Cleaner for grease rejuvenation and method of maintaining bearings, bushings, linkage pins, and chains

Abstract

A cleaner and method for maintaining bearings, bushings, linkage pins and chains used in various types of machinery, including industrial machinery is disclosed. The cleaner is effective to rejuvenate spent grease and includes a polar fraction, a miscible non-polar fraction, and a non-ionic surface activating agent.

Claims

1. A cleaner effective to rejuvenate spent grease, consisting essentially of, by approximate weight percent, 40% to 90% silicone, 10% to 50% acetone, and trace 5% alkylphenol ethoxylate.

2. A method for maintaining bearings, bushings, linkage pins and chains used in various types of machinery, comprising the steps of: (a) providing a cleaner consisting essentially of, by approximate weight percent, 40% to 90% silicone, 10% to 50% acetone, and trace to 5% alkylphenol ethoxylate; (b) applying the cleaner to a joint of a piece of machinery; (c) applying oil to the joint; (d) testing joint to ensure proper timing; and (e) repeating steps (a) through (d) if necessary.

3. The method according to claim 2, wherein the cleaner is applied to the joint until it floods out sides of the joint.

4. The method according to claim 2, further including the step of repeating step (b) to thoroughly clean the joint.

5. The method according to claim 4, further including the step of waiting five to thirty seconds between repeating step (b) to allow for capillary uptake of the cleaner into the joint.

6. The method according to claim 2, wherein the oil is applied to the joint until it begins to run down sides of the joint.

7. The method according to claim 2, further including the step of repeating step (c) to ensure adequate oil has been added to the joint.

Description

BRIEF DESCRIPTION OF THE INVENTION

(1) The subject matter that is regarded as the invention may be best understood by reference to the following description taken in conjunction with the accompanying drawing figures in which:

(2) FIG. 1 shows an example circuit breaker mechanism;

(3) FIG. 2 shows accessible bearings and bushings of a circuit breaker mechanism;

(4) FIGS. 3 and 4 show inaccessible bearings and bushings of a circuit breaker mechanism;

(5) FIGS. 5-7 show coagulation of grease thickeners; and

(6) FIGS. 8 illustrates a method for cleaning a mechanism having bearings and bushings.

DETAILED DESCRIPTION OF THE INVENTION

(7) The present invention incorporates a new cleaner formulation and its use that stabilizes the grease thickeners, varnishes, and other debris that may be slowing or locking the bearing. The particles treated with this specialized cleaner form a stable colloid after miscible oil is added.

(8) As the grease ages in a bearing, failures occur due to the oil bleeding out, drying up, and/or oxidizing. Oxidation causes oils to become gummy. Evaporation of the oil and separation of the oil from the grease leave thickeners in a dry immovable state. The end result is a crusty residue, comprised of grease thickener and oxidation byproducts, which slows or prevents the operation of the bearing. Commercial degreasers remove the oil and oxidation byproducts, but destabilize the grease thickeners, leading to coagulation. See FIGS. 5-7. Coagulation inhibits the ability of the grease to uptake new oil.

(9) The lubrication of circuit breaker mechanisms is often addressed by exercising the mechanism, spraying the mechanism with a general purpose penetrant and lubricant, or a combination of both. For purposes of this application, penetrating oil is defined as a light hydrocarbon distillate or surfactant that reduces the surface tension of oil to allow the oil to travel into tight spaces quickly by pulling the oil into the spaces through diffusion. The effectiveness is limited and, based on laboratory testing, these methods are only effective for a few hours. Some users spray bearings and bushings with degreaser and then spray or pour lubricating oil over the mechanism. The use of general purpose sprays and exercising of the mechanism are commonly performed; however, their effectiveness in the field is not consistent in terms of repeatable performance and long lubricant life.

(10) Based on testing, several observations were made. Penetrating oil loosens oxidized grease and provides an initial improvement in operation time; however, by the next morning slow operation time reoccurs. Sprays used on bearings with aged grease may not “free” the bearing for operation for more than 12 hours. Renewing Grease—Cannot pour oil onto old thickener and get original grease. Varnishes remain in the system, which inhibit movement. Sealed Ball Bearings—Must use oil with a substantial amount of penetrant due to inability of even light oil to go past the bearing seal. Synthetic oil with penetrant is effective and provides longer life than aerosols. Aerosol propellants do not provide better penetration of tight bearing clearances —only penetration effectiveness factor is interfacial tension. Many aerosols contain petroleum oils that are solid or thickening at −18° C. (0° F.). Long-life synthetic oils are too viscous to form an aerosol without being diluted with significant amounts of solvent. This limits the amount of lubricating oil which can be brought into the system. Sleeve Bearings—If there is shim protecting the bearing from dirt, cleaner/degreaser must be used before lubricant is applied. Multi-step process of degreaser and oil produces significantly better results. Many degreasers leave residue even though label says not.

(11) The new cleaner improves the efficacy of cleaning without coagulation of the thickeners; thereby, increasing the success rate of rejuvenating spent grease in a bearing. The cleaner consists of a polar fraction, such as acetone, a miscible non-polar fraction, such as silicone cleaner, and a non-ionic surface activating agent, such as an alkylphenol ethoxylate or polymethylated primary alcohol. An example formulation, by approximate weight percent, includes about 40%-90% silicone (MW<1000), 10%-50% Acetone, trace—5% alkylphenol ethoxylate, or trace—5% polymethylated primary alcohol Block 11. The formulation contains no VOC's as defined by the Environmental Protection Agency.

(12) It was found through experimentation that the mixed polarity solvent of the current invention (silicone +acetone along with a non-ionic activating agent −alkylphenol ethoxylate or polymethylated primary alcohol) was very effective in removing spent oil or grease and, along with the steps below, improved the trip time of mechanical devices, such as circuit breakers. For the experiment, several solvents were chosen based on their solvent classification. Five classifications were chosen. Non-Polar—a solvent whose molecules contain no net dipole. Semi-Polar—a molecule which contains no net dipole, but does contain local polarities. Polar Proctic—a solvent whose molecules contain a net dipole and has the ability to release a proton in solution. Polar Aprotic—a solvent whose molecules contain a net dipole, and does not release protons in solution. Mixed Polarity—a mixture of solvents or a solvent dissolved in another solvent.

(13) The majority of synthetic greases used utilize a Polyalphaolefin (PAO) oil. These include greases such as Mobil 28, Mobilith SHC, and Kluber L152. Other common grease selections utilize petroleum base oils.

(14) To model oxidized oil from an end of life grease, synthetic PAO oil was oxidized on a hot plate for several hours until it formed into a brown, sticky gel. For each test solvent, approximately 70 mg of oxidized PAO oil was placed in a beaker. The beaker was filled with 40 mL of the specified solvent and stirred rigorously for several minutes. The excess solvent was decanted out. The beaker was placed in an oven for 15 minutes to evaporate any residual solvent. The new weight was recorded. The results are presented in Table 1 below.

(15) TABLE-US-00001 TABLE 1 Empty Before After Oil VOC Beaker Cleaning Cleaning Oxidized Removed Removal Solvent Classification Status (g) (g) (g) Oil (g) (g) Rate (%) Pentane Non-Polar VOC 28.8793 28.971 28.902 0.0917 0.069 75.25 Acetone Polar Aprotic Non- 29.4635 29.535 29.521 0.0715 0.014 19.58 VOC OS-2 Semi-Polar Non- 29.0489 29.115 29.056 0.0661 0.059 89.26 VOC Isopropanol Polar Protic Non- 29.623  29.6943 29.6802 0.0713 0.0141 19.78 VOC Naphtha Semi-Polar VOC 29.3769 29.453 29.396 0.0761 0.057 74.90 OS-2 + Mixed Non- 28.6365 28.7144 28.639 0.0779 0.0754 96.79 Acetone Polarity VOC OS-2 + Mixed Non- 30.3298 30.4196 30.36 0.08980 0.0596 66.37 Isopropanol Polarity VOC TRUE Mixed VOC 29.2365 29.2975 29.2701 0.061 0.0274 44.92 BLITZ Polarity

(16) As opposed to the prior art methods of disassembling the mechanisms to clean and lubricate the bearings, the cleaner of the present invention allows a user to clean and lubricate the bearing by injecting the cleaner onto the mechanism and following the cleaner with a long life, low interfacial tension oil to obtain long lasting results without disassembly of the mechanism. The current method allows the mechanism to operate with performance and life comparable to applying new grease/lubricant without the need to take the mechanism apart.

(17) In use, the cleaner is injected onto or into the joint of the mechanism multiple times to dissolve grease oxidation byproducts and fluidize the grease. The cleaner is drawn into the bearing or bushing by capillary action. The ability of the cleaner to flush out oxidation byproducts is limited by the clearance between moving parts. The cleaner is applied in short spurts, allowing time for the joint to soak up the cleaning fluid by capillary action. Aerosol sprays are not used because the propellants cause bubbles, which interfere with capillary action.

(18) Long life, low interfacial tension oil, for example fluorosilicone oil, is applied to the joint immediately after cleaning. The oil must be miscible with the cleaner. The oil is drawn into crevices by diffusion through the cleaner. This forms concentration gradients which draw the oil into the grease matrix.

(19) The process is more clearly defined through the following steps: (1) apply cleaner to the joint until it begins to flood out the sides, Block 12; (2) repeat two to three times to thoroughly clean the part, giving five to thirty seconds between applications for capillary uptake, Block 13; (3) apply oil until it begins to run down the sides, Block 14; (3) repeat two or more times to ensure adequate oil has been added, Block 16; (4) test the mechanism to ensure that the breaker times properly (test to make sure the breaker operates within specified time limits), Block 17; and (5) repeat entire process if necessary, Block 18.

(20) Testing was performed using the cleaner and method of the current invention. The tests were performed using field aged bearings and a mechanical device having a solenoid-powered linkage to simulate a tripped circuit breaker. To determine the effectiveness of relubrication processes, several unused bearings were lubricated with popular greases to determine acceptable trip times. After several tests with trip times varying between 47 and 68 milliseconds, it was concluded that anything above 70 milliseconds was a slow trip.

(21) For each test, the bearings were aged in a 140 degrees Celsius oven to rapidly age and oxidize lubricants in the bearing to failure. After oxidation, various techniques were used and tested. While several cleaners and techniques resulted in varying results such as no trip and trip times above 200 milliseconds, it was found that the inventive cleaner was able to provide consistent trip times and a higher degree of success. See Table 2.

(22) TABLE-US-00002 TABLE 2 Trip Time (DNT = Did Not Trip) Process - Steps Preceding Test (Using Cleaners such as ZEP ID RED) DNT DNT Clean with ZEP ID RED or Equivalent DNT Clean with ZEP ID RED or Equivalent DNT Cleaner, EZ Reach, Cleaner, EZ Reach, Wait 5 Minutes DNT DNT DNT Clean, Lube, Manually Move 2X 100 Clean, Lube, Manually Move 2X 103 98 101 249 131 160 132 184 147 111 115 135 610 Process - Steps Preceding Test (Using Cleaner of Current Invention) 218 67 Clean with Inventive Cleaner 75 69 67 63 159 Oven Aged 2 Days at 140° C., Cooled to −40° C. 75 64 80 79 65 Clean with Inventive Cleaner and Lube with FS-1265 Fluorosilicone Fluid 83 90 61 67 72

(23) As shown in Table 2, the use of the inventive cleaner not only provided a more stable trip time, but also required less work on the part of the operator, i.e. manually moving the mechanism.

(24) The foregoing has described a cleaner and method for maintaining bearings, bushings, linkage pins and chains used in various types of machinery, including industrial machinery. While specific embodiments of the present invention have been described, it will be apparent to those skilled in the art that various modifications thereto can be made without departing from the spirit and scope of the invention. Accordingly, the foregoing description of the preferred embodiment of the invention and the best mode for practicing the invention are provided for the purpose of illustration only and not for the purpose of limitation.