STEERING WHEEL

Abstract

A steering wheel includes a core and a foamed polyurethane coating that covers a ring section of the core. The foamed polyurethane coating is formed by foam molding of a polyurethane material containing 91 parts by mass of a base polyol, 10 to 25 parts by mass of a pigment, 1 to 3 parts by mass of a benzotriazole ultraviolet absorber, 0.8 to 2.5 parts by mass of a hindered amine photostabilizer, and a polyisocyanate. A total amount of the ultraviolet absorber and the photostabilizer is 2.7 parts by mass or more. The foamed polyurethane coating is in the form of an integral skin foam including a highly foamed core foam and a lowly foamed skin layer. The surface of the skin layer is not provided with a coating film formed from a coating material, and serves as a product surface that assumes a color of the pigment.

Claims

1. A steering wheel comprising a core, and a foamed polyurethane coating that covers a ring section of the core, wherein: the foamed polyurethane coating is formed by foam molding of a polyurethane material containing 91 parts by mass of a base polyol, 10 to 25 parts by mass of a pigment, 1 to 3 parts by mass of a benzotriazole ultraviolet absorber, 0.8 to 2.5 parts by mass of a hindered amine photostabilizer, and a polyisocyanate, wherein a total amount of the ultraviolet absorber and the photostabilizer is 2.7 parts by mass or more; the foamed polyurethane coating is in the form of an integral skin foam including a highly foamed core foam and a lowly foamed skin layer; the skin layer has a non-foamed surface and a thickness of 50 μm or more, wherein a degree of foaming increases with an increase in depth from the surface, and the skin layer ranges from the surface to a depth at which a specific gravity is 90% of that at the surface; and the surface of the skin layer is not provided with a coating film formed from a coating material, and serves as a product surface that assumes a color of the pigment.

Description

BRIEF DESCRIPTION OF DRAWINGS

[0025] FIGS. 1A to 1C show a steering wheel of each Example, where

[0026] FIG. 1A is a front view, FIG. 1B is a Ib-Ib cross-sectional view, and FIG. 1C is an enlarged view of an arrow-indicating portion Ic of a foamed polyurethane coating;

[0027] FIG. 2 is a graph showing the relationship between the depth from the surface of the foamed polyurethane coating of the Example and the specific gravity thereof; and

[0028] FIGS. 3A and 3B show an apparatus and method for molding the foamed polyurethane coating, where FIG. 3A is a plan view of a lower die, and FIG. 3B is a cross-sectional view of the lower die.

DESCRIPTION OF EMBODIMENTS

[0029] [1] Base Polyol

[0030] Examples of the base polyol used in the polyurethane material include, but are not particularly limited to, polyether polyols (e.g., polypropylene glycol (PPG), polyethylene glycol (PEG), and polyoxytetramethylene glycol (PTMG)), polyester polyols, and polymer polyols. These polyols may be used in combination of plural species.

[0031] [2] Polyisocyanate

[0032] Examples of the polyisocyanate used in the polyurethane material include, but are not particularly limited to, known aliphatic, alicyclic, and aromatic organic isocyanate compounds having two or more isocyanate groups. These compounds may be used in combination of plural species. Specific examples of the polyisocyanate include hexamethylene diisocyanate, isophorone diisocyanate, 4,4-dicyclohexylmethane diisocyanate, 2,4- or 2,6-tolylene diisocyanate (toluene diisocyanate or toluidine diisocyanate: TDI), alkylene diisocyanate or arylene isocyanate such as 2,2′- or 2,4- or 4,4′-diphenylmethane diisocyanate (MDI), and known triisocyanates and polymeric MDI.

[0033] [3] Pigment

[0034] Examples of the pigment include, but are not particularly limited to, carbon black and ceramic materials.

[0035] No particular limitation is imposed on the diameter (aggregation diameter) of the pigment contained in the foamed polyurethane coating, but the diameter is preferably 250 nm or less, more preferably 150 nm or less.

[0036] [4] Benzotriazole Ultraviolet Absorber

[0037] Examples of the benzotriazole ultraviolet absorber include, but are not particularly limited to, 2-(2-hydroxy-5-methylphenyl)benzotriazole, 2-(2-hydroxy-4,6-di-tert-phenyl)benzotriazole, 2-(3-tert-butyl-2-hydroxy-5-methylphenyl)-5-chlorobenzotria zole, and a three-component mixture

((α-[3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hy droxyphenyl]-1-oxopropyl]-ω-hydroxypoly(oxo-1,2-ethanediyl), α-[3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl]-ω-[3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropoxy]poly(oxy-1,2-ethanediyl), H(OCH2CH2)6-7OH).

[0038] [5] Hindered Amine Photostabilizer

[0039] Examples of the hindered amine photostabilizer include, but are not particularly limited to, bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-[[3,5-bis(1,1-dime thylethyl)-4-hydroxyphenyl]methyl], and a two-component mixture (bis(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate, methyl(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate).

[0040] [6] Additional Compounding Agent

[0041] The polyurethane material may contain, besides the aforementioned components, a catalyst, a foam stabilizer, an antioxidant, a foaming agent, etc. If necessary, the polyurethane material may further contain, for example, a filler or a flame retardant.

[0042] [7] Foaming

[0043] Examples of the type of foaming of the foamed polyurethane coating include, but are not particularly limited to, foaming under reduced pressure (bumping of occluded gas passively contained in the polyurethane material under reduced pressure), foaming with a foaming agent, and foaming by combination of these.

[0044] Examples of the foaming agent include, but are not particularly limited to, water (generation of CO.sub.2 through promotion of the reaction between water and the isocyanate).

Examples

[0045] Next will be described Examples of the present invention together with Comparative Examples. The structure, material, shape, and size of each section in the Examples are merely an example, and they may be appropriately modified without departing from the spirit of the invention.

[0046] As shown in FIGS. 1A to 1C, the steering wheel of each of the Examples and Comparative Examples includes a core 4 having a boss section 5, a spoke section 6, and a ring section 7; a foamed polyurethane coating 1 that covers the ring section 7 and a portion of the spoke section 6; and a pad 8 disposed on the boss section 5 and the spoke section 6.

[0047] The foamed polyurethane coating 1 is in the form of an integral skin foam including a highly foamed core foam 2 and a lowly foamed skin layer 3. The terms “highly foamed” and “lowly foamed” as used herein refer to relative concepts. The skin layer 3 has a non-foamed surface, and the degree of foaming increases with an increase in depth from the surface. The skin layer 3 ranges from the surface to a depth at which the specific gravity is 90% of that at the surface. The surface of the skin layer 3 is not provided with a coating film formed from a coating material, and serves as a product surface that assumes a color of the aforementioned pigment.

[0048] The polyurethane coating 1 is formed by RIM molding using the material, molding apparatus, and method described below.

[0049] The polyurethane materials (main agent and curing agent) of Examples 1 to 4 and Comparative Examples 1 to 5 for RIM molding of polyurethane coatings were prepared to achieve formulations shown in Table 1 below.

TABLE-US-00001 TABLE 1 Comparative Comparative Comparative Comparative Comparative Example 1 Example 2 Example 3 Example 4 Example 5 Formulation Main Base PPG part by 91 ← ← ← ← Agent Polyol mass Crosslinking Low-molecular- part by 15.5 ← ← ← ← Agent weight Diol mass Catalyst Amine part by 6.8 ← ← ← ← mass Foam Silicone part by 0.7 ← ← ← ← Atabilizer mass Ultraviolet Tinuvin213 part by 0 1.sub.  2.sub.  1.sub.  1.5 Absorber mass Photostabilizer Tinuvin765 part by 0.4 0.5 0.5 1.5 1.sub.  mass Antioxidant Irganox1135 part by 0.2 0.2 0.2 0.2 0.2 mass Pigment Carbon part by 15 ← ← ← ← Black mass Foaming Water part by 0.15 ← ← ← ← Agent mass Curing Polyisocyanate MDI part by 89.6 ← ← ← ← Agent mass Property Tensile Initial MPa 2 2.sub.  2.sub.  2.sub.  2.sub.  Strength After 400-hour MPa 1 1.2 1.2 1.2 1.1 Light Resistance Test Percent % 51 62   60   62   59   Retention Evaluation Δ ◯ ◯ ◯ ◯ Appearance Grade 3 3.sub.  3.sub.  3.sub.  3.sub.  Evaluation X X X X X Example 1 Example 2 Example 3 Example 4 Formulation Main Base PPG part by 91 ← ← ← Agent Polyol mass Crosslinking Low-molecular- part by 15.5 ← ← ← Agent weight Diol mass Catalyst Amine part by 6.8 ← ← ← mass Foam Silicone part by 0.7 ← ← ← Atabilizer mass Ultraviolet Tinuvin213 part by 1.6 2 1.5 2.sub.  Absorber mass Photostabilizer Tinuvin765 part by 1.2 1 1.5 1.5 mass Antioxidant Irganox1135 part by 0.2 .sub. 0.2 0.2 0.2 mass Pigment Carbon part by 15 ← ← ← Black mass Foaming Water part by 0.15 ← ← ← Agent mass Curing Polyisocyanate MDI part by 89.6 ← ← ← Agent mass Property Tensile Initial MPa 1.8 2 2.sub.  2.sub.  Strength After 400-hour MPa 1.5 .sub. 1.1 1.1 1.3 Light Resistance Test Percent % 63 55  58   65   Retention Evaluation ◯ ◯ ◯ ◯ Appearance Grade 4 4 4.sub.  4.sub.  Evaluation ◯ ◯ ◯ ◯

[0050] [Main Agent (Polyol Component)]

[0051] The base polyol is PPG having an average molecular weight of 5,000.

[0052] The crosslinking agent is a low-molecular-weight diol and is used for adjustment of hardness.

[0053] The catalyst is an amine catalyst and is used for enhancing reactivity.

[0054] The foam stabilizer is a silicone foam stabilizer and is used for controlling bubble formation.

[0055] The ultraviolet absorber is a benzotriazole ultraviolet absorber. Trade name “Tinuvin 213” available from BASF Japan Ltd. was used.

[0056] The photostabilizer is a hindered amine photostabilizer. Trade name “Tinuvin 765” available from BASF Japan Ltd. was used.

[0057] The antioxidant used was trade name “Irganox 1135” available from BASF Japan Ltd.

[0058] The pigment contains carbon black as a main component. Trade name “NRC-F7DT3” available from Nippon Pigment Company Limited was used.

[0059] The foaming agent is water.

[0060] [Curing Agent (Polyisocyanate Component)] The polyisocyanate is diphenylmethane diisocyanate (MDI).

[0061] The molding apparatus used is described in Japanese Unexamined Patent Application Publication No. 2001-96544 (JP 2001-96544 A) by the present applicant. Briefly, as shown in FIGS. 3A and 3B, the molding apparatus includes a molding die 10 composed of two separate dies; a vacuum box 14 wherein the molding die 10 can be disposed; a vacuum pump 15 for vacuum suction in the vacuum box 14; and a material ejector 16 for ejecting a polyurethane material. The molding die 10 includes an upper die 11 and a lower die 12, and the facing surfaces of these dies have concave portions to form a ring-shaped cavity 13 during attachment of the dies.

[0062] The core 4 was placed in the molding die 10, and the main agent and the curing agent were mixed by the material ejector 16 and injected into the cavity 13 wherein the ring section 7 was set. The polyurethane material was injected from the gate on the left side into the cavity 13 so as to flow in two different directions, and the cavity 13 was filled with foamed material. Subsequently, the different material flows were converged at the final filling position L on the right side, and the material was slightly ejected from the vent. The injected polyurethane material became a highly foamed core foam at a position away from the molding surface, and became a lowly foamed skin layer at a position in contact with the molding surface, to thereby form a polyurethane coating. After the polyurethane material was cured, the resultant steering wheel was removed from the die.

[0063] Each of the polyurethane coatings of Examples 1 to 4 and Comparative Examples 1 to 5 was subjected to measurement of the properties described below.

[0064] [1] Thickness of Skin Layer

[0065] Test pieces were cut out from the polyurethane coating at the surface and at depths of 1.5 mm, 4.5 mm, 6 mm, and 7.5 mm from the surface. The specific gravity of each of the test pieces was measured according to JIS 28807. The results of measurement in Example 1 are shown in the graph of FIG. 2. The approximation described in the graph was assumed to be effective, and the thickness was calculated from the same approximation. As described above, the skin layer ranges from the surface to a depth at which the specific gravity is 90% (1.0) of the specific gravity at the surface (1.1). Thus, the thickness of the skin layer was 150 μm. Similarly, the thickness of the skin layer was 150 μm in Examples 2 to 4 and Comparative Examples 1 to 5.

[0066] [2] Tensile Strength

[0067] According to JIS K6251, a dumbbell No. 1 test piece (including the surface skin layer) was cut out from each of the aforementioned initial polyurethane coating after molding and the polyurethane coating after the following light resistance test, and the tensile strength of the test piece was measured.

[0068] The light resistance test was performed on a 10 cm length sample cut out from the polyurethane coating with a tester “UV Fade Meter U48B” available from Suga Test Instruments Co., Ltd. through irradiation of ultraviolet rays at an irradiation intensity of 500 W/m.sup.2 for 400 hours (back panel temperature of the tester: 83° C.). These test conditions assume the use in the market for three years. A dumbbell No. 1 test piece was cut out from the tested sample.

[0069] The thus-measured tensile strength is shown in Table 1 above. The tensile strength was evaluated as good (0) when the percent retention of tensile strength before and after the light resistance test was 53% or more, or evaluated as fail (A) when the percent retention was less than 53% (preferably 55% or more).

[0070] [3] Appearance

[0071] The appearance of the polyurethane coating was observed after the aforementioned light resistance test. According to the following criteria, the appearance was evaluated as good (◯) in the case of Grade 4 or higher, or evaluated as fail (×) in the case of Grade 3 or lower. The results are shown in Table 1 above.

[0072] Grade 1: Abnormality is quite severe.

[0073] Grade 2: Abnormality is severe.

[0074] Grade 3: Abnormality is subtle, but clearly visible.

[0075] Grade 4: Abnormality is slightly observed, but hardly noticeable.

[0076] Grade 5: No abnormality is observed.

[0077] The present invention is not limited to the aforementioned Examples, and may be appropriately modified and embodied without departing from the spirit of the invention.

REFERENCE SIGNS LIST

[0078] 1 Foamed polyurethane coating [0079] 2 Core foam [0080] 3 Skin layer [0081] 4 Core [0082] 7 Ring section