SIDEWARD EMITTING LUMINESCENT STRUCTURES AND ILLUMINATION DEVICE COMPRISING SUCH LUMINESCENT STRUCTURES
20170309797 · 2017-10-26
Inventors
- Dirk Kornelis Gerhardus DE BOER (EINDHOVEN, NL)
- Marcus Antonius VERSCHUUREN (EINDHOVEN, NL)
- JAMIE GóMEZ RIVAS (EINDHOVEN, NL)
- RAHIMZADEH KALALEH RODRIGUEZ (EINDHOVEN, NL)
Cpc classification
H01L33/507
ELECTRICITY
F21K9/68
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F21K9/61
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
H01L2933/0083
ELECTRICITY
International classification
F21K9/61
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F21K9/64
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
Illumination structure (100) and illumination devices comprising such illumination structure are described. The illumination structure comprises a wavelength conversion layer (102) configured for receiving light of at least a first wavelength (108) and converting said received light into light of at least a second wavelength; and, an array of nanoparticles (110) arranged in a plane in close proximity to said wavelength conversion layer, at least part of said array forming a lattice characterized by at least one lattice period, wherein said lattice period is selected such that in operation: localized resonances of said nanoparticles are diffractively coupled into collective resonant modes at said second wavelength in said wavelength conversion layer (102); and, a sideward emitting radiation pattern is generated by said illumination structure that comprises field intensities in one or more directions of large inclination angle Θ.sub.i (114) with respect to said array plane that are larger than field intensities in one or more directions of small inclination angle.
Claims
1. Illumination structure comprising: a wavelength conversion layer configured for receiving light of at least a first wavelength and converting said received light into light of at least a second wavelength; an array of nanoparticles arranged in a plane in contact with or in close proximity to said wavelength conversion layer, at least part of said array forming a lattice characterized by at least one lattice period p, wherein said lattice period is selected such that in operation: resonances of at least part of said nanoparticles are diffractively coupled into one or more collective resonant modes at said second wavelength in said wavelength conversion layer; and, a sideward emitting radiation pattern is generated by said illumination structure, wherein said radiation pattern comprises field intensities in one or more directions of large inclination angle θ.sub.i with respect to said array plane that are larger than field intensities in one or more directions of small inclination angle.
2. Illumination structure according to claim 1, wherein said one or more collective resonant modes comprise one or more surface-lattice resonant modes associated with said nanoparticle array, said at least one lattice period being selected such that at least one of said one or more surface lattice resonant modes is resonant with said light of said second wavelength.
3. Illumination structure according to claim 1, wherein said one or more collective resonant modes comprise one or more waveguide modes associated with said wavelength conversion layer, said at least one lattice period being selected such that at least one of said one or more waveguide modes is resonant with said light of said second wavelength.
4. Illumination structure according to claim 3, wherein at least part of said wavelength conversion layer is in contact with a low-index layer for providing strong waveguide modes in said wavelength conversion layer, the refractive index of said low-index layer being smaller than the refractive index of said wavelength conversion layer.
5. Illumination structure according to claim 3, wherein the thickness of said wavelength conversion layer is selected such that said field intensities in one or more directions of large inclination angle θ.sub.i are enhanced by said at least one of said one or more waveguide modes that is resonant with said light of said second wavelength.
6. Illumination structure according to claim 1, wherein said least one lattice period is selected such that if said wavelength conversion layer is in contact with a light guide at least part of said one or more directions of large inclination angle θ.sub.i are larger than the critical angle for total reflection in said light guide.
7. Illumination structure according to claim 6, wherein said least one lattice period is selected such that:
λ/(n.sub.1+n.sub.2)<Λ<λ/(1+n.sub.2) wherein the lattice distance Λ(φ) is defined as the lattice vector at azimuthal angle φ, n.sub.1 is the refractive index of said wavelength conversion layer, n.sub.2 is the refractive index of said light guide layer and λ is the wavelength of the light of said second wavelength.
8. Illumination structure according to claim 1, wherein said lattice is arranged to have one or more symmetries, preferably said one or more symmetries including a rotational, reflectional, translational, helical, scale and/or fractal symmetry; and/or, wherein said lattice is formed by aperiodic tiling, preferably said aperiodic tiling forming a Penrose lattice.
9. Illumination structure according to claim 1, wherein at least apart of said nanoparticles are metallic nanoparticles or dielectric nanoparticles.
10. Illumination structure according to claim 1, wherein at least part of said nanoparticles have a shape of a (truncated) pyramid or a (truncated) cone, preferably said truncated pyramid having a bottom side length in the range of 100 to 300 nm and a top side length in the range of 30 nm to 250 nm and said truncated cone having a bottom diameter in the range 100 to 300 nm, a top diameter in the range of 30 to 250 nm and a height in the range of 50 to 400 nm.
11. Illumination structure according to claim 1, wherein the thickness of the wavelength conversion layer is selected between 400 and 4000 nm, preferably between 1300 and 1900 nm.
12. Illumination device comprising: at least one light source configured to emit light of at least a first wavelength; and, one or more illumination structures according to claim 1.
13. Illumination device according to claim 12, further comprising: a light guide optically coupled to said illumination structure such that at least part of the light with large inclination angle is injected in said light guide, preferably an optical coupling layer being arranged between said light guide and said illumination structure wherein the refractive index of said coupling layer is selected between the refractive index of said light guide and the refractive index of air.
14. Illumination device according to claim 12, further comprising: one or more reflective members for converting at least part of the sideward emitting light of the illumination structure into a substantially collimated light beam, preferably said one or more reflective members forming an angle-to-area converter, more preferably said one or more reflective members forming a compound parabolic concentrator or an equivalent thereof.
15. Illumination device according to claim 13, wherein at least part of said light guide is configured as a transparent sheet comprising a top surface, a bottom surface and one or more side faces, wherein said top and/or bottom surface comprises one or more light extraction structures for coupling light out of said light guide; or, wherein at least a part of said one of said side faces is coupled to at least one light extraction structure that is configured as an angle-to-area converter of a transparent material, preferably the angle-to-area conversion in said converter being achieved by total internal reflection.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0035]
[0036] The wavelength conversion layer may be configured for receiving light of at least a first wavelength, preferably light in the blue part of the optical spectrum, and converting at least part of said received light into light of at least a second wavelength, preferably light in the red or green part of the optical spectrum. To that end, the wavelength conversion layer may be of a transparent material in which a wavelength converting material is embedded. The wavelength converting material may comprise molecules, ions and/or particles that have the ability to absorb light from at least a first wavelength and to emit light of at least a second wavelength. Typically the wavelength converting material may comprise one or more fluorescent and/or luminescent materials, including phosphors, dyes (e.g. dyes from the Lumogen F series of BASF™ such as Red 305), quantum dots (e.g. CdSe/CdS quantum dots) and/or rare earth ions or combinations thereof that absorb light in the UV or blue part of the electromagnetic spectrum and emit light in parts of the red or green part of the electromagnetic spectrum.
[0037] The transparent material of the wavelength conversion layer may be of suitable (optical grade) polymer that is sufficiency transparent and stable for serving as a matrix (host) material for the wavelength converting material. Examples of suitable optically transparent polymers include polystyrenes, polymethyl methacrylates (PMMA) polycarbonates (PC), polyethylene terephthalate (PET), polyethylene naphthalate (PEN) or derivatives thereof. Alternatively and/or in addition, the transparent material may comprise a transparent inorganic material, e.g. a silica glass or hybrid organic/inorganic networks formed by e.g. a sol-gel method or the like. It is submitted that the wavelength conversion layer in
[0038] The wavelength conversion layer and the nanoparticle array may be formed on a transparent support substrate 112, e.g. a transparent polymer or glass layer. The wavelength conversion layer comprises a light receiving first surface 106 for receiving light 108 of at least a first wavelength originating from a light source 109 e.g. a solid-state light source comprising one or more light emitting diodes and/or lasers.
[0039] The nanoparticle array may comprise nanoparticles that are in close proximity to the wavelength conversion layer. As will be described hereunder in more detail, the nanoparticle array and its optical properties may be characterized by its symmetry (rotational or axial), periodicity, its lattice parameters, particle shape, particle dimensions and/or its dimensions. The nanoparticles may have an asymmetrical shape including (truncated) pyramids, (truncated) cones or cylinders. Typical particle dimensions (width, height, diameter) may range between 20-500 nm. For example, in an embodiment, the nanoparticles may have a shape of a truncated pyramid having a bottom side length in the range of 100 to 300 nm and a top side length in the range of 30 nm to 250 nm. In another embodiment, the nanoparticles may have a shape of a truncated cone having a bottom diameter in the range 100 to 300 nm, a top diameter in the range of 30 to 100 nm and a height in the range of 50 to 400 nm.
[0040] The nanoparticles can resonantly enhance the emission of light in the wavelength conversion layer. For example, metallic nanoparticles exhibit plasmon resonances when exposed to light of a wavelength that is of the order of the dimensions of the nanoparticle. Such metal nanoparticles may comprise Ag, Al, Ga, Cu, Au or alloys thereof. Similarly, dielectric nanoparticles exhibit Mie resonances when exposed to light of a wavelength that is of the order of the dimensions of the nanoparticle. Such dielectric nanoparticles may comprise metal oxide nanoparticles (e.g. Al2O3, Ta2O5, Ti3O5, TiO2, SrTiO3, BaTiO3, ZrO2, Nb2O5, CeO2 and Si3N4), semiconducting (e.g. Si) or insulating (e.g. SiO2, nano-porous siliconoxide (made by templating methods e.g. low K materials know from the semi-conductor industry)=LOW INDEX) nanoparticles and/or polymer nanoparticles including nanoparticles comprising polymethyl methacrylates (PMMA) polycarbonates (PC), polyethylene terephthalate (PET), polyethylene naphthalate (PEN) or derivatives thereof or silicones or fluoropolymers.
[0041] As shown in
[0042]
[0043] One type of resonant mode relates to diffractive coupling of the localized surface plasmon resonance of individual nanoparticles causing collective photonic resonances that are known as surface-lattice resonances (SLRs). Another type of collective resonant modes relates to diffractive coupling of the localized surface to waveguide modes of the wavelength conversion layer. An example of such resonant mode is shown in
[0044] It has been surprisingly found that the nanoparticle array in
[0045] As will be shown hereunder in more detail, emitted light with a large inclination angles, in particular inclination angles equal to or larger than the critical angle of the wavelength conversion layer, may be achieved by controlling the parameters of the nanoparticle array (the symmetry, lattice period, particle shape, particle material) and/or the wavelength conversion layer (material, dimensions).
[0046]
[0047] The nanoparticles were fabricated on a fused silica substrate (n=1.46) and covered with wavelength conversion layer made of a 700 nm thick polystyrene layer (n=1.58) comprising the wavelength conversion material, in this example is the organic luminescent dye F305 that emits red light at a wavelength of 620 nm. The aluminum particles have a truncated conical shape with a height of 150 nm, a 140 nm bottom diameter and 80 nm top diameter.
[0048] The angle-dependent emission is measured by a Fourier microscope using a filter at 620 (±10) nm and immersion oil with refractive index 1.52. The results are shown in
[0049]
[0050] The influence of the inclination angle of the emitted light by the lattice period of the nanoparticle array is further shown in
λ/Λ=|±n.sub.1 sin θ.sub.i±n.sub.2| (1)
where Λ is the lattice distance associated with a lattice vector of length p and azimuthal angle φ, n.sub.1 is the refractive index of the medium into which emission takes place (e.g. the light guide or in case no light guide is used air) and n.sub.2 is the refractive index of the medium for the surface-lattice (Rayleigh) mode (e.g. the wavelength conversion layer).
[0051] Equation (1) yields that for inclination angles larger than the critical angle θc=asin(1/n.sub.1) for total reflection (i.e. θc<θ<90°) the lattice distance Λ(φ) in a certain azimuthal direction should be in the range of:
λ/(n.sub.1+n.sub.2)<Λ<λ/(1+n.sub.2) (2)
[0052] Condition (2) may be applied to arrays of various symmetries. For example, a hexagonal lattice structure comprising a lattice period p as depicted in
[0053] When using n.sub.1=n.sub.2 =1.52 (e.g. PMMA or glass or the like) condition (2) implies for a certain wavelength of interest λ that the lattice period should be within a predetermined range. For example, when selecting λ=620 nm (the wavelength of light that is emitted by a red phosphor) the lattice period p should be within the range of 272<p<284 nm. Similarly, for green light of λ=530 nm that is emitted by a green phosphor the lattice period p should be within the range of: 232<p<243 nm.
[0054]
[0055] As already described above, local resonances of the individual nanoparticles (e.g. plasmon resonances or Mie resonances) may also collectively couple to waveguide modes of the wavelength conversion layer that may exist in cases the refractive index of the wavelength conversion layer is higher than the refractive index of the medium surrounding it.
[0056] Further, for diffractive coupling of local resonances to a waveguide mode, similar diagrams than those depicted in
[0057] Hence, the thickness of the wavelength conversion layer may be optimized such that the photoluminescence is maximally enhanced by collective coupling of localized resonances to waveguide modes at a certain desired frequency (typically the wavelength of the light emitted by the wavelength converting material in the wavelength converting layer).
[0058]
[0059] As shown in
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[0061] The above-described effects also hold for arrays of low-index dielectric nanoparticles, e.g. low-refractive inorganic dielectric nanoparticles such as nanoparticles of [materials] and/or low-refractive organic dielectric nanoparticles such as metal oxide nanoparticles (e.g. A12O3, Ta2O5, Ti3O5, TiO2, SrTiO3, BaTiO3, ZrO2, Nb2O5, CeO2 and Si3N4, semiconducting (e.g. Si) or insulating (e.g. SiO2) nanoparticles and/or polymer nanoparticles, e.g. polymethyl methacrylates (PMMA) polycarbonates (PC), polyethylene terephthalate (PET), polyethylene naphthalate (PEN) or derivatives thereof or silicones or fluoropolymers. The advantage of dielectric nanoparticles is that they do not absorb the light, at least less strongly than metals.
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[0067] In contrast to conventional solid-state luminescent light sources that require inefficient and bulky secondary optics comprising a combination of reflective and diffractive optical elements, the luminescent sideward emitting structure enables the realization of illumination devices that only need one or more reflective elements for the realization of directional light beams. This is particular advantageous in case of high-brightness directional light sources (e.g. for projection), automotive headlights spot lights, etc.
[0068] The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a,” “an,” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
[0069] The corresponding structures, materials, acts, and equivalents of all means or step plus function elements in the claims below are intended to include any structure, material, or act for performing the function in combination with other claimed elements as specifically claimed. The description of the present invention has been presented for purposes of illustration and description, but is not intended to be exhaustive or limited to the invention in the form disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the invention. The embodiment was chosen and described in order to best explain the principles of the invention and the practical application, and to enable others of ordinary skill in the art to understand the invention for various embodiments with various modifications as are suited to the particular use contemplated.