OPTICALLY-INDUCED COOLING
20230178448 · 2023-06-08
Inventors
Cpc classification
H01L23/34
ELECTRICITY
F25B23/003
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
H01S3/0408
ELECTRICITY
International classification
Abstract
An illumination source is configured to illuminate a medium with light at a wavelength selected based on an emission band of a selected absorption band of the medium. The selected absorption and emission bands being associated with an electric-dipole-allowed transition of the medium. Upon illumination by the light the medium is cooled.
Claims
1. A method includes: cooling a medium including a mass characterized by a selected absorption band of one or more electric-dipole-allowed transitions, the selected absorption band having a corresponding fluorescence spectrum by: illuminating the medium with light at a selected wavelength for an emission band of the corresponding fluorescence spectrum, where: the selected wavelength is greater than an average fluorescence wavelength of the medium for the corresponding fluorescence spectrum.
2. The method of claim 1, further including pumping the medium to support lasing in the medium.
3. The method of claim 2, further including operating the medium as a lasing medium for a radiation balanced laser.
4. The method of claim 1, where cooling the medium includes cooling the medium to a cryogenic temperature or below.
5. The method of claim 1, further including implementing the medium as a refrigerated test bed for experiments.
6. The method of claim 1, where the medium includes a substrate for a semiconductor circuit.
7. The method of claim 1, where the medium includes a titanium sapphire crystal.
8. The method of claim 1, where illuminating the medium includes illuminating the medium with a low entropy light source.
9. The method of claim 1, where the selected wavelength includes 950 nm±20 nm.
10. The method of claim 1, further including implementing the medium as a refrigeration device for a semiconductor sensor.
11. The method of claim 1, where illuminating the medium includes saturating one or more parasitic background effects intrinsic to the medium.
12. The method of claim 1, where the medium includes a material with an excitation characterized by a fast relaxation time.
13. A system including: a medium including a mass characterized by a selected absorption band of one or more electric-dipole-allowed transitions, the selected absorption band having a corresponding fluorescence spectrum; and an illumination source configured to illuminate the medium with light at a selected wavelength for an emission band of the corresponding fluorescence spectrum, where: the selected wavelength is greater than an average fluorescence wavelength of the medium for the corresponding fluorescence spectrum.
14. The system of claim 13, where the illumination source is further configured to pump the medium to support lasing in the medium.
15. The system of claim 14, where the illumination source is further configured to pump the medium to operate the medium as a lasing medium for a radiation balanced laser.
16. The system of claim 13, where the illumination source is further configured to illuminate the medium to cool the medium to a cryogenic temperature or below.
17. The system of claim 13, further including sensor circuitry, where: the medium includes a refrigeration device for the sensor circuitry.
18. The system of claim 13, where the medium includes a substrate for a semiconductor circuit.
19. The system of claim 13, where the medium includes a titanium sapphire crystal.
20. A device including: an illumination source configured to illuminate a medium with light to effect cooling within the medium; and control circuitry configured to cause the illumination source to generate the light at a selected wavelength for an emission band of a fluorescence spectrum of a selected absorption band of one or more electric-dipole-allowed transitions of the medium, where the selected wavelength is longer than an average fluorescence wavelength of the medium for the fluorescence spectrum.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0012] Laser cooling of solids has not been so widely employed in photonic device applications because the cooling rate and efficiency demonstrated to date are poorer than in vapors. In condensed matter it has not been possible to implement rapid, efficient cooling with allowed electric-dipole transitions because in general the dense environment of solids causes heating due to configuration relaxation during optical interactions. Forbidden transitions incur no extra heating due to configuration relaxation, and permit lower temperatures to be reached than by any other means to date. On the other hand, optical refrigeration based on forbidden transitions may not necessarily be fast enough for all applications and may not necessarily scale to all payloads.
[0013] In various contexts, it may be desirable to cool a target, including some cases, where forbidden-transition-based cooling alone (e.g., without combination with other technologies) may be insufficient. For example, it may be desirable to cool a sensor (or other semiconductor device), act as a coolable substrate for a semiconductor device (for example a Ill-IV and/or II-VI semiconductor device) to create a self-cooled radiation-balanced laser, to refrigerate a target to a cryogenic temperature or below, to cool a target with minimal or no induced vibration as a result of the cooling, and/or to implement other systems where increased cooling power or efficiency is desirable.
[0014] In optical cooling, heat can be removed from a target by having a laser induce excitation in the material with laser light including photons of a first energy. The excitations in the material relax over time and release photons of a second energy. If the second energy is higher than the first energy, the excitation-relaxation cycle carries heat away from the target material. To achieve the excitation in the material, an energy-level transition may be used. According to conventional wisdom, optical cooling must avoid the use of electric-dipole-allowed transitions. According to the conventional wisdom, the intense interactions of the electrons with the “cooling” light on electric-dipole-allowed transitions induces in-material vibrations due to configuration relaxation. According to the conventional wisdom, these vibrations would clearly lead to heating that would overwhelm any cooling effect achievable through use of the electric-dipole-allowed transitions.
[0015] Contrary to the conventional wisdom, various ones of the techniques and architectures discussed herein implement optical cooling using electric-dipole-allowed transitions. Electric-dipole-allowed transitions may be comparatively faster than forbidden or disallowed transitions, for example some electric-dipole-allowed transitions may have fluorescent relaxation time scales shorter than 10-7 seconds. In some cases, forbidden transitions may have relaxation times longer than 10-3 seconds. As an illustrative example, the 2E-2T2 transition in trivalent titanium ions may have a relaxation time on the scale of 10-6 seconds. Accordingly, cooling via electric-dipole-allowed transitions may be able to increase the rate of cooling by factors of 103-104 or more. Thus, electric-dipole-allowed transitions may have fast relaxation times, e.g., relaxation time faster than 10-4 seconds or other short-time-scale relaxation times.
[0016] The short time scales of various electric-dipole-allowed transitions may be shorter than those of impurities or other parasitic heating pathways in a cooled material. Accordingly, as an unexpected result, various ones of these impurities and/or other parasitic heating pathways may be saturated with sufficient cooling illumination and be unable to relax quickly enough to compete with the cooling rate of the electric-dipole-allowed transition. Therefore, in some cases, the heating by unintended impurities through parasitic absorption may be overwhelmed and increased cooling efficiency may be achieved.
[0017] In various implementations, cooling wavelengths longer than the mean fluorescence wavelength may be used for illumination of the medium to avoid non-radiative relaxation processes. The quantum efficiency at room temperature may be around 1.0 at such wavelengths for some implementations. This is an effect similar to zero phonon transitions in gamma ray spectroscopy because the excitation of the bulk crystal can be avoided while using electronic transitions of dopant ions.
[0018] A further unexpected result is that designing a system to operate using illumination at one or more discrete wavelengths within the emission band increases the cooling power of the system (e.g., relative to operation using wavelengths other than the discrete peaks). In various implementations, the discrete wavelengths at which this increased cooling power can be achieved may be dependent on the material selected for the target cooling medium of the cooling system. Accordingly, in various implementations, the light from an illumination source of an optical cooling system may include light at the one or more material-dependent discrete wavelengths. In some implementations, a medium with a high figure of merit (FOM) may be used. FOM is defined as the ratio of the absorption coefficients at pump and emission wavelengths for a corresponding application of the medium. The FOM may provide a quality measure of the medium for the specific corresponding application, and in some cases, a general quality measure of impurities/defects in the medium. In some cases, a high FOM medium may be used, e.g., a ratio of about 200 or more. Nevertheless, other medium quality measures may be used.
[0019] Referring now to
[0020] The OCS 100 may further include an illumination source 104. The illumination source may illuminate the medium with light at a selected wavelength within a portion of the corresponding fluorescence spectrum (including the long-wavelength tail portion). In some cases, the selected wavelength may be greater than an average fluorescence wavelength of the mass for the corresponding fluorescence spectrum. In various implementations, the illumination source 104 may provide light that is spectrally distributed. At least some of the light from the illumination source 104 may be at the selected wavelength, while other portions of the light from the illumination source 104 may be at one or more other wavelengths. Thus, the illumination source may illuminate 104 the medium 102 with light at the selected wavelength, and, in some cases, light at other wavelengths.
[0021] In various implementations, the illumination source may include a laser light source. In some cases, a low-entropy light source, such as a single-mode laser may be absorbed to cause anti-Stokes fluorescence in a dispersed form with greater entropy than that of the beam at the time of absorption. Accordingly, the light exiting the material is “hotter” (e.g., more disorganized) and more energetic photon by photon than the beam coming into the material. Hence, the light may carry heat (e.g., via disorganization) out of the material.
[0022] Various laser systems may be used as the illumination source, such as titanium sapphire lasers, indium gallium arsenide (InGaAs) lasers, other semiconductor lasers, or various other laser sources. Conversely, titanium sapphire lasers, indium gallium arsenide (InGaAs) lasers, other semiconductor lasers, or various other laser sources may serve as cooling targets or operate in radiation balanced configurations using the cooling architectures and techniques discussed herein. The light source may be continuous-wave or pulsed.
[0023] In some cases, the illumination source may further be used to perform laser pumping for population inversion within the material. For example, when a lasing material, such as titanium sapphire, is used as the cooling target, the illumination source may double as a laser pump in addition to providing cooling. The combination of cooling and laser pumping may support a radiation-balanced laser. In some cases, uniform cooling (or non-uniform cooling with the same spatial profile as the pumping power) by the illumination source may mitigate thermal effects normally present due to heating by the pump laser, such as thermal lensing. In some cases, this may allow for higher pumping powers than that achievable without self-cooling or radiation balancing.
[0024] In some cases, pumping for lasing in the medium may be provided using a laser pump that is separate from the illumination source used for cooling.
[0025] Referring now to
[0026] At 154, cooling may be implemented via illumination of the medium by the illumination source 104 with light at the selected wavelength. As discussed above, illumination of the medium 102 via the illumination source 104 may cause excitation of particles in the material which may lead to eventual relaxation via the electric-dipole-allowed transitions. The emissions associated with the electric-dipole-allowed transitions may correspond to higher energy photons than that of the light at the selected wavelength. Thus, the excitation-emission cycle may, on average, carry energy out of the medium (e.g., resulting in cooling).
[0027] At 156, the cooling may be executed in accord with a selected cooling scheme. For example, the material may be continuously and/or continually refrigerated by constant and/or repetitive exposure to the light at the selected wavelength. For example, the material may be cooled to a specific temperature and/or held within a specific temperature range. For example, the medium may be cooled to a cryogenic temperature and/or held within a cryogenic temperature range.
[0028] For example, the medium may be cooled without net cooling by the cooling process. For example, the cooling may be implemented to counteract (in part) heating done by the illumination source itself. For example, the medium may include a lasing medium pumped by the illumination source. In the absence of cooling, the pumping process generates net heat at a higher level than when the illumination source is also tuned to effect simultaneous cooling. Thus, cooling requirements for such a lasing system (e.g., a radiation “sub-balanced” laser) may be relaxed relative to cooling requirements for systems without tuning for simultaneous cooling.
[0029] For example, the material may be cooled in accord with specific timings and/or specific target cooling rates. In some implementations, various criteria for cooling may be set, e.g., initiate cooling when the material exceeds a threshold temperature, cease cooling when the material falls below a threshold temperature; e.g., initiate cooling when the system is exposed to solar (or other celestial) radiation; and/or other cooling criteria.
Example Implementations
[0030] Various illustrative example implementations are included below.
[0031] In an illustrative example scenario, a system may perform optical refrigeration (e.g., cooling) of Ti:Sapphire on an allowed 2E-2T2 transition. This constitutes cooling on an electric-dipole-allowed transition in a bulk solid. In some cases, electric-dipole-allowed transitions may support more rapid cooling than forbidden transitions of rare earths. Further, titanium sapphire crystals may serve as a substrate material suitable for the growth of Ill-V semiconductor circuits. This may support imaging arrays with improved signal-to-noise performance at cryogenic temperatures for sensing applications in outer space.
[0032] For a proof-of-principle, an example Ti:Sapphire sample was grown using a specialized heat exchange method (HEM). In Ti:Sapphire, a figure of merit (FOM) is defined as the ratio of the absorption coefficients at specific pump and emission wavelengths of 532 nm and 800 nm. This ratio, e.g., (α532 nm/α800 nm), is used as a measure of crystal quality and the potential performance of the a.sub.800 nm crystal as a laser gain medium. The sample was specifically selected because of its comparatively-high quoted FOM of 844 and was Brewster-cut with dimensions of 4×5×20 mm to avoid the need for coatings on the end faces which can cause heating. Normalized absorption and emission spectra 200 are shown in
[0033] Thermal lens spectroscopy (TLS), demonstrated in the plot 300 of
[0034]
[0035] In this illustrative example demonstration, thermal lens spectroscopy has shown a strong reversal of signal polarity between the absorptive and emissive spectral ranges in a sample of Ti:Sapphire with a high figure of merit and Brewster-cut end faces. An unexpected finding was that efficient cooling took place at discrete (material-dependent) wavelengths within the emission band, at wavelengths longer than the mean fluorescent wavelength.
[0036] Table 1 shows wavelengths for selected discrete cooling resonances in Ti:Al2O3 for the π-polarization corresponding to the resonances shown in the plot 500 of
TABLE-US-00001 TABLE 1 Wavelengths for selected discrete cooling resonances l.sub.obs k.sub.obs k.sub.calc k.sub.obs − k.sub.calc (nm) (cm.sup.−1) Initial Level Site (cm.sup.−1) (cm.sup.−1) 800.03 12499.53 (.sup.2A(0), v.sub.c) 4 12575.48 79.95 812.84 12306.93 (.sup.2A(0), v.sub.d) 2 12276.79 −30.14 814.39 12285.01 (.sup.2A(0), v.sub.d) 3 12276.79 −8.22 817.86 12229.72 (.sup.2A(0), v.sub.d) 4 12276.79 47.07 822.85 12152.88 (.sup.2A(1), v = 0) 1 11957.89 −194.99 827.43 12085.61 (.sup.2A(1), v = 0) 2 11957.89 −127.72 829.41 12056.76 (.sup.2A(1), v = 0) 3 11957.89 −98.87 831.39 12020.24 (.sup.2A(1), v = 0) 4 11957.89 −62.35 897.44 11142.81 (.sup.2A(1), v.sub.d) 1 11076.89 −65.91 906.92 11026.33 (.sup.2A(1), v.sub.d) 2 11076.89 50.56 930.47 10747.26 (.sup.2A(1), v.sub.d) 3 11076.89 329.64 937.15 10670.65 (.sup.2A(1), v.sub.d) 4 11076.89 406.24 944.04 10592.77 (.sup.2A(2), v = 0) 1 10547.89 −44.88 950.08 10525.43 (.sup.2A(2), v = 0) 2 10547.89 22.47 954.41 10477.68 (.sup.2A(2), v = 0) 3 10547.89 70.22 955.36 10467.26 (.sup.2A(2), v = 0) 4 10547.89 80.64 958.87 10428.94 (.sup.2A(2), v.sub.a) 1 10149.89 −279.05 961.51 10400.31 (.sup.2A(2), v.sub.a) 2 10149.89 −250.41 974.92 10257.25 (.sup.2A(2), v.sub.a) 3 10149.89 −107.36 Average: −8.04
[0037] Table 2 shows wavelengths for selected discrete cooling resonances in Ti:Al.sub.2O.sub.3 for 6-polarization corresponding to the resonances shown in the plot 600 of
TABLE-US-00002 TABLE 2 Wavelengths for selected discrete cooling resonances λ.sub.obs k.sub.obs k.sub.calc k.sub.obs − k.sub.calc (nm) (cm.sup.−1) Initial Level Site (cm.sup.−1) (cm.sup.−1) 815.80 12257.91 (.sup.2A(0), v.sub.d) 4 12199.56 −58.35 822.80 12153.62 (.sup.2A(1), v = 0) 3 11906.16 −247.46 832.14 12017.21 (.sup.2A(1), v = 0) 4 11906.16 −111.05 906.65 10993.24 (.sup.2A(1), v.sub.d) 1 10999.56 6.32 913.25 10949.90 (.sup.2A(1), v.sub.d) 2 10999.56 49.66 933.84 10708.47 (.sup.2A(1), v.sub.d) 3 10999.56 291.09 937.17 10670.42 (.sup.2A(1), v.sub.d) 4 10999.56 329.14 944.03 10592.88 (.sup.2A(2), v = 0) 1 10496.16 −96.72 950.08 10525.43 (.sup.2A(2), v = 0) 2 10496.16 −29.27 954.42 10477.57 (.sup.2A(2), v = 0) 3 10496.16 18.59 957.90 10439.50 (.sup.2A(2), v = 0) 4 10496.16 56.66 974.93 10257.15 (.sup.2A(2), v.sub.a) 4 10111.17 −14.98 Average: 4.82
[0038] It is possible to cool crystals optically on electric-dipole-allowed transitions with very large relaxational (Stokes) shifts between absorption and emission wavelengths. Successful cooling of sapphire is primarily mediated by discrete absorptive transitions involving electronic and optical phonon sublevels in the ground state of Ti3+. This demonstration may be significant for applications in vacuum or space since this material is a valid substrate for radiation-hard Ill-V semiconductor circuitry appropriate for infrared sensing and other applications.
[0039] Various example implementations have been included for illustration. Other implementations are possible. Table 3 shows various examples.
TABLE-US-00003 TABLE 3 Examples 1. A method includes: cooling a medium including a mass characterized by a selected absorption band of one or more electric-dipole-allowed transitions, the selected absorption band having a corresponding fluorescence spectrum by: illuminating the medium with light at a selected wavelength within (or near) an emission band of the corresponding fluorescence spectrum, where: optionally, the selected wavelength is greater than an average fluorescence wavelength of the mass for the corresponding fluorescence spectrum; and optionally, the selected wavelength is in resonance with an electronic transition, an optical phonon sideband absorption, or an acoustic phonon sideband; and optionally, the method is in accord with any other example in this table. 2. A system including: a medium including a mass characterized by a selected absorption band of one or more electric-dipole-allowed transitions, the selected absorption band having a corresponding fluorescence spectrum; and an illumination source configured to illuminate the medium with light at a selected wavelength within (or near) an emission band of the corresponding fluorescence spectrum, where: optionally, the selected wavelength is greater than an average fluorescence wavelength of the mass for the corresponding fluorescence spectrum; and optionally, the selected wavelength is in resonance with an electronic transition, an optical phonon sideband absorption, or an acoustic phonon sideband; and optionally, the system is in accord with any other example in this table. 3. The method or system of any of the other examples in this table, where the light includes: optionally, visible and/or near infrared light; optionally, coherent light; optionally, laser light; optionally, continuous wave laser light; optionally, pulsed laser light; optionally, light characterized by a bandwidth less than 1 Mhz, 100 kHz, 50 kHz, and/or narrower bandwidth; optionally, single-mode laser light; optionally, titanium sapphire laser light; optionally, indium gallium arsenide (InGaAs) laser light; optionally, with laser light a wavelength longer than 760 nm; optionally, with laser light a wavelength longer than 770 nm; optionally, with laser light a wavelength shorter than 770 nm; optionally, with laser light a wavelength longer than 820 nm; optionally, with laser light a wavelength shorter than 820 nm; optionally, with laser light a wavelength longer than 830 nm; optionally, with laser light a wavelength shorter than 830 nm; optionally, with laser light a wavelength longer than 850 nm; optionally, with laser light a wavelength shorter than 850 nm; optionally, with laser light a wavelength longer than 900 nm; optionally, with laser light a wavelength shorter than 900 nm; optionally, with laser light a wavelength longer than 950 nm; optionally, with laser light a wavelength shorter than 950 nm; optionally, with laser light a wavelength longer than 1000 nm; optionally, with laser light a wavelength shorter than 1000 nm; optionally, polarized light, (e.g., polarized with reference to a material axis): optionally, σ-polarized light; and optionally, π-polarized light; and optionally, illumination selected to perform cooling using one or more discrete material-dependent cooling wavelengths, where: optionally, the one or more discrete material-dependent cooling wavelengths include any of (or any grouping of) the discrete wavelengths listed in Table 1 and/or Table 2 (above). 4. The method or system any of the other examples in this table, where the mass includes: optionally, a bulk solid; optionally, a crystal, such as a Brewster cut crystal; optionally, a glass; optionally, a liquid; optionally, a lasing medium; optionally, a doped material, where optionally the dopant includes a transition metal ion; optionally, a doped material, where optionally the dopant includes a rare earth ion; optionally, a corundum crystal (e.g., ruby, sapphire, or other corundum); optionally, a garnet crystal, such as yttrium aluminum garnet; optionally, an oxide crystal; optionally, a low-impurity material; optionally, a material with low excited-state absorption; optionally, a titanium sapphire crystal, e.g., a sapphire crystal doped with ionic titanium; optionally, a material with a high figure of merit relevant to laser operation, e.g., for laser crystal the figure of merit may include the ratio of absorption coefficients at the pumping and lasing wavelengths:
[0040] The present disclosure has been described with reference to specific examples that are intended to be illustrative only and not to be limiting of the disclosure. Changes, additions and/or deletions may be made to the examples without departing from the spirit and scope of the disclosure.
[0041] The foregoing description is given for clearness of understanding only, and no unnecessary limitations should be understood therefrom.