Fulvic Acid Sterilization Deodorant As Well As Preparation Method and Application Thereof

Abstract

The invention discloses a fulvic acid sterilization deodorant as well as a preparation method and application thereof, and belongs to the technical field of deodorants. Natural polymer compound fulvic acid is modified to prepare a fulvic acid surfactant which is compounded with plant extract to prepare the deodorant with good sterilization and deodorization effects. The fulvic acid with strong hydrophilicity is enhanced in surface activity by introducing a lipophilic end through reaction with a cationic surfactant; an emulsifier is introduced to the fulvic acid solution and the plant extract with strong volatility to prolong interaction between deodorant and odor molecules, achieving an efficient removal purpose. The preparation method is simple in process and low in cost, adopts easily-available raw materials, and can achieve large-scale production. The sterilization deodorant prepared has good deodorization and sterilization performances and can be widely applied to the aspects of odor removal, environmental governance, etc.

Claims

1. A fulvic acid sterilization deodorant, comprising the following raw materials in parts by mass: 8-12 parts of a fulvic acid surfactant, 20-40 parts of gleditsia sinensis extract, 10-30 parts of camphor extract, 3-6 parts of ginger extract, 20-44 parts of peppermint extract, 0.1-2 parts of an emulsifier, 1-3 parts of a penetrating agent and 40-60 parts of deionized water.

2. A preparation method for the fulvic acid sterilization deodorant, in parts by mass, comprising the following steps: step 1: taking and completely dissolving 8-12 parts of fulvic acid surfactant into 40-60 parts of deionized water by stirring in a 50° C. water bath to obtain a uniform solution A; step 2: adding 0.1-2 parts of the emulsifier into the solution A, and continuously emulsifying for 30 min at 50° C. to obtain pre-emulsion B; step 3: mixing 20-40 parts of gleditsia sinensis extract, 10-30 parts of camphor extract, 3-6 parts of ginger extract and 20-44 parts of peppermint extract to obtain a mixed solution, and ultrasonically treating the mixed solution for 25-30 min at the normal temperature to obtain a solution C; step 4: adding the solution C and 1-3 parts of the penetrating agent into the pre-emulsion B, and uniformly stirring at the room temperature to obtain the fulvic acid sterilization deodorant.

3. The preparation method for the fulvic acid sterilization deodorant according to claim 2, wherein preparation method for the fulvic acid sterilization deodorant comprises the following steps: reacting fulvic acid and the cationic surfactant for 3-4 h in a 45-60° C. water bath in a mass ratio of 42 to 1, drying the filtrate at 60° C. after vacuum filtration to prepare the fulvic acid sterilization deodorant.

4. The preparation method for the fulvic acid sterilization deodorant according to claim 3, wherein the cationic surfactant is dodecyl trimethylammonium chloride, cetyltrimethylammonium chloride or octadecyl trimethylammonium chloride.

5. The preparation method for the fulvic acid sterilization deodorant according to claim 2, wherein the preparation method for the gleditsia sinensis extract comprises the following steps: cleaning and adding gleditsia sinensis into equal volume of deionized water to soak for 4 h, squeezing and adopting a 100-mesh screen to filter, and concentrating the filtrate to 1.3 g/cm.sup.3, thereby obtaining the gleditsia sinensis extract.

6. The preparation method for the fulvic acid sterilization deodorant according to claim 2, wherein the preparation method for the camphor extract comprises the following steps: crushing camphor to pass through a 80-mesh screen, and mixing camphor powder and petroleum ether in a solid-liquid ratio of 1 to 20 to obtain a mixture, and ultrasonically extracting the mixture for 50 min at 70° C. to obtain the camphor extract.

7. The preparation method for the fulvic acid sterilization deodorant according to claim 2, wherein the preparation method for the ginger extract comprises the following steps: crushing gingers to pass through a 80-mesh screen, mixing the ginger powder with absolute ethyl alcohol in a solid-liquid ratio of 1 to 20 to obtain a mixture, and ultrasonically extracting the mixture for 50 min at 70° C. to obtain the ginger extract.

8. The preparation method for the fulvic acid sterilization deodorant according to claim 2, wherein the preparation method for peppermint extract comprises the following steps: crushing peppermints to pass through a 80-mesh screen, mixing peppermint powder with petroleum ether in a solid-liquid ratio of 1 to 12 to soak at 40° C. to obtain the pepper peppermint extract.

9. The preparation method for the fulvic acid sterilization deodorant according to claim 2, wherein the emulsifier is Tween-20 and the penetrating agent is fatty alcohol polyoxyethylene ether.

Description

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0029] The invention will be further described in detail below in conjunction with specific embodiments, which are for explanation rather than limitation of the invention. The parts involved in the embodiment are all calculated in parts by mass.

Embodiment 1

[0030] Fulvic acid and dodecyl trimethyl ammonium chloride reacted for 3 h in a 45° C. water bath in a mass ratio of 42 to 1, the filtrate was dried after vacuum filtration to obtain a fulvic acid surfactant; gleditsia sinensis was cleaned and added into equal volume of deionized water to soak for 4 h, squeezed and filtered with a 100-mesh screen, and the filtrate was concentrated to 1.3 g/cm.sup.3 to obtain the gleditsia sinensis extract; camphor was crushed to pass through a 80-mesh screen, camphor powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically treated for 50 min at 70° C. to obtain the camphor extract; gingers were crushed to pass through a 80-mesh screen, the ginger powder was mixed with absolute ethyl alcohol in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically extracted for 50 min at 70° C. to obtain the ginger extract; and peppermints were crushed to pass through a 80-mesh screen, peppermint powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 12 to soak at 40° C. to obtain the pepper peppermint extract.

[0031] 8 parts of fulvic acid surfactant was taken and completely dissolved into 40 parts of deionized water by stirring in a 50° C. water bath to obtain a uniform solution A; 0.1 part of the emulsifier was added into the solution A, and continuously emulsified for 30 min at 50° C. to obtain pre-emulsion B; 20 parts of gleditsia sinensis extract, 10 parts of camphor extract, 3 parts of ginger extract and 20 parts of peppermint extract were taken and mixed to obtain a mixed solution, and the mixed solution was ultrasonically treated for 25 min at the normal temperature to obtain a solution C; 1 part of fatty alcohol-polyoxyethylene ether and the solution C were added into the pre-emulsion B, and were uniformly stirred at the room temperature to obtain the fulvic acid sterilization deodorant.

Embodiment 2

[0032] Fulvic acid and dodecyl trimethyl ammonium chloride reacted for 3.5 h in a 50° C. water bath in a mass ratio of 42 to 1, the filtrate was dried after vacuum filtration to obtain a fulvic acid surfactant; gleditsia sinensis was cleaned and added into equal volume of deionized water to soak for 4 h, squeezed and filtered with a 100-mesh screen, and the filtrate was concentrated to 1.3 g/cm.sup.3 to obtain the gleditsia sinensis extract; camphor was crushed to pass through a 80-mesh screen, camphor powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically treated for 50 min at 70° C. to obtain the camphor extract; gingers were crushed to pass through a 80-mesh screen, the ginger powder was mixed with absolute ethyl alcohol in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically extracted for 50 min at 70° C. to obtain the ginger extract; and peppermints were crushed to pass through a 80-mesh screen, peppermint powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 12 to soak at 40° C. to obtain the pepper peppermint extract.

[0033] 10 parts of fulvic acid surfactant was taken and completely dissolved into 50 parts of deionized water by stirring in a 50° C. water bath to obtain a uniform solution A; 1 part of the Tween-20 was added into the solution A, and continuously emulsified for 30 min at 50° C. to obtain pre-emulsion B; 30 parts of gleditsia sinensis extract, 20 parts of camphor extract, 4 parts of ginger extract and 32 parts of peppermint extract were taken and mixed to obtain a mixed solution, and the mixed solution was ultrasonically treated for 30 min at the normal temperature to obtain a solution C; 2 parts of fatty alcohol-polyoxyethylene ether and the solution C were added into the pre-emulsion B, and were uniformly stirred at the room temperature to obtain the fulvic acid sterilization deodorant.

Embodiment 3

[0034] Fulvic acid and dodecyl trimethyl ammonium chloride reacted for 4 h in a 60° C. water bath in a mass ratio of 42 to 1, the filtrate was dried after vacuum filtration to obtain a fulvic acid surfactant; gleditsia sinensis was cleaned and added into equal volume of deionized water to soak for 4 h, squeezed and filtered with a 100-mesh screen, and the filtrate was concentrated to 1.3 g/cm.sup.3 to obtain the gleditsia sinensis extract; camphor was crushed to pass through a 80-mesh screen, camphor powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically treated for 50 min at 70° C. to obtain the camphor extract; gingers were crushed to pass through a 80-mesh screen, the ginger powder was mixed with absolute ethyl alcohol in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically extracted for 50 min at 70° C. to obtain the ginger extract; and peppermints were crushed to pass through a 80-mesh screen, peppermint powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 12 to soak at 40° C. to obtain the pepper peppermint extract.

[0035] 12 parts of fulvic acid surfactant was taken and completely dissolved into 60 parts of deionized water by stirring in a 50° C. water bath to obtain a uniform solution A; 2 part of the Tween-20 was added into the solution A, and continuously emulsified for 30 min at 50° C. to obtain pre-emulsion B; 40 parts of gleditsia sinensis extract, 30 parts of camphor extract, 6 parts of ginger extract and 44 parts of peppermint extract were taken and mixed to obtain a mixed solution, and the mixed solution was ultrasonically treated for 35 min at the normal temperature to obtain a solution C; 3 parts of fatty alcohol-polyoxyethylene ether and the solution C were added into the pre-emulsion B, and were uniformly stirred at the room temperature to obtain the fulvic acid sterilization deodorant.

Embodiment 4

[0036] Fulvic acid and dodecyl trimethyl ammonium chloride reacted for 3 h in a 45° C. water bath in a mass ratio of 42 to 1, the filtrate was dried after vacuum filtration to obtain a fulvic acid surfactant; gleditsia sinensis was cleaned and added into equal volume of deionized water to soak for 4 h, squeezed and filtered with a 100-mesh screen, and the filtrate was concentrated to 1.3 g/cm.sup.3 to obtain the gleditsia sinensis extract; camphor was crushed to pass through a 80-mesh screen, camphor powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically treated for 50 min at 70° C. to obtain the camphor extract; gingers were crushed to pass through a 80-mesh screen, the ginger powder was mixed with absolute ethyl alcohol in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically extracted for 50 min at 70° C. to obtain the ginger extract; and peppermints were crushed to pass through a 80-mesh screen, peppermint powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 12 to soak at 40° C. to obtain the pepper peppermint extract.

[0037] 8 parts of fulvic acid surfactant was taken and completely dissolved into 40 parts of deionized water by stirring in a 50° C. water bath to obtain a uniform solution A; 0.1 part of the Tween-20 was added into the solution A, and continuously emulsified for 30 min at 50° C. to obtain pre-emulsion B; 20 parts of gleditsia sinensis extract, 10 parts of camphor extract, 3 parts of ginger extract and 20 parts of peppermint extract were taken and mixed to obtain a mixed solution, and the mixed solution was ultrasonically treated for 25 min at the normal temperature to obtain a solution C; 1 part of fatty alcohol-polyoxyethylene ether and the solution C were added into the pre-emulsion B, and were uniformly stirred at the room temperature to obtain the fulvic acid sterilization deodorant.

Embodiment 5

[0038] Fulvic acid and dodecyl trimethyl ammonium chloride reacted for 3.5 h in a 50° C. water bath in a mass ratio of 42 to 1, the filtrate was dried after vacuum filtration to obtain a fulvic acid surfactant; gleditsia sinensis was cleaned and added into equal volume of deionized water to soak for 4 h, squeezed and filtered with a 100-mesh screen, and the filtrate was concentrated to 1.3 g/cm.sup.3 to obtain the gleditsia sinensis extract; camphor was crushed to pass through a 80-mesh screen, camphor powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically treated for 50 min at 70° C. to obtain the camphor extract; gingers were crushed to pass through a 80-mesh screen, the ginger powder was mixed with absolute ethyl alcohol in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically extracted for 50 min at 70° C. to obtain the ginger extract; and peppermints were crushed to pass through a 80-mesh screen, peppermint powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 12 to soak at 40° C. to obtain the pepper peppermint extract.

[0039] 10 parts of fulvic acid surfactant was taken and completely dissolved into 50 parts of deionized water by stirring in a 50° C. water bath to obtain a uniform solution A; 1 part of the Tween-20 was added into the solution A, and continuously emulsified for 30 minat 50° C. to obtain pre-emulsion B; 30 parts of gleditsia sinensis extract, 20 parts of camphor extract, 4 parts of ginger extract and 32 parts of peppermint extract were taken and mixed to obtain a mixed solution, and the mixed solution was ultrasonically treated for 30 min at the normal temperature to obtain a solution C; 2 parts of fatty alcohol-polyoxyethylene ether and the solution C were added into the pre-emulsion B, and were uniformly stirred at the room temperature to obtain the fulvic acid sterilization deodorant.

Embodiment 6

[0040] Fulvic acid and dodecyl trimethyl ammonium chloride reacted for 4 h in a 60° C. water bath in a mass ratio of 42 to 1, the filtrate was dried after vacuum filtration to obtain a fulvic acid surfactant; gleditsia sinensis was cleaned and added into equal volume of deionized water to soak for 4 h, squeezed and filtered with a 100-mesh screen, and the filtrate was concentrated to 1.3 g/cm.sup.3 to obtain the gleditsia sinensis extract; camphor was crushed to pass through a 80-mesh screen, camphor powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically treated for 50 min at 70° C. to obtain the camphor extract; gingers were crushed to pass through a 80-mesh screen, the ginger powder was mixed with absolute ethyl alcohol in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically extracted for 50 min at 70° C. to obtain the ginger extract; and peppermints were crushed to pass through a 80-mesh screen, peppermint powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 12 to soak at 40° C. to obtain the pepper peppermint extract.

[0041] 12 parts of fulvic acid surfactant was taken and completely dissolved into 60 parts of deionized water by stirring in a 50° C. water bath to obtain a uniform solution A; 2 parts of the Tween-20 were added into the solution A, and continuously emulsified for 30 min at 50° C. to obtain pre-emulsion B; 40 parts of gleditsia sinensis extract, 30 parts of camphor extract, 6 parts of ginger extract and 44 parts of peppermint extract were taken and mixed to obtain a mixed solution, and the mixed solution was ultrasonically treated for 35 min at the normal temperature to obtain a solution C; 3 parts of fatty alcohol-polyoxyethylene ether and the solution C were added into the pre-emulsion B, and were uniformly stirred at the room temperature to obtain the fulvic acid sterilization deodorant.

Embodiment 7

[0042] Fulvic acid and dodecyl trimethyl ammonium chloride reacted for 3 h in a 45° C. water bath in a mass ratio of 42 to 1, the filtrate was dried after vacuum filtration to obtain a fulvic acid surfactant; gleditsia sinensis was cleaned and added into equal volume of deionized water to soak for 4 h, squeezed and filtered with a 100-mesh screen, and the filtrate was concentrated to 1.3 g/cm.sup.3 to obtain the gleditsia sinensis extract; camphor was crushed to pass through a 80-mesh screen, camphor powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically treated for 50 min at 70° C. to obtain the camphor extract; gingers were crushed to pass through a 80-mesh screen, the ginger powder was mixed with absolute ethyl alcohol in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically extracted for 50 min at 70° C. to obtain the ginger extract; and peppermints were crushed to pass through a 80-mesh screen, peppermint powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 12 to soak at 40° C. to obtain the pepper peppermint extract.

[0043] 8 parts of fulvic acid surfactant was taken and completely dissolved into 40 parts of deionized water by stirring in a 50° C. water bath to obtain a uniform solution A; 0.1 part of the Tween-20 was added into the solution A, and continuously emulsified for 30 min at 50° C. to obtain pre-emulsion B; 20 parts of gleditsia sinensis extract, 10 parts of camphor extract, 3 parts of ginger extract and 20 parts of peppermint extract were taken and mixed to obtain a mixed solution, and the mixed solution was ultrasonically treated for 25 min at the normal temperature to obtain a solution C; and 1 part of fatty alcohol-polyoxyethylene ether and the solution C were added into the pre-emulsion B, and were uniformly stirred at the room temperature to obtain the fulvic acid sterilization deodorant.

Embodiment 8

[0044] Fulvic acid and dodecyl trimethyl ammonium chloride reacted for 3.5 h in a 50° C. water bath in a mass ratio of 42 to 1, the filtrate was dried after vacuum filtration to obtain a fulvic acid surfactant; gleditsia sinensis was cleaned and added into equal volume of deionized water to soak for 4 h, squeezed and filtered with a 100-mesh screen, and the filtrate was concentrated to 1.3 g/cm.sup.3 to obtain the gleditsia sinensis extract; camphor was crushed to pass through a 80-mesh screen, camphor powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically treated for 50 min at 70° C. to obtain the camphor extract; gingers were crushed to pass through a 80-mesh screen, the ginger powder was mixed with absolute ethyl alcohol in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically extracted for 50 min at 70° C. to obtain the ginger extract; and peppermints were crushed to pass through a 80-mesh screen, peppermint powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 12 to soak at 40° C. to obtain the pepper peppermint extract.

[0045] 10 parts of fulvic acid surfactant was taken and completely dissolved into 50 parts of deionized water by stirring in a 50° C. water bath to obtain a uniform solution A; 1 part of the Tween-20 was added into the solution A, and continuously emulsified for 30 min at 50° C. to obtain pre-emulsion B; 30 parts of gleditsia sinensis extract, 20 parts of camphor extract, 4 parts of ginger extract and 32 parts of peppermint extract were taken and mixed to obtain a mixed solution, and the mixed solution was ultrasonically treated for 30 min at the normal temperature to obtain a solution C; 2 parts of fatty alcohol-polyoxyethylene ether and the solution C were added into the pre-emulsion B, and were uniformly stirred at the room temperature to obtain the fulvic acid sterilization deodorant.

Embodiment 9

[0046] Fulvic acid and dodecyl trimethyl ammonium chloride reacted for 4 h in a 60° C. water bath in a mass ratio of 42 to 1, the filtrate was dried after vacuum filtration to obtain a fulvic acid surfactant; gleditsia sinensis was cleaned and added into equal volume of deionized water to soak for 4 h, squeezed and filtered with a 100-mesh screen, and the filtrate was concentrated to 1.3 g/cm.sup.3 to obtain the gleditsia sinensis extract; camphor was crushed to pass through a 80-mesh screen, camphor powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically treated for 50 min at 70° C. to obtain the camphor extract; gingers were crushed to pass through a 80-mesh screen, the ginger powder was mixed with absolute ethyl alcohol in a solid-liquid ratio of 1 to 20 to obtain a mixture, and the mixture was ultrasonically extracted for 50 min at 70° C. to obtain the ginger extract; and peppermints were crushed to pass through a 80-mesh screen, peppermint powder was mixed with petroleum ether in a solid-liquid ratio of 1 to 12 to soak at 40° C. to obtain the pepper peppermint extract.

[0047] 12 parts of fulvic acid surfactant was taken and completely dissolved into 60 parts of deionized water by stirring in a 50° C. water bath to obtain a uniform solution A; 2 parts of the Tween-20 were added into the solution A, and continuously emulsified for 30 min at 50° C. to obtain pre-emulsion B; 40 parts of gleditsia sinensis extract, 30 parts of camphor extract, 6 parts of ginger extract and 44 parts of peppermint extract were taken and mixed to obtain a mixed solution, and the mixed solution was ultrasonically treated for 35 min at the normal temperature to obtain a solution C; and 3 parts of fatty alcohol-polyoxyethylene ether and the solution C were added into the pre-emulsion B, and were uniformly stirred at the room temperature to obtain the fulvic acid sterilization deodorant.

[0048] The preferred embodiments of the invention have been described in detail above, but the invention is not limited to the above-mentioned embodiments. Within the scope of knowledge possessed by those of ordinary skill in the art, various changes can be made without departing from the purpose of the invention. There is no need to and cannot give an exhaustive list of all implementation methods. The obvious changes or modifications derived from this are still within the protection scope of the invention.