Method of Using TIG Welding Flux for Super Duplex Stainless Steel

Abstract

A method of using a tungsten inert gas (TIG) welding flux for super duplex stainless steel (SDSS) is used to solve the problems of low weld depth/width ratio, low corrosion resistance, and arc blow existing in the conventional TIG welding flux for duplex stainless steel. The TIG welding flux for SDSS includes 20-30 wt % of silicon dioxide (SiO.sub.2), 20-25 wt % of titanium dioxide (TiO.sub.2), 15-20 wt % of vanadium dioxide (VO.sub.2), 10-15 wt % of molybdenum trioxide (MoO.sub.3), 10-15 wt % of zirconium diboride (ZrB.sub.2), 5-10 wt % of aluminum nitride (AlN), 5-10 wt % of manganese carbonate (MnCO.sub.3) and 5-10 wt % of nickel carbonate (NiCO.sub.3).

Claims

1. A method of using a tungsten inert gas (TIG) welding flux for super duplex stainless steel (SDSS), comprising: dispersing the TIG welding flux for SDSS in a volatile solvent, forming a paste-like slurry, wherein the TIG welding flux for SDSS comprises 20-30 wt % of silicon dioxide (SiO.sub.2), 20-25 wt % of titanium dioxide (TiO.sub.2), 15-20 wt % of vanadium dioxide (VO.sub.2), 10-15 wt % of molybdenum trioxide (MoO.sub.3), 10-15 wt % of zirconium diboride (ZrB.sub.2), 5-10 wt % of aluminum nitride (AlN), 5-10 wt % of manganese carbonate (MnCO.sub.3) and 5-10 wt % of nickel carbonate (NiCO.sub.3); spreading the paste-like slurry on surfaces of two workpieces of SDSS; and performing a TIG welding process to join the two workpieces of SDSS into a welded assembly.

2. The method of using the TIG welding flux for SDSS as claimed in claim 1, wherein the TIG welding flux for SDSS comprises 5-9 wt % of AlN, 5-7 wt % of MnCO.sub.3 and 5-7 wt % of NiCO.sub.3.

3. The method of using the TIG welding flux for SDSS as claimed in claim 1, wherein the TIG welding flux for SDSS comprises 5 wt % of AlN, 5 wt % of MnCO.sub.3 and 5 wt % of NiCO.sub.3.

4. The method of using the TIG welding flux for SDSS as claimed in claim 1, further comprising a volatile solvent.

5. The method of using the TIG welding flux for SDSS as claimed in claim 1, wherein the volatile solvent comprises methanol, acetone or isopropanol.

6. The method of using the TIG welding flux for SDSS as claimed in claim 1, wherein the TIG welding flux for SDSS has a plurality of powdered particles each having a diameter of 50-90 μm.

7. The method of using the TIG welding flux for SDSS as claimed in claim 1, wherein the TIG welding flux for SDSS comprises 5 wt % of AlN, 10 wt % of MnCO.sub.3 and 5 wt % of NiCO.sub.3.

8. The method of using the TIG welding flux for SDSS as claimed in claim 1, wherein the TIG welding flux for SDSS consists of 20-30 wt % of SiO.sub.2, 20-25 wt % of TiO.sub.2, 15-20 wt % of VO.sub.2, 10-15 wt % of MoO.sub.3, 10-15 wt % of ZrB.sub.2, 5-10 wt % of AlN, 5-10 wt % of MnCO.sub.3 and 5-10 wt % of NiCO.sub.3.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0018] The present invention will become more fully understood from the detailed description given hereinafter and the accompanying drawings which are given by way of illustration only, and thus are not limitative of the present invention, and wherein:

[0019] FIG. 1 depicts a cross-sectional view of a weld of group B08, which is formed between joined two SDSS workpieces by the TIG welding process utilizing the TIG welding flux of group A08.

[0020] FIG. 2 depicts a cross-sectional view of a weld of group B12, which is formed between joined two SDSS workpieces by the TIG welding process utilizing the TIG welding flux of group A12.

[0021] FIG. 3 depicts a cross-sectional view of a weld of group B17, which is formed between joined two SDSS workpieces by the TIG welding process without the TIG welding flux.

DETAILED DESCRIPTION OF THE INVENTION

[0022] A TIG welding flux for SDSS according to a specific embodiment of the present invention can include 20-30 wt % of SiO.sub.2 (silicon dioxide), 20-25 wt % of TiO.sub.2 (titanium dioxide), 15-20 wt % of VO.sub.2 (vanadium dioxide), 10-15 wt % of MoO.sub.3 (molybdenum trioxide), 10-15 wt % of ZrB.sub.2 (zirconium diboride), 5-10 wt % of AlN (aluminum nitride), 5-10 wt % of MnCO.sub.3 (manganese carbonate) and 5-10 wt % of NiCO.sub.3 (nickel carbonate). In another specific embodiment, the TIG welding flux for SDSS includes 9 wt % of AlN, 5 wt % of MnCO.sub.3 and 5 wt % of NiCO.sub.3. In another specific embodiment, the TIG welding flux for SDSS includes 5 wt % of AlN, 6 wt % of MnCO.sub.3 and 5 wt % of NiCO.sub.3. In another specific embodiment, the TIG welding flux for SDSS includes 5 wt % of AlN, 5 wt % of MnCO.sub.3 and 5 wt % of NiCO.sub.3. In another specific embodiment, the TIG welding flux for SDSS includes 9 wt % of AlN, 5 wt % of MnCO.sub.3 and 6 wt % of NiCO.sub.3. In another specific embodiment, the TIG welding flux for SDSS includes 6 wt % of AlN, 6 wt % of MnCO.sub.3 and 5 wt % of NiCO.sub.3. In another specific embodiment, the TIG welding flux for SDSS includes 5 wt % of AlN, 10 wt % of MnCO.sub.3 and 5 wt % of NiCO.sub.3.

[0023] Accordingly, when two SDSS workpieces are joined by the TIG welding process utilizing the TIG welding flux for SDSS, with specific weight percentages of SiO.sub.2, TiO.sub.2, VO.sub.2, MoO.sub.3, ZrB.sub.2, AlN, MnCO.sub.3 and NiCO.sub.3, according to the present invention, a weld between the two joined SDSS workpieces has a weld D/W ratio more than or equal to 0.8. Thus, a relative smaller HAZ can be obtained, reducing the risk of problems such as thermal deformation and residual stress of the weldment. The weld metal has a higher austenite phase content than a ferrite phase content, improving the corrosion resistance of the weld. Moreover, no arc blow occurs during the TIG welding.

[0024] In a specific embodiment, the TIG welding flux for SDSS according to the present invention can further include a volatile solvent. In another specific embodiment, the volatile solvent can include, but not limited to, methanol, acetone or isopropanol.

[0025] In a specific embodiment, the TIG welding flux for SDSS according to the present invention can have a plurality of powdered particles each having a diameter of 50-90 μm.

[0026] In a specific embodiment, the TIG welding flux for SDSS according to the present invention can be applied to join two workpieces made of SDSS including, but not limited to, UNS 532750 and UNS 532760.

[0027] To validate whether a weld between the two joined SDSS workpieces has a higher weld D/W ratio and a better corrosion resistance, as well as whether arc blow occurs during the TIG welding, when two SDSS workpieces are joined by the TIG welding process utilizing the TIG welding flux for SDSS according to the present invention, the following trials are carried out.

[0028] Trial (A).

[0029] Powdered particles of SiO.sub.2, TiO.sub.2, VO.sub.2, MoO.sub.3, ZrB.sub.2, AlN, MnCO.sub.3 and NiCO.sub.3 are mixed according to TABLE 1. The TIG welding fluxes of groups A1-A15 are prepared by forming paste-like slurries by dispersing the mixtures in acetone.

TABLE-US-00001 TABLE 1 SiO.sub.2 TiO.sub.2 VO.sub.2 MoO.sub.3 ZrB.sub.2 AlN MnCO.sub.3 NiCO.sub.3 Groups (wt %) (wt %) (wt %) (wt %) (wt %) (wt %) (wt %) (wt %) A01 20 20 15 11 11 10 7 6 A02 20 25 15 10 15 5 5 5 A03 20 22 16 15 10 6 6 5 A04 21 21 18 10 10 9 5 6 A05 23 20 20 10 10 5 5 7 A06 25 20 15 10 10 5 10 5 A07 25 20 15 10 10 5 5 10 A08 26 20 15 10 10 9 5 5 A09 28 20 15 10 10 5 6 5 A10 30 20 15 10 10 5 5 5 A11 20 25 20 15 10 0 5 5 A12 25 23 15 10 15 2 0 10 A13 25 22 15 10 15 3 10 0 A14 28 21 15 10 15 7 2 2 A15 30 20 15 11 11 4 5 4

[0030] Moreover, powdered particles of SiO.sub.2, Cr.sub.2O.sub.3, MoO.sub.3, NiO, Fe.sub.2P.sub.3. Co.sub.3O.sub.4, MnO.sub.2 and CuO are mixed according to TABLE 2. The conventional TIG welding flux of group A16 is prepared by forming paste-like slurries by dispersing the mixtures in acetone.

TABLE-US-00002 TABLE 2 SiO.sub.2 Cr.sub.2O.sub.3 MoO.sub.3 NiO Fe.sub.2O.sub.3 Co.sub.3O.sub.4 MnO.sub.2 CuO Group (wt %) (wt %) (wt %) (wt %) (wt %) (wt %) (wt %) (wt %) A16 30 23 12 10 7 10 5 3

[0031] Trial (B).

[0032] In this trial, UNS 532750 plates with thickness being 6.0 mm are used as the SDSS workpieces. After removing contaminants attached on surface of the SDSS workpieces using a 400-grit silicon carbide sandpaper. The SDSS workpieces are swiped by acetone wipes. Then, the paste-like slurries formed by TIG welding fluxes for SDSS of groups A01-A16 are spread on surface of the two SDSS workpieces. The TIG welding process is carried out after acetone is completely evaporated to obtain the welded assembly (the joined two workpieces) of groups B1-B16, as shown in TABLE 3. In addition, a welded assembly of group B17 is obtained by the TIG welding without the TIG welding flux of groups A01-16.

TABLE-US-00003 TABLE 3 Group TIG welding flux used during the TIG welding B01 Group A01 (the TIG welding flux for SDSS according to the present invention) B02 Group A02 (the TIG welding flux for SDSS according to the present invention) B03 Group A03 (the TIG welding flux for SDSS according to the present invention) B04 Group A04 (the TIG welding flux for SDSS according to the present invention) B05 Group A05 (the TIG welding flux for SDSS according to the present invention) B06 Group A06 (the TIG welding flux for SDSS according to the present invention) B07 Group A07 (the TIG welding flux for SDSS according to the present invention) B08 Group A08 (the TIG welding flux for SDSS according to the present invention) B09 Group A09 (the TIG welding flux for SDSS according to the present invention) B10 Group A10 (the TIG welding flux for SDSS according to the present invention) B11 Group A11 (the TIG welding flux without A1N) B12 Group A12 (the TIG welding flux without MnCO.sub.3) B13 Group A13 (the TIG welding flux without NiCO.sub.3) B14 Group A14 (the TIG welding flux with 2% of MnCO.sub.3 and 2% of NiCO.sub.3) B15 Group A15 (the TIG welding flux with 4% of NiCO.sub.3) B16 Group A16 (the conventional TIG welding flux) B17 No

[0033] During the TIG welding for obtaining the joined two SDSS workpieces of groups B01-B17, the occurrences of arc blow are recorded. After the TIG welding, cross sections of the joined two SDSS workpieces of groups B01-B17 are obtained. The weld depth “D” and the bead width “W” of the resultant weld between the jointed two SDSS workpieces of groups B01-B17 are recorded. NM stands for not measured. The weld D/W ratio of groups B01-B17 is calculated. Moreover, the ferrite phase content of the weld metal between the joined two SDSS workpieces of groups B01-B17 is also measured, and the ferrite/austenite phase ratio is calculated. All results are shown in TABLE 4.

TABLE-US-00004 TABLE 4 Ferrite/ Weld depth Bead width Weld D/W austenite Arc blow Groups (mm) (mm) ratio phase ratio occurs B01 5.7 7.1 0.80 38%/62% No B02 5.8 6.9 0.84 47%/53% No B03 6.0 6.8 0.88 41%/59% No B04 6.2 7.0 0.89 40%/60% No B05 6.1 7.1 0.86 46%/54% No B06 5.9 6.8 0.87 45%/55% No B07 5.8 7.0 0.83 44%/56% No B08 7.1 7.3 0.97 40%/60% No B09 6.8 7.4 0.92 47%/53% No B10 6.9 7.6 0.91 46%/54% No B11 NM NM NM 58%/42% Yes B12 4.1 9.6 0.43 56%/44% Yes B13 NM NM NM 55%/45% Yes B14 NM NM NM 53%/47% Yes B15 NM NM NM 54%/46% Yes B16 NM NM NM 60%/40% Yes B17 2.8 10.7  0.26 64%/36% No

[0034] FIGS. 1-3 show the cross sections of the joined two SDSS workpieces of groups B08, B12 and B17, respectively. The weld between the jointed two SDSS workpieces of group B08 completely penetrates the SDSS workpiece, while the weld between the two jointed SDSS workpieces of groups B12 and B17 cannot completely penetrate the SDSS workpiece. Moreover, referring to TABLE 3 and FIGS. 1-3, compared to the welds between the jointed two SDSS workpieces of groups B12 and B17, the welded joint of groups B01-B10 has an increased weld depth and a reduced bead width. The weld D/W ratio of the resultant weld of groups B01-B10 is more than or equal to 0.8, and even up to 0.97. Thus, relative smaller HAZ can be obtained, reducing the risk of problems such as thermal deformation and residual stress of the weldment.

[0035] Moreover, referring to TABLE 3, compared to the welds between the jointed two SDSS workpieces of groups B11-B17, the welds between the jointed two SDSS workpieces of groups B01-B10 have a lower ferrite phase content, which is lower than 50%. That is, the welds between the jointed two SDSS workpieces of groups B01-B10 have an austenite phase content higher than the ferrite phase content, indicating the weld between the jointed two SDSS workpieces of groups B01-B10 have good corrosion resistance. In addition, no arc blow occurs during the TIG welding for forming the joined two SDSS workpieces of groups B01-B10.

[0036] Accordingly, when two SDSS workpieces are joined by the TIG welding process utilizing the TIG welding flux for SDSS, with specific weight percentages of SiO.sub.2, TiO.sub.2, VO.sub.2, MoO.sub.3, ZrB.sub.2, AlN, MnCO.sub.3 and NiCO.sub.3, according to the present invention, the weld between the two joined SDSS workpieces has a weld D/W ratio more than or equal to 0.8. Thus, a relative smaller HAZ can be obtained, reducing the risk of problems such as thermal deformation and residual stress of the weldment. The weld metal has a higher austenite phase content than a ferrite phase content, improving the corrosion resistance of the weld. Moreover, no arc blow occurs during the TIG welding.

[0037] Although the invention has been described in detail with reference to its presently preferable embodiment, it will be understood by one of ordinary skill in the art that various modifications can be made without departing from the spirit and the scope of the invention, as set forth in the appended claims.