Color Liquid Crystal Displays and Display Backlights
20230176275 · 2023-06-08
Inventors
Cpc classification
G02F1/133614
PHYSICS
G02F1/133606
PHYSICS
G02F1/133611
PHYSICS
International classification
C09K11/88
CHEMISTRY; METALLURGY
C09K11/61
CHEMISTRY; METALLURGY
Abstract
There is provided a display backlight (604), including an excitation source (644) for generating blue light (650); and a wavelength converter (654) being a unitary construction including a combination of a wavelength selective filter layer (658) bonded to a photoluminescence layer (660), where the photoluminescence layer (658) includes a green photoluminescence material and a red photoluminescence material; and where the wavelength selective filter layer (658) is transmissive to blue light and reflective to green and red light.
Claims
1. A display backlight, comprising: an excitation source for generating blue light; and a wavelength converter being a unitary construction comprising a combination of a wavelength selective filter layer bonded to a photoluminescence layer, wherein the photoluminescence layer comprises a green photoluminescence material and a red photoluminescence material; and wherein the wavelength selective filter layer is transmissive to blue light and is reflective to green and red light.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0052] In order that the present invention is better understood, embodiments of the invention will now be described, by way of example only, with reference to the accompanying drawings in which:
[0053]
[0054]
[0055]
[0056]
[0057]
[0058]
[0059]
[0060]
[0061]
[0062]
[0063]
[0064]
[0065]
DETAILED DESCRIPTION OF THE INVENTION
[0066] Embodiments of the invention are directed to color LCDs including a photoluminescence wavelength converting layer which when excited by excitation light, typically blue light, generates white light for operating the display. Typically, the photoluminescence wavelength converting layer comprises a part of the backlight. Various embodiments of the invention concern arrangements which increase display efficacy by reducing the number of layers within the display/backlight or otherwise reduces light losses at the interface between layers of the display by for example eliminating the air interfaces.
[0067] Embodiments of the present invention will now be described in detail with reference to the drawings, which are provided as illustrative examples of the invention so as to enable those skilled in the art to practice the invention. Notably, the figures and examples below are not meant to limit the scope of the present invention to a single embodiment, but other embodiments are possible by way of interchange of some or all of the described or illustrated elements. Moreover, where certain elements of the present invention can be partially or fully implemented using known components, only those portions of such known components that are necessary for an understanding of the present invention will be described, and detailed descriptions of other portions of such known components will be omitted so as not to obscure the invention. In the present specification, an embodiment showing a singular component should not be considered limiting; rather, the invention is intended to encompass other embodiments including a plurality of the same component, and vice-versa, unless explicitly stated otherwise herein. Moreover, applicants do not intend for any term in the specification or claims to be ascribed an uncommon or special meaning unless explicitly set forth as such. Further, the present invention encompasses present and future known equivalents to the known components referred to herein by way of illustration. Throughout this specification like reference numerals preceded by the figure number are used to denote like features.
[0068] Referring to
[0069] LC Display Panel
[0070] As shown in
[0071] As shown in
[0072] The color filter plate 220 comprises an array of different color sub-pixels filter elements 224, 226, 228 which respectively allow transmission of red (R), green (G), and blue (B) light. Each unit pixel 230 of the display comprises a group of three sub-pixels filter elements 224, 226, 228.
[0073] Referring to
[0074] Direct-Lit Backlight
[0075] Referring to
[0076] As shown in
[0077] The Backlight 604 further comprises, in order of proximity from the excitation sources 644, a light diffusive layer 652, a wavelength converter 654 and a Brightness Enhancement Film (BEF) 656. The light diffusive layer 652 ensures uniform illumination of the wavelength converter 654 with blue excitation light 650.
[0078] Brightness Enhancement Film (BEF)
[0079] The Brightness Enhancement Film (BEF) 656, also known as a Prism Sheet, comprises a precision micro-structured optical film and controls the emission of white light 640 from the backlight within a fixed angle (typically 70 degrees), thereby increasing luminous efficacy of the backlight. Typically, the BEF comprises an array of micro-prisms on a light emitting face of the film and can increase brightness by 40-60%. The BEF 656 can comprise a single BEF or a combination of multiple BEFs and in the case of the latter even greater increases in brightness can be achieved. Examples of suitable BEFs include Vikuiti™ BEF II from 3M or prism sheets from MNTech. In some embodiments, the BEF 656 can comprise a Multi-Functional Prism Sheet (MFPS) that integrates a prism sheet with a diffusion film and can have a better luminous efficiency than a normal prism sheet. In some embodiments, the BEF 656 can comprise a Micro-Lens Film Prism Sheet (MLFPS) such as those available from MNTech.
[0080] Wavelength Converter
[0081] Referring to
[0082] One of the important features of the invention is the unitary construction of the wavelength converter formed from the filter layer 658 and the photoluminescence layer 660, such that the unitary construction is a combination of the filter layer 658 and the photoluminescence layer 660. The provision of a unitary construction in this manner is more cost effective than known arrangements because it does not require the presence of an additional layer, such as light transmissive layer, to which the photoluminescence layer would normally be bound in known constructions. The absence of such an additional layer also makes the unitary construction formed in accordance with the invention more robust and reliable than known arrangements. Since the unitary construction has a simple and efficient design, its assembly and manufacture as part of the display backlight is significantly faster and less prone to errors than the assembly and manufacture of known backlights. Further, experiments have confirmed that a unitary construction can improve the quantum efficiency of the display backlight by approximately 10% compared with known arrangements, and provides a significant reduction (20-60%) in the amount of photoluminescence materials required. It may be that the red photoluminescence material is in direct contact with the wavelength selective filter layer.
[0083] Wavelength Converter—Photoluminescence Layer
[0084] The photoluminescence layer 658 contains photoluminescence materials and in operation converts blue excitation light 650 into white light 640 for operating the LC Display Panel. More specifically, the photoluminescence layer 658 contains blue light excitable green-emitting (Peak emission wavelength 530 nm to 545 nm) and red-emitting (Peak emission wavelength 600 nm to 650 nm) photoluminescence materials. The combination of photoluminescence generated red light 662, photoluminescence generated green light 664 and unconverted blue excitation light 650 results in a white light emission product 640. To optimize the efficacy and color gamut of the display, the green- and red-emitting photoluminescence materials are selected to match their peak emission (PE) wavelength λ.sub.p with the transmission characteristic of their corresponding color filter elements. Preferably, the green-emitting photoluminescence material has a peak emission wavelength λ.sub.p≈535 nm. In order to maximize display color gamut and efficacy, the green-emitting and/or red-emitting photoluminescence materials preferably comprise narrow-band emitting materials having an emission peak with a FWHM (Full Width Half Maximum) of about 50 nm of less.
[0085] The green- and red-emitting photoluminescence materials can comprise phosphor materials or quantum dots (QDs) or combinations thereof. For the purposes of illustration, the current description specifically refers to photoluminescence materials embodied as phosphor materials. The phosphor materials can comprise inorganic and organic phosphor materials. Inorganic phosphors can comprise aluminate, silicate, phosphate, borate, sulfate, chloride, fluoride or nitride phosphor materials. As is known phosphor materials are doped with a rare-earth element called an activator. The activator typically comprises divalent europium, cerium or tetravalent manganese. Dopants such as halogens can be substitutionally or interstitially incorporated into the crystal lattice and can for example reside on lattice sites of the host material and/or interstitially within the host material. Examples of suitable green-emitting and red-emitting phosphor materials are given in tables 1 and 2 respectively.
TABLE-US-00001 TABLE 1 Example green-emitting phosphor materials Phosphor FWHM family Composition λ.sub.p (nm) (nm) Sulfide SrGa.sub.2S.sub.4: Eu ≈536 48-50 β-SiAlON M.sub.xSi.sub.12-(m+n)Al.sub.m+nO.sub.nN.sub.16-n: Eu 525-545 50-52 M = Mg, Ca and/or Sr Aluminate YAG Y.sub.3(Al.sub.1-xGa.sub.x).sub.5O.sub.12: Ce 500-550 ≈110 Aluminate LuAG Lu.sub.3(Al.sub.1-xM.sub.x).sub.5O.sub.12: Ce 500-550 ≈110 Silicate A.sub.2SiO.sub.4: Eu 500-550 ≈70 A = Mg, Ca, Sr and/or Ba Silicate (Sr.sub.1-xBa.sub.x).sub.2SiO.sub.4: Eu 500-550 ≈70
TABLE-US-00002 TABLE 2 Example red-emitting phosphor materials FWHM Phosphor family Composition λ.sub.p (nm) (nm) Hexafluorosilicate KSF K.sub.2SiF.sub.6: Mn.sup.4+ ≈632 ≈10 Hexafluorosilicate KTF K.sub.2TiF.sub.6: Mn.sup.4+ ≈632 ≈10 Selenide sulfide CSS MSe.sub.1-xS.sub.x: Eu 600-630 50-55 M = Mg, Ca, Sr and/or Ba Selenide sulfide CSS CaSeS: Eu 610-630 50-55 Silicon-ni tride CASN CaAlSiN.sub.3: Eu 600-620 ≈75 1:1:1:3 (Ca.sub.1-x-Sr.sub.x)AlSiN.sub.3: Eu Silicon-nitride Ba.sub.2-xSr.sub.xSi.sub.5N.sub.8: Eu 580-620 ≈80 2:5:8
[0086] A quantum dot (QD) is a portion of matter (e.g. semiconductor) whose excitons are confined in all three spatial dimensions that may be excited by radiation energy to emit light of a particular wavelength or range of wavelengths. QDs can comprise different materials, for example cadmium selenide (CdSe). The color of light generated by a QD is enabled by the quantum confinement effect associated with the nano-crystal structure of the QD. The energy level of each QD relates directly to the physical size of the QD. For example, the larger QDs, such as red QDs, can absorb and emit photons having a relatively lower energy (i.e. a relatively longer wavelength). On the other hand, green QDs, which are smaller in size can absorb and emit photons of a relatively higher energy (shorter wavelength). Examples of suitable QDs can include: CdZnSeS (cadmium zinc selenium sulfide), Cd.sub.xZn.sub.1-x Se (cadmium zinc selenide), CdSe.sub.xS.sub.1-x (cadmium selenium sulfide), CdTe (cadmium telluride), CdTe.sub.xS.sub.1-x (cadmium tellurium sulfide), InP (indium phosphide), InxGa.sub.1-x P (indium gallium phosphide), InAs (indium arsenide), CuInS.sub.2 (copper indium sulfide), CuInSe.sub.2 (copper indium selenide), CuInSxSe.sub.2-x (copper indium sulfur selenide), Cu InxGa.sub.1-x S.sub.2 (copper indium gallium sulfide), CuIn.sub.xGa.sub.1-xSe.sub.2 (copper indium gallium selenide), CuIn.sub.xAl.sub.1-x Se.sub.2 (copper indium aluminum selenide), CuGaS.sub.2 (copper gallium sulfide) and CuInS.sub.2xZnS.sub.1-x (copper indium selenium zinc selenide). The optical properties of the core nano-crystals in one material can be altered by growing an epitaxial-type shell of another material. Depending on the requirements, the core/shell nano-crystals can have a single shell or multiple shells. The shell materials can be chosen based on the band gap engineering. For example, the shell materials can have a band gap larger than the core materials so that the shell of the nano-crystals can separate the surface of the optically active core from its surrounding medium. In the case of the cadmium-based QDs, e.g. CdSe QDs, the core/shell quantum dots can be synthesized using the formula of CdSe/ZnS, CdSe/CdS, CdSe/ZnSe, CdSe/CdS/ZnS, or CdSe/ZnSe/ZnS. Similarly, for CuInS.sub.2 quantum dots, the core/shell nanocrystals can be synthesized using the formula of CuInS.sub.2/ZnS, CuInS.sub.2/CdS, CuInS.sub.2/CuGaS.sub.2, CuInS.sub.2/CuGaS.sub.2/ZnS and so on.
[0087] As described above the wavelength converter is of a unitary construction. When using inorganic phosphor materials, the green-emitting and red-emitting phosphors, which are in the form of particles, can be incorporated as a mixture in a curable light transmissive liquid binder material and the mixture deposited directly as a uniform layer on a wavelength selective filter layer using for example screen printing or slot die coating. In this patent specification, depositing directly means in direct contact with, in that is there is no air gap between the layers. There may be an intervening layer, for instance a light transmissive binder/bonding layer, which is bonded to the wavelength selective filter layer and the photoluminescence layer. Such an arrangement is still encompassed within the meaning of “deposing directly” and “in direct contact with” for the purposes of this specification. By way of illustration only, the various layers in the figures are shown separated when they are not in direct contact with each other, that is where they are fabricated separately and then stacked together. When depositing the photoluminescence wavelength converting layer using screen printing, the light transmissive binder material can comprise for example a light transmissive UV-curable acrylic adhesive such as UVA4103 clear base from STAR Technology of Waterloo, Ind. USA. An advantage of depositing the photoluminescence layer directly onto the filter layer is that this can increase light emission from the backlight by eliminating an air interface between the photoluminescence layer and filter layer. Such an air interface could otherwise lead to a greater probability of internal reflection occurring at the interface between the photoluminescence layer and filter layer. The photoluminescence layer can be of a thickness in a range 50 μm to 100 μm, more typically 40 μm to 80 μm.
[0088] In any embodiment, the photoluminescence layer can further incorporate particles of a light scattering (diffusive) material, preferably zinc oxide (ZnO). The light diffusive material can comprise silicon dioxide (SiO.sub.2), titanium dioxide (TiO.sub.2), magnesium oxide (MgO), barium sulfate (BaSO.sub.4), aluminum oxide (Al.sub.2O.sub.3) or combinations thereof. Inclusion of a light scattering material can increase uniformity of light emission from the photoluminescence layer and can eliminate the need for a separate light diffusive layer as are commonly used in color LCDs. Additionally, incorporating particles of a light scattering material with the mixture of green- and red-emitting phosphor can result in an increase in light generation by the photoluminescence layer and a substantial, up to 40%, reduction in the quantity of phosphor materials required to generate a given color of light. Given the relatively high cost of phosphor materials, inclusion of an inexpensive light scattering material can result in a significant reduction in manufacturing cost for larger displays such a tablet computers, laptops, TVs and monitors. Further details of an exemplary approach to implement scattering particles are described in U.S. Pat. No. 8,610,340 issued Dec. 17, 2013, which is hereby incorporated by reference in its entirety. The size of the light scattering particles can be selected to scatter excitation light relatively more than light generated by the phosphor. In some embodiments, the light scattering material particles have an average diameter (D50) of 200 nm of less, typically 100 nm to 150 nm.
[0089] Wavelength Converter—Wavelength Selective Filter Layer
[0090] Referring to
[0091] The filter layer 758 can comprise a thin-film dichroic filter (interference filter). Typically the filter layer comprises a film of thickness 80 μm to 150 μm.
[0092] As indicated in
[0093] Edge-Lit Backlight
[0094] While the backlight of the invention finds particular utility in direct-lit backlight arrangements, the backlight, in particular wavelength converter of the invention, also finds utility in edge-lit backlight arrangements.
[0095]
[0096] The excitation sources 944 are configured such that in operation, they generate blue excitation light 950 which is coupled into one or more edges of the light guide 966 and then guided, by total internal reflection, throughout the volume of the light guide 966 and finally emitted from the front light emitting face 970 of the light guide (upper face that faces the Display Panel). As shown in
[0097] As with the direct-lit configuration of
[0098]
[0099] As shown in
[0100] In this embodiment, and as indicated in
[0101]
[0102] As shown in
[0103] As shown in
[0104] As shown in
[0105] As shown in
[0106] As shown in
[0107] As shown in
[0108] As shown in
[0109] As shown in
[0110] As used in this document, both in the description and in the claims, and as customarily used in the art, the words “substantially,” “approximately,” and similar terms of approximation are used to account for manufacturing tolerances, manufacturing variations, manufacturing imprecisions, and measurement inaccuracy and imprecision that are inescapable parts of fabricating and operating any physical object.
[0111] It will be appreciated that the present invention is not restricted to the specific embodiments described, and that variations can be made that are within the scope of the invention.
REFERENCE NUMERALS
[0112] 00 Color LCD [0113] 02 LC Display Panel [0114] 04 Backlight [0115] 06 Front plate [0116] 08 Back plate [0117] 10 Liquid Crystal (LC) [0118] 12 Glass plate [0119] 14 Viewing face [0120] 16 First polarizing filter layer [0121] 18 Anti-reflective layer [0122] 20 Color filter plate [0123] 22 Light transmissive common electrode plane [0124] 24 Red sub-pixel filter element [0125] 26 Green sub-pixel filter element [0126] 28 Blue sub-pixel filter element [0127] 30 Unit pixel [0128] 32 Opaque divider/black matrix [0129] 34 Glass plate [0130] 36 TFT [0131] 38 Second polarizing filter layer [0132] 40 white Light [0133] 42 Backlight light emitting face [0134] 44 Excitation source [0135] 46 Enclosure Floor [0136] 48 Enclosure [0137] 50 Blue excitation light [0138] 52 Light diffusive layer [0139] 54 Wavelength converter [0140] 56 Brightness Enhancement Film (BEF) [0141] 58 Wavelength selective filter layer [0142] 60 Photoluminescence wavelength converting layer (photoluminescence layer) [0143] 62 Green photoluminescence light [0144] 64 Red photoluminescence light [0145] 66 Light guide [0146] 68 Light reflective layer [0147] 70 Light emitting face of light guide [0148] 72 Edge face of light guide [0149] 74 Light transmissive protective layer [0150] 76 Light diffusive layer [0151] 78 Light transmissive bonding layer [0152] 80 Light transmissive bonding layer