made as to whether or not the members have been appropriately bonded together.
[0116] More specifically, in the case where pressure is applied during the bonding step for the bonded structure 10, the quality following bonding has conventionally been confirmed by detecting the pressure applied to the entire bonded structure 10, but because the distributed optical fiber 16 enables the pressure to be detected at the actual bonding location, the adequacy of the bonding step can be evaluated more precisely.
Second Embodiment
[0117] A second embodiment of the present invention is described below.
[0118]
[0119] As illustrated in
[0120] As illustrated in
Third Embodiment
[0121] A third embodiment of the present invention is described below.
[0122]
[0123] As illustrated in
[0124] As illustrated in
[0125] In the example of
Fourth Embodiment
[0126] A fourth embodiment of the present invention is described below.
[0127]
[0128] Structural items in
[0129] As illustrated in
[0130] As illustrated in
[0131] As a result, the bonded structure 10 according to the fourth embodiment can easily convert radial deformation in the distributed optical fiber 16 to axial deformation.
[0132] As illustrated in
Fifth Embodiment
[0133] A fifth embodiment of the present invention is described below.
[0134]
[0135] Structural items in
[0136] In a similar manner to the bonded structure 10, the bonded structure 21 includes the laminated sheet 12A, the laminated sheet 12B, the adhesive 14 that bonds the laminated sheet 12A and the laminated sheet 12B, and the distributed optical fiber 16 that is sandwiched between the laminated sheet 12A and the laminated sheet 12B. The bonded structure 21 also includes the flexible member 40. The distributed optical fiber 16 is sandwiched between the laminated sheet 12A and the laminated sheet 12B via the flexible member 40.
[0137] The flexible member 40 is, for example, a cured adhesive. The adhesive may be a chemical-curing, thermosetting or thermoplastic adhesive. Which of a chemical-curing adhesive, a thermosetting adhesive and a thermoplastic adhesive is selected for the flexible member 40 can be determined as appropriate based on factors such as the shape of the flexible member 40 and the type of adhesive 14 used. By forming the flexible member 40 by curing the same adhesive as that used for the adhesive 14, the flexible member 40 and the adhesive 14 can be integrated (assimilated) during the bonding process for the bonded structure 21, meaning the flexible member 40 does not become an impurity within the bonded structure 21. As a result, the strength does not deteriorate near the locations where the flexible member 40 has been inserted.
[0138] The flexible member 40 has an optical fiber embedment portion 41 and a plurality of feet 42. In
[0139] A thickness t.sub.1 of the optical fiber embedment portion 41 with the distributed optical fiber 16 embedded therein is typically at least 10 μm but not more than 1,000 μm, and is preferably at least 50 μm but not more than 200 μm. If the thickness t.sub.1 is too thin, then the optical fiber tends to become exposed through the element. If the thickness t.sub.1 is too great, then there is a strong possibility that the entire element including the optical fiber may protrude from the adhesive layer. The thickness t.sub.1 of the optical fiber embedment portion 41 may be set within the above range in accordance with the thickness of the adhesive (the adhesive layer) and the bonding pressure and the like.
[0140] The plurality of feet 42 are provided so as to protrude from the surface of the optical fiber embedment portion 41B. Although not indicated in
[0141] As illustrated in
[0142] As a result, the bonded structure 21 according to the fifth embodiment can easily convert radial deformation in the distributed optical fiber 16 to axial deformation. This enables detection of the bonding state in the bonded structure 21. In the fifth embodiment, by setting the thickness t.sub.1 of the optical fiber embedment portion 41, the thickness t.sub.2 of the flexible member 40, the width w of the feet 42, and the spacing s between adjacent feet 42 so as to satisfy the size correlations described above, the flexible member 40 can be warped in a stable manner, enabling favorable detection of the bonding state in the bonded structure 21.
[0143]
[0144] The “Length (m)” shown along the horizontal axis of
[0145] In the test, the portion where pressure was applied to the bonded structure 21 (hereafter referred to as the “compressed portion”) is from about 5.43 m to 5.56 m. The pressure applied to the bonded structure 21 in the test was within a range from 0.18 atm (about 0.018 MPa) to 0.97 atm (about 0.1 MPa).
[0146] In
[0147]
[0148] The “Length (m)” shown along the horizontal axis of
[0149] In the test, the portion where pressure was applied to the bonded structure 21 (hereafter referred to as the “compressed portion”) is from about 7.052 m to 7.156 m. The pressure applied to the bonded structure 10 in the test was within a range from 0.18 atm (about 0.018 MPa) to 0.98 atm (about 0.1 MPa).
[0150] In
[0151] As illustrated in
[0152] Although the present invention has been described above using the aforementioned embodiments, the technical scope of the present invention is in no way limited by the embodiments described above. Various modifications and improvements can be made to the above embodiments without departing from the features of the present invention, and all such modifications and improvements are also included within the technical scope of the invention. The above embodiments may also be combined as appropriate.
[0153] For example, each of the above embodiments was described using the case where the laminated sheets 12A and 12B of a carbon fiber composite material were used as the members to be bonded, but the present invention is not limited to such members, and the members to be bonded may be fiber-reinforced resin-based composite materials reinforced with glass fiber or the like, or metal materials such as aluminum alloys.
[0154] The bonded structure 10 according to the embodiments described above may also be used for repairing damaged composite material structures.
[0155]
[0156] As illustrated in
[0157] Accordingly, during the autoclaving, the temperatures of the repair ply 12D and the laminated sheet 12C are measured by the thermocouple, and the pressure is measured by the distributed optical fiber 16. This enables confirmation to be made that the temperature and pressure for the repair are appropriate, namely that the autoclaving conditions are appropriate.
[0158] Once the autoclaving conditions have been confirmed as being appropriate, the release film 32 is peeled off, and the distributed optical fiber 16 is removed. The adhesive 14 and the repair ply 12D are then once again stacked in the region requiring repair, and following covering with the bagging film 34, autoclaving is performed under the confirmed appropriate conditions.
[0159] In this manner, by arranging the distributed optical fiber 16 on the laminated sheet 12C that requires repair, stacking the release film 32, the adhesive 14 and the repair ply 12D on top, and then applying pressure and using the distributed optical fiber 16 to detect the appropriateness of the pressure, the adequacy of the repair process can be evaluated, and a quality guarantee can be given for the repaired region.
[0160] An optical fiber according to the fourth embodiment described above may also be used as the distributed optical fiber 16. Further, an adhesive according to the second embodiment may be used as the adhesive 14. A structure according to the third embodiment may be used as the repair ply 12D. The sensitivity improvement element 30 according to the first embodiment may also be used.
[0161]
[0162] As illustrated in
[0163] As a result, the pressure applied to the repair ply 12D and the laminated sheet 12C is measured by the distributed optical fiber 16. This enables confirmation to be made that the pressure for the repair is appropriate.
[0164] Once the pressure conditions for repair have been confirmed as being appropriate, the release films 32 are peeled off, and the flexible member 40 is removed. The adhesive 14 and the repair ply 12D are then once again stacked in the region requiring repair, and following covering with the bagging film 34, the repair is performed under the confirmed appropriate conditions.
[0165] In this manner, by arranging the distributed optical fiber 16 on the laminated sheet 12C that requires repair, stacking the release film 32, the adhesive 14 and the repair ply 12D on top, and then applying pressure and using the distributed optical fiber 16 to detect the appropriateness of the pressure, the adequacy of the repair process can be evaluated, and a quality guarantee can be given for the repaired region.
REFERENCE SIGNS LIST
[0166] 10, 21: Bonded structure [0167] 12A: Laminated sheet [0168] 12B: Laminated sheet [0169] 12C: Laminated sheet [0170] 12D: Repair ply [0171] 14: Adhesive [0172] 16: Distributed optical fiber [0173] 16C: Core [0174] 16D: Cladding [0175] 20: Connector [0176] 30: Sensitivity improvement element [0177] 32: Release film [0178] 34: Bagging film [0179] 40: Flexible member [0180] 41A, B: Optical fiber embedment portion [0181] 42: Foot