MULTILAYER COATING FOR OPTICAL SOLAR REFECTOR

Abstract

A product comprising a substrate and a multilayer coating for the thermal control of a surface comprising a first inner layer intended to be deposited on said surface, a second intermediate layer applied on said first inner layer and a third outer layer applied on said second intermediate layer in which: said first inner layer comprises a co-dispersion of conductive nanoparticles and dielectric nanoparticles

Claims

1-17. (canceled)

18. A product, comprising: a substrate; and a multilayer coating for thermal control of a surface of the substrate, the multilayer coating including a first inner layer intended to be deposited on the surface, a second intermediate layer applied on the first inner layer, and a third outer layer applied on the second intermediate layer, wherein: the first inner layer includes a co-dispersion of conductive nanoparticles and dielectric nanoparticles, wherein a volume fraction of conductive nanoparticles increases along a thickness of the first inner layer moving away from the second intermediate layer, and wherein the first inner layer has a hemispheric emissivity between 0.5 and 0.8; the second intermediate layer includes a plurality of layers, wherein the plurality of layers includes at least one layer of a dielectric material transparent in the visible with a high refractive index in the visible is alternated with at least one layer of a dielectric material transparent in the visible with a low refractive index in the visible, wherein a refractive index of each of the layers of dielectric material transparent in the visible with high refractive index in the visible is higher than the refractive index of each adjacent layer of dielectric material transparent in the visible with low refractive index in the visible; and the third outer layer is made of a conductive oxide transparent in the visible having a resistivity of less than 1×10.sup.−3 ohm×cm.

19. The product of claim 18, wherein the conductive nanoparticles include a material selected from the group consisting of aluminum, Al.sub.xO, TiN, indium tin oxide, aluminum zinc oxide, steel, Ti, Mo, rare earths, transition metals, and combinations thereof.

20. The product of claim 18, wherein the dielectric nanoparticles include a material selected in the group consisting of Al.sub.2O.sub.3, Al, SiO.sub.2, Ta.sub.2O.sub.5, ZrO.sub.2, Nb.sub.2O.sub.5, Y.sub.2O.sub.3, TiO.sub.2, AN, and combinations thereof.

21. The product of claim 18, wherein the dielectric nanoparticles are made of Al.sub.2O.sub.3 and the conductive nanoparticles are made of Al.sub.xO or Al.

22. The product of claim 18, wherein the first inner layer has a thickness between 1 and 4 micrometers.

23. The product of claim 18, wherein the second intermediate layer has a thickness between 5 and 15 micrometers.

24. The product of claim 18, wherein the second intermediate layer includes between 45 and 150 dielectric layers transparent in the visible.

25. The product of claim 18, wherein the second intermediate layer is made of a material selected in the group consisting of SiO.sub.2, MgF.sub.2, Ta.sub.2O.sub.5, ZrO.sub.2, TiO.sub.2, Nb.sub.2O.sub.5, Y.sub.2O.sub.3, YF.sub.3, and combinations thereof.

26. The product of claim 18, wherein a difference between the refractive index of the layer of the dielectric material transparent in the visible with the high refractive index in the visible and the refractive index of the layer of the dielectric material transparent in the visible with the low refractive index in the visible is at least 0.5.

27. The product of claim 18, wherein the layer of the dielectric material transparent in the visible with the high refractive index in the visible has a refractive index in the visible between 1.6 and 2.5.

28. The product of claim 18, wherein the layer of the dielectric material transparent in the visible with the low refractive index in the visible has a refractive index in the visible between 1.2 and 1.7.

29. The product of claim 18, wherein the third outer layer is made of a material selected in the group consisting of indium tin oxide, alumina doped zinc oxide, cadmium oxide and alloys thereof, zinc oxide and alloys thereof, tin oxide and alloys thereof, antimony, and fluorine doped tin oxide.

30. The product of claim 18, wherein the third outer layer has a surface resistivity between 10.sup.3 and 10.sup.6 ohm/square.

31. An optical solar reflector comprising the product of claim 18.

32. The optical solar reflector of claim 31, wherein the substrate is a flexible substrate.

33. The optical solar reflector of claim 32, wherein the flexible substrate includes a metal film, polymer film, composite, or flexible glass.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0024] FIG. 1 shows a schematic representation of the multilayer coating according to the present invention.

[0025] FIG. 2 shows a schematic representation of a radiator panel comprising an optical solar radiator according to the present invention.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS OF THE INVENTION

[0026] The present invention will now be described in detail with reference to the accompanying figures to allow a skilled person to make and use it. Various modifications of the embodiment described will be immediately clear to the skilled person and the general principles disclosed can be applied to other embodiments and applications without departing from the protection scope of the present invention, as defined in the accompanying drawings. Therefore, the present invention should not be considered limited to the embodiments described and shown but should be granted the widest protective scope in accordance with the features described and claimed.

[0027] Unless otherwise defined, all the herein used technical and scientific terms have the same meaning commonly used by the ordinary skilled in the art of the present invention. In case of conflict, the present invention, including definitions provided, will be binding. Furthermore, the examples are provided for merely illustrative purposes and must not be regarded as limiting.

[0028] In order to facilitate understanding of the embodiments described herein, reference will be made to some specific embodiments and a specific language will be used to describe them. The terminology used herein is for the purpose of describing only particular embodiments, and is not intended to limit the scope of the present invention.

Multilayer Coating 1

[0029] Referring to FIG. 1, the multilayer coating 1 of the present invention is a coating with thereto-optical properties which can be produced by sputtering or with other physical vapour deposition technique and consists of three functionally and structurally distinct layers: [0030] a first inner layer 2, which acts as an emitter of infrared radiations, deposited on the surface of the substrate to be coated; [0031] a second intermediate layer 3, which acts as a solar reflector, arranged above the first inner layer 2; and [0032] a third outer layer 4, which acts as an electrostatic dissipator, facing outwards, i.e. towards the space.

First Inner Layer 2—Infrared Emitter

[0033] The first inner layer 2 is made of a co-dispersion of conductive nanoparticles and dielectric nanoparticles. These materials are ceramic-metal composites also known as CERMET.

[0034] The first inner layer 2 is graded, i.e. the volume fraction of the conductive nanoparticles increases along the thickness of the first inner layer 2 moving away from the interface thereof with the second intermediate layer 3. In one embodiment, the volume fraction of the conductive nanoparticles increases along the thickness of the inner layer 2, from a maximum value ≥70% at the interface with the substrate to a minimum value ≤30% at the interface with the intermediate layer 3.

[0035] In one embodiment, the volume fraction of the conductive nanoparticles increases continuously along the thickness of the first inner layer 2 moving away from the interface thereof with the second intermediate layer 3. In an alternative embodiment, the volume fraction of the conductive nanoparticles increases in small, discontinuous steps.

[0036] The infrared extinction coefficient follows the same trend: low at the interface of the inner layer 2 with the second intermediate layer 3 and high at the interface of the inner layer 2 facing towards the substrate. This configuration creates an electromagnetic trap, wherein the radiation coming from the space is absorbed within a progressively denser medium, with no reflections at the interfaces. In one embodiment, the first inner layer 2 effectively absorbs the infrared radiation from 3 to 20 microns and beyond.

[0037] Taking into account that:

[0038] absorbance and emissivity are equivalent according to Kirchoff's law;

[0039] the working temperature of a radiator panel of a spacecraft is around 300 K; and

[0040] the emissivity peak of a black body at 300 K is at a wavelength of 10 microns, it follows that the first inner layer 2 is characterized by a high hemispherical emissivity ε.

[0041] A second relevant feature of the first inner layer 2 is of the mechanical type. Unlike many black coatings that have a porous or columnar structure, the first inner layer 2 is compact and hard, and shows excellent adhesion to a variety of substrate materials. Furthermore, thanks to its graduated composition, it is effective in compensating for the misalignment of the coefficient of thermal expansion (CTE) between the substrate (higher CTE) and the second intermediate layer 3 (lower CTE).

[0042] The first inner layer 2 may be deposited on the bare substrate directly or by interposing an intermediate layer of alumina or other material that promotes the thermo-mechanical coupling and the adhesion to the substrate.

[0043] In one embodiment, the first inner layer 2 has a thickness between 1 and 4 microns, and a hemispherical emissivity between 0.5 and 0.8.

[0044] In one embodiment, the first inner layer 2 is made using a conductive material selected from the group consisting of aluminium, Al.sub.xO (i.e. aluminium sub-oxides), TiN, indium tin oxide, aluminium zinc oxide, steel, Ti, Mo, rare earths, transition metals and their combinations, preferably aluminium and Al.sub.xO.

[0045] In one embodiment, the first inner layer 2 is made using a dielectric material selected from the group consisting of Al.sub.2O.sub.3, Al, SiO.sub.2, Ta.sub.2O.sub.5, ZrO.sub.2, Nb.sub.2O.sub.5, Y.sub.2O.sub.3, TiO.sub.2, and their combinations, preferably Al.sub.2O.sub.3.

[0046] The first inner layer 2 can be produced by reactive sputtering from a single source by gradually changing the oxidation state of the material during deposition. In an alternative embodiment, the layer is produced by co-deposition of different materials from two or more distinct sources.

Second Intermediate Layer 3—Solar Reflector

[0047] The second intermediate layer 3 is arranged above the first inner layer 2 and acts as a solar reflector. It consists of a sequence of layers of dielectric and transparent materials wherein a layer of material with a high refractive index 3′ is alternated with a layer of material with a low refractive index 3″.

[0048] The layers of materials with high refractive index 3′ can be all made of the same material or different materials. The term “high refractive index” means a refractive index in the visible between 1.6 and 2.5.

[0049] The layers of materials with low refractive index 3″ can also be made all of the same material or different materials. The term “low refractive index” means a refractive index in the visible between 1.2 and 1.7.

[0050] For the intermediate layer 3 to perform its function, it is necessary that each layer with high refractive index 3′ has a refractive index higher than the refractive index of the adjacent layers with low refractive index 3″. In one embodiment this difference between the refractive index of the layer 3′ and that of the layer 3″ is at least 0.5, preferably 0.7.

[0051] The term “transparent” means a material having an extinction coefficient in the visible spectrum of less than 1×10.sup.−3 preferably 1×10.sup.−4.

[0052] The constructive and destructive interferences of the electromagnetic waves at the interfaces between the layers with high refractive index 3′ and the layers with low refractive index 3″ are used to generate a high reflectance in the solar spectrum.

[0053] The succession of the materials of the second intermediate layer 3 can be designed following one of the several approaches known to the optical designer, e.g. using quarter-wavelength sequences or quasi-periodic Fibonacci sequences or rugate filters and/or hybrid solutions. In the quarter-wavelength approach, the second intermediate layer 3 results by superposition of several filters that reflect different portions of the solar spectrum. Each filter is based on a three-layer unit (U) which can be repeated several times to improve performance. Using the standard notation wherein:

[0054] 1H denotes a layer of material with a high refractive index having an optical thickness equal to one quarter of the central wavelength; and

[0055] 1L denotes a layer with low index material having an optical thickness equal to one quarter of the central working wavelength of the filter;

the basic unit U of the filter is constructed using the relation:

1U=½L 1H ½L

or

1U=½H 1L½H.

[0056] Each filter is obtained by repeating the basic unit from 2 to 5 times. Different filters are used to reflect different areas of the solar spectrum. As a whole, the second intermediate layer 3 derives from the superposition of 15-50 filters centred at different wavelengths so as to uniformly cover the entire UV-VIS-NIR spectrum, from 100 nm to 1500 nm.

[0057] The second intermediate layer 3 may be deposited on the first inner layer 2 directly or by interposition of an intermediate layer of alumina or other material that improves the thermo-optical and/or mechanical coupling between the two layers.

[0058] In one embodiment, the materials of the second intermediate layer 3 are those commonly used to construct optical coatings in the UV-VIS-NIR spectrum, and comprise SiO.sub.2, MgF.sub.2, Ta.sub.2O.sub.5, ZrO.sub.2, TiO.sub.2, Nb.sub.2O.sub.5, Y.sub.2O.sub.3, YF.sub.3 and their mixtures.

[0059] In one embodiment, the second intermediate layer 3 is deposited by reactive sputtering.

[0060] In one embodiment, the second intermediate layer 3 consists of 45-150 layers, has a total thickness of 5-15 microns, and guarantees α in the range 0.20÷0.05 or less on smooth surfaces.

[0061] The second intermediate layer 3 always has a positive effect on the emissivity of the multilayer coating of the invention, which tends to increase. However, the effect may be more or less strong or weaker depending on the materials used and the total thickness.

Third Outer Layer 4—Electrostatic Dissipator

[0062] The third outer layer 4 is made of a transparent, and conductive oxide having a resistivity of less than 1×10.sup.−3 ohm×cm and an extinction coefficient in the visible of less than 1×10.sup.−3 preferably 1×10.sup.−4.

[0063] In a preferred embodiment, the transparent and conductive layer is made of a transparent and conductive oxide selected from the group consisting of indium tin oxide, alumina doped zinc oxide, cadmium oxide and its alloys, zinc oxide and its alloys, tin oxide and its alloys, antimony and fluorine doped tin oxide.

[0064] The outer layer 4 may be deposited on the second intermediate layer 3 directly or mediated by an intermediate layer made of SiO.sub.2, alumina, or other material transparent in the UV-VIS-NIR spectrum which can be used, among other things, to protect the upper layers of the multilayer coating of the invention from erosion due to atomic oxygen.

[0065] In one embodiment, the third outer layer 4 may be deposited by sputtering above the second intermediate layer, and may have a thickness of 10÷50 nm and a surface resistivity of 10.sup.3÷10.sup.6 Ohm/square.

Applications of the Multilayer Coating of the Invention

[0066] The multilayer coating 1 of the invention may be used to make a product, for example a radiator panel or parts of a spacecraft including antennas or other external structures requiring mitigation of temperature excursions, wherein the multilayer coating is applied to the substrate to be coated.

[0067] The multilayer coating 1 may be applied directly to the surface whose thermo-optical properties are to be modified, for example the aluminium or carbon fibre reinforced polymer skin of a radiator panel or of an antenna. The application of the coating may also precede the final assembly of the product, i.e. the coupling between the skin and the honeycomb bearing structure of the product. The surface to be coated can be polished prior to application of the coating to improve the performance α of the coating.

[0068] In an alternative embodiment, the multilayer coating of the invention can be used to manufacture a flexible optical solar reflector.

[0069] For this purpose, the multilayer coating is deposited on a flexible substrate, preferably a metal film, polymer film, composite (in particular CFRP) or flexible glass. Subsequently, the surface of the film opposite to that on which the coating was deposited is glued on the radiator panel or on the other outer surface of the spacecraft using, for example, a conductive resin or a pressure sensitive adhesive (PSA).

[0070] In one embodiment, the flexible substrate is made of polyimide or polyetherketone (PEEK), and the film thickness is between 25 and 100 microns.

[0071] In an alternative embodiment, the flexible substrate is made of fluorinated ethylene polymers (FEP), polycarbonate, polyethylene or other polymer suitable for use in the space, titanium, aluminium or other metal material, graphite, CFPR or other composite material, ultra-thin flexible glass.

[0072] The substrate acts only as a flexible support for the coating and no longer needs to be optically transparent. This allows the FEP used in known flexible SSMs to be replaced by other types of polymer that are cheaper and easier to coat.

[0073] In one embodiment, the surface of the flexible substrate not coated with the multilayer coating of the invention is metallised and the electrical contact between the surface of the optical solar reflector facing outwards and the surface facing towards the surface to be coated is determined through a path of small through holes (the so-called perforated interconnections).

[0074] FIG. 2 shows an exemplary embodiment of a solar radiator 100 incorporating a flexible optical solar reflector 5 according to the invention.

[0075] In particular, the flexible optical solar reflector 5 is applied to the outer surface (skin) 6 of the solar radiator 100 by means of a layer of pressure sensitive adhesive 7.

[0076] The flexible optical solar reflector 5 comprises a first outer portion consisting of the multilayer coating 1 deposited on a polymer sheet 9. The surface of the polymer film facing towards the skin 6 of the radiator 100 is coated with a metal layer 8 which is then in contact with the adhesive layer 7.

[0077] The flexible optical solar reflector according to the invention combines the ease of use and applicability on either flat or curved surfaces typical of the flexible SSMs with the thermo-optical properties and spatial durability of the quartz OSRs, which make it suitable for application on devices involved in 15-year missions in orbit. Furthermore, the overall cost for an optical solar reflector according to the invention is similar to that of a flexible OSR known in the art but much lower than that of a quartz OSR.

[0078] The multilayer coating of the invention preferably has a hemispherical emissivity between 0.1 and 0.8.