Split-Gate, Twin-Bit Non-volatile Memory Cell
20170317093 · 2017-11-02
Inventors
Cpc classification
H01L29/40114
ELECTRICITY
G11C16/0433
PHYSICS
H01L29/42328
ELECTRICITY
International classification
H01L29/423
ELECTRICITY
Abstract
A memory device that includes a substrate of semiconductor material of a first conductivity type, first and second regions spaced apart in the substrate and having a second conductivity type different than the first conductivity type, with a continuous channel region in the substrate extending between the first and second regions. A first floating gate is disposed over and insulated from a first portion of the channel region adjacent to the first region. A second floating gate is disposed over and insulated from a second portion of the channel region adjacent to the second region. A word line gate is disposed over and insulated from a third portion of the channel region between the first and second channel region portions. A first erase gate disposed over and insulated from the first region. A second erase gate disposed is over and insulated from the second region.
Claims
1. A memory device, comprising: a substrate of semiconductor material of a first conductivity type; first and second regions spaced apart in the substrate and having a second conductivity type different than the first conductivity type, with a continuous channel region in the substrate extending between the first and second regions; a first floating gate disposed over and insulated from a first portion of the channel region adjacent to the first region; a second floating gate disposed over and insulated from a second portion of the channel region adjacent to the second region; a word line gate disposed over and insulated from a third portion of the channel region between the first and second channel region portions; a first erase gate disposed over and insulated from the first region; and a second erase gate disposed over and insulated from the second region.
2. The memory device of claim 1, wherein the first floating gate is partially disposed over and insulated from the first region, and the second floating gate is partially disposed over and insulated from the second region.
3. The memory device of claim 1, wherein the first erase gate includes a notch facing an edge of the first floating gate, and wherein the second erase gate includes a notch facing an edge of the second floating gate.
4. The memory device of claim 1, wherein: the word line gate is insulated from the first floating by first insulation, the first floating gate is insulated from the first erase gate by second insulation, and the first insulation is thicker than the second insulation; and the word line gate is insulated from the second floating by third insulation, the second floating gate is insulated from the second erase gate by fourth insulation, and the third insulation is thicker than the fourth insulation.
5. The memory device of claim 1, wherein: the first floating gate includes a first upper surface that slopes downwardly as the first upper surface extends away from the first erase gate; and the second floating gate includes a second upper surface that slopes downwardly as the second upper surface extends away from the second erase gate.
6. The memory device of claim 1, further comprising: a first coupling gate disposed over and insulated from the first floating gate; and a second coupling gate disposed over and insulated from the second floating gate.
7. The memory device of claim 6, further comprising: control circuitry configured to: program the first floating gate by applying a positive voltage to the first erase gate, a zero voltage to the second erase gate, a positive voltage to the word line gate, a positive voltage to the first coupling gate, a positive voltage to the second coupling gate, a positive voltage to the first region and a current to the second region; read the first floating gate by applying a zero voltage to the first and second erase gates, the first coupling gate and the first region, a positive voltage to the word line gate, a positive voltage to the second coupling gate, and a positive voltage to the second region; and erase the first floating gate by applying a positive voltage to the first erase gate and a negative voltage to the first coupling gate.
8. The memory device of claim 1, further comprising: control circuitry configured to: program the first floating gate by applying a positive voltage to the first erase gate, a zero voltage to the second erase gate, a positive voltage to the word line gate, a positive voltage to the first region and a current to the second region; read the first floating gate by applying a zero voltage to the first erase gate and the first region, a positive voltage to the second erase gate, a positive voltage to the word line gate and a positive voltage to the second region; and erase the first floating gate by applying a positive voltage to the first erase gate.
9. A method of forming a pair of non-volatile memory cells comprising: forming a first insulation layer on a semiconductor substrate; forming a first polysilicon layer on the first insulation layer in a first polysilicon deposition process; forming spaced apart first and second insulation blocks on the first polysilicon layer, the first insulation block having a first side facing the second insulation block and a second side facing away from the second insulation block, and the second insulation block having a first side facing the first insulation block and a second side facing away from the first insulation block; removing a portion of the first polysilicon layer disposed between the first and second insulation blocks while maintaining portions of the first polysilicon layer disposed underneath the first and second insulation blocks and adjacent the second sides of the first and second insulation blocks; removing the portions of the first polysilicon layer adjacent the second sides of the first and second insulation blocks while maintaining a pair of polysilicon blocks of the first polysilicon layer each disposed under one of the first and second insulation blocks; forming a first drain region in the substrate and adjacent the second side of the first insulation block; forming a second drain region in the substrate and adjacent the second side of the second insulation block; forming a second polysilicon layer over the substrate and the first and second insulation blocks in a second polysilicon deposition process; and removing portions of the second polysilicon layer while maintaining a first polysilicon block, a second polysilicon block and a third polysilicon block of the second polysilicon layer, wherein: the first polysilicon block is disposed between the first and second insulation blocks, the second polysilicon block is disposed over the first drain region, and the third polysilicon block is disposed over the second drain region; wherein the substrate includes a continuous channel region extending between the first and second drain regions.
10. The method of claim 9, wherein one of the pair of polysilicon blocks is partially disposed over and insulated from the first drain region, and the other one of the pair of polysilicon blocks is partially disposed over and insulated from the second drain region.
11. The method of claim 9, wherein the second polysilicon block includes a notch facing an edge of the first floating gate, and wherein the second erase gate includes a notch facing an edge of the second floating gate.
12. The method of claim 9, further comprising: forming a fourth polysilicon block that is disposed over and insulated from one of the pair of polysilicon blocks and under the first insulation block; forming a fifth polysilicon block that is disposed over and insulated from the other one of the pair of polysilicon blocks and under the second insulation block.
13. The method of claim 9, further comprising: removing the first polysilicon block; forming a metal block between the first and second insulation blocks; and forming a layer of high-K insulation material between the metal block and the substrate and between the metal block and the first and second insulation blocks.
14. The method of claim 9, wherein the first and second insulation blocks are spacers.
15. The method of claim 9, wherein before the forming of the first and second insulation blocks, further comprising: performing a poly slope etch to an upper surface of the first polysilicon layer, such that the upper surface included downwardly sloping portions, wherein the first and second insulation blocks are formed on the sloping portions.
16. A method of forming a pair of non-volatile memory cells comprising: forming a first insulation layer on a semiconductor substrate; forming a first polysilicon layer on the first insulation layer in a first polysilicon deposition process; forming an insulation layer stack on the first polysilicon layer; forming a second polysilicon layer on the insulation layer stack; forming spaced apart first and second insulation blocks on the second polysilicon layer, the first insulation block having a first side facing the second insulation block and a second side facing away from the second insulation block, and the second insulation block having a first side facing the first insulation block and a second side facing away from the first insulation block; removing portions of the second polysilicon layer, the insulation layer stack and the first polysilicon layer disposed between the first and second insulation blocks and adjacent the second sides of the first and second insulation blocks, while maintaining a pair of polysilicon blocks of the first polysilicon layer each disposed under one of the first and second insulation blocks; forming a first drain region in the substrate and adjacent the second side of the first insulation block; forming a second drain region in the substrate and adjacent the second side of the second insulation block; forming a third polysilicon layer over the substrate and the first and second insulation blocks in a second polysilicon deposition process; and removing portions of the third polysilicon layer while maintaining a first polysilicon block, a second polysilicon block and a third polysilicon block of the third polysilicon layer, wherein: the first polysilicon block is disposed between the first and second insulation blocks, the second polysilicon block is disposed over the first drain region, and the third polysilicon block is disposed over the second drain region; wherein the substrate includes a continuous channel region extending between the first and second drain regions.
17. The method of claim 16, further comprising: forming first insulation between the first polysilicon block and the pair of polysilicon blocks; forming second insulation between the second polysilicon block and one of the pair of polysilicon blocks; forming third insulation between the third polysilicon block and the other of the pair of polysilicon blocks; wherein the first insulation is thicker than the second insulation and the third insulation.
18. A method of operating a memory device that includes a substrate of semiconductor material of a first conductivity type, first and second regions spaced apart in the substrate and having a second conductivity type different than the first conductivity type with a continuous channel region in the substrate extending between the first and second regions, a first floating gate disposed over and insulated from a first portion of the channel region adjacent to the first region, a second floating gate disposed over and insulated from a second portion of the channel region adjacent to the second region, a word line gate disposed over and insulated from a third portion of the channel region between the first and second channel region portions, a first erase gate disposed over and insulated from the first region, a second erase gate disposed over and insulated from the second region, a first coupling gate disposed over and insulated from the first floating gate, and a second coupling gate disposed over and insulated from the second floating gate, the method comprising: programming the first floating gate by applying a positive voltage to the first erase gate, a zero voltage to the second erase gate, a positive voltage to the word line gate, a positive voltage to the first coupling gate, a positive voltage to the second coupling gate, a positive voltage to the first region and a current to the second region; reading the first floating gate by applying a zero voltage to the first and second erase gates, the first coupling gate and the first region, a positive voltage to the word line gate, a positive voltage to the second coupling gate, and a positive voltage to the second region; and erasing the first floating gate by applying a positive voltage to the first erase gate and a negative voltage to the first coupling gate.
19. A method of operating a memory device that includes a substrate of semiconductor material of a first conductivity type, first and second regions spaced apart in the substrate and having a second conductivity type different than the first conductivity type with a continuous channel region in the substrate extending between the first and second regions, a first floating gate disposed over and insulated from a first portion of the channel region adjacent to the first region, a second floating gate disposed over and insulated from a second portion of the channel region adjacent to the second region, a word line gate disposed over and insulated from a third portion of the channel region between the first and second channel region portions, a first erase gate disposed over and insulated from the first region, and a second erase gate disposed over and insulated from the second region, the method comprising: programming the first floating gate by applying a positive voltage to the first erase gate, a zero voltage to the second erase gate, a positive voltage to the word line gate, a positive voltage to the first region and a current to the second region; reading the first floating gate by applying a zero voltage to the first erase gate and the first region, a positive voltage to the second erase gate, a positive voltage to the word line gate and a positive voltage to the second region; and erasing the first floating gate by applying a positive voltage to the first erase gate.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
[0020] The present invention is a memory cell design, architecture and method of manufacture of a split-gate, two bit memory cell design. Referring to
[0021] Photoresist material (not shown) is coated on the structure, and a photolithography masking step is performed exposing selected portions of the photoresist material. The photoresist is developed such that portions of the photoresist are removed. Using the remaining photoresist as a mask, the structure is etched. Specifically, nitride layer 16, poly layer 13 and insulating layer stack 11 are anisotropically etched (using poly layer 14 as an etch stop), leaving pairs of nitride blocks 16 and poly blocks 13 as shown in
[0022] After removal of photoresist 18, spacers 20 are then formed on the sides of the structure. Formation of spacers is well known in the art, and involves the deposition of a material over the contour of a structure, followed by an anisotropic etch process, whereby the material is removed from horizontal surfaces of the structure, while the material remains largely intact on vertically oriented surfaces of the structure (with a rounded upper surface). Spacers 20 can be oxide or oxide-nitride. The resultant structure is shown in
[0023] After removal of photoresist 22, an oxide layer is formed over the structure, including oxide layer 26 along the sides and top of the structures. A photoresist coating and photolithography masking step is used to cover the structure with photoresist except for the inner region. An oxide anisotropic etch (e.g. dry anisotropic etch) is then used to remove the oxide over the substrate 10. After removal of photoresist, an oxide layer 15 is grown over the structure in the inner region, which thickens oxide layer 12 over the substrate 10 in the outer regions, as shown in
[0024] Optionally, poly block 28 can be replaced with a metal block for improved conductivity as follows. A photoresist coating and masking process are used to cover the structure with photoresist except for the inner region. Poly and oxide etches are used to remove the poly block 28 and the oxide layers 15 and 26 from the inner region. An insulation layer 32 is formed on the substrate and exposed structure sidewalls in the inner region. Layer 32 is preferably a high K material (i.e. having a dielectric constant K greater than that of oxide, such as HfO2, ZrO2, TiO2, etc.). A metal deposition and etch back are then used to form a block of metal material 34 in the inner region (i.e. on and alongside the high K insulation layer 32). Preferably, CMP is used to planarize the top surfaces. The resulting structure is shown in
[0025] The final 2-bit memory cell structure is shown in
[0026] Table 1 below illustrates exemplary operational voltages for program, read and erase operations of the two-bit memory cell.
TABLE-US-00001 TABLE 1 EG EG WL CG CG BL BL 30A 30B 28 13A 13B 24A 24B Program 4.5 V 0 1 V 10.5 V 4.5 V 4.5 V −1 uA bit 1 Program 0 4.5 V 1 V 4.5 V 10.5 V −1 uA 4.5 V bit 2 Read bit 1 0 0 Vcc 0 4.5 V 0 1 V Read bit 2 0 0 Vcc 4.5 V 0 1 V 0 Erase both 8.5 V 8.5 V 0 −7 V −7 V 0 0 bits
To program floating gate 14A, voltage 4.5V is applied to erase gate 30A and voltage 10.5V is applied to coupling gate 13A which are capacitively coupled to floating gate 14A. A voltage of 1V is applied to the word line gate 34 which turns on the underlying channel portion. Voltage 4.5V is applied to coupling gate 13B which is capacitively coupled to floating gate 14B to turn on the underlying channel portion. Voltage 4.5V is applied to bit line 24A and −1 uA on bit line 24B. Electrons travel from bit line 24B toward bit line 24A, and inject themselves onto floating gate 14A because of the positive voltage capacitively coupled thereto by erase gate 30A. Floating gate 14B is similarly programmed.
[0027] To erase the floating gates 14A and 14B, a voltage of 8.5 volts is applied to the erase gates 30A and 30B, and a negative voltage of −7V is applied to the coupling gate 13A and 13B, which causes electrons to tunnel through the insulation from the floating gates 14 to the erase gates 30.
[0028] To read floating gate 14A, Vcc is applied to word line 34 which turns on the underlying channel portion. A voltage of 1V is applied to the bit line 24B and zero volts applied to bit line 24A. A 4.5V voltage is applied to coupling gate 13B, which is capacitively coupled to floating gate 14B (turning on the underlying channel region portion). Current will flow through the channel if floating gate 14A is erased (i.e., erased state will have a positive voltage on floating gate 14A and therefore the underlying channel region portion is turned on), and current will not flow through the channel if floating gate 14A is programmed (i.e. is programmed with electrons sufficient to prevent turning on the underlying channel region portion). Floating gate 14B is similarly read.
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[0031] After removal of photoresist 44, oxide 48 is formed on the structure, which removes exposed portions of oxide layer 12 on the substrate. A photoresist coating and photolithography masking process is used to open the inner region, but leave the outer regions covered by photoresist. A oxide anisotropic etch is then used to remove the oxide 12 over the substrate 10 in the inner region. After removal of the photoresist, an oxide layer 50 (e.g. by thermal oxidation) is grown in the inner region, which thickens oxide layer 12 over the substrate 10 in the outer regions. A polysilicon deposition and etch back or CMP is used to form a layer of polysilicon in the inner and outer regions. A photoresist coating and photolithography masking, and polysilicon etch, are used to define the outer edges of the polysilicon layer in the outer regions. The resulting structure is shown in
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TABLE-US-00002 TABLE 2 EG 30A EG 30B WL 34 BL 24A BL 24B Program bit 1 HV1 0 1 V HV2 −1 uA Program bit 2 0 HV1 1 V −1 uA HV2 Read bit 1 0 Vegr Vcc 0 Vblr Read bit 2 Vegr 0 Vcc Vblr 0 Erase both bits 11.5 V 11.5 V 0 0 0
[0035] Control circuitry 96 preferably (but not necessarily) formed on the same substrate 10 (as shown in
[0036] It is to be understood that the present invention is not limited to the embodiment(s) described above and illustrated herein, but encompasses any and all variations falling within the scope of the appended claims. For example, references to the present invention herein are not intended to limit the scope of any claim or claim term, but instead merely make reference to one or more features that may be covered by one or more of the claims. Materials, processes and numerical examples described above are exemplary only, and should not be deemed to limit the claims. Further, as is apparent from the claims and specification, not all method steps need be performed in the exact order illustrated or claimed, but rather in any order that allows the proper formation of the memory cell array of the present invention. Lastly, single layers of material could be formed as multiple layers of such or similar materials, and vice versa.
[0037] It should be noted that, as used herein, the terms “over” and “on” both inclusively include “directly on” (no intermediate materials, elements or space disposed there between) and “indirectly on” (intermediate materials, elements or space disposed there between). Likewise, the term “adjacent” includes “directly adjacent” (no intermediate materials, elements or space disposed there between) and “indirectly adjacent” (intermediate materials, elements or space disposed there between), “mounted to” includes “directly mounted to” (no intermediate materials, elements or space disposed there between) and “indirectly mounted to” (intermediate materials, elements or spaced disposed there between), and “electrically coupled” includes “directly electrically coupled to” (no intermediate materials or elements there between that electrically connect the elements together) and “indirectly electrically coupled to” (intermediate materials or elements there between that electrically connect the elements together). For example, forming an element “over a substrate” can include forming the element directly on the substrate with no intermediate materials/elements there between, as well as forming the element indirectly on the substrate with one or more intermediate materials/elements there between.