Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant

Abstract

The subject of the present invention is a composition for dyeing human keratin fibres such as the hair, comprising: (a) at least one colouring agent chosen from oxidation dye precursors, direct dyes and mixtures thereof; (b) at least one amphoteric or zwitterionic surfactant; (c) at least one non-ionic surfactant; (d)at least one anionic surfactant (e) one or more fatty substances at a total content of at least 10% by weight relative to the weight of the composition; (f) at least one cationic polymer; (g) at least one oxidizing agent other than atmospheric oxygen. The present invention also relates to a process for dyeing human keratin fibres, in which this composition is applied to said fibres, and also to a suitable multicompartment device.

Claims

1. A composition for dyeing keratin fibers, comprising: at least one coloring agent chosen from oxidation dye precursors, direct dyes, or mixtures thereof; at least one amphoteric or zwitterionic surfactant; at least one non-ionic surfactant; at least one anionic surfactant; at least one fatty substance chosen from liquid paraffins, petroleum jelly, liquid petroleum jelly, polydecenes, or hydrogenated polyisobutene, present in an amount of at least 10% by weight, relative to the weight of the composition; at least one cationic polymer; and at least one oxidizing agent other than atmospheric oxygen wherein the amphoteric surfactant and anionic surfactant are present in a weight ratio ranging from 0.1 to 10.

2. The composition according to claim 1, wherein at least one coloring agent is an oxidation dye precursor, chosen from oxidation bases or addition salts thereof.

3. The composition according to claim 2, wherein the oxidation dye precursors are chosen from couplers and acid addition salts thereof.

4. The composition according to claim 1, wherein the at least one coloring agent is a direct dye chosen from cationic direct dyes; azo direct dyes; (poly)methin dyes; carbonyl dyes; azine dyes; nitro (hetero)aryl dyes; tri(hetero)arylmethane dyes; porphyrins; phthalocyanines, natural direct dyes, or mixtures thereof.

5. The composition according to claim 1, wherein at least one coloring agent is chosen from direct dyes chosen from hydrazono cationic dyes of formulae (II) or (Ill), or azo cationic dyes of formulae (IV) or (V) below:
Het.sup.+-C(R.sub.a)═N—N(R.sub.b)—Ar, Q.sup.−  (II)
Het.sup.+-N(R.sub.a)—N═C(R.sub.b)—Ar, Q.sup.−  (III)
Het.sup.+-N═N—Ar, Q.sup.−  (IV)
Ar.sup.+—N═N—Ar″, Q.sup.−  (V) wherein: Her.sup.+ is a cationic heteroaryl radical, optionally substituted; Ar.sup.+ is an aryl radical carrying an exocyclic cationic charge; Ar is chosen from an aryl group, optionally substituted, or a julolidine group; Ar″ is a (hetero)aryl group, optionally substituted; R.sub.a and R.sub.b, which may be identical or different, are chosen from a hydrogen atom or a (C.sub.1-C.sub.8)alkyl group which is optionally substituted; or R.sub.a with a substituent of Her.sup.+ and/or R.sub.b, with a substituent of Ar, form, together with the atoms which bear them, a (hetero)cycloalkyl; and Q.sup.− is an organic or inorganic anionic counterion; wherein the cationic direct dyes of formula (II) to (V) optionally carry endocyclic cationic charges.

6. A composition according to claim 1, wherein the at least one amphoteric or zwitterionic surfactant is chosen from derivatives of optionally quaternized aliphatic secondary or tertiary amines, in which derivatives the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group.

7. The composition according to claim 1, wherein the at least one amphoteric or zwitterionic surfactant is chosen from the following compounds: (C.sub.8-C.sub.20)alkylbetaines, (C.sub.8-C.sub.20)alkylsulfobetaines, (C.sub.8-C.sub.20)alkylamido(C.sub.3-C.sub.8)alkylbetaines, (C.sub.8-C.sub.20)alkylamido(C.sub.6-C.sub.8)alkylsulfobetaines, the compounds of following structure (B1):
R.sub.a—C(O)—NH—CH.sub.2—CH.sub.2—N.sup.+(R.sub.b)(R.sub.c)—CH.sub.2C(O)O.sup.−, M.sup.+, X.sup.−  (B1) wherein R.sub.a represents a C.sub.10-C.sub.30 alkyl or alkenyl group derived from an acid R.sub.a—COOH, or a heptyl, nonyl or undecyl group; R.sub.b represents a β-hydroxyethyl group; and R.sub.c represents a carboxymethyl group; M.sup.+ represents a cationic counterion derived from an alkali metal or alkaline-earth metal, an ammonium ion or an ion derived from an organic amine, and X.sup.− represents an organic or inorganic anionic counterion, or alternatively M.sup.+ and X.sup.− are absent, the compounds of following structure (B2):
R.sub.a′—C(O)—NH—CH.sub.2—CH.sub.2—N(B)(B′)  (B2) wherein B is the group —CH.sub.2—CH.sub.2—O—X′; B′ is the group —(CH.sub.2).sub.zY′, with z equal to the integer 1 or 2; X′ is chosen from the groups —CH.sub.2—C(O)OH, —CH.sub.2—C(O)OZ′, —CH.sub.2—CH.sub.2—C(O)OH, —CH.sub.2—CH.sub.2—C(O)OZ′, or a hydrogen atom; Y′ is chosen from the groups —C(O)OH, —C(O)OZ′, —CH.sub.2—CH(OH)—SO.sub.3H or —CH.sub.2—CH(OH)—SO.sub.3—Z′; Z′ is chosen from cationic counterions derived from an alkali metal or alkaline-earth metal, an ammonium ion or an ion derived from an organic amine; R.sub.a′ is chosen from C.sub.10-C.sub.30 alkyl or alkenyl groups of an acid R.sub.a′—C(O)OH, alkyl groups, or unsaturated C.sub.17 groups, and the compounds of formula (B′2):
R.sub.a″—NH—CH(Y″)—(CH.sub.2)n-C(O)—NH—(CH.sub.2)n′-N(R.sub.d)(R.sub.e)  (B′2) wherein: Y″ is chosen from the groups —C(O)OH, —C(O)OZ″, —CH.sub.2—CH(OH)—SO.sub.3H or —CH.sub.2—CH(OH)—SO.sub.3—Z″; R.sub.d and R.sub.e, independently of each other, are C.sub.1-C.sub.4 alkyl or hydroxyalkyl radicals; Z″ is chosen from cationic counterions derived from an alkali metal or alkaline-earth metal, an ammonium ion or an ion derived from an organic amine; R.sub.a″ is chosen from C.sub.10-C.sub.30 alkyl or alkenyl groups of an acid R.sub.a″—C(O)OH; and n and n′, independently of each other, are integers ranging from 1 to 3.

8. The composition according to claim 1, wherein the at least one amphoteric or zwitterionic surfactant is present in an amount ranging from about 0.1% to about 30% by weight, relative to the total weight of the composition.

9. The composition according to claim 1, wherein the at least one non-ionic surfactant is chosen from oxyalkylenated or glycerolated non-ionic surfactants, or mixtures thereof: oxyalkylenated (C.sub.8-C.sub.24)alkylphenols; saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated C.sub.8-C.sub.30 alcohols; saturated or unsaturated, linear or branched, oxyalkylenated C.sub.8-C.sub.30 fatty acid amides; esters of saturated or unsaturated, linear or branched, C.sub.8-C.sub.30 acids and of polyethylene glycols; esters of saturated or unsaturated, linear or branched, C.sub.8-C.sub.30 acids and of sorbitol; fatty acid esters of sucrose; (C.sub.8-C.sub.30)alkylpolyglycosides, (C.sub.8-C.sub.30)alkenylpolyglycosides, optionally oxyalkylenated (0 to 10 oxyalkylene units) and comprising 1 to 15 glucose units, (C.sub.8-C.sub.30)alkylglucoside esters; oxyethylenated and saturated or unsaturated vegetable oils; condensates of ethylene oxide and/or of propylene oxide, inter alis, alone or as mixtures; N—(C.sub.8-C.sub.30 )alkylglucamine derivatives and N—(C.sub.8- C.sub.30)acyl-methylglucamine derivatives; aldobionamides; amine oxides; oxyethylenated and/or oxypropylenated silicones; or mixtures thereof.

10. The composition according to claim 1, wherein the at least one non-ionic surfactant is present in an amount ranging from about 0.1% to about 30% by weight, relative to the total weight of the composition.

11. The composition according to claim 1, wherein the at least one anionic surfactant is chosen from alkyl sulfates, alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkyl sulfonates, alkylamide sulfonates, alkylaryl sulfonates, alpha-olefin sulfonates, paraffin sulfonates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamide sulfosuccinates, alkyl sulfoacetates, acyl sarcosinates, acyl glutamates, alkyl sulfosuccinamates, acyl isethionates and N-acyl taurates; salts of alkyl monoesters of polyglycoside-polycarboxylic acids, acyl lactylates, salts of D-galactoside uronic acids, salts of alkyl ether carboxylic acids, salts of alkylaryl ether carboxylic acids, salts of alkylamido ether carboxylic acids, and the corresponding non-salified forms thereof, and the alkyl and acyl groups thereof comprising from 6 to 40 carbon atoms, wherein the aryl group is a phenyl group.

12. The composition according to claim 1, wherein the at least one anionic surfactant is present in an amount ranging from about 0.1% to about 30% by weight, relative to the total weight of the composition.

13. The composition according to claim 1, wherein the at least one fatty substance is present in an amount ranging from about 15% to about 70% by weight, relative to the total weight of the composition.

14. The composition according to claim 1, wherein the at least one cationic polymer has a charge density of at least 1 meq/g.

15. The composition according to claim 1, wherein the at least one cationic polymer is chosen from the following polymers, alone or as mixtures: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides, and comprising at least one of the units of formula (I), (II), (Ill) or (IV) below: ##STR00015## wherein: R.sub.3, which may be identical or different, denote a hydrogen atom or a CH.sub.3 radical; A, which may be identical or different, represent a linear or branched C.sub.1-C.sub.6 alkyl group or a hydroxyalkyl group, the alkyl of which is C.sub.1-C.sub.4; R.sub.4, R.sub.5 and R.sub.6, which may be identical or different, are chosen from C.sub.1-C.sub.18 alkyl group or a benzyl radical; R.sub.1 and R.sub.2, which may be identical or different, are chosen from hydrogen or C.sub.1-C.sub.6 alkyl group; (2) cationic cellulose derivatives; (3) cationic guar gums; (4) polymers consisting of piperazinyl units and of linear or branched divalent alkyl or hydroxyalkyl radicals, optionally interrupted with oxygen, sulfur, or nitrogen atoms, or with aromatic or heterocyclic rings; or oxidation and/or quaternization products of these polymers; (5) water-soluble polyaminoamides, optionally crosslinked; (6) polymers obtained by reaction of a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid; (7) cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium, in the form of homopolymers or copolymers containing, as main constituent of the chain, units corresponding to formula (V) or (VI): ##STR00016## wherein: k and t are integers equal to 0 or 1, the sum k+t being equal to 1; R.sub.9 is a hydrogen atom or a methyl radical; R.sub.7 and R.sub.8, independently of each other, are chosen from C.sub.1-C.sub.8 alkyl groups, hydroxyalkyl groups in which the alkyl group is C.sub.1-C.sub.5, or amidoalkyl groups in which the alkyl is C.sub.1-C.sub.4; or R.sub.7 and R.sub.8, together with the nitrogen atom to which they are attached, are chosen from heterocyclic groups; and Y.sup.− is an organic or inorganic anion; (8) diquaternary ammonium polymers containing repeating units corresponding to the formula: ##STR00017## wherein: R.sub.10, R.sub.11, R.sub.12 and R.sub.13, which may be identical or different, are chosen from linear, branched or cyclic, saturated, unsaturated or aromatic, C.sub.1-C.sub.20 hydrocarbon-based radicals, linear or branched hydroxyalkyl radicals in which the alkyl part is C.sub.1-C.sub.4, or linear or branched C.sub.1-C.sub.6 alkyl radicals, substituted with nitrile, ester, acyl or amide groups or a group —CO—O—R.sub.14-D or —CO—NH—R.sub.14-D with R.sub.14 chosen from alkyl radicals and D chosen from quaternary ammonium groups, or R.sub.10, R.sub.11, R.sub.12 and R.sub.13 form, together or separately, with the nitrogen atoms to which they are attached, heterocycles optionally containing a second heteroatom other than nitrogen; A.sub.1 and B.sub.1 are chosen from linear or branched, saturated or unsaturated, C.sub.2-C.sub.20 radicals, optionally substituted with one or more aromatic rings, oxygen or sulfur atoms or groups bearing at least one of these atoms; and X.sup.− is an organic or inorganic anion; wherein A.sub.1, R.sub.10 and R.sub.12 may optionally form, with the two nitrogen atoms to which they are attached, a piperazine ring; and further wherein, if A.sub.1 is chosen from a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B.sub.1 can also be chosen from a —(CH.sub.2).sub.nCO-D-OC(CH.sub.2).sub.n- group wherein n ranges from 1 to 100, and D is chosen from a glycol, bis-secondary diamine, bis-primary diamine or ureylene residue; (9) polyquaternary ammonium polymers consisting of repeating units of formula (IX): ##STR00018## wherein p is an integer ranging from 1 to 6, D may be zero or may be a —(CH.sub.2).sub.r—CO- group in which r ranges from 4 to 7, and X.sup.— is an organic or inorganic anion; (10) quaternary polymers of vinylpyrrolidone and of vinylimidazole; and (11) polyamines.

16. The composition according to claim 1, wherein the at least one cationic polymer is present in an amount ranging from about 0.01% to about 10% by weight, relative to the weight of the composition.

17. A process for dyeing keratin fibers, comprising: (a) preparing a dye composition by mixing: a first composition free of oxidizing agent other than atmospheric oxygen, comprising at least one coloring agent chosen from oxidation dye precursors, direct dyes and mixtures thereof; and a second composition comprising at least one oxidizing agent other than atmospheric oxygen; wherein at least one of the first or second compositions comprises at least one fatty substance chosen from liquid paraffins, petroleum jelly, liquid petroleum jelly, Polvdecenes, or hydrogenated polyisobutene, at least one cationic polymer, and at least one amphoteric or zwitterionic surfactant; wherein the resulting mixture has a total fatty substance content of at least about 10% by weight relative to the weight of the mixture; wherein the amphoteric surfactant and anionic surfactant are present in a weight ratio ranging from 0.1 to 10; and (b) applying said dye composition to said keratin fibers.

18. A device for mixing and using a composition for dyeing keratin fibers, comprising: a first compartment containing a composition free of oxidizing agent other than atmospheric oxygen, comprising at least one coloring agent chosen from oxidation dye precursors, direct dyes or mixtures thereof; and a second compartment containing an oxidizing composition; wherein at least one of the compositions comprises at least one fatty substance chosen from liquid paraffins, petroleum jelly, liquid petroleum jelly, polvdecenes, or hydrogenated polyisobutene, at least one cationic polymer, at least one amphoteric or zwitterionic surfactant, at least one anionic surfactant; wherein the amphoteric surfactant and anionic surfactant are present in a weight ratio ranging from 0.1 to 10; and wherein the composition in the first compartment and the composition in the second compartment are mixed before use.

Description

EXAMPLE

(1) The following compositions are prepared (the amounts are expressed in g % of active material):

(2) Composition 1:

(3) TABLE-US-00001 Resorcinol 0.5 Ethanolamine 5 Sodium laureth sulfate comprising 2 OE 1.75 Hydroxypropyl guar 1 Ascorbic acid 0.5 N,N-Bis(2-hydroxyethyl)-p-phenylenediamine sulfate 0.073 m-Aminophenol 0.18 EDTA 0.2 2-Methylresorcinol 0.1 PEG-40 hydrogenated castor oil 1 2,4-Diaminophenoxyethanol hydrochloride 0.019 Cocobetaine 3 Sodium chloride 0.65 Sodium metabisulfite 0.5 Mineral oil 60 2,5-Toluenediamine 0.6732 Water q.s. for 100
Composition 2:

(4) TABLE-US-00002 Tocopherol 0.1 Sodium stannate 0.04 Pentasodium pentetate 0.06 Polyquaternium-6 0.2 Glycerol 0.5 Cetearyl alcohol 6 Hexadimethrine chloride 0.15 Hydrogen peroxide 6 Tetrasodium pyrophosphate 0.03 Mineral oil 20 PEG-4 Rapeseedamide 1.19 Steareth-20 5 Phosphoric acid q.s. for pH 2.2 Water q.s. for 100
Application Method:

(5) The two compositions are mixed together at the time of use in the following proportions: 10 g of composition 1 with 15 g of composition 2.

(6) The resulting mixture is easily applied to locks of dark chestnut hair in a proportion of 10 g of mixture for 1 g of hair, for 30 minutes at ambient temperature (20° C.).

(7) The hair is then easily rinsed, then washed with a standard shampoo and dried.

(8) A light chestnut colour is obtained.

(9) Composition 3:

(10) TABLE-US-00003 Ethanolamine 5 Sodium laureth sulfate comprising 2.2 OE 1.75 Hydroxypropyl guar 1 Ascorbic acid 0.5 N,N-bis(2-Hydroxyethyl)-p-phenylenediamine 0.073 sulphate EDTA 0.2 PEG-40 hydrogenated castor oil 1 Cocobetaine 3 Sodium chloride 0.65 Sodium metabisulfite 0.5 Basic Yellow 87 0.3 Basic Orange 31 0.225 Mineral oil 60 Water q.s. for 100
Composition 4:

(11) TABLE-US-00004 Tocopherol 0.1 Sodium stannate 0.04 Pentasodium pentetate 0.06 Polyquaternium-6 0.2 Glycerol 0.5 Cetearyl alcohol 6 Hexadimethrine chloride 0.15 Hydrogen peroxide 6 Tetrasodium pyrophosphate 0.03 Mineral oil 20 PEG-4 Rapeseedamide 1.19 Steareth-20 5 Phosphoric acid q.s. for pH 2.2 Water q.s. for 100
Application Method:

(12) The two compositions are mixed at the time of use in the following proportions: 10 g of composition 3 with 15 g of composition 4.

(13) The resulting mixture is easily applied to locks of dark chestnut hair in a proportion of 10 g of mixture for 1 g of hair, for 30 minutes at ambient temperature (20° C.).

(14) The hair is then easily rinsed, then washed with a standard shampoo and dried.

(15) A coppery light chestnut colour is obtained.