TRANSPARENT PANE WITH AN ELECTRICAL HEATING LAYER AND PRODUCTION METHOD THEREOF
20170339750 · 2017-11-23
Assignee
Inventors
Cpc classification
H05B3/84
ELECTRICITY
H05B2203/014
ELECTRICITY
H05B2203/031
ELECTRICITY
H05B2203/005
ELECTRICITY
B23K2101/36
PERFORMING OPERATIONS; TRANSPORTING
International classification
H05B3/84
ELECTRICITY
Abstract
A transparent pane is described, having an electrical heating layer extending at least over part of the pane surface and divided into a main heating region and an additional heating region electrically insulated therefrom. The transparent pane has connection means, which can be electrically connected to a voltage source and which has at least a first collecting conductor and a second collecting conductor. The collecting conductors are each electrically connected to the heating layer in the main heating region in direct contact such that upon application of a supply voltage, a heating current flows across a heating field formed by the heating layer. The transparent pane has at least one electrical line heating element, which is arranged, at least in sections, in the additional heating region of the heating layer.
Claims
1.-18. (canceled)
19. A transparent pane comprising: an electrical heating layer extending at least over a part of a pane surface, and being divided into a main heating region and an additional heating region electrically insulated from the main heating region, a connection means, configured to be electrically connected to a voltage source, wherein the connection means comprises a first collecting conductor and a second collecting conductor, wherein the first and second collecting conductors are electrically connected to the electrical heating layer in direct contact with the main heating region such that, upon application of a supply voltage, a heating current flows across a heating field formed by the electrical heating layer, and at least one electrical line heating element, arranged, at least in sections, in the additional heating region of the electrical heating layer, wherein the line heating element is in direct contact with and electrically connected to the heating layer, the line heating element is configured to be electrically connected to the voltage source or to another voltage source, the line heating element has an ohmic resistance for heating the additional heating region upon application of the supply voltage, and the line heating element is configured such that, upon application of the supply voltage, a heating current can flow between sections of the line heating element through the heating layer in the additional heating region, the additional heating region being configured for being additionally heated.
20. The pane according to claim 19, wherein the line heating element is electrically connected to the connection means in a parallel electrical connection with the heating field.
21. The pane according to claim 20, wherein at least one connection conductor is electrically connected to the line heating element and at least one of the connection means.
22. The pane according to claim 21, wherein the connection conductors are arranged, at least in regions, in a heating-layer-free edge strip of the pane and/or at least in regions in a heating-layer-free separating region between the main heating region and the additional heating region.
23. The pane according to claim 20, wherein at least one connection of the line heating element is in direct electric contact with one of the collecting conductors.
24. The pane according to claim 20, wherein the connection means comprises one or more connecting conductors connected to the first and second collecting conductors and wherein at least one connection of the line heating element is in direct electrical contact with at least one of the connecting conductors.
25. The pane according to claim 20, wherein the line heating element and/or the connection conductor are a heating wire or a heating line made of a printed-on electrically conductive paste.
26. The pane according to claim 25, wherein the heating line has a thickness of 6 μm to 14 μm, a width of 0.2 mm to 8 mm, a length of 1000 mm to 10000 mm, and/or a specific resistance of 0.5*10.sup.−8 ohm*m to 5*10.sup.−8 ohm*m.
27. The pane according to claim 25, wherein the line heating element is configured such that when the supply voltage is in a range from 12 to 48 V, a deicing power in a range from 400 to 1000 W/m.sup.2 of pane surface is available.
28. The pane according to claim 25, wherein the line heating element has an ohmic resistance of 0.5 ohm/m to 4 ohm/m.
29. The pane according to claim 25, wherein the line heating element is meander-shaped and not rectangular.
30. The pane according to claim 25, wherein the line heating element is trapezoidal.
31. The pane according to claim 30, wherein a sum of bases is less than or equal to the half of the periodic interval.
32. The pane according to claim 25, wherein the line heating element has a periodic course and within a period, sections of the line heating element are arranged nonparallel and non-antiparallel to one another.
33. The pane according to claim 25, wherein the line heating element has a periodic course and within a period, sections which are arranged nonparallel to the direction of the current flow through the heating layer are arranged nonparallel and non-antiparallel to one another.
34. The pane according to claim 25, wherein the line heating element has a periodic course and within a period, a distance between the section of the line heating element before a reversal point or before a reversal region and the section of the line heating element after the reversal point or after a reversal region decreases continuously.
35. The pane according to claim 19, wherein the pane is a composite pane comprising two individual panes bonded to one another by a thermoplastic adhesive layer, wherein the heating layer is situated on at least one surface of the two individual panes and/or on one surface of a carrier arranged between the two individual panes.
36. A method for producing a transparent pane, comprising the steps of: a) depositing an electrical heating layer on at least one part of a pane surface, b) dividing the electrical heating layer into a main heating region and an additional heating region electrically insulated from the main heating region, c) applying at least one first collecting conductor and one second collecting conductor on the electrical heating layer in the main heating region, wherein the first and second collecting conductors are in direct contact with and electrically connected to the electrical heating layer, such that upon application of a supply voltage from a voltage source on connecting means connectable to the first and second collecting conductors, a heating current can flow across a heating field formed by the heating layer, d) applying at least one electrical line heating element, at least in sections, on the heating layer in the additional heating region, wherein the line heating element is in direct contact with and electrically connected to the heating layer, the line heating element is configured to be electrically connected to the connecting means in parallel electrical connection with the heating field or is configured to be electrically connected to the first and second collecting conductors of the heating layer in the main heating region, the line heating element has an ohmic resistance for heating the additional heating region, upon application of the supply voltage, and the line heating element is configured such that after application of the supply voltage between sections of the line heating element, a heating current can flow through the heating layer in the additional heating region, the additional heating region being configured for being additionally heated, e) applying at least one connection conductor on the pane surface, wherein the line heating element is connected to the first and second collecting conductors and/or connected to the connecting means, f) applying the connecting means on the pane surface wherein the connecting means is in direct contact with and electrically connected to the first and second collecting conductors, the line heating element, and/or the at least one connection conductor.
37. The method for producing a transparent pane according to claim 36, wherein the first and second collecting conductors, the line heating element, and the at least one connection conductor are applied by screen printing an electrically conductive paste onto the pane surface.
38. A method comprising: using the transparent pane according to claim 19 as a functional and/or decorative single piece, as an assembly part in furniture, appliances, or buildings, or as a windshield, rear window, side window, and/or glass roof in a means of transportation for travel on land, in the air, or on water, wherein a resting or parking zone of windshield wipers provided to wipe the pane is arranged in the additional heating region of the pane.
39. The pane according to claim 29, wherein the line heating element is sinusoidal or triangular.
40. The method according to claim 36, wherein c), d), and e) are performed simultaneously.
41. The method according to claim 36, comprising dividing the electrical heating layer into a main heating region and an additional heating region by laser ablation.
Description
[0052] The invention is now explained in detail using exemplary embodiments with reference to the accompanying figures. They depict in simplified, not-true-to-scale representation:
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[0070] The contour of the windshield 1 is defined by a pane edge 5, which is composed, according to the trapezoidal shape, of two long pane edges 5a, 5a′ (top and bottom in the installed position) and two short pane edges 5b, 5b′ (left and right in the installed position). A transparent heating layer 6 serving for electrical heating of the windshield 1 is deposited on the side of the inner pane 3 (“side III”) bonded to the adhesive layer 4. The heating layer 6 is applied substantially to the entire surface of the inner pane 3, with a peripheral edge strip 7 on all sides of the inner pane 3 not coated such that a heating layer edge 8 is set back inwardly relative to the pane edge 5 by a width r. The width r is, for example, 10 mm. This measure serves for electrical isolation of the heating layer 6 relative to the outside. In addition, the heating layer 6 is protected against moisture penetrating from the pane edge 5, which can otherwise result in corrosion of the heating layer 6.
[0071] In a manner known per se, the heating layer 6 comprises a layer sequence with at least one electrically conductive metallic sublayer, preferably silver, and, optionally, other sublayers such as antireflective and blocker layers. Advantageously, the layer sequence has high thermal stability such that it withstands the high temperatures required for the bending of glass panes of typically more than 600° C. without damage, but also with the possibility of providing layer sequences with low thermal stability. Instead of being applied directly on the inner pane 3, it could also, for example, be applied on a plastic film that is subsequently bonded to outer and inner pane 2, 3. The heating layer 6 is, for example, applied by sputtering (magnetron cathodic sputtering). The sheet resistance of the heating layer 6 is, for example, in the range from 0.1 to 6 ohm/unit area.
[0072] The heating layer 6 is electrically conductively connected to a first collecting conductor 10 and to a second collecting conductor 11 in direct contact. The two collecting conductors 10, 11 are in each case implemented band-shaped or strip-shaped and serve as connection electrodes for the broad introduction of a supply current into the heating layer 6. For this, the collecting conductors 10,11 are, for example, arranged over their full band length on the heating layer 6, with the first collecting conductor 10 extending along the upper long pane edge 5a and the second collecting conductor 11 extending roughly along the lower long pane edge 5a′. The two collecting conductors 10, 11 are made, for example, from the same material and can be produced, for example, by printing a paste onto the heating layer 6, for example, by the screen printing method. Alternatively, however, it would also be possible to produce the collecting conductors 10, 11 from narrow metal foil strips, for example, made of copper or aluminum. These can, for example, be fixed on the adhesive layer 4 and arranged on the heating layer 6 at the time of the bonding of the outer and inner pane 2, 3. Electrical contact can be guaranteed during the bonding of the individual panes by the action of heat and pressure.
[0073] A first connecting conductor 12, which is implemented here, for example, as a flat-band conductor (e.g., narrow metal foil), is electrically connected to the first collecting conductor 10. The connecting conductor 12 has, for example, a first external connection 20, which is provided for the connection to one pole (for example, the minus pole) of a voltage source 25 for providing a supply voltage. The first connecting conductor 12 is arranged roughly in the center of the upper long pane edge 5a. A second connecting conductor 13, which is likewise implemented here, for example, as a flat-band conductor (e.g., narrow metal foils), is electrically connected to the second collecting conductor 11, and has a second external connection 21′, which is provided for the connection to the other pole (for example, the plus pole) of the voltage source 25. The connecting conductors 12,13 are, for example, provided with a plastic insulation sheath, preferably made of polyimide, and thus electrically insulated in order to avoid a short-circuit with other electrically conductive and/or voltage-carrying structures in the pane 1.
[0074] A heating field 17, in which a heating current 16 flows upon application of a supply voltage, is enclosed by the two collecting conductors 10, 11. Due to negligible ohmic resistance compared to the heating layer 6, the collecting conductors 10, 11 heat up only a little and make no appreciable contribution to the heating power. It is understood that the ohmic resistance of the collecting conductors 10,11 can also be selected such that selective heating of pane regions by the collecting conductors 10,11 is enabled.
[0075] As has already been explained in the introduction, the connection resistance of the heating layer 6 increases with the length of the current paths of the heating current 16 such that it is advantageous in terms of satisfactory heating power for the two collecting conductors 10, 11 to have the smallest possible distance between them. For this reason, it makes sense to implement a lower pane region, which is no longer part of the field of vision, but corresponds to the region of a resting or parking position of windshield wipers provided for wiping the pane, as an additional heating region 14, which is electrically isolated from the main heating region 9. Nevertheless, the heating layer 6, which is, however, not situated between the two collecting conductors 10, 11, is situated in the additional heating region 14, cannot be flowed through by the heating current 16 and thus cannot be heated by the collecting conductors 10,11.
[0076] In order to prevent electrical short circuits, the main heating region 9 of the heating layer 6 is electrically and, in particular, galvanically isolated from the additional heating region 14, for example, by a heating-layer-free separating region 19 of a width d of, for example, 100 μm. The heating layer 6 is removed in the separating region 19, for example, by laser ablation. Alternatively, the heating layer 6 can also be mechanically removed or already be excluded by shadowing during coating.
[0077] In order to heat the additional heating region 14, it has an electrically heatable line heating element 15. The line heating element 15 is formed, for example, by a sinusoidally curved linear electrically conductive structure, hereinafter referred to as “heating line”. The heating line preferably has a periodicity of 30 to 60 and, for example, 50 and an amplitude of 20 mm to 70 mm and, for example, 60 mm and extends along the lower pane edge 5a′ over the entire longer width of the pane 1. The heating line is made, for example, of a printed-on electrically conductive paste and is preferably printed at the same time as the collecting conductors 10,11 in a screen printing method onto the inner pane 3. The heating line is printed directly onto the heating coating 6 and thus directly contacted with it over its entire length and electrically conductively connected thereto. The width b of the heating line is preferably between 0.5 mm and 4 mm and here, for example, 1 mm. The thickness of the heating line is, for example, 10 μm and the specific resistance 2.3*10.sup.−8 ohm*m of the line length. It is understood that the line heating element 15 can also be formed by an another electrically conductive structure, for example, a heating wire such as a tungsten wire.
[0078] The line heating element 15 is directly connected in this example to a connection to the second collecting conductor 11 on its outer end via an electrical line connection 26′. In the simplest case, the printed heating line transitions there continuously into the printed collecting conductor 11. The other connection of the line heating element 15 is connected, in this example, via a connection conductor 23 to the first collecting conductor 10. The connection conductor 23 is, for example, a printed-on conductor, which runs along the heating-layer-free edge strip 7 along the pane edge 5b. The connection conductor 23 can have the same dimensions as the heating line in the additional heating region 14 and can heat the pane 1 in the edge region upon application of a supply voltage. Usually, the connection conductor 23 is implemented lower ohmic such that no appreciable voltage drop takes place there and no warming occurs. By means of the above-described circuitry, the line heating element 15 is electrically connected to the connection means 10, 11, 12, 13, of the heating layer 6 in parallel electrical connection with the heating field 17 and, thus, no additional connection is necessary for the line heating element 15 in the additional heating region 14.
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[0080] Upon application of a supply voltage, a heating current 16 flows between the collecting conductors 10,11 through the heating field 17. Because of the parallel electrical connection of the line heating element 15 to the collecting conductors 10,11 of the heating field 17, a current likewise flows through the line heating element 15. Since the line heating element 15 is in direct electrical contact with the heating layer 6 in the additional heating region 14, the current flow splits: Part of the current I.sub.Z flows through the line heating element 15 itself, here, in other words, along the printed-on electrically conductive heating line, for example, in the section 18a. Due to the difference in potential, a current I.sub.H1-3 additionally flows through a region of the heating layer 6, which is situated in each case between two adjacent sections 18a,18b of the line heating element 15. Here, the current density is a function of the difference in potential between the sections 18a and 18b and is determined by the shape of the heating line, the specific resistance of the heating line, and the specific resistance of the heating layer 6 and can be optimized in the context of simple simulations. Both current components result in a heating current and, thus, in heating of the pane 1 in the respective region. By means of the combination of the two current components I.sub.Z, I.sub.H1-3, greater homogeneity of the heating power distribution and greater homogeneity of the resultant temperature distribution can be achieved in the additional heating region 14 than would, for example, be the case with a heating line without an additional heating layer. This was unexpected and surprising for the person skilled in the art.
[0081] The higher homogeneity of the heating power distribution and the higher homogeneity of the temperature distribution are particularly advantageous here when the additional heating region 14 is arranged, as depicted in this example, in the region of the parking and resting position of windshield wipers and these can be deiced quickly and reliably.
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[0084] It is understood that the periodicity, the width b, and the thickness of the heating line and the shape of its course can vary across the pane 1 and, thus, selectively determined regions are increasingly heatable.
[0085] The heating line preferably, but not necessarily, contains a metallic material, in particular silver and glass frits. The heating line has, for example, ohmic resistance in the range from 0.2 ohm to 8 ohm/m, which has suitable heating power for practical use with the customary onboard voltage of a motor vehicle of 12 to 48 V. Preferably, heating power in the range from 400 to 1000 W/m.sup.2 of pane surface in the additional heating region 14 can be made available.
[0086] The main heating region 9 and the additional heating region 14 of the heating layer 6 can have other heating-layer-free regions, for example, for forming one or a plurality of communication windows. Alternatively, the line heating element 15 in the additional heating region 14 can also be routed such that it has one or a plurality of sections without a printed heating line, for example, in order to ensure an undisturbed view of a vehicle identification number below the pane 1.
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[0088] Two line heating elements 15,15′ are arranged in the additional heating region 14. The two line heating elements 15,15′ consist of heating lines, which correspond in their dimensions to those of
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[0091] In this exemplary embodiment, two second connecting conductors 13, 13′, which are implemented here, as well, for example, as insulated flat-band conductors (e.g., narrow metal foils), are electrically connected to the second collecting conductor 11 and have, in each case, two second external connections 21, 21′, which are provided for the connection to the other pole (for example, the plus pole) of the voltage source 25.
[0092] Two line heating elements 15,15′, which are connected on their outer connections via connection conductors 23,23′ to the first collecting conductors 10, are arranged in the additional heating region 14 as in
[0093] The connection conductors 23″, 23′″ in the separating region 19 were dimensioned such that the connection conductors 23″,23′″ can be heated by application of a supply voltage on the outer connections 20, 21, 21′ of the pane 1. This has a particular advantage that, by this means, the separating region 19 can be selectively heated and deiced.
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[0097] An exemplary production method for the windshield 1 is described schematically in the following:
[0098] First, the outer and inner pane 2, 3 are cut in the desired trapezoidal shape from a glass blank. Then, the inner pane 3 is coated with the heating layer 6 by sputtering, wherein the edge strip 7 is not coated through the use of a mask. Alternatively, it would also be possible to first coat a glass blank, from which the inner pane 3 is then cut. The inner pane 3 pretreated in this manner is decoated for forming the edge strip 7, which can be done in industrial series production, for example, by a mechanically degrading grinding wheel or by laser ablation.
[0099] Subsequently or simultaneously, the heating layer 6 is electrically isolatingly divided into a main heating region 9 and an additional heating region 14, for example, by decoating a separating region 19 or a plurality of separating regions 19.1,19.2. The separating region 19,19.1,19.2 is preferably decoated by laser ablation. This has the particular advantage that reliable electrical isolation can be achieved and, at the same time, the separating region 19, 19.1,19.2 is only minimally noticeable visually.
[0100] Then, the two collecting conductors 10, 11, the line heating element 15,15′, as well as any connection conductors 23,23′,23″,23′″ are printed on the inner pane 3, for example, by screen printing. A silver printing paste, for example, can be used as the printing paste. Then, the printing paste is pre-fired, followed by bending of the panes 2, 3 at a high temperature. An electrical connection of the collecting conductors 10,11 to the first and second connecting conductors 12, 13, 13′ can be made, for example, by soldering or fixing using a conductive adhesive, for example, by ultrasonic welding. Then, the outer and inner pane 2, 3 are positioned together and bonded by means of the adhesive layer 4.
[0101] The invention makes available a transparent pane 1 with an electrical heating layer 6, in which at least one line heating element 15, 15′ is arranged in an additional heating region 14 of the pane 1, which element is connected to the electrical connection means 10,11,12, 13,13′ of the heating layer 6. Separate external connections for the line heating element 15,15′ can advantageously be dispensed with. By means of the implementation according to the invention of the line heating element 15,15′ in electrical contact with the heating layer 6, great homogeneity of the heating power distribution and of the temperature distribution during electrical heating is achieved. This was unexpected and surprising for the person skilled in the art.
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[0105] The simulations were based in each case on a rectangular strip of heating layer 6 with sheet resistance of 0.9 ohm/square and a supply voltage of 14 V on the two ends of the line heating element 15. The amplitude of the linear course was, in each case, 80 mm from peak to peak and the periodic interval was 80 mm. The periodic course is repeated 9 times in each case.
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[0107] In the reversal region 29, in which another section 28 of the line heating element 15 directly connects the sections 18a and 18b of the line heating element, a current I.sub.Z2 flows through the section 28 of the line heating element 15. The difference in potential between the regions of the line heating element 15 adjacent the section 28 is reduced by the current flow I.sub.Z2 in the sections 18a and 18b. This results in the fact that the current flow I.sub.H3 through the heating layer 6 in these adjacent regions is lower than the current flow I.sub.H1 and I.sub.H2 through the heating layer 6 in more remote regions. Due to the antiparallel arrangement of the line heating element 15 in the sections 18a and 18b, the distance between the sections 18a and 18b is equidistant to one another. The lower current flow I.sub.H3 through the heating layer 6 results in a drastic reduction of the heating power density in the region adjacent the section 28 and in a significant increase in the heating power density in the remote regions. In
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[0109] At the same time, the distance between the line heating element 15 in the sections 18a and 18b is reduced due to the triangular course. In other words, the distance between corresponding points of the line heating element 15 in section 18a and points of the line heating element 15 in section 18b decreases when approaching the connection point in the reversal point 27 between section 18a and section 18b roughly proportionally to the amount that the difference in potential drops. The result is that the current flow through the heating layer 6 remains approx. constant, in other words I.sub.H3 is almost as great as I.sub.H2 and almost as great as I.sub.H1. With a constant sheet resistance of the heating layer 6, the constant current I.sub.H1,2,3 results in a constant heating power density.
[0110] In
LIST OF REFERENCE CHARACTERS
[0111] 1 pane, windshield [0112] 2 individual pane, outer pane [0113] 3 individual pane, inner pane [0114] 4 adhesive layer [0115] 5 pane edge [0116] 5a, 5a′ long pane edge [0117] 5b, 5b′ short pane edge [0118] 6 heating layer [0119] 7 edge strip [0120] 8 heating layer edge [0121] 9 main heating region [0122] 10 first collecting conductor [0123] 11 second collecting conductor [0124] 12 first connecting conductor [0125] 13, 13′ second connecting conductor [0126] 14 additional heating region [0127] 15, 15′ line heating element [0128] 16 heating current [0129] 17 heating field [0130] 18a, 18b section of the line heating element 15 [0131] 19,19.1,19.2 separating region [0132] 20 first external connection [0133] 21, 21′ second external connection [0134] 23, 23′ connection conductor [0135] 24 supply line [0136] 25 voltage source [0137] 26,26′,26″,26″″ electrical line connection [0138] 27 reversal point [0139] 28 another section of the line heating element 15 [0140] 29 reversal region [0141] A-A′ cross section line, [0142] B,C detail [0143] b width of the line heating element 15,15′ [0144] d width of the separating region 19 [0145] g width of the additional heating region 14 [0146] I.sub.H1, I.sub.H2, I.sub.H3 current through the heating layer 6 in the additional heating region 14 [0147] I.sub.Z, I.sub.Z1, I.sub.Z2 current through the line heating element 15,15′ [0148] r width of the edge strip 7 [0149] II pane surface of the outer pane 2 [0150] III pane surface of the inner pane 3