METHODS AND SYSTEMS FOR CAPTURING AND STORING CARBON DIOXIDE

Abstract

Methods and systems for capturing and storing carbon dioxide are disclosed. In some embodiments, the methods include the following: mixing materials including magnesium or calcium with one or more acids and chelating agents to form a magnesium or calcium-rich solvent; using the organic acids derived from biogenic wastes as acids or chelating agents; generating carbonate ions by reacting a gas including carbon dioxide with a carbonic anhydrase biocatalyst; reacting the solvent with the carbonate ions to form magnesium or calcium carbonates; recycling a solution containing the biocatalyst after forming magnesium or calcium carbonates for re-use in the generating step; using the magnesium and calcium carbonates as carbon neutral filler materials and using the silica product as green filler materials or inexpensive absorbents.

Claims

1. A method of capturing and storing carbon dioxide, said method comprising: mixing materials including magnesium or calcium with at least one of one or more acids and chelating agents to form a magnesium or calcium-rich solvent; generating carbonate ions by reacting a gas including carbon dioxide with a biocatalyst; and reacting said solvent with said carbonate ions to form magnesium or calcium carbonates.

2. The method according to claim 1, further comprising: recycling a solution containing said biocatalyst after forming said magnesium or calcium carbonates for re-use in said generating step.

3. The method according to claim 1, wherein said biocatalyst is a carbonic anhydrase.

4. The method according to claim 3, wherein said carbonic anhydrase is one of the enzymes Cam or Cab.

5. The method according to claim 3, wherein said carbonic anhydrase is a whole cell that expresses one of the enzymes Cam or Cab.

6. The method according to claim 1, wherein said magnesium or calcium materials include at least one of magnesium or calcium bearing minerals and industrial wastes.

7. The method according to claim 1, wherein said magnesium or calcium carbonates are formed so as to mimic a particular structure of calcium carbonate.

8. The method according to claim 1, wherein said silica product is formed so as to mimic a particular structure of precipitated silica or fume silica.

9. The method according to claim 1, wherein said one or more chelating agents in acidic form include at least one of ethylenediaminetetraacetic acid (EDTA), acetic acid, ascorbic acid, (ortho) phosphoric acid, oxalic acid, citric acid, succinic acid, valeric acid, glutamic acid, gluconic acid, IDA, and NTA for magnesium and calcium leaching, and one or more chelating agents including catechol, guanidine, imidazole, histidine, and arginine targeting silica layer, and a combination thereof.

10. The method according to claim 9, wherein at least one of said one or more acids and chelating agents is produced from biogenic wastes.

11. The method according to claim 1, wherein a pH in said reactor is from about 7.5 to about 10.

12. The method according to claim 1, wherein a solid silica material having surface area greater than 200 m/g remains after magnesium is extracted from said minerals to form said solvent.

13. The method according to claim 1, wherein said gas is one of a syngas produced from the gasification of carboneous fuel, a flue gas produced from combusting a carbonaceous fuel, a gas stream from steel manufacturing process, and a combination thereof.

14. A system for capturing and storing carbon dioxide, said system comprising: a dissolution reactor for mixing materials including magnesium or calcium with at least one of one or more acids and one or more catalysts to form a magnesium or calcium-rich solvent; a first stream including magnesium or calcium in fluid communication with said dissolution reactor; a second stream including at least one of one or more acids and one or more catalysts in fluid communication with said dissolution reactor; a combined biocatalyst and carbonation reactor in fluid communication with said dissolution reactor for reacting a gas including carbon dioxide with a biocatalyst to form carbonate ions and for reacting said carbonate ions with said magnesium or calcium-rich solvent to form magnesium or calcium carbonates; a biocatalyst source stream in fluid communication with said combined biocatalyst and carbonation reactor; a gas source stream, said gas source stream including carbon dioxide, in fluid communication with said combined biocatalyst and carbonation reactor; a magnesium or calcium-rich solvent stream in fluid communication with said dissolution reactor and said combined biocatalyst and carbonation reactor; a magnesium or calcium carbonate product stream exiting said combined biocatalyst and carbonation reactor; a liquid-solid separator to produce silica product, said liquid-solid separator in fluid communication with said dissolution reactor; a heat source in communication with said dissolution reactor, said heat source being configured to heat said dissolution reactor thereby increasing a temperature inside said dissolution reactor; and a control module for controlling said heat source.

15. The system according to claim 14, further comprising: a biocatalyst recycle stream; and a biocatalyst recycle module positioned to direct said biocatalyst recycle stream to said combined biocatalyst and carbonation reactor after forming magnesium or calcium carbonates in said combined biocatalyst and carbonation reactor for re-use in said combined biocatalyst and carbonation reactor.

16. The system according to claim 14, further comprising: a carbonate ion recycle stream; and a carbonate ion recycle module positioned to direct said carbonate ion recycle stream to said combined biocatalyst and carbonation reactor after forming magnesium or calcium carbonates in said combined biocatalyst and carbonation reactor for re-use in said combined biocatalyst and carbonation reactor.

17. The system according to claim 14, wherein said biocatalyst is a carbonic anhydrase in the form of one of the enzymes Cam or Cab or in the form of a whole cell that expresses one of the enzymes Cam or Cab.

18. The system according to claim 14, wherein said one or more acids and chelating agents in acidic forms include at least one of ethylenediaminetetraacetic acid (EDTA), acetic acid, ascorbic acid, (ortho) phosphoric acid, oxalic acid, citric acid, succinic acid, valeric acid, glutamic acid, gluconic acid, IDA, and NTA for magnesium and calcium leaching, and one or more chelating agents including catechol, guanidine, imidazole, histidine, and arginine targeting silica layer, and a combination thereof.

19. The system according to claim 14, further comprising: a pH control module in fluid communication with said combined biocatalyst and carbonation reactor, said pH control module including a supply of basic material for increasing pH in said combined biocatalyst and carbonation reactor.

20. A method of capturing and storing carbon dioxide, said method comprising: mixing materials including magnesium or calcium with one or more acids to form a magnesium or calcium-rich solvent; generating carbonate ions by reacting a gas including carbon dioxide with a carbonic anhydrase biocatalyst; reacting said solvent with said carbonate ions to form magnesium or calcium carbonates; and recycling a solution containing said biocatalyst after forming magnesium or calcium carbonates for re-use in said generating step; wherein said carbonic anhydrase biocatalyst is one of the enzymes Cam or Cab or a whole cell that expresses one of the enzymes Cam or Cab.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0009] The drawings show embodiments of the disclosed subject matter for the purpose of illustrating the invention. However, it should be understood that the present application is not limited to the precise arrangements and instrumentalities shown in the drawings, wherein:

[0010] FIG. 1 is a schematic diagram of methods and systems according to some embodiments of the disclosed subject matter;

[0011] FIG. 2 is a schematic diagram of methods and systems according to some embodiments of the disclosed subject matter;

[0012] FIG. 3 is a schematic diagram of methods and systems according to some embodiments of the disclosed subject matter; and

[0013] FIG. 4 is a chart of a method according to some embodiments of the disclosed subject matter.

DETAILED DESCRIPTION

[0014] Referring now to FIG. 1, aspects of the disclosed subject matter include a system 100 for capturing and storing carbon dioxide 102. In some embodiments, system 100 includes a mineral dissolution reactor 104, a combined biocatalyst and carbonation reactor 106, and a control module 108.

[0015] Dissolution reactor 104 is configured for mixing materials 110 including magnesium or calcium, e.g., serpentine, olivine, basalt, labradorite, or similar including industrial wastes such as stainless steel slags, with at least one of one or more acids 112 and one or more catalysts or chelating agents 114 to form a magnesium or calcium-rich solvent 116.

[0016] Combined biocatalyst and carbonation reactor 106 is in fluid communication with dissolution reactor 104. In some embodiments, reactor 106 includes a first chamber 118 for reacting a gas 120 including carbon dioxide 102 with a biocatalyst 122 to form carbonate ions 124 and a second chamber 126 for reacting the carbonate ions with magnesium or calcium-rich solvent 116 to form magnesium or calcium carbonate 128. A first semi-porous distributor plate 130 separates first and second chambers 118 and 126, respectively, and a second and semi-porous distributor plate 132 separates first chamber 118 from a cleaned gas outlet 134.

[0017] Still referring to FIG. 1, system 100 includes a heat source 136 in fluid communication with dissolution reactor 104, which is configured to heat the dissolution reactor thereby increasing a temperature inside the reactor.

[0018] System 100 includes a carbonate ion recycle module 138 in fluid communication with combined biocatalyst and carbonation reactor 106 for recycling a solution 140 containing carbonate ions 124 after forming magnesium or calcium carbonates 128 in the reactor for re-use in the reactor.

[0019] In some embodiments, system 100 includes a biocatalyst recycle module (not shown) in fluid communication with combined biocatalyst and carbonation reactor 106 for recycling a solution containing biocatalyst 122 after forming magnesium or calcium carbonates 128 in the reactor for re-use in the reactor.

[0020] Still referring to FIG. 1, in some embodiments, system 100 includes a pH control module 142 in fluid communication with combined biocatalyst and carbonation reactor 106. pH control module 142 includes a supply of basic material, e.g., sodium hydroxide, ammonium hydroxide, or similar, for increasing pH in combined biocatalyst and carbonation reactor 106.

[0021] Control module 108 is used to control various valves, pumps, gauges (not shown) that control the flow of gas 120, biocatalyst 122, bearing materials 110 including magnesium or calcium, one or more acids 112, and one or more catalysts or chelating agents 114 to dissolution reactor 104 and combined biocatalyst and carbonation reactor 106. Control module 108 also controls heat source 136 and pH control module 142. Control module 108 typically includes both wired and wireless components.

[0022] In some embodiments, system 100 includes one or more liquid solids separators. Magnesium or calcium carbonates 128, which are formed, are either disposed of, e.g., in a reclaimed mine, etc., and/or used to make useful products such as fillers and/or construction materials.

[0023] In some embodiments, system 100 includes one or more liquid solids separators. Silica products from magnesium or calcium-rich solvent 116, which are reaction byproducts, are either disposed of, e.g., in a reclaimed mine, etc., and/or used to make useful products such as fillers and/or construction materials.

[0024] Referring now to FIG. 2, in some embodiments, a system 100′ includes a biocatalyst reactor 144 that is separate and independent from a carbonation reactor 146. In some embodiments, reactor 144 is a bubble column. System 100′ is otherwise substantially the same as system 100 as indicated by like element numbers.

[0025] Referring now to FIG. 3, in some embodiments, a system 100″ includes a combined biocatalyst and carbonation reactor 148 that has a single chamber 150. System 100″ is otherwise substantially the same as systems 100 and 100′ as indicated by like element numbers.

[0026] Referring now to FIG. 4, some embodiments of the disclosed subject matter include a method 200 of capturing and storing carbon dioxide. At 202, materials including magnesium or calcium, e.g., serpentine, olivine, basalt, labradorite, industrial wastes, or similar, are mixed with one or more acids and/or chelating agents to form a magnesium or calcium-rich solvent. Examples of the one or more chelating agents in acidic forms include at least one of ethylenediaminetetraacetic acid (EDTA), acetic acid, ascorbic acid, (ortho) phosphoric acid, oxalic acid, citric acid, succinic acid, valeric acid, glutamic acid, gluconic acid, IDA, and NTA for magnesium and calcium leaching, and one or more chelating agents including catechol, guanidine, imidazole, histidine, and arginine targeting silica layer, and a combination thereof. A number of organic acids that can be used as chelating agents are produced from biogenic wastes.

[0027] At 204, carbonate ions are generated by reacting a gas including carbon dioxide with a biocatalyst. Typically, the gas is a syngas produced from the gasification of carboneous fuel, a flue gas produced from combusting a carbonaceous fuel, a gas produced during steel manufacturing process, or a combination thereof. In some embodiments, the biocatalyst is a carbonic anhydrase such as one of the enzymes Cam or Cab. In some embodiments, the carbonic anhydrase is a whole cell that expresses one of the enzymes Cam or Cab.

[0028] At 206, the magnesium or calcium-rich solvent is reacted with the carbonate ions to form magnesium or calcium carbonates. In some embodiments, the various constituents i.e., the materials including magnesium or calcium, e.g., magnesium or calcium-bearing minerals or industrial wastes, the composition of the solvent, the reaction catalysts, and the particular biocatalyst, and the reaction time of those constituents, are selected so that the magnesium or calcium carbonates formed mimic a particular structure of calcium carbonate, e.g., one used commercially as a filler product. In some embodiments, a solid silica material having a surface area >200 m.sup.2/g remains after the magnesium is extracted from the mineral. Another source of Si product would be the precipitated silica from the process water. The silica products mimic precipitate silica or fume silica and are used as filler materials for rubber, green tires, adhesives, sealants, pharmaceuticals, cosmetics, paints, plastics, etc. They can also be used as inexpensive absorbents. In some embodiments, the pH in the reactor is maintained at about 7.5 to about 10 during the reaction between the solvent and the carbonate. In some embodiments, the reaction between the solvent and the carbonate ions is carried out to form the magnesium or calcium carbonates.

[0029] At 208, a solution containing the biocatalyst is recycled after forming magnesium or calcium carbonates for re-use at 204.

[0030] Methods and systems according to the disclosed subject matter offer benefits and advantages over known technology. Mineralization is especially promising because it combines capture and storage into a single step, eliminating the need for regeneration of the absorbing material, and because the solids generated containing magnesium, calcium, or silica are useful for other applications.

[0031] Methods and systems according to the disclosed subject matter allow for tailoring the structure of precipitate magnesium carbonate (MgCO3) to mimic commercially-available CaCO3-based materials, while sequestering carbon dioxide. Thus, a commercially-useful, carbon-neutral material is generated. The silica products are tailored for applications such as filler materials for rubber, green tires, adhesives, sealants, pharmaceuticals, cosmetics, paints, plastics, etc. They can also be used as inexpensive absorbents.

[0032] Using engineered biological catalysts, i.e., carbonic anhydrase, methods and systems according to the disclosed subject matter enhance the hydration of gaseous carbon dioxide and reduce the required pH for the reaction, from greater than about 9.6 to about 8.

[0033] Unlike Ca-based carbon dioxide capture using Ca-based sorbent derived from limestone, technology according to the disclosed subject matter does not require sorbent regeneration. Once carbon dioxide is captured, there is in the form that can be directly stored long term. By capturing and storing and storing carbon dioxide directly from flue gas, technology according to the disclosed subject matter improves the overall sustainability.

[0034] Technology according to the disclosed subject matter utilizes unpurified carbonic anhydrase. Generally, the cost of enzymes is expensive due to the separation and purification processes. Because in methods and systems according to the disclosed subject matter, whole cells are used for carbon dioxide hydration, the overall cost of the technology is also lowered. The particle size and morphological structure of magnesium or calcium carbonates can also be engineered to mimic those of precipitated calcium carbonates, which are currently used as filler materials.

[0035] Although the disclosed subject matter has been described and illustrated with respect to embodiments thereof, it should be understood by those skilled in the art that features of the disclosed embodiments can be combined, rearranged, etc., to produce additional embodiments within the scope of the invention, and that various other changes, omissions, and additions may be made therein and thereto, without parting from the spirit and scope of the present invention.