ELECTROLYTIC CELL, METHOD FOR OPERATING A CELL OF THIS TYPE AND ELECTROLYSER

Abstract

An electrolytic cell may include a cathode half-cell having a cathode, an anode half-cell having an anode, and a separator that separates the two half-cells from one another and that is permeable to electrolyte present in the half-cells during operation. At least one inlet for electrolyte is provided in a first half-cell of the two half-cells, and at least one outlet for electrolyte and no inlet for electrolyte are provided in the second half-cell such that electrolyte supplied via the at least one inlet is dischargeable via the at least one outlet after passing through the separator. A method can also be utilized to operate such an electrolytic cell. And an electrolyzer may include multiple of such electrolytic cells.

Claims

1.-11. (canceled)

12. An electrolytic cell comprising: a cathode half-cell having a cathode; an anode half-cell having an anode; and a separator that separates the two half-cells from one another and that is permeable to electrolyte present in the two half-cells during operation, wherein a first half-cell of the two half-cells includes an inlet for electrolyte and wherein a second half-cell of the two half-cells includes an outlet for the electrolyte and is free of any inlet for electrolyte such that electrolyte supplied via the inlet is dischargeable via the outlet after passing through the separator, wherein the electrolytic cell is configured to perform alkaline water electrolysis, wherein the cathode half-cell is the first half-cell that includes the inlet for electrolyte and the anode half-cell is the second half-cell that includes the outlet for electrolyte.

13. The electrolytic cell of claim 12 comprising a gas separator configured to separate a product gas from electrolyte in at least one of the two half-cells, wherein the gas separator is connected to an electrolyte return that is configured to return electrolyte that has entered the gas separator to the respective half-cell.

14. The electrolytic cell of claim 13 wherein the electrolyte return is disposed inside the at least one of the two half-cells.

15. An electrolyzer comprising electrolytic cells that are electrically connected in series and hydraulically connected in parallel in an electrolyte circuit, wherein each of the electrolytic cells is configured to perform alkaline water electrolysis and comprises: a cathode half-cell having a cathode; an anode half-cell having an anode; and a separator that separates the two half-cells from one another and that is permeable to electrolyte present in the two half-cells during operation, wherein a first half-cell of the two half-cells includes an inlet for electrolyte and wherein a second half-cell of the two half-cells includes an outlet for the electrolyte and is free of any inlet for electrolyte such that electrolyte supplied via the inlet is dischargeable via the outlet after passing through the separator, wherein the cathode half-cell is the first half-cell that includes the inlet for electrolyte and the anode half-cell is the second half-cell that includes the outlet for electrolyte.

16. The electrolyzer of claim 15 wherein the electrolyte circuit is the sole electrolyte circuit for supplying electrolyte to the cathode half-cells and the anode half-cells, wherein the electrolyzer and the separator are configured such that electrolyte is supplied to the anode half-cells through the separator.

17. The electrolyzer of claim 15 comprising means for generating a positive pressure by way of which a positive pressure is appliable to the cathode half-cells relative to the anode half-cells.

18. A method for operating the electrolytic cell of claim 12, the method comprising: connecting the inlet and the outlet to an electrolyte circuit that is closed via the separator and filling the two half-cells with electrolyte; starting an electrolysis process by closing an electrical circuit via the cathode and the anode of the electrolytic cell and an external power source; discharging, during the electrolysis process, product gas formed in the two half-cells; and applying to the first half-cell, during the electrolysis process, a positive pressure compared to the second half-cell to promote passage of electrolyte through the separator.

19. The method of claim 18 wherein the electrolytic cell comprises a gas separator configured to separate a product gas from electrolyte in at least one of the two half-cells, wherein the gas separator is connected to an electrolyte return that is configured to return electrolyte that has entered the gas separator to the respective half-cell, the method comprising returning electrolyte that has entered the gas separator to the respective half-cell.

Description

[0029] The invention is described below on the basis of exemplary embodiments with reference to the accompanying drawings. In the figures:

[0030] FIG. 1: shows a schematic representation of an already known electrolytic cell having an electrolyte inlet and outlet for each half-cell and a permeable separator,

[0031] FIG. 2: shows a schematic representation of an electrolytic cell according to the invention having an electrolyte inlet and outlet for each electrolytic cell and a separator permeable to the electrolyte,

[0032] FIG. 3: shows a schematic representation of an electrolytic cell according to the invention with an internal return of the electrolyte recovered in the gas separator, and

[0033] FIG. 4: shows a schematic representation of an electrolytic cell according to the invention with an external return of the electrolyte recovered in the gas separator,

[0034] FIG. 5: shows a schematic representation of an electrolyzer according to the invention having a multiplicity of electrolytic cells according to the invention that are hydraulically connected in parallel in an electrolyte circuit.

[0035] In the various figures, identical parts are always provided with the same reference signs and are therefore also generally each named or mentioned only once.

[0036] FIG. 1 shows a classic electrolytic cell which has an anolyte circuit and a catholyte circuit, i.e., comprises an inlet and outlet for each half-cell. The permeable separator separates the two half-cells from one another, said separator being permeable to ions in order to close the circuit. During electrolysis, product gases rise and entrain droplets of the electrolyte, the respective electrolytes being separated from the respective product gases in the gas separators.

[0037] An electrolytic cell 1 shown in FIG. 1 comprises two electrolyte circuits—one for each half-cell 2, 3—with a total of four pipelines for inlets 4, 5 and outlets 6, 7 for processed or consumed electrolyte 8. This results in a high degree of technical complexity, especially the installation of pipelines. Not only does this drive up the production costs and the complexity of the system, but the multiplicity of pipelines also causes a high degree of stray currents, which lower the efficiency of the electrolytic cell and which moreover lead to undesired corrosion.

[0038] A preferred embodiment of the electrolytic cell 1 according to the invention that is depicted in FIG. 2 comprises a separator 9 permeable to electrolyte 8, and also, in the first of the two half-cells 2 besides an electrode 10, an inlet for electrolyte 4 and, in the second half-cell 3 besides an electrode 11, at least one outlet 7 for electrolyte 8 and no inlet for electrolyte 8. This means that electrolyte 8 supplied via the one inlet 4 is dischargeable via the at least one outlet 7 after passing through the separator 9. With regard to the already known electrolytic cell 1, this means that the function of the outlet 6 of one of the half-cells 2 and the function of the inlet 5 of the other half-cell 3 have been taken over by the separator 9 permeable to electrolyte 8. This not only significantly lowers the number of electrolyte circuits or necessary pipelines, but also achieves a reduction in stray currents. This in turn advantageously leads to a reduction in secondary reactions and corrosion.

[0039] In the case of the electrolytic cell 1 according to the invention that is depicted in FIG. 2, a positive pressure compared to the second half-cell is applied to the first half-cell 2 during the electrolysis process in order to promote the passage of the electrolyte 8 through the separator 9. This significantly raises the throughput of the electrolytic cell 1 relative to a flow of electrolyte 8 through the separator 9 that is not driven by the pressure conditions in the half-cells 2, 3. Moreover, the separator 9 permeable to electrolyte 8 guarantees separation of the different product gases, which, for example, is necessary in water electrolysis to avoid an oxyhydrogen reaction.

[0040] Preferably, the first half-cell 2 forms the cathode half-cell and the second half-cell 3 forms the anode half-cell, and so the inlet 4 for electrolyte 8 is provided in the cathode half-cell 2 and the outlet 7 for electrolyte 8 is provided in the anode half-cell 3.

[0041] The separator 9 is preferably hydrophilic. The separator can, for example, be made of zirconium oxide. The separator 9 preferably has a permeability in the range from 17 to 175 liters of electrolyte 8 per hour per square meter of active separator surface at a pressure difference between the two half-cells 2, 3 of up to 500 mbar.

[0042] According to one development of the electrolytic cell 1 according to the invention that is depicted in FIG. 3, product gas and electrolyte 7 are separated in a gas separator 12 of the first half-cell 2, the recovered electrolyte 8 being returned to the electrolyte reservoir through an internal return line 13. In the context of the electrolytic cell according to the invention, the gas separator(s) can alternatively also be realized in a functional unit with the electrolyte outlet. Owing to the return of the electrolyte 8, electrolyte consumption can be significantly reduced, thereby also making it possible to reduce the operating costs. The advantage of the internal return lies in a compact, space-saving design.

[0043] FIG. 4 shows one development of the electrolytic cell 1 according to the invention that is an alternative to FIG. 3, in which the return of the electrolyte 8 obtained in the gas separator 12 is realized as an external return with an external return line 14 and a second inlet 15. Such a return configuration does not impair the rise of product gas. Likewise, the return line 14 can be directly connected to the inlet 4, thereby limiting the number of necessary inlets to one.

[0044] FIG. 5 shows an electrolyzer having a multiplicity of electrolytic cells 1 according to the exemplary embodiment in FIG. 2 that are hydraulically connected in parallel in an electrolyte circuit. The electrolytic cells 1 are electrically connected in series (not depicted).

[0045] The electrolyzer 100 depicted in FIG. 5 comprises only one electrolyte circuit for supplying electrolyte 8 to the cathode half-cells 2 and the anode half-cells 3. Electrolyte 8 is supplied to the anode half-cells 3 as a result of the electrolyte 8 passing through the separator 9. Particularly preferably, the electrolyte circuit is designed in such a way that the entire circulating electrolyte 8 is conducted through the separators 9 of the electrolyzer 100.

[0046] Starting from an electrolyte processing device 110, the electrolyte 8 is hydraulically supplied in parallel to the respective cathode half-cells 2 via an inflow distributor 120. Inside the electrolytic cells 1, the electrolyte 8 passes through the separator 9 to supply the anode half-cells 3 with electrolyte 8. The electrolyte 8 leaves the anode half-cells 3 via the outlet 7 and is returned to the electrolyte processing device 110 via a return collector 130.

[0047] The electrolyzer 100 further comprises means for generating a positive pressure 150, by means of which a positive pressure is appliable to the cathode half-cells 2 in relation to the anode half-cells 3. In the example shown in FIG. 5, the means for generating a positive pressure 150 are formed by adjustable pressure control valves in the gas discharge lines 140 for the product gases. As a result, it is possible for the pressures p0 and p1 in the cathode half-cells 2 and the anode half-cells 3, respectively, to be adjusted separately from one another in order to achieve a desired pressure drop. In principle, it is also possible to provide a pressure control valve only in the gas discharge line of the cathode half-cells 2 and to operate the anode half-cells 3 at ambient pressure. A pressure difference of less than 500 mbar is preferably set between the cathode half-cells 2 and the anode half-cells 3, particularly preferably less than 100 mbar.

[0048] The electrolytic cells 1 shown in FIG. 3 or 4 can also be connected together to form an electrolyzer in an analogous manner to FIG. 5. Therefore, all discussions relating to FIGS. 2 to 4 apply accordingly to the electrolytic cells 1 of the electrolyzer 100.

LIST OF REFERENCE SIGNS

[0049] 1 Electrolytic cell [0050] 2 First half-cell [0051] 3 Second half-cell [0052] 4 Inlet for electrolyte [0053] 5 Inlet for electrolyte [0054] 6 Outlet for electrolyte [0055] 7 Outlet for electrolyte [0056] 8 Electrolyte [0057] 9 Separator [0058] 10 Electrode [0059] 11 Electrode [0060] 12 Gas separator [0061] 13 Internal return line for electrolyte [0062] 14 External return line for electrolyte [0063] 15 Inlet for electrolyte [0064] 100 Electrolyzer [0065] 110 Electrolyte processing device [0066] 120 Inflow distributor [0067] 130 Return collector [0068] 140 Gas discharge [0069] 150 Means for generating a positive pressure