METHOD FOR MANUFACTURING MOLTEN GALVANIZED STEEL SHEET
20220056570 · 2022-02-24
Inventors
Cpc classification
B05B1/10
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
The present invention relates to a molten metal plated steel sheet manufacturing method for cooling a molten galvanized layer with high efficiency when manufacturing a molten galvanized steel sheet, and the purpose of the present invention is to provide a method for manufacturing a molten galvanized plating, wherein a molten galvanized steel sheet having an aesthetically pleasing surface without fitting defects, drop mark defects, and linear comb-pattern defects can be stably obtained by cooling a galvanized layer with high efficiency during a molten metal plated steel sheet manufacturing process. This method for manufacturing a molten galvanized steel sheet having excellent surface properties is characterized by comprising the steps in which a molten galvanized layer is formed on the surface of a steel sheet while the steel sheet passes through a galvanizing pot, the thickness of the galvanized layer formed on the surface of the steel sheet is adjusted while the steel sheet passes through a gas wiping device, the steel sheet that has had the thickness of the galvanized layer adjusted undergoes a primary cooling while passing through a bottom cooler, and the galvanized steel sheet that has undergone the primary cooling undergoes a secondary cooling while passing through a cooling chamber, wherein: the primary cooling is performed with cooling air blown from the bottom cooler until right before a galvanizing solution of the galvanized layer attached to the surface of the steel sheet becomes solidified, the amount of air blown being adjusted according to the temperature of the galvanized layer attached to the surface of the steel sheet; and the secondary cooling is performed with ionic air generated from an ionic air generator provided in the cooling chamber and a spray solution sprayed from a solution atomization part, the secondary cooling being performed from the start of the solidification of the galvanizing solution until the end of the solidification, and the cooling chamber cooling the galvanized steel sheet while moving up and down according to the temperature of the galvanized layer attached to the surface of the galvanized steel sheet.
Claims
1. A method of manufacturing a hot-dip galvanized steel sheet having excellent surface quality, in which: a hot-dip galvanized layer is formed on a surface of a steel sheet as the steel sheet passes through a galvanizing pot; a thickness of the galvanized layer formed on the surface of the steel sheet is adjusted as the galvanized layer passes through a gas wiping apparatus; the steel sheet whose galvanized layer thickness is adjusted is primarily cooled while passing through a bottom cooler; and the primarily cooled galvanized steel sheet is secondarily cooled while passing through a cooling chamber, wherein the primary cooling is carried out using cooling air supplied from the bottom cooler until immediately before a galvanizing solution in the galvanized layer attached to the surface of the steel sheet solidifies, and a volume of the air is adjusted according to a temperature of the galvanized layer attached to the surface of the steel sheet, and the secondary cooling is carried out from a time point at which the solidification of the galvanizing solution in the galvanized layer begins to a time point at which the solidification ends, by using ionic wind generated by an ionic-wind generator provided in the cooling chamber and a solution sprayed from a solution atomizing unit, and the cooling chamber is moved up or down according to the temperature of the galvanized layer attached to the surface of the steel sheet being galvanized.
2. The method of claim 1, wherein the adjustment of the volume of the air of the bottom cooler and the up or down movement of the cooling chamber are controlled by a separately provided control unit in accordance with a relative relationship between the temperature of the galvanized layer attached to the surface of the steel sheet and a reference temperature set according to a condition of the galvanized layer, and a temperature of the steel sheet entering the cooling chamber is 419° C. or more, and a temperature of the steel sheet exiting the cooling chamber is 418° C. or less.
3. The method of claim 2, wherein the temperature of the galvanized layer attached to the surface of the steel sheet is measured by optical thermometers set at an emissivity of 0.12 and installed above and below the cooling chamber, and a reference temperature for initiation of the solidification is 340° C., and a reference temperature for termination of the solidification is 380° C.
4. The method of claim 3, wherein the volume of the air of the bottom cooler is controlled as follows: when T.sub.pt-T.sub.pb is 20° C. or less, and at the same time, T.sub.pb and T.sub.pt are greater than Ts, or when T.sub.pt-T.sub.pb is greater than 20° C., and at the same time, T.sub.pb is smaller than Tl, and T.sub.pt is between Ts and Tl, the volume of the air of the bottom cooler is reduced; when T.sub.pt-T.sub.pb is 20° C. or less, and at the same time, T.sub.pb is smaller than Ts, and T.sub.pt is greater than Ts, the volume of the air of the bottom cooler is increased; and when T.sub.pt-T.sub.pb is greater than 20° C., and at the same time, T.sub.pb is smaller than Tl, and T.sub.pt is greater than Ts, the volume of the air of the bottom cooler is maintained, (wherein, T.sub.pt is a temperature measured by the optical thermometer set at an emissivity of 0.12 and installed above the cooling chamber, T.sub.pb is a temperature measured by the optical thermometer set at an emissivity of 0.12 and installed below the cooling chamber, Tl is a reference temperature for a molten galvanized layer input to the control unit, and Ts is a reference temperature for a solidified galvanized layer input to the control unit).
5. The method of claim 3, wherein the up or down movement of the cooling chamber is controlled as follows: when T.sub.pt-T.sub.pb is greater than 20° C., and at the same time, T.sub.pb is smaller than Tl, and T.sub.pt is between Ts and Tl, the position of the cooling chamber is maintained; when T.sub.pt-T.sub.pb is 20° C. or less, and at the same time, T.sub.pt and T.sub.pb are greater than Ts, the cooling chamber is moved down, and, after the moving down of the cooling chamber, when T.sub.pt-T.sub.pb is 20° C. or less, and at the same time, T.sub.pb is smaller than Ts, and T.sub.pt is greater than Ts, the cooling chamber is moved further down; and when T.sub.pt-T.sub.pb is greater than 20° C., and at the same time, T.sub.pb is smaller than Tl, and T.sub.pt is between Ts and Tl, the cooling chamber is moved up, (wherein, T.sub.pt is a temperature measured by the optical thermometer set at an emissivity of 0.12 and installed above the cooling chamber, T.sub.pb is a temperature measured by the optical thermometer set at an emissivity of 0.12 and installed below the cooling chamber, Tl is a reference temperature for a molten galvanized layer input to the control unit, and Ts is a reference temperature for a solidified galvanized layer input to the control unit).
6. The method of claim 1, wherein a flow velocity of the ionic wind is increased by air supplied from an air injection device installed at the rear of the ionic-wind generator.
7. The method of claim 1, wherein the ionic wind is generated by the ionic-wind generator in which a direct-current high voltage is superposed with a pulse high voltage.
8. The method of claim 2, wherein a flow velocity of the ionic wind is increased by air supplied from an air injection device installed at the rear of the ionic-wind generator.
9. The method of claim 2, wherein the ionic wind is generated by the ionic-wind generator in which a direct-current high voltage is superposed with a pulse high voltage.
Description
DESCRIPTION OF DRAWINGS
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MODES OF THE INVENTION
[0051] One aspect of the present invention provides a method of manufacturing a hot-dip galvanized steel sheet having excellent surface quality.
[0052] As shown in
[0053] In particular, the primary cooling is carried out using cooling air supplied from the bottom cooler 3 until immediately before a galvanizing solution in the galvanized layer attached to the surface of the steel sheet solidifies, and the air volume is adjusted according to the temperature of the galvanized layer attached to the surface of the steel sheet.
[0054] The secondary cooling is carried out from a time point at which the solidification of the galvanizing solution in the galvanized layer attached to the surface of the steel sheet begins to a time point at which the solidification ends, by using ionic wind generated by an ionic-wind generator 5 provided in the cooling chamber 4 and a solution sprayed from a solution atomizing unit 6, and the cooling chamber 4 is moved up or down according to the temperature of the galvanized layer attached to the surface of the steel sheet being galvanized.
[0055] Hereinafter, the present invention will be described in detail.
[0056] In the present invention, in a hot-dip galvanizing process such as shown in
[0057] The cooling apparatus includes a cooling chamber 4, a chamber vertical driving device 10, and a bottom cooler 3.
[0058] The cooling chamber 4 consists of an ionic-wind generator 5 and a solution atomizing unit 6 configured to spray a solution, and the cooling chamber has the cooling ability to initiate and complete the solidification of a galvanized layer.
[0059] The ionic-wind generator 5 includes a high-voltage charged electrode such as illustrated in
[0060] When electricity is applied to the charged electrode, corona discharge occurs at the charged electrode and thus ionic wind is generated, and since the ionic wind is directed toward the steel sheet, the steel sheet is cooled by the ionic wind.
[0061] The ionic wind is generated as follows. When corona discharge occurs in air, 1 to 2% of the electrical energy is converted into the kinetic energy of gas particles and causes air to flow. That is, ions discharged during the corona discharge collide with air molecules, causing the air molecules to move in the same direction as the ions, and a combination of such movements of the air molecules is finally used as wind power.
[0062] An air injection device 7 may be attached to increase the cooling effect of the ionic wind by supplying air from the outside of the cooling chamber to the inside of the cooling chamber. When air is supplied from the air injection device 7 toward the steel sheet, since the airflow directed toward the steel sheet is increased, the flow velocity of the ionic wind generated in the charged electrode is increased, which is effective for cooling.
[0063] The air injection device is installed at a rear end of the charged electrode, and the distance of the steel sheet to the air injection device should be more than twice the distance of the steel sheet to the charged electrode. When the distance to the air injection device is less than twice the distance to the charged electrode, the ionic wind is not directed toward the steel sheet, reducing the cooling effect.
[0064] In the air injection device 7, air injection holes are arranged in parallel along the width direction of the steel sheet, and one or more slit-type nozzles can be used. In addition, as the air injection device of the present invention, a device capable of causing air to flow toward the steel sheet using a rotating motor and a rotating fan can also be used.
[0065] A solution atomizing unit 6 is installed above, below, or above and below the ionic-wind generator 5. The solution atomizing unit includes a plurality of solution spray nozzles 11 configured to spray a solution into the space between the charged electrode and the steel sheet, the spray angle of which is adjusted so that the solution does not penetrate the charged electrode. That is, in the solution atomizing unit, one or more rows of nozzle bundles, in which two or more solution spray nozzles 11 are horizontally aligned along the width direction of the steel plate, may be provided along the vertical direction.
[0066] The solution spray nozzles of the solution atomizing unit 6 installed above, below, or above and below the corona-charged electrode spray a solution into the space between the charged electrode and the steel sheet at an angle that does not allow the solution to come into contact with the charged electrode or penetrate the charged electrode. Since the direction of spraying is controlled so that the sprayed solution droplets do not come into contact with the charged electrode or penetrate the charged electrode, a drop mark defect, which occurs when a solution condensed and grown into large droplets on a charged electrode adheres to a surface of a steel sheet, can be prevented.
[0067] In addition, since the aqueous solution droplets sprayed into the space between the charged electrode and the steel sheet are moved toward the steel sheet by the ionic wind, the cooling effect is further increased.
[0068] In the solution spraying device, when there are two or more rows of the spray nozzles 11, the spraying angle of the nozzles may be in the range of 0 to 45 degrees with respect to the moving direction of the steel sheet, and different nozzle rows may have different spraying angles.
[0069] As the solution spray nozzle 11 of the present invention, any nozzle which has an air spraying pressure of 1 to 5 kgf/cm.sup.2, sprays a solution by the principle of a siphon, and produces droplets of which at least 99% have a size of 100 μm or less can be used.
[0070] In addition, as the solution spray nozzle used in the cooling apparatus of the present invention, a high-pressure spray nozzle which has an air spraying pressure range of 1 to 5 kgf/cm.sup.2 and a solution spraying pressure range of 1 to 4 kgf/cm.sup.2, and produces droplets of which at least 99% have a size of 100 μm or less can be used. When less than 99% of droplets have a size of 100 μm or less, the large droplets increase the risk of pitting marks. The solution pressurizing device and solution storage tank required for spraying the solution are not particularly limited, and are sufficient if they are types used for typical high-pressure solution spraying.
[0071] According to the experiments of the present inventors, as the intensity of the high voltage increases, the intensity of the ionic wind directed toward a surface of the steel sheet is increased, and thus, the adhesion efficiency of droplets adhering to the steel sheet is increased. In addition, since the amount of aqueous solution droplets adhering to the steel sheet by the ionic wind increases, the cooling effect is increased.
[0072] When a high voltage of −2 to −60 kV is applied to the charged electrode as a voltage for generating ionic wind in the present invention, ionic wind that blows in the direction from the charged electrode to the steel sheet is generated.
[0073] When the voltage is less than −2 kV, it is difficult to design the cooling apparatus because the steel sheet should be placed very close to the charged electrode to generate ionic wind.
[0074] When a peak high voltage is more than −60 kV, the costs of insulating the apparatus are increased. In addition, although there is no problem in generating ionic wind under normal conditions even when only a direct-current power source is used, in some cases, partial discharge may occur due to the sensitive reaction of direct current to irregularities such as projections on an electrode surface, and therefore, there is a probability that the generation of ionic wind becomes non-uniform.
[0075] A more stable ionic wind can be generated by superposing a direct-current high voltage of −1 to −30 kV with a pulse-type high voltage of −1 to −30 kV and using the same as the high voltage for generating ionic wind. That is, when direct-current electricity is superposed with pulse electricity and used, a discharge current is uniformly formed at an electrode surface, and thus, the flow velocity of the ionic wind is stably maintained.
[0076] On the other hand, when only a pulse high voltage is used, a pulse high-voltage generator should be large enough to fully supply the necessary current. When pulse high voltage is superposed to direct-current high voltage and used, a smaller pulse high-voltage generator can be used.
[0077]
[0078] Characteristics of a pulse power source include pulse generation frequency (frequency) and application time (pulse width). The present invention proposes that the characteristics of the pulse high voltage are sufficient if the pulse generation frequency is 10 to 1000 pulses/second and the pulse width is 10 to 100 ms.
[0079]
[0080] In the above, it has been described that the use of direct-current electricity superposed with pulse electricity as proposed in the present invention increases the cooling ability of the cooling chamber by increasing the flow velocity of ionic wind at the same time as increasing the adhesion efficiency of aqueous solution droplets sprayed into the space between the charged electrode and the steel sheet adhering to the steel sheet.
[0081] In order to reduce the occurrence of a linear comb pattern defect using the cooling apparatus, it is preferable that the solidification of the steel sheet begins and ends while the steel sheet passes through the cooling apparatus. That is, since molten zinc containing aluminum at 0.2 to 0.3 wt % typically solidifies at a temperature of about 418 to 419° C., it is preferable that the temperature of the cooling chamber satisfies the above range while the steel sheet passes therethrough. That is, when the steel sheet enters the cooling chamber at a temperature of less than 418° C., or when the steel sheet exits the cooling chamber at a temperature of more than 419° C., the effect of the present invention is reduced.
[0082] The height at which the solidification of the galvanized layer in a molten state occurs while the steel sheet leaving the galvanizing pot moves upward varies depending on the temperature of the steel sheet immersed in the galvanizing bath, the temperature of the galvanizing pot, the thickness of the steel sheet, the amount of attached galvanizing material, the temperature of air in the factory, and the like, and the thicker the steel sheet thickness, or the greater the amount of attached galvanizing material, or the higher the temperature of the galvanizing pot, the higher and more distant from the galvanizing pot the solidification point is. Therefore, it is more effective when there is extra space above and below the cooling chamber and a power generating motor is used to move the cooling chamber to a height where a hot-dip galvanized layer solidifies.
[0083] Since relying on operator experience to locate a point where solidification occurs during the manufacture of a galvanized steel sheet is very cumbersome and may bring a high risk of a difference in galvanized layer quality, in the hot-dip galvanizing process, a non-contact optical thermometer is installed to measure the temperature of the steel sheet, and the cooling chamber is moved up or down accordingly.
[0084] Although it is important to know the exact emissivity of an object to be measured in order to accurately measure the temperature of a steel sheet with the optical thermometer, there is a high level of uncertainty. For example, although it is generally known that the emissivity of a hot-dip galvanized layer is 0.23 and the emissivity of mirror-polished zinc is 0.05, the emissivity actually measured in the galvanizing process is often between 0.09 to 0.12. This is because the emissivity changes depending on the condition of the galvanized layer, and when measuring the temperature of a steel sheet with an optical thermometer, a measurement error inevitably occurs.
[0085]
[0086] The steel sheet temperature measured with a sheathed thermocouple is an actual steel sheet temperature according to measurement principle. When measuring a temperature with an optical thermometer, the steel sheet temperature changes similarly to an actual steel sheet temperature measured with a thermocouple at a temperature of 419° C. or more, and at a temperature of 419° C. (temperature at which the solidification of a galvanized layer starts) or less, the temperature measured with an optical thermometer significantly decreases and thus becomes greatly different from the actual temperature measured with a thermocouple.
[0087]
[0088] Referring to (1) of
[0089] In
[0090] Therefore, when the cooling chamber is driven up or down based on temperature values measured with an optical thermometer, there is a high probability that a product of non-uniform quality will be produced.
[0091] In order to solve this problem, the present invention proposes a new method of driving the cooling chamber up or down.
[0092] The function of the optical thermometer for the purpose of the present invention is not to accurately measure a steel sheet temperature, but to find an exact point where the solidification of the galvanized layer occurs.
[0093] That is, since the emissivity of the galvanized layer is different before and after solidification, there is a point where the measurement error of temperature measurement with an optical thermometer becomes large, and this point corresponds to the point at which the solidification of the galvanized layer occurs.
[0094] As illustrated in
[0095] In the present invention, since the cooling chamber has the cooling ability to initiate and complete the solidification of a galvanized layer therein, the emissivity of the steel sheet is different when the steel sheet enters the cooling chamber and when the steel sheet exits the cooling chamber. Due to this change of emissivity, temperature values measured with the upper and lower optical thermometers are significantly different, even though actual steel sheet temperatures are not significantly different. Therefore, it is possible to locate a point where solidification occurs by locating a point where the difference between temperatures measured with the upper and lower optical thermometers is large.
[0096] When the driving motor control unit 12 of
[0097] The control principle of the driving motor control unit 12 will be described in more detail below.
[0098] The present invention provides a cooling apparatus which includes: a control unit 12 configured to drive a vertical driving device so that the cooling chamber is positioned in a section where a temperature value measured with an optical thermometer installed above, T.sub.pt, and a temperature value measured with a pyrometer installed below, T.sub.pb, are different by at least 20° C.; and a cooling chamber vertical driving device 10.
[0099] When a temperature value measured by an upper optical thermometer is referred to as T.sub.pt, and a temperature value measured by a lower optical thermometer is referred to as T.sub.pb, when T.sub.pt-T.sub.pb is 20° C. or more, it means that the solidification of a galvanized layer starts and ends in the cooling chamber.
[0100] The method of driving the cooling chamber up or down proposed in the present invention can be described below with reference to
[0101] In a continuous hot-dip galvanizing line, the temperature of the steel sheet which has left the galvanizing pot 1 decreases as the steel sheet is cooled while it moves upward. However, when emissivity is set at 0.12 for an optical thermometer, the temperature may be measured as having increased rather than decreased. That is, the temperature of a galvanized layer is measured to be lower than 340° C. in a molten state, and is measured to be 380° C. or more when solidification is completed. Therefore, a reference temperature value Tl representing a molten state in
[0102] In
[0103] (3-3) of
[0104] (3-2) of
[0105] The control logic can be configured as follows, with reference to the illustration of
[0106]
[0107] That is, when T.sub.pt-T.sub.pb is 20° C. or less, and T.sub.pb and T.sub.pt are greater than Ts, the cooling chamber is moved down. After the cooling chamber is moved down, when T.sub.pt-T.sub.pb is 20° C. or less, T.sub.pb is smaller than Ts, and T.sub.pt is greater than Ts, the cooling chamber is moved further down.
[0108] When T.sub.pt-T.sub.pb is greater than 20° C., T.sub.b is smaller than Tl, and T.sub.pt is between Ts and Tl, it means that the cooling chamber has moved down excessively. In this case, the cooling chamber should be moved up.
[0109] When T.sub.pt-T.sub.pb is greater than 20° C., T.sub.pb is smaller than Tl, and T.sub.pt is greater than Ts, it means that solidification occurs inside the cooling chamber. In this case, the steel sheet is cooled while maintaining the position of the cooling chamber.
[0110] In addition, the solidification of the galvanized layer may be carried out in the cooling chamber while maintaining the position of the cooling chamber and controlling the air volume of a bottom cooler 3 of
[0111]
[0112] The following is a control logic for controlling the air volume of the bottom cooler.
[0113] When T.sub.pt-T.sub.pb is 20° C. or less, and T.sub.pb and T.sub.pt are greater than Ts, the air volume of the bottom cooler is reduced.
[0114] When T.sub.pt-T.sub.pb is 20° C. or less, T.sub.pb is smaller than Ts, and T.sub.pt is greater than Ts, the air volume of the bottom cooler is increased.
[0115] When T.sub.pt-T.sub.pb is greater than 20° C., T.sub.pb is smaller than Tl, and T.sub.pt is between Ts and Tl, since it means that the air volume of the bottom cooler is excessively large, the air volume of the bottom cooler is reduced.
[0116] When T.sub.pt-T.sub.pb is greater than 20° C., T.sub.pb is smaller than Tl, and T.sub.pt is greater than Ts, it means that solidification occurs inside the cooling chamber, and in this case, the air volume of the bottom cooler is maintained.
[0117] Although “reference values for T.sub.pt-T.sub.pb” and reference temperatures for Tl and Ts shown in
[0118] In addition, when emissivity is set at any value within the range of 0.04 to 0.3, the “reference value for T.sub.pt-T.sub.pb” may be set at about 20.
[0119] In addition, the Tl and Ts values may be set based on temperatures measured by an optical thermometer before and after solidification while monitoring the condition of the galvanized layer. Once set, the “reference value for T.sub.pt-T.sub.pb” and the Tl and Ts values do not need to be changed unless the optical thermometer fails.
DESCRIPTION OF REFERENCE NUMERALS
[0120] 1: galvanizing pot, 2: gas wiping apparatus, 3: bottom cooler, 4: cooling chamber, 5: ionic-wind generator, 6: solution atomizing unit, 7: air injection device, 8: pyrometer, 9: solution supply device, 10: cooling chamber vertical driving device, 11: solution spray nozzle, 12: control unit, 13: steel sheet, 14: support, 15: wire, 16: high-voltage generating device, 17: charged electrode needle, 18: slit-type nozzle
[0121] T.sub.pt: temperature measured by optical thermometer installed above cooling chamber
[0122] T.sub.pb: temperature measured by optical thermometer installed below cooling chamber
[0123] Tl: reference temperature for molten galvanized layer input to control unit
[0124] Ts: reference temperature for solidified galvanized layer input to control unit