Superconducting devices with ferromagnetic barrier junctions
11264089 · 2022-03-01
Assignee
Inventors
- Oleg A. Mukhanov (Putnam Valley, NY, US)
- Alan M. Kadin (Princeton Junction, NJ, US)
- Ivan P. Nevirkovets (Evanston, IL, US)
- Igor V. Vernik (Yorktown Heights, NY, US)
Cpc classification
Y10S505/832
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
G11C11/161
PHYSICS
International classification
Abstract
A superconducting memory cell includes a magnetic Josephson junction (MJJ) with a ferromagnetic material, having at least two switchable states of magnetization. The binary state of the MJJ manifests itself as a pulse appearing, or not appearing, on the output. A superconducting memory includes an array of memory cells. Each memory cell includes a comparator with at least one MJJ. Selected X and Y-directional write lines in their combination are capable of switching the magnetization of the MJJ. A superconducting device includes a first and a second junction in a stacked configuration. The first junction has an insulating layer barrier, and the second junction has an insulating layer sandwiched in-between two ferromagnetic layers as barrier. An electrical signal inputted across the first junction is amplified across the second junction.
Claims
1. A method of operating a superconducting electronic device, comprising: providing: a Josephson junction, formed of a pair of superconducting films, separated by an intervening barrier comprising a non-superconducting magnetic material, which impedes direct tunneling between the pair of superconducting films, a magnetic state of the non-superconducting magnetic material altering a property of the Josephson junction; a pair of electrodes connected to the pair of superconducting films, configured to impose a voltage across the intervening barrier; and a write port, configured to persistently change the magnetic state of the non-superconducting magnetic material; generating pulses in the Josephson junction detected through the pair of electrodes in a first pattern; changing the magnetic state of the non-superconducting magnetic material by a signal at the write port; and after changing the magnetic state, generating pulses in the Josephson junction detected through the pair of electrodes in a second pattern.
2. The method according to claim 1, further comprising: writing digital data as the signal to the write port with a digital computer; and after writing, reading the magnetic state of the non-superconducting magnetic material to determine the digital data; and operating the digital computer dependent on the determine the digital data.
3. The method according to claim 1, wherein the intervening barrier comprises a non-superconducting magnetic material film, further comprising inducing a current flow in the film selectively dependent on the write port.
4. The method according to claim 1, wherein the intervening barrier comprises a non-superconducting magnetic material film and an insulating film, between the at least two superconducting films.
5. The method according to claim 1, wherein the intervening barrier comprises a non-superconducting magnetic material film sandwiched between two layers of insulating film, between the at least two superconducting films.
6. The method according to claim 1, wherein the intervening barrier comprises at least two distinct layers of non-superconducting magnetic material film.
7. The method according to claim 1, wherein the intervening barrier comprises a non-superconducting magnetic material particles embedded in a non-magnetic matrix.
8. The method according to claim 1, wherein the intervening barrier comprises a non-superconducting magnetic material comprising at least one of iron and nickel.
9. The method according to claim 1, wherein the intervening barrier comprises at least one of silicon oxide, silicon nitride, aluminum oxide, and aluminum nitride.
10. The superconducting electronic device according to claim 1, wherein the non-superconducting magnetic material comprises a ferromagnetic material.
11. The superconducting electronic device according to claim 1, wherein the Josephson junction comprises a pair of outer superconducting layers, separated by a first non-superconducting ferromagnetic material layer, over a first insulating layer, over a second non-superconducting ferromagnetic layer, over a barrier superconducting layer, over a second insulating layer.
12. The method according to claim 1, further comprising storing digital information in a state of the magnetic state of the non-superconducting magnetic material.
13. The method according to claim 1, wherein the non-superconducting magnetic material is formed in a layer having a thickness larger than a respective superconducting coherence length of the non-superconducting magnetic material, and a thickness smaller than a quasiparticle energy diffusion length of both the non-superconducting magnetic material and an adjacent superconducting layer, and a thickness smaller than the adjacent superconducting layer.
14. The method according to claim 1, further comprising injecting quasiparticles into a superconducting layer, to create a non-equilibrium state with suppressed superconducting energy gap in the respective superconducting layer, from the non-superconducting magnetic material.
15. The method according to claim 1, wherein the write port is further configured to persistently change the magnetic state of the non-superconducting magnetic material between at least two different magnetic states comprises a first state associated with a generated single flux quantum (SFQ) pulse, and a second state associated with suppression of a generated single flux quantum (SFQ) pulse.
16. The method according to claim 1, further comprising a second Josephson junction in series with the superconducting electronic device, comprising a pair of superconducting layers with an intervening insulating layer.
17. The method according to claim 1, wherein the write port comprises a magnetic thin film transformer.
18. The method according to claim 1, wherein the intervening barrier comprises at least one non-superconducting ferromagnetic magnetic material film, and at least one insulating material film, and the superconducting electronic device is configured to act as a digital memory cell.
19. A method of operating a superconducting electronic device, comprising: generating pulses with a Josephson junction, comprising a pair of superconducting films, separated by an intervening barrier comprising a non-superconducting magnetic material, which impedes direct tunneling between the pair of superconducting films, a magnetic state of the non-superconducting magnetic material altering a property of the Josephson junction; a pair of electrodes connected to the pair of superconducting films, configured to impose a voltage across the intervening barrier; and a write port, configured to persistently change the magnetic state of the non-superconducting magnetic material; and persistently changing the magnetic state of the non-superconducting magnetic material based on a signal at the write port, to thereby change a pattern of the generated pulses dependent on the magnetic state of the non-superconducting magnetic material.
20. A method of operating a superconducting electronic device, comprising: storing a magnetic state of a non-superconducting magnetic material; imposing a voltage across a pair of electrodes; generating pulses dependent on the stored magnetic state of a non-superconducting magnetic material, with a Josephson junction, comprising a pair of superconducting films connected to the pair of electrodes, separated by an intervening barrier comprising the non-superconducting magnetic material, which impedes direct tunneling between the pair of superconducting films; changing the magnetic state of the non-superconducting magnetic material by a signal at a write port, to thereby change the pulses of the Josephson junction.
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
(1) These and other features of the present invention will become apparent from the accompanying detailed description and drawings, wherein:
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DETAILED DESCRIPTION
(13) Superconducting digital electronics typically is based on the motion of a magnetic single flux quantum (SFQ) pulse with integrated voltage Φ.sub.0=h/2e=2 mV-ps=2 mA-pH. It is well known that this same quantity also provides the basis for non-volatile storage in memory cells with stored magnetic flux Φ=LI˜Φ.sub.0, where L is the inductance of a superconducting loop, and I is the lossless current around the loop. This loop may also comprise one or more Josephson junctions, provided that the current I is less than the critical current Ic of the junction(s).
(14) A Josephson junction (JJ) comprises two superconducting layers with a thin insulating or normal-metallic layer between them (SIS or SNS). For example, this may be Nb/Al/AlOx/Nb, where the Al is sufficiently thin to be induced into the superconducting state, for circuits that are designed to operate at ˜5° K or below. It is known in the art that a magnetic field applied in the plane of the JJ will modulate the critical current Ic according to a sinc function dependence: (|sin(x)/x|), where x=πΦ/Φ.sub.0 and Φ is the magnetic flux inside the junction.
(15) A Josephson junction is a 2-terminal device, which when biased above its critical current Ic, can generate a time-series of SFQ pulses. The Ic of a given JJ is effectively a constant. Although Ic varies with temperature, thermal switching of Ic is generally not useful for fast electronics. In comparison, a switchable MJJ has an Ic that may be tuned over a range of values. Because the barrier of an MJJ contains a ferromagnetic material, which being a permanent magnet material has hysteresis, the stable magnetic flux in the junction may have (at least) two different values. These correspond to two different values of the critical current, Ic, and one may repeatedly switch between them. The non-volatile aspect, namely that magnetization stays on after the stimulation has ceased, makes this switchable MJJ useful as a memory element. The term “ferromagnetic material” is being used in this disclosure in its broadest sense, namely, meaning that a state of magnetization of the material remains even after any external stimulus has been terminated, and the magnetization has a hysteretic behavior. By way of example, without intent of limiting, ferromagnetic materials include Fe, Co, Ni, some rare earth elements, and alloys of all of these.
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(17) One may also combine JJs and MJJs in the same circuit. For example, one may adapt a standard JJ comparator comprising two Josephson junctions in series. If an input SFQ pulse enters on the top, in one mode of operation, either the JJ or the MJJ will switch, regenerating an SFQ pulse. In general, the junction with the lower value of Ic will switch. Therefore, if the MJJ has a critical current that is less than Ic0 of the JJ, there will be an SFQ pulse appearing on the output line. This corresponds to a binary state of “1”, or true value, stored in the MJJ. On the other hand, if the MJJ has a critical current that is greater than Ic0 of the JJ, the JJ will switch, while the MJJ will not, and there will be no SFQ pulse on the output line. This corresponds to a binary state of “0” stored in the MJJ. It is understood, or course, that the binary assignment could be the other way around, with a pulse meaning “0” and the lack of a pulse meaning “1”. If the MJJ is designed so that it can be repeatedly switched between a value of Ic less than Ic0 and one that is greater than Ic0, this forms a memory cell. One could use an MJJ as either the lower, or the upper junction. One can also switch the roles, and the assigned binary state values, of the two junctions.
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(22) As miniaturization progresses, junction areas will be ever smaller. It may happen that in a scaled MJJ the ferromagnetic material, which typically, but not necessarily, forms a ferromagnetic layer, has only a few, possibly only a single, magnetic domain. To decisively control the magnetization of such small junctions it may be useful to be able to rotate the barrier magnetization not only in the plane of the MJJ, but also in the plane perpendicular to it. One can define a horizontal plane, or the plane of the MJJ, as the plane which is parallel with its layer(s) of the barrier. Such rotation of the magnetization vector in the perpendicular plane, may be best accomplished by spin injection and with non-planar, or non-horizontal, transformers. In a high-density memory array applications line widths would be preferred to be ˜1 μm or less.
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(24) MJJs are already known in the art. In one representative embodiment, a possible MJJ junction may have a composition of Nb/Pd.sub.0.99FeO.sub.0.01/Nb. The given ratio of the PdFe material should not be interpreted as limitation, it is for illustrative purposes. Other materials besides the PdFe compositions are available, as well.
(25) The preferred magnetic material for cryogenic applications may be one that is easily switched with a small control current at the temperature of operation. Materials optimized for room temperature are likely to have a value of the coercive field Hc, namely a sufficient applied magnetic field for switching the magnetic state of the junction, that becomes impractically large at cryogenic temperatures ˜4° K. Conversely, a ferromagnetic material that is magnetically soft, i.e., it has low Hc at 4° K, may not even be a ferromagnet at room temperature. For example, an alloy of Pd with ˜1% Fe has a Curie temperature only about 20-30° K, but this may be chosen in some embodiments for a 4° K device, since its value of Hc is in the range of a few Oe, maybe about 1 Oe (˜100 A/m in SI units). In a switchable MJJ, the value of Ic, and the corresponding I-V characteristic, would be repeatedly switched back and forth between two different values, as controlled by an appropriate write pulse. The above discussion should not be read in a limiting fashion, other compositions of these materials, and other ferromagnetic materials may also be used for MJJ application.
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(27) When a memory cell device is integrated into a memory array, there may be a need for further peripheral circuits, as well, for interfacing to logic circuits. Such are already generally available in the relevant arts. For instance, addressing may follow Kirichenko et al., in U.S. Pat. No. 7,443,719 “Superconducting circuit for high-speed lookup table” (2008), or “Pipelined dc powered SFQ RAM”, IEEE Trans. Appl. Supercond., vol. 11, p. 537 (2001), or Yuh et al., “One-junction superconducting memory cell with column sense”, IEEE Trans. Appl. Supercond., vol. 5, p. 3459 (1995), or Polonsky, et al., “Rapid Single Flux Quantum Random Access Memory”, IEEE Trans. Appl. Supercond., vol. 5, p. 3000 (1995).
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(29) X and Y-directional write lines, each pertaining to one of the rows and one of the columns respectively, couple to the write ports of the memory cells. A selected X-directional write line and a selected Y-directional write line in their combination are capable of inducing a switch between the states of magnetization in the memory cell that is located at their intersection. The figure schematically depicts an inductive write scheme such as that of
(30) Each memory cell has a read contact, or port, for interrogating the binary state of the MJJ, which read port can accept the read SFQ pulse. Furthermore, each memory cell has a bias current line. The bias current lines are typically arranged in the Y direction.
(31) There is no obvious upper limit for the size of such a randomly accessible memory array (RAM). It is a question of general progress with fabrication techniques, and shrinking of line widths. For example, a 1 MB RAM, 1000 rows and columns each, in an area of 1 cm.sup.2, when one includes array addressing, read, and write circuits, would entail that each memory cell be approximately about 5 μm apart for a two-dimensional array. Such density is already achievable. With finer lithography line width, each memory cells can be as small as tens of nanometers apart. It is understood that the memory array is not constrained to have equal number of rows and columns.
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(33) As depicted
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(35) There may be practically no limit to the applicability of such superconducting memories based on MJJ cells. Without limiting intent, they may be used as Superconducting Ferromagnetic Random Access Memory (SF-RAM), various levels of cache memory, main memory, register files, look-up tables, memory controlled logic: similar to FPGAs (SF-PGAs or MPGAs), and various combinations of these.
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(37) The material making up the junction shown in
(38) Remaining with structural considerations,
(39) The multi-layer fabrication of superconducting logic circuits, up to computer processor complexity, based on JJs has already been demonstrated in the art. The
(40) The memory cells, and arrays disclosed in the instant application may be advantageously interfaced with as broad a range of superconducting devices as possible. It is further advantageous of having devices in the same ferromagnetic junction fabrication schemes as the memory arrays themselves. Embodiment of such a device, exhibiting gain, is discussed now.
(41) The middle electrode in the device is a bilayer comprising of a superconductor S.sub.2 in proximity with a ferromagnetic metal F.sub.2. That is, both the F.sub.1 and F.sub.2 ferromagnetic metal layers in the device are adjacent to the injector tunnel barrier from both sides. In case if the SFIFSIS structure performs a role of readout device in a memory cell, the SFIFS part of it should not exhibit the superconducting current. This can be realized if the layers F.sub.1 and F.sub.2 are in the normal (non-superconducting) state while being in proximity with the superconducting layers S.sub.1 and S.sub.2, respectively. In turn this can be realized if their superconducting coherence lengths, ξ.sub.F1 and ξ.sub.F2, which determine the decay of the superconducting order parameter, are shorter than their respective thicknesses, d.sub.F1 and d.sub.F2. At the same time, the thickness of the F.sub.2 layer has to be kept as small as possible (smaller than the quasiparticle energy diffusion length both in F.sub.2 and in S.sub.2, and smaller than the thickness of the S.sub.2 layer that itself has to be as thin as possible in order to provide high concentration of the injected quasiparticles); the small thickness of the F.sub.2 layer is necessary to reduce trapping in it of the quasiparticles injected into the S.sub.2/F.sub.2 bilayer from the injector junction. The majority of injected quasiparticles are transferred to the superconducting S.sub.2 layer to create therein a non-equilibrium state with suppressed superconducting energy gap. On the other hand, the thickness of the F.sub.2 layer has to be large enough to prevent direct tunneling from the S.sub.2 layer to the F.sub.1S.sub.1 bilayer, which can be realized if the quasiparticle mean free path in the F.sub.2 layer is short. The role of the F.sub.2 layer is therefore to screen the manifestation of the energy gap of the superconducting layer S.sub.2 in the I-V curve of the injector junction. Similarly, the role of the F.sub.1 layer is therefore to screen the manifestation of the energy gap of the superconducting layer S.sub.1 in the I-V curve of the injector junction. The F.sub.1 layer may have the same properties as the F.sub.2 layer (small thickness, short coherence length, and short mean free path), if it is in proximity with the superconducting S.sub.1 layer, but the requirement of having small thickness can be relaxed. For fabrication reasons, this layer will have approximately the same thickness as the F.sub.2 layer.
(42) The technique for fabrication of Nb/Al multi-terminal devices comprising of two stacked tunnel junctions may include additional Ni layers. Ni cannot be etched by Reactive Ion Etching (RIE) using traditional reactive gases (CF.sub.4 and SF.sub.6). Appropriate treatment of the Ni layers using ion milling may be needed in the processing of the entire structure.
(43) The current-voltage characteristics of the acceptor (S.sub.2I.sub.2S.sub.3) and the injector (S.sub.1F.sub.1I.sub.1F.sub.2S.sub.2) junctions can be recorded using the electric contacts, C. The S.sub.2 superconducting layer may have either one or two contacts (the configuration with two contacts is shown in
(44) Indeed, according to their properties as described above, the S.sub.1F.sub.1 and F.sub.2S.sub.2 electrodes in the injector S.sub.1F.sub.1I.sub.1F.sub.2S.sub.2 junction manifest themselves as normal (non-superconducting) electrodes, and therefore, the I-V curve of the injector junction can be described according to the formulae for the tunneling between the normal metals as known in the arts:
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(46) where A is a constant; T is the tunneling matrix element; .sub.1(0) and
.sub.2(0) are electronic densities of states at the Fermi level of the F.sub.1 and F.sub.2 layers, respectively; f(E) is the Fermi distribution function; eV is the chemical potential difference between the S.sub.1F.sub.1 and F.sub.2S.sub.2 electrodes; and G.sub.NN is conductivity of the junction. It is clear from the above formulae that the injector junction has a linear I-V curve, and that this I-V curve is not affected by the quasiparticle injection from the acceptor junction in a reasonable approximation that the Fermi distribution functional form is preserved under the injection.
(47) One may consider the properties of the non-superconducting materials F.sub.1 and F.sub.2 in a more detail. The coherence length in the ferromagnetic Ni layer can be expressed as ξ.sub.Ni=√{square root over (ℏν.sub.Fl.sub.Ni/6πk.sub.BT.sub.C)}, where T.sub.C is the Curie temperature, T.sub.C˜600 K for Ni films. From resistivity measurements, with ρ.sub.Ni=6.9 μΩcm and the mean free path l.sub.Ni=2.7 nm in Ni at 300 K, one deduces l.sub.Ni=3.2 nm at 4.2 K. Using ν.sub.F=0.28×10.sup.8 cm/s, one estimates the ξ.sub.Ni to be 0.7 nm. The penetration depth of the superconducting order parameter in the normal metal is b.sub.N≅[ρ.sub.N/ρ.sub.S]ξ.sub.N, where ρ.sub.N and ρ.sub.S are the resistivities of the normal and superconducting layers, respectively, and ξ.sub.N is the coherence length of the normal layer. Applying this relation to the Ni layer, one obtains b.sub.Ni≅0.8 nm; hence the I-V curve of the Nb.sub.(1)/Ni/AIO.sub.x/Ni/Nb.sub.(2) injector junction in the devices will not display any superconducting energy gap of the Nb.sub.(1)/Ni and Ni/Nb.sub.(2) bilayers, even if the thickness of the Ni layer, d.sub.Ni, is considerably less than 7.5 nm. Therefore the I-V curve of the injector junction will be insensitive to the gap suppression in the Nb.sub.(1) and Nb.sub.(2) layers, the property that provides isolation in the device.
(48) The isolation between the acceptor and the injector junctions can be characterized by the ratio of transresistances, R.sub.m(a)/R.sub.m(i). The SFIFSIS device of
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(50) Such a SFIFSIS device could be used, for example, to provide gain and buffering between the write line of the magnetic memory cell and the RSFQ circuits. It also can be used for a sense line amplifier. It also can be used as a part of cryogenic non-superconducting STT-RAM cells (Spin Transfer Torque Random Access Memory) instead of an FET (field-effect transistor) to facilitate readout function.
(51) In the foregoing specification, the invention has been described with reference to specific embodiments. However, one of ordinary skill in the art appreciates that various modifications and changes can be made without departing from the scope of the present invention as set forth in the claims below. Accordingly, the specification and figures are to be regarded in an illustrative rather than a restrictive sense, and all such modifications are intended to be included within the scope of present invention.
(52) Benefits, other advantages, and solutions to problems have been described above with regard to specific embodiments. However, the benefits, advantages, solutions to problems, and any element(s) that may cause any benefit, advantage, or solution to occur or become more pronounced are not to be construed as a critical, required, or essential feature or element of any or all the claims.
(53) Many modifications and variations of the present invention are possible in light of the above teachings, and could be apparent for those skilled in the art. The scope of the invention is defined by the appended claims.