Heat-resistant Ir alloy

Abstract

Provided is an Ir alloy, which is further improved in Vickers hardness. Specifically, provided is a heat-resistant Ir alloy, including: 5 mass % to 30 mass % of Rh; 0.5 mass % to 5 mass % of Ta; and 0.003 mass % to 0.15 mass % of at least one kind selected from the group consisting of: Sc; Hf; and W, with the balance being Ir.

Claims

1. A heat-resistant Ir alloy, comprising: 5 mass % to 30 mass % of Rh; 0.5 mass % to 5 mass % of Ta; and 0.003 mass % to 0.15 mass % of at least one kind selected from the group consisting of: Sc; Hf; and W, with the balance being Ir.

Description

DESCRIPTION OF THE EMBODIMENTS

(1) The present invention is directed to a heat-resistant Ir alloy, including: 5 mass % to 30 mass % of Rh; 0.5 mass % to 5 mass % of Ta; and 0.003 mass % to 0.15 mass % in total of at least one kind selected from the group consisting of: Sc; Hf; and W, with the balance being Ir. The “Ir alloy” refers to an alloy including Ir as a main element. In addition, the Ir alloy according to at least one embodiment of the present invention may include inevitable impurities in addition to the above-mentioned elements. The presence or absence of the inevitable impurities does not affect the above-mentioned effects.

(2) When the Ir alloy includes 5 mass % to 30 mass % of Rh, oxidative volatilization of Ir from a crystal grain boundary is suppressed in the air at high temperature or in an oxidizing atmosphere, and the oxidation wear resistance of the alloy is remarkably improved. When the content of Rh is less than 5 mass %, the oxidation wear resistance of the Ir alloy is insufficient. Meanwhile, when the content of Rh is more than 30 mass %, the oxidation wear resistance of the Ir alloy is satisfactory, but the melting point of the Ir alloy is reduced. The content of Rh is preferably from 7 mass % to 25 mass %.

(3) When an Ir-Rh alloy includes 0.5 mass % to 5 mass % of Ta, the hardness of the alloy is increased through solid solution hardening due to Ta. The content of Ta is preferably 0.7 mass % or more. When the content of Ta is less than 0.5 mass %, the solid solution hardening is insufficient. Meanwhile, when the content of Ta is more than 5 mass %, it becomes difficult to process the alloy owing to a reduction in plastic deformability.

(4) When an Ir—Rh—Ta alloy includes 0.003 mass % to 0.15 mass % of at least one kind selected from the group consisting of: Sc; Hf; and W, the hardness of the alloy is increased through solid solution strengthening and finer crystal grains. Specifically, Sc and Hf, which each have a lower melting point than the Ir—Rh—Ta alloy, are preferentially solid-soluted in a grain boundary at a final solidification portion of the alloy, to thereby suitably strengthen a fragile crystal grain boundary of the Ir alloy. W, which has a higher melting point than the Ir—Rh—Ta alloy, serves as a nucleation site at the time of solidification, to thereby make a solidified structure of the Ir—Rh—Ta alloy finer.

(5) The content of the at least one kind selected from the group consisting of: Sc; Hf; and W (as a total content in the case in which two or more kinds thereof are included) is preferably 0.005 mass % or more. The content of the at least one kind selected from the group consisting of: Sc; Hf; and W (as a total content in the case in which two or more kinds thereof are included) is more preferably 0.01 mass % or more. When the addition amount is more than 0.15 mass %, the hardness of the alloy is satisfactory, but the processability thereof is reduced.

(6) The Vickers hardness of the heat-resistant Ir alloy according to at least one embodiment of the present invention is 600 HV or more.

(7) Each of the above-mentioned alloys is formed of a single-phase solid solution which is free of a second phase. Accordingly, each of the alloys has satisfactory ductility, can be plastically formed into various shapes and dimensions through known warm working or hot working, and is also easily mechanically processed or welded.

EXAMPLES

(8) Examples of the present invention are described. First, raw material powders (Ir powder, Rh powder, Ta powder, Sc powder, Hf powder, and W powder) were mixed at a predetermined ratio to obtain mixed powder. Next, the resultant mixed powder was molded with a uniaxial pressing machine to provide a green compact. The resultant green compact was melted by an arc melting method to produce an ingot.

(9) Next, the ingot thus produced was subjected to hot forging at 1,500° C. or more to provide a square bar having a width of 15 mm. The square bar was subjected to hot groove rolling and wire drawing die processing to provide a wire rod of φ0.5 mm.

(10) The hardness of a longitudinal cross section of the wire rod having been cut into a predetermined length was measured under the conditions of a load of 200 gf and a retention time of 10 seconds with a micro Vickers hardness tester.

(11) The processability was evaluated through the above-mentioned step of processing the ingot into the wire rod. In Table 1, a case in which a wire rod of φ0.5 mm was obtained was indicated by Symbol “o”, and a case in which the wire rod of φ0.5 mm was not obtained was indicated by Symbol “x”.

(12) The compositions and test results of the alloys of Examples and Comparative Examples are shown in Table 1.

(13) TABLE-US-00001 TABLE 1 Composition (mass %) Hardness Process- Number Ir Rh Ta Sc Hf W HV ability Example 1 Balance 5 1 0.075 — — 629 ∘ 2 Balance 5 1 — — 0.075 610 ∘ 3 Balance 5 3 0.075 — — 708 ∘ 4 Balance 5 3 — 0.075 — 711 ∘ 5 Balance 10 3 0.005 — — 679 ∘ 6 Balance 10 3 0.15 — — 724 ∘ 7 Balance 10 3 — 0.005 — 664 ∘ 8 Balance 10 3 — 0.15 — 693 ∘ 9 Balance 10 3 — — 0.015 642 ∘ 10 Balance 30 3 0.075 — — 614 ∘ 11 Balance 30 3 — 0.075 — 615 ∘ 12 Balance 30 3 — — 0.15 621 ∘ 13 Balance 30 5 — 0.075 — 654 ∘ 14 Balance 30 5 — — 0.075 642 ∘ 15 Balance 10 3 0.05 0.05 0.05 711 ∘ Compar- 1 Balance 10 3 0.2 — — 751 x ative 2 Balance 10 3 — 0.2 — 723 x Example 3 Balance 5 1 — — — 578 ∘ 4 Balance 10 3 — — — 593 ∘ 5 Balance 30 1 — — — 489 ∘ 6 Balance 30 3 — — — 583 ∘ 7 Balance 30 5 — — — 596 ∘

(14) The alloys of Examples 1 to 14 are each an alloy in which any one kind of Sc, Hf, or W is added to Ir—Rh—Ta. The alloys of Examples 1 to 14 are increased in hardness as compared to those of Comparative Examples 3 to 7, in each of which Sc, Hf, and W are not added. Meanwhile, the alloys of Comparative Examples 1 and 2, in each of which Sc or Hf is added in an amount of 0.2 mass %, are increased in hardness, but are remarkably reduced in processability. In addition, the alloy of Example 15, in which each of Sc, Hf, and W is added in an amount of 0.05 mass % to Ir—Rh—Ta, is increased in hardness as compared to that of Comparative Example 4.

(15) It was able to be recognized that the alloys of Examples each had a hardness of from 610 HV to 724 HV and processability indicated by Symbol “o”, and thus achieved both a high hardness and satisfactory processability, and had excellent characteristics as a heat-resistant Ir alloy.